CN112266799A - Delayed coking method for realizing energy consumption reduction of absorption stabilization system - Google Patents

Delayed coking method for realizing energy consumption reduction of absorption stabilization system Download PDF

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CN112266799A
CN112266799A CN202011014432.XA CN202011014432A CN112266799A CN 112266799 A CN112266799 A CN 112266799A CN 202011014432 A CN202011014432 A CN 202011014432A CN 112266799 A CN112266799 A CN 112266799A
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tower
gasoline
oil
gas
diesel oil
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CN112266799B (en
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李国庆
黄文杰
盖朋波
卓楷升
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Guangdong Chuanxun Technology Co ltd
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South China University of Technology SCUT
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Abstract

The invention belongs to the technical field of petrochemical industry, and discloses a delayed coking method for realizing energy consumption reduction of an absorption stabilization system; the product gasoline is sent to the lower part of the reabsorption tower and is used as an absorbent of the reabsorption tower together with the product diesel oil to reduce the circulation amount of the absorbent supplemented by the upstream absorption tower, the rich gasoline and diesel oil at the bottom of the reabsorption tower are directly sent to a downstream gasoline and diesel oil hydrofining device after being flashed, the flashed gas is sent to the inlet of a rich gas compressor, the original lean diesel oil-rich diesel oil heat exchanger is cancelled, and the flow of other pipelines is unchanged. The process flow of the invention sends the product gasoline to the lower part of the reabsorption tower and the product diesel oil to the top of the reabsorption tower as the absorbent, thus reducing the flow rate of the gasoline which is circularly stabilized by the supplementary absorbent, greatly reducing the circular processing amount of the absorption stabilizing system, and not influencing the quality indexes of the dry gas and liquefied gas products of the coking device.

Description

Delayed coking method for realizing energy consumption reduction of absorption stabilization system
Technical Field
The invention belongs to the technical field of petrochemical industry, and particularly relates to a delayed coking method for reducing energy consumption of an absorption stabilization system (reducing flow of a supplementary absorbent).
Background
Delayed coking is one of the main processes for petroleum secondary processing, and is characterized by that the heavy distillate oil (such as vacuum residuum) is undergone the processes of cracking and condensation reaction under the condition of high temp. to produce dry gas, liquid hydrocarbon, gasoline, diesel oil, wax oil and cokeThe process consists of three parts of coke formation, fractionation and stable absorption. Wherein the absorption stabilizing system comprises a condensing oil tank, an absorption tower, a reabsorption tower, a desorption tower and a stabilizing tower, the reabsorption tower aims to secondarily adsorb the lean gas from the top of the absorption tower by means of diesel oil so as to ensure that the dry gas product contains C or more3The content of the components is less than or equal to 3 mol percent, thereby obtaining liquid hydrocarbon (LPG) products to the maximum extent.
Gasoline and diesel oil are main products of coking, but cannot be directly delivered from factories due to high sulfur content, high olefin content and the like, and both need hydrofining. And because the sulfur content, the olefin content and the impurity content of the components are far higher than those of other gasoline and diesel oil fractions (such as catalytic gasoline, diesel oil, straight-run gasoline, diesel oil and the like) and the composition difference is large, the components are not mixed with other fractions for hydrogenation generally, but coked gasoline and diesel oil are mixed for hydrogenation firstly and then separated. Can the product gasoline be used as an absorbent for the reabsorber along with the product diesel? Firstly, the downstream flow of the coking gasoline and the diesel oil is not influenced, and the coking gasoline and the diesel oil are discharged from the bottom of a reabsorber and directly sent to hydrofining after flash evaporation; secondly, the function of the reabsorption tower is strengthened, the pressure of the upstream absorption tower is reduced, and the flow rate of the absorption tower for supplementing the absorbent, namely circulating stable gasoline, can be greatly reduced, so that the treatment capacity of the desorption tower is reduced, and the energy consumption is reduced. The present invention has been made in view of such a consideration.
Disclosure of Invention
The invention aims to solve the defects that the energy consumption of a desorber is high due to the fact that the flow of gasoline is circularly stabilized by supplementing an absorbent of an absorption stabilizing system of the existing delayed coking device is high, and the flow is complex and the processing amount of a main fractionating tower is large due to the fact that rich diesel oil returns to the main fractionating tower for recycling. The method directly flash-vaporizes the coking rich gasoline and diesel oil and then directly sends the coking rich gasoline and diesel oil to a downstream gasoline and diesel oil hydrofining device.
The invention is realized by the following technical scheme:
the delayed coking process with low power consumption for absorbing stable system includes the following steps: the original product gasoline is sent to a downstream gasoline and diesel oil hydrofining device, the product gasoline is changed into product gasoline which is sent to the lower part of a reabsorption tower 19, rich gasoline and diesel oil at the tower bottom of the reabsorption tower 19 are flashed by a rich gasoline and diesel oil flash evaporation tank 11 and then directly sent to the downstream gasoline and diesel oil hydrofining device, the flashed gas is sent to an inlet of a rich gas compressor, an original lean diesel oil-rich diesel oil heat exchanger 8 is cancelled, and the flow of other pipelines is unchanged.
A delayed coking method for realizing energy consumption reduction of an absorption stabilization system comprises the following steps:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in a de-superheating section of a main fractionating tower 1, the oil gas enters a rectifying section, the liquid phase enters a stripping section, is fed into a heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ below zero, which can cause coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to cause deep thermal cracking reaction and is converted into coke and oil gas; obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40-45 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas and flash gas of rich gasoline and diesel oil are compressed to 1.3MPag by a first rich gas compressor 4-1 and a second rich gas compressor 4-2 together and cooled to 40-45 ℃, then the non-condensable gas and the flash gas of the rich gasoline and diesel oil are mixed with tower top gas of a desorption tower 22 and tower bottom oil of an absorption tower 16 pumped by a bottom oil suction pump 18 and enter a condensed oil tank, a circulating water cooler 15 is cooled to 43-44 ℃, the circulating water cooler is mixed with the tank bottom oil of a gas-liquid separation tank 13 at the first-level outlet of the compressor and enters a condensed oil tank 17, and the condensed crude gasoline is pressurized;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; the other strand is taken out by a diesel pump 6 after heat exchange as a product diesel, and is sent to the top of a reabsorption tower 19 as an absorbent through a lean and rich absorption oil heat exchanger 7, a lean diesel-hot water heat exchanger 8, a lean absorption diesel air cooler 9 and a lean absorption diesel circulating water cooler 10 to 40-45 ℃;
the operating pressure of the absorption tower 16 is 1.1 MPag-1.23 MPag, the gas from the condensation oil tank 17 enters the lower part, the crude gasoline from the main fractionating tower and the circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and the intermediate circulating water cooler is used for realizing heat balance; the lean gas from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19 and is in countercurrent contact with the product gasoline and the product diesel oil from a main fractionating tower to absorb components which are more than or equal to C3 carried by the lean gas, the product dry gas is discharged from the top of the tower, and the gasoline-rich diesel oil at the bottom of the tower directly enters a raw material buffer tank of a downstream gasoline-diesel oil hydrofining device after passing through a flash tank 11;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then enters the top of a desorption tower 22 after exchanging heat with stable gasoline to 50-55 ℃ through a condensed oil-stable gasoline heat exchange 21, the tower bottom reboiler 23 of the desorption tower exchanges heat with the stable gasoline to 160-164.2 ℃ through a deethanized gasoline-stable gasoline heat exchanger 24, the deethanized gasoline enters a stabilization tower 25, the tower bottom reboiler 26 of the stabilization tower exchanges heat with the stable gasoline through the middle section of a main diversion tower in a backflow mode, LPG light components are distilled from the top of the tower, are condensed and cooled to 41-43.1 ℃ through an air cooler 31 of the stabilization tower top and enter a gas-liquid separation tank 32 of the stabilization tower top, part of liquefied gas is pressurized through a reflux pump 33 of the stabilization tower top to serve as cold reflux, and part of liquefied gas is pressurized through a liquefied gas product pump 34 to serve as a product to be sent; the stable gasoline at the bottom of the tower sequentially passes through a de-ethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a deoxidized water-stable gasoline heat exchanger 27 and an air cooler 28, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product gasoline and sent to the lower part of the reabsorption tower.
Compared with the prior art, the invention has the following advantages and effects:
(1) the product gasoline is sent to the lower part of the reabsorption tower and the product diesel oil is sent to the top of the reabsorption tower to be used as absorbent, so that the flow rate of the gasoline which is circularly stabilized by the supplementary absorbent is reduced, the circular processing amount of an absorption stabilizing system is greatly reduced, and the quality indexes of dry gas and liquefied gas products of a coking device are not influenced.
(2) The process of recycling the delayed coking rich diesel is stopped, the rich diesel which is not subjected to the recycling treatment does not influence the material balance of a downstream hydrofining device even if the rich diesel contains a certain amount of gasoline and LPG components, and the rich diesel which is discharged from the bottom of the coking reabsorption tower is directly sent to the gasoline and diesel hydrofining device after being flashed, so that the process of coking rich diesel is omitted, the processing load of a main fractionating tower is reduced, the material balance of the downstream gasoline and diesel hydrofining device is basically not influenced, and the process has remarkable innovative significance.
(3) The process flow reduces the treatment capacity of the main fractionating tower of the delayed coking device, reduces the cooling load of the tower top gas, and absorbs the energy consumption of the desorption tower in the stabilizing system.
(4) The process flow of the invention increases the top cycle heat output of the main fractionating tower of the delayed coking device.
Drawings
FIG. 1 is a process flow diagram of a comparative example of the present invention (existing delayed coking main fractionator and absorption stabilization system).
FIG. 2 is a process flow diagram of an embodiment of the present invention.
The numbering in the figures is as follows: 1-main fractionation column; 2-a first circulating water cooler; 3-a gas-liquid separation tank; 4-1 a first rich gas compressor; 4-2 a second rich gas compressor; 5-crude gasoline pump; 6-a diesel pump; 7-lean diesel-rich diesel heat exchanger; 8-lean diesel-hot water heat exchanger; 9-an air cooler; 10-lean absorption diesel oil circulating water cooler; 11-rich diesel flash tank; 12-a compressor first-stage outlet circulating water cooler; 13-a gas-liquid separation tank at the first-stage outlet of the compressor; 14-a compressor secondary outlet circulating water cooler; 15-circulating water cooler before condensing oil tank; 16-an absorption column; 17-a condensation oil tank; 18-a bottom oil suction pump; 19-a reabsorption column; 20-desorber feed pump; 21-condensed oil-stable gasoline heat exchanger; 22-a desorber; 23-a reboiler at the bottom of the desorber; 24-deethanized gasoline-stabilized gasoline heat exchanger; 25-a stabilizer column; 26-a stabilizer column bottom reboiler; 27-deoxidized water-stabilized gasoline heat exchanger; 28-an air cooler; 29-a second circulating water cooler; 30-a stable gasoline pump; 31-a stabilizer overhead air cooler; 32-a gas-liquid separation tank at the top of the stabilizing tower; 33-a stabilizer overhead reflux pump; 34-liquefied gas product pump.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Comparative example
The comparative example is the existing delayed coking main fractionating tower and absorption stabilizing system;
the process flow is shown in figure 1. The specific process is as follows:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in the de-superheating section of the main fractionating tower 1, the oil gas enters the rectifying section, the liquid phase enters the stripping section, is fed into the heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ which can generate coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to generate deep thermal cracking reaction and is converted into coke and oil gas. Obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas enters a first rich gas compressor 4-1 and a second rich gas compressor 4-2 and is compressed to 1.3MPag and is cooled to 40 ℃, the non-condensable gas and the condensed crude gasoline are mixed with the top gas of a desorption tower 22 and the bottom oil of an absorption tower 16 pumped by a bottom oil suction pump 18 and enter a circulating water cooler 15 to be cooled to 44 ℃, the condensed crude gasoline and the bottom oil of a gas-liquid separation tank 13 at the primary outlet of the compressor are mixed into a condensed oil tank 17, and the condensed crude gasoline at 40 ℃ is pressurized by a crude gasoline pump 5 and then is sent to the top of the;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; another strand of diesel oil is pumped out by a diesel oil pump 6 after heat exchange and divided into two strands, and one strand of diesel oil serving as lean diesel oil is sent to the top of a reabsorption tower 19 as an absorbent through a lean rich absorption oil heat exchanger 7, a lean diesel oil-hot water heat exchanger 8, a lean absorption diesel oil air cooler 9 and a lean absorption diesel oil circulating water cooler 10 to 45 ℃; the other strand is taken as product diesel oil and is sent to a raw material buffer tank of a gasoline and diesel oil hydrofining device after heat exchange;
the operation pressure of the absorption tower 16 is 1.23MPag, gas from the condensation oil tank 17 enters the lower part, crude gasoline from the main fractionating tower and circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and an intermediate circulating water cooler helps to realize heat balance; the lean gas coming out from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19 and is in countercurrent contact with the lean diesel oil from the main fractionating tower to absorb the carried C and C3The components, namely, the product dry gas is discharged from the top of the tower, and the rich diesel oil at the bottom of the tower returns to the main fractionating tower through a lean and rich absorption oil heat exchanger 7;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then exchanges heat with stable gasoline through a condensed oil-stable gasoline heat exchanger 21 to 55 ℃, enters the top of a desorption tower 22, a reboiler 23 at the bottom of the desorption tower is used for supplying heat through diesel oil reflux of a main fractionating tower, deethanized gasoline at the bottom of the desorption tower exchanges heat with stable gasoline through a deethanized gasoline-stable gasoline heat exchanger 24 to 170 ℃, enters a stabilization tower 25, a reboiler 26 at the bottom of the stabilization tower is used for supplying heat through reflux of the middle section of the main fractionating tower, LPG light components are distilled from the top of the tower, are condensed and cooled to 40.1 ℃ through an air cooler 31, enter a gas-liquid separation tank 32 at the top of the stabilization tower, one part of liquefied gas is pressurized through a reflux pump 33 at the top of the stabilization tower to be used as cold reflux, and the; the stable gasoline at the bottom of the tower sequentially passes through a deethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a hot water heat exchanger 27 and an air cooler 28, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product to be sent to a raw material buffer tank of a gasoline and diesel oil hydrofining device.
The embodiment of the invention comprises the following steps:
the original product gasoline is sent to a downstream gasoline and diesel oil hydrofining device, the product gasoline is changed into product gasoline which is sent to the lower part of a reabsorber, rich gasoline and diesel oil at the bottom of the reabsorber is directly sent to the downstream gasoline and diesel oil hydrofining device after being flashed, the flashed gas is sent to an inlet of a rich gas compressor, an original lean diesel oil-rich diesel oil heat exchanger is omitted, and the flow of other pipelines is unchanged.
The process flow diagram is shown in fig. 2, and the specific process flow is as follows:
after the high-temperature oil gas from the coke tower and the vacuum residue oil from the atmospheric and vacuum distillation device after heat exchange are fully contacted in the de-superheating section of the main fractionating tower 1, the oil gas enters the rectifying section, the liquid phase enters the stripping section, is fed into the heating furnace and pumped into the heating furnace, is rapidly heated in the furnace tube to the temperature of 550 ℃ which can generate coking reaction in the coke tower, and then enters the coke tower, and the coking oil flows into the coke tower to generate deep thermal cracking reaction and is converted into coke and oil gas. Obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower 1 is cooled to 40 ℃ by a first circulating water cooler 2 and enters a gas-liquid separation tank 3, non-condensable gas and condensed crude gasoline are separated, the non-condensable gas and flash gas of rich gasoline and diesel oil are fed into a first rich gas compressor 4-1 and a second rich gas compressor 4-2 together and compressed to 1.3MPag and cooled to 40 ℃, then the non-condensable gas and the flash gas of the rich gasoline and the oil at the bottom of an absorption tower 16 pumped by a bottom oil suction pump 18 are mixed with a circulating water cooler 15 and cooled to 44 ℃, the non-condensable gas and the oil at the bottom of a gas-liquid separation tank 13 at the primary outlet of the compressor are mixed into a condensed oil tank 17, and the condensed crude gasoline is pressurized by a crude gasoline pump 5 at 40 ℃ and then is fed to the top of;
diesel oil is extracted from the 14 th layer of the main fractionating tower 1 and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; the other strand is taken out by a diesel pump 6 after heat exchange as a product diesel, and is sent to the top of a reabsorption tower 19 as an absorbent through a lean rich absorption oil heat exchanger 7, a lean diesel-hot water heat exchanger 8, a lean absorption diesel air cooler 9 and a lean absorption diesel circulating water cooler 10 to 45 ℃;
the operation pressure of the absorption tower 16 is 1.23MPag, gas from the condensation oil tank 17 enters the lower part, crude gasoline from the main fractionating tower and circulating stable gasoline from the stabilizing tower as a supplementary absorbent enter the top part of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and an intermediate circulating water cooler helps to realize heat balance; the lean gas coming out from the top of the absorption tower 16 is sent to the bottom of a reabsorption tower 19, and is mixed with the product gasoline and comes from a main fractionating towerThe product diesel oil is in countercurrent contact to absorb the carried C or more3The components are that the dry gas of the product is discharged from the top of the tower, and the rich gasoline and diesel oil at the bottom of the tower directly enters a raw material buffer tank of a downstream gasoline and diesel oil hydrofining device after passing through a flash tank 11;
condensed oil is pressurized from a condensed oil tank 17 through a feeding pump 20 of a desorption tower, then exchanges heat with stable gasoline through a condensed oil-stable gasoline heat exchanger 21 to 55 ℃, enters the top of a desorption tower 22, a reboiler 23 at the bottom of the desorption tower is used for supplying heat through diesel oil reflux of a main fractionating tower, deethanized gasoline at the bottom of the desorption tower exchanges heat with stable gasoline through a deethanized gasoline-stable gasoline heat exchanger 24 to 164.2 ℃, enters a stabilization tower 25, a reboiler 26 at the bottom of the stabilization tower is used for supplying heat through reflux of the middle section of the main fractionating tower, LPG light components are distilled from the top of the tower, are condensed and cooled to 43.1 ℃ through an air cooler 31 and enter a gas-liquid separation tank 32 at the top of the stabilization tower, a part of liquefied gas is pressurized through a reflux pump 33 at the top of the stabilization tower to serve as cold reflux, and a part; the stable gasoline at the bottom of the tower passes through a deethanized gasoline-stable gasoline heat exchanger 24, a condensed oil-stable gasoline heat exchanger 21, a hot water heat exchanger 27 and an air cooler 28 in sequence, and a second circulating water cooler 29 is cooled to 40 ℃, and is pressurized by a stable gasoline pump 30 and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product gasoline and sent to the lower part of the absorption tower.
The main operation of the comparative examples and examples will be described below by taking a 180 ten thousand ton/year delayed coking plant as an example.
Table 1 comparative and example main fractionator reflux heat removal
Figure BDA0002698578150000081
Table 2 comparative and example rich gas compressor operation
Figure BDA0002698578150000082
Based on isentropic compression efficiency 75%;
TABLE 3 comparative and example rich gas cooling duty
Figure BDA0002698578150000083
TABLE 4 intermediate cooling duty of absorption towers of comparative and example
Figure BDA0002698578150000084
Table 5 comparative and example make-up absorbent flow rates
Figure BDA0002698578150000085
Table 6 comparative and example stripper reboiler runs
Figure BDA0002698578150000091
Table 7 comparative and example stabilizer energy consumption behavior
Figure BDA0002698578150000092
As can be seen from tables 1 to 7, the invention:
1. the condensing load on the top of the main fractionating tower is reduced by 4 x 104kcal/h, amplitude reduction 0.4%;
2. the power consumption of the rich gas compressor is increased by 20kw by 1.1%, and the steam consumption of the driving turbine at 3.5MPa is reduced by 0.35 t/h;
3. main fractionating tower top circulation multi-heat extraction 265X 104kcal/h, which saves steam of 1.0MPa by 5.3 t/h;
4. the desorption tower reduces reboiling load 371X 104kcal/h (1.0 MPa steam 7.4t/h), reduced amplitude 42.8%;
5. increasing reboiling load of stabilizing tower by 7X 104kcal/h (equivalent 3.5MPa steam)0.14t/h) and the amplification is 2.0 percent;
the steam is saved by 12.2t/h in the total embodiment, and the energy consumption cost is reduced by 1844.6 ten thousand yuan/year in the embodiment compared with the comparative embodiment based on the steam unit price of 180 yuan/t and the calculation of 8400 hours of annual operation of the device.
The process flow of the invention sends the product gasoline to the lower part of the reabsorption tower and the product diesel oil to the top of the reabsorption tower as the absorbent, thus reducing the flow rate of the gasoline which is circularly stabilized by the supplementary absorbent, greatly reducing the circular processing amount of the absorption stabilizing system, and not influencing the quality indexes of the dry gas and liquefied gas products of the coking device. The process of recycling the delayed coking rich diesel oil is stopped, the rich diesel oil which is not subjected to the recycling treatment does not influence the material balance of a downstream hydrofining device even if the rich diesel oil contains a certain amount of gasoline and LPG components, and the rich diesel oil which is discharged from the bottom of the coking reabsorption tower is directly sent to the gasoline and diesel oil hydrofining device after being flashed, so that the process of coking rich diesel oil is omitted, the processing load of a main fractionating tower is reduced, and the material balance of the downstream gasoline and diesel oil hydrofining device is basically not influenced.
As described above, the present invention can be preferably realized.
The embodiments of the present invention are not limited to the above-described embodiments, and any other changes, modifications, substitutions, combinations, and simplifications which do not depart from the spirit and principle of the present invention should be construed as equivalents thereof, and they are included in the scope of the present invention.

Claims (3)

1. A delayed coking method for realizing energy consumption reduction of an absorption stabilization system is characterized by comprising the following improvements: the original product gasoline is sent to a downstream gasoline and diesel oil hydrofining device, the product gasoline is changed into product gasoline which is sent to the lower part of a reabsorption tower (19), rich gasoline and diesel oil at the tower bottom of the reabsorption tower (19) are flashed by a rich gasoline and diesel oil flash evaporation tank (11) and then directly sent to the downstream gasoline and diesel oil hydrofining device, the flash evaporation gas is sent to the inlet of a rich gas compressor, a heat exchanger (8) for original poor diesel oil to rich diesel oil is eliminated, and the flow of other pipelines is unchanged.
2. A delayed coking method for realizing energy consumption reduction of an absorption stabilization system is characterized by comprising the following steps:
after high-temperature oil gas from a coke tower and vacuum residue oil from an atmospheric and vacuum device after heat exchange are fully contacted in a de-superheating section of a main fractionating tower (1), the oil gas enters a rectifying section, a liquid phase enters a stripping section, the oil gas is rapidly heated in a furnace tube to the temperature of 550 ℃ below zero which can generate coking reaction in the coke tower by a heating furnace feeding pump heating furnace, and the coking oil enters the coke tower to generate deep thermal cracking reaction and is converted into coke and oil gas; obtaining rich gas, crude gasoline, diesel oil and wax oil in sequence through fractionation, and taking away the excessive heat through a tower top cooling system, top circulation reflux, diesel oil reflux, middle section reflux and wax oil reflux;
the gas at the top of the main fractionating tower (1) is cooled to 40-45 ℃ by a first circulating water cooler (2) and enters a gas-liquid separation tank (3), non-condensable gas and condensed crude gasoline are separated, the non-condensable gas and flash gas of rich gasoline and diesel oil are fed into a first rich gas compressor (4-1) and a second rich gas compressor (4-2) together and compressed to 1.3MPag and cooled to 40-45 ℃, then the non-condensable gas and the flash gas of the rich gasoline and diesel oil are mixed with tower top gas of a desorption tower (22) and tower bottom oil of an absorption tower (16) pumped by a bottom oil pump (18) and enter a condensation oil tank, a circulating water cooler (15) is cooled to 43-44 ℃ before the mixed with the tower bottom oil of a gas-liquid separation tank (13) at the first-stage outlet of the compressor and then enters a condensation oil tank (17), and the condensed crude gasoline is pressurized by a crude oil;
diesel oil is extracted from the 14 th layer of the main fractionating tower (1) and is divided into two parts after heat exchange: one strand of the waste liquid is used as hot reflux to return to the main fractionating tower; the other strand of the diesel oil as a product is pumped out by a diesel oil pump (6) after heat exchange, and is sent to the top of a reabsorption tower (19) to be used as an absorbent through a lean and rich absorption oil heat exchanger (7), a lean diesel oil-hot water heat exchanger (8), a lean absorption diesel oil air cooler (9) and a lean absorption diesel oil circulating water cooler (10) at the temperature of 40-45 ℃;
the operating pressure of the absorption tower (16) is 1.1 MPag-1.23 MPag, gas from a condensation oil tank (17) enters the lower part, crude gasoline from a main fractionating tower and circulating stable gasoline from a stabilizing tower serving as a supplementary absorbent enter the top of the absorption tower, and the crude gasoline and the circulating stable gasoline are in countercurrent contact to finish mass transfer and heat transfer, and an intermediate circulating water cooler is used for realizing heat balance; the lean gas from the top of the absorption tower (16) is sent to the bottom of a reabsorption tower (19) and is in countercurrent contact with the product gasoline and the product diesel oil from a main fractionating tower to absorb components which are more than or equal to C3 carried by the lean gas, the product dry gas is discharged from the top of the tower, and the rich gasoline and diesel oil at the bottom of the tower directly enters a raw material buffer tank of a downstream gasoline and diesel oil hydrofining device after passing through a flash tank (11).
3. The delayed coking process for achieving a reduction in energy consumption of an absorption stabilization system according to claim 2, further comprising the steps of:
condensed oil is pressurized from a condensed oil tank (17) through a feeding pump (20) of a desorption tower, then enters the top of a desorption tower (22) after being subjected to heat exchange between the condensed oil and stable gasoline (21) and the stable gasoline to 50-55 ℃, a reboiler (23) at the bottom of the desorption tower is heated by diesel oil reflux of a main fractionating tower, deethanized gasoline at the bottom of the desorption tower is subjected to heat exchange between the deethanized gasoline and the stable gasoline through a deethanized gasoline-stable gasoline heat exchanger (24) and the stable gasoline to 160-164.2 ℃ and enters a stabilizing tower (25), a reboiler (26) at the bottom of the stabilizing tower is subjected to reflux heat supply from the middle section of the main fractionating tower, LPG light components are distilled from the top of the tower, are condensed and cooled to 41-43.1 ℃ through an air cooler (31) at the top of the stabilizing tower and enter a gas-liquid separating tank (32) at the top of the stabilizing tower, one part of the liquefied gas is pressurized; the stable gasoline at the bottom of the tower sequentially passes through a de-ethanized gasoline-stable gasoline heat exchanger (24), a condensed oil-stable gasoline heat exchanger (21), a deoxidized water-stable gasoline heat exchanger (27) and an air cooler (28), a second circulating water cooler (29) is cooled to 40 ℃, and the stable gasoline is pressurized by a stable gasoline pump (30) and then divided into two paths, wherein one path is used as a supplementary absorbent and sent to the top of the absorption tower, and the other path is used as a product gasoline and sent to the lower part of the reabsorption tower.
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CN113476878A (en) * 2021-07-09 2021-10-08 山东金诚重油化工技术研究院 Method for combined removal of trace nitrogen
CN114225652A (en) * 2021-12-08 2022-03-25 华南理工大学 Petroleum absorption stabilizing process without supplementary absorbent and petroleum refining equipment

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