CN112300583A - Low-odor rubber-plastic heat-insulation board for automobile decoration - Google Patents

Low-odor rubber-plastic heat-insulation board for automobile decoration Download PDF

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Publication number
CN112300583A
CN112300583A CN202011222182.9A CN202011222182A CN112300583A CN 112300583 A CN112300583 A CN 112300583A CN 202011222182 A CN202011222182 A CN 202011222182A CN 112300583 A CN112300583 A CN 112300583A
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CN
China
Prior art keywords
rubber
smell
insulation board
mass
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011222182.9A
Other languages
Chinese (zh)
Inventor
秦伯军
张君
秦天德
刘远斌
谢存剑
曹鑫
吉娇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yingsheng Energy Saving Group Co ltd
Original Assignee
Yingsheng Energy Saving Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yingsheng Energy Saving Group Co ltd filed Critical Yingsheng Energy Saving Group Co ltd
Priority to CN202011222182.9A priority Critical patent/CN112300583A/en
Publication of CN112300583A publication Critical patent/CN112300583A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06Waxes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a low-odor rubber-plastic heat-insulation board for automobile decoration, which comprises the following components in percentage by weight: 11.32-11.34% of nitrile rubber, 1.2-1.4% of butadiene rubber, 20.88-20.90% of talcum powder, 12.93-12.95% of aluminum hydroxide, 14.88-14.90% of polyvinyl chloride, 1.93-1.95% of carbon black, 20.70-20.72% of chlorinated paraffin, 1.2-1.4% of dispersing agent and 4-6% of smell removing agent, wherein a plurality of smell removing agents are added into a raw material system to replace unnecessary products generating irritant smell in the raw materials, and meanwhile, the smell is removed by physical methods such as baking and the like subsequently, so that the volatile smell of the rubber and plastic product reaches the level of 3.0 required by the automobile industry.

Description

Low-odor rubber-plastic heat-insulation board for automobile decoration
Technical Field
The invention relates to the technical field of rubber and plastic heat-insulation boards, in particular to a low-odor rubber and plastic heat-insulation board for automobile decoration.
Background
The existing automobile materials are mostly CR and polyurethane sponge and foamed polyethylene, a single material is difficult to meet the effects of heat preservation, sound insulation and decoration, an adhesive composite mode is often adopted, the tear strength is poor, the process cost is increased, the problems that the water absorption rate and the dust absorption are increased due to the open-cell semi-open structure and the like are solved, and the long-term use experience is poor.
Therefore, we propose a low-odor rubber-plastic insulation board for automobile decoration to solve the above problems.
Disclosure of Invention
The invention aims to solve the defects in the prior art, and the low-odor rubber and plastic heat-insulation board for automobile decoration uses excellent heat-insulation and sound-insulation performance of rubber and plastic to replace a composite material, so that the use cost is reduced, and the problem of unstable long-term use performance is solved.
The low-odor rubber-plastic heat-insulation board for automobile decoration contains: 11.32-11.34% of nitrile rubber, 1.2-1.4% of butadiene rubber, 20.88-20.90% of talcum powder, 12.93-12.95% of aluminum hydroxide, 14.88-14.90% of polyvinyl chloride, 1.93-1.95% of carbon black, 20.70-20.72% of chlorinated paraffin, 1.2-1.4% of dispersing agent and 4-6% of deodorant.
The invention has the beneficial effects that:
a plurality of deodorant components are added into a raw material system to replace unnecessary products which generate pungent odor in the raw materials, and simultaneously, the odor is removed by physical methods such as baking and the like, so that the volatile odor of the rubber and plastic product reaches the level of 3.0 required by the automobile industry.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
Example one
The low-odor rubber-plastic heat-insulation board for automobile decoration contains: 11.32% by mass of nitrile rubber, 1.2% by mass of butadiene rubber, 20.88% by mass of talc, 12.93% by mass of aluminum hydroxide, 14.88% by mass of polyvinyl chloride, 1.93% by mass of carbon black, 20.70% by mass of chlorinated paraffin, 1.2% by mass of a dispersant, and 3% by mass of a deodorant.
Example two
The low-odor rubber-plastic heat-insulation board for automobile decoration contains: 11.33% by mass of nitrile rubber, 1.3% by mass of butadiene rubber, 20.89% by mass of talc, 12.94% by mass of aluminum hydroxide, 14.89% by mass of polyvinyl chloride, 1.94% by mass of carbon black, 20.71% by mass of chlorinated paraffin, 1.3% by mass of a dispersant, and 5% by mass of a deodorant.
EXAMPLE III
The low-odor rubber-plastic heat-insulation board for automobile decoration contains: 11.34% by mass of nitrile rubber, 1.4% by mass of butadiene rubber, 20.90% by mass of talc, 12.95% by mass of aluminum hydroxide, 14.90% by mass of polyvinyl chloride, 1.95% by mass of carbon black, 20.72% by mass of chlorinated paraffin, 1.4% by mass of a dispersant, and 6% by mass of a deodorant.
The production process of the low-odor rubber and plastic heat-insulation board for automobile decoration comprises the following steps:
s1, banburying and open mixing;
a. placing nitrile rubber, plasticizer, polyvinyl chloride, chlorinated polyvinyl chloride and aluminum hydroxide into an internal mixer for internal mixing, discharging, mixing materials by an open mill, and slicing into a material No. 1;
b. respectively mixing a plasticizer, a foaming agent, nitrile rubber and a nucleating agent, and banburying, milling and rolling into a foaming agent film which is a No. 2 material;
c. respectively weighing an activating agent, an accelerator, nitrile rubber, a plasticizer and a nucleating agent, and carrying out closed milling and rolling to obtain a vulcanization accelerator rubber sheet as a material No. 3;
d. respectively weighing materials No. 1, No. 2 and No. 3 according to the required weight of the formula, uniformly mixing and rolling in an open mill, and cutting into rubber strips with certain specifications;
s2, extrusion: feeding the materials into an extruder, flattening, integrating and re-extruding the materials through a multi-roll calender, and controlling the extrusion temperature, pressure and rotating speed;
s3, vulcanization foaming: continuously feeding the extruded and shaped film to be foamed into a foaming furnace for foaming, and adjusting the material rod transmission rate in the foaming furnace and the temperature of each area to enable the film to be vulcanized and foamed according to preset requirements;
s4, traction cooling: cooling the product formed by foaming in the foaming furnace by air cooling to solidify the structure;
s5, post-processing: the produced rubber and plastic product is baked in a 80 ℃ oven to continuously remove volatile gas, and is taken out after two hours and cooled, and the process is repeated for 4 to 5 times.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (1)

1. Low-odor rubber and plastic heat-insulation board for automobile decoration is characterized by comprising: 11.32-11.34% of nitrile rubber, 1.2-1.4% of butadiene rubber, 20.88-20.90% of talcum powder, 12.93-12.95% of aluminum hydroxide, 14.88-14.90% of polyvinyl chloride, 1.93-1.95% of carbon black, 20.70-20.72% of chlorinated paraffin, 1.2-1.4% of dispersing agent and 4-6% of deodorant.
CN202011222182.9A 2020-11-05 2020-11-05 Low-odor rubber-plastic heat-insulation board for automobile decoration Pending CN112300583A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011222182.9A CN112300583A (en) 2020-11-05 2020-11-05 Low-odor rubber-plastic heat-insulation board for automobile decoration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011222182.9A CN112300583A (en) 2020-11-05 2020-11-05 Low-odor rubber-plastic heat-insulation board for automobile decoration

Publications (1)

Publication Number Publication Date
CN112300583A true CN112300583A (en) 2021-02-02

Family

ID=74325025

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011222182.9A Pending CN112300583A (en) 2020-11-05 2020-11-05 Low-odor rubber-plastic heat-insulation board for automobile decoration

Country Status (1)

Country Link
CN (1) CN112300583A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114181440A (en) * 2021-11-29 2022-03-15 陕西秦力橡胶有限责任公司 Low-VOC rubber floor composition and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109851916A (en) * 2018-12-28 2019-06-07 成都金发科技新材料有限公司 A kind of permanent fragrance type fiber glass reinforced polypropylene material of low VOC and preparation method thereof
CN111117015A (en) * 2020-01-06 2020-05-08 神州节能科技集团有限公司 Rubber and plastic product with low TVOC release amount and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109851916A (en) * 2018-12-28 2019-06-07 成都金发科技新材料有限公司 A kind of permanent fragrance type fiber glass reinforced polypropylene material of low VOC and preparation method thereof
CN111117015A (en) * 2020-01-06 2020-05-08 神州节能科技集团有限公司 Rubber and plastic product with low TVOC release amount and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张军: "聚氯乙烯/丁腈橡胶/顺丁橡胶浅色模压胶辊的研制", 《橡胶工业》 *
郑晓降等: "丁腈橡胶/聚氯乙烯/顺丁橡胶共混弹性体的形态和性质", 《成都科技大学学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114181440A (en) * 2021-11-29 2022-03-15 陕西秦力橡胶有限责任公司 Low-VOC rubber floor composition and preparation method thereof

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Application publication date: 20210202

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