CN112266799B - Delayed coking method for realizing energy consumption reduction of absorption stabilization system - Google Patents

Delayed coking method for realizing energy consumption reduction of absorption stabilization system Download PDF

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CN112266799B
CN112266799B CN202011014432.XA CN202011014432A CN112266799B CN 112266799 B CN112266799 B CN 112266799B CN 202011014432 A CN202011014432 A CN 202011014432A CN 112266799 B CN112266799 B CN 112266799B
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tower
gasoline
gas
oil
diesel
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CN112266799A (en
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李国庆
黄文杰
盖朋波
卓楷升
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Guangdong Chuanxun Technology Co ltd
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South China University of Technology SCUT
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

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  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

本发明属于石油化工技术领域，公开了一种实现吸收稳定系统能耗降低的延迟焦化方法；将产品汽油送再吸收塔下部同产品柴油一起做再吸收塔的吸收剂，以降低上游吸收塔补充吸收剂的循环量，再吸收塔底富汽柴油经闪蒸后直接送下游汽柴油加氢精制装置，其闪蒸气送富气压缩机入口，并取消原贫柴油～富柴油换热器，其它管线流程不变。本发明工艺流程将产品汽油送再吸收塔下部及产品柴油送再吸收塔顶部做吸收剂，减少了补充吸收剂循环稳定汽油的流量，吸收稳定系统的循环加工量大幅降低，还不影响焦化装置的干气、液化气产品质量指标。

Figure 202011014432

The invention belongs to the technical field of petrochemical industry, and discloses a delayed coking method for realizing the reduction of energy consumption of an absorption stabilization system; the product gasoline is sent to the lower part of a reabsorption tower together with the product diesel oil as an absorbent of the reabsorption tower, so as to reduce the replenishment of the upstream absorption tower The circulating amount of the absorbent, the rich gasoline and diesel oil at the bottom of the reabsorption tower is flashed and sent directly to the downstream gasoline and diesel hydrotreating unit. The pipeline process remains unchanged. In the process flow of the invention, the product gasoline is sent to the lower part of the reabsorption tower and the product diesel oil is sent to the top of the reabsorption tower as the absorbent, which reduces the flow of the supplementary absorbent circulating and stabilized gasoline, greatly reduces the circulating processing volume of the absorption stabilization system, and does not affect the coking unit. The quality indicators of dry gas and liquefied gas products.

Figure 202011014432

Description

Delayed coking method for realizing energy consumption reduction of absorption stabilization system
Technical Field
The invention belongs to the technical field of petrochemical industry, and particularly relates to a delayed coking method for reducing energy consumption of an absorption stabilization system (reducing flow of a supplementary absorbent).
Background
Delayed coking is one of the main processes for secondary processing of petroleum, and is a process for producing dry gas, liquid hydrocarbon, gasoline, diesel oil, wax oil and coke by cracking and condensation reaction of heavy distillate oil (such as vacuum residue) at high temperature, and the process comprises raw coke, fractionation and absorption stabilization. Wherein the absorption stabilizing system comprises a condensing oil tank, an absorption tower, a reabsorption tower, a desorption tower and a stabilizing tower, the reabsorption tower aims to secondarily adsorb the lean gas from the top of the absorption tower by means of diesel oil so as to ensure that the dry gas product contains C or more3The content of the components is less than or equal to 3 mol percent, thereby obtaining liquid hydrocarbon (LPG) products to the maximum extent.
Gasoline and diesel oil are main products of coking, but cannot be directly delivered from factories due to high sulfur content, high olefin content and the like, and both need hydrofining. And because the sulfur content, the olefin content and the impurity content of the components are far higher than those of other gasoline and diesel oil fractions (such as catalytic gasoline, diesel oil, straight-run gasoline, diesel oil and the like) and the composition difference is large, the components are not mixed with other fractions for hydrogenation generally, but coked gasoline and diesel oil are mixed for hydrogenation firstly and then separated. Can the product gasoline be used as an absorbent for the reabsorber along with the product diesel? Firstly, the downstream flow of the coking gasoline and the diesel oil is not influenced, and the coking gasoline and the diesel oil are discharged from the bottom of a reabsorber and directly sent to hydrofining after flash evaporation; secondly, the function of the reabsorption tower is strengthened, the pressure of the upstream absorption tower is reduced, and the flow rate of the absorption tower for supplementing the absorbent, namely circulating stable gasoline, can be greatly reduced, so that the treatment capacity of the desorption tower is reduced, and the energy consumption is reduced. The present invention has been made in view of such a consideration.
Disclosure of Invention
The invention aims to solve the defects that the energy consumption of a desorber is high due to the fact that the flow of gasoline is circularly stabilized by supplementing an absorbent of an absorption stabilizing system of the existing delayed coking device is high, and the flow is complex and the processing amount of a main fractionating tower is large due to the fact that rich diesel oil returns to the main fractionating tower for recycling. The method directly flash-vaporizes the coking rich gasoline and diesel oil and then directly sends the coking rich gasoline and diesel oil to a downstream gasoline and diesel oil hydrofining device.
The invention is realized by the following technical scheme:
the delayed coking process with low power consumption for absorbing stable system includes the following steps: the original product gasoline is sent to a downstream gasoline and diesel oil hydrofining device, the product gasoline is changed into product gasoline which is sent to the lower part of a reabsorption tower 19, rich gasoline and diesel oil at the tower bottom of the reabsorption tower 19 are flashed by a rich gasoline and diesel oil flash evaporation tank 11 and then directly sent to the downstream gasoline and diesel oil hydrofining device, the flashed gas is sent to an inlet of a rich gas compressor, an original lean diesel oil-rich diesel oil heat exchanger 8 is cancelled, and the flow of other pipelines is unchanged.
A delayed coking method for realizing energy consumption reduction of an absorption stabilization system comprises the following steps:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in a de-superheating section of a main fractionating tower 1, the oil gas enters a rectifying section, the liquid phase enters a stripping section, is fed into a heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ below zero, which can cause coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to cause deep thermal cracking reaction and is converted into coke and oil gas; obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40-45 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas and flash gas of rich gasoline and diesel oil are compressed to 1.3MPag by a first rich gas compressor 4-1 and a second rich gas compressor 4-2 together and cooled to 40-45 ℃, then the non-condensable gas and the flash gas of the rich gasoline and diesel oil are mixed with tower top gas of a desorption tower 22 and tower bottom oil of an absorption tower 16 pumped by a bottom oil suction pump 18 and enter a condensed oil tank, a circulating water cooler 15 is cooled to 43-44 ℃, the circulating water cooler is mixed with the tank bottom oil of a gas-liquid separation tank 13 at the first-level outlet of the compressor and enters a condensed oil tank 17, and the condensed crude gasoline is pressurized by a crude gasoline pump 5 and then is sent to the top of an absorption and stabilization part of the absorption tower 16;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; the other strand is taken out by a diesel pump 6 after heat exchange as a product diesel, and is sent to the top of a reabsorption tower 19 as an absorbent through a lean diesel-rich diesel heat exchanger 7, a lean diesel-hot water heat exchanger 8, a lean absorption diesel air cooler 9 and a lean absorption diesel circulating water cooler 10 to 40-45 ℃;
the operating pressure of the absorption tower 16 is 1.1 MPag-1.23 MPag, the gas from the condensation oil tank 17 enters the lower part, the crude gasoline from the main fractionating tower and the circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and the intermediate circulating water cooler is used for realizing heat balance; the lean gas from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19 and is in countercurrent contact with the product gasoline and the product diesel oil from a main fractionating tower to absorb components which are carried by the lean gas and are not less than C3, the product dry gas is discharged from the top of the tower, and the gasoline-rich diesel oil at the bottom of the tower directly enters a raw material buffer tank of a downstream gasoline-diesel oil hydrofining device after passing through a flash tank 11;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then passes through the heat exchange 21 of the condensed oil and stable gasoline, the condensed oil and the stable gasoline exchange heat to 50-55 ℃, and enter the top of the desorption tower 22, a reboiler 23 at the bottom of the desorption tower exchanges heat with the diesel oil of a main fractionating tower through reflux heat supply, deethanized gasoline at the bottom of the desorption tower exchanges heat with the stable gasoline through a deethanized gasoline-stable gasoline heat exchanger 24 to 160-164.2 ℃ and enters a stabilizing tower 25, a reboiler 26 at the bottom of the stabilizing tower exchanges heat through reflux of the middle section of the main fractionating tower, LPG light components are distilled from the top of the tower, are condensed and cooled to 41-43.1 ℃ through an air cooler 31 at the top of the stabilizing tower and enter a gas-liquid separation tank 32 at the top of the stabilizing tower, one part of liquefied gas is pressurized through a reflux pump 33 at the top of the stabilizing tower to serve as cold reflux, and the other part of the liquefied gas is pressurized through a liquefied gas product pump 34 to serve as a product to be sent out of the device; the stable gasoline at the bottom of the tower sequentially passes through a de-ethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a deoxidized water-stable gasoline heat exchanger 27 and an air cooler 28, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product gasoline and sent to the lower part of the reabsorption tower.
Compared with the prior art, the invention has the following advantages and effects:
(1) the product gasoline is sent to the lower part of the reabsorption tower and the product diesel oil is sent to the top of the reabsorption tower to be used as absorbent, so that the flow rate of the gasoline which is circularly stabilized by the supplementary absorbent is reduced, the circular processing amount of an absorption stabilizing system is greatly reduced, and the quality indexes of dry gas and liquefied gas products of a coking device are not influenced.
(2) The process of recycling the delayed coking rich diesel is stopped, the rich diesel which is not subjected to the recycling treatment does not influence the material balance of a downstream hydrofining device even if the rich diesel contains a certain amount of gasoline and LPG components, and the rich diesel which is discharged from the bottom of the coking reabsorption tower is directly sent to the gasoline and diesel hydrofining device after being flashed, so that the process of coking rich diesel is omitted, the processing load of a main fractionating tower is reduced, the material balance of the downstream gasoline and diesel hydrofining device is basically not influenced, and the process has remarkable innovative significance.
(3) The process flow reduces the treatment capacity of the main fractionating tower of the delayed coking device, reduces the cooling load of the tower top gas, and absorbs the energy consumption of the desorption tower in the stabilizing system.
(4) The process flow of the invention increases the top cycle heat output of the main fractionating tower of the delayed coking device.
Drawings
FIG. 1 is a process flow diagram of a comparative example of the present invention (existing delayed coking main fractionator and absorption stabilization system).
FIG. 2 is a process flow diagram of an embodiment of the present invention.
The numbering in the figures is as follows: 1-main fractionation column; 2-a first circulating water cooler; 3-a gas-liquid separation tank; 4-1 a first rich gas compressor; 4-2 a second rich gas compressor; 5-crude gasoline pump; 6-a diesel pump; 7-lean diesel-rich diesel heat exchanger; 8-lean diesel-hot water heat exchanger; 9-lean absorption diesel air cooler; 10-lean absorption diesel oil circulating water cooler; 11-passing the gasoline-rich diesel through a flash tank; 12-a compressor first-stage outlet circulating water cooler; 13-a gas-liquid separation tank at the first-stage outlet of the compressor; 14-a compressor secondary outlet circulating water cooler; 15-circulating water cooler before condensing oil tank; 16-an absorption column; 17-a condensation oil tank; 18-a bottom oil suction pump; 19-a reabsorption column; 20-desorber feed pump; 21-condensed oil-stable gasoline heat exchanger; 22-a desorber; 23-a reboiler at the bottom of the desorber; 24-deethanized gasoline-stabilized gasoline heat exchanger; 25-a stabilizer column; 26-a stabilizer column bottom reboiler; 27-deoxidized water-stabilized gasoline heat exchanger; 28-an air cooler; 29-a second circulating water cooler; 30-a stable gasoline pump; 31-a stabilizer overhead air cooler; 32-a gas-liquid separation tank at the top of the stabilizing tower; 33-a stabilizer overhead reflux pump; 34-liquefied gas product pump.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Comparative example
The comparative example is the existing delayed coking main fractionating tower and absorption stabilizing system;
the process flow is shown in figure 1. The specific process is as follows:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in the de-superheating section of the main fractionating tower 1, the oil gas enters the rectifying section, the liquid phase enters the stripping section, is fed into the heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ which can generate coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to generate deep thermal cracking reaction and is converted into coke and oil gas. Obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas enters a first rich gas compressor 4-1 and a second rich gas compressor 4-2 and is compressed to 1.3MPag and is cooled to 40 ℃, the non-condensable gas and the condensed crude gasoline are mixed with the top gas of a desorption tower 22 and the bottom oil of an absorption tower 16 pumped by a bottom oil suction pump 18 and enter a circulating water cooler 15 to be cooled to 44 ℃, the condensed crude gasoline and the bottom oil of a gas-liquid separation tank 13 at the primary outlet of the compressor are mixed into a condensed oil tank 17, and the condensed crude gasoline at 40 ℃ is pressurized by a crude gasoline pump 5 and then is sent to the top of the absorption tower 16 of an absorption stabilizing part;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; another strand of diesel oil is pumped out by a diesel oil pump 6 after heat exchange and divided into two strands, and one strand of diesel oil serving as lean diesel oil is sent to the top of a reabsorption tower 19 as an absorbent through a lean diesel oil-rich diesel oil heat exchanger 7, a lean diesel oil-hot water heat exchanger 8, a lean absorption diesel oil air cooler 9 and a lean absorption diesel oil circulating water cooler 10 to 45 ℃; the other strand is taken as product diesel oil and is sent to a raw material buffer tank of a gasoline and diesel oil hydrofining device after heat exchange;
the operation pressure of the absorption tower 16 is 1.23MPag, gas from the condensation oil tank 17 enters the lower part, crude gasoline from the main fractionating tower and circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and an intermediate circulating water cooler helps to realize heat balance; the lean gas coming out from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19 and is in countercurrent contact with the lean diesel oil from the main fractionating tower to absorb the carried C and C3The components, the dry gas of the product is discharged from the top of the tower, and the rich diesel oil at the bottom of the tower returns to the main fractionating tower through a lean diesel oil-rich diesel oil heat exchanger 7;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then passes through a condensed oil-stable gasoline heat exchanger 21, exchanges heat with stable gasoline to 55 ℃, enters the top of a desorption tower 22, exchanges heat with the stable gasoline to 170 ℃ through a reboiler 23 at the bottom of the desorption tower, enters a stabilization tower 25 through a heat exchanger 24 for removing ethane gasoline-stable gasoline, exchanges heat with the stable gasoline to 170 ℃, and returns to the stabilization tower through the middle section of a main fractionating tower to supply heat through a reboiler 26 at the bottom of the stabilization tower, LPG light components are distilled from the top of the tower, are condensed and cooled to 40.1 ℃ through an air cooler 31, enter a gas-liquid separation tank 32 at the top of the stabilization tower, one part of liquefied gas is pressurized through a reflux pump 33 at the top of the stabilization tower to serve as cold reflux, and one part of liquefied gas is pressurized through a liquefied gas product pump 34 to serve as a product discharge device; the stable gasoline at the bottom of the tower sequentially passes through a deethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a hot water heat exchanger 27 and an air cooler 28, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product to be sent to a raw material buffer tank of a gasoline and diesel oil hydrofining device.
The embodiment of the invention comprises the following steps:
the original product gasoline is sent to a downstream gasoline and diesel oil hydrofining device, the product gasoline is changed into product gasoline which is sent to the lower part of a reabsorber, rich gasoline and diesel oil at the bottom of the reabsorber is directly sent to the downstream gasoline and diesel oil hydrofining device after being flashed, the flashed gas is sent to an inlet of a rich gas compressor, an original lean diesel oil-rich diesel oil heat exchanger is omitted, and the flow of other pipelines is unchanged.
The process flow diagram is shown in fig. 2, and the specific process flow is as follows:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in the de-superheating section of the main fractionating tower 1, the oil gas enters the rectifying section, the liquid phase enters the stripping section, is fed into the heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ which can generate coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to generate deep thermal cracking reaction and is converted into coke and oil gas. Obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas and flash gas of rich gasoline and diesel oil are fed into a first rich gas compressor 4-1 and a second rich gas compressor 4-2 together and compressed to 1.3MPag and cooled to 40 ℃, then the non-condensable gas and the flash gas of the rich gasoline and the oil at the bottom of an absorption tower 16 pumped by a bottom oil suction pump 18 are mixed with a circulating water cooler 15 and cooled to 44 ℃, the non-condensable gas and the oil at the bottom of a gas-liquid separation tank 13 at the primary outlet of the compressor are mixed into a condensed oil tank 17, and the condensed crude gasoline is pressurized by a crude gasoline pump 5 at 40 ℃ and then is fed to the top of an absorption tower 16 of an absorption stabilizing part;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; the other strand is taken out by a diesel pump 6 after being used as the product diesel oil for heat exchange, and is sent to the top of a reabsorption tower 19 to be used as an absorbent through a lean diesel oil-rich diesel oil heat exchanger 7, a lean diesel oil-hot water heat exchanger 8, a lean absorption diesel oil air cooler 9 and a lean absorption diesel oil circulating water cooler 10 to 45 ℃;
the operation pressure of the absorption tower 16 is 1.23MPag, gas from the condensation oil tank 17 enters the lower part, crude gasoline from the main fractionating tower and circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and an intermediate circulating water cooler helps to realize heat balance; the lean gas coming out from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19 and is in countercurrent contact with the product gasoline and the product diesel oil from a main fractionating tower to absorb the carried C and C3The components are that the dry gas of the product is discharged from the top of the tower, and the rich gasoline and diesel oil at the bottom of the tower directly enters a raw material buffer tank of a downstream gasoline and diesel oil hydrofining device after passing through a rich gasoline and diesel oil flash tank 11;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then passes through a condensed oil-stable gasoline heat exchanger 21, exchanges heat with stable gasoline to 55 ℃, enters the top of a desorption tower 22, exchanges heat with the stable gasoline to 164.2 ℃ through a heat exchanger 24 for removing the ethane-gasoline-stable gasoline, enters a stabilization tower 25, exchanges heat with the stable gasoline through the middle section of the main distillation tower for refluxing and supplying heat through a reboiler 23 at the bottom of the desorption tower, and condenses and cools to 43.1 ℃ through an air cooler 31, and then enters a gas-liquid separation tank 32 at the top of the stabilization tower, wherein one part of liquefied gas is pressurized as cold reflux through a reflux pump 33 at the top of the stabilization tower, and the other part of liquefied gas is pressurized as a product to be sent out of the device through a liquefied gas product pump 34; the stable gasoline at the bottom of the tower passes through a deethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a hot water heat exchanger 27 and an air cooler 28 in sequence, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product gasoline and sent to the lower part of the absorption tower.
The main operation of the comparative examples and examples will be described below by taking a 180 ten thousand ton/year delayed coking plant as an example.
Table 1 comparative and example main fractionator reflux heat removal
Figure GDA0003304969200000081
Table 2 comparative and example rich gas compressor operation
Figure GDA0003304969200000082
Based on isentropic compression efficiency 75%;
TABLE 3 comparative and example rich gas cooling duty
Figure GDA0003304969200000083
TABLE 4 intermediate cooling duty of absorption towers of comparative and example
Figure GDA0003304969200000084
Table 5 comparative and example make-up absorbent flow rates
Figure GDA0003304969200000085
Table 6 comparative and example stripper reboiler runs
Figure GDA0003304969200000091
Table 7 comparative and example stabilizer energy consumption behavior
Figure GDA0003304969200000092
As can be seen from tables 1 to 7, the invention:
1. the condensing load on the top of the main fractionating tower is reduced by 4 x 104kcal/h, amplitude reduction 0.4%;
2. the power consumption of the rich gas compressor is increased by 20kw by 1.1%, and the steam consumption of the driving turbine at 3.5MPa is reduced by 0.35 t/h;
3. main fractionating tower top circulation multi-heat extraction 265X 104kcal/h, which saves steam of 1.0MPa by 5.3 t/h;
4. the desorption tower reduces reboiling load 371X 104kcal/h (1.0 MPa steam 7.4t/h), reduced amplitude 42.8%;
5. increasing reboiling load of stabilizing tower by 7X 104kcal/h (equivalent 3.5MPa steam 0.14t/h), amplification 2.0%;
the steam is saved by 12.2t/h in the total embodiment, and the energy consumption cost is reduced by 1844.6 ten thousand yuan/year in the embodiment compared with the comparative embodiment based on the steam unit price of 180 yuan/t and the calculation of 8400 hours of annual operation of the device.
The process flow of the invention sends the product gasoline to the lower part of the reabsorption tower and the product diesel oil to the top of the reabsorption tower as the absorbent, thus reducing the flow rate of the gasoline which is circularly stabilized by the supplementary absorbent, greatly reducing the circular processing amount of the absorption stabilizing system, and not influencing the quality indexes of the dry gas and liquefied gas products of the coking device. The process of recycling the delayed coking rich diesel oil is stopped, the rich diesel oil which is not subjected to the recycling treatment does not influence the material balance of a downstream hydrofining device even if the rich diesel oil contains a certain amount of gasoline and LPG components, and the rich diesel oil which is discharged from the bottom of the coking reabsorption tower is directly sent to the gasoline and diesel oil hydrofining device after being flashed, so that the process of coking rich diesel oil is omitted, the processing load of a main fractionating tower is reduced, and the material balance of the downstream gasoline and diesel oil hydrofining device is basically not influenced.
As described above, the present invention can be preferably realized.
The embodiments of the present invention are not limited to the above-described embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and they are included in the scope of the present invention.

Claims (2)

1.一种实现吸收稳定系统能耗降低的延迟焦化方法，其特征在于包括如下步骤：1. a delayed coking method that realizes absorption stabilization system energy consumption reduction is characterized in that comprising the steps: 来自焦炭塔的高温油气与来自常减压装置经过换热后的减压渣油在主分馏塔（1）脱过热段充分接触后，油气进入精馏段，液相进入提馏段，经加热炉进料泵送加热炉，在炉管内被快速加热到能够在焦炭塔内发生焦化反应的温度~550℃进焦炭塔，焦化油流入焦炭塔发生深度热裂化反应转化为焦炭及油气；经分馏依次得到富气、粗汽油、柴油和蜡油，过剩热则由塔顶冷却系统、顶循回流、柴油回流、中段回流和蜡油回流取走；After the high-temperature oil and gas from the coke tower and the vacuum residue after heat exchange from the atmospheric and vacuum unit are fully contacted in the desuperheating section of the main fractionation tower (1), the oil and gas enter the rectifying section, and the liquid phase enters the stripping section. After heating The furnace feed is pumped to the heating furnace, and is rapidly heated in the furnace tube to a temperature of ~550 °C, which can cause coking reaction in the coke drum. The coke drum flows into the coke drum, and the coke oil flows into the coke drum and undergoes deep thermal cracking reaction and is converted into coke and oil and gas; after fractional distillation The rich gas, crude gasoline, diesel oil and wax oil are obtained in sequence, and the excess heat is taken away by the cooling system at the top of the tower, the top circulation reflux, the diesel reflux, the middle section reflux and the wax oil reflux; 主分馏塔（1）塔顶气体经第一循环水冷却器（2）冷至40℃～45℃进入气液分离罐（3），分出不凝气和凝结粗汽油，不凝气与富汽柴油闪蒸气一起进第一富气压缩机（4-1）和第二富气压缩机（4-2）压缩至1.3MPag冷却至40℃～45℃，再与解吸塔（22）塔顶气、经吸底油泵（18）泵入的吸收塔（16）塔底油混合进入凝缩油罐前循环水冷却器（15）冷却至43℃～44℃，与压缩机一级出口气液分离罐（13）罐底油混合进入凝缩油罐（17），凝结粗汽油40℃～45℃经粗汽油泵（5）加压后送往吸收稳定部分的吸收塔（16）顶部；The gas at the top of the main fractionation tower (1) is cooled to 40°C to 45°C by the first circulating water cooler (2) and enters the gas-liquid separation tank (3), where the non-condensable gas and the condensed crude gasoline are separated, and the non-condensable gas and the rich gas are separated. The flash gas of gasoline and diesel is fed into the first rich gas compressor (4-1) and the second rich gas compressor (4-2), compressed to 1.3MPag and cooled to 40°C to 45°C, and then combined with the top of the desorption tower (22). The gas and the bottom oil of the absorption tower (16) pumped by the suction bottom oil pump (18) are mixed with the circulating water cooler (15) before entering the condensing oil tank and cooled to 43°C to 44°C. The bottom oil of the separation tank (13) is mixed into the condensed oil tank (17), and the condensed crude gasoline at 40℃～45℃ is pressurized by the crude gasoline pump (5) and sent to the top of the absorption tower (16) which absorbs the stable part; 柴油从主分馏塔（1）第14层抽出经换热后分成两股：一股由作为热回流返回主分馏塔；另一股作为产品柴油换热后由柴油泵（6）抽出，经贫柴油~富柴油换热器（7）、贫柴油~热水换热器（8）、贫吸收柴油空冷器（9）、贫吸收柴油循环水冷却器（10）至40℃～45℃送到再吸收塔（19）顶部做吸收剂；Diesel is extracted from the 14th layer of the main fractionation tower (1) and divided into two shares after heat exchange: one is returned to the main fractionation tower as heat reflux; Diesel to rich diesel heat exchanger (7), lean diesel to hot water heat exchanger (8), lean absorption diesel air cooler (9), lean absorption diesel circulating water cooler (10) to 40 ℃ ~ 45 ℃ to send The top of the reabsorption tower (19) is used as an absorbent; 吸收塔（16）操作压力1.1MPag～1.23MPag，从凝缩油罐（17）来的气体进入下部，从主分馏塔来的粗汽油及来自稳定塔作为补充吸收剂的循环稳定汽油进入吸收塔顶部，它们逆流接触，完成传质和传热，中间循环水冷却器则作为实现热平衡；从吸收塔（16）塔顶出来的贫气送再吸收塔（19）底部，与产品汽油及来自主分馏塔的产品柴油逆流接触，以吸收其携带的≥C3组分，产品干气从塔顶排出，塔底富汽柴油经过闪蒸罐（11）后直接进下游汽柴油加氢精制装置原料缓冲罐。The operating pressure of the absorption tower (16) is 1.1MPag～1.23MPag, the gas from the condensing oil tank (17) enters the lower part, the crude gasoline from the main fractionation tower and the circulating stabilized gasoline from the stabilization tower as supplementary absorbent enter the absorption tower At the top, they are in countercurrent contact to complete mass transfer and heat transfer, and the intermediate circulating water cooler is used to achieve heat balance; the lean gas from the top of the absorption tower (16) is sent to the bottom of the reabsorption tower (19), where it is mixed with the product gasoline and main gas. The product diesel oil in the fractionation tower is contacted in countercurrent to absorb the ≥C3 components carried by it, the product dry gas is discharged from the top of the tower, and the rich gasoline and diesel oil at the bottom of the tower passes through the flash tank (11) and directly enters the downstream gasoline and diesel hydrotreating unit. Can. 2.根据权利要求1所述实现吸收稳定系统能耗降低的延迟焦化方法，其特征在于，所述延迟焦化方法还包括如下步骤：2. The delayed coking method for realizing the reduction of energy consumption of the absorption stabilization system according to claim 1, is characterized in that, the delayed coking method further comprises the steps: 凝缩油自凝缩油罐（17）出来经解吸塔进料泵（20）加压后，经过凝缩油~稳定汽油换热器（21），与稳定汽油换热到50℃～55℃进入解吸塔（22）顶部，解吸塔塔底重沸器（23）由主分馏塔的柴油回流供热，解吸塔塔底脱乙烷汽油则经脱乙烷汽油~稳定汽油换热器（24）与稳定汽油换热至160℃～164.2℃进入稳定塔（25），稳定塔塔底重沸器（26）由主分馏塔中段回流供热，LPG轻组分从塔顶馏出，经稳定塔顶空气冷却器（31）冷凝冷却到41℃～43.1℃进入稳定塔顶气液分液罐（32），液化气一部分经稳定塔顶回流泵（33）加压作为冷回流，一部分经液化气产品泵（34）加压作为产品送出装置；塔底稳定汽油则依次经脱乙烷汽油~稳定汽油换热器（24）、凝缩油~稳定汽油换热器（21）、除氧水~稳定汽油换热器（27）、空气冷却器（28），第二循环水冷却器（29）冷却至40℃，经稳定汽油泵（30）加压后分成两路，一路作为补充吸收剂送吸收塔顶部，另一路则是产品汽油送再吸收塔下部。After the condensed oil comes out of the condensed oil tank (17) and is pressurized by the feed pump (20) of the desorption tower, it passes through the condensed oil-stabilized gasoline heat exchanger (21), and exchanges heat with the stabilized gasoline to 50℃～55℃ Entering the top of the desorption tower (22), the reboiler (23) at the bottom of the desorption tower is heated by the diesel reflux of the main fractionation tower, and the deethaned gasoline at the bottom of the desorption tower is passed through the deethanized gasoline-stabilized gasoline heat exchanger (24). ) and stabilized gasoline to exchange heat to 160℃～164.2℃ and enter the stabilization tower (25), the reboiler (26) at the bottom of the stabilization tower is refluxed from the middle section of the main fractionation tower, and the LPG light components are distilled from the top of the tower and stabilized The tower top air cooler (31) is condensed and cooled to 41°C to 43.1°C and enters the stable tower top gas-liquid separation tank (32). A part of the liquefied gas is pressurized by the stable tower top reflux pump (33) as cold reflux, and a part is liquefied The gas product pump (34) is pressurized as a product sending device; the stabilized gasoline at the bottom of the tower is sequentially passed through the deethane gasoline-stabilized gasoline heat exchanger (24), the condensed oil-stabilized gasoline heat exchanger (21), and the deoxygenated water. ~Stable gasoline heat exchanger (27), air cooler (28), and second circulating water cooler (29) are cooled to 40°C, and are divided into two channels after being pressurized by the stabilized gasoline pump (30), and one channel is used as a supplementary absorbent It is sent to the top of the absorption tower, and the other way is to send the product gasoline to the lower part of the reabsorption tower.
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