CN112226132A - Preparation method of matte water-based wood paint - Google Patents

Preparation method of matte water-based wood paint Download PDF

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Publication number
CN112226132A
CN112226132A CN202011292310.7A CN202011292310A CN112226132A CN 112226132 A CN112226132 A CN 112226132A CN 202011292310 A CN202011292310 A CN 202011292310A CN 112226132 A CN112226132 A CN 112226132A
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parts
agent
preparation
matte
wood paint
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CN202011292310.7A
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Chinese (zh)
Inventor
季维
白琴
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Tianjin Meilianda Technology Co ltd
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Tianjin Meilianda Technology Co ltd
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Priority to CN202011292310.7A priority Critical patent/CN112226132A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention provides a preparation method of matte waterborne wood paint, and relates to the technical field of matte waterborne wood paint. The preparation method of the matte waterborne wood paint comprises the following raw materials in parts by weight: 35-60 parts of modified acrylic resin emulsion, 5-15 parts of silicone-acrylic emulsion, 1-2 parts of dispersing agent, 3-6 parts of flatting agent, 4-8 parts of thickening agent, 0.5-2 parts of cerate, 1-3 parts of defoaming agent, 10-30 parts of pigment, 10-20 parts of flatting agent and 30-50 parts of deionized water; the preparation method comprises the following preparation processes: step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly; and 2, adding the pigment into the reaction tank, and fully stirring. By selecting reasonable formula proportion and preparation process, the prepared matte water-based wood paint product is a low-viscosity paint, is convenient to coat, can meet construction requirements, and has the characteristics of good fullness, permeability, dullness and smoothness of a coating film.

Description

Preparation method of matte water-based wood paint
Technical Field
The invention relates to the technical field of matte waterborne wood paint, in particular to a preparation method of the matte waterborne wood paint.
Background
The development and production of water paint have been in the history of more than 20 years in China, a lot of experience is accumulated in the period, the coating industry is gradually turning to environment-friendly and resource-saving products such as water paint, radiation curing paint, powder paint and high-solid paint from traditional varieties which are high in pollution and energy consumption and extremely depend on products in the petroleum industry, the material is usually protected by a matt or flat coating in the field of wood products due to the using purpose and the environmental requirement, particularly, furniture and home furnishings adopt the matt or flat coating, so that the aesthetic appearance of modern people is met, the visual fatigue is not easy to cause, and the wood products are very popular with modern people.
The water-based matte paint is prepared by adding a matting material SiO2 and wax slurry on the basis of varnish to cause surface roughness, form light diffuse reflection and generate a matte effect, wherein the matte paint can be prepared according to the addition amount of the matte powder: full matte (no light), 7 parts of matte (30 percent of gloss), semi-matte (50 percent of gloss), 3 parts of matte (70 percent of gloss), the type of the matte, the compatibility of the matte with resin, the particle size distribution of the matte, the arrangement state of the matte in paint, the relationship between the particle size of the matte and the thickness of the paint film, the relationship between the drying speed of the paint film and the extinction and the like directly influence the extinction effect.
The traditional water-based matte wood lacquer has the following problems: bad permeability, whitening and bluing phenomena, extinction and blooming and other defects; the main existence in the aspect of the performance of the matt wood lacquer is as follows: permeability, extinction, smoothness, fullness, hand feeling, water resistance and scratch resistance are poor; the solid content is one of the marks of the quality level of the paint, the high-solid-content film-forming material has high content, usually, the resin film-forming material is high, the paint with the high film-forming material is generally high, the quality is superior to the paint with the low solid content, the cost of the paint mainly comprises resin and pigment, and therefore, the selling price of the paint with the high solid content is higher than that of the paint with the low solid content.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation method of a matte water-based wood paint, which solves the problems of poor fullness, permeability, dulling property and smoothness of the traditional water-based matte wood paint and higher cost price.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the preparation method of the matte waterborne wood paint comprises the following raw materials in parts by weight: 35-60 parts of modified acrylic resin emulsion, 5-15 parts of silicone-acrylic emulsion, 1-2 parts of dispersing agent, 3-6 parts of flatting agent, 4-8 parts of thickening agent, 0.5-2 parts of cerate, 1-3 parts of defoaming agent, 10-30 parts of pigment, 10-20 parts of flatting agent and 30-50 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly;
step 2, adding the pigment into the reaction tank, and fully stirring;
step 3, adding a dispersing agent, a flatting agent, a defoaming agent, cerate and a thickening agent, and fully stirring;
step 4, adding the flatting agent in equal amount for multiple times, and fully stirring to completely disperse the flatting agent in the slurry;
and 5, finally adding deionized water, dispersing for 60 minutes at a high speed, and detecting the viscosity.
Preferably, the step 1 is performed by low-speed stirring for 20 minutes, the step 2 is performed by low-speed stirring for 30 minutes, the step 3 is performed by medium-speed stirring for 20 minutes, and the step 4 is performed by medium-speed stirring for 20 minutes.
Preferably, the flatting agent is added in 5-7 times in equal amount in the step 4.
Preferably, the viscosity detected in step 5 is 30 ± 1 second (coating 4# cup).
Preferably, the thickener is one or more of polyacrylamide thickener, KSE 881G.
Preferably, the wax ointment is one or more of polyethylene wax, palm wax and paraffin wax.
Preferably, the flatting agent is one or more of gel process flatting powder AZ-200, AZ-400, AD-2000 and AD-4004.
Preferably, the antifoaming agent is momentve coatosil 1211.
Preferably, the dispersant is one or more of an anionic dispersant, (WP-4040, WP-4050) cationic dispersant (LH-80docx) nonionic dispersant and a macromolecular dispersant (Winsperse4080A, 4190).
Preferably, the leveling agent is one or more of a modified polysiloxane type leveling agent, a long-chain resin type leveling agent, special modified polyether silicone oil, DISPERBYK-110, DISPERBYK-111 and EVONIK SURFYNOL 4.
(III) advantageous effects
The invention provides a method for producing a composite material. The method has the following beneficial effects:
1. according to the invention, by selecting a reasonable formula proportion and a preparation process, the prepared matte water-based wood paint product is a low-viscosity paint, is convenient to coat, can meet construction requirements, has the characteristics of good fullness, permeability and dulling property of a coating film and good smoothness, has low solid content, and overcomes the defects of poor fullness and low quality of the coating film caused by adding water in the traditional matte water-based wood paint, increase of paint yield and expansion of coating area.
2. The invention reduces the cost and increases the benefit by reducing the resin content of the matte waterborne wood paint.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides a preparation method of matte waterborne wood paint, which comprises the following raw materials in parts by weight: 45 parts of modified acrylic resin emulsion, 5 parts of silicone-acrylic emulsion, 2 parts of dispersing agent, 4 parts of flatting agent, 6 parts of thickening agent, 1 part of cerate, 2 parts of defoaming agent, 15 parts of pigment, 15 parts of matting powder and 50 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly;
step 2, adding the pigment into the reaction tank, and fully stirring;
step 3, adding a dispersing agent, a flatting agent, a defoaming agent, cerate and a thickening agent, and fully stirring;
step 4, adding the flatting agent in equal amount for multiple times, and fully stirring to completely disperse the flatting agent in the slurry;
and 5, finally adding deionized water, dispersing for 60 minutes at a high speed, and detecting the viscosity.
Stirring at a low speed for 20 minutes in the step 1, stirring at a low speed for 30 minutes in the step 2, stirring at a medium speed for 20 minutes in the step 3, and stirring at a medium speed for 20 minutes in the step 4;
adding the flatting agent into the mixture in 6 times in an equal amount in the step 4;
the viscosity is detected to be 30 +/-1 seconds in the step 5 (coating 4# cup);
the thickener is a polyacrylamide thickener;
the cerate is polyethylene wax;
the flatting agent is gel-process flatting powder AD-4004;
the antifoaming agent is MOMENTIVE Coatosil 1211;
the dispersant is an anionic dispersant;
the leveling agent is a long-chain resin type leveling agent.
Example two:
the embodiment of the invention provides a preparation method of matte waterborne wood paint, which comprises the following raw materials in parts by weight: 80 parts of modified acrylic resin emulsion, 15 parts of silicone-acrylic emulsion, 3 parts of dispersing agent, 3 parts of flatting agent, 9 parts of thickening agent, 2 parts of cerate, 4 parts of defoaming agent, 25 parts of pigment, 30 parts of matting powder and 30 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly;
step 2, adding the pigment into the reaction tank, and fully stirring;
step 3, adding a dispersing agent, a flatting agent, a defoaming agent, cerate and a thickening agent, and fully stirring;
step 4, adding the flatting agent in equal amount for multiple times, and fully stirring to completely disperse the flatting agent in the slurry;
and 5, finally adding deionized water, dispersing for 60 minutes at a high speed, and detecting the viscosity.
Stirring at a low speed for 20 minutes in the step 1, stirring at a low speed for 30 minutes in the step 2, stirring at a medium speed for 20 minutes in the step 3, and stirring at a medium speed for 20 minutes in the step 4;
adding the flatting agent into the mixture in 6 times in an equal amount in the step 4;
the viscosity is detected to be 30 +/-1 seconds in the step 5 (coating 4# cup);
the thickener is a polyacrylamide thickener;
the cerate is polyethylene wax;
the flatting agent is gel-process flatting powder AD-4004;
the antifoaming agent is MOMENTIVE Coatosil 1211;
the dispersant is an anionic dispersant;
the leveling agent is a long-chain resin type leveling agent.
Example three:
the embodiment of the invention provides a preparation method of matte waterborne wood paint, which comprises the following raw materials in parts by weight: 80 parts of modified acrylic resin emulsion, 15 parts of silicone-acrylic emulsion, 3 parts of dispersing agent, 6 parts of flatting agent, 9 parts of thickening agent, 2 parts of cerate, 4 parts of defoaming agent, 25 parts of pigment, 30 parts of matting powder and 30 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly;
step 2, adding the pigment into the reaction tank, and fully stirring;
step 3, adding a dispersing agent, a flatting agent, a defoaming agent, cerate and a thickening agent, and fully stirring;
step 4, adding the flatting agent in equal amount for multiple times, and fully stirring to completely disperse the flatting agent in the slurry;
and 5, finally adding deionized water, dispersing for 60 minutes at a high speed, and detecting the viscosity.
Stirring at a low speed for 20 minutes in the step 1, stirring at a low speed for 30 minutes in the step 2, stirring at a medium speed for 20 minutes in the step 3, and stirring at a medium speed for 20 minutes in the step 4;
adding the flatting agent into the mixture in 6 times in an equal amount in the step 4;
the viscosity is detected to be 30 +/-1 seconds in the step 5 (coating 4# cup);
the thickener is a polyacrylamide thickener;
the cerate is polyethylene wax;
the flatting agent is gel-process flatting powder AD-4004;
the antifoaming agent is MOMENTIVE Coatosil 1211;
the dispersant is an anionic dispersant;
the leveling agent is a long-chain resin type leveling agent.
Example four:
the embodiment of the invention provides a preparation method of matte waterborne wood paint, which comprises the following raw materials in parts by weight: 45 parts of modified acrylic resin emulsion, 5 parts of silicone-acrylic emulsion, 2 parts of dispersing agent, 4 parts of flatting agent, 6 parts of thickening agent, 1 part of cerate, 2 parts of defoaming agent, 15 parts of pigment, 15 parts of matting powder and 50 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, starting a reaction tank to stir, and respectively adding 50% parts of acrylic resin emulsion, silicone-acrylic emulsion, modified polysiloxane emulsion and deionized water into the reaction tank, and stirring the mixture at a low speed for 20 minutes;
step 2, adding 50% of deionized water into another reaction tank, slowly adding the pigment and the anionic dispersing agent, stirring for 30 minutes, adding the long-chain resin leveling agent, the MOMENTIVE COATOSIL 1211 antifoaming agent and the polyethylene wax paste, adjusting to the medium speed, stirring for 20 minutes, and uniformly mixing;
and 3, slowly adding the step 2 into the step 1, stirring for 30 minutes, uniformly mixing, adding the gel method AD-4004 matting powder for 5-7 times, stirring at medium speed for 20 minutes (the matting powder is completely dispersed in the slurry), and dispersing at medium speed for 60 minutes. Obtaining the water-based matte wood lacquer.
Comparative example: is common water-based wood lacquer on the market.
Experimental example the aqueous matte wood paints of examples 1-4 and comparative example were sprayed on the surface of oak board respectively four times (thickness about 40 μm) under the same conditions, and after the paint films were completely dried, the performance was tested
Figure BDA0002784278610000071
The water-based matte wood lacquer provided by the invention has the advantages that the film forming temperature is low, the hardness of a lacquer film is high, the resistance is good, the effect is good, the results of the above table show that the water-based matte wood lacquer obtained by the method can reach the matte lacquer standard below 25, the impact resistance, the wear resistance and the solvent resistance reach the qualified standard, the materials adopted by the invention are all green and environment-friendly, no organic solvent is adopted, no toxic or harmful gas is released, the VOC content is far lower than that of the lacquer, and no harm is caused to the environment and human body.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (10)

1. The preparation method of the matte waterborne wood paint is characterized by comprising the following steps: comprises the following raw materials in parts by weight: 35-60 parts of modified acrylic resin emulsion, 5-15 parts of silicone-acrylic emulsion, 1-2 parts of dispersing agent, 3-6 parts of flatting agent, 4-8 parts of thickening agent, 0.5-2 parts of cerate, 1-3 parts of defoaming agent, 10-30 parts of pigment, 10-20 parts of matting powder and 30-50 parts of deionized water;
the preparation method comprises the following preparation processes:
step 1, placing the modified acrylic resin emulsion and the silicone-acrylate emulsion into a reaction tank for stirring, and stirring uniformly;
step 2, adding the pigment into the reaction tank, and fully stirring;
step 3, adding a dispersing agent, a flatting agent, a defoaming agent, cerate and a thickening agent, and fully stirring;
step 4, adding the flatting agent in equal amount for multiple times, and fully stirring to completely disperse the flatting agent in the slurry;
and 5, finally adding deionized water, dispersing for 60 minutes at a high speed, and detecting the viscosity.
2. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the step 1 adopts low-speed stirring for 20 minutes, the step 2 adopts low-speed stirring for 30 minutes, the step 3 adopts medium-speed stirring for 20 minutes, and the step 4 adopts medium-speed stirring for 20 minutes.
3. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: and (4) adding the flatting agent in 5-7 times in an equal amount.
4. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the viscosity was measured in step 5 to be 30. + -.1 seconds (coating 4# cup).
5. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the thickening agent is one or more of polyacrylamide thickening agent and KSE 881G.
6. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the cerate is one or more of polyethylene wax, palm wax and paraffin wax.
7. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the matting agent is one or more of gel matting powder AZ-200, AZ-400, AD-2000 and AD-4004.
8. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the antifoaming agent is MOMENTIVE coatosil 1211.
9. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the dispersing agent is one or more of anionic dispersing agent, (WP-4040, WP-4050) cationic dispersing agent (LH-80docx) nonionic dispersing agent and macromolecular dispersing agent (Winsperse4080A, 4190).
10. The preparation method of the matte waterborne wood paint according to claim 1, which is characterized in that: the leveling agent is one or more of modified polysiloxane type leveling agent, long-chain resin type leveling agent, special modified polyether silicone oil, DISPERBYK-110, DISPERBYK-111 and EVONIK SURFYNOL 4.
CN202011292310.7A 2020-11-18 2020-11-18 Preparation method of matte water-based wood paint Pending CN112226132A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102408801A (en) * 2011-10-22 2012-04-11 李远登 Aqueous transparent low luster furniture paint and its preparation method
CN107892848A (en) * 2017-11-23 2018-04-10 广东华兹卜新材料科技有限公司 A kind of self-crosslinking aqueous wood lacquer emulsion and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102408801A (en) * 2011-10-22 2012-04-11 李远登 Aqueous transparent low luster furniture paint and its preparation method
CN107892848A (en) * 2017-11-23 2018-04-10 广东华兹卜新材料科技有限公司 A kind of self-crosslinking aqueous wood lacquer emulsion and preparation method thereof

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