CN1122764A - Composition of activated ceramic container, and mfg. method thereof - Google Patents
Composition of activated ceramic container, and mfg. method thereof Download PDFInfo
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- CN1122764A CN1122764A CN 94113896 CN94113896A CN1122764A CN 1122764 A CN1122764 A CN 1122764A CN 94113896 CN94113896 CN 94113896 CN 94113896 A CN94113896 A CN 94113896A CN 1122764 A CN1122764 A CN 1122764A
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Abstract
The ceramic vessels are made from 5-80% medical stone, 5% China mainland clay, 5% Jinmen clay and 10-85% semiporcelain clay. The materials are pulverized into powder and mixed with water to form sludge, after moulding into blank, medical stoone sludge is coated on the interior face of the blank, after drying in air, glaze material is coated and the blank is sintered under 1200 deg.C to form a vessel with strong adsorption and ion exchange properties.
Description
The present invention relates to the composition and the manufacture method of earthenware porcelain receptacle, refer to powerful adsorption of a kind of tool and ion exchange especially, can change the composition and the manufacture method thereof of the activated ceramic container of solution quality in the container.
For the dregs in filtering fluid such as the water, mostly adopt filter paper in the prior art, filter cloth or activated carbon material, make fluid pass through filter material, with impurity wherein, filterings such as outstanding absurd creature, reach peace and quiet effect, but for a lot of fermentation liquid of content in the moisture, as fermented wine, soy sauce reveals, and fluid solutions such as vinegar are example with wine, in its manufacturing process after filtration, sterilization, if filter with filter material again, will filtering sugar wherein, essence is graded, and the quality that makes wine becomes bad, loses its local flavor greatly, so pure and sweet for the quality that keeps wine in the past, mostly wine is store the root of Dahurian angelica in wine jar, as Shaoxing rice wine, yellow rice wine, red rice wine etc., through storing chronically, make the vinosity esterification, it is more warm aromatic thick to enter the mouth, when drinking, heated or freezing its taste that makes better.Therefore, drink and both kept containing the sufficient nutrition composition, can not lose original local flavor again, just must be through storing chronically, this is not a good method for the individual of quantity-produced public institution or a small amount of product meal with wine, and the composition structure of ceramic wine jar, because crystallization shape difference causes chemical reactivity and deliquescent problem, cause ceramic surface to generate mineral matter, inorganic matter and mineral ion etc., with the passage of time, can't dissolve, the phenomenon that promptly causes precipitation to run off takes place again.
The activated ceramic container that the object of the present invention is to provide a kind of tool ion exchanging function also can change solution quality is rapidly formed and manufacture method, provide a kind of tool adsorption, but the activated ceramic container of foreign material is formed and manufacture method in the filtering solution.
The object of the present invention is achieved like this: a kind of activated ceramic container is formed and manufacture method is with medical stone, continent soil, Jinmen soil, clay pits such as half china clay are formed, it is characterized in that: in wheat rice-mouth 5%-80%, add 5% continent soil, half china clay of 5% Jinmen soil and 10-85% is formed, earlier will be according to the broken grind into fine powder of various raw materials of above-mentioned proper proportion, again with moisture mix form slurry, after the mold filling, treat that it forms hard container idiosome, take out the container idiosome, in the container idiosome, add the medical stone slurry again, draw embryo to make inner surface of container form a thin layer gradually through rotation, after repairing embryo, treat that it fully dries in the shade, coat the container that glaze is formed a powerful adsorption and ion exchange and is easy to regenerate with 1200 ℃ of sintering again.
The invention has the advantages that: the present invention is according to the container of an amount of ratio composition, sinter a porosity, resistance to acids, wine container that mechanical strength is big after mixing into, the adsorption and the ion exchange of medical stone composition tool brute force wherein, heavy metal in the adsorbable fluid, organic matter and impurity etc., and the Ca in it
+ 2Ion, Mg
+ 2Ion then has a small amount of stripping, can adjust pH value, and helps the mineralizing of solution, activate, so fermented material can become aromatic good to eat rapidly; Moreover its chemically, all stable on the calorifics, the long and repetitiousness of regenerating easily of wear life uses, and has the practical value on the industry.
Concrete structure of the present invention further specifies by following examples and accompanying drawing thereof:
Fig. 1: be manufacturing flow chart of the present invention
Fig. 2: be idiosome figure of the present invention
Fig. 3: be product cutaway view of the present invention
Referring to Fig. 1 is manufacturing flow chart of the present invention, a kind of activated ceramic container is formed and manufacture method is with medical stone, continent soil, Jinmen soil, clay pits such as half china clay are formed, it is characterized in that: in wheat rice-mouth 5%-80%, add 5% continent soil, half china clay of 5% Jinmen soil and 10-85% is formed, earlier will be according to the broken grind into fine powder of various raw materials of above-mentioned proper proportion, with moisture mix form slurry, after the mold filling, treat that it forms hard container idiosome again, take out the container idiosome, in the container idiosome, add the medical stone slurry again, after rotation is drawn embryo to make inner surface of container form a thin layer gradually, repaiied embryo, treat that it fully dries in the shade, coat the container that glaze is formed a powerful adsorption and ion exchange and is easy to regenerate with 1200 ℃ of sintering again.Wherein by medical stone, continent soil, Jinmen soil and half china clay clay pit are through the broken powder that is ground into about 100 sieve apertures, again with water through mixing machine mix form slurry, slip casting then---mold filling---is dried in the shade, wait it to do solid back taking-up container idiosome as shown in Figure 2, in holding idiosome, this adds medical stone mud again, draw embryo through rotation, make inner surface of container form the mud layer of the about 1-5mm of one deck gradually, this mud layer is mixed by 100% maifanite powder water mixing, (be to repair embryo → combination in the diagram of circuit, back → the coat glaze → again that fully dries in the shade is again formed as shown in Figure 3 the porosity that has with 1200 ℃ of sintering, and the container of permeability to air wherein represents the main component of medical stone as shown in the table: material silicon stone aluminium oxide red oxide ferrous oxide magnesium oxide calcium oxide albite chemistry formula Sio
2AL
2O
3Fe
2O
3FeO MgO CaO Na
2O percentum 69.56 14 1.1 1.3 3.4 2.00 3.06
Potassium lime titanium dioxide phosphoric acid manganese chloride is being paid water
K
2O????????TiO
2????P
2O
3???MmO?????H
2O
3.00????????0.30?????0.26??????0.02????2.00
By the table in as can be known: the medical stone composition by 100% the combination except silicon stone ore and bauxite mine, multiple oxide is still arranged, as basic oxide Na
2O, K
2O, FeO, MnO, MgO, CaO; Acid chloride: P
2O
3And neutral oxide Fe
2O
3, TiO
2Deng composition.The clay-type substance that this container is formed has plasticity and coking property, at high temperature can gradually change, and forms hard crystlline, other oxide such as Na
2O, K
2O contains alkali and divides many ores, can be used as flux to reduce the fusing point of silicon stone; Aluminium oxide (Al in addition
2O
3), titanium oxide (TiO
2) can improve the whiteness of clay mixture, thermal endurance and mechanical strength; Cao, mgo can make crystlline have refractoriness and antioxidation in high temperature erosion liquid, and wherein calcium oxide (cao) also has the effect of adhesives; The medical stone powder of above be combined into has very strong adsorption and ion exchange, and above-mentioned medical stone powder, continent soil, the container that Jinmen soil and half china clay are made according to part by weight has the resistance to acids of height, anti-alkali, high temperature resistant, fireproofness, fastness to water has powerful adsorption to the impurity in the liquid, and the inorganic matter that comprises in the leachable multiple stone matter, but balance is augmented the deficiency of solution mineral matter; Have good deodorization functions for the fermentation drinks, can remove fusel oil and bad smell in the alcohol; For soy sauce, fermented liquids such as vinegar more can change quality, and more sweet-smelling is delicious good to eat to make it; It for example is example with the fermented wine, 100CC wine is poured in this container, through about 10 minutes (changing) according to wine capacity number, because the medical stone composition in the sintering container is as catalyst, but the carrying out of acceleration response makes wine produce the acetify reaction, generates ester class thing and moisture content, cause the vinosity activate, make the wine fragrance that becomes rapidly pure and local flavor is excellent; And basic oxide in the container and the moisture in the wine produce oxidizing reaction, stripping ca in solution
++, mg
++, k
+, Na
+But Deng the potential of hydrogen in the mineral matter neutralization solution, promote the regeneration function of human body cell, help mineralizing of water, the ion-exchange capacity of while medical stone powder brute force, can be being dissolved in impurity absorption such as calcium salt in the water and magnesium salts and removing heavy metal in anhydrating, organic matter and bacterium etc. reach good ion exchange effect.
Activated ceramic container is a trial target with the fermented wine, before processing with handle after, the particular case of all kinds of component contents sees the following form in the wine:
Before the processing | After the processing | Remarks | |
Proportion | 1.0008-1.0013 | 1.0011-1.0013 | |
Alcohol | 15.36-15.55 degree | 15.16-15.26 degree | |
Purity | 30.1-30.8 degree | 29.6-30.6 degree | |
The calcium branch | 0.032-0.034% | 0.030-0.034% | |
Volatile acid | 0.0050-0.0061% | 0.0039-0.0056% | |
The wood volatile acid | 0.0917% | 0.0912% | |
Amino acid | 1.96-1.97% | 1.91-1.92% | |
Sugar | 3.27-3.29% | 3.27-3.29% | |
Alcohol oil | 0.012-0.017% | 0.008-0.011% | |
Glycerine | 0.200-0.232% | 0.204-0.216% | |
Phosphoric acid | 0.024-0.038% | 0.022-0.035% |
Above-mentioned experimental result is with medical stone and Jinmen soil, fine-powdered more than 100 sieve apertures mixes for the clay pit of main component is crushed to respectively for continent soil and half china clay etc., with this sintering, and holding inside face to form one be the thin layer of main component with the medical stone powder, fermented wine is poured in the container for 100 milliliters, experimental result after about 10 minutes, from observed data as can be known; Wherein wooden volatile acid and fusel oil all reduce, impurity in the wine, different hide absorbed fully by container and esterification arranged, make the solution activate, so the vinosity quality gentleness that can become at short notice, mellow, more reveal out the fragrance that one is old, glycerine after treatment has a small amount of increase, demonstrates the effect that medical stone slurry layer truly has catalyst, has quickened both reactions; Next is a heavy metal, and organic matter etc. are fully by no longer stripping of ion exchange, and mineral ion ca wherein
+2, mg
+2 have a small amount of stripping, Fe
+3 have minimizing, help the mediation of pH value and vinosity to mineralize.In addition, this container can be with the Impurity removal in the solution when producing ion exchange and adsorption, when long-time in-use performance became bad, available pickling made its repeated use of regenerating, as twisting lemon acid, sulfuric acid or salt acid elution, fully cleaning with former water is renewable use again.
The present invention has the practical value on the industry, can greatly improve the generation rate of wine brewing, produce up-to-standard, the wine that sweet-smelling is delicious.
Claims (4)
1, a kind of activated ceramic container is formed and manufacture method is with medical stone, continent soil, Jinmen soil, clay pits such as half china clay are formed, it is characterized in that: in wheat rice-mouth 5%-80%, add 5% continent soil, half china clay of 5% Jinmen soil and 10-85% is formed, earlier will be according to the broken grind into fine powder of various raw materials of above-mentioned proper proportion, again with moisture mix form slurry, after the mold filling, treat that it forms hard container idiosome, take out the container idiosome, in the container idiosome, add the medical stone slurry again, draw embryo to make inner surface of container form a thin layer gradually through rotation, after repairing embryo, treat that it fully dries in the shade, coat the container that glaze is formed a powerful adsorption and ion exchange and is easy to regenerate with 1200 ℃ of sintering again.
2, the composition of activated ceramic container according to claim 1 and manufacture method thereof, it is characterized in that: the formed thin layer of this inner surface of container is to be mixed by 100% maifanite powder water mixing to form slurry, through rotation draw embryo and gradually symbol show at inner surface of container.
3, the composition of activated ceramic container according to claim 1 and manufacture method thereof is characterized in that: the main component of 100% maifanite powder is: Sio
2-69.56%, Al
2o
3-14%, Fe
2o
3-1.1%, Feo-1.30%, Mgo-3.4%, Cao-2%, Na
2O-3.06%, k
2O-3%, Tio
2-0.3%, p
2o
3-0.26%, Mno-0.02%, H
2O-2% forms.
4, the composition of activated ceramic container according to claim 1 and manufacture method thereof, it is characterized in that: fermentation liquid comprises fermented wine, soy sauce, vinegar.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 94113896 CN1122764A (en) | 1994-11-11 | 1994-11-11 | Composition of activated ceramic container, and mfg. method thereof |
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---|---|---|---|
CN 94113896 CN1122764A (en) | 1994-11-11 | 1994-11-11 | Composition of activated ceramic container, and mfg. method thereof |
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Publication Number | Publication Date |
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CN1122764A true CN1122764A (en) | 1996-05-22 |
Family
ID=5036867
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---|---|---|---|
CN 94113896 Pending CN1122764A (en) | 1994-11-11 | 1994-11-11 | Composition of activated ceramic container, and mfg. method thereof |
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CN (1) | CN1122764A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103030368A (en) * | 2012-12-14 | 2013-04-10 | 潮州市嘉柏陶瓷有限公司 | Ceramic product for closestool, and preparation method thereof |
CN103044002A (en) * | 2012-12-14 | 2013-04-17 | 潮州市嘉柏陶瓷有限公司 | Ceramic product in toilet and bathroom and preparation method thereof |
CN103058629A (en) * | 2012-12-14 | 2013-04-24 | 潮州市嘉柏陶瓷有限公司 | Ceramic product for bathroom and preparation method for ceramic product |
CN109205014A (en) * | 2017-06-30 | 2019-01-15 | 黄期骏 | Method for manufacturing bottle body lines and structure thereof |
-
1994
- 1994-11-11 CN CN 94113896 patent/CN1122764A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103030368A (en) * | 2012-12-14 | 2013-04-10 | 潮州市嘉柏陶瓷有限公司 | Ceramic product for closestool, and preparation method thereof |
CN103044002A (en) * | 2012-12-14 | 2013-04-17 | 潮州市嘉柏陶瓷有限公司 | Ceramic product in toilet and bathroom and preparation method thereof |
CN103058629A (en) * | 2012-12-14 | 2013-04-24 | 潮州市嘉柏陶瓷有限公司 | Ceramic product for bathroom and preparation method for ceramic product |
CN109205014A (en) * | 2017-06-30 | 2019-01-15 | 黄期骏 | Method for manufacturing bottle body lines and structure thereof |
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