CN1122814A - Light converting film - Google Patents
Light converting film Download PDFInfo
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- CN1122814A CN1122814A CN94114161A CN94114161A CN1122814A CN 1122814 A CN1122814 A CN 1122814A CN 94114161 A CN94114161 A CN 94114161A CN 94114161 A CN94114161 A CN 94114161A CN 1122814 A CN1122814 A CN 1122814A
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- -1 polyethylene Polymers 0.000 claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 239000004698 Polyethylene Substances 0.000 claims abstract description 23
- 229920000573 polyethylene Polymers 0.000 claims abstract description 23
- 239000000654 additive Substances 0.000 claims abstract description 22
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 93
- 230000003712 anti-aging effect Effects 0.000 claims description 26
- 239000004596 additive masterbatch Substances 0.000 claims description 15
- 239000008187 granular material Substances 0.000 claims description 14
- 238000007664 blowing Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 8
- 230000032683 aging Effects 0.000 claims description 7
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 3
- 238000000071 blow moulding Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 3
- 150000002910 rare earth metals Chemical class 0.000 abstract description 3
- 229910052693 Europium Inorganic materials 0.000 abstract description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 abstract description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 abstract description 2
- 230000003287 optical effect Effects 0.000 abstract 2
- 229920006254 polymer film Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 235000013311 vegetables Nutrition 0.000 description 4
- 239000002861 polymer material Substances 0.000 description 3
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000009849 Cucumis sativus Nutrition 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008918 Chaenomeles cathayensis Species 0.000 description 1
- 235000009810 Chaenomeles cathayensis Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- 244000000626 Daucus carota Species 0.000 description 1
- 235000002767 Daucus carota Nutrition 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 235000017309 Hypericum perforatum Nutrition 0.000 description 1
- 244000141009 Hypericum perforatum Species 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 240000002924 Platycladus orientalis Species 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 244000184734 Pyrus japonica Species 0.000 description 1
- 235000001537 Ribes X gardonianum Nutrition 0.000 description 1
- 235000001535 Ribes X utile Nutrition 0.000 description 1
- 235000016919 Ribes petraeum Nutrition 0.000 description 1
- 244000281247 Ribes rubrum Species 0.000 description 1
- 235000002355 Ribes spicatum Nutrition 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 244000046738 asparagus lettuce Species 0.000 description 1
- 235000006705 asparagus lettuce Nutrition 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Greenhouses (AREA)
- Protection Of Plants (AREA)
Abstract
These films are prepared from improved farm polymer films such as polyethylene etc. high-molecular polymer which is compatible with rare-earth europium and terbium chelates used as optical convertion additive, and its concentrated grains is compatible with selected antiager and antifog-drip agent. The optical convertion shed and ground films prepared by this method can transform ultraviolet light into orange-red light, and have antiager and anti-fog-drip properties.
Description
The present invention is an improvement on agricultural high-molecular material film. In particular to a light conversion film, which belongs to the field of polymer material compositions. The film is applied to agricultural shed mulching films, can convert ultraviolet light in sunlight into orange red light, and has aging resistance and anti-fogging property.
The prior art on which the present invention is based is:
U.S. Pat. No. 3398099 discloses a fluorescent material. They produced a rare earth metal chelate and made progress in the application of laser technology.
The former Soviet Union reports in Dutch patent No189794 that the application of various rare earth chelates as additives to prepare high molecular materials for greenhouse covering has good effect in agriculture. The additive is characterized by containing at least one f element which can absorb ultraviolet rays in the sunlight and make the ultraviolet rays emit light in an orange red region. f elemental additive compound formula:
Me n+XmYn-mLk
wherein M iseComprises the following steps: eu, Sm, Tb, Dy and UO2；
X and Y are: cl, NO3，COO-And a diketone anion;
l is: r3PO，(RO)3PO，R2SO, (R is alkyl or aryl);
2DP( 2, 2' -bipyridine),
phen( 
1, 10-phenanthroline),
VBI( 
n＝3，2；m＝0，1；k＝0，1，2，3；
polyethylene, polyvinyl chloride, polypropylene, polystyrene, polycarbonate, polymethyl methacrylate, polymethyl acrylate, styrene and methyl methacrylate copolymer and the like are used as high polymer materials, and additives with different compositions are added in the amount of about 0.001-5% by weight, and the formula of 172 examples of light conversion high polymer materials is listed. Covering greenhouse plants with films of these materials is compared to ordinary films: in a unit greenhouse, the harvest of cucumbers, tomatoes and cabbages is respectively improved by 15-17%, 20-30% and 92-96%.
However, these polymeric film materials with light conversion properties, although absorbing the ultraviolet rays in sunlight and converting them into orange-red light, do not have other functions, such as: sufficient light aging resistance, anti-fogging property, and the like.
There are many types of current anti-aging polyethylene agricultural films. Commonly used anti-aging agents are: benzotriazole-based UV.326 and UV.327; light stabilization 2002, 1084 for organic nickel chromium species; benzophenone-type UV.9, UV-24, UV.531; and the like, cannot be used in a light conversion film. This is because the additives containing iron, nickel, titanium and other metal compounds influence the light-converting properties of the light-converting additive. It is not always possible to use different types of surfactant-containing anti-fogging drops in light-converting films. Especially, the double-prevention type auxiliary agent has an influence on the light conversion performance.
The aim of the invention is to solve the following problems: the light conversion film made of the light conversion additive has aging resistance and anti-fogging property. The film simultaneously meets the following requirements:
(1) transparent in the visible range of the spectrum;
(2) can absorb ultraviolet rays in sunlight;
(3) the coating has good heat preservation and improves the light transmittance of a red light area;
(4) and no toxic substances are contained and decomposed.
The invention aims to determine the following formula of the light conversion film by strictly screening different types of anti-aging agents and anti-fogging agents: a selected light-converting film comprising: the polymer compound such as polyethylene at least contains one of the following light conversion additives, and the molecular formula of the polymer compound is as follows:
Me n+XmYn-mLk(ii) a Wherein,
Mecomprises the following steps: eu (europium), Tb (terbium);
x and Y are: cl-，NO3 -，COO-And a diketone anion;
l is: 2DP, phen, VBI;
n＝2，3；m＝0，1；k＝0，1，2，3；
in addition to the above-mentioned light-converting additive Me n+XmYn-mLkThe light conversion film can meet the requirements of the invention only by mixing with polyethylene high molecular compounds and adding an anti-aging agent and/or an anti-fog drop agent necessary auxiliary agent.
The light conversion film comprises the following components in percentage by weight:
the high molecular compound such as polyethylene is: 100 portions of
Light conversion additive Me n+XmYn-mLkComprises the following steps: 0.1 to 5.0 parts
The hindered amine compound in the anti-aging agent is as follows: 0.1 to 1.0 portion
And/or fatty acid polyols in anti-fogging drops
The alcohol ester compound is: 0.5 to 1.0 portion
Hindered amine compounds in the anti-aging agent selected by the film mainly refer to: 944 (Switzerland: manufactured by Kyogaki Co., Ltd.), or 540 (handbook of Plastic auxiliaries, published by Beijing light industry Press, 1984), or GFW-2 (manufactured by Kogyo chemical plant).
The preparation method of the anti-aging light conversion film comprises the following steps:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene powder or granules; adding a light conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, then heating to 150-200 ℃, and extruding and granulating for later use.
(II) blowing the anti-aging light conversion film: taking 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.1-1.0 part of 944, or 540, or GFW-2 of anti-aging agent; the anti-aging light conversion film is formed by blowing through common film making process equipment.
The fatty acid polyol ester compound of the anti-fogging agent selected by the film mainly comprises the following components: FY-2, or FY-22 (a product of Beijing institute of chemical industry).
The manufacturing method of the anti-fogging light conversion film is carried out by the following steps:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene granules; adding intoLight conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, then heating to 150-200 ℃, and extruding and granulating for later use.
(II) blowing an anti-fogging light conversion film: taking 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.5-1.0 part of FY-2 or FY-22 of anti-fogging agent or single-prevention master batch of one of the three; and blowing the film into the anti-fogging light conversion film by using common film making process equipment.
The light conversion film with double-proofing property, anti-aging property and anti-fog drop property, which is provided by the film, is manufactured by the following steps:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene granules; adding a light conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, then heating to 150-200 ℃, and extruding and granulating for later use.
(II) blowing a light conversion film with aging resistance and anti-fogging property: preparing 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.1-1.0 part of 540 parts of anti-aging agent or GFW-2 and 0.5-1.0 part of FY-2 of anti-fogging agent or single-prevention master batch of FY-2; the light conversion film with the anti-aging property and the anti-fogging property is formed by blowing through common film making process equipment.
The film can also be made into a light conversion film with a three-layer structure. Which is prepared by respectively adding the following components in 100 parts of polyethylene granules: 0.2-0.5 part of an anti-aging agent 540, or GFW-2; 0.15-0.5 part of light conversion additive master batch; 0.8-1.0 part of FY-2 of the anti-fogging agent or single-prevention master batch of the FY-2; blow molding in three layers. The cross section structure of the three-layer film is as follows: the outer sunny side is anti-aging light conversion film, the middle layer is light conversion film, and the inner layer is anti-fog light conversion film.
Examples of the invention are the formulations of the weathering resistant and anti-fogging light-converting films listed in Table 1:
table 1: the light conversion film has aging resistance and antifog drip resistance.
The formula of the adopted light conversion additive master batch is as follows: 0.2kg of light conversion additive and 10kg of high-pressure polyethylene are uniformly stirred and extruded and granulated at 180 ℃.
Table 1:
the hindered amine anti-aging agent selected by the invention has a structural formula with substituted piperidine groups, is a novel long-acting light-resistant aging agent, and has less light conversion interference on a light conversion additive.
The FY-type anti-fogging agent adopted by the invention has less light conversion interference on the light conversion additive because the single anti-fogging agent is adopted.
Therefore, the light conversion film has high light transmittance and good light conversion effect in farmland experiments. The rapid detection method of the various light conversion films uses a common ultraviolet lamp (with the wavelength of 250-390 nm) for irradiation, and bright red light is emitted under the visible film.
The formulation of each embodiment of the invention is blown into 0.10-0.12 mm greenhouse film and 0.008-0.014 mm mulching film on a common blow molding device, and each is more than 100 kg. The greenhouse light conversion film prepared by the formulas No. 6, No. 9, No. 11 and No. 12 in the formulas of the embodiments is used in agricultural experimental fields, particularly applied to vegetable planting, and has a positive effect, so that the mature period of crops is advanced by 3-15 days, the temperature in the greenhouse is increased by 3-5 ℃ due to the increase of red light in winter, and the freezing injury of the crops is prevented. In summer, the temperature in the greenhouse is properly reduced due to the absorption and conversion of strong ultraviolet rays. The superiority of the light conversion film can be seen in the following experimental data:
compared with glass or common films, the light conversion film is used in greenhouses, and the yield of vegetables is increased as follows (%):
50-90 tomatoes and 15-50 cucumbers
20 to 25 parts of carrot and 15 to 20 parts of pepper
15-20 asparagus lettuce pumpkin 10-15
In the light conversion film greenhouse, the weight of a single vegetable head is increased by 74 percent on average and the area of vegetable leaves is increased by 75 percent on average compared with the common film greenhouse.
Compared with the common film greenhouse, the growth conditions of the flowers in the family of the bouquet inflorescence in the light conversion film greenhouse are as follows: see table 2:
TABLE 2
Under the condition of the light conversion film, the rooting of the cuttings of all woody plants is greatly superior to that of the common film, and the following table 3 shows that:
TABLE 3 comparative test for growth of various flowers
| Plant species | Comparative test | The rooting percentage is% | Number of roots | Root length mm | Root diameter mm |
| Jasmine flower | Light conversion film of common film | 100100 | 16.115.3 | 52.760.5 | 37.745.1 |
| Chinese flowering quince | Light conversion film of common film | 100100 | 14.717.2 | 86.696.7 | 38.750.7 |
| Hypericum perforatum L.var.japonica | Light conversion film of common film | 93100 | 26.721.9 | 82.270.1 | 28.630.7 |
| American currant | Light conversion film of common film | 100100 | 13.315.0 | 83.7100.8 | 38.542.5 |
| Twig of Chinese arborvitae | Light conversion film of common film | 93100 | 5.89.5 | 38.551.7 | 28.028.3 |
In addition, the light conversion film has the following obvious characteristics: in the greenhouse, ultraviolet rays in natural light are blocked and converted into red orange light, and the ultraviolet light below 380nm is reduced, so that the growth of pathogenic bacteria such as gray mold, sclerotinia sclerotiorum and the like can be inhibited, insect pests such as aphids, mites and the like lose light sensation, and the occurrence and harm of the diseases and insects are reduced.
Claims (8)
1. A light converting film comprising: the polymer compound such as polyethylene at least contains one of the following light conversion additives, and the molecular formula of the polymer compound is as follows:
Me n+XmYn-mLk(ii) a Wherein,
Mecomprises the following steps: eu, Tb;
x and Y are: cl-，NO3 -，COO-And a diketone anion;
l is: 2DP, phen, VBI;
n＝2，3 ；m＝0，1；k＝0，1，2，3；
the method is characterized in that: the light conversion film also contains an anti-aging agent and/or an anti-fog drop agent.
2. A light conversion film as defined in claim 1, wherein: the light conversion film comprises the following components in percentage by weight:
the high molecular compound such as polyethylene is: 100 parts of (A);
light conversion additive Me n+XmYn-mLkComprises the following steps: 0.1-5.0 parts;
the hindered amine compound in the anti-aging agent is as follows: 0.1-1.0 part;
and/or fatty acid polyols in anti-fogging drops
The alcohol ester compound is: 0.5-1.0 part;
3. a light conversion film according to claim 1 or 2, wherein: the hindered amine compound in the anti-aging agent mainly comprises the following components: 944, or 540, or GFW-2.
4. The method for manufacturing a light conversion film according to claim 3, wherein: the light conversion film is manufactured by the following steps:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene powder or granules; adding a light conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, then heating to 150-200 ℃, and extruding and granulating for later use;
(II) blowing the anti-aging light conversion film: taking 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.1-1.0 part of 944, or 540, or GFW-2 of anti-aging agent; the anti-aging light conversion film is formed by blowing through common film making process equipment.
5. A light conversion film according to claim 1 or 2, wherein: the fatty acid polyol ester compounds of the anti-fogging drop mainly refer to: FY-2, or FY-22.
6. The method for manufacturing a light conversion film according to claim 5, wherein: the manufacturing steps of the light conversion film are as follows:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene granules; adding a light conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, and then extruding and granulating the mixture at 150-200 ℃ for later use;
(II) blowing an anti-fogging light conversion film: taking 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.5-1.0 part of FY-2 or FY-22 of anti-fogging agent or single-prevention master batch of one of the two; and blowing the film into the anti-fogging light conversion film by using common film making process equipment.
7. A method for manufacturing a light conversion film according to claim 1 or 2, wherein: the manufacturing steps of the light conversion film are as follows:
preparing a light conversion additive master batch: taking 100 parts of high-pressure polyethylene granules; adding a light conversion additive Me n+XmYn-mLk0.5-5.0 parts; stirring for 3-5 minutes by a high-speed stirrer at 2000 rpm until the mixture is uniform, and then extruding and granulating the mixture at 150-200 ℃ for later use;
(II) blowing a light conversion film with aging resistance and anti-fogging property: taking 100 parts of high-pressure polyethylene granules; adding 0.1-1.0 part of light conversion additive master batch, and simultaneously adding 0.1-1.0 part of 540 parts of anti-aging agent or GFW-2 and 0.5-1.0 part of FY-2 of anti-fogging agent or single-prevention master batch of FY-2; the light conversion film with the anti-aging property and the anti-fogging property is formed by blowing through common film making process equipment.
8. A light conversion film according to claim 1 or 2, wherein: the light conversion film is prepared by respectively adding 0.2-0.5 part of an anti-aging agent 540 or GFW-2 into 100 parts of polyethylene granules; 0.15-0.5 part of light conversion additive master batch; 0.8-1.0 part of FY-2 of the anti-fogging agent or single-prevention master batch of the FY-2; the three-layer film is manufactured by blow molding in three layers, and the cross section structure of the three-layer film is as follows: the outer sunny side is an anti-aging light conversion film, the middle layer is a light conversion film, and the inner layer is an anti-fog-drop light conversion film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94114161A CN1052493C (en) | 1994-11-07 | 1994-11-07 | Light converting film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94114161A CN1052493C (en) | 1994-11-07 | 1994-11-07 | Light converting film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1122814A true CN1122814A (en) | 1996-05-22 |
| CN1052493C CN1052493C (en) | 2000-05-17 |
Family
ID=5037078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94114161A Expired - Fee Related CN1052493C (en) | 1994-11-07 | 1994-11-07 | Light converting film |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1052493C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079407C (en) * | 1997-12-15 | 2002-02-20 | 中国科学院电子学研究所 | Optical conversion agent for agricultural film and its manufacturing method |
| CN100447183C (en) * | 2006-04-25 | 2008-12-31 | 罗维鸿 | Day/night light conversion agricultural film and preparation method thereof |
| CN101857690A (en) * | 2010-05-19 | 2010-10-13 | 淮滨县创佳科技开发有限公司 | Rare-earth organic complex light conversion film with ultraviolet light-to-red light performance and preparation process thereof |
| CN102634102A (en) * | 2012-04-26 | 2012-08-15 | 界首市天鸿包装材料有限公司 | Preparation method of multifunctional light-conversion thin film added with rare earth |
| CN105623141A (en) * | 2015-06-11 | 2016-06-01 | 侯培毅 | Multifunctional agricultural light conversion net |
| CN109181059A (en) * | 2018-08-03 | 2019-01-11 | 东莞市济丰农业生态园开发有限公司 | It is a kind of to increase awning film of crop yield and preparation method thereof |
| CN111944221A (en) * | 2020-07-31 | 2020-11-17 | 中国农业科学院农业环境与可持续发展研究所 | Low-waveband ultraviolet absorption antibacterial light conversion film and preparation method thereof |
| WO2021036378A1 (en) * | 2019-08-31 | 2021-03-04 | 吴广龙 | Plastic light-converting agricultural film having long-lasting light conversion effect, and preparation method therefor |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH667463A5 (en) * | 1983-10-31 | 1988-10-14 | Inst Obschei I Neoorganichesko | POLYMERS COMPOSITION. |
| CN1009557B (en) * | 1988-02-23 | 1990-09-12 | 石家庄市东风塑料厂 | Anti-aging and dropless agricultural film |
-
1994
- 1994-11-07 CN CN94114161A patent/CN1052493C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079407C (en) * | 1997-12-15 | 2002-02-20 | 中国科学院电子学研究所 | Optical conversion agent for agricultural film and its manufacturing method |
| CN100447183C (en) * | 2006-04-25 | 2008-12-31 | 罗维鸿 | Day/night light conversion agricultural film and preparation method thereof |
| CN101857690A (en) * | 2010-05-19 | 2010-10-13 | 淮滨县创佳科技开发有限公司 | Rare-earth organic complex light conversion film with ultraviolet light-to-red light performance and preparation process thereof |
| CN102634102A (en) * | 2012-04-26 | 2012-08-15 | 界首市天鸿包装材料有限公司 | Preparation method of multifunctional light-conversion thin film added with rare earth |
| CN105623141A (en) * | 2015-06-11 | 2016-06-01 | 侯培毅 | Multifunctional agricultural light conversion net |
| CN109181059A (en) * | 2018-08-03 | 2019-01-11 | 东莞市济丰农业生态园开发有限公司 | It is a kind of to increase awning film of crop yield and preparation method thereof |
| WO2021036378A1 (en) * | 2019-08-31 | 2021-03-04 | 吴广龙 | Plastic light-converting agricultural film having long-lasting light conversion effect, and preparation method therefor |
| CN111944221A (en) * | 2020-07-31 | 2020-11-17 | 中国农业科学院农业环境与可持续发展研究所 | Low-waveband ultraviolet absorption antibacterial light conversion film and preparation method thereof |
| CN111944221B (en) * | 2020-07-31 | 2022-05-27 | 中国农业科学院农业环境与可持续发展研究所 | Low-waveband ultraviolet absorption antibacterial light conversion film and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1052493C (en) | 2000-05-17 |
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