CN112221341A - A high-efficient desulfurization absorption tower for industrial flue gas - Google Patents

A high-efficient desulfurization absorption tower for industrial flue gas Download PDF

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Publication number
CN112221341A
CN112221341A CN202011167341.XA CN202011167341A CN112221341A CN 112221341 A CN112221341 A CN 112221341A CN 202011167341 A CN202011167341 A CN 202011167341A CN 112221341 A CN112221341 A CN 112221341A
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China
Prior art keywords
absorption tower
flue gas
desulfurization absorption
pipe
tower body
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CN202011167341.XA
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顾文华
顾旭
徐世杰
万立斌
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Ningxia Hexing Carbon Based Materials Co ltd
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Ningxia Hexing Carbon Based Materials Co ltd
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Priority to CN202011167341.XA priority Critical patent/CN112221341A/en
Publication of CN112221341A publication Critical patent/CN112221341A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80Semi-solid phase processes, i.e. by using slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D49/00Separating dispersed particles from gases, air or vapours by other methods
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/96Regeneration, reactivation or recycling of reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a high-efficiency desulfurization absorption tower for industrial flue gas, which comprises a desulfurization absorption tower body, wherein a flue gas inlet is formed in the middle of the desulfurization absorption tower body, a direct exhaust chimney is arranged at the top of the desulfurization absorption tower body, the lower part of the direct exhaust chimney is positioned in the desulfurization absorption tower body, and a second-stage demister, a first-stage demister, a second-stage spray pipe and a first-stage spray pipe are sequentially arranged from top to bottom. The device has the advantages of advanced integral technology, reliable equipment operation, small resistance, simple and convenient operation and maintenance, and is a practical and effective flue gas treatment process.

Description

A high-efficient desulfurization absorption tower for industrial flue gas
Technical Field
The invention relates to the technical field of flue gas desulfurization, in particular to a high-efficiency desulfurization absorption tower for industrial flue gas.
Background
China is one of the largest coal producing and consuming countries in the world, and the proportion of coal in an energy structure is as high as about 80%. At present, a large amount of sulfur dioxide, carbon monoxide, dust and smoke dust are generated in the process of producing silicon carbide, SO SO2 in flue gas in the process of producing silicon carbide is a main SO2 pollution source, and the treatment of SO2 in coal-fired flue gas is mainly wet flue gas desulfurization. In the wet desulphurization, the absorption tower is the main equipment for carrying out the flue gas desulphurization and is also the key equipment. For the absorption tower, how to deal with the change of the flue gas volume caused by the load change is very important, because the change of the flue gas volume directly causes the change of the flow velocity in the tower, and a plurality of parameters such as the desulfurization efficiency, the water flushing volume of the demister and the like are influenced. Meanwhile, in the process of treating SO2, a large amount of dust and smoke dust contained in the flue gas can also corrode and block the demisting system and the spraying system, SO that the structures of the demisting system and the spraying system are also considered in the design of the desulfurization absorption tower, and the working efficiency of the whole desulfurization absorption tower is improved.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides the high-efficiency desulfurization absorption tower for the industrial flue gas, and when the high-efficiency desulfurization absorption tower is applied, the flow velocity of the flue gas in the tower and the spraying amount of absorption liquid can be adjusted through the connection of the automatic control system, the flushing liquid regulating valve, the primary circulating pump, the secondary circulating pump, the draught fan, the water supply control valve and the blow-down valve, the desulfurization efficiency is improved, the dust removal effect is ensured, and therefore, the consumption of flushing water and the absorption liquid of a demister is reduced on the whole.
The invention is realized by the following technical scheme:
a high-efficiency desulfurization absorption tower for industrial flue gas comprises a desulfurization absorption tower body, wherein a flue gas inlet is formed in the middle of the desulfurization absorption tower body, a direct exhaust chimney is arranged at the top of the desulfurization absorption tower body, the lower part of the direct exhaust chimney is positioned in the desulfurization absorption tower body, and a second-stage demister, a first-stage demister, a second-stage spray pipe and a first-stage spray pipe are sequentially arranged from top to bottom, the upper parts of the second-stage demister and the first-stage demister are respectively provided with an upper washing pipeline, the lower parts of the second-stage demister and the first-stage demister are respectively provided with a lower washing pipeline, the upper washing pipeline and the lower washing pipeline are connected with a washing liquid inlet pipe, the upper washing pipeline and the lower washing pipeline are respectively provided with a washing liquid regulating valve, the first-stage spray pipe is connected, the bottom of one-level circulating pipe and the bottom intercommunication of desulfurization absorption tower body, the second grade shower is connected with the second grade circulating pipe, be provided with the second grade circulating pump on the second grade circulating pipe, the bottom of second grade circulating pipe and the bottom intercommunication of desulfurization absorption tower body, flue gas inlet and flue gas pipeline are connected, the last draught fan that is provided with of flue gas pipeline, the inside shower that is provided with of flue gas inlet, be connected with the upper hose on the shower, be provided with water-supply control valve on the upper hose, the inside lower part that is located flue gas inlet of desulfurization absorption tower body is provided with the absorption liquid, the bottom of desulfurization absorption tower body is provided with the blowoff valve.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, be provided with high-pressure cleaning shower nozzle on upper portion washout duct, the lower part washout duct.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, all be provided with high-pressure vaporific shower nozzle on one-level shower, second grade shower, the shower.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, the gas inlet sets up to the horn mouth, is close to the inside expansion one side that is the horn mouth of desulfurization absorption tower body, the gas inlet is provided with the angle of downward sloping, the angle of slope sets up to: between 10 and 15 degrees.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, be provided with the defogging blade on one-level defroster, the second grade defroster.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, be provided with automatic control system on the desulfurization absorption tower body, automatic control system is connected with flush fluid governing valve, one-level circulating pump, second grade circulating pump, draught fan, water control valve, blowoff valve electricity, and automatic control system controls the switch and the opening and the stop of flush fluid governing valve, one-level circulating pump, second grade circulating pump, draught fan, water control valve, blowoff valve.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, this internal inside that is located the absorption liquid of desulfurization absorption tower is provided with liquid concentration detector.
Further, a high-efficient desulfurization absorption tower for industrial flue gas, the material of desulfurization absorption tower originally from inside to outside sets gradually to granite, acidproof clay, carbon steel.
At present, can produce a large amount of sulfur dioxide at the in-process of production carborundum, carbon monoxide, the dust, the smoke and dust, how can the efficient get rid of harmful substance be the difficult problem that needs to solve at present, so this application provides a high-efficient desulfurization absorption tower for industrial flue gas, including desulfurization absorption tower body, the middle part of desulfurization absorption tower body is provided with the flue gas import, the top of desulfurization absorption tower body is provided with direct vent chimney, the lower part of direct vent chimney is located desulfurization absorption tower body and has set gradually the second grade defroster from top to bottom, the one-level defroster, the second grade shower, the one-level shower, the second grade flushing fluid, the upper portion of one-level defroster all is provided with the upper portion and washes the pipeline, the lower part of second grade defroster, the lower part of one-level defroster all is provided with the lower part and washes the pipeline, All be provided with the flush fluid governing valve on the lower part flushing pipe, the one-level shower is connected with the one-level circulating pipe, be provided with the one-level circulating pump on the one-level circulating pipe, the bottom of one-level circulating pipe and the bottom intercommunication of desulfurization absorption tower body, the second grade shower is connected with the second grade circulating pipe, be provided with the second grade circulating pump on the second grade circulating pipe, the bottom of second grade circulating pipe and the bottom intercommunication of desulfurization absorption tower body, flue gas inlet and flue gas piping connection, be provided with the draught fan on the flue gas pipeline, the inside shower that is provided with of flue gas inlet, be connected with the water pipe on the shower, be provided with water control valve on the water pipe, the inside lower part that is located flue gas inlet of desulfurization. In the absorption process, under the action of high-temperature and high-speed flowing flue gas, complex physical and chemical reactions are formed on the surface of slurry from top to bottom, on one hand, water on the surface of the slurry absorbs SO2 in the flue gas and generates an outside-in diffusion process in slurry particles, and a concentration gradient of SO2 is formed in the slurry particles; on the other hand, the moisture on the surface of the slurry gradually evaporates, the surface moisture gradually decreases, and the moisture diffuses from the inside of the slurry to the surface. During the absorption of the slurry droplets, evaporation, the moisture content on the surface gradually decreases and the concentration of SO2 on the surface gradually increases, SO that during the descent of the droplets, the slurry droplets gradually saturate during evaporation and absorption, and the absorption process tends to stop. And in the descending process of the liquid drops, the liquid drops collide with each other, so that the small liquid drops are changed into large liquid drops, and the surface area of the absorbent is reduced. The combined result of these processes is that the absorption rate gradually slows down as the droplets fall away from the head. The demister is used for separating liquid drops carried by flue gas and is provided with a washing water system and a spraying system (comprising a pipeline, a valve, a nozzle and the like). The demister system comprises a coarse demister arranged at the lower part and two fine demisters arranged at the upper part. The first stage demister located below is a large liquid droplet separator, and the blade gap is slightly larger and is used for separating larger liquid droplets carried by the rising flue gas. The second demister above is a fine liquid droplet separator, the distance between the blades is small, and the fine liquid droplet separator is used for separating fine slurry liquid droplets in rising flue gas and washing water droplets of the demister. When the flue gas flows through the demister, liquid drops are left on the baffle due to the inertia effect. Because the retained liquid drops also contain solid substances, the risk of scaling on the baffle exists, and meanwhile, in order to ensure that the pressure drop generated when the flue gas passes through the demister does not exceed a set value, the online cleaning is required to be carried out regularly. For this purpose, periodically operated cleaning devices are provided, including nozzle systems. The flushing medium is industrial water.
In summary, the following beneficial effects of the invention are:
1. the high-efficiency desulfurization absorption tower for the industrial flue gas is provided with the automatic control system, and the automatic control system is connected with the flushing liquid regulating valve, the primary circulating pump, the secondary circulating pump, the induced draft fan, the water supply control valve and the blow-down valve, so that the flow rate of the flue gas in the tower and the spraying amount of the absorption liquid can be adjusted, the desulfurization efficiency is improved, the dust removal effect is ensured, and the consumption of flushing water and the absorption liquid of a demister is reduced on the whole.
2. The high-efficiency desulfurization absorption tower for industrial flue gas provided by the invention has the advantages that the operation cost is fully reduced, the source of the desulfurizer is reliable, the byproduct is reasonably treated, no secondary pollution is generated due to no discharge, the desulfurization water is recycled, and the whole set of equipment is economical and reasonable
3. The efficient desulfurization absorption tower for the industrial flue gas has the advantages of advanced technology of the whole device, reliable equipment operation, small resistance, simple and convenient operation and maintenance, and is a practical and effective flue gas treatment process.
Drawings
The accompanying drawings, which are included to provide a further understanding of the embodiments of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the principles of the invention. In the drawings:
FIG. 1 is a schematic view of the structure of the present invention.
Reference numbers and corresponding part names in the drawings:
1-a desulfurization absorption tower body, 2-a straight-line chimney, 3-a first-stage demister, 4-a second-stage demister, 5-an upper-part flushing pipeline, 6-a lower-part flushing pipeline, 7-a flushing liquid inlet pipe, 8-a flushing liquid regulating valve, 9-a first-stage spraying pipe, 10-a second-stage spraying pipe, 11-a first-stage circulating pipe, 12-a second-stage circulating pipe, 13-a first-stage circulating pump, 14-a second-stage circulating pump, 15-a flue gas inlet, 16-a flue gas pipeline, 17-an induced draft fan, 18-a spraying pipe, 19-a water feeding pipe, 20-a water feeding control valve, 21-absorption liquid and 22-a.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to examples and accompanying drawings, and the exemplary embodiments and descriptions thereof are only used for explaining the present invention and are not meant to limit the present invention.
Examples
As shown in figure 1, a high-efficiency desulfurization absorption tower for industrial flue gas comprises a desulfurization absorption tower body 1, a flue gas inlet 15 is arranged at the middle part of the desulfurization absorption tower body 1, a direct exhaust chimney 2 is arranged at the top part of the desulfurization absorption tower body 1, a second-stage demister 4, a first-stage demister 3, a second-stage spray pipe 10 and a first-stage spray pipe 9 are sequentially arranged at the lower part of the direct exhaust chimney 2 in the desulfurization absorption tower body 1 from top to bottom, upper flushing pipes 5 are arranged at the upper parts of the second-stage demister 4 and the first-stage demister 3, lower flushing pipes 6 are arranged at the lower parts of the second-stage demister 4 and the first-stage demister 3, the upper flushing pipe 5 and the lower flushing pipe 6 are connected with a flushing fluid inlet pipe 7, regulating valves 8 are arranged on the upper flushing pipe 5 and the lower flushing pipe 6, and the first-stage spray pipe 9 is connected with a, be provided with one-level circulating pump 13 on the one-level circulating pipe 11, the bottom of one-level circulating pipe 11 and desulfurization absorption tower body 1's bottom intercommunication, second grade shower 10 is connected with second grade circulating pipe 12, be provided with second grade circulating pump 14 on the second grade circulating pipe 12, the bottom of second grade circulating pipe 12 and desulfurization absorption tower body 1's bottom intercommunication, flue gas inlet 15 is connected with flue gas pipeline 16, be provided with draught fan 17 on the flue gas pipeline 16, the inside shower 18 that is provided with of flue gas inlet 15, be connected with water-supply pipe 19 on the shower 18, be provided with water-supply control valve 20 on the water-supply pipe 19, the inside lower part that is located flue gas inlet 15 of desulfurization absorption tower body 1 is provided with absorption liquid 21, the bottom of desulfurization absorption tower body 1 is provided with blowoff valve 22.
Specifically, the upper flushing pipeline 5 and the lower flushing pipeline 6 are provided with high-pressure cleaning nozzles.
Specifically, the first-stage spray pipe 9, the second-stage spray pipe 10 and the spray pipe 18 are all provided with high-pressure mist spray heads.
Specifically, flue gas inlet 15 sets up to the horn mouth, is close to the inside expansion one side that is the horn mouth of desulfurization absorption tower body 1, flue gas inlet 15 is provided with the angle of downward sloping, the angle of slope sets up to: between 10 and 15 degrees.
Specifically, the first-stage demister 3 and the second-stage demister 4 are provided with demisting blades.
Specifically, be provided with automatic control system on the desulfurization absorption tower body 1, automatic control system is connected with flush fluid governing valve 8, one-level circulating pump 13, second grade circulating pump 14, draught fan 17, water control valve 20, blowoff valve 22 electricity, and automatic control system controls the switch and the start-stop of flush fluid governing valve 8, one-level circulating pump 13, second grade circulating pump 14, draught fan 17, water control valve 20, blowoff valve 22.
Specifically, a liquid concentration detector is arranged inside the absorption liquid 21 in the desulfurization absorption tower body 1.
Specifically, the desulfurization absorption tower body 1 is sequentially provided with granite, acid-resistant daub and carbon steel from inside to outside.
The above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are merely exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (8)

1. The utility model provides a high-efficient desulfurization absorption tower for industrial flue gas, its characterized in that, includes desulfurization absorption tower body (1), the middle part of desulfurization absorption tower body (1) is provided with flue gas inlet (15), the top of desulfurization absorption tower body (1) is provided with direct vent chimney (2), the lower part of direct vent chimney (2) is located desulfurization absorption tower body (1) and has set gradually second grade defroster (4), one-level defroster (3), second grade shower (10), one-level shower (9) from top to bottom, the upper portion of second grade defroster (4), one-level defroster (3) all is provided with upper portion flushing pipe (5), the lower part of second grade defroster (4), one-level defroster (3) all is provided with lower part flushing pipe (6), upper portion flushing pipe (5), lower part flushing pipe (6) are connected with flush fluid feed liquor pipe (7), all be provided with flush fluid governing valve (8) on upper portion washing pipeline (5), lower part washing pipeline (6), one-level shower (9) are connected with one-level circulating pipe (11), be provided with one-level circulating pump (13) on one-level circulating pipe (11), the bottom of one-level circulating pipe (11) and the bottom intercommunication of desulfurization absorption tower body (1), second grade shower (10) are connected with second grade circulating pipe (12), be provided with second grade circulating pump (14) on second grade circulating pipe (12), the bottom of second grade circulating pipe (12) and the bottom intercommunication of desulfurization absorption tower body (1), flue gas inlet (15) are connected with flue gas pipeline (16), be provided with draught fan (17) on flue gas pipeline (16), flue gas inlet (15) inside is provided with shower (18), be connected with water feeding pipe (19) on shower (18), the device is characterized in that an upper water control valve (20) is arranged on the upper water pipe (19), absorption liquid (21) is arranged on the lower portion, located at the flue gas inlet (15), of the inside of the desulfurization absorption tower body (1), and a blow-down valve (22) is arranged at the bottom of the desulfurization absorption tower body (1).
2. The tower of claim 1, wherein the upper washing pipe (5) and the lower washing pipe (6) are provided with high pressure cleaning nozzles.
3. The tower of claim 1, wherein the primary spray pipe (9), the secondary spray pipe (10) and the spray pipe (18) are provided with high pressure mist spray nozzles.
4. The high-efficiency desulfurization absorption tower for industrial flue gas according to claim 1, wherein the flue gas inlet (15) is arranged as a bell mouth, the enlarged side of the bell mouth is close to the inside of the desulfurization absorption tower body (1), the flue gas inlet (15) is provided with a downward inclined angle, and the inclined angle is arranged as follows: between 10 and 15 degrees.
5. The tower of claim 1, wherein the first-stage demister (3) and the second-stage demister (4) are provided with demisting blades.
6. The efficient desulfurization absorption tower for industrial flue gas according to claim 1, wherein an automatic control system is arranged on the desulfurization absorption tower body (1), the automatic control system is electrically connected with the flushing liquid regulating valve (8), the primary circulating pump (13), the secondary circulating pump (14), the induced draft fan (17), the water supply control valve (20) and the blowdown valve (22), and the automatic control system controls the on-off and on-off of the flushing liquid regulating valve (8), the primary circulating pump (13), the secondary circulating pump (14), the induced draft fan (17), the water supply control valve (20) and the blowdown valve (22).
7. The high-efficiency desulfurization absorption tower for industrial flue gas according to claim 1, characterized in that a liquid concentration detector is arranged inside the absorption liquid (21) in the desulfurization absorption tower body (1).
8. The high-efficiency desulfurization absorption tower for industrial flue gas according to claim 1, wherein the desulfurization absorption tower body (1) is made of granite, acid-resistant daub and carbon steel from inside to outside in sequence.
CN202011167341.XA 2020-10-28 2020-10-28 A high-efficient desulfurization absorption tower for industrial flue gas Pending CN112221341A (en)

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CN202011167341.XA CN112221341A (en) 2020-10-28 2020-10-28 A high-efficient desulfurization absorption tower for industrial flue gas

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117839394A (en) * 2023-12-29 2024-04-09 连云港泓昊复合材料有限公司 Glass fiber reinforced plastic desulfurization absorption tower

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117839394A (en) * 2023-12-29 2024-04-09 连云港泓昊复合材料有限公司 Glass fiber reinforced plastic desulfurization absorption tower

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