Background
With the advent of the 5G era, the operating frequency of electronic chips (chips formed by placing a large number of integrated circuits formed by microelectronic components on a plastic substrate) has increased, and electronic devices have been gradually developed toward light weight and high integration, resulting in a great increase in the amount of heat generated by the electronic devices. The working state of electronic components can be greatly influenced if the redundant heat in the electronic equipment is not conducted out in time, and even the electronic chip can be out of work if the working state is serious, so that the service life is shortened. In order to solve the problem, thermal interface materials are produced, however, the traditional thermal interface materials have low thermal conductivity, which is mainly concentrated on 1-6W/(mK), and it is difficult to meet the high heat conduction requirement of electronic devices.
The heat-conducting interface material obtains a good heat-conducting effect by utilizing the anisotropic characteristic of the heat-conducting filler in the heat-conducting property; the heat-conducting filler with anisotropic property includes heat-conducting fiber, boron nitride, graphene, aluminum nitride, etc., and the heat-conducting fiber includes carbon fiber, glass fiber, etc. The heat conducting fibers have ultrahigh heat conductivity in the axial direction, which can reach 600-1300W/(mK), and after the heat conducting fibers are directionally sequenced in the colloid, the heat conductivity in the axial direction can be remarkably improved. At present, the heat conducting fibers are directionally sequenced in two modes, namely, the first mode is that the heat conducting fibers are sequenced by utilizing a strong magnetic field; the second sequencing is to use a common extrusion device, such as the related technology with the applicant's publication number of CN210792014U, which discloses a directional extrusion molding device for heat-conducting fibers, comprising an extrusion flow channel, an extrusion head located at the end of the extrusion flow channel, the end of the extrusion head being connected with a honeycomb extrusion nozzle, and a flow divider being arranged between the honeycomb extrusion nozzle and the extrusion head; the sequencing mode mainly utilizes the shearing force of the extrusion equipment to realize the oriented sequencing of the heat-conducting fibers.
With respect to the related art in the above, the inventors consider that there are the following drawbacks: the first sorting mode needs magnetic field intensity of more than 5T, expensive equipment needs to be purchased in the strong magnetic field, the production and maintenance cost is high, large-scale production cannot be realized, and adverse effects on the surrounding environment are also generated. The second ordering has a large requirement on the viscosity and hardness of the prepared material, and in addition, the prepared material containing the heat-conducting fibers is easy to have inconsistent relative flow speed in an extrusion flow channel due to various practical production reasons, so that the orientation of the heat-conducting fibers is not completely consistent, and the heat-conducting stability of the colloid product containing the heat-conducting fibers is poor.
Disclosure of Invention
In order to solve the problems of high production and maintenance cost and poor heat conduction stability of colloid containing heat-conducting fibers in the colloid production equipment, the first purpose of the application is to provide automatic oriented sequencing equipment for the heat-conducting fibers in the colloid, and the equipment has the advantages of low production and maintenance cost and good heat conduction stability of the colloid containing the heat-conducting fibers in the colloid production equipment containing the heat-conducting fibers.
The second objective of the present application is to provide a method for automatically orienting and sequencing heat conducting fibers in a colloid, which has the advantages of simple process and strong operability.
In order to achieve the first object, the present application provides an apparatus for automatically orienting and sequencing heat conducting fibers in a colloid, which adopts the following technical scheme:
an automatic directional sequencing device for heat conducting fibers in colloid comprises a fixed container, a conical extrusion flow channel for extruding the colloid containing the heat conducting fibers into the fixed container, an X-axis running module for driving the fixed container or the conical extrusion flow channel to relatively and linearly move in the X-axis direction, a Y-axis running module for driving the fixed container or the conical extrusion flow channel to relatively and linearly scan in the Y-axis direction, and a Z-axis running module for driving the fixed container or the conical extrusion flow channel to discharge the colloid to the required thickness in a layer-by-layer overlapping relative movement mode in the Z-axis direction.
By adopting the technical scheme, the colloid containing the heat conducting fibers forms flow velocity orientation in the tapered extrusion flow channel, so that the carbon fibers in the colloid preliminarily complete axial sequencing in the tapered extrusion flow channel, then the carbon fibers move linearly in the X-axis direction in the fixed container through the X-axis operation module, the Y-axis operation module scans and moves relatively line by line in the Y-axis direction to match the relative linear movement of the X-axis operation module, and the Z-axis operation module superposes and moves relatively layer by layer in the Z-axis direction to enable the colloid containing the heat conducting fibers to be paved to the required thickness in the fixed container, and finally the directional sequencing of the colloid containing the heat conducting fibers in the X-axis direction is completed. The problem of runner and X axle operation module, Y axle operation module, Z axle operation module are extruded through the toper and coordinate the cooperation each other and have improved the poor stability of the colloid heat conduction that contains the heat conduction fibre, and simultaneously, the heat conduction fibre automatic orientation sequencing equipment simple structure in the colloid of this application need not to use expensive equipment, has improved the high problem of production maintenance cost of the colloid production facility that contains the heat conduction fibre.
Preferably, the device comprises a pressure barrel for storing colloid containing the heat-conducting fibers, a colloid discharge port die, a colloid discharge valve for controlling the output capacity and speed of the colloid containing the heat-conducting fibers in the colloid discharge port die, a conveying pipe and a driving part; the conveying pipe is used for communicating the pressure barrel with the glue discharging valve, the driving part is used for conveying glue containing heat conducting fibers in the pressure barrel to the glue discharging valve through the conveying pipe, and the tapered extrusion flow channel is formed in the glue discharging port die.
Through adopting above-mentioned technical scheme, carry the binder removal bush through the colloid of drive division in with the pressure cylinder for the colloid forms the velocity of flow orientation in the runner is extruded to the toper, and the output speed of cooperation binder removal valve control colloid make and accomplish in the interior heat conduction fibre of the colloid after the velocity of flow orientation derives the fixed container in order, have improved the accuracy of heat conduction fibre in the axial row order.
Preferably, the glue discharging die comprises an accommodating part, a circulating part and a glue outlet part which are sequentially arranged from top to bottom, the accommodating part is in a circular truncated cone shape, the circulating part is in a conical shape, and the glue outlet part is in a cylindrical shape; the conical extrusion flow channel is formed by an accommodating part, a circulating part and a glue outlet part which are arranged in sequence from top to bottom.
Through adopting above-mentioned technical scheme, the runner is extruded to holding portion, circulation portion and play gluey portion convergence formula form the toper from the top down in proper order to make the colloid that contains the heat conduction fibre form stable even velocity of flow in the runner is extruded to the toper, do benefit to the colloid that contains the heat conduction fibre and obtain better orientation in the runner is extruded to the toper.
Preferably, the glue discharging die comprises a rack, wherein the rack comprises a base platform and a portal frame, the portal frame is arranged on the base platform, and the glue discharging die is arranged on the portal frame; the Y-axis operation module comprises a Y-axis moving plate and a Y-axis driving piece, the Y-axis moving plate is connected to the base platform in a sliding mode, the Y-axis driving piece is used for driving the Y-axis moving plate to reciprocate along the Y-axis direction, and the Y-axis moving plate is used for driving the fixed container or the glue discharging mouth mold to reciprocate along the Y-axis direction.
Through adopting above-mentioned technical scheme, install the binder removal bush in the portal frame and make the binder removal bush be located fixed container top so that go out glue in order, after starting Y axle driving piece, Y axle driving piece drive Y axle movable plate removes along Y axle direction, realizes containing the fibrous colloid of heat conduction and scans relative movement line by line along Y axle direction.
Preferably, the X-axis operation module includes an X-axis moving plate and an X-axis driving element for driving the X-axis moving plate to reciprocate along the X-axis direction, and the X-axis moving plate is slidably connected to the gantry or the Y-axis moving plate.
By adopting the technical scheme, after the X-axis driving piece is started, the X-axis driving piece drives the X-axis moving plate to move along the X-axis direction, and the colloid containing the heat-conducting fibers can move linearly along the X-axis direction relatively.
Preferably, the Z-axis operation module includes a Z-axis moving plate and a Z-axis driving member for driving the Z-axis moving plate to reciprocate along the Z-axis direction, the Z-axis moving plate is slidably connected to the X-axis moving plate or the Y-axis moving plate, and the fixed container is mounted on the Z-axis moving plate or the Y-axis moving plate.
By adopting the technical scheme, after the Z-axis driving piece is started, the Z-axis driving piece drives the Z-axis moving plate to move along the Z-axis direction, and the glue containing the heat conducting fibers is discharged to the required thickness in a layer-by-layer superposition relative movement mode along the Z-axis direction.
In order to achieve the second objective, the present application provides a method for automatically orienting and sequencing heat conducting fibers in a colloid, which is performed by using a carbon fiber colloid orienting and sequencing device, and adopts the following technical scheme:
a method for automatically orienting and sequencing heat-conducting fibers in a colloid comprises the following steps:
s1: putting the colloid containing the heat-conducting fibers into a pressure barrel, and setting the starting position and the ending position of the colloid discharge opening die relative to the fixed container;
s2: moving the glue discharging port die to a starting position along the X-axis direction, and vertically moving the glue discharging port die to a proper height along the Z-axis direction;
s3: the glue discharging valve controls the glue discharging pipe to output glue containing heat conducting fibers, and after the glue discharging pipe outputs the glue containing the heat conducting fibers, the X-axis operation module drives the glue discharging pipe or the fixed container to move linearly relatively in the X-axis direction; meanwhile, the Y-axis operation module moves in the direction far away from or close to the glue discharging port die along the Y-axis direction, so that the glue containing the heat-conducting fibers relatively moves in the Y-axis direction in a line-by-line scanning manner;
s4: after the step S3 is finished, a layer of colloid containing heat-conducting fibers is paved at the bottom of the fixed container, and the Z-axis operation module drives the glue discharging port die or the fixed container to pave glue in a layer-by-layer superposition relative movement mode in the Z-axis direction;
s5: repeating the steps S3 and S4 until the glue discharging die moves to the end position relative to the fixed container, so that the glue containing the heat-conducting fibers is discharged to the required thickness in a layer-by-layer overlapping relative movement mode;
s6: and solidifying the colloid containing the heat conducting fibers after the directional sequencing in the fixed container obtained in the step S5 to obtain the colloid after the directional sequencing of the heat conducting fibers.
Preferably, the top of the rubber outlet die is provided with a rubber inlet, the diameter of the rubber inlet is 20-45mm, and the diameter of the rubber outlet pipe is 1-5 mm; the glue dripping speed of the glue outlet pipe is 1-20cm/min, the moving speed of the Y-axis operation module is set to be 1-500mm/s, the moving speed of the X-axis operation module is set to be 1-500mm/s, and the moving speed of the Z-axis operation module is set to be 1-150 mm/s.
Preferably, the vertical distance of the rubber tube relative to the top of the fixed container is set to be 25-250 mm; the pressure of the driving part is set to be 0.05-25 MPa.
Preferably, the glue dripping speed of the glue dripping opening is 5-10cm/min, the pressure of the oil pump device is set to be 5-10Mpa, the moving speed of the X-axis running module is set to be 50-350mm/s, the moving speed of the Y-axis running module is set to be 50-350mm/s, and the moving speed of the Z-axis running module is set to be 80-120 mm/s.
Preferably, the colloid containing the heat conducting fibers after the orientation sorting obtained in the step S5 fixing container is cured at the temperature of 50-160 ℃ for 1-12 h.
In summary, the present application includes at least one of the following beneficial technical effects:
1. the method comprises the steps that a conical extrusion flow channel is arranged, so that irregular heat-conducting fibers in a colloid are oriented in the flow direction, and the colloid containing the heat-conducting fibers is directionally sequenced in a fixed container through the mutual coordination of an X-axis operation module, a Y-axis operation module and a Z-axis operation module, so that a thermal interface material with the heat-conducting fibers oriented in the X-axis direction is obtained, and the problems of high production and maintenance cost of colloid production equipment containing the heat-conducting fibers and poor heat-conducting stability of the colloid containing the heat-conducting fibers are solved;
2. the equipment and the method for automatically orienting and sequencing the colloid containing the heat conducting fibers in the colloid accurately control the orienting and sequencing of the heat conducting fibers in the axial direction, and have simple process and strong operability.
Detailed Description
The present application is described in further detail below with reference to figures 1-7.
Example 1
The embodiment of the application discloses automatic directional sequencing equipment for heat-conducting fibers in colloid. Referring to fig. 1, the automatic directional ordering device for the heat conducting fibers in the colloid comprises a machine base 1, a fixed container 2, a glue discharging module 4 for extruding the colloid containing the heat conducting fibers into the fixed container 2, an X-axis running module 5 for driving the glue discharging module 4 to relatively linearly move along the X-axis direction, a Y-axis running module 3 for driving the fixed container 2 to relatively linearly move along the Y-axis direction, a Z-axis running module 6 for driving the fixed container 2 to discharge the glue to a required thickness along the Z-axis direction in a layer-by-layer overlapping relative movement mode, and a control module; the control module is a computer control system 7, and the computer control system 7 is used for controlling the operation tracks of the Y-axis operation module 3, the X-axis operation module 5, the Z-axis operation module 6 and the glue discharging module 4 to be automatically carried out.
Referring to fig. 1 and 2, the glue discharging module 4 includes a pressure barrel 41 for storing glue containing heat conducting fibers, a glue discharging valve 42 for controlling the output capacity and speed of the glue containing heat conducting fibers, a glue discharging die 43 communicated with the glue discharging valve 42, a conveying pipe 44 and a driving part; the pressure barrel 41 and the glue discharging valve 42 are communicated through a conveying pipe 44, the driving part is used for conveying glue containing heat conducting fibers in the pressure barrel 41 to the glue discharging valve 42 through the conveying pipe 44, and the glue discharging valve 42 is electrically connected with the computer control system 7, so that the computer control system 7 controls the glue discharging valve 42 to be opened and closed through electric signals. The glue discharging valve 42 is installed at a glue inlet of the glue discharging port 43, and the glue discharging port 43 is installed at the Z-axis operation module 6. The driving part is electrically connected with the computer control system 7, so that the computer control system 7 provides an electric signal to control the opening and closing of the driving part. In the present embodiment, the driving unit is exemplified as the oil pump device 45, and the driving source of the driving unit is not limited.
The frame comprises a base platform 11 and a portal frame 12, wherein the portal frame 12 is vertical and is arranged on the base platform 11. The gantry 12 includes a top beam 121 and two supporting columns 122, one ends of the two supporting columns 122 in the length direction are perpendicular and are installed on the top beam 121, and one ends of the two supporting columns 122 far away from the top beam 121 are respectively installed on two opposite sides of the base platform 11. The X-axis operation module 5 and the Z-axis operation module 6 are both arranged on a portal frame 12, and the Y-axis operation module 3 is arranged on a base platform 11.
The Y-axis operation module 3 includes a Y-axis moving plate 32 slidably connected to the base platform 11, and a Y-axis driving member for driving the Y-axis moving plate 32 to reciprocate along the Y-axis direction, and the Y-axis moving plate 32 is used for placing the fixed container 2 so that the Y-axis driving member drives the fixed container 2 to reciprocate along the Y-axis direction. The Y-axis driving member is electrically connected to the computer control system 7, so that the computer control system 7 provides electrical signals to control the opening and closing of the Y-axis driving member. In the present embodiment, the Y-axis driver is taken as an example of the servo motor, and the driving source of the Y-axis driver is not limited. The base platform 11 is provided with a Y-axis linear sliding table 31, and the Y-axis moving plate 32 is installed on a slider of the Y-axis linear sliding table 31 to realize reciprocating movement along the Y-axis direction of the Y-axis linear sliding table 31.
The X-axis operation module 5 includes an X-axis moving plate 52 slidably connected to the top beam 121, and an X-axis driving member for driving the X-axis moving plate 52 to reciprocate along the X-axis direction, and the nozzle 43 is mounted on the X-axis moving plate 52. The X-axis driving member is electrically connected with the computer control system 7, so that the computer control system 7 provides electric signals to control the opening and closing of the X-axis driving member. In the present embodiment, the X-axis driver is taken as an example of the servo motor, and the drive source of the X-axis driver is not limited. The top beam 121 is provided with a slide rail 51, and the X-axis moving plate 52 is in sliding fit with the slide rail 51 to realize the reciprocating movement of the X-axis moving plate 52 along the X-axis direction.
The Z-axis operation module 6 comprises a Z-axis moving plate 61 connected to the X-axis moving plate 52 in a sliding manner and a Z-axis driving piece for driving the Z-axis moving plate 61 to move in a reciprocating manner along the Z-axis direction; the Z-axis driving member is electrically connected with the computer control system 7, so that the computer control system 7 provides an electric signal to control the opening and closing of the Z-axis driving member. In the present embodiment, the Z-axis driver is exemplified as the servo motor, and the driving source of the Z-axis driver is not limited. First sliding grooves 62 are formed in two sides of the X-axis moving plate 52 in the Z-axis direction, and two sides of the Z-axis moving plate 61 in the Z-axis direction are in sliding fit with the two first sliding grooves 62 respectively to achieve reciprocating movement of the Z-axis moving plate 61 in the X-axis direction.
The trajectories of the fixed container 2 and the dispensing die 43 are programmed and input to the computer control system 7, placing the fixed container 2 on the Y-axis moving plate 32. Adjusting the Y-axis operation module 3, the Z-axis operation module 6, and the X-axis operation module 5 to position the glue-discharging die 43 at a suitable position above the fixed container 2, then starting the oil pump device 45, conveying the glue containing the heat-conducting fibers in the pressure barrel 41 to the glue-discharging die 43 through the conveying pipe 44, and controlling the glue discharge amount of the glue-discharging valve 42 through the computer control system 7, wherein the glue containing the heat-conducting fibers is extruded from the glue-discharging pipe to the fixed container 2 under the control of the computer control system 7, and the glue containing the heat-conducting fibers forms flow velocity orientation in the tapered extrusion flow channel, so that the glue containing the heat-conducting fibers is directionally sequenced in the fixed container 2, as shown in fig. 3.
Two side walls of the fixed container 2 perpendicular to the X-axis direction are named as a first side wall 21 and a second side wall 22 respectively, two side walls of the fixed container 2 perpendicular to the Y-axis direction are named as a third side wall 23 and a fourth side wall 24 respectively, and the junction of the first side wall 21 and the third side wall 23 is used as the starting position of glue dripping of the glue discharging pipe. In the present embodiment, the heat conductive fibers are exemplified as carbon fibers, and the kind of the heat conductive fibers is not limited.
The direction indicated by the arrow in fig. 3 is the moving direction of the X-axis operation module 5, that is, the X-axis operation module 5 drives the glue discharging port 43 to move from the first side wall 21 to the second side wall 22 along the X-axis direction, and the glue discharging port 43 stops glue discharging after reaching the second side wall 22; then the Y-axis operation module 3 drives the fixed container 2 to move in the direction close to the glue discharging port mould 43 along the Y-axis direction (the Y-axis operation module 3 drives the fixed container 2 to move in the direction close to or far from the glue discharging port mould 43 along the Y-axis direction, that is, the fixed container 22 moves linearly along the Y-axis direction relatively), at this time, the glue discharging port mould 43 recovers glue, then the X-axis operation module 5 drives the glue discharging port mould 43 to move from the second side wall 22 to the first side wall 21 along the X-axis direction (the X-axis operation module 5 drives the glue discharging port mould 43 to move from the first side wall 21 to the second side wall 22 along the X-axis direction, or the X-axis operation module 5 drives the glue discharging port mould 43 to move linearly along the X-axis direction from the second side wall 22 to the first side wall 21, that is, such circulation is performed until a layer of glue containing carbon fiber is laid in the fixed container 2, and finally the Z-axis operation module 6 drives the glue discharging port mould 43 to move, until the colloid containing the carbon fiber is laid to the required thickness along the Z-axis direction (the colloid discharging die 43 moves the fixed container 22 along the Z-axis direction to the direction far away from the fixed container 2 to discharge the colloid to the required thickness in a layer-by-layer superposition relative movement mode along the Z-axis direction, namely the colloid is discharged to the required thickness by the fixed container 22 in a layer-by-layer superposition relative movement mode along the Z-axis direction).
As shown in fig. 4, the direction indicated by the arrow is another moving manner of the moving direction of the X-axis moving module 5; namely, the X-axis operation module 5 drives the glue discharging die 43 to move from the first side wall 21 to the second side wall 22 along the X-axis direction; the glue discharging port mould 43 stops glue discharging after reaching the second side wall 22, then the Y-axis operation module 3 drives the fixed container 2 to move towards the direction close to the glue discharging port mould 43 along the Y-axis direction, then the X-axis operation module 5 drives the glue discharging port mould 43 to return to the first side wall 21, the glue discharging port mould 43 returns to the first side wall 21, glue discharging is recovered from the glue discharging port mould 43, the X-axis operation module 5 drives the glue discharging port mould 43 to move towards the second side wall 22 from the first side wall 21 along the X-axis direction, the operation is repeated until a layer of glue containing carbon fiber is paved in the fixed container 2, and finally the Z-axis operation module 6 drives the glue discharging port mould 43 to move towards the direction far away from the fixed container 2 along the Z-axis direction until the glue containing carbon fiber is paved to the required thickness along the.
As shown in fig. 5, the direction indicated by the arrow is another moving manner of the moving direction of the X-axis moving module 5; that is, the X-axis operation module 5 drives the glue discharging port mold 43 to move from the first side wall 21 to the second side wall 22 along the X-axis direction, then the Y-axis operation module 3 drives the fixed container 2 to move along the Y-axis direction towards the direction close to the glue discharging port mold 43, the glue discharging port mold 43 continuously discharges glue, and the X-axis operation module 5 drives the glue discharging port mold 43 to move from the second side wall 22 to the first side wall 21 along the X-axis direction, the above process is circulated until a layer of colloid containing carbon fiber is laid in the fixed container 2, and finally the Z-axis operation module 6 drives the glue discharging port mold 43 to move along the Z-axis direction towards the direction far away from the fixed container 2 until the colloid containing carbon fiber is laid to the required thickness along the Z-. For the colloid shown in fig. 5, which is obtained by directionally sequencing the carbon fibers in the moving direction of the X-axis operation module 5, the carbon fibers in the colloid at the end close to the first side wall 21 and the colloid at the end close to the second side wall 22 of the colloid are difficult to directionally sequence in the fiber direction, and the colloid is cut off at a later stage.
Referring to fig. 2 and 6, the nozzle 43 includes an accommodating portion 431, a flow portion 432, and a glue discharging portion 433, the accommodating portion 431, the flow portion 432, and the glue discharging portion 433 are sequentially provided from top to bottom, the accommodating portion 431, the flow portion 432, and the glue discharging portion 433 are integrally provided, and the central axes of the accommodating portion 431, the flow portion 432, and the glue discharging portion 433 overlap. The accommodating part 431 is in a round table shape, the circulating part 432 is in a cone shape, and the glue outlet part 433 is in a cylinder shape; the length of the containing part 431 on the central axis is greater than that of the circulating part 432 on the central axis, the length of the circulating part 432 on the central axis is greater than that of the glue outlet part 433 on the central axis, the glue outlet die 43 is wide at the top and narrow at the bottom to form a tapered extrusion flow channel for extruding the glue containing the heat-conducting fibers to the fixed container 2, and the glue outlet pipe is used for directionally sequencing the glue containing the heat-conducting fibers to the fixed container 2.
The implementation principle of the equipment for directionally sequencing the heat-conducting fibers in the colloid in the embodiment of the application is as follows: the trajectories of the fixed container 2 and the dispensing die 43 are programmed and input to the computer control system 7, placing the fixed container 2 on the Y-axis moving plate 32. Adjusting the Y-axis operation module 3, the Z-axis operation module 6 and the X-axis operation module 5 to enable the glue discharging port mold 43 to be located at a proper position above the fixed container 2, starting the oil pump device 45 at the moment, conveying the glue containing the heat-conducting fibers in the pressure barrel 41 to the glue discharging port mold 43 through the conveying pipe 44 to provide power for the flow velocity orientation of the glue containing the heat-conducting fibers in the tapered extrusion flow channel, controlling the glue discharging amount of the glue discharging valve 42 through the computer control system 7, and extruding the glue containing the heat-conducting fibers from the glue discharging pipe at the tail end of the glue discharging port mold 43 under the control of the computer control system 7, so that the glue containing the heat-conducting fibers is directionally sequenced in the fixed container 2.
Example 2
Referring to fig. 1 and 7, embodiment 2 is different from embodiment 1 in that the Y-axis moving module 3 has a different structure and installation manner, and the Y-axis moving module 3 is used to drive the glue discharging module 4 to move linearly in the Y-axis direction. The Y-axis operation module 3 comprises a Y-axis moving plate 32 and a Y-axis driving piece for driving the Y-axis moving plate 32 to reciprocate along the Y-axis direction; the Y-axis moving plate 32 is two supporting columns 122, two sliding grooves 13 are respectively formed in two sides of the base in the Y-axis direction, the two supporting columns 122 are respectively in sliding fit with the two sliding grooves 13, and the Y-axis driving piece drives the gantry 12 to reciprocate along the length direction of the sliding grooves 13 so as to realize the relative linear movement of the glue discharging module 4 along the Y-axis direction. The fixed container 2 is placed on the base platform 11 so that the Y-axis driving piece drives the portal frame 12 to reciprocate along the Y-axis direction to discharge glue.
Example 3
Referring to fig. 1 and 8, the difference between embodiment 3 and embodiment 1 is that an X-axis operation module 5 is used for driving the fixed container 2 to move linearly along the X-axis direction, a Y-axis operation module 3 is used for driving the fixed container 2 to move linearly along the Y-axis direction, a Z-axis operation module 6 is used for driving the fixed container 2 to move linearly along the Z-axis direction in a layer-by-layer overlapping manner, and is matched with the glue discharging module 4 to discharge glue to a required thickness, and a glue discharging die 43 is mounted on the top beam 121.
The X-axis moving plate 52 is slidably connected to the upper end surface of the Y-axis moving plate 32, and the Y-axis moving plate 32 is provided with a second sliding groove 14 slidably engaged with the X-axis moving plate 52 to realize the relative linear movement of the X-axis moving plate 52 along the X-axis direction. The fixed container 2 is installed at one end, far away from the base platform 11, of the Z-axis moving plate 61, and the fixed container 2 is matched with the glue discharging module 4 to discharge glue to the required thickness in a layer-by-layer superposition relative movement mode in the Z-axis direction through the reciprocating movement of the Z-axis moving plate 61 along the Z-axis direction of the X-axis moving plate 52.
Example 4
Referring to fig. 1 and 9, embodiment 4 is different from embodiment 1 in that the structure and installation manner of the Z-axis moving module 6 are different, and the glue discharging die 43 is installed on the X-axis moving plate 52; the Z axis includes a Z axis moving plate 61 and a Z axis driving member that drives the Z axis moving plate 61 to reciprocate in the Z axis direction. The Z-axis moving plate 61 is the top beam 121, the two opposite sides of the two support columns 122 are respectively provided with a third sliding groove 15, the third sliding grooves 15 are arranged along the length direction of the support columns 122, and the Z-axis driving member drives the top beam 121 to reciprocate along the length direction of the support columns 122, so that the glue outlet die 43 reciprocates along the Z-axis direction to superpose layer by layer and relatively move glue to a required thickness.
Examples 1, 2, 3 and 4 only exemplify some embodiments of the relative movement of the glue discharging die 43 and the fixed container 2, and there are various embodiments of the relative movement of the glue discharging die 43 and the fixed container 2, for example, the glue discharging die 43 reciprocates in the X-axis direction, and the fixed container 2 reciprocates in the Y-axis direction and the Z-axis direction with respect to the glue discharging die 43; the glue discharging die 43 may be taken as a relative stationary direction in any one direction, any two directions or three directions of the X-axis direction, the Y-axis direction or the Z-axis direction, and the fixed container 2 may be adapted to move relatively in the X-axis direction, the Y-axis direction or the Z-axis direction, which is not described herein again.
Example 5
The embodiment of the application discloses a method for directionally sequencing heat-conducting fibers in a colloid. Taking the automatic directional ordering device of the heat-conducting fibers in the colloid as an example for explanation, the method for directional ordering of the heat-conducting fibers in the colloid comprises the following steps:
s1: putting the colloid containing the heat-conducting fibers into the pressure barrel 41 and the fixed container 2 on the Y-axis moving plate 32, and setting the starting position and the ending position of the colloid discharge die 43 on the fixed container 2;
s2: the computer control system 7 gives an electric signal for starting operation to the Z-axis operation module 6 and the X-axis operation module 5, moves the glue discharging port die 43 to the starting position along the X-axis direction, and enables the glue discharging port die 43 to vertically move to a proper height along the Z-axis direction;
s3: the computer control system 7 gives an electric signal for starting the operation of the oil pump device 45 and the glue discharging valve 42, and the glue discharging port die 43 outputs glue containing heat conducting fibers;
s4: after the glue discharging port die 43 outputs the glue containing the heat conducting fibers, the computer control system 7 gives an electric signal for the X-axis operation module 5 to start to operate, and the X-axis operation module 5 drives the glue discharging port die 43 to relatively linearly move in the X-axis direction; meanwhile, the computer control system 7 gives the Y-axis operation module 3 to move in the direction far away from or close to the glue discharging port mould 43 along the Y-axis direction, so that the glue containing the heat conducting fibers relatively moves in the Y-axis direction in a line-by-line scanning manner;
s5: after the step S4 is completed, a layer of colloid containing heat conducting fibers is laid on the bottom of the fixed container 2, and the Z-axis operation module 6 drives the glue discharging port die 43 to lay glue in a layer-by-layer overlapping relative movement mode in the Z-axis direction;
s6: repeating the steps S4 and S5 until the glue discharging die 43 moves to the end position, so that the glue containing the heat-conducting fibers is discharged to the required thickness in a layer-by-layer superposition relative movement mode;
s7: and (3) curing the colloid containing the heat-conducting fibers after the directional sequencing obtained in the step (S6) fixed container 2 at the temperature of 60 ℃ for 4h to obtain the colloid after the directional sequencing of the heat-conducting fibers, wherein as shown in FIG. 10, the carbon fibers 8 in the colloid are all directionally sequenced in the X-axis direction.
Wherein the diameter of a glue inlet of the glue discharging port mould 43 is 30mm, and the diameter of a glue outlet pipe of the glue discharging port mould 43 is 3 mm;
the glue dripping speed of the glue outlet pipe is 5 cm/min;
setting the vertical distance d of the side of the rubber outlet pipe away from the accommodating part 431 relative to the top of the fixed container 2 to be 150 mm;
setting the pressure of the oil pump device 45 to be 5 Mpa;
an included angle R is formed between the central axis of the glue discharging port mould 43 and the moving direction of the fixed container 2 in the Y-axis direction, and the included angle R is an acute angle of 90 degrees;
setting the moving speed V1 of the Y-axis operation module 3 to be 150 mm/s;
setting the moving speed V2 of the X-axis operation module 5 to be 200 mm/s;
the moving speed V3 of the Z-axis moving module 6 was set to 100 mm/s.
In this embodiment, the boundary between the first sidewall 21 and the third sidewall 23 is set as the starting position of the glue dripping start of the glue discharging tube, and the height of the fixing container corresponding to the required thickness of the glue containing the heat conducting fibers is set as the ending position of the glue dripping end of the glue discharging tube.
Examples 6 to 23
Examples 6 to 23 differ from example 5 in the relevant parameters of steps S1 to S6, see in particular Table 1.
Comparative examples 1 to 9
Comparative examples 1 to 15 differ from example 5 in the relevant parameters of the individual steps from S1 to S6, see in particular tables 2 and 3.
Example 24
The embodiment of the application discloses a colloid containing heat-conducting fibers.
The colloid containing the heat-conducting fibers comprises the following raw materials in parts by weight: 90-110 parts of vinyl silicone oil, 2-4 parts of hydrogen-containing silicone oil, 50-1500 parts of heat-conducting filler, 0.1-3 parts of inhibitor, 0.5-4 parts of platinum catalyst and 0.1-3 parts of coupling agent.
Wherein, the viscosity of the vinyl silicone oil is 50-30000 mPas, and the hydrogen content of the hydrogen-containing silicone oil is 0.25%.
The heat-conducting filler comprises one or a mixture of two or more of carbon fiber, boron nitride, graphene, graphite flakes, magnesium oxide, aluminum nitride, zinc oxide, aluminum powder, copper powder, silver-coated aluminum powder and the like. Wherein the diameter of the carbon fiber is 10-25 μm, the length is 200-500 μm, and the particle size range of the alumina is 1-15 μm.
The inhibitor is at least one of ethynyl cyclohexanol, dimethyl hexynol and dimethyl sulfoxide.
The concentration of the platinum catalyst is 1000-3500 ppm.
The coupling agent is at least one of octadecyl triethoxy siloxane, hexadecyl trimethoxy silane, hexadecyl triethoxy silane, hexadecyl trimethyl silane, gamma-aminopropyl triethoxy silane, gamma-methacryloxypropyl trimethoxy silane, amino silane, methacryloxy silane, vinyl tri-tert-butyl peroxy silane and butadienyl triethoxy silane.
Adding vinyl silicone oil, hydrogen-containing silicone oil, a coupling agent, an inhibitor and a heat-conducting filler into a homogenizer for preliminary stirring and mixing, wherein the rotation speed of the homogenizer is 2500rpm, and the stirring time is 10 min; then adding platinum catalyst, stirring for 5min to obtain the colloid containing the heat-conducting fiber with the viscosity of 500-3000mPa & s. The present application is only illustrated by the colloid containing the thermally conductive fibers of the embodiment, and the specific composition of the colloid containing the thermally conductive fibers is not limited.
TABLE 1 relevant parameters for steps S1-S6 of examples 5-10.
TABLE 2 relevant parameters for comparative examples 1-8, Steps S1-S6.
TABLE 3 relevant parameters for comparative examples 9-14, Steps S1-S6.
The thermally conductive fiber oriented gel obtained in step S6 of examples 5 to 10 and comparative examples 1 to 14 was tested for thermal conductivity and dielectric constant, the criterion for thermal conductivity was astm d5470, the criterion for dielectric constant was ASTD150, the criterion for temperature resistance range was EN344, the criterion for hardness was ASTD2240, the criterion for tensile strength was ASTD412, the criterion for volume resistance was ASTD257, and the criterion for flame retardancy was UL-94, and the test results were shown in table 4.
Table 4 performance testing of the thermally conductive fiber oriented gel obtained in examples 5-10 and comparative examples 1-14.
As can be seen from tables 1-4, the glue obtained by the automatic orienting and sequencing equipment and method for the heat-conducting fibers in the glue in the examples 5-8 has better performance in all aspects and better heat-conducting stability than the glue obtained by the automatic orienting and sequencing equipment and method for the heat-conducting fibers in the glue in the examples 9-23, namely the pressure of an oil pump device is preferably 5-10MPa, the moving speed V1 of a Y-axis running module is preferably 50-350mm/s, the moving speed V2 of an X-axis running module is preferably 50-350mm/s, and the moving speed V3 of a Z-axis running module is preferably 80-120 mm/s.
This is because the drive division pressure increase can lead to the volume of gluing of binder removal bush to be bigger than normal, though increased out gluey efficiency, the volume of gluing increases and means that the play glue pipe goes out the glue and takes place a small amount of deformations after the fixed container easily for the carbon fiber takes place weak skew in the sequencing of axial (being fibre direction), thereby reduces some heat conduction stability, and the less volume of gluing of drive division pressure can reduce, influences the orientation of carbon fiber in the flow direction, influences the sequencing of carbon fiber in the axial equally. The smaller the moving speed of the X-axis operation module, the Y-axis operation module and the Z-axis operation module is, the larger the glue output is, and the glue body is easy to deform slightly after the glue output from the obtained rubber tube is arranged in a fixed container; the larger the moving speed of the X-axis operation module, the Y-axis operation module and the Z-axis operation module is, the smaller the glue output amount is, although the glue output from the glue output pipe to the fixed container is not easy to deform, the orientation of the carbon fiber in the flow direction is also influenced.
The diameters of the glue inlet and the glue outlet of the comparative examples 1 to 4 are larger than those of the examples 5 to 23, and the comparative examples 1 to 4 compare the diameters of the glue inlet and the glue outlet by increasing the diameters of the glue inlet and the glue outlet, so that the heat conductivity and the dielectric constant of the glue inlet and the glue outlet with increased diameters are poor, because the tapered extrusion flow channel is increased by the glue inlet and the glue outlet with increased diameters, the orientation of carbon fibers in the flow velocity direction is poor, the ordering of the carbon fibers close to the central part of the tapered extrusion flow channel is disordered, and the heat conductivity stability of the obtained colloid product containing the heat-conducting fibers is poor.
The glue dripping speed of the comparative examples 5 to 6 is higher than that of the examples 5 to 10, and although the production efficiency can be improved by increasing the glue dripping speed, the orientation of the carbon fibers in the flow velocity direction is deteriorated due to the excessively high glue dripping speed, the performance of the finally obtained glue containing the heat-conducting fibers in the aspects of heat conductivity and dielectric constant is poor, the performances of other dimensions are not ideal, and the heat-conducting stability of the obtained glue product containing the heat-conducting fibers is poor.
The vertical distances d of comparative examples 7 to 8 are all larger than those of examples 5 to 23, and although the orientation of the carbon fibers in the flow direction becomes good, the colloid is easily deformed after the colloid containing the heat-conducting fibers is discharged to the fixed container through the glue dripping pipe due to the high vertical distance, the influence of self gravity and the inertia influence of the flow rate of the tapered extrusion flow channel, so that the oriented ordering of the heat-conducting fibers in the fiber direction is still maintained after the glue is discharged to the fixed container, and the performances of the obtained colloid containing the heat-conducting fibers are not ideal in all aspects.
The pressure of the driving part of the comparative example 9 is higher than that of the driving parts of the examples 5 to 23, the orientation of the carbon fibers in the flow velocity direction can be faster due to the increase of the pressure, but the problem of too large glue output is also solved, and the glue is easy to deform after the glue is output from the glue output pipe to the fixed container, so that the heat-conducting fibers are difficult to ensure to be still kept in the orientation sequencing in the fiber direction after being output from the glue output pipe to the fixed container, and the performances of the obtained glue containing the heat-conducting fibers are not ideal in all aspects.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.