CN112323538A - Waterproof fresh-keeping coating, fresh stained paper and preparation method - Google Patents
Waterproof fresh-keeping coating, fresh stained paper and preparation method Download PDFInfo
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- CN112323538A CN112323538A CN202011180606.XA CN202011180606A CN112323538A CN 112323538 A CN112323538 A CN 112323538A CN 202011180606 A CN202011180606 A CN 202011180606A CN 112323538 A CN112323538 A CN 112323538A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N3/00—Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a waterproof fresh-keeping coating, fresh stained paper and a preparation method thereof, wherein the coating is prepared from the following components in parts by weight: 25-55 parts of resin, 3-5 parts of tea polyphenol, 35-65 parts of water, 0.6-9 parts of an antibacterial agent, 0.4-5 parts of a slow release agent and 0.03-1 part of an emulsifier; the preferred scheme is as follows: 45 parts of resin, 4 parts of tea polyphenol, 60 parts of water, 5 parts of an antibacterial agent, 2 parts of a slow release agent and 0.5 part of an emulsifier. The coating formed by coating the waterproof fresh-keeping coating on carriers such as a paper base layer can release tea polyphenol, can effectively inhibit the growth and reproduction of microorganisms, can slow down the respiration of flowers, has antibacterial and fresh-keeping effects on the flowers, can not cause harm to human bodies, has a waterproof function, and can be recycled and pulped again, and the prepared flower paper is degradable, green and pollution-free.
Description
Technical Field
The invention belongs to the technical field of coatings and fresh flower paper, and particularly relates to a waterproof fresh-keeping coating, fresh flower paper and a preparation method thereof.
Background
With the development of networks, the living standard of people is continuously improved, and the living quality has higher requirements. Flowers are used as interspersion in life, and there are different varieties of flowers all over the world, but because of geographical factors, flower lovers cannot feel at a short distance. Flowers often contain more water, and the flowers are rotten due to the water after being stored for a long time. In addition, flowers still have life activity during the storage, absorb oxygen, breathe out carbon dioxide to carry out the in-process of autoxidation, can lead to the temperature to rise constantly, can make the flower dewater and lose original fragrance of flowers, lose look. Therefore, the packaging material is required to have good protection and keep the normal physiological requirements of flowers. However, the applicant found that: the existing materials for flower packaging are mostly plastic packaging films, can not be degraded and recycled, and simultaneously do not play a fresh-keeping role on flowers, such as ventilation and antibacterial performance, so that a flower packaging paper needs to be developed, and the fresh-keeping effect of the flowers and the protection effect are achieved.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a coating which can release tea polyphenol, effectively inhibit the growth and reproduction of microorganisms, slow down the respiration of flowers, play a role in resisting and preserving fresh flowers, has no harm to human bodies and has a waterproof function, fresh stained paper using the waterproof fresh-keeping coating and a preparation method of the fresh stained paper.
In order to solve the technical problems, the invention adopts the following technical scheme:
a waterproof fresh-keeping coating is prepared from the following components in parts by weight: 25-55 parts of resin, 3-5 parts of tea polyphenol, 35-65 parts of water, 0.6-9 parts of an antibacterial agent, 0.4-5 parts of a slow release agent and 0.03-1 part of an emulsifier; the preferred scheme is as follows: 45 parts of resin, 4 parts of tea polyphenol, 60 parts of water, 5 parts of an antibacterial agent, 2 parts of a slow release agent and 0.5 part of an emulsifier.
Further, the resin is at least one of acrylate copolymer, polyvinyl alcohol and ethylene-vinyl acetate copolymer.
Further, the antibacterial agent is at least one of chitosan, sodium benzoate and Chinese medicinal extract.
The flower paper comprises a paper base layer, wherein at least one side surface of the paper base layer is provided with a waterproof fresh-keeping coating, and the waterproof fresh-keeping coating is formed by drying and curing the waterproof fresh-keeping coating.
Further, the surface of one side of the paper base layer, which is provided with the waterproof fresh-keeping coating, is a rough surface, and the waterproof fresh-keeping coating is coated on the rough surface and dried and cured to form the waterproof fresh-keeping coating.
A preparation method of fresh stained paper comprises the following steps:
a1. preparing a waterproof fresh-keeping coating, weighing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier according to the parts by weight, and then fully mixing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier;
a2. coating, namely coating the waterproof fresh-keeping coating on the surface of the paper substrate, wherein the coating weight is 6g/m2-10g/m2And standing at constant temperature and humidity for 2 days to obtain the fresh stained paper with the fresh-keeping function.
Further, the coating manner is one of roller coating, dip coating, painting coating and spray coating.
The invention mainly has the following beneficial effects:
the waterproof fresh-keeping coating is coated on a carrier such as a paper base layer to form a coating, can release tea polyphenol, can effectively inhibit the growth and reproduction of microorganisms, can slow down the respiration of flowers, has the effects of resisting bacteria and keeping fresh of the flowers, does not cause harm to human bodies, has a waterproof function, and can be recycled and pulped to prepare fresh flower paper, so that the fresh flower paper is degradable, green and environment-friendly and pollution-free.
Drawings
FIG. 1 is a schematic view of a partial structure of an embodiment of a flower paper of the present invention;
fig. 2 is a flow chart schematic diagram of a preparation method of fresh stained paper.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
The waterproof fresh-keeping coating provided by the embodiment of the invention is prepared from the following components in parts by weight: 25-55 parts of resin, 3-5 parts of tea polyphenol, 35-65 parts of water, 0.6-9 parts of an antibacterial agent, 0.4-5 parts of a slow release agent and 0.03-1 part of an emulsifier; the preferred scheme is as follows: 45 parts of resin, 4 parts of tea polyphenol, 60 parts of water, 5 parts of an antibacterial agent, 2 parts of a slow release agent and 0.5 part of an emulsifier. Wherein, the resin is preferably at least one of acrylate copolymer, polyvinyl alcohol and ethylene-vinyl acetate copolymer, and the antibacterial agent is preferably at least one of chitosan, sodium benzoate and traditional Chinese medicine extract.
The fresh flower paper comprises a paper base layer 1, wherein at least one side surface (namely, the inner side surface and/or the outer side surface) of the paper base layer 1 is provided with a waterproof fresh-keeping coating 2, and the preferable scheme is that at least the inner side surface is provided with the waterproof fresh-keeping coating 2; the waterproof fresh-keeping coating 2 is formed by drying and curing the waterproof fresh-keeping coating. As shown in fig. 2, the specific preparation method comprises the following steps:
s100, preparing the waterproof fresh-keeping coating, weighing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier according to the parts by weight, and then fully mixing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier.
S200, coating, namely coating the waterproof fresh-keeping coating on the surface of the paper base layer, wherein the coating weight is 6g/m2-10g/m2After being placed for 2 days at constant temperature and humidity, the fresh stained paper with the fresh-keeping function is obtained; wherein the coating may be one of roll coating, dip coating, brush coating, and spray coating.
When the fresh flower paper is used for binding fresh flowers, the waterproof fresh-keeping coating 2 can release tea polyphenol, can effectively inhibit the growth and reproduction of microorganisms, can slow down the respiration of the flowers, has the antibacterial and fresh-keeping effects on the fresh flowers, cannot cause harm to human bodies, has the waterproof function, prevents the paper base layer 1 from being broken due to wet water, and can be recycled and pulped again, so that the fresh flower paper is degradable, green, environment-friendly and pollution-free.
In addition, the surface of one side of the paper base layer 1 with the waterproof fresh-keeping coating 2 of the fresh stained paper is preferably a rough surface, and the waterproof fresh-keeping coating is coated on the rough surface and dried and cured to form the waterproof fresh-keeping coating; the adhesion of the waterproof fresh-keeping coating 2 on the surface of the paper base layer 1 is further enhanced, the separation and the falling are not easy, and the performance is more stable and reliable.
Experiments show that the fresh flower paper and the conventional plastic fresh flower packing paper are respectively wrapped with roses and lily flowers (the roses and the lily flowers are inserted into flower mud with the same specification during wrapping), the flower is placed at normal temperature, and the wilting and withering time of the flowers is recorded, and the results are shown in the following table 1.
TABLE 1
From table 1 it can be seen that: the fresh flower paper bandage has antibacterial and fresh-keeping effects on the roses and the lily, and greatly prolongs the placing time of the roses and the lily.
Of course, the waterproof fresh-keeping coating can also be coated on other carriers (such as vases, paper bags and the like) to form a waterproof fresh-keeping coating, and has the antibacterial and fresh-keeping effects on flowers, vegetables, fruits and the like
While the foregoing is directed to the preferred embodiment of the present invention, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention.
Claims (8)
1. The waterproof fresh-keeping coating is characterized by being prepared from the following components in parts by weight: 25-55 parts of resin, 3-5 parts of tea polyphenol, 35-65 parts of water, 0.6-9 parts of an antibacterial agent, 0.4-5 parts of a slow release agent and 0.03-1 part of an emulsifier.
2. The waterproof fresh-keeping coating material as claimed in claim 1, which is prepared from the following components in parts by weight: 45 parts of resin, 4 parts of tea polyphenol, 60 parts of water, 5 parts of an antibacterial agent, 2 parts of a slow release agent and 0.5 part of an emulsifier.
3. The waterproof fresh-keeping coating material as claimed in claim 1 or 2, wherein the resin is at least one of an acrylate copolymer, polyvinyl alcohol, and an ethylene-vinyl acetate copolymer.
4. The waterproof fresh-keeping coating material as claimed in claim 1 or 2, wherein the antibacterial agent is at least one of chitosan, sodium benzoate and Chinese medicinal extracts.
5. A flower paper, characterized by comprising a paper substrate (1), wherein at least one side surface of the paper substrate (1) is provided with a waterproof fresh-keeping coating (2), and the waterproof fresh-keeping coating (2) is formed by drying and curing the waterproof fresh-keeping coating of any one of claims 1 to 4.
6. Fresh flower paper according to claim 5, characterized in that the paper substrate (1) has a rough surface on the side having the water-proof freshness-retaining coating (2), and the water-proof freshness-retaining paint is coated on the rough surface and dried and cured to form the water-proof freshness-retaining coating.
7. The preparation method of the fresh stained paper is characterized by comprising the following steps:
a1. preparing a waterproof fresh-keeping coating, weighing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier according to the parts by weight in the claims 1-4, and then fully mixing the resin, the tea polyphenol, the water, the antibacterial agent, the slow-release agent and the emulsifier;
a2. coating, namely coating the waterproof fresh-keeping coating on the surface of the paper substrate, wherein the coating weight is 6g/m2-10g/m2And standing at constant temperature and humidity for 2 days to obtain the fresh stained paper with the fresh-keeping function.
8. The decal paper according to claim 7, wherein said coating is one of roller coating, dip coating, brush coating and spray coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011180606.XA CN112323538A (en) | 2020-10-29 | 2020-10-29 | Waterproof fresh-keeping coating, fresh stained paper and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011180606.XA CN112323538A (en) | 2020-10-29 | 2020-10-29 | Waterproof fresh-keeping coating, fresh stained paper and preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN112323538A true CN112323538A (en) | 2021-02-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011180606.XA Pending CN112323538A (en) | 2020-10-29 | 2020-10-29 | Waterproof fresh-keeping coating, fresh stained paper and preparation method |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2028861A (en) * | 2021-06-16 | 2022-12-22 | Wuhan Eudeco Co Ltd | Environmentally friendly coating flower sleeve paper, flower sleeve, manufacturing method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106608442A (en) * | 2015-10-27 | 2017-05-03 | 戚炎思 | Packing carton for transporting fresh flowers |
| CN107620226A (en) * | 2017-10-18 | 2018-01-23 | 常德金德新材料科技股份有限公司 | Mouldproof preservative paper and preparation method thereof |
| CN108060610A (en) * | 2017-12-29 | 2018-05-22 | 常德金德新材料科技股份有限公司 | A kind of mouldproof preservative paper and preparation method thereof |
-
2020
- 2020-10-29 CN CN202011180606.XA patent/CN112323538A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106608442A (en) * | 2015-10-27 | 2017-05-03 | 戚炎思 | Packing carton for transporting fresh flowers |
| CN107620226A (en) * | 2017-10-18 | 2018-01-23 | 常德金德新材料科技股份有限公司 | Mouldproof preservative paper and preparation method thereof |
| CN108060610A (en) * | 2017-12-29 | 2018-05-22 | 常德金德新材料科技股份有限公司 | A kind of mouldproof preservative paper and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2028861A (en) * | 2021-06-16 | 2022-12-22 | Wuhan Eudeco Co Ltd | Environmentally friendly coating flower sleeve paper, flower sleeve, manufacturing method and application |
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Application publication date: 20210205 |
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