CN112316673A - Odor and sewage treatment system - Google Patents

Odor and sewage treatment system Download PDF

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Publication number
CN112316673A
CN112316673A CN202011290542.9A CN202011290542A CN112316673A CN 112316673 A CN112316673 A CN 112316673A CN 202011290542 A CN202011290542 A CN 202011290542A CN 112316673 A CN112316673 A CN 112316673A
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ozone
sewage
odor
generator
pipeline
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许岳虎
毛小艺
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Hunan Natural Creation Biotechnology Co ltd
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Hunan Natural Creation Biotechnology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention provides an odor and sewage treatment system which comprises a spray tower, wherein a sewage collecting tank is arranged at the bottom in the spray tower, and an air inlet, an air outlet and a sewage discharge pipe opening are formed in the spray tower. The odor and sewage treatment system also comprises an ozone microbubble generation assembly, and the ozone microbubble generation assembly comprises an ozone generator and a first microbubble generator communicated with the ozone generator. The ozone generator generates ozone and delivers the ozone into the first microbubble generator. The first micro-bubble generator mixes the ozone with the water liquid in the first micro-bubble generator and generates ozone micro-bubbles. The first microbubble generator is communicated with the sewage collecting tank through a first pipeline and is used for conveying ozone microbubbles into the sewage collecting tank. According to the invention, by designing the ozone microbubble generating assembly, the ozone microbubble generating assembly can provide ozone microbubbles for the sewage collecting tank in the spray tower, so that the treatment efficiency and effect of water liquid (dissolved with harmful components in odor) in the sewage collecting tank are accelerated.

Description

Odor and sewage treatment system
Technical Field
The invention belongs to the field of environmental protection, relates to a waste gas and sewage treatment equipment technology, and particularly relates to a stink and sewage treatment system.
Background
With the progress of society and the development of industry, a large amount of waste water and toxic and harmful gas are inevitably generated, and the production environment of human beings is seriously damaged after the waste water and the toxic and harmful gas are discharged into the environment, so that the environmental problems are paid high attention and concern to various countries in the world, and people take various measures to prevent and control the environmental pollution.
The treatment of exhaust gas is currently carried out by water washing (neutral water, acid washing, alkali washing). Generally, the water washing converts the soluble or partially slightly water-soluble substances in the exhaust gas into other substances, such as neutral water (e.g. deionized water) which can convert ammonia gas into ammonia water; the acid washing can convert ammonia, amines and the like into other alkaline substances; alkaline washing is suitable for converting hydrogen sulfide, lower fatty acids, etc. into other acidic substances. Therefore, in order to convert various kinds of malodorous substances in waste gas and wastewater into harmless substances, a multistage chemical washing mode of acid washing and alkali washing in series is generally adopted for deodorization, and an irreversible chemical reaction is generated between the malodorous components and main components of chemical liquid medicine to generate new malodorous substances so as to achieve the aim of deodorization.
At present, the waste gas is handled through the spray column mostly to the washing mode and is realized, and its principle is: and introducing the waste gas into the spray tower to make the waste gas contact with spray water in the spray tower, and treating the waste gas through physical dissolution and chemical reaction. In the actual operation process, after the components in the waste gas are dissolved by the spray water, the chemical reaction efficiency is low, and pollutants cannot be effectively treated. The discharged waste gas and waste liquid also contain untreated pollutants, so that the discharged waste gas and waste water need to be treated again on one hand, and the risk of environmental pollution can be caused on the other hand.
Therefore, there is a need for an improvement of the existing odor and sewage treatment apparatus to solve the above problems.
Disclosure of Invention
The invention aims to solve the problems of low efficiency, high cost and low treatment effect of the existing odor and sewage treatment device for treating odor and/or sewage, and provides an odor and sewage treatment system which has a simple structure, good decomposition effect of pollutant components in odor and/or sewage and low cost.
The design idea of the invention is as follows: cavitation is a physical phenomenon occurring in a liquid medium and refers to the process of formation, development and collapse of vapor or gas cavities within a liquid or at a liquid-solid interface when the local pressure within the liquid is reduced. When cavitation reaction occurs, local extremely high temperature and high pressure are formed at the moment when cavitation bubbles collapse, and strong shock waves and microjets are accompanied, so that strong disturbance and huge shearing force action can be formed in liquid, and simultaneously, impact is formed on an object surface to form a mechanical effect of cavitation; meanwhile, although the collapse time of the cavitation bubbles is extremely short, local hot spots can be formed in tiny spaces around the bubbles during collapse of the cavitation bubbles at the moment of collapse, and a cavitation heat effect can be formed, which can cause decomposition of high molecules of substances, breakage of chemical bonds and generation of free radicals. For example: when the collapse time of the cavitation bubble is in the order of microseconds, the generated high-temperature and high-pressure condition is enough to open O-H bonds (the binding energy is 498.7kJ/mol) in water molecules, so that the water molecules are directly cracked into H and OH free radicals, and the free radicals can further generate HO2And H202. Active radicals having strong oxidizing properties and oxidizing substances are present in a gas phase region inside the cavitation bubbles, an interface layer region near the bubble walls, and a liquid phase region at ambient normal temperature and pressure.
Meanwhile, the ozone catalytic oxidation technology is a process for removing the organic matters which are difficult to biodegrade in the sewage by utilizing the high-reaction-activity free radical intermediate generated on the surface of the catalyst by ozone molecules, particularly hydroxyl free radical oxidation. During the reaction, a large amount of strong oxidative HO radicals can be generated, which can oxidize and decompose organic substances in water to achieve the purpose of purifying water. When dissolved with O3When the sewage (ozone) passes through the filter layer, the catalytic oxidation reaction is carried out under the action of the catalyst, so that the color, turbidity and odor can be effectively removed, and pollutants such as phenol, cyanogen, sulfide, pesticide, petroleum and the like in the sewage can be removed.
Therefore, it is considered that the hydrodynamic cavitation technology can be combined with the ozone catalytic oxidation technology to degrade pollutants in sewage and odor.
The technical scheme for realizing the purpose of the invention is as follows: the odor and sewage treatment system comprises a spray tower, wherein a sewage collecting tank is arranged at the bottom in the spray tower, and an air inlet, an air outlet and a sewage discharge pipe opening are formed in the spray tower.
Wherein, odor and sewage treatment system still includes ozone microbubble and takes place the subassembly, and ozone microbubble takes place the subassembly and includes ozone generator and the first microbubble generator that communicates with ozone generator.
The ozone generator generates ozone and delivers the ozone into the first microbubble generator. The first micro-bubble generator mixes the ozone with the water liquid in the first micro-bubble generator and generates ozone micro-bubbles.
The first microbubble generator is communicated with the sewage collecting tank through a first pipeline and is used for conveying ozone microbubbles into the sewage collecting tank.
According to the invention, by designing the ozone microbubble generating assembly, the ozone microbubble generating assembly can provide ozone microbubbles for the sewage collecting tank in the spray tower, so that the treatment efficiency and effect of water liquid (dissolved with harmful components in odor) in the sewage collecting tank are accelerated.
Furthermore, the first microbubble generator is also communicated with a sewage collecting tank through a second pipeline, and the sewage collecting tank discharges part of water liquid into the first microbubble generator through the second pipeline and mixes the water liquid with ozone to generate ozone microbubbles. The water liquid in the sewage collecting tank circulates between the sewage collecting tank and the first microbubble generator through the second pipeline, so that the utilization rate of the water liquid in the sewage collecting tank is improved, and the water use cost of the system and the subsequent water treatment cost are reduced.
Furthermore, a first ozone catalyst is arranged in the sewage collecting tank and used for catalyzing the decomposition of ozone and generating OH with strong oxidizing property. Specifically, a first ozone catalyst can be placed on the grid, and the first ozone catalyst can efficiently catalyze the conversion of ozone into OH hydroxyl radicals with strong oxidation activity. The ozone microbubbles are in full contact with the first ozone catalyst in the sewage collecting tank and react to generate OH which can oxidize macromolecular harmful substances in water liquid (namely sewage) in the sewage collecting tank and decompose and convert the macromolecular harmful substances into harmless micromolecules so as to achieve the treatment effect.
In a preferred embodiment of the present invention, the odor and sewage treatment system further comprises a hydrodynamic cavitation device, one end of the hydrodynamic cavitation device is communicated with the sewage collecting tank through a third pipeline, and the other end of the hydrodynamic cavitation device is communicated with the spray pipeline in the spray tower through a fourth pipeline. The hydraulic cavitator is used for performing hydraulic cavitation reaction on part of water liquid discharged from the sewage collecting tank and then spraying the water liquid through a spray head of the spray pipeline. The principle of the hydrodynamic cavitation reaction is as follows: when the local pressure in the water liquid is reduced, the formation, development and collapse of steam or gas cavities in the water liquid or on the liquid-solid interface of the water liquid, when the cavitation reaction occurs, local extreme high temperature and high pressure are formed at the moment of collapse of cavitation bubbles, and strong shock waves and micro-jet are accompanied, so that strong disturbance and huge shear force action can be formed in the water liquid, and simultaneously, the impact is formed on the object surface of pollutants in the water liquid to form the mechanical effect of cavitation; although the collapse time of the cavitation bubbles is extremely short, local hot spots are formed in the micro space around the bubbles during collapse of the cavitation bubbles at the moment of collapse, and a cavitation heat effect is formed, which can cause decomposition of high molecules of substances, breakage of chemical bonds and generation of free radicals. In the invention, the hydrodynamic cavitation device can be any device and apparatus which can realize hydrodynamic cavitation principle, including but not limited to jet cavitation device, orifice plate cavitation device, Venturi tube cavitation device, etc.
Furthermore, the hydraulic cavitator is also communicated with an ozone generator through a fifth pipeline, the ozone generator inputs the part for generating ozone into the hydraulic cavitator, and the ozone is mixed with water liquid input into the hydraulic cavitator through a third pipeline, so that the generated liquid vacuoles are ozone vacuoles.
Preferably, the third pipeline is further provided with a pressure gauge, a flow meter and a pressure regulating valve, the pressure gauge and the flow meter can measure the pressure and the flow of the water liquid before cavitation, and then the pressure regulating valve can regulate the pressure of the sewage entering the hydrodynamic cavitation device, so that the hydrodynamic cavitation device can better operate.
Furthermore, the spray head is a hydraulic cavitation spray head, and the hydraulic cavitation spray head is selected, so that the water liquid sprayed out through the spray pipeline can be subjected to further hydraulic cavitation reaction.
Ultraviolet rays are invisible light having a higher frequency than blue-violet light in an electromagnetic spectrum having a wavelength of 400nm to 10nm, and do not cause human vision. When the photon energy of ultraviolet light is greater than the chemical bond energy of organic pollutants, a photolysis reaction is usually generated, so that the chemical bond of the organic pollutants is broken. For example: the photon energy of 185nm ultraviolet rays and 254nm ultraviolet rays is 647kJ/mol and 472kJ/mol respectively, the photon energy is larger than the molecular covalent bond energy of most organic waste gas gases, the covalent bond of most organic waste gas molecules can be directly broken, the molecular chain breakage is caused, and therefore, the macromolecular odor molecules are decomposed into H2O、O2And other small molecules to achieve the odor treatment effect. Meanwhile, when the ultraviolet wavelength is 200nm or less, O is present2The molecule will be decomposed to generate active O; active O and O2Combined to form O3。O3Can produce simple, low-harmful or harmless substances such as H by oxidation reaction with organic pollutant ions in a free state2O、CO2And the like. Irradiating 185nm photons to oxygen molecules to convert oxygen (O)2) After the covalent bond is broken into oxygen atoms, the oxygen atoms are further reacted with the surrounding oxygen molecules (O)2) Combine to form ozone (O) containing 3 oxygen atoms3)。
Therefore, the present invention improves the odor and sewage treatment system on the basis of the above odor and sewage treatment system. The odor and sewage treatment system further comprises an ultraviolet lamp assembly, the ultraviolet lamp assembly is used for decomposing and catalyzing odor entering the spray tower, and the ultraviolet lamp assembly comprises a first ultraviolet lamp arranged on the inner wall of the spray tower. When the odor and sewage treatment system treats odor, the odor enters the spray tower from the air inlet of the spray tower, moves upwards along the spray tower, passes through the packing layer and the spray layer and is discharged from the air outlet at the top of the spray tower. The first ultraviolet lamp on the inner wall of the spray tower can emit ultraviolet light (185nm and 254nm) with specific wavelength to further treat odor.
Because ozone has a certain poisoning effect, the direct discharge of the ozone can cause the nerve poisoning of people, so that the people have dizziness, headache, vision deterioration, memory decline and the like, a second ozone catalyst is arranged in the spray tower and close to the exhaust port, and is used for catalytically decomposing the ozone in the spray tower into oxygen, so that the gas discharged from the exhaust port does not contain ozone.
In the present invention, the second ozone catalyst is disposed on the grid. Meanwhile, a packing layer is arranged in the spray tower and consists of a grating and packing. The grid is mainly used for supporting the filler, the filler is loose and porous, the retention time of the odor in the spray tower can be prolonged, meanwhile, the odor can be fully contacted with sprayed liquid drops, and the odor treatment efficiency is improved. The liquid drops sprayed by the spraying layer are converged into the sewage collecting tank at the bottom of the spraying layer under the action of gravity to form sewage (namely water liquid) to be treated, and pollutants in the sewage to be treated are decomposed at an accelerated speed under the action of ozone microbubbles and an ozone catalyst in the sewage collecting tank.
Further, in order to further improve the treatment effect of the odor, the ultraviolet lamp assembly further comprises a second ultraviolet lamp, the second ultraviolet lamp is positioned in the odor pipeline communicated with the air inlet, the second ultraviolet lamp pretreats the odor in the odor pipeline, decomposes partial pollutants in the odor, and then discharges the pollutants into the spray tower for treatment.
In a preferred embodiment of the present invention, the odor and sewage treatment system further comprises a second micro-bubble generator, an inlet end of the second micro-bubble generator is connected to the sewage inlet pipe and the ozone generator respectively, an outlet end of the second micro-bubble generator is communicated with the sewage inlet at the upper part of the spray tower, and the second micro-bubble generator is used for mixing the sewage and the ozone to form the nano micro-bubbles. Set up the second microbubble generator on sewage inlet channel, can make foul smell and sewage treatment system both can handle the foul smell, also can handle sewage, also can handle foul smell and sewage simultaneously, in the actual operation in-process, according to actual demand, open and close through the valve control pipeline on each pipeline. The working process specifically comprises the following steps: the sewage to be treated and the ozone form nano microbubbles in the second microbubble generator, the nano microbubbles enter the spray tower through the sewage inlet at the upper part of the spray tower, and the nano microbubbles are sprayed out through the nozzle to form small sewage droplets; the small sewage droplets move downwards under the action of gravity and are converged into sewage which is treated in a sewage collecting tank; and a part of sewage moves upwards under the action of the water pump, sequentially passes through the third pipeline, the hydraulic cavitator, the fourth pipeline and the spray pipeline, then flows into the spray tower from the hydraulic cavitator nozzle, then flows downwards into the sewage collection tank, and is treated in a reciprocating cycle manner. And a part of sewage is discharged from a sewage discharge pipe port of the sewage collecting tank and enters the next procedure for treatment.
Compared with the prior art, the invention has the beneficial effects that:
1. through the design of the ozone microbubble generation assembly, the ozone microbubble generation assembly can provide ozone microbubbles for the sewage collection pool in the spray tower, so that the treatment efficiency and effect of water liquid (dissolved with harmful components in odor) in the sewage collection pool are accelerated.
2. Through design the second pipeline between sewage collecting tank and first microbubble generator, can make the water liquid in the sewage collecting tank circulate between sewage collecting tank and first microbubble generator, improve the utilization ratio of water liquid in the sewage collecting tank, reduce the water cost of system and subsequent water treatment cost.
3. The ultraviolet lamp component can emit ultraviolet light (185nm and 254nm) with specific wavelength to further treat odor and sewage in the spray tower.
4. When the local pressure in the liquid (sewage) is reduced, the process of the formation, development and collapse of steam or gas cavities in the liquid or on the liquid-solid interface is formed, namely, the hydrodynamic cavitation reaction is formed. When cavitation reaction occurs, local extremely high temperature and high pressure are formed at the moment when cavitation bubbles collapse, and strong shock waves and microjets are accompanied, so that strong disturbance and huge shearing force action can be formed in liquid, and simultaneously, impact is formed on an object surface to form a mechanical effect of cavitation; although the collapse time of the cavitation bubbles is extremely short, local hot spots can be formed in tiny spaces around the bubbles during collapse of the cavitation bubbles at the instant of collapse, and a cavitation heat effect can be formed, which can cause decomposition of high molecules of substances, breakage of chemical bonds and generation of free radicals, so that pollutants in water can be decomposed. Meanwhile, the first ozone catalyst in the sewage collecting tank can catalyze the ozone in the ozone micro-bubbles to form OH with strong oxidizing property, and the OH can further decompose pollutants in water liquid. By coupling the hydrodynamic cavitation technology and the ozone advanced oxidation technology, the treatment effect of the water liquid sprayed with odor and the sewage input through the sewage inlet can be ensured.
Drawings
In order to more clearly illustrate the technical solution of the embodiment of the present invention, the drawings used in the description of the embodiment will be briefly introduced below. It should be apparent that the drawings in the following description are only for illustrating the embodiments of the present invention or technical solutions in the prior art more clearly, and that other drawings can be obtained by those skilled in the art without any inventive work.
FIG. 1 is a schematic view of an odor and sewage treatment system of example 1 of the present invention;
FIG. 2 is a schematic view of an odor and sewage treatment system of example 2 of the present invention;
wherein, 0, the sewage discharge pipe orifice; 1. a spray tower; 2. a sewage collection tank; 3. an air inlet; 4. an exhaust port; 5. a fan; 6. a frequency converter; 7. an ozone generator; 8. a first microbubble generator; 9. a first conduit; 10. a second conduit; 11. a hydrodynamic cavitator; 12. a third pipeline; 13. a fourth conduit; 14. a spray pipe; 15. a spray head; 16. a fifth pipeline; 17. a pressure gauge; 18. a flow meter; 19. a pressure regulating valve; 20. a water pump; 21. a second microbubble generator; 22. a sewage inlet pipeline; 22-1. a sewage inlet; 23, a nozzle; 24. a first ultraviolet lamp.
Detailed Description
The invention will be further described with reference to specific embodiments, and the advantages and features of the invention will become apparent as the description proceeds. These examples are illustrative only and do not limit the scope of the present invention in any way. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention, and that such changes and modifications may be made without departing from the spirit and scope of the invention.
In the description of the present embodiments, it is to be understood that the terms "center", "longitudinal", "lateral", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", etc. indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of describing the present invention and simplifying the description, but do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention.
Furthermore, the terms "first," "second," "third," and the like are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicit to a number of indicated technical features. Thus, a feature defined as "first," "second," etc. may explicitly or implicitly include one or more of that feature. In the description of the invention, the meaning of "a plurality" is two or more unless otherwise specified.
Example 1:
the embodiment provides an odor and sewage treatment system, and the odor and sewage treatment system of the embodiment is used for treating odor.
In the present embodiment, referring to fig. 1, the odor and sewage treatment system includes a spray tower 1, a sewage collecting tank 2 is disposed at the bottom of the spray tower 1, and an air inlet 3, an air outlet 4, and a sewage outlet pipe orifice 0 are disposed on the spray tower 1. In the embodiment, the exhaust port 4 is located at the top of the spray tower 1, and a fan 5 and a frequency converter 6 are arranged on a pipeline connected with the exhaust port 4; the odor treated by ultraviolet rays and spray water (water liquid) in the spray tower 1 is discharged under the action of a fan 5 and a frequency converter 6; the air inlet 3 is arranged on the outer wall of the spray tower 1 and is positioned at the upper part of the sewage collecting tank 2.
Wherein, the odor and sewage treatment system also comprises an ozone microbubble generation assembly, and the ozone microbubble generation assembly comprises an ozone generator 7 and a first microbubble generator 8 communicated with the ozone generator 7. The ozone generator 7 generates ozone and delivers the ozone into the first microbubble generator 8. The first micro-bubble generator 8 mixes ozone with the water in the first micro-bubble generator 7 and generates ozone micro-bubbles. Specifically, the first microbubble generator 8 is communicated 9 with the sewage collecting tank 2 through a first pipeline, and the first microbubble generator 8 is used for conveying ozone microbubbles into the sewage collecting tank 2.
Further, a first ozone catalyst is arranged in the sewage collecting tank 2, and the ozone catalyst is used for catalyzing ozone and generating OH with strong oxidizing property. Specifically, a first ozone catalyst can be placed on the grid, and the first ozone catalyst can efficiently catalyze the conversion of ozone into OH hydroxyl radicals with strong oxidation activity. The ozone microbubbles are in full contact with the first ozone catalyst in the sewage collecting tank and react to generate OH which can oxidize macromolecular harmful substances in water liquid (namely sewage) in the sewage collecting tank and decompose and convert the macromolecular harmful substances into harmless micromolecules so as to achieve the treatment effect.
Wherein, the first microbubble generator 8 is also communicated with the sewage collecting tank 2 through a second pipeline 10, and the sewage collecting tank 2 discharges part of the water liquid into the first microbubble generator 8 through the second pipeline 10 and mixes with ozone to generate ozone microbubbles. The water liquid in the sewage collecting tank 2 circulates between the sewage collecting tank 2 and the first microbubble generator 8 through the second pipeline 10, so that the utilization rate of the water liquid in the sewage collecting tank 2 is improved, and the water use cost of the system and the subsequent water treatment cost are reduced.
The odor and sewage treatment system further comprises a hydraulic cavitator 11, one end of the hydraulic cavitator 11 is communicated with the sewage collecting tank 2 through a third pipeline 12, and the other end of the hydraulic cavitator 11 is communicated with a spraying pipeline 14 in the spraying tower 1 through a fourth pipeline 13. The hydraulic cavitator 11 is used for hydraulic cavitation reaction and then is sprayed out through a spray head of the spray pipeline 14. The principle of the hydrodynamic cavitation reaction is as follows: when the local pressure in the water liquid is reduced, the formation, development and collapse of steam or gas cavities in the water liquid or on the liquid-solid interface of the water liquid, when the cavitation reaction occurs, local extreme high temperature and high pressure are formed at the moment of collapse of cavitation bubbles, and strong shock waves and micro-jet are accompanied, so that strong disturbance and huge shear force action can be formed in the water liquid, and simultaneously, the impact is formed on the object surface of pollutants in the water liquid to form the mechanical effect of cavitation; although the collapse time of the cavitation bubbles is extremely short, local hot spots are formed in the micro space around the bubbles during collapse of the cavitation bubbles at the moment of collapse, and a cavitation heat effect is formed, which can cause decomposition of high molecules of substances, breakage of chemical bonds and generation of free radicals. In the present invention, the hydrodynamic cavitation device 11 can be any device and apparatus capable of implementing hydrodynamic cavitation principle, including but not limited to jet cavitation device, orifice plate cavitation device, venturi tube cavitation device, etc.
Further, the third pipeline 12 is further provided with a pressure gauge 17, a flow meter 18 and a pressure regulating valve 19, the pressure gauge 12 and the flow meter 18 can measure the pressure and the flow of the water liquid before cavitation, and then the pressure regulating valve 19 can regulate the pressure of the sewage entering the hydrodynamic cavitation device 11, so that the hydrodynamic cavitation device 11 can better operate.
Further, the nozzle 15 is a hydrodynamic cavitation nozzle, and the hydrodynamic cavitation nozzle is selected to perform further hydrodynamic cavitation reaction on the water liquid sprayed out through the spraying pipeline 14.
Further, the hydrodynamic cavitation device 11 is also communicated with the ozone generator 7 through a fifth pipeline 16, the ozone generator 7 inputs the part of the generated ozone into the hydrodynamic cavitation device 11, and the ozone is mixed with the water liquid input into the hydrodynamic cavitation device 11 through the third pipeline 12, so that the generated liquid cavitation is ozone cavitation.
The working process of the odor and sewage treatment system of the embodiment is as follows:
firstly, odor is input into a spray tower 1 through an air inlet 3, goes upwards through a packing layer and a spray layer, and is downwards flowed into a sewage collecting tank 2 under the action of gravity by a water liquid absorption part sprayed by a spray pipeline 14 and a spray nozzle 15 of the spray layer, and the treated odor is discharged through an air outlet 4 at the top of the spray tower 1 under the action of a fan 5 and a frequency converter 6;
secondly, the ozone generator 7 generates ozone and inputs the ozone into the first micro-bubble generator 8 to be mixed with water liquid in the first micro-bubble generator 8 to form ozone micro-bubbles; in this step, the water may be water circulating between the wastewater collection tank 2 and the first microbubble generator 8, which contains contaminants; other solutions that newly introduce ozone-microbubble generating solutions are also possible.
Thirdly, ozone microbubbles are input into the sewage collecting tank 2 through a first pipeline 9 to be mixed with water liquid in the sewage collecting tank 2, and pollutants in the water liquid are decomposed under the action of an ozone catalyst;
then, the liquid in the sewage collecting pool 2 is input into the hydraulic cavitator 11 through the third pipeline 12 under the action of the water pump 20, and is mixed with the ozone input into the hydraulic cavitator 11 through the fifth pipeline 16 to generate ozone microbubbles; ozone microbubbles are sprayed into the spray tower 1 through a fourth pipeline 13, a spray pipeline 14 and a spray head 15, dissolve odor entering and ascending through the air inlet 3, and then flow into the sewage collection tank 2.
The water liquid in the sewage collecting pool 2 continuously circulates among the sewage collecting pool 2, the hydrodynamic cavitation device 11 and the first micro bubble generator 8 through 2 paths, so that the odor input into the spray tower 1 is treated, and the sewage treated in the sewage collecting pool 2 is discharged through the sewage discharge pipe port 0. The invention can provide ozone microbubbles for the sewage collecting tank 2 in the spray tower 1 by designing the ozone microbubble generating assembly, thereby accelerating the treatment efficiency and effect of water liquid (dissolved with harmful components in odor) in the sewage collecting tank 2.
Example 2:
the present embodiment provides an odor and sewage treatment system, which is used for treating sewage, can also treat odor, and can also treat odor and sewage simultaneously.
Referring to fig. 2, in the embodiment, the odor and sewage treatment system includes a spray tower 1, a sewage collecting tank 2 is disposed at the bottom of the spray tower 1, and an air inlet 3 is disposed on the spray tower 1. In this embodiment, the top of the spray tower 1 is provided with an exhaust port 4, and a pipeline connected with the exhaust port 4 is provided with a fan 5 and a frequency converter 6; the odor treated by ultraviolet rays and spray water (water liquid) in the spray tower 1 is discharged under the action of a fan 5 and a frequency converter 6; the air inlet 3 is arranged on the outer wall of the spray tower 1 and is positioned at the upper part of the sewage collecting tank 2.
Wherein, the odor and sewage treatment system also comprises an ozone microbubble generation assembly, and the ozone microbubble generation assembly comprises an ozone generator 7 and a first microbubble generator 8 communicated with the ozone generator 7. The ozone generator 7 generates ozone and delivers the ozone into the first microbubble generator 8. The first micro-bubble generator 8 mixes ozone with the water in the first micro-bubble generator 7 and generates ozone micro-bubbles. Specifically, the first microbubble generator 8 is communicated 9 with the sewage collecting tank 2 through a first pipeline, and the first microbubble generator 8 is used for conveying ozone microbubbles into the sewage collecting tank 2.
Further, a first ozone catalyst is arranged in the sewage collecting tank 2, and the ozone catalyst is used for catalyzing ozone and generating OH with strong oxidizing property. Specifically, a first ozone catalyst can be placed on the grid, and the first ozone catalyst can efficiently catalyze the conversion of ozone into OH hydroxyl radicals with strong oxidation activity. The ozone microbubbles are in full contact with the first ozone catalyst in the sewage collecting tank and react to generate OH which can oxidize macromolecular harmful substances in water liquid (namely sewage) in the sewage collecting tank and decompose and convert the macromolecular harmful substances into harmless micromolecules so as to achieve the treatment effect.
Wherein, the first microbubble generator 8 is also communicated with the sewage collecting tank 2 through a second pipeline 10, and the sewage collecting tank 2 discharges part of the water liquid into the first microbubble generator 8 through the second pipeline 10 and mixes with ozone to generate ozone microbubbles. The water liquid in the sewage collecting tank 2 circulates between the sewage collecting tank 2 and the first microbubble generator 8 through the second pipeline 10, so that the utilization rate of the water liquid in the sewage collecting tank 2 is improved, and the water use cost of the system and the subsequent water treatment cost are reduced.
The odor and sewage treatment system further comprises a hydraulic cavitator 11, one end of the hydraulic cavitator 11 is communicated with the sewage collecting tank 2 through a third pipeline 12, and the other end of the hydraulic cavitator 11 is communicated with a spraying pipeline 14 in the spraying tower 1 through a fourth pipeline 13. The hydraulic cavitator 11 is subjected to hydraulic cavitation reaction and then is sprayed out through a spray head of the spray pipeline 14. The principle of the hydrodynamic cavitation reaction is as follows: when the local pressure in the water liquid is reduced, the formation, development and collapse of steam or gas cavities in the water liquid or on the liquid-solid interface of the water liquid, when the cavitation reaction occurs, local extreme high temperature and high pressure are formed at the moment of collapse of cavitation bubbles, and strong shock waves and micro-jet are accompanied, so that strong disturbance and huge shear force action can be formed in the water liquid, and simultaneously, the impact is formed on the object surface of pollutants in the water liquid to form the mechanical effect of cavitation; although the collapse time of the cavitation bubbles is extremely short, local hot spots are formed in the micro space around the bubbles during collapse of the cavitation bubbles at the moment of collapse, and a cavitation heat effect is formed, which can cause decomposition of high molecules of substances, breakage of chemical bonds and generation of free radicals. In the present invention, the hydrodynamic cavitation device 11 can be any device and apparatus capable of implementing hydrodynamic cavitation principle, including but not limited to jet cavitation device, orifice plate cavitation device, venturi tube cavitation device, etc.
Further, the third pipeline 12 is further provided with a pressure gauge 17, a flow meter 18 and a pressure regulating valve 19, the pressure gauge 12 and the flow meter 18 can measure the pressure and the flow of the water liquid before cavitation, and then the pressure regulating valve 19 can regulate the pressure of the sewage entering the hydrodynamic cavitation device 11, so that the hydrodynamic cavitation device 11 can better operate.
Further, the nozzle 15 is a hydrodynamic cavitation nozzle, and the hydrodynamic cavitation nozzle is selected to perform further hydrodynamic cavitation reaction on the water liquid sprayed out through the spraying pipeline 14.
Further, the hydrodynamic cavitation device 11 is also communicated with the ozone generator 7 through a fifth pipeline 16, the ozone generator 7 inputs the part of the generated ozone into the hydrodynamic cavitation device 11, and the ozone is mixed with the water liquid input into the hydrodynamic cavitation device 11 through the third pipeline 12, so that the generated liquid cavitation is ozone cavitation.
The odor and sewage treatment system further comprises a second micro-bubble generator 21, wherein the inlet end of the second micro-bubble generator 21 is connected with a sewage inlet pipe 22 and an ozone generator 7 respectively, the outlet end of the second micro-bubble generator 21 is communicated with a sewage inlet 22-1 at the upper part of the spray tower 1, and the second micro-bubble generator 21 is used for mixing sewage and ozone to form nano micro-bubbles. The second micro-bubble generator 21 is arranged on the sewage inlet pipeline 22, so that the odor and sewage treatment system can treat odor, sewage and both odor and sewage, and the pipelines can be controlled to open and close according to actual requirements in the actual operation process. The working process specifically comprises the following steps: the sewage to be treated and the ozone form nano microbubbles in the second microbubble generator 21, the nano microbubbles enter the spray tower 2 through the sewage inlet at the upper part of the spray tower 2, and the nano microbubbles are sprayed out through the nozzle 23 to form small sewage droplets; the small sewage droplets move downwards under the action of gravity and are collected into sewage which is treated in a sewage collecting tank 1; a part of sewage moves upwards under the action of a water pump 20, passes through a third pipeline 12, a hydraulic cavitator 11, a fourth pipeline 13 and a spray pipeline 14 in sequence, is sprayed into a spray tower 1 by a hydraulic cavitator nozzle (nozzle 15), then flows downwards into a sewage collecting tank 2, and is treated in a reciprocating cycle manner. And a part of sewage is discharged through the sewage collecting tank 1 and enters the next working procedure for treatment.
The working process of the odor and sewage treatment system of the embodiment is as follows:
firstly, odor is input into a spray tower 1 through an air inlet 3, the odor passes through a packing layer and a spray layer, a water liquid absorption part sprayed by a spray pipeline 14 and a spray nozzle 15 of the spray layer can be dissolved in the odor of the water liquid, the water liquid absorbing the odor flows downwards into a sewage collection pool 2 under the action of gravity, and the treated odor is discharged through an exhaust port 4 at the top of the spray tower 1 under the action of a fan 5 and a frequency converter 6; meanwhile, sewage is input into the second microbubble generator 21 through the sewage inlet pipeline 22, meanwhile, part of ozone generated by the ozone generator 7 is input into the second microbubble generator 21, the ozone and the sewage are mixed in the second microbubble generator 21 to generate nano microbubbles, and the nano microbubbles enter the sewage collecting tank 22 through the nozzle 23 and enter the spray tower 1;
secondly, the ozone generator 7 generates ozone and inputs the ozone into the first micro-bubble generator 8 to be mixed with water liquid in the first micro-bubble generator 8 to form ozone micro-bubbles; in this step, the water may be water circulating between the wastewater collection tank 2 and the first microbubble generator 8, which contains contaminants; other solutions that newly introduce ozone-microbubble generating solutions are also possible.
Thirdly, ozone microbubbles are input into the sewage collecting tank 2 through a first pipeline 9 to be mixed with water liquid in the sewage collecting tank 2, and pollutants in the water liquid are decomposed under the action of an ozone catalyst; the water liquid in the sewage collecting tank 2 circulates between the sewage collecting tank 2 and the first microbubble generator 8 through the second pipeline 10, so that the utilization rate of the water liquid in the sewage collecting tank 2 is improved, and the water use cost of the system and the subsequent water treatment cost are reduced.
Then, the liquid in the sewage collecting tank 2 is input into the hydraulic cavitator 11 through the third pipeline 12 under the action of the water pump 20, and is mixed with the ozone input into the hydraulic cavitator 11 through the fifth pipeline 16 to generate ozone microbubbles; the water liquid is sprayed into the spray tower 1 through a fourth pipeline 13, a spray pipeline 14 and a spray head 15, the odor entering and ascending through the air inlet 3 is dissolved, and then the water liquid flows into the sewage collecting tank 2; meanwhile, the sewage in the sewage collecting tank 2 is discharged through a sewage discharge pipe port 0 of the sewage collecting tank 2.
The water liquid in the sewage collecting tank 2 continuously circulates among the sewage collecting tank 2, the hydrodynamic cavitation device 11 and the first micro-bubble generator 8 through 2 paths, so that the odor input into the spray tower 1 is treated. According to the invention, by designing the ozone microbubble generating assembly, the ozone microbubble generating assembly can provide ozone microbubbles for the sewage collecting tank 2 in the spray tower 1, so that the treatment efficiency and effect of water liquid (dissolved with harmful components in odor) in the sewage collecting tank 2 are accelerated.
Example 3:
as a further improvement to examples 1 and 2, when the odor and sewage treatment system is treating odor. Since ultraviolet rays are invisible light having a higher frequency than blue-violet light in an electromagnetic spectrum having a wavelength of 400nm to 10nm, they do not cause human vision. When the photon energy of ultraviolet light is greater than the chemical bond energy of organic pollutants, a photolysis reaction is usually generated, so that the chemical bond of the organic pollutants is broken. For example: the photon energy of 185nm ultraviolet rays and 254nm ultraviolet rays is 647kJ/mol and 472kJ/mol respectively, the photon energy is larger than the molecular covalent bond energy of most organic waste gas gases, the covalent bond of most organic waste gas molecules can be directly broken, the molecular chain breakage is caused, and therefore, the macromolecular odor molecules are decomposed into H2O、O2And other small molecules to achieve the odor treatment effect. Simultaneously, when the ultraviolet ray is appliedAt a line wavelength of 200nm or less, O2The molecule will be decomposed to generate active O; active O and O2Combined to form O3。O3Can produce simple, low-harmful or harmless substances such as H by oxidation reaction with organic pollutant ions in a free state2O、CO2And the like. Irradiating 185nm photons to oxygen molecules to convert oxygen (O)2) After the covalent bond is broken into oxygen atoms, the oxygen atoms are further reacted with the surrounding oxygen molecules (O)2) Combine to form ozone (O) containing 3 oxygen atoms3)。
Therefore, the present embodiment improves the odor and sewage treatment system on the basis of the above odor and sewage treatment system. As shown in fig. 1 and 2, the odor and sewage treatment system further includes an ultraviolet lamp assembly for decomposing and catalyzing odor entering the spray tower 1, the ultraviolet lamp assembly including a first ultraviolet lamp 24 disposed on an inner wall of the spray tower 1. When the odor and sewage treatment system treats odor, the odor enters the spray tower 1 from the air inlet 2 of the spray tower 1, moves upwards along the spray tower 1, passes through the packing layer and the spray layer and is discharged from the air outlet 4 at the top of the spray tower 1. The first ultraviolet lamps 24 on the inner wall of the spray tower 1 can emit ultraviolet light (185nm and 254nm) with specific wavelength to further treat the odor.
In the embodiment, because ozone has a certain poisoning effect, and the direct discharge of ozone can cause people to suffer from nerve poisoning, dizziness, headache, vision deterioration, memory deterioration and the like, the second ozone catalyst is arranged in the spray tower 1 and close to the exhaust port 4, and is used for catalyzing and decomposing ozone in the spray tower 1 into oxygen, so that the gas discharged from the exhaust port 4 does not contain ozone.
In the invention, the second ozone catalyst is arranged on the grid, the packing layer is also arranged in the spray tower 1 and consists of the grid and the packing, the grid is mainly used for supporting the packing, the packing is loose and porous, the retention time of odor in the spray tower 1 can be prolonged, meanwhile, the odor can be fully contacted with sprayed liquid drops, and the odor treatment efficiency is improved; the liquid drops sprayed by the spraying layer are converged into a sewage collecting tank 2 at the bottom 1 of the spraying tower under the action of gravity to form sewage (namely water liquid) to be treated, and pollutants in the sewage to be treated are decomposed at an accelerated speed under the action of ozone microbubbles and an ozone catalyst in the sewage collecting tank 2.
Further, in order to further improve the treatment effect of the odor, the ultraviolet lamp assembly further comprises a second ultraviolet lamp (not shown in the attached drawing), the second ultraviolet lamp is positioned in an odor pipeline (not shown in the attached drawing) communicated with the air inlet 3, the second ultraviolet lamp pretreats the odor by communicating the odor pipeline, decomposes partial pollutants in the odor, and then discharges the decomposed partial pollutants into the spray tower 1 for treatment.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (10)

1. A system for treating odor and sewage comprises a spray tower, wherein a sewage collecting pool is arranged at the bottom in the spray tower, and an air inlet, an air outlet and a sewage discharge pipe opening are formed in the spray tower; the method is characterized in that: the odor and sewage treatment system also comprises an ozone microbubble generation assembly, wherein the ozone microbubble generation assembly comprises an ozone generator and a first microbubble generator communicated with the ozone generator;
the ozone generator generates ozone and delivers the ozone into the first microbubble generator; the first micro-bubble generator mixes the ozone with water in the first micro-bubble generator and generates ozone micro-bubbles;
the first microbubble generator is communicated with the sewage collecting tank through a first pipeline, and the first microbubble generator is used for conveying the ozone microbubbles to the sewage collecting tank.
2. The odor and sewage treatment system according to claim 1, wherein: the first microbubble generator is also communicated with the sewage collecting tank through a second pipeline, and the sewage collecting tank discharges part of the water liquid into the first microbubble generator through the second pipeline and mixes with the ozone to generate the ozone microbubbles.
3. The odor and sewage treatment system according to claim 1, wherein: be equipped with first ozone catalyst in the sewage collecting pit, first ozone catalyst is used for catalyzing ozone decomposition in the ozone microbubble and produce the OH of strong oxidizing property.
4. The odor and sewage treatment system according to any one of claims 1 to 3, wherein: the odor and sewage treatment system also comprises a hydraulic cavitator, one end of the hydraulic cavitator is communicated with the sewage collecting tank through a third pipeline, and the other end of the hydraulic cavitator is communicated with a spray pipeline in the spray tower through a fourth pipeline;
the hydraulic cavitator is used for performing hydraulic cavitation reaction on part of the water liquid discharged from the sewage collecting tank and then spraying the water liquid out through a spray head of the spray pipeline.
5. The odor and sewage treatment system according to claim 4, wherein: the hydraulic cavitator is also communicated with the ozone generator through a fifth pipeline, the ozone generator inputs part of generated ozone into the hydraulic cavitator, and the ozone and water liquid input into the hydraulic cavitator through the third pipeline are mixed to enable the generated liquid vacuole to be ozone vacuole.
6. The odor and sewage treatment system according to claim 5, wherein: and the third pipeline is also provided with a pressure gauge, a flowmeter and a pressure regulating valve.
7. The odor and sewage treatment system according to claim 4, wherein: the spray head is a hydraulic cavitation spray head.
8. The odor and sewage treatment system according to any one of claims 5 to 7, wherein: the odor and sewage treatment system also comprises an ultraviolet lamp assembly, the ultraviolet lamp assembly is used for decomposing odor entering the spray tower, and the ultraviolet lamp assembly comprises a first ultraviolet lamp arranged on the inner wall of the spray tower;
and a second ozone catalyst is arranged in the spray tower and close to the exhaust port, and is used for catalytically decomposing the ozone in the spray tower into oxygen.
9. The odor and sewage treatment system according to claim 8, wherein: the ultraviolet lamp assembly further comprises a second ultraviolet lamp, and the second ultraviolet lamp is located in the odor gas pipeline communicated with the gas inlet.
10. The odor and sewage treatment system according to claim 9, wherein: the odor and sewage treatment system further comprises a second micro-bubble generator, wherein the inlet end of the second micro-bubble generator is respectively connected with a sewage inlet pipeline and the ozone generator, the outlet end of the second micro-bubble generator is communicated with a sewage inlet on the upper part of the spray tower, and the second micro-bubble generator is used for mixing sewage with ozone to form nano micro-bubbles.
CN202011290542.9A 2020-11-18 2020-11-18 Odor and sewage treatment system Pending CN112316673A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113813750A (en) * 2021-10-29 2021-12-21 湖南众德新材料科技有限公司 New material production is with chemical industry exhaust-gas treatment environment-friendly device
CN114314904A (en) * 2021-12-11 2022-04-12 国网湖北省电力有限公司电力科学研究院 Combined sewage treatment system and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113813750A (en) * 2021-10-29 2021-12-21 湖南众德新材料科技有限公司 New material production is with chemical industry exhaust-gas treatment environment-friendly device
CN114314904A (en) * 2021-12-11 2022-04-12 国网湖北省电力有限公司电力科学研究院 Combined sewage treatment system and method

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