CN112280412A - Primer-topcoat integrated building interior and exterior wall coating and preparation method thereof - Google Patents

Primer-topcoat integrated building interior and exterior wall coating and preparation method thereof Download PDF

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Publication number
CN112280412A
CN112280412A CN202011268454.9A CN202011268454A CN112280412A CN 112280412 A CN112280412 A CN 112280412A CN 202011268454 A CN202011268454 A CN 202011268454A CN 112280412 A CN112280412 A CN 112280412A
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China
Prior art keywords
parts
exterior wall
primer
wall coating
topcoat
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CN202011268454.9A
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Chinese (zh)
Inventor
关有俊
熊永强
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SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT CO LTD
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SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT CO LTD
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Priority to CN202011268454.9A priority Critical patent/CN112280412A/en
Publication of CN112280412A publication Critical patent/CN112280412A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to the technical field of building coatings, in particular to a primer-topcoat integrated building interior and exterior wall coating and a preparation method thereof, wherein the primer-topcoat integrated building interior and exterior wall coating for building exterior wall heat insulation putty is prepared from the following raw materials: inorganic modified polymer resin, silane coupling agent, defoaming agent, wetting dispersant, pigment, filler, thickening agent, antibacterial mildew preventive, film forming auxiliary agent and water. The invention has the beneficial effects that: the inorganic modified polymer resin has good permeability and sealing performance on the base material, can seal the seepage of harmful substances such as salt and alkali of the base material, and can form a continuous and complete firm coating on the surface, the silane coupling agent has good infiltration adsorbability, and can form good adhesion between the organic resin and the inorganic base material, so that the organic resin can better infiltrate into the gaps of the base material to form the sealing and reinforcing effects, and the sealing, reinforcing and decorating effects can be achieved by adopting one-time construction.

Description

Primer-topcoat integrated building interior and exterior wall coating and preparation method thereof
Technical Field
The invention relates to the technical field of building coatings, in particular to a primer-topcoat integrated building interior and exterior wall coating and a preparation method thereof.
Background
At present, the existing building area of China reaches more than 500 hundred million square meters, and 16 hundred million to 20 hundred million square meters are newly built every year. Most of decorations in the buildings are carried out by adopting exterior wall coatings, the building coatings in China reach more than 1000 million tons in 2019, wherein the building coatings on the interior and exterior walls reach more than 550 million tons, the coatings are more and more applied to the interior and exterior decoration of the buildings, and particularly, the building coatings have great advantages for renovating and transforming a large number of existing buildings.
Because the main body of the building structure adopts a reinforced concrete structure, alkaline substances continuously seep out in the using process due to the characteristics of cement, if no sealing measure is adopted, the coating can quickly generate the conditions of efflorescence, fading, pulverization and the like, the whole coating effect and the protection life are influenced, and for the renovation of the existing building, because the conditions of the original wall surface are complex, such as oil stain, pulverization and the like, and if primer is not adopted, the coating after construction is easy to drop, crack and the like.
In the actual construction process, because the primer coating needs to be carried out by one additional labor, the conditions that construction workers do not coat the primer, the primer coating is not uniform or the primer is directly added into the finish paint for construction can occur under many conditions, so that a large number of building decoration adverse conditions are caused.
Therefore, the building interior and exterior wall coating with the integrated bottom and interior walls is developed, the purposes of sealing and strengthening the wall base layer and achieving the decorative effect by one-time construction are achieved, a large amount of labor cost can be saved, the problems caused by multiple constructions are reduced, the work efficiency is improved, the consumption of primer can be saved, the consumption of raw materials is reduced, and good social and economic benefits are achieved.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the building interior and exterior wall coating with the integrated bottom and top surfaces and the preparation method thereof are provided, and the obtained building interior and exterior wall coating can achieve one-time construction and achieve the effect of integrating sealing, basal plane reinforcement and decoration effects.
In order to solve the technical problems, the invention adopts the technical scheme that: the building exterior wall heat-insulating putty and bottom surface integrated building interior and exterior wall coating is prepared from the following raw materials in parts by weight: 25-45 parts of inorganic modified polymer resin, 0.3-0.5 part of silane coupling agent, 0.3-0.6 part of defoaming agent, 0.5-1.2 parts of wetting dispersant, 5.0-25 parts of pigment, 10-20 parts of filler, 0.5-1.0 part of thickening agent, 0.3-0.5 part of antibacterial mildew preventive, 3.0-5.0 parts of film forming assistant and 10-20 parts of water.
Further, in the primer-topcoat integrated architectural interior and exterior wall coating, the inorganic modified polymer resin is an inorganic modified polymer emulsion.
Further, in the primer-topcoat integrated architectural interior and exterior wall coating, the inorganic modified polymer resin is a chemically modified grafted polymer resin.
Further, in the primer-topcoat integrated architectural interior and exterior wall coating material, the inorganic modified polymer resin is a composition obtained by mixing an organic resin and an inorganic slurry.
Further, in the primer-topcoat integrated building interior and exterior wall coating, the pigment is rutile type titanium dioxide or anatase type titanium dioxide.
The other technical scheme of the invention is as follows: the preparation method of the primer-topcoat integrated building interior and exterior wall coating comprises the following steps:
adding 10-20 parts of water, 0.3-0.5 part of silane coupling agent, 0.3-0.6 part of defoaming agent and 0.5-1.0 part of wetting dispersant into a paint mixing tank, stirring at 400-600rpm for 15-20min, adding 5-23 parts of titanium dioxide and 10-20 parts of filler, increasing the rotation speed to 1500-2000rpm, grinding to 20-30 mu m, adding 25-45 parts of inorganic modified polymer resin, adding 2.0-4.0 parts of film-forming auxiliary agent while stirring, continuing stirring for 15-20min, then adding 0.5-1.0 part of thickening agent to adjust to the required viscosity, adding 0.3-0.5 part of antibacterial mildew preventive, finally adding 0-3 part of color paste, uniformly stirring, discharging and packaging to obtain the bottom-integrated building interior and exterior wall coating.
The invention has the beneficial effects that: the primer-topcoat integrated building interior and exterior wall coating and the preparation method thereof are obtained based on the permeation film-forming property of an inorganic modified polymer and the infiltration and adsorption property of a silane coupling agent. The inorganic modified polymer resin has good permeability and sealing performance on the base material, can seal the seepage of harmful substances such as salt and alkali of the base material, and can form a continuous and complete firm coating on the surface, the silane coupling agent has good infiltration adsorbability, and can form good adhesion between the organic resin and the inorganic base material, so that the organic resin can better infiltrate into the gaps of the base material to form the sealing and reinforcing effects, and the sealing, reinforcing and decorating effects can be achieved by adopting one-time construction.
Detailed Description
In order to explain the technical content, the objects and the effects of the present invention in detail, the following description will be given with reference to the embodiments.
Example 1:
adding 10 parts of water, 0.5 part of silane coupling agent (MP-200), 0.6 part of defoaming agent (byk-012) and 0.8 part of wetting dispersant (5040) into a paint mixing tank, stirring at 600rpm for 20min, adding 18 parts of titanium dioxide (rutile type) and 12 parts of filler (8 parts of heavy calcium CM-6000 and 4 parts of calcined kaolin filler) in the pigment, increasing the rotating speed to 2000rpm, grinding to 30 mu m, adding 45 parts of (inorganic silicon modified acrylic polymer resin), adding 4.0 parts of film-forming assistant (TEXANOL alcohol ester 12) while stirring, continuously stirring for 20min, then adding 0.8 part of thickener (TEGO ViscoPlus 3030) to adjust to the required viscosity, adding 80.5 parts of antibacterial mildew inhibitor (ICIL QK-20), finally adding 2 parts of colorant (Kelaine Clariant aqueous color paste), uniformly stirring, discharging and packaging.
Example 2:
adding 20 parts of water, 0.3 part of silane coupling agent (MP-200), 0.4 part of defoaming agent (byk-012) and 1.0 part of wetting dispersant into a paint mixing tank, stirring for 20min at 500rpm, adding 8 parts of titanium dioxide (anatase type) and 20 parts of filler (12 parts of heavy calcium CM-6000 and 8 parts of calcined kaolin filler) in the pigment, increasing the rotating speed to 2000rpm, grinding to 20 mu m, adding 25 parts of inorganic modified polymer resin (inorganic silicon modified acrylic polymer resin), adding 2.0 parts of film-forming assistant (TEXANOL alcohol ester 12) while stirring, continuously stirring for 20min, then adding 1.0 part of thickener (TEGO ViscoPlus 3030) to adjust to the required viscosity, adding 0.4 part of antibacterial mildew preventive (ICIL QK-20), discharging and packaging after uniform stirring.
Example 3:
adding 15 parts of water, 0.4 part of silane coupling agent (MP-200), 0.5 part of defoaming agent (byk-012) and 0.8 part of wetting dispersant (5040) into a paint mixing tank, stirring for 15min at 500rpm, adding 15 parts of titanium dioxide (rutile type) and 15 parts of filler (9 parts of heavy calcium CM-6000 and 6 parts of calcined kaolin filler) in the pigment, increasing the rotating speed to 1500rpm, grinding to 30 mu m, adding 35 parts of inorganic modified polymer resin (inorganic silicon modified acrylic polymer resin), adding 3 parts of film-forming assistant (TEXANOL alcohol ester 12) while stirring, continuously stirring for 20min, then adding 0.8 part of thickener (TEGO ViscoPlus 3030) to adjust to the required viscosity, adding 0.5 part of antibacterial mildew preventive (ICIL QK-20), uniformly stirring, discharging and packaging.
Performance testing
The primer-topcoat one-building interior and exterior wall coatings obtained in examples 1 to 3 were tested for alkali resistance, saltpetering resistance, water permeability, scrubbing resistance, weathering resistance, and the like, respectively.
The test results are given in table 1 below.
TABLE 1
Figure BDA0002776847450000041
In conclusion, the primer-topcoat integrated building interior and exterior wall coating provided by the invention has good alkali resistance, saltpetering resistance, water permeability, scrubbing resistance and artificial weather aging resistance.
The above description is only an embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent modifications made by the present invention in the specification or directly or indirectly applied to the related technical field are included in the scope of the present invention.

Claims (6)

1. The primer-topcoat integrated building interior and exterior wall coating is characterized by being prepared from the following raw materials in parts by weight: 25-45 parts of inorganic modified polymer resin, 0.3-0.5 part of silane coupling agent, 0.3-0.6 part of defoaming agent, 0.5-1.2 parts of wetting dispersant, 5.0-25 parts of pigment, 10-20 parts of filler, 0.5-1.0 part of thickening agent, 0.3-0.5 part of antibacterial mildew preventive, 3.0-5.0 parts of film forming assistant and 10-20 parts of water.
2. The primer-topcoat-based architectural interior/exterior wall coating material of claim 1, wherein the inorganic modified polymer resin is an inorganic modified polymer emulsion.
3. The primer-topcoat-based architectural interior/exterior wall coating material of claim 1, wherein the inorganic modified polymer resin is a chemically modified graft polymer resin.
4. The primer-topcoat-type architectural interior/exterior wall coating material according to claim 1, wherein the inorganic modified polymer resin is a composition obtained by mixing an organic resin and an inorganic slurry.
5. The primer-topcoat-based architectural interior and exterior wall coating material of claim 1, wherein the pigment is rutile type titanium dioxide or anatase type titanium dioxide.
6. A method for preparing a primer-topcoat-based coating for interior and exterior walls of a building as claimed in any one of claims 1 to 5, comprising the steps of:
adding 10-20 parts of water, 0.3-0.5 part of silane coupling agent, 0.3-0.6 part of defoaming agent and 0.5-1.0 part of wetting dispersant into a paint mixing tank, stirring at 400-600rpm for 15-20min, adding 5-23 parts of titanium dioxide and 10-20 parts of filler, increasing the rotation speed to 1500-2000rpm, grinding to 20-30 mu m, adding 25-45 parts of inorganic modified polymer resin, adding 2.0-4.0 parts of film-forming auxiliary agent while stirring, continuing stirring for 15-20min, then adding 0.5-1.0 part of thickening agent to adjust to the required viscosity, adding 0.3-0.5 part of antibacterial mildew preventive, finally adding 0-3 part of color paste, uniformly stirring, discharging and packaging to obtain the bottom-integrated building interior and exterior wall coating.
CN202011268454.9A 2020-11-13 2020-11-13 Primer-topcoat integrated building interior and exterior wall coating and preparation method thereof Pending CN112280412A (en)

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CN202011268454.9A CN112280412A (en) 2020-11-13 2020-11-13 Primer-topcoat integrated building interior and exterior wall coating and preparation method thereof

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881516A (en) * 2014-04-16 2014-06-25 雅士利涂料(苏州)有限公司 One coat paint prepared by organic and inorganic compound emulsion and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103881516A (en) * 2014-04-16 2014-06-25 雅士利涂料(苏州)有限公司 One coat paint prepared by organic and inorganic compound emulsion and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭淑静: "《国内外涂料助剂品种手册》", 31 October 2000, 化学工业出版社 *

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Application publication date: 20210129