CN112323007A - Supersonic flame spraying self-lubricating wear-resistant coating process - Google Patents

Supersonic flame spraying self-lubricating wear-resistant coating process Download PDF

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Publication number
CN112323007A
CN112323007A CN202011067626.6A CN202011067626A CN112323007A CN 112323007 A CN112323007 A CN 112323007A CN 202011067626 A CN202011067626 A CN 202011067626A CN 112323007 A CN112323007 A CN 112323007A
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powder
mos
crni
spraying
self
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Inventor
李羿含
赵阳
李星彤
高植强
徐建
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Hubei Super Aviation Technology Co ltd
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Hubei Super Aviation Technology Co ltd
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Priority to CN202011067626.6A priority Critical patent/CN112323007A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/129Flame spraying

Abstract

The invention relates to a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps: CrNi-Cr3C2Powder, Ni powder and Ni-MoS2Uniformly mixing the powder to prepare spraying powder; in the spray powder, the CrNi-Cr3C2The weight ratio of the powder is 50-70 percent, and the Ni-MoS2The weight ratio of the powder is 10 to 20 percent; the balance being Ni powder; the CrNi-Cr3C2Powder and Ni-MoS2The powder is coated powder; preprocessing a workpiece to be sprayed; and (4) spraying. Coated CrNi-Cr3C2、Ni‑MoS2Can effectively avoid Cr3C2And MoS2Is oxidized in the spraying process to improve Cr3C2And MoS2The bonding strength with the coating is favorable for improving the wear resistance and the self-lubricating property of the coating.

Description

Supersonic flame spraying self-lubricating wear-resistant coating process
Technical Field
The invention relates to a high-speed spraying technology, in particular to a supersonic flame spraying self-lubricating wear-resistant coating process.
Background
Sliding parts such as airplane bearing journals, landing gears, flap guide rails and the like require materials with high specific strength and good wear resistance, and high-strength base materials are generally adopted and wear-resistant coatings are sprayed on the surfaces of the base materials to meet the requirements. Although the existing coatings such as tungsten carbide, chromium carbide and the like have good wear resistance, the friction coefficient is high, a large amount of friction heat is generated in the sliding process, the friction heat is easy to accumulate at the interface of a base material and the coating, and the service life of a sliding part is shortened.
Disclosure of Invention
Based on the above, there is a need for a supersonic flame spraying self-lubricating wear-resistant coating process, which can spray a coating with high wear resistance and low friction coefficient.
A supersonic flame spraying self-lubricating wear-resistant coating process comprises the following steps:
CrNi-Cr3C2Powder, Ni powder and Ni-MoS2Uniformly mixing the powder to prepare spraying powder;
the CrNi-Cr3C2The weight ratio of the powder is 50-70 percent, and the Ni-MoS2The weight ratio of the powder is 10 to 20 percent; the balance being Ni powder; the CrNi-Cr3C2Powder and Ni-MoS2The powder is coated powder;
preprocessing a workpiece to be sprayed;
and (4) spraying.
Preferably, in the spray powder, the CrNi-Cr3C260-70% of powder by weight and Ni-MoS2The weight ratio of the powder is 10 to 20 percent; the balance being Ni powder.
Preferably, the CrNi-Cr3C2Cr in powder3C225-50% of CrNi in weight ratio and the balance of CrNi; the Ni-MoS2Wherein the weight ratio of Ni is 25 percent, and the balance is MoS2
In some of these embodiments, the CrNi-Cr3C2The particle size of the powder is 11-45 mu m, the particle size of the Ni powder is 10-50 mu m, and the Ni-MoS2The particle size is 48 to 75 μm.
In some of these embodiments, the CrNi-Cr3C2Powder, Ni powder and Ni-MoS2Powder mixtureThe mixing method is ball milling mixing, the rotating speed of the ball mill is 250-300 r/min, and the ball milling time is 4 hours.
In some of these embodiments, the spray process parameters are: the spraying distance is 250-300 mm, the powder feeding speed is 30-40 g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 200-300L/min, the propane pressure is 0.6Mpa, and the propane flow is 80-120L/min.
In some embodiments, the workpiece base material to be sprayed is low-alloy ultrahigh-strength steel.
In some embodiments, the pretreatment of the workpiece to be sprayed comprises a step of blowing sand on the surface of the workpiece, wherein the process parameters of the sand blowing step are as follows: corundum sand with the diameter of 0.3-0.8 mm is adopted, and the sand blowing pressure is 0.4-0.5 MPa; and blowing sand until the roughness of the surface of the workpiece reaches Ra3.0-3.8 mu m.
Further, the invention also provides a self-lubricating wear-resistant coating sprayed by the method.
The invention has the beneficial effects that:
the invention adopts coated CrNi-Cr3C2、Ni-MoS2Coating CrNi-Cr powder mixed with Ni powder as spraying powder3C2、Ni-MoS2Can effectively avoid Cr3C2And MoS2Oxidized in the spraying process, and also improves Cr3C2And MoS2The bonding strength of the Ni powder and the coating is improved, the bonding strength of the coating and the base material and the density of the coating are improved, and the wear resistance and the self-lubricating property of the coating are improved. Microhardness (HV) of the coating sprayed by this process0.3) 537 or more, 52.8MPa or more in bonding strength, 0.386 or less in friction coefficient and excellent comprehensive performance.
Detailed Description
Coated CrNi-Cr in examples and comparative examples3C2The average particle size of the powder was 30 μm, Cr3C2The weight ratio is 25%. The average particle diameter of the Ni powder was 10 μm. Coated Ni-MoS2Has an average particle diameter of 50 μm. Spraying by a Diamond Jet spray gun, and adopting low-alloy high-strength steel Q345 as a base material.
Example 1
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 500g of coated CrNi-Cr3C2Powder, 100g coated Ni-MoS2Mixing the powder and 400gNi powder in a planetary ball mill, wherein the rotating speed of the planetary ball mill is 250r/min, and the ball milling time is 4h, thus obtaining the spraying powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the steel surface by acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying process parameters are that the spraying distance is 300mm, the powder feeding speed is 40g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 300L/min, the propane pressure is 0.6Mpa, and the propane flow is 80L/min.
Example 2
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 600g of coated CrNi-Cr3C2Powder, 150g coated Ni-MoS2Mixing the powder and 250gNi powder in a planetary ball mill, wherein the ball-material ratio is 3:1, the rotating speed of the planetary ball mill is 250r/min, and the ball milling time is 4h, thus obtaining the spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the steel surface by acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
Example 3
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 600g of coated CrNi-Cr3C2Powder, 200g of coated Ni-MoS2Mixing the powder and 250gNi powder in a planetary ball mill, wherein the ball-material ratio is 3:1, the rotating speed of the planetary ball mill is 250r/min, and the ball milling time is 4h, thus obtaining the spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
Example 4
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 700g of coated CrNi-Cr3C2Powder, 100g coated Ni-MoS2Mixing with 200gNi powder in a planetary ball mill at a ball-to-material ratio of 3:1, a planetary ball mill rotation speed of 250r/min and a ball milling time of 4h to obtain spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 250mm, the powder feeding speed is 30g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 400L/min, the propane pressure is 0.6Mpa, and the propane flow is 120L/min.
Comparative example 1
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 700g of coated CrNi-Cr3C2Mixing the powder and 287.5gNi powder in a planetary ball mill, and ball millingThe ratio is 3:1, the rotating speed of the planetary ball mill is 250r/min, and the ball milling time is 4h, so as to obtain the spraying powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
Comparative example 2
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 700g of coated CrNi-Cr3C2Flour, 287.5gNi flour, and 112.5gMoS2Mixing the powder in a planetary ball mill at a ball-material ratio of 3:1, a planetary ball mill rotating speed of 250r/min and a ball milling time of 4h to obtain the spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
Comparative example 3
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 600g of mixed CrNi-Cr3C2Powder, 150g coated Ni-MoS2Mixing the powder and 250gNi powder in a planetary ball mill, wherein the ball-material ratio is 3:1, the rotating speed of the planetary ball mill is 250r/min, and the ball milling time is 4h, thus obtaining the spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
Comparative example 4
The embodiment provides a supersonic flame spraying self-lubricating wear-resistant coating process, which comprises the following steps:
s1, preparing a spray powder: 600g of coated CrNi-Cr3C2Powder, 150g coated Ni-MoS2Mixing in a planetary ball mill with a ball-material ratio of 3:1, a planetary ball mill rotating speed of 250r/min and ball milling time of 4h to obtain the spray powder.
S2, workpiece pretreatment: and carrying out sand blowing treatment on the low-alloy high-strength steel after integral steam degreasing, wherein the sand blowing adopts corundum sand with the diameter of 0.5mm, the pressure is 0.5MPa, the distance is 180mm, and the sand blowing is carried out until the surface roughness reaches Ra3.8 mu m. And cleaning the surface of the high-strength steel by using acetone and industrial alcohol after sand blasting.
S3, spraying: the spraying distance is 280mm, the powder feeding speed is 35g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 350L/min, the propane pressure is 0.6Mpa, and the propane flow is 100L/min.
TABLE 1 Process parameters of examples 1-4 and comparative examples 1-4
Example 1 Example 2 Example 3 Example 4 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
CrNi-Cr3C2/g 500 600 600 700 600 600 600 600
CrNi-Cr3C2Type (B) Coated type Coated type Coated type Coated type Coated type Coated type Hybrid type Coated type
Ni/g 400 250 250 100 287.5 287.5 250 /
Ni-MoS2/g 100 150 200 200 / / 150 150
MoS2/g / / / / / 112.5 / /
Spraying distance/mm 300 280 280 250 280 280 280 280
Powder feeding rate g/min 40 35 35 30 35 35 35 35
Oxygen flow L/min 300 350 350 400 350 350 350 350
Propane flow L/min 80 100 100 120 100 100 100 100
Test examples
The coatings prepared in examples 1-4 and comparative examples 1-4 were tested by the following methods:
the microhardness of the coating was measured with a microhardness tester (MICROMET-6030, Buehler, America), load 2.94N, dwell time 15 s. To ensure the stability of the data, the microhardness values are the average of 5 measurement points.
The coating bond strength was tested according to GB/T8462-2002 "determination of tensile bond strength by thermal spraying".
The dry friction coefficients of the coatings in examples and comparative examples during sliding friction were analyzed by an abrasion tester. In the test, a diamond sheet is selected as a pair grinding pair, the pressure of the testing machine is 40N, the linear speed is 1m/s, the testing time is 300s, the friction travel is 300m, and the friction coefficient is directly read from the testing machine.
Table 2 test results of examples 1 to 4 and comparative examples 1 to 4
Example 1 Example 2 Example 3 Example 4 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
microhardness/HV0.3 537 584 546 594 739 597 542 509
Bonding strength/MPa 73.2 60.3 56.4 52.8 74.5 45.6 47.9 35.4
Coefficient of friction 0.386 0.325 0.235 0.308 0.621 0.474 0.395 0.425
As can be seen from Table 2, MoS was added2Can effectively reduce the friction coefficient of the coating, and adopts coated Ni-MoS2Is beneficial to improving the microhardness and the bonding strength of the coating and more effectively reducing the friction coefficient. Adopts coated CrNi-Cr3C2The powder can effectively improve the microhardness and the bonding strength of the coating.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (9)

1. A supersonic flame spraying self-lubricating wear-resistant coating process is characterized by comprising the following steps:
CrNi-Cr3C2Powder, Ni powder and Ni-MoS2Uniformly mixing the powder to prepare spraying powder;
in the spray powder, the CrNi-Cr3C2The weight ratio of the powder is 50-70 percent, and the Ni-MoS2The weight ratio of the powder is 10 to 20 percent; the balance being Ni powder; the CrNi-Cr3C2Powder and Ni-MoS2The powder is coated powder;
preprocessing a workpiece to be sprayed;
and (4) spraying.
2. The process of claim 1, wherein the CrNi-Cr is present in the spray powder3C260-70% of powder by weight and Ni-MoS2The weight ratio of the powder is 10 to 20 percent; the balance being Ni powder.
3. The supersonic flame spray self-lubricating abradable coating process of claim 2, wherein the CrNi-Cr3C2Cr in powder3C225-50% of CrNi in weight ratio and the balance of CrNi; the Ni-MoS2Wherein the weight ratio of Ni is 25 percent, and the balance is MoS2
4. The supersonic flame spraying self-lubricating wear-resistant coating process according to claims 1 to 3, wherein the CrNi-Cr3C2The particle size of the powder is 11-45 mu m, the particle size of the Ni powder is 10-50 mu m, and the Ni-MoS2The particle size of the powder is 48-75 μm.
5. The supersonic flame spray of claims 1-3The self-lubricating wear-resistant coating process is characterized in that the CrNi-Cr3C2Powder, Ni powder and Ni-MoS2The powder mixing mode is ball milling mixing, the rotating speed of the ball mill is 250-300 r/min, and the ball milling time is 4 hours.
6. The supersonic flame spraying self-lubricating wear-resistant coating process according to claims 1-3, wherein the spraying process parameters are as follows: the spraying distance is 250-300 mm, the powder feeding speed is 30-40 g/min, the oxygen pressure is 1.2Mpa, the oxygen flow is 200-300L/min, the propane pressure is 0.6Mpa, and the propane flow is 80-120L/min.
7. The supersonic flame spraying self-lubricating wear-resistant coating process according to claims 1-3, wherein the workpiece substrate material to be sprayed is low-alloy high-strength steel.
8. The supersonic flame spraying self-lubricating wear-resistant coating process according to claims 1-3, wherein the pretreatment of the workpiece to be sprayed comprises a sand blowing step on the surface of the workpiece, and the sand blowing step comprises the following process parameters: corundum sand with the diameter of 0.3-0.8 mm is adopted, and the sand blowing pressure is 0.4-0.5 MPa; and blowing sand until the roughness of the surface of the workpiece reaches Ra3.0-3.8 mu m.
9. A self-lubricating wear-resistant coating prepared by the process of any one of claims 1 to 3.
CN202011067626.6A 2020-10-06 2020-10-06 Supersonic flame spraying self-lubricating wear-resistant coating process Pending CN112323007A (en)

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Publication number Priority date Publication date Assignee Title
US5763106A (en) * 1996-01-19 1998-06-09 Hino Motors, Ltd. Composite powder and method for forming a self-lubricating composite coating and self-lubricating components formed thereby
CN101736279A (en) * 2008-11-05 2010-06-16 沈阳黎明航空发动机(集团)有限责任公司 Hypersonic flame spraying process for self-lubricating wear-resistant coating
CN110218962A (en) * 2019-06-19 2019-09-10 西安交通大学 A kind of wear-resistant self-lubricating chromium carbide cermet composite coating and preparation method thereof
CN111057986A (en) * 2019-12-31 2020-04-24 广东省新材料研究所 Self-lubricating coating for wide temperature range, workpiece and preparation method of self-lubricating coating
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CN101736279A (en) * 2008-11-05 2010-06-16 沈阳黎明航空发动机(集团)有限责任公司 Hypersonic flame spraying process for self-lubricating wear-resistant coating
CN110218962A (en) * 2019-06-19 2019-09-10 西安交通大学 A kind of wear-resistant self-lubricating chromium carbide cermet composite coating and preparation method thereof
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