CN112204038B - Agricultural bactericide and application and preparation method thereof - Google Patents
Agricultural bactericide and application and preparation method thereof Download PDFInfo
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- CN112204038B CN112204038B CN202080002012.1A CN202080002012A CN112204038B CN 112204038 B CN112204038 B CN 112204038B CN 202080002012 A CN202080002012 A CN 202080002012A CN 112204038 B CN112204038 B CN 112204038B
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- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
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Abstract
The invention relates to an agricultural bactericide and an application and a preparation method thereof, wherein the agricultural bactericide has a chemical structure shown as a formula I or a formula II. The agricultural bactericide is used for preventing and treating plant bacterial diseases or plant fungal diseases.
Description
Technical Field
The invention belongs to the field of agriculture, and particularly relates to a novel agricultural bactericide and an application and preparation method thereof.
Background
1, 2-benzisothiazol-3 (2H) -one is a fungicide for agricultural and industrial use, but it has problems of strong irritation, poor stability and narrow application range.
The synthesis of 1, 2-benzo-isothiazolin-3-one, zinc (II) and copper (II) complexes such as Paraloysitum minor leaves and the like, the bacteriostatic activity thereof, and the fine chemical engineering, No. 29, No. 7 of 2012. It discloses the preparation of complexes by reacting 1, 2-benzo-isothiazolin-3-one with zinc acetate, copper acetate in the presence of methanol, dichloromethane or tetrahydrofuran solvent. The products disclosed in this publication are complexes prepared by organic solvents.
Patent application 201810149359.3 discloses a process for the preparation of benziothiazolinone metal complexes in organic solvents, which are also complexes prepared by organic solvents. And patent application 201910173745.0 discloses the preparation of the resulting benziothiazolinone metal complexes in organic solvents.
The complex or complex structure and the preparation method thereof related to the above disclosure are prepared in an organic solvent, and the product structure thereof is essentially different from the present invention.
The invention provides a brand-new agricultural bactericide which has important values in structure and agricultural application.
Disclosure of Invention
In order to solve the technical problem, the invention provides an agricultural bactericide, which is characterized by having a chemical structure as shown in formula I or formula II:
preferably, in the agricultural fungicide, the sum of the probability of the formula I and the probability of the formula II is 100%, the probability of the formula I is X, the probability of the formula II is Y, X is 0 to 100%, and Y is 0 to 100%.
Preferably, in the agricultural fungicide, the X is 1 to 99% and the Y is 1 to 99%.
Preferably, in the agricultural fungicide, X is 81.5% and Y is 18.5%.
Preferably, in the agricultural fungicide, the agricultural fungicide is characterized by having crystallographic data and parameters as follows:
wherein a, b and c are the side lengths of the unit cells; α, β and γ are the angles of the unit cell; z is the number of molecules in the unit cell,
in the chemical structure of formula I or formula II, one ligand (C8-C14, S2, N2, O2) is in a crystallographically disordered state, in formula I, O2 is coordinated with Zn2, N2 is coordinated with Zn1, in formula II, O2A is coordinated with Zn1, and N2A is coordinated with Zn 2.
The invention also provides application of the agricultural bactericide, which is characterized in that the application is the application of the agricultural bactericide in preventing and treating plant bacterial diseases or plant fungal diseases.
Preferably, the plant bacterial disease is caused by Pseudomonas (Pseudomonas), Xanthomonas (Xanthomonas), Agrobacterium (Agrobacterium), Erwinia (Erwinia), Pantoea (Pantoea), pectinase Bacillus (peobacterium), Burkholderia (Burkholderia), Ralstonia (Ralstonia), Acidovorax (Acidovorax), xylem Bacillus (Xylella), liberibacter (Liberobacter), Enterobacter (Enterobacter), rhizobacterium (rhizobacterium), Xylophilus (Xylophilus), xylinum Bacillus (clavibacterium), streptothrix (Streptomyces), brevibacterium (curobacterium), Arthrobacter (arthromobacter), Rhodococcus (Rhodococcus), Bacillus (Rhodococcus) or Bacillus (streptococcus) or Streptomyces;
further preferably, the plant bacterial disease is selected from any one or more of the following bacterial diseases 1) to 22):
1) bacterial diseases in plants caused by the genus Pseudomonas (Pseudomonas): bacterial blight of rice caused by pseudomonas glumae (p. glumae); bacterial black spot of capsicum caused by pseudomonas aeruginosa (p.syringae var. capsicii); cucumber bacterial angular leaf spot and cucumber bacterial angular leaf spot caused by pseudomonas syringae lachrymans (p. syringae pv. lachrymans); tobacco wildfire caused by pseudomonas syringae tobacco pathogenic variant (p.syringae pv. tabaci); kiwifruit canker disease caused by syzygium aromaticum pseudomonas pvt. actinoniae; kiwi fruit floral rot caused by pseudomonas (p. viriflava); bacterial medullary necrosis of tomato, pseudomonitis of tomato caused by pseudomonas winkle (p.corrugate); bacterial leaf spot disease in tomato caused by pseudomonas syringae tomato pathogenic variety (p.syringae pv. tomato); pseudomonas syringae is suitable for pepper bacterial leaf spot caused by pathotype (p.syringae pv. aptata); broccoli head rot caused by fluorescent pseudomonads (p.fluoroscens); bacterial black spot of rape caused by pseudomonas syringae var maculata (p. syringae pv. maculicola); bacterial angular leaf spot of sesame caused by pseudomonas syringae sesame cultivar (p.syringae pv. sesami); bacterial brown spot in corn caused by pseudomonas oryzae (p.oryzihabituans); broad bean bacterial stem blight caused by pseudomonas fasuensis (p.fabae); bacterial leaf spot disease in soybean caused by pseudomonas stutzeri soybean pathogenic variant (p. savastanoi pv. glycinea); bacterial leaf blight of sugar beet caused by pseudomonas solanacearum (p.aptata); pseudomonas aeruginosa (p. aeruginosa) causes ginseng pseudomonas aeruginosa soft rot;
2) bacterial diseases in plants caused by Xanthomonas (Xanthomonas): bacterial blight of rice caused by xanthomonas oryzae pathovar oryzae (x. oryzae pv. oryzae); bacterial leaf streak of rice caused by xanthomonas oryzae germinal pathogenic variant (x. oryzae pv. oryzae) and; citrus canker disease caused by xanthomonas citri (x.citri subsp.citri); peach bacterial perforation disease caused by xanthomonas arborescens peach pathogenic variant (X. arboricola pv. prune); brassicaceae black rot caused by Xanthomonas campestris pathogenic variety X.campestris pv. campestris; watermelon spot disease caused by Xanthomonas glycanorrhoeae (X.campestis pv. cucurbitae); bacterial scab of tomato and pepper caused by Xanthomonas campestris pepper spot pathogenic variety (X.campestis pv. vesicatoria); bacterial black spot disease in mango caused by xanthomonas campestris mango pathovar (x. campestis pv. mangifereae); bacterial leaf spot of pepper caused by xanthomonas campestris piperis pathogenic variety (x. campestis pv. betuliola); bacterial blight of poinsettia caused by xanthomonas campestris poinsettia pathovar x.campesticola (pv. poinsetticola); cotton angular leaf spot caused by xanthomonas carpi mallow pathogenic variety (x. axonopodis pv. malvacearum); soybean bacterial leaf spot disease caused by Xanthomonas carpi soybean pathogenic variety (X.axonopodis pv. glycines); bacterial wilt of cassava caused by Xanthomonas carpi (X. axonopodis pv. manihot); anthurium bacterial blight caused by Xanthomonas carpi Huanyanqing pathogenic variety (X.axonopodis pv. dieffenbachiae); strawberry angular leaf spot caused by xanthomonas strawberrii (x. fragariae);
3) bacterial diseases in plants caused by the genus Agrobacterium (Agrobacterium): watermelon bacterial crown gall and rosaceous root cancer caused by agrobacterium tumefaciens (a. tumefaciens); melon bacterial hairy root disease caused by agrobacterium rhizogenes (a. grobacter tumefaciens);
4) bacterial diseases in plants caused by Erwinia (Erwinia): clearing away erwinia amylovora (E.amylovora) caused pear fire blight; bacterial basal rot of rice caused by erwinia maize cultivar (e.chrysanthemi pv. zeae); soft rot of Brassicaceae, watermelon and onion caused by Erwinia carotovora (E.carotovora subsp.carotovora); watermelon wilt disease caused by erwinia avicularis (e.tracheiphila);
5) bacterial diseases in plants caused by Pantoea (Pantoea): pantoea zeae leaf spot caused by Pantoea ananatis (P.ananatis); bacterial leaf blight of red bean caused by Pantoea agglomerans (P.agglomerans);
6) bacterial diseases in plants caused by the genus Pectobacterium (Pectibacter): tomato soft rot and pepper soft rot caused by pectobacterium carotovorum subsp. Soft rot disease of potato caused by p.carotovorum subsp.brasiliensis; potato black shank caused by p.atrosepticum;
7) bacterial diseases in plants caused by Burkholderia (Burkholderia): onion bulb rot disease caused by burkholderia cepacia (b.cepacia); bacterial spike blight of rice caused by burkholderia glumae (b.glumae); bacterial wilt of dianthus caryophyllus caused by burkholderia malabarica (b. caryophyli);
8) bacterial diseases in plants caused by the genus Ralstonia (Ralstonia): potato bacterial wilt, tomato bacterial wilt, pepper bacterial wilt and watermelon bacterial wilt caused by Laurella sp.solanacearum;
9) bacterial diseases in plants caused by Acidovorax (Acidovorax): bacterial fruit rot of melons caused by acidovorax citrulli (a. citrulli); bacterial brown streak disease in rice caused by oat acidovorax avenae subsp.
10) Bacterial diseases in plants caused by xylaria (Xylella): grapevine dermatosis caused by xylella fastidiosa x.fastidiosa;
11) bacterial diseases in plants caused by the genus of the genus Liberobacter: citrus yellow shoot caused by asian (l.asiaticus), african (l.africanus), american (l.americanus);
12) bacterial diseases in plants caused by the genus Enterobacter (Enterobacter): yellowing disease in papaya fruits caused by enterobacter cloacae (e.cloacae); poplar wilt disease caused by enterobacter carcinogens (e.cancerogenus);
13) bacterial diseases in plants caused by the genus rhizobacterium (Rhizobacter): carrot gall disease caused by daucus;
14) bacterial diseases in plants caused by the genus Xylophilus (Xylophilus): grape canker disease caused by ampelinus;
15) bacterial diseases in plants caused by dikaya (Dickeya): bacterial stalk rot in maize caused by d.zeae; sweet potato stem rot caused by daldantii (d.dadantii); potato black shank caused by diskettsia solanacearum (d.solani); erwinia rust disease caused by daldikaea (d. fangzhongdai);
16) bacterial diseases in plants caused by the genus Clavibacter (Clavibacter): potato ring rot disease caused by clavibacter michiganensis subsp. Tomato canker disease caused by clavibacter michiganensis subsp.
17) Bacterial diseases in plants caused by the genus Streptomyces (Streptomyces): potato scab caused by streptomyces scab (s.scabies);
18) bacterial diseases in plants caused by the genus brevibacterium (Curtobacterium): bean wilt caused by Bacillus pumilus wilt pathogenic variety (C. flaccumfaciens pv. flaccumfaciens); bacterial leaf spot of beet caused by Bacillus pumilus beet pathogenic variant (C. flaccumfaciens pv. bet); tulip yellow bleb spot caused by bacillus pumilus austenic variant (c. flaccumfaciens pv. orctii);
19) bacterial diseases in plants caused by Arthrobacter (Arthrobacter): ilex purpurea caused by ilicis;
20) bacterial diseases in plants caused by the genus Rhodococcus (Rhodococcus): sweet pea banding disease caused by fascians and the like;
21) bacterial diseases in plants caused by the genus Bacillus (Bacillus): bacillus megaterium (b.megaterium) induced leaf spot of bacillus zeae;
22) bacterial diseases in plants caused by the genus Rathaibacter (Rathayibacter): rathayi causes dactylosia.
Preferably, the plant fungal diseases are plant fungal diseases caused by any one or more of the following pathogenic bacteria 1) to 7):
1) pythium (Pythium), Phytophthora (Phytophthora), Phytophthora (sclerophora), peronophythora (perophthora), peronophythora (peronophytora), Albugo (Albugo), Peronospora (Peronospora), Pseudoperonospora (Pseudoperonospora), plasmopara (Plasmopora), stemphylium (Bremia), aureospora (Sclerospora) in Oomycetes (Oomycetes);
2) chytrium (Olpidium), chytrium (syncytium), chytrium (phynoderma) in chytrium (chydiycetes);
3) plasmodiophoromycetes (Plasmodiophoromycetes), sphaerotheca (Spongospora), Polymyxa (Polymyxa) among Plasmodiophoromycetes (Plasmodiophoromycetes);
4) puccinia (Puccinia), colletotrichum (gynosporangium), polyspora (Phragmidium), unicospora (Uromyces), Phakopsora (Phakopsora), corymbosa (Melampsora), Ustilago (Ustilago), Ustilago (Urocystis), Ustilago (Entyloma), triticale (Tilletia), Ustilago (sphacelotheca), eurotia (doassasiopsis), and ectomycosis (isobasidium) among Basidiomycetes (Basidiomycetes);
5) penicillium (Penicillium), Aspergillus (Aspergillus), Mycosphaerella (Mycosphaeralla), Encapsulated (Physiospora), Mycosphaerella (Guignardia), Staphyloccocus (Botryosphaeria), Venturia (Venturia), Erysiphe (Erysiphe), Sphaerotheca (Sphaerotheca), Blumeria (Blumeria), Sphaerotheca (Podosphaera), Sphaerotheca (Phyllantia), Sphaerotheca (Microsphaera), Uncaria (Uncaria), Rhynchophylla (Ceratocarpis), gibberella (Gibberella), humicola (Valsa), plexiglas (Glomerella), pustulosis (Polystima), ischium (Diaporthe), Elsinoe (Elsinoe), pyrenophora (Drechslera), Cochliobolus (Cochliobolus), Sclerotinia (sclerotiotinotia), soot (Capnodium), sphaerotheca (setospora), streptoverticillium (Monilinia), acrocarpus (Gaeumannomyces), ergothrips (Claviceps), botrytis (Pleospora);
6) pediobolus species (Monilinia), Botrytis, Microsporum species (Trichothecium), Cylindrocarpon species (Ramularia), Trichosporon species (Oidium), Pyricularia species (Pyricularia), Verticillium species (Verticillium), Cercospora species (Cercospora), Alternaria species (Alternaria), Cladosporium species (Cladosporium), Venerigeron species (Fusarium), Helicoveromyces species (Drecholera), Helicoveromyces species (Cochliobolus), Theobromyces species (Exophilum), Curvularia species (Curvularia), Pseudocercospora species (Pseudorhizospora), Phaeococcus species (Cordada), Thelephora species (Corynebacterium), Rhizoctonia species (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia ), Rhizoctonia (Rhizoctonia, or (Rhizoctonia, or a, Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, phoma (Phoma), Phoma (Phytolytica), Phoma (Macrophoma), Phomopsis (Phomopsis), Septoria (Septoria), Ascomyces (Valsa), Dichloropsis (Diplodia), Trichosporon (Ascochyta), Fusarium (Fusiococcum), Trichosporon (Coniella), Coniothyrium (Coniothyrium), Coccidium globosum (Botrydiplodia);
7) rhizopus (Rhizopus), dichocrochora (Choanephora) in Zygomycotina (Zygomycotina);
further preferably, the plant fungal diseases are selected from any one or more of the following fungal diseases 1) to 103):
1) fungal diseases of plants caused by Pythium (Pythium): cucumber rot caused by pythium aphanidermatum (P.aphanidermatum), cucurbit rot rape damping-off, soybean damping-off, cabbage damping-off, cauliflower damping-off, spinach damping-off, water spinach damping-off, vegetable soybean damping-off, beet root cluster disease, tobacco damping-off, cotton seedling damping-off, broccoli seedling damping-off, fennel damping-off, sunflower seedling rot, bitter gourd damping-off;
2) fungal diseases of plants caused by Phytophthora (Phytophthora): potato late blight, tomato late blight, phytophthora parasitica tobacco pathogenic type (p.parasitica var. nicotianae) tobacco black shank, phytophthora capsici (p.capsicii) pepper blight, phytophthora parasitica (p.nicotianae var. parasitica) pineapple heart rot, p.citrophthora induced citrus brown rot, p.fragaria induced strawberry red heart, phytophthora melonis (p.melonis) cucumber blight;
3) fungal diseases of plants caused by Phytophthora (Sclerophora): maize mad top disease caused by macropora;
4) plant fungal diseases caused by phytophthora parasitica (Peronophythora): downy blight of litchi caused by downy phytophthora litchi (p. litchii);
5) fungal plant diseases caused by white rust (Albugo): white rust of plants such as rape, Chinese cabbage and radish caused by white rust of Cruciferae white rust (A. Candida);
6) fungal diseases of plants caused by Peronospora (Peronospora): tobacco downy mildew caused by tobacco downy mildew (p.tabacina); downy mildew of Chinese cabbage caused by parasitic downy mildew (p. parasitica); downy mildew of soybean caused by downy mildew of northeast downy mildew (p.man-schurica);
7) fungal plant diseases caused by the genus Pseudoperonospora (Pseudoperonospora): downy mildew of melons such as cucumber and pumpkin caused by pseudoperonospora cubensis (p. cubensis);
8) fungal plant diseases caused by Plasmopora (Plasmopora): grapevine downy mildew caused by grapevine downy mildew (p.viticola);
9) fungal plant diseases caused by the genus stemphylium (Bremia): lettuce downy mildew caused by Bremia lactucae (B.lactucae);
10) fungal plant diseases caused by the genus stemphylium (Sclerospora): rhizopus graminicola (s.graminicola) causing the development of millet bloom;
11) fungal diseases of plants caused by the genus olea (Olpidium): a Vicia faba-Hui fungus fire swelling disease caused by Soy bean oil chytrid (O.vitae);
12) fungal plant diseases caused by the genus thraustochytrium (syncytrium): potato canceration caused by endophytic chytrium (s.endobioticum);
13) fungal plant diseases caused by the genus nodularia (phynoderma): zea mays (p. maydis) causes brown spot in corn;
14) fungal diseases of plants caused by Plasmodiophora (Plasmodiophora): plasmodiophora brassicae (p. brassicae) causes plasmodiophora brassicae;
15) plant fungal diseases caused by the genus eschar (Spongospora): potato powdery scab is caused by potato powdery scab bacteria (s. subterranean);
16) fungal plant diseases caused by Puccinia (Puccinia): wheat straw rust caused by puccinia graminis (p.graminis per. var. tritici);
17) fungal plant diseases caused by the genus phakopsora (Gymnosphaangium): pear rust caused by rust of pear gum (g. acanthom);
18) fungal plant diseases caused by the genus Puccinia (Phragmidium): rust disease of rose caused by rust of short-tipped polyspora (p. mucronatum);
19) fungal plant diseases caused by the genus rust (Uromyces): bean rust disease caused by p.verrucosa (u.apendiculus);
20) fungal plant diseases caused by Phakopsora (Phakopsora): jujube rust caused by multi-layer rust of jujube (P. ziziphi-vulgaris);
21) fungal plant diseases caused by the genus Graptosphaera (Melampsora): flax rust caused by m.lini;
22) fungal plant diseases caused by smut (Ustilago): wheat powdery mildew caused by wheat aleuromyces dispersus (U.tritici);
23) fungal plant diseases caused by the genus Ustilago (Urocystis): wheat straw smut caused by wheat smut (u.tritic);
24) plant fungal diseases caused by smut (Entyloma): smut of rice leaves caused by smut (e.oryzae);
25) plant fungal diseases caused by Tilletia (Tilletia): tilletia reticulata (T.caries) Tilletia foetida; rice smut caused by stinkbug-layana (t. barc-layana);
26) fungal plant diseases caused by axial smut (Sphacelootheca): sorghum smut caused by ustilago sorghum (s.cruenta);
27) plant fungal diseases caused by the genus nigrospora (Doassansiopsis): arrowhead smut caused by arrowhead smut (d.horiana);
28) fungal plant diseases caused by the genus Exobasidium (Exobasidium): tea cake disease caused by exobasidiomycetes (e.vexans);
29) fungal plant diseases caused by the genus Penicillium (Penicillium): citrus rot disease caused by penicillium italicum (p. italicum);
30) fungal plant diseases caused by Aspergillus (Aspergillus): fruit mildew rot caused by Aspergillus sp;
31) fungal diseases of plants caused by the genus Mycosphaerella (Mycosphaerella): citrus brown spot due to mycosphaerella citri (m.citri), cercospora cherry (m.cerasella), cercospora persimmon (m.nawae), cercospora peanut (m.berkeley), and cercospora peanut (m.arachidis);
32) fungal diseases of plants caused by the genus ascochyta (physiospora): peanut stem rot caused by citrus ascospora chrysosporium (physospora rhodotina), grape house blight caused by botrytis cinerea (p.baccae), and ring rot of pear tree, apple, peach, plum and apricot caused by ascospora chrysosporium (physospora sp);
33) fungal plant diseases caused by globulus (Guignardia): grape black rot caused by ascosphaera botrytis (G.biwellii), and leaf blight of tea caused by G.camelliae;
34) fungal plant diseases caused by plasmodiophora (Botryosphaeria): apple white rot and blueberry stem blight caused by globispherea sp, peach gummosis, peach branch withering, grape canker and grape branch blight caused by botrytis sp;
35) fungal plant diseases caused by the genus Venturia (Venturia): black spot disease of pear caused by black bean fungus (v.pirina), and black spot disease of peach caused by black bean fungus (v.carpopocilum);
36) fungal diseases of plants caused by powdery mildew (Erysiphe): powdery mildew of cereal caused by powdery mildew (e.graminis), powdery mildew of cabbage caused by powdery mildew (e.cruciferae);
37) fungal plant diseases caused by the genus Sphaerotheca (Sphaerotheca): powdery mildew of melons and beans caused by cucurbit unisporum powdery mildew (s.furiginea);
38) plant fungal diseases caused by erysiphe (Blumeria): powdery mildew of gramineous plants caused by powdery mildew of gramineous powdery mildew (b.graminis);
39) fungal plant diseases caused by the genus aphanotheca (Podosphaera): powdery mildew of crab apple, plum and apple caused by P.leucotricha;
40) fungal diseases of plants caused by the genus Stropharia (Phyllantia): powdery mildew caused by P.chrysosporium (P.chrysosporium) such as chestnut, papaya, phoenix tree, pear, persimmon, walnut, etc.;
41) fungal plant diseases caused by the genus aphanidermia (microphaga): berberis powdery mildew caused by sphaerotheca berberidis (m.berberidicola), and aristolochia debilis caused by sphaerotheca aristolochiae (m.aristolochiae);
42) fungal plant diseases caused by the genus Uncinula (Uncinula): grape powdery mildew caused by leptospira vitis (u.necator);
43) fungal diseases of plants caused by the genus Ceratocystis (Ceratocystis): sweet potato black spot disease caused by sweet potato chayote (C.fimbriata) and sugarcane pineapple disease caused by paradoxa (C.paradoxa);
44) fungal plant diseases caused by the genus Gibberella (Gibberella): gibberella zeae (g.zeae) causes wheat scab, gibberella granatum (g.jikuroi) causes rice bakanae disease;
45) fungal plant diseases caused by the genus Humicola (Valsa): apple tree rot caused by apple humicola (v.mali);
46) fungal plant diseases caused by the genus Lepidium (Glomerella): anthracnose of fruit trees caused by cingulata;
47) fungal diseases of plants caused by furunculosis (Polystima): red spot disease of plum caused by plum furunculosis (Polystigma rubrum);
48) fungal plant diseases caused by Diaporthe (Diaporthe): citrus gummosis caused by citrus intercropping fungus (d.citricola), sweet potato dry rot caused by sweet potato intercropping fungus (d.batatatis), soybean northern stem canker caused by kidney bean intercropping fungus (d.phaseolorum var.caulivora), apple hypocotyl (d.pomigena) causes apple black spot disease;
49) plant fungal diseases caused by Elsinoe (Elsinoe): vitis vinifera anthracnose caused by Elsinoe ampelina (E.ampelina);
50) fungal plant diseases caused by Pyrenophora (Drechslera): wheat stripe disease caused by wheat sclerotinia (d.graminea);
51) plant fungal diseases caused by the genus Cochliobolus (Cochliobolus): wheat root rot caused by colletotrichum gloeosporioides (c.sativas);
52) fungal diseases of plants caused by Sclerotinia (sclerotiotinia): sclerotinia rot of colza and cucumber caused by sclerotinia sclerotiorum (s.sclerotiorum);
53) fungal diseases of plants caused by soot (Capnodium): citrus sooty mould, hawthorn sooty mould, tea mould and mango mould caused by citrus bituminous coal pathogen (c.citri);
54) fungal plant diseases caused by the genus phyllosphaeria (setosperia): northern leaf blight of maize caused by sitophila macrosperma (s.turcicaca);
55) fungal plant diseases caused by the genus streptomyces (Monilinia): brown rot of apple, pear, peach caused by sclerotinia sclerotiorum (m.fructicola);
56) fungal plant diseases caused by the genus Gaeumannomyces (Gaeumannomyces): cereal and wheat take-all caused by gaeumannomyces graminis variety (g.graminis var. graminis), gaeumannomyces graminis variety (g.graminis (Sacc.) arxet oliver var. tritici);
57) fungal diseases of plants caused by the ergot genus (Claviceps): ergot (c. purpurea) graminis;
58) fungal plant diseases caused by the genus botrytis (Pleospora): tomato gray leaf spot caused by tomato botrytis cinerea (p.lycopersici), and chive leaf blight caused by onion blight (p.herbarum);
59) fungal plant diseases caused by the genus aureobasidium (Monilinia): apple and pear brown rot caused by aureobasidium reniformis (M.fructigena), peach brown rot and apricot brown rot caused by M.laxa;
60) fungal diseases of plants caused by Botrytis (Botrytis): botrytis cinerea (b.cinerea) causes botrytis cinerea, cucumber gray mold, pepper gray mold, grape gray mold, and apple gray mold;
61) fungal plant diseases caused by the genus polyporus (Trichothecium): maize polyporus pinus head rot caused by polyporus pinus (t. roseum);
62) fungal plant diseases caused by the genus septoria (Ramularia): cotton vitiligo caused by exosporium leucotrichum (r. areola);
63) fungal plant diseases caused by the genus Trichosporon (Oidium): lycium barbarum powdery mildew caused by Oidium sp, tomato powdery mildew caused by tomato powdery mildew (o.lycopersic);
64) fungal diseases of plants caused by Pyricularia (Pyricularia): pyricularia oryzae (P.oryae) caused by Pyricularia oryzae;
65) fungal plant diseases caused by Verticillium (Verticillium): verticillium wilt of cotton and verticillium wilt of eggplant caused by verticillium dahliae (V.dahliae);
66) fungal diseases of plants caused by Cercosporella (Cercosporella): white spot disease of Chinese cabbage caused by Cercospora leucoderma (C.albo-maculans);
67) fungal diseases of plants caused by Cercospora (Cercospora): cercospora arachidicola (c.arachidicola) induced peanut brown spot disease, Cercospora colata (c.beticola) induced sugar beet brown spot disease, Cercospora sp, etc. induced oriental cherry brown spot disease, clove brown spot disease, osmanthus fragrans leaf spot disease, azalea leaf spot disease;
68) fungal plant diseases caused by Alternaria (Alternaria): alternaria apple specialization (a. Alternaria f. sp mali) induced Alternaria leaf spot, a. solani induced tomato early blight, a. alternata induced tobacco brown spot, Alternaria sp induced cotton ring spot, apple brown spot, Alternaria late blight, almond root rot, radish black spot;
69) fungal plant diseases caused by Cladosporium (Cladosporium): cucumber scab caused by cladosporium cucumerinum (c. cucumerinum);
70) plant fungal diseases caused by the genus nigrospora (fusarium): pear scab caused by black bean fungus (Fusicillarium virecens);
71) fungal plant diseases caused by helmholysis (Drechslera): barley net blotch caused by helminthosporium cucumerinum (d. teres);
72) fungal plant diseases caused by helminthosporium peregrinum (Cochliobolus): leaf spot of rice flax caused by helminthosporium oryzae (c.miyabenus);
73) fungal plant diseases caused by helminthosporium (Exserohilum): northern leaf blight of corn caused by eurotium megamaculatum (e.turcicum);
74) fungal diseases of plants caused by Curvularia (Curvularia): leaf spot of Curvularia lunata caused by Lunata;
75) fungal plant diseases caused by Pseudocercospora (Pseudocercospora): sigatoka caused by pseudocercospora banana (p.musae), sigatoka caused by pseudocercospora fijiensis (p.fijiensis), cercospora viticola (p.vitis);
76) fungal plant diseases caused by the genus Lawsonia (Cordana): banana gray streak disease caused by banana dim spore (c.musae);
77) fungal diseases of plants caused by Stemphylium (stemphyllium): rhizopus solanacearum (s.solani) tomato gray leaf spot disease, and phoma termatamum leptopodum (s.botryosum) induced leaf blight of chive;
78) plant fungal diseases caused by the genus trichoderma (Fulvia): tomato leaf mold and pepper leaf mold caused by fulvia fulva (f.fulva);
79) fungal plant diseases caused by corynebacterium (Corynespora): cucumber brown spot disease caused by cucumber brown spot pathogen (Corynespora cassiicola);
80) fungal diseases of plants caused by Rhizoctonia (Rhizoctonia): rhizoctonia solani (r.solani) induced sheath blight of rice, cucumber rhizoctonia solani;
81) fungal diseases of plants caused by sclerotium (Selerotium): oil tea, Aleurites fordii, catalpa bungei, citrus, apple, phoenix tree, paulownia, walnut, masson pine, peanut, pepper, shallot southern blight caused by sclerotium rolfsii (Selerotium rolfsii);
82) fungal plant diseases caused by Fusarium (Fusarium): fusarium oxysporum cucumber fusarium wilt caused by cucumber specialization (f.oxysporum f.sp.cucumerium), cotton fusarium wilt caused by fusarium oxysporum wilting specialization (f.oxysporum f.sp.vassifnfectium), and fusarium graminearum caused by fusarium graminearum;
83) fungal plant diseases caused by the genus sclerotium virescens (Ustilaginoidea): rice false smut caused by sclerotinia graminicola (u.oryzae);
84) plant fungal diseases caused by the genus Sphaceloma (Sphaceloma): grape anthracnose caused by Stachybotrys scaber (S.ampelium), citrus scab caused by Stachybotrys citricola (S.fawcettii), solanaceous vegetable scab, pomelo scab and peanut scab caused by Sphaceloma sp;
85) plant fungal diseases caused by Colletotrichum (Colletotrichum): grape anthracnose caused by Colletotrichum gloeosporioides (c.orbiosporioides), cucurbitaceae Colletotrichum sp, oats, brome, orange, citrus, apple, banana, pea, bean, cabbage, melon, sugar beet, tea, tobacco and sugarcane anthracnose;
86) fungal plant diseases caused by discorea (Marssonina): cercospora leaf spot of apple caused by diplospora piricola (m.mali);
87) fungal diseases of plants caused by ray-spores (Actinonema): rosae-induced melasma roseoflavae;
88) fungal plant diseases caused by Pestalotia (Pestalotia): tea leaf spot caused by pestalotiopsis chaetosa (p. theta.);
89) fungal plant diseases caused by discothrix (Gloeosporium): tea anthracnose caused by theasinesis;
90) fungal diseases of plants caused by Phoma (Phoma): brassica napus black shank caused by phoma nigricans (p.lingam);
91) fungal diseases of plants caused by the genus Phyllosticta (Phyllosticta): cotton brown spot caused by cotton lobular spot mould (p. gossypina);
92) fungal diseases of plants caused by the genus Macrophoma (Macrophoma): ring spot disease of apple, pear, etc. caused by large stem of ring spot (m.kuwatsukai);
93) fungal diseases of plants caused by Phomopsis (Phomopsis): pseudophomopsis solanacearum (p. vexans);
94) plant fungal diseases caused by Septoria (Septoria): wheat glume blight caused by septoria nodorum (s.nodorum);
95) fungal plant diseases caused by ascochyta (Valsa): pear tree rot caused by apple black hull pear variety (v.mali var. pyri);
96) fungal plant diseases caused by the species Diplodia (Diplodia): cotton boll melanosis caused by cotton bicells (Diplodia gossypina);
97) fungal diseases of plants caused by Ascochyta (Ascochyta): cucumber gummy stem blight caused by Ascochyta cucumis (Ascochyta cucumis);
98) fungal plant diseases caused by Fusarium (Fusicoccum): vine blight caused by Fusarium botrytis (F. viticola);
99) fungal plant diseases caused by the genus Microcospora (Coniella): grape white rot caused by colletotrichum solani (c. diplodiella);
100) fungal plant diseases caused by Coniothyrium (Coniothyrium): white rot of grape caused by Coniothyrium dipnodiella;
101) plant fungal diseases caused by globisporus (Botryodiplodia): mango rot caused by theobromae;
102) fungal diseases of plants caused by Rhizopus (Rhizopus): sweet potato soft rot caused by rhizopus stolonifer (r.stolonifer);
103) fungal diseases of plants caused by Choanephora (Choanephora): rotten flowers or young fruits of melons caused by Choanephora sp, rotten organs of seeds and bulbs in the storage period, rotten soft tissues of flowers and trees (calamus glauca corms and purple goldenrod roots), rotten soft tissues of strawberries and soft rot diseases of melons.
The invention provides an agricultural bactericide which is Cu-K at 25 DEG CαThe X-ray powder diffraction pattern under radiation has the following characteristic data expressed by the d value of the interplanar spacing:
the invention also provides application of the agricultural bactericide, which is characterized in that the application is the application of the agricultural bactericide in preventing and treating plant bacterial diseases or plant fungal diseases.
Preferably, the plant bacterial disease is caused by Pseudomonas (Pseudomonas), Xanthomonas (Xanthomonas), Agrobacterium (Agrobacterium), Erwinia (Erwinia), Pantoea (Pantoea), pectinase Bacillus (peobacterium), Burkholderia (Burkholderia), Ralstonia (Ralstonia), Acidovorax (Acidovorax), xylem Bacillus (Xylella), liberibacter (Liberobacter), Enterobacter (Enterobacter), rhizobacterium (rhizobacterium), Xylophilus (Xylophilus), xylinum Bacillus (clavibacterium), streptothrix (Streptomyces), brevibacterium (curobacterium), Arthrobacter (arthromobacter), Rhodococcus (Rhodococcus), Bacillus (Rhodococcus) or Bacillus (streptococcus) or Streptomyces;
further preferably, the plant bacterial disease is selected from any one or more of the following bacterial diseases 1) to 22):
1) bacterial diseases in plants caused by the genus Pseudomonas (Pseudomonas): bacterial blight of rice caused by pseudomonas glumae (p. glumae); bacterial black spot of capsicum caused by pseudomonas aeruginosa (p.syringae var. capsicii); cucumber bacterial angular leaf spot and cucumber bacterial angular leaf spot caused by pseudomonas syringae lachrymans (p. syringae pv. lachrymans); tobacco wildfire caused by pseudomonas syringae tobacco pathogenic variant (p.syringae pv. tabaci); kiwifruit canker disease caused by syzygium aromaticum pseudomonas pvt. actinoniae; kiwi fruit floral rot caused by pseudomonas (p. viriflava); bacterial medullary necrosis of tomato, pseudomonitis of tomato caused by pseudomonas winkle (p.corrugate); bacterial leaf spot disease in tomato caused by pseudomonas syringae tomato pathogenic variety (p.syringae pv. tomato); pseudomonas syringae is suitable for pepper bacterial leaf spot caused by pathotype (p.syringae pv. aptata); broccoli head rot caused by fluorescent pseudomonads (p.fluoroscens); bacterial black spot of rape caused by pseudomonas syringae var maculata (p. syringae pv. maculicola); bacterial angular leaf spot of sesame caused by pseudomonas syringae sesame cultivar (p.syringae pv. sesami); bacterial brown spot in corn caused by pseudomonas oryzae (p.oryzihabituans); broad bean bacterial stem blight caused by pseudomonas fasuensis (p.fabae); bacterial leaf spot disease in soybean caused by pseudomonas stutzeri soybean pathogenic variant (p. savastanoi pv. glycinea); bacterial leaf blight of sugar beet caused by pseudomonas solanacearum (p.aptata); pseudomonas aeruginosa (p. aeruginosa) causes ginseng pseudomonas aeruginosa soft rot;
2) bacterial diseases in plants caused by Xanthomonas (Xanthomonas): bacterial blight of rice caused by xanthomonas oryzae pathovar oryzae (x. oryzae pv. oryzae); bacterial leaf streak of rice caused by xanthomonas oryzae germinal pathogenic variant (x. oryzae pv. oryzae) and; citrus canker disease caused by xanthomonas citri (x.citri subsp.citri); peach bacterial perforation disease caused by xanthomonas arborescens peach pathogenic variant (X. arboricola pv. prune); brassicaceae black rot caused by Xanthomonas campestris pathogenic variety X.campestris pv. campestris; watermelon spot disease caused by Xanthomonas glycanorrhoeae (X.campestis pv. cucurbitae); bacterial scab of tomato and pepper caused by Xanthomonas campestris pepper spot pathogenic variety (X.campestis pv. vesicatoria); bacterial black spot disease in mango caused by xanthomonas campestris mango pathovar (x. campestis pv. mangifereae); bacterial leaf spot of pepper caused by xanthomonas campestris piperis pathogenic variety (x. campestis pv. betuliola); bacterial blight of poinsettia caused by xanthomonas campestris poinsettia pathovar x.campesticola (pv. poinsetticola); cotton angular leaf spot caused by xanthomonas carpi mallow pathogenic variety (x. axonopodis pv. malvacearum); soybean bacterial leaf spot disease caused by Xanthomonas carpi soybean pathogenic variety (X.axonopodis pv. glycines); bacterial wilt of cassava caused by Xanthomonas carpi (X. axonopodis pv. manihot); anthurium bacterial blight caused by Xanthomonas carpi Huanyanqing pathogenic variety (X.axonopodis pv. dieffenbachiae); strawberry angular leaf spot caused by xanthomonas strawberrii (x. fragariae);
3) bacterial diseases in plants caused by the genus Agrobacterium (Agrobacterium): watermelon bacterial crown gall and rosaceous root cancer caused by agrobacterium tumefaciens (a. tumefaciens); melon bacterial hairy root disease caused by agrobacterium rhizogenes (a. grobacter tumefaciens);
4) bacterial diseases in plants caused by Erwinia (Erwinia): clearing away erwinia amylovora (E.amylovora) caused pear fire blight; bacterial basal rot of rice caused by erwinia maize cultivar (e.chrysanthemi pv. zeae); soft rot of Brassicaceae, watermelon and onion caused by Erwinia carotovora (E.carotovora subsp. carotovora); watermelon wilt disease caused by erwinia avicularis (e.tracheiphila);
5) bacterial diseases in plants caused by Pantoea (Pantoea): pantoea zeae leaf spot caused by Pantoea ananatis (P.ananatis); bacterial leaf blight of red bean caused by Pantoea agglomerans (P.agglomerans);
6) bacterial diseases in plants caused by the genus Pectobacterium (Pectibacter): tomato soft rot and pepper soft rot caused by pectobacterium carotovorum subsp. Soft rot disease of potato caused by p.carotovorum subsp.brasiliensis; potato black shank caused by p.atrosepticum;
7) bacterial diseases in plants caused by Burkholderia (Burkholderia): onion bulb rot disease caused by burkholderia cepacia (b.cepacia); bacterial spike blight of rice caused by burkholderia glumae (b.glumae); bacterial wilt of dianthus caryophyllus caused by burkholderia malabarica (b. caryophyli);
8) bacterial diseases in plants caused by the genus Ralstonia (Ralstonia): potato bacterial wilt, tomato bacterial wilt, pepper bacterial wilt and watermelon bacterial wilt caused by Laurella r.solanacearum;
9) bacterial diseases in plants caused by Acidovorax (Acidovorax): bacterial fruit rot of melons caused by acidovorax citrulli (a. citrulli); bacterial brown streak disease in rice caused by oat acidovorax avenae subsp.
10) Bacterial diseases in plants caused by xylaria (Xylella): grapevine dermatosis caused by xylella fastidiosa x.fastidiosa;
11) bacterial diseases in plants caused by the genus of the genus Liberobacter: citrus yellow shoot caused by asian (l.asiaticus), african (l.africanus), american (l.americanus);
12) bacterial diseases in plants caused by the genus Enterobacter (Enterobacter): yellowing disease in papaya fruits caused by enterobacter cloacae (e.cloacae); poplar wilt disease caused by enterobacter carcinogens (e.cancerogenus);
13) bacterial diseases in plants caused by the genus rhizobacterium (Rhizobacter): carrot gall disease caused by daucus;
14) bacterial diseases in plants caused by the genus Xylophilus (Xylophilus): grape canker disease caused by ampelinus;
15) bacterial diseases in plants caused by dikaya (Dickeya): bacterial stalk rot in maize caused by d.zeae; sweet potato stem rot caused by daldantii (d.dadantii); potato black shank caused by diskettsia solanacearum (d.solani); erwinia rust disease caused by daldikaea (d. fangzhongdai);
16) bacterial diseases in plants caused by the genus Clavibacter (Clavibacter): potato ring rot disease caused by clavibacter michiganensis subsp. Tomato canker disease caused by clavibacter michiganensis subsp.
17) Bacterial diseases in plants caused by the genus Streptomyces (Streptomyces): potato scab caused by streptomyces scab (s.scabies);
18) bacterial diseases in plants caused by the genus brevibacterium (Curtobacterium): bean wilt caused by Bacillus pumilus wilt pathogenic variety (C. flaccumfaciens pv. flaccumfaciens); bacterial leaf spot of beet caused by Bacillus pumilus beet pathogenic variant (C. flaccumfaciens pv. bet); tulip yellow bleb spot caused by bacillus pumilus austenic variant (c. flaccumfaciens pv. orctii);
19) bacterial diseases in plants caused by Arthrobacter (Arthrobacter): ilex purpurea caused by ilicis;
20) bacterial diseases in plants caused by the genus Rhodococcus (Rhodococcus): sweet pea banding disease caused by fascians and the like;
21) bacterial diseases in plants caused by the genus Bacillus (Bacillus): bacillus megaterium (b.megaterium) induced leaf spot of bacillus zeae;
22) bacterial diseases in plants caused by the genus Rathaibacter (Rathayibacter): rathayi causes dactylosia.
Preferably, the plant fungal diseases are plant fungal diseases caused by any one or more of the following pathogenic bacteria 1) to 7):
1) pythium (Pythium), Phytophthora (Phytophthora), Phytophthora (sclerophora), peronophythora (perophthora), peronophythora (peronophytora), Albugo (Albugo), Peronospora (Peronospora), Pseudoperonospora (Pseudoperonospora), plasmopara (Plasmopora), stemphylium (Bremia), aureospora (Sclerospora) in Oomycetes (Oomycetes);
2) chytrium (Olpidium), chytrium (syncytium), chytrium (phynoderma) in chytrium (chydiycetes);
3) plasmodiophoromycetes (Plasmodiophoromycetes), sphaerotheca (Spongospora), Polymyxa (Polymyxa) among Plasmodiophoromycetes (Plasmodiophoromycetes);
4) puccinia (Puccinia), colletotrichum (gynosporangium), polyspora (Phragmidium), unicospora (Uromyces), Phakopsora (Phakopsora), corymbosa (Melampsora), Ustilago (Ustilago), Ustilago (Urocystis), Ustilago (Entyloma), triticale (Tilletia), Ustilago (sphacelotheca), eurotia (doassasiopsis), and ectomycosis (isobasidium) among Basidiomycetes (Basidiomycetes);
5) penicillium (Penicillium), Aspergillus (Aspergillus), Mycosphaerella (Mycosphaeralla), Encapsulated (Physiospora), Mycosphaerella (Guignardia), Staphyloccocus (Botryosphaeria), Venturia (Venturia), Erysiphe (Erysiphe), Sphaerotheca (Sphaerotheca), Blumeria (Blumeria), Sphaerotheca (Podosphaera), Sphaerotheca (Phyllantia), Sphaerotheca (Microsphaera), Uncaria (Uncaria), Rhynchophylla (Ceratocarpis), gibberella (Gibberella), humicola (Valsa), plexiglas (Glomerella), pustulosis (Polystima), ischium (Diaporthe), Elsinoe (Elsinoe), pyrenophora (Drechslera), Cochliobolus (Cochliobolus), Sclerotinia (sclerotiotinotia), soot (Capnodium), sphaerotheca (setospora), streptoverticillium (Monilinia), acrocarpus (Gaeumannomyces), ergothrips (Claviceps), botrytis (Pleospora);
6) pediobolus species (Monilinia), Botrytis, Microsporum species (Trichothecium), Cylindrocarpon species (Ramularia), Trichosporon species (Oidium), Pyricularia species (Pyricularia), Verticillium species (Verticillium), Cercospora species (Cercospora), Alternaria species (Alternaria), Cladosporium species (Cladosporium), Venerigeron species (Fusarium), Helicoveromyces species (Drecholera), Helicoveromyces species (Cochliobolus), Theobromyces species (Exophilum), Curvularia species (Curvularia), Pseudocercospora species (Pseudorhizospora), Phaeococcus species (Cordada), Thelephora species (Corynebacterium), Rhizoctonia species (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia ), Rhizoctonia (Rhizoctonia, or (Rhizoctonia, or a, Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, phoma (Phoma), Phoma (Phytolytica), Phoma (Macrophoma), Phomopsis (Phomopsis), Septoria (Septoria), Ascomyces (Valsa), Dichloropsis (Diplodia), Trichosporon (Ascochyta), Fusarium (Fusiococcum), Trichosporon (Coniella), Coniothyrium (Coniothyrium), Coccidium globosum (Botrydiplodia);
7) rhizopus (Rhizopus), dichocrochora (Choanephora) in Zygomycotina (Zygomycotina);
further preferably, the plant fungal diseases are selected from any one or more of the following fungal diseases 1) to 103):
1) fungal diseases of plants caused by Pythium (Pythium): cucumber rot caused by pythium aphanidermatum (P.aphanidermatum), cucurbit rot rape damping-off, soybean damping-off, cabbage damping-off, cauliflower damping-off, spinach damping-off, water spinach damping-off, vegetable soybean damping-off, beet root cluster disease, tobacco damping-off, cotton seedling damping-off, broccoli seedling damping-off, fennel damping-off, sunflower seedling rot, bitter gourd damping-off;
2) fungal diseases of plants caused by Phytophthora (Phytophthora): potato late blight, tomato late blight, phytophthora parasitica tobacco pathogenic type (p.parasitica var. nicotianae) tobacco black shank, phytophthora capsici (p.capsicii) pepper blight, phytophthora parasitica (p.nicotianae var. parasitica) pineapple heart rot, p.citrophthora induced citrus brown rot, p.fragaria induced strawberry red heart, phytophthora melonis (p.melonis) cucumber blight;
3) fungal diseases of plants caused by Phytophthora (Sclerophora): maize mad top disease caused by macropora;
4) plant fungal diseases caused by phytophthora parasitica (Peronophythora): downy blight of litchi caused by downy phytophthora litchi (p. litchii);
5) fungal plant diseases caused by white rust (Albugo): white rust of plants such as rape, Chinese cabbage and radish caused by white rust of Cruciferae white rust (A. Candida);
6) fungal diseases of plants caused by Peronospora (Peronospora): tobacco downy mildew caused by tobacco downy mildew (p.tabacina); downy mildew of Chinese cabbage caused by parasitic downy mildew (p. parasitica); downy mildew of soybean caused by downy mildew of northeast downy mildew (p.man-schurica);
7) fungal plant diseases caused by the genus Pseudoperonospora (Pseudoperonospora): downy mildew of melons such as cucumber and pumpkin caused by pseudoperonospora cubensis (p. cubensis);
8) fungal plant diseases caused by Plasmopora (Plasmopora): grapevine downy mildew caused by grapevine downy mildew (p.viticola);
9) fungal plant diseases caused by the genus stemphylium (Bremia): lettuce downy mildew caused by Bremia lactucae (B.lactucae);
10) fungal plant diseases caused by the genus stemphylium (Sclerospora): rhizopus graminicola (s.graminicola) causing the development of millet bloom;
11) fungal diseases of plants caused by the genus olea (Olpidium): a Vicia faba-Hui fungus fire swelling disease caused by Soy bean oil chytrid (O.vitae);
12) fungal plant diseases caused by the genus thraustochytrium (syncytrium): potato canceration caused by endophytic chytrium (s.endobioticum);
13) fungal plant diseases caused by the genus nodularia (phynoderma): zea mays (p. maydis) causes brown spot in corn;
14) fungal diseases of plants caused by Plasmodiophora (Plasmodiophora): plasmodiophora brassicae (p. brassicae) causes plasmodiophora brassicae;
15) plant fungal diseases caused by the genus eschar (Spongospora): potato powdery scab is caused by potato powdery scab bacteria (s. subterranean);
16) fungal plant diseases caused by Puccinia (Puccinia): wheat straw rust caused by puccinia graminis (p.graminis per. var. tritici);
17) fungal plant diseases caused by the genus phakopsora (Gymnosphaangium): pear rust caused by rust of pear gum (g. acanthom);
18) fungal plant diseases caused by the genus Puccinia (Phragmidium): rust disease of rose caused by rust of short-tipped polyspora (p. mucronatum);
19) fungal plant diseases caused by the genus rust (Uromyces): bean rust disease caused by p.verrucosa (u.apendiculus);
20) fungal plant diseases caused by Phakopsora (Phakopsora): jujube rust caused by multi-layer rust of jujube (P. ziziphi-vulgaris);
21) fungal plant diseases caused by the genus Graptosphaera (Melampsora): flax rust caused by m.lini;
22) fungal plant diseases caused by smut (Ustilago): wheat powdery mildew caused by wheat aleuromyces dispersus (U.tritici);
23) fungal plant diseases caused by the genus Ustilago (Urocystis): wheat straw smut caused by wheat smut (u.tritic);
24) plant fungal diseases caused by smut (Entyloma): smut of rice leaves caused by smut (e.oryzae);
25) plant fungal diseases caused by Tilletia (Tilletia): tilletia reticulata (T.caries) Tilletia foetida; rice smut caused by stinkbug-layana (t. barc-layana);
26) fungal plant diseases caused by axial smut (Sphacelootheca): sorghum smut caused by ustilago sorghum (s.cruenta);
27) plant fungal diseases caused by the genus nigrospora (Doassansiopsis): arrowhead smut caused by arrowhead smut (d.horiana);
28) fungal plant diseases caused by the genus Exobasidium (Exobasidium): tea cake disease caused by exobasidiomycetes (e.vexans);
29) fungal plant diseases caused by the genus Penicillium (Penicillium): citrus rot disease caused by penicillium italicum (p. italicum);
30) fungal plant diseases caused by Aspergillus (Aspergillus): fruit mildew rot caused by Aspergillus sp;
31) fungal diseases of plants caused by the genus Mycosphaerella (Mycosphaerella): citrus brown spot due to mycosphaerella citri (m.citri), cercospora cherry (m.cerasella), cercospora persimmon (m.nawae), cercospora peanut (m.berkeley), and cercospora peanut (m.arachidis);
32) fungal diseases of plants caused by the genus ascochyta (physiospora): peanut stem rot caused by citrus ascospora chrysosporium (physospora rhodotina), grape house blight caused by botrytis cinerea (p.baccae), and ring rot of pear tree, apple, peach, plum and apricot caused by ascospora chrysosporium (physospora sp);
33) fungal plant diseases caused by globulus (Guignardia): grape black rot caused by ascosphaera botrytis (G.biwellii), and leaf blight of tea caused by G.camelliae;
34) fungal plant diseases caused by plasmodiophora (Botryosphaeria): apple white rot and blueberry stem blight caused by globispherea sp, peach gummosis, peach branch withering, grape canker and grape branch blight caused by botrytis sp;
35) fungal plant diseases caused by the genus Venturia (Venturia): black spot disease of pear caused by black bean fungus (v.pirina), and black spot disease of peach caused by black bean fungus (v.carpopocilum);
36) fungal diseases of plants caused by powdery mildew (Erysiphe): powdery mildew of cereal caused by powdery mildew (e.graminis), powdery mildew of cabbage caused by powdery mildew (e.cruciferae);
37) fungal plant diseases caused by the genus Sphaerotheca (Sphaerotheca): powdery mildew of melons and beans caused by cucurbit unisporum powdery mildew (s.furiginea);
38) plant fungal diseases caused by erysiphe (Blumeria): powdery mildew of gramineous plants caused by powdery mildew of gramineous powdery mildew (b.graminis);
39) fungal plant diseases caused by the genus aphanotheca (Podosphaera): powdery mildew of crab apple, plum and apple caused by P.leucotricha;
40) fungal diseases of plants caused by the genus Stropharia (Phyllantia): powdery mildew caused by P.chrysosporium (P.chrysosporium) such as chestnut, papaya, phoenix tree, pear, persimmon, walnut, etc.;
41) fungal plant diseases caused by the genus aphanidermia (microphaga): berberis powdery mildew caused by sphaerotheca berberidis (m.berberidicola), and aristolochia debilis caused by sphaerotheca aristolochiae (m.aristolochiae);
42) fungal plant diseases caused by the genus Uncinula (Uncinula): grape powdery mildew caused by leptospira vitis (u.necator);
43) fungal diseases of plants caused by the genus Ceratocystis (Ceratocystis): sweet potato black spot disease caused by sweet potato chayote (C.fimbriata) and sugarcane pineapple disease caused by paradoxa (C.paradoxa);
44) fungal plant diseases caused by the genus Gibberella (Gibberella): gibberella zeae (g.zeae) causes wheat scab, gibberella granatum (g.jikuroi) causes rice bakanae disease;
45) fungal plant diseases caused by the genus Humicola (Valsa): apple tree rot caused by apple humicola (v.mali);
46) fungal plant diseases caused by the genus Lepidium (Glomerella): anthracnose of fruit trees caused by cingulata;
47) fungal diseases of plants caused by furunculosis (Polystima): red spot disease of plum caused by plum furunculosis (Polystigma rubrum);
48) fungal plant diseases caused by Diaporthe (Diaporthe): citrus gummosis caused by citrus intercropping fungus (d.citricola), sweet potato dry rot caused by sweet potato intercropping fungus (d.batatatis), soybean northern stem canker caused by kidney bean intercropping fungus (d.phaseolorum var.caulivora), apple hypocotyl (d.pomigena) causes apple black spot disease;
49) plant fungal diseases caused by Elsinoe (Elsinoe): vitis vinifera anthracnose caused by Elsinoe ampelina (E.ampelina);
50) fungal plant diseases caused by Pyrenophora (Drechslera): wheat stripe disease caused by wheat sclerotinia (d.graminea);
51) plant fungal diseases caused by the genus Cochliobolus (Cochliobolus): wheat root rot caused by colletotrichum gloeosporioides (c.sativas);
52) fungal diseases of plants caused by Sclerotinia (sclerotiotinia): sclerotinia rot of colza and cucumber caused by sclerotinia sclerotiorum (s.sclerotiorum);
53) fungal diseases of plants caused by soot (Capnodium): citrus sooty mould, hawthorn sooty mould, tea mould and mango mould caused by citrus bituminous coal pathogen (c.citri);
54) fungal plant diseases caused by the genus phyllosphaeria (setosperia): northern leaf blight of maize caused by sitophila macrosperma (s.turcicaca);
55) fungal plant diseases caused by the genus streptomyces (Monilinia): brown rot of apple, pear, peach caused by sclerotinia sclerotiorum (m.fructicola);
56) fungal plant diseases caused by the genus Gaeumannomyces (Gaeumannomyces): cereal and wheat take-all caused by gaeumannomyces graminis variety (g.graminis var. graminis), gaeumannomyces graminis variety (g.graminis (Sacc.) arxet oliver var. tritici);
57) fungal diseases of plants caused by the ergot genus (Claviceps): ergot (c. purpurea) graminis;
58) fungal plant diseases caused by the genus botrytis (Pleospora): tomato gray leaf spot caused by tomato botrytis cinerea (p.lycopersici), and chive leaf blight caused by onion blight (p.herbarum);
59) fungal plant diseases caused by the genus aureobasidium (Monilinia): apple and pear brown rot caused by aureobasidium reniformis (M.fructigena), peach brown rot and apricot brown rot caused by M.laxa;
60) fungal diseases of plants caused by Botrytis (Botrytis): botrytis cinerea (b.cinerea) causes botrytis cinerea, cucumber gray mold, pepper gray mold, grape gray mold, and apple gray mold;
61) fungal plant diseases caused by the genus polyporus (Trichothecium): maize polyporus pinus head rot caused by polyporus pinus (t. roseum);
62) fungal plant diseases caused by the genus septoria (Ramularia): cotton vitiligo caused by exosporium leucotrichum (r. areola);
63) fungal plant diseases caused by the genus Trichosporon (Oidium): lycium barbarum powdery mildew caused by Oidium sp, tomato powdery mildew caused by tomato powdery mildew (o.lycopersic);
64) fungal diseases of plants caused by Pyricularia (Pyricularia): pyricularia oryzae (P.oryae) caused by Pyricularia oryzae;
65) fungal plant diseases caused by Verticillium (Verticillium): verticillium wilt of cotton and verticillium wilt of eggplant caused by verticillium dahliae (V.dahliae);
66) fungal diseases of plants caused by Cercosporella (Cercosporella): white spot disease of Chinese cabbage caused by Cercospora leucoderma (C.albo-maculans);
67) fungal diseases of plants caused by Cercospora (Cercospora): cercospora arachidicola (c.arachidicola) induced peanut brown spot disease, Cercospora colata (c.beticola) induced sugar beet brown spot disease, Cercospora sp, etc. induced oriental cherry brown spot disease, clove brown spot disease, osmanthus fragrans leaf spot disease, azalea leaf spot disease;
68) fungal plant diseases caused by Alternaria (Alternaria): alternaria apple specialization (a. Alternaria f. sp mali) induced Alternaria leaf spot, a. solani induced tomato early blight, a. alternata induced tobacco brown spot, Alternaria sp induced cotton ring spot, apple brown spot, Alternaria late blight, almond root rot, radish black spot;
69) fungal plant diseases caused by Cladosporium (Cladosporium): cucumber scab caused by cladosporium cucumerinum (c. cucumerinum);
70) plant fungal diseases caused by the genus nigrospora (fusarium): pear scab caused by black bean fungus (Fusicillarium virecens);
71) fungal plant diseases caused by helmholysis (Drechslera): barley net blotch caused by helminthosporium cucumerinum (d. teres);
72) fungal plant diseases caused by helminthosporium peregrinum (Cochliobolus): leaf spot of rice flax caused by helminthosporium oryzae (c.miyabenus);
73) fungal plant diseases caused by helminthosporium (Exserohilum): northern leaf blight of corn caused by eurotium megamaculatum (e.turcicum);
74) fungal diseases of plants caused by Curvularia (Curvularia): leaf spot of Curvularia lunata caused by Lunata;
75) fungal plant diseases caused by Pseudocercospora (Pseudocercospora): sigatoka caused by pseudocercospora banana (p.musae), sigatoka caused by pseudocercospora fijiensis (p.fijiensis), cercospora viticola (p.vitis);
76) fungal plant diseases caused by the genus Lawsonia (Cordana): banana gray streak disease caused by banana dim spore (c.musae);
77) fungal diseases of plants caused by Stemphylium (stemphyllium): rhizopus solanacearum (s.solani) tomato gray leaf spot disease, and phoma termatamum leptopodum (s.botryosum) induced leaf blight of chive;
78) plant fungal diseases caused by the genus trichoderma (Fulvia): tomato leaf mold and pepper leaf mold caused by fulvia fulva (f.fulva);
79) fungal plant diseases caused by corynebacterium (Corynespora): cucumber brown spot disease caused by cucumber brown spot pathogen (Corynespora cassiicola);
80) fungal diseases of plants caused by Rhizoctonia (Rhizoctonia): rhizoctonia solani (r.solani) induced sheath blight of rice, cucumber rhizoctonia solani;
81) fungal diseases of plants caused by sclerotium (Selerotium): oil tea, Aleurites fordii, catalpa bungei, citrus, apple, phoenix tree, paulownia, walnut, masson pine, peanut, pepper, shallot southern blight caused by sclerotium rolfsii (Selerotium rolfsii);
82) fungal plant diseases caused by Fusarium (Fusarium): fusarium oxysporum cucumber fusarium wilt caused by cucumber specialization (f.oxysporum f.sp.cucumerium), cotton fusarium wilt caused by fusarium oxysporum wilting specialization (f.oxysporum f.sp.vassifnfectium), and fusarium graminearum caused by fusarium graminearum;
83) fungal plant diseases caused by the genus sclerotium virescens (Ustilaginoidea): rice false smut caused by sclerotinia graminicola (u.oryzae);
84) plant fungal diseases caused by the genus Sphaceloma (Sphaceloma): grape anthracnose caused by Stachybotrys scaber (S.ampelium), citrus scab caused by Stachybotrys citricola (S.fawcettii), solanaceous vegetable scab, pomelo scab and peanut scab caused by Sphaceloma sp;
85) plant fungal diseases caused by Colletotrichum (Colletotrichum): grape anthracnose caused by Colletotrichum gloeosporioides (c.orbiosporioides), cucurbitaceae Colletotrichum sp, oats, brome, orange, citrus, apple, banana, pea, bean, cabbage, melon, sugar beet, tea, tobacco and sugarcane anthracnose;
86) fungal plant diseases caused by discorea (Marssonina): cercospora leaf spot of apple caused by diplospora piricola (m.mali);
87) fungal diseases of plants caused by ray-spores (Actinonema): rosae-induced melasma roseoflavae;
88) fungal plant diseases caused by Pestalotia (Pestalotia): tea leaf spot caused by pestalotiopsis chaetosa (p. theta.);
89) fungal plant diseases caused by discothrix (Gloeosporium): tea anthracnose caused by theasinesis;
90) fungal diseases of plants caused by Phoma (Phoma): brassica napus black shank caused by phoma nigricans (p.lingam);
91) fungal diseases of plants caused by the genus Phyllosticta (Phyllosticta): cotton brown spot caused by cotton lobular spot mould (p. gossypina);
92) fungal diseases of plants caused by the genus Macrophoma (Macrophoma): ring spot disease of apple, pear, etc. caused by large stem of ring spot (m.kuwatsukai);
93) fungal diseases of plants caused by Phomopsis (Phomopsis): pseudophomopsis solanacearum (p. vexans);
94) plant fungal diseases caused by Septoria (Septoria): wheat glume blight caused by septoria nodorum (s.nodorum);
95) fungal plant diseases caused by ascochyta (Valsa): pear tree rot caused by apple black hull pear variety (v.mali var. pyri);
96) fungal plant diseases caused by the species Diplodia (Diplodia): cotton boll melanosis caused by cotton bicells (Diplodia gossypina);
97) fungal diseases of plants caused by Ascochyta (Ascochyta): cucumber gummy stem blight caused by Ascochyta cucumis (Ascochyta cucumis);
98) fungal plant diseases caused by Fusarium (Fusicoccum): vine blight caused by Fusarium botrytis (F. viticola);
99) fungal plant diseases caused by the genus Microcospora (Coniella): grape white rot caused by colletotrichum solani (c. diplodiella);
100) fungal plant diseases caused by Coniothyrium (Coniothyrium): white rot of grape caused by Coniothyrium dipnodiella;
101) plant fungal diseases caused by globisporus (Botryodiplodia): mango rot caused by theobromae;
102) fungal diseases of plants caused by Rhizopus (Rhizopus): sweet potato soft rot caused by rhizopus stolonifer (r.stolonifer);
103) fungal diseases of plants caused by Choanephora (Choanephora): rotten flowers or young fruits of melons caused by Choanephora sp, rotten organs of seeds and bulbs in the storage period, rotten soft tissues of flowers and trees (calamus glauca corms and purple goldenrod roots), rotten soft tissues of strawberries and soft rot diseases of melons.
The invention also provides a preparation method of the agricultural bactericide, which is characterized in that the agricultural bactericide is prepared by reacting alkali, 1, 2-benzisothiazol-3 (2H) -one and zinc salt in water without organic solvent.
Preferably, in the method for preparing the agricultural fungicide, the method comprises the following steps:
sequentially adding water, alkali and 1, 2-benzisothiazol-3 (2H) -ketone into a reaction vessel, then dropwise adding a zinc salt water solution, stirring and reacting for 1-5 hours at the temperature of room temperature to 100 ℃, separating out crystals, filtering, washing and drying to obtain the agricultural bactericide.
Preferably, in the above method for producing an agricultural fungicide, the alkali is an inorganic alkali or an organic alkali; further preferred is an aqueous solution of sodium hydroxide, potassium hydroxide, ammonia water, or trimethylamine.
Preferably, in the above method for preparing an agricultural fungicide, the zinc salt is a water-soluble zinc salt; further preferred is zinc sulfate, zinc chloride or zinc acetate containing crystal water or anhydrous.
Preferably, the method for producing an agricultural fungicide according to the above aspect is characterized in that the ratio of the base: 1, 2-benzisothiazol-3 (2H) -one: zinc salt is 1 to 5: 1; further preferably 2 to 3: 1.
The invention also provides a preparation containing the agricultural bactericide, which is characterized by comprising the agricultural bactericide and an auxiliary agent for pesticide, wherein the agricultural bactericide in the preparation accounts for 0.1-90% of the preparation by mass.
Preferably, the agricultural fungicide is prepared into the dosage forms of powder, granules, water dispersible granules, wettable powder, oil dispersible powder, emulsion powder, suspending agent, microcapsule suspending agent, dispersible oil suspending agent, suspoemulsion and smoke agent; further preferably, the formulation is a suspension, an aqueous dispersion or a wettable powder.
The invention has the advantages of
1. The invention provides a brand-new agricultural bactericide, and confirms the structure of the bactericide, the agricultural bactericide is environment-friendly and low in toxicity, and the amount of organic matters actually used in the process of preventing and treating diseases in agriculture is low.
2. The invention also provides a preparation method of the novel agricultural bactericide, wherein the preparation method uses a reaction system which does not contain any organic solvent, no organic waste is generated in the preparation method, and the production process of the product does not pollute the environment.
3. The agricultural bactericide provided by the invention has excellent effect of preventing and treating crop diseases, long action duration, safety to crops and low residue.
Drawings
FIGS. 1a and 1b are single crystal X-ray diffraction patterns of the agricultural fungicide of example 1
FIG. 2 is a powder X-ray diffraction chart of the agricultural fungicide of example 1
FIG. 3 is a powder X-ray diffraction pattern of single crystal data simulation of the agricultural fungicide of example 1
Detailed Description
EXAMPLE 1 preparation of agricultural fungicides
100.0g of water, 8.0g of sodium hydroxide and 30.2g of 1, 2-benzisothiazol-3 (2H) -one are sequentially added into a 500mL three-neck flask, stirred, heated to 50 ℃, then an aqueous solution containing 16.1g of zinc sulfate is dropwise added, after the dropwise addition is finished, the reaction is stirred for 2 hours, the reaction is finished, cooled, crystallized and filtered, and then the mixture is washed by a small amount of water and dried to obtain a white solid product (hereinafter referred to as an example 1 bactericide), wherein the yield is 92%.
Example 2 single crystal X-ray diffraction analysis of the germicide of example 1
The agricultural fungicide of example 1 was subjected to single crystal X-ray diffraction detection and collected at 170K using a Bruker D8 Venture single crystal diffractometer using a wavelength of 0.71073 (MoK)α) The obtained single crystal X-ray diffraction pattern is shown in the attached figure 1a and figure 1b, and the crystallographic data and parameters are as follows:
wherein a, b and c are the side lengths of the unit cells; α, β and γ are the angles of the unit cell; z is the number of molecules in the unit cell.
Based on the single crystal X-ray diffraction pattern and crystallographic data and parameters described above, the chemical structure of the fungicide of example 1 was determined to be either formula I or formula II as follows:
wherein the probability of the presence of formula I and formula II is 81.5% and 18.5%, respectively.
In the chemical structures of formula I and formula II, one ligand (C8-C14, S2, N2, O2) is in a crystallographically disordered state, in formula I, O2 is coordinated with Zn2, N2 is coordinated with Zn1, in formula II, O2A is coordinated with Zn1, and N2A is coordinated with Zn 2.
Example 3 powder X-ray diffraction analysis of the germicides of example 1
The agricultural fungicide of example 1 was subjected to powder X-ray diffraction detection, and the powder X-ray diffraction data were collected on a PNanalytical X' Pert PRO diffractometer at an operating voltage of 40kV and a current of 40mA, using Cu-K at 25 deg.CαRadiation of radiation
The powder X-ray diffraction pattern recorded is shown in fig. 2, and the characteristic data are as follows:
the X-ray diffraction pattern of the powder obtained by simulating the single crystal data of the example 2 by using the software Mercury 4.1.3 is shown in the attached figure 3; the powder X-ray diffraction pattern obtained by actual measurement (FIG. 2) was consistent with the powder X-ray diffraction pattern obtained by simulation of single crystal data (FIG. 3).
EXAMPLE 45% preparation of the Fungicide suspending agent of example 1
5% of the bactericide in the embodiment 1, 3% of fatty alcohol-polyoxyethylene ether, 4% of macromolecular polycarboxylate, 5% of propylene glycol, 0.1% of xanthan gum, 1% of magnesium aluminum silicate, 0.1% of organic silicon defoamer, 0.1% of cason and 100% of deionized water are supplemented to be fully mixed, the mixture is put into a high-shear homogeneous emulsifier to be subjected to high-speed shearing coarse grinding and homogenization, then the mixture is pumped into a sand mill to be subjected to sand grinding to a certain particle size, and the 5% of the agricultural bactericide suspending agent in the embodiment 1 is obtained after filtration.
Example 5 preparation of agricultural fungicides Using solutions containing organic solvents
According to the preparation method of Paraloyd leaves (fine chemical engineering, vol. 29, No. 7, 2012), benziothiazolinone (0.2mmol, 0.0302g) was dissolved in CH2Cl2(5mL) and filtered to the bottom of the tube and Zn (CH) is added3COO)2·2H2O (0.2mmol, 0.044g) in CH3OH (5mL), filtering, laying the filtrate on the upper layer of the benziothiazolinone solution, sealing, standing at room temperature, separating out a white solid after 14 days, collecting the white solid, and washing with absolute ethyl alcohol and acetone to obtain the comparative bactericide A.
According to the preparation method of the patent (application No. 201810149359.3) example 5, 4.0kg of cyclohexanone is added into a 10L glass reaction kettle, stirring is started, 0.227kg of zinc chloride, 0.227kg of water and 1.25kg of benziothiazolinone are added, the kettle temperature is raised to 95 ℃, water is separated out, after the kettle temperature is raised to 156 ℃, the temperature is reduced to 30 ℃ after no water drops in a water separator are determined; filtering, wherein the filter cake contains unreacted benziothiazolinone, pulping and washing the filter cake with 2.0kg cyclohexanone, filtering, repeating the process once, merging and concentrating the mother liquor and the washing liquor, then mechanically applying the mother liquor and the washing liquor to the reaction solution, feeding the mother liquor and the washing liquor in proportion, and drying the filter cake to obtain the comparative bactericide B.
According to the preparation method of example 2 of the patent (application No. 201910173745.0), 2mmol of benziothiazolinone and 1mmol of zinc chloride were weighed out in a ratio of 2: 1. Benziothiazolinone was dissolved in 10mL of DMF, and zinc chloride was dissolved in a mixed solution of 5mL of distilled water and 5mL of anhydrous methanol. Dropwise adding a zinc chloride solution into a benziothiazolinone solution at the temperature of 45 ℃, adjusting the pH to about 8.0 by using triethylamine, carrying out magnetic stirring reaction for 1h, gradually turbidity the clear transparent solution, cooling, standing to obtain a white solid, carrying out suction filtration, washing by using a small amount of water and ethanol, and drying to obtain the comparative bactericide C.
EXAMPLE 6 indoor Activity measurement test of Fungicide in example 1
Example 1 determination of the activity of fungicides on phytopathogenic eubacteria 6 representative species were selected: cabbage soft rot (Erwinia carotovora subsp. carotovora), citrus canker (Xanthomonas axonopodis pv. citri), rice leaf blight (Xanthomonas oryzae pv. oryzae), rice blast (Pyricularia oryzae), cucumber Colletotrichum (Colletotrichum orbiculata) and cucumber gray mold (Botrytis cinerea). The fungicide of example 1 and the control agent benziothiazolinone were prepared as 5% suspension for testing, as described in example 4. The indoor activity determination test method of the plant pathogenic bacteria refers to part 16 of indoor bioassay test criteria bactericides of NY/T1156.16-2006 pesticide: turbidity method for bacterial growth inhibition test; the indoor activity determination test method of the plant pathogenic fungi refers to part 2 of indoor bioassay test criteria bactericides of NY/T1156.2-2006 pesticide: the plate method of pathogenic fungus hypha growth inhibition test. The results are detailed in tables 1-6 below, wherein: inhibition was mean ± standard deviation, and significance analysis of differences was performed using SPSS 19.0 independent sample T test.
TABLE 1 indoor Activity measurement results of the Fungicide on Soft rot of Chinese cabbage
TABLE 2 indoor Activity measurement results of Fungicide for Citrus canker
TABLE 3 indoor Activity measurement results of Fungicide on Paddy rice bacterial blight
TABLE 4 indoor Activity measurement results of fungicides on Pyricularia oryzae
TABLE 5 indoor Activity measurement results of Fungicide on cucumber colletotrichum
TABLE 6 indoor Activity measurement results of Fungicide for Botrytis cinerea
Example 7 field Activity assay test for the fungicides of example 1
Control subjects and targets:
soft rot of green vegetables, the test crop is green vegetables, and the variety is Shanghai green.
The conditions of the test were as follows:
the place is located in a greenhouse of a base of the Xian Ju Sheng measuring center in Zhejiang province. The row spacing of the green vegetable planting plants is 0.15 m multiplied by 0.2m, and a simple plastic greenhouse is arranged in the greenhouse. The soil quality of the test soil is loam, the pH value is 5-7, the soil fertility is high, and the organic matter content is about 1.3 wt%.
Test agents:
5% example 1 biocide suspension: supplied by Zhejiang New Agrochemical Productwork, Inc. (i.e., prepared by example 4);
control agents:
5% comparative fungicide a suspension: supplied by Zhejiang New agro-chemical industries, Ltd;
5% comparative biocide B suspension: supplied by Zhejiang New agro-chemical industries, Ltd;
5% comparative fungicide C suspension: supplied by Zhejiang New agro-chemical industries, Ltd;
5% benziothiazolinone suspension: supplied by Zhejiang New agro-chemical industries, Ltd;
20% zinc thiazole suspension: manufactured by Zhejiang New agro-chemical industries, Ltd;
the auxiliary agent varieties and the contents of the 5% bactericide suspending agent of the embodiment 1, the 5% contrast bactericide A suspending agent, the 5% contrast bactericide B suspending agent and the 5% contrast bactericide C suspending agent are the same, and the preparation methods of the suspending agents are the same.
The treatment numbers and the amounts of each agent are shown in table 7 below.
TABLE 7 test agent dosage and test treatment
| Processing number | Medicament | Dilution factor | Concentration of active ingredient (mg/L) |
| K1 | 5% example 1 Fungicide suspension | 625 | 80 |
| K2 | 5% control fungicide A suspension | 625 | 80 |
| K3 | 5% control fungicide B suspension | 625 | 80 |
| K4 | 5% control fungicide C suspension | 625 | 80 |
| K5 | 5% Thiothiazolinone suspension | 625 | 80 |
| |
20% zinc thiazole suspending agent | 400 | 500 |
| K7 | Clear water Contrast (CK) | — | — |
Three replicates of each treatment were processed, each 8 square meters. The spray method is adopted to uniformly spray each treatment agent on the whole green vegetable plant until the green vegetable plant is wet and is to be dropped. The pesticide applying apparatus adopts a knapsack electric sprayer, the working pressure of the sprayer is about 0.2-0.4MPa, the caliber of a spray hole is 1.2mm, and the water spraying amount per minute is 1.1L. The test is carried out by applying the medicine once respectively on 27 days 12 and 27 months in 2019, 04 days 01 and 11 months in 2020, and applying the medicine 3 times in total. The water consumption is 900L/hm2The disease did not occur before the first time of the test, and the number of the predose bases was 0. The first disease investigation was conducted 7 days (18 days at 01 month) after the third dose, and the second disease investigation was conducted 14 days (25 days at 1 month) after the third dose. During investigation, all plants are investigated in each cell, the total number of plants and the number of plants with diseases are recorded, and the disease incidence and the prevention and treatment effect are calculated. The specific calculation method is as follows:
incidence (%) ═ incidence/total investigated strains 100
Control effect (%) ═ disease rate (incidence in placebo area-incidence in treated area)/incidence in placebo area) × 100
The specific test results obtained according to the above experiments are shown in table 8 below.
TABLE 8 test results of the bactericide for preventing and treating soft rot of vegetables
As can be seen from the test data in table 8, the effect of the bactericide suspending agent in example 1 on preventing soft rot of green vegetables is higher than that of benziothiazolinone, and the bactericide suspending agent in example 1 has at least 10% higher prevention effect than the comparative bactericide a suspending agent, the comparative bactericide B suspending agent and the comparative bactericide C suspending agent prepared from organic solvent, and the prevention effect is increased by 11.5-25.1%.
Claims (22)
1. An agricultural fungicide, characterized in that the agricultural fungicide has a chemical structure as shown in formula I or formula II below:
wherein the sum of the probability of the formula I and the probability of the formula II is 100%, the probability of the formula I is X, the probability of the formula II is Y, X is 1-99%, and Y is 1-99%.
2. An agricultural fungicide according to claim 1 characterized in that it has crystallographic data and parameters characterized as follows:
wherein a, b and c are the side length of the unit cell; α, β, γ are angles of the unit cell; z is the number of molecules in the unit cell;
in the chemical structure of the formula I or the formula II, one ligand (C8-C14, S2, N2 and O2) is in a crystallographically disordered state, in the formula I, O2 is coordinated with Zn2, N2 is coordinated with Zn1, in the formula II, O2A is coordinated with Zn1, and N2A is coordinated with Zn 2.
3. Use of the agricultural fungicide according to any one of claims 1 to 2, characterized in that the use is the use of the agricultural fungicide according to any one of claims 1 to 2 for controlling bacterial diseases or fungal diseases of plants.
4. Use according to claim 3, characterized in that the plant bacterial disease is caused by Pseudomonas (Pseudomonas), Xanthomonas (Xanthomonas), Agrobacterium (Agrobacterium), Erwinia (Erwinia), Pantoea (Pantoea), Pectibacterium (Pectibacter), Burkholderia (Burkholderia), Ralstonia (Ralstonia), Acidovorax (Acidovorax), Microbacterium xylinum (Xylella), Brevibacterium (Liberobacter), Enterobacter (Enterobacter), Rhizobacter), Xylophilus (Xylophilus), Dicke (Dicke), Corynebacterium (Clavibacterium), Streptomyces (Epetomyces), Brevibacterium (Bacillus), Arthrobacter (Arthrobacter), Rhodococcus (Rhodococcus), Rhodobacter (Streptomyces), or Bacillus (Bacillus).
5. Use according to claim 3, characterized in that the plant bacterial diseases are selected from any one or more of the following bacterial diseases 1) to 22):
1) bacterial diseases in plants caused by the genus Pseudomonas (Pseudomonas): bacterial blight of rice caused by pseudomonas glumae (p. glumae); bacterial black spot of capsicum caused by pseudomonas aeruginosa (p.syringae var. capsicii); cucumber bacterial angular leaf spot and cucumber bacterial angular leaf spot caused by pseudomonas syringae lachrymans (p. syringae pv. lachrymans); tobacco wildfire caused by pseudomonas syringae tobacco pathogenic variant (p.syringae pv. tabaci); kiwifruit canker disease caused by syzygium aromaticum pseudomonas pvt. actinoniae; kiwi fruit floral rot caused by pseudomonas (p. viriflava); bacterial medullary necrosis of tomato, pseudomonitis of tomato caused by pseudomonas winkle (p.corrugate); bacterial leaf spot disease in tomato caused by pseudomonas syringae tomato pathogenic variety (p.syringae pv. tomato); pseudomonas syringae is suitable for pepper bacterial leaf spot caused by pathotype (p.syringae pv. aptata); broccoli head rot caused by fluorescent pseudomonads (p.fluoroscens); bacterial black spot of rape caused by pseudomonas syringae var maculata (p. syringae pv. maculicola); bacterial angular leaf spot of sesame caused by pseudomonas syringae sesame cultivar (p.syringae pv. sesami); bacterial brown spot in corn caused by pseudomonas oryzae (p.oryzihabituans); broad bean bacterial stem blight caused by pseudomonas fasuensis (p.fabae); bacterial leaf spot disease in soybean caused by pseudomonas stutzeri soybean pathogenic variant (p. savastanoi pv. glycinea); bacterial leaf blight of sugar beet caused by pseudomonas solanacearum (p.aptata); pseudomonas aeruginosa (p. aeruginosa) causes ginseng pseudomonas aeruginosa soft rot;
2) bacterial diseases in plants caused by Xanthomonas (Xanthomonas): bacterial blight of rice caused by xanthomonas oryzae pathovar oryzae (x. oryzae pv. oryzae); bacterial leaf streak of rice caused by xanthomonas oryzae germinal pathogenic variant (x. oryzae pv. oryzae) and; citrus canker disease caused by xanthomonas citri (x.citri subsp.citri); peach bacterial perforosis caused by xanthomonas arborescens peach pathogenic variants (x. arboricola pv. prune); brassicaceae black rot caused by Xanthomonas campestris pathogenic variety X.campestris pv. campestris; watermelon spot disease caused by Xanthomonas glycanorrhoeae (X.campestis pv. cucurbitae); bacterial scab of tomato and pepper caused by Xanthomonas campestris pepper spot pathogenic variety (X.campestis pv. vesicatoria); bacterial black spot disease in mango caused by xanthomonas campestris mango pathovar (x. campestis pv. mangifereae); bacterial leaf spot of pepper caused by xanthomonas campestris piperis pathogenic variety (x. campestis pv. betuliola); bacterial blight of poinsettia caused by xanthomonas campestris poinsettia pathovar x.campesticola (pv. poinsetticola); cotton angular leaf spot caused by xanthomonas carpi mallow pathogenic variety (x. axonopodis pv. malvacearum); soybean bacterial leaf spot disease caused by Xanthomonas carpi soybean pathogenic variety (X.axonopodis pv. glycines); bacterial wilt of cassava caused by Xanthomonas carpi (X. axonopodis pv. manihot); anthurium bacterial blight caused by Xanthomonas carpi Huanyanqing pathogenic variety (X.axonopodis pv. dieffenbachiae); strawberry angular leaf spot caused by xanthomonas strawberrii (x. fragariae);
3) bacterial diseases in plants caused by the genus Agrobacterium (Agrobacterium): watermelon bacterial crown gall and rosaceous root cancer caused by agrobacterium tumefaciens (a. tumefaciens); melon bacterial hairy root disease caused by agrobacterium rhizogenes (a. grobacter tumefaciens);
4) bacterial diseases in plants caused by Erwinia (Erwinia): clearing away erwinia amylovora (E.amylovora) caused pear fire blight; bacterial basal rot of rice caused by erwinia maize cultivar (e.chrysanthemi pv. zeae); erwinia carotovora soft rot disease of cruciferae, soft rot disease of watermelon and soft rot disease of onion caused by erwinia carotovora subsp carotovora; watermelon wilt disease caused by erwinia avicularis (e.tracheiphila);
5) bacterial diseases in plants caused by Pantoea (Pantoea): pantoea zeae leaf spot caused by Pantoea ananatis (P.ananatis); bacterial leaf blight of red bean caused by Pantoea agglomerans (P.agglomerans);
6) bacterial diseases in plants caused by the genus Pectobacterium (Pectibacter): tomato soft rot and pepper soft rot caused by pectobacterium carotovorum subsp. Soft rot disease of potato caused by p.carotovorum subsp.brasiliensis; potato black shank caused by p.atrosepticum;
7) bacterial diseases in plants caused by Burkholderia (Burkholderia): onion bulb rot disease caused by burkholderia cepacia (b.cepacia); bacterial spike blight of rice caused by burkholderia glumae (b.glumae); bacterial wilt of dianthus caryophyllus caused by burkholderia malabarica (b. caryophyli);
8) bacterial diseases in plants caused by the genus Ralstonia (Ralstonia): potato bacterial wilt, tomato bacterial wilt, pepper bacterial wilt and watermelon bacterial wilt caused by Laurella sp.solanacearum;
9) bacterial diseases in plants caused by Acidovorax (Acidovorax): bacterial fruit rot of melons caused by acidovorax citrulli (a. citrulli); bacterial brown streak disease in rice caused by oat acidovorax avenae subsp.
10) Bacterial diseases in plants caused by xylaria (Xylella): grapevine dermatosis caused by xylella fastidiosa (x.fastidiosa);
11) bacterial diseases in plants caused by the genus of the genus Liberobacter: citrus yellow shoot caused by asian (l.asiaticus), african (l.africanus), american (l.americanus);
12) bacterial diseases in plants caused by the genus Enterobacter (Enterobacter): yellowing disease in papaya fruits caused by enterobacter cloacae (e.cloacae); poplar wilt disease caused by enterobacter carcinogens (e.cancerogenus);
13) bacterial diseases in plants caused by the genus rhizobacterium (Rhizobacter): carrot gall disease caused by daucus;
14) bacterial diseases in plants caused by the genus Xylophilus (Xylophilus): grape canker disease caused by ampelinus;
15) bacterial diseases in plants caused by dikaya (Dickeya): bacterial stalk rot in maize caused by d.zeae; sweet potato stem rot caused by daldantii (d.dadantii); potato black shank caused by diskettsia solanacearum (d.solani); erwinia rust disease caused by daldikaea (d. fangzhongdai);
16) bacterial diseases in plants caused by the genus Clavibacter (Clavibacter): potato ring rot disease caused by clavibacter michiganensis subsp. Tomato canker disease caused by clavibacter michiganensis subsp.
17) Bacterial diseases in plants caused by the genus Streptomyces (Streptomyces): potato scab caused by streptomyces scab (s.scabies);
18) bacterial diseases in plants caused by the genus brevibacterium (Curtobacterium): bean wilt caused by Bacillus pumilus wilt pathogenic variety (C. flaccumfaciens pv. flaccumfaciens); bacterial leaf spot of beet caused by Bacillus pumilus beet pathogenic variant (C. flaccumfaciens pv. bet); tulip yellow bleb spot caused by bacillus pumilus austenic variant (c. flaccumfaciens pv. orctii);
19) bacterial diseases in plants caused by Arthrobacter (Arthrobacter): ilex purpurea caused by ilicis;
20) bacterial diseases in plants caused by the genus Rhodococcus (Rhodococcus): sweet pea banding disease caused by fascians;
21) bacterial diseases in plants caused by the genus Bacillus (Bacillus): bacillus megaterium (b.megaterium) induced leaf spot of bacillus zeae;
22) bacterial diseases in plants caused by the genus Rathaibacter (Rathayibacter): rathayi causes dactylosia.
6. The use according to claim 3, characterized in that the plant fungal diseases are plant fungal diseases caused by one or more pathogenic bacteria selected from the group consisting of 1) to 7) below:
1) pythium (Pythium), Phytophthora (Phytophthora), Phytophthora (sclerophora), peronophythora (perophthora), peronophythora (peronophytora), Albugo (Albugo), Peronospora (Peronospora), Pseudoperonospora (Pseudoperonospora), plasmopara (Plasmopora), stemphylium (Bremia), aureospora (Sclerospora) in Oomycetes (Oomycetes);
2) chytrium (Olpidium), chytrium (syncytium), chytrium (phynoderma) in chytrium (chydiycetes);
3) plasmodiophoromycetes (Plasmodiophoromycetes), sphaerotheca (Spongospora), Polymyxa (Polymyxa) among Plasmodiophoromycetes (Plasmodiophoromycetes);
4) puccinia (Puccinia), colletotrichum (gynosporangium), polyspora (Phragmidium), unicospora (Uromyces), Phakopsora (Phakopsora), corymbosa (Melampsora), Ustilago (Ustilago), Ustilago (Urocystis), Ustilago (Entyloma), triticale (Tilletia), Ustilago (sphacelotheca), eurotia (doassasiopsis), and ectomycosis (isobasidium) among Basidiomycetes (Basidiomycetes);
5) penicillium (Penicillium), Aspergillus (Aspergillus), Mycosphaerella (Mycosphaeralla), Encapsulated (Physiospora), Mycosphaerella (Guignardia), Staphyloccocus (Botryosphaeria), Venturia (Venturia), Erysiphe (Erysiphe), Sphaerotheca (Sphaerotheca), Blumeria (Blumeria), Sphaerotheca (Podosphaera), Sphaerotheca (Phyllantia), Sphaerotheca (Microsphaera), Uncaria (Uncaria), Rhynchophylla (Ceratocarpis), gibberella (Gibberella), humicola (Valsa), plexiglas (Glomerella), pustulosis (Polystima), ischium (Diaporthe), Elsinoe (Elsinoe), pyrenophora (Drechslera), Cochliobolus (Cochliobolus), Sclerotinia (sclerotiotinotia), soot (Capnodium), sphaerotheca (setospora), streptoverticillium (Monilinia), acrocarpus (Gaeumannomyces), ergothrips (Claviceps), botrytis (Pleospora);
6) pediobolus species (Monilinia), Botrytis, Microsporum species (Trichothecium), Cylindrocarpon species (Ramularia), Trichosporon species (Oidium), Pyricularia species (Pyricularia), Verticillium species (Verticillium), Cercospora species (Cercospora), Alternaria species (Alternaria), Cladosporium species (Cladosporium), Venerigeron species (Fusarium), Helicoveromyces species (Drecholera), Helicoveromyces species (Cochliobolus), Theobromyces species (Exophilum), Curvularia species (Curvularia), Pseudocercospora species (Pseudorhizospora), Phaeococcus species (Cordada), Thelephora species (Corynebacterium), Rhizoctonia species (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia ), Rhizoctonia (Rhizoctonia, or (Rhizoctonia, or a, Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, phoma (Phoma), Phoma (Phytolytica), Phoma (Macrophoma), Phomopsis (Phomopsis), Septoria (Septoria), Ascomyces (Valsa), Dichloropsis (Diplodia), Trichosporon (Ascochyta), Fusarium (Fusiococcum), Trichosporon (Coniella), Coniothyrium (Coniothyrium), Coccidium globosum (Botrydiplodia);
7) rhizopus (Rhizopus) and Choanephora (Choanephora) in the subdivision Zygomycotina (Zygomycotina).
7. Use according to claim 3, characterized in that the fungal plant diseases are selected from any one or more of the following fungal diseases 1) to 103):
1) fungal diseases of plants caused by Pythium (Pythium): cucumber rot caused by pythium aphanidermatum (P.aphanidermatum), cucurbit rot rape damping-off, soybean damping-off, cabbage damping-off, cauliflower damping-off, spinach damping-off, water spinach damping-off, vegetable soybean damping-off, beet root cluster disease, tobacco damping-off, cotton seedling damping-off, broccoli seedling damping-off, fennel damping-off, sunflower seedling rot, bitter gourd damping-off;
2) fungal diseases of plants caused by Phytophthora (Phytophthora): potato late blight, tomato late blight, phytophthora parasitica tobacco pathogenic type (p.parasitica var. nicotianae) tobacco black shank, phytophthora capsici (p.capsicii) pepper blight, phytophthora parasitica (p.nicotianae var. parasitica) pineapple heart rot, p.citrophthora induced citrus brown rot, p.fragaria induced strawberry red heart, phytophthora melonis (p.melonis) cucumber blight;
3) fungal diseases of plants caused by Phytophthora (Sclerophora): maize mad top disease caused by macropora;
4) plant fungal diseases caused by phytophthora parasitica (Peronophythora): downy blight of litchi caused by downy phytophthora litchi (p. litchii);
5) fungal plant diseases caused by white rust (Albugo): white rust of rape, cabbage and radish caused by cruciferae white rust (a. Candida);
6) fungal diseases of plants caused by Peronospora (Peronospora): tobacco downy mildew caused by tobacco downy mildew (p.tabacina); downy mildew of Chinese cabbage caused by parasitic downy mildew (p. parasitica); downy mildew of soybean caused by downy mildew of northeast downy mildew (p.man-schurica);
7) fungal plant diseases caused by the genus Pseudoperonospora (Pseudoperonospora): cucumber, pumpkin downy mildew caused by pseudoperonospora cubensis (p. cubensis);
8) fungal plant diseases caused by Plasmopora (Plasmopora): grapevine downy mildew caused by grapevine downy mildew (p.viticola);
9) fungal plant diseases caused by the genus stemphylium (Bremia): lettuce downy mildew caused by Bremia lactucae (B.lactucae);
10) fungal plant diseases caused by the genus stemphylium (Sclerospora): rhizopus graminicola (s.graminicola) causing the development of millet bloom;
11) fungal diseases of plants caused by the genus olea (Olpidium): a Vicia faba-Hui fungus fire swelling disease caused by Soy bean oil chytrid (O.vitae);
12) fungal plant diseases caused by the genus thraustochytrium (syncytrium): potato canceration caused by endophytic chytrium (s.endobioticum);
13) fungal plant diseases caused by the genus nodularia (phynoderma): zea mays (p. maydis) causes brown spot in corn;
14) fungal diseases of plants caused by Plasmodiophora (Plasmodiophora): plasmodiophora brassicae (p. brassicae) causes plasmodiophora brassicae;
15) plant fungal diseases caused by the genus eschar (Spongospora): potato powdery scab is caused by potato powdery scab bacteria (s. subterranean);
16) fungal plant diseases caused by Puccinia (Puccinia): wheat straw rust caused by puccinia graminis (p.graminis per. var. tritici);
17) fungal plant diseases caused by the genus phakopsora (Gymnosphaangium): pear rust caused by rust of pear gum (g. acanthom);
18) fungal plant diseases caused by the genus Puccinia (Phragmidium): rust disease of rose caused by rust of short-tipped polyspora (p. mucronatum);
19) fungal plant diseases caused by the genus rust (Uromyces): bean rust disease caused by p.verrucosa (u.apendiculus);
20) fungal plant diseases caused by Phakopsora (Phakopsora): jujube rust caused by multi-layer rust of jujube (P. ziziphi-vulgaris);
21) fungal plant diseases caused by the genus Graptosphaera (Melampsora): flax rust caused by m.lini;
22) fungal plant diseases caused by smut (Ustilago): wheat powdery mildew caused by wheat aleuromyces dispersus (U.tritici);
23) fungal plant diseases caused by the genus Ustilago (Urocystis): wheat straw smut caused by wheat smut (u.tritic);
24) plant fungal diseases caused by smut (Entyloma): smut of rice leaves caused by smut (e.oryzae);
25) plant fungal diseases caused by Tilletia (Tilletia): tilletia reticulata (T.caries) Tilletia foetida; rice smut caused by stinkbug-layana (t. barc-layana);
26) fungal plant diseases caused by axial smut (Sphacelootheca): sorghum smut caused by ustilago sorghum (s.cruenta);
27) plant fungal diseases caused by the genus nigrospora (Doassansiopsis): arrowhead smut caused by arrowhead smut (d.horiana);
28) fungal plant diseases caused by the genus Exobasidium (Exobasidium): tea cake disease caused by exobasidiomycetes (e.vexans);
29) fungal plant diseases caused by the genus Penicillium (Penicillium): citrus rot disease caused by penicillium italicum (p. italicum);
30) fungal plant diseases caused by Aspergillus (Aspergillus): fruit mildew rot caused by Aspergillus sp;
31) fungal diseases of plants caused by the genus Mycosphaerella (Mycosphaerella): citrus brown spot due to mycosphaerella citri (m.citri), cercospora cherry (m.cerasella), cercospora persimmon (m.nawae), cercospora peanut (m.berkeley), and cercospora peanut (m.arachidis);
32) fungal diseases of plants caused by the genus ascochyta (physiospora): peanut stem rot caused by citrus ascospora chrysosporium (physospora rhodotina), grape house blight caused by botrytis cinerea (p.baccae), and ring rot of pear tree, apple, peach, plum and apricot caused by ascospora chrysosporium (physospora sp);
33) fungal plant diseases caused by globulus (Guignardia): grape black rot caused by ascosphaera botrytis (G.biwellii), and leaf blight of tea caused by G.camelliae;
34) fungal plant diseases caused by plasmodiophora (Botryosphaeria): apple white rot and blueberry stem blight caused by globispherea sp, peach gummosis, peach branch withering, grape canker and grape branch blight caused by botrytis sp;
35) fungal plant diseases caused by the genus Venturia (Venturia): black spot disease of pear caused by black bean fungus (v.pirina), and black spot disease of peach caused by black bean fungus (v.carpopocilum);
36) fungal diseases of plants caused by powdery mildew (Erysiphe): powdery mildew of cereal caused by powdery mildew (e.graminis), powdery mildew of cabbage caused by powdery mildew (e.cruciferae);
37) fungal plant diseases caused by the genus Sphaerotheca (Sphaerotheca): powdery mildew of melons and beans caused by cucurbit unisporum powdery mildew (s.furiginea);
38) plant fungal diseases caused by erysiphe (Blumeria): powdery mildew of gramineous plants caused by powdery mildew of gramineous powdery mildew (b.graminis);
39) fungal plant diseases caused by the genus aphanotheca (Podosphaera): powdery mildew of crab apple, plum and apple caused by P.leucotricha;
40) fungal diseases of plants caused by the genus Stropharia (Phyllantia): chinese chestnut, papaya, phoenix tree, pear, persimmon and walnut powdery mildew caused by corylus heterophylla (p. chrysosporium);
41) fungal plant diseases caused by the genus aphanidermia (microphaga): berberis powdery mildew caused by sphaerotheca berberidis (m.berberidicola), and aristolochia debilis caused by sphaerotheca aristolochiae (m.aristolochiae);
42) fungal plant diseases caused by the genus Uncinula (Uncinula): grape powdery mildew caused by leptospira vitis (u.necator);
43) fungal diseases of plants caused by the genus Ceratocystis (Ceratocystis): sweet potato black spot disease caused by sweet potato chayote (C.fimbriata) and sugarcane pineapple disease caused by paradoxa (C.paradoxa);
44) fungal plant diseases caused by the genus Gibberella (Gibberella): gibberella zeae (g.zeae) causes wheat scab, gibberella granatum (g.jikuroi) causes rice bakanae disease;
45) fungal plant diseases caused by the genus Humicola (Valsa): apple tree rot caused by apple humicola (v.mali);
46) fungal plant diseases caused by the genus Lepidium (Glomerella): anthracnose of fruit trees caused by cingulata;
47) fungal diseases of plants caused by furunculosis (Polystima): red spot disease of plum caused by plum furunculosis (Polystigma rubrum);
48) fungal plant diseases caused by Diaporthe (Diaporthe): citrus gummosis caused by citrus intercropping fungus (d.citricola), sweet potato dry rot caused by sweet potato intercropping fungus (d.batatatis), soybean northern stem canker caused by kidney bean intercropping fungus (d.phaseolorum var.caulivora), apple hypocotyl (d.pomigena) causes apple black spot disease;
49) plant fungal diseases caused by Elsinoe (Elsinoe): vitis vinifera anthracnose caused by Elsinoe ampelina (E.ampelina);
50) fungal plant diseases caused by Pyrenophora (Drechslera): wheat stripe disease caused by wheat sclerotinia (d.graminea);
51) plant fungal diseases caused by the genus Cochliobolus (Cochliobolus): wheat root rot caused by colletotrichum gloeosporioides (c.sativas);
52) fungal diseases of plants caused by Sclerotinia (sclerotiotinia): sclerotinia rot of colza and cucumber caused by sclerotinia sclerotiorum (s.sclerotiorum);
53) fungal diseases of plants caused by soot (Capnodium): citrus sooty mould, hawthorn sooty mould, tea mould and mango mould caused by citrus bituminous coal pathogen (c.citri);
54) fungal plant diseases caused by the genus phyllosphaeria (setosperia): northern leaf blight of maize caused by sitophila macrosperma (s.turcicaca);
55) fungal plant diseases caused by the genus streptomyces (Monilinia): brown rot of apple, pear, peach caused by sclerotinia sclerotiorum (m.fructicola);
56) fungal plant diseases caused by the genus Gaeumannomyces (Gaeumannomyces): cereal and wheat take-all caused by gaeumannomyces graminis variety (g.graminis var. graminis), gaeumannomyces graminis variety (g.graminis (Sacc.) arxet oliver var. tritici);
57) fungal diseases of plants caused by the ergot genus (Claviceps): ergot (c. purpurea) graminis;
58) fungal plant diseases caused by the genus botrytis (Pleospora): tomato gray leaf spot caused by tomato botrytis cinerea (p.lycopersici), and chive leaf blight caused by onion blight (p.herbarum);
59) fungal plant diseases caused by the genus aureobasidium (Monilinia): apple and pear brown rot caused by aureobasidium reniformis (M.fructigena), peach brown rot and apricot brown rot caused by M.laxa;
60) fungal diseases of plants caused by Botrytis (Botrytis): botrytis cinerea (b.cinerea) causes botrytis cinerea, cucumber gray mold, pepper gray mold, grape gray mold, and apple gray mold;
61) fungal plant diseases caused by the genus polyporus (Trichothecium): maize polyporus pinus head rot caused by polyporus pinus (t. roseum);
62) fungal plant diseases caused by the genus septoria (Ramularia): cotton vitiligo caused by exosporium leucotrichum (r. areola);
63) fungal plant diseases caused by the genus Trichosporon (Oidium): lycium barbarum powdery mildew caused by Oidium sp, tomato powdery mildew caused by tomato powdery mildew (o.lycopersic);
64) fungal diseases of plants caused by Pyricularia (Pyricularia): pyricularia oryzae (P.oryae) caused by Pyricularia oryzae;
65) fungal plant diseases caused by Verticillium (Verticillium): verticillium wilt of cotton and verticillium wilt of eggplant caused by verticillium dahliae (V.dahliae);
66) fungal diseases of plants caused by Cercosporella (Cercosporella): white spot disease of Chinese cabbage caused by Cercospora leucoderma (C.albo-maculans);
67) fungal diseases of plants caused by Cercospora (Cercospora): cercospora arachidicola (c.arachidicola) induced peanut brown spot disease, Cercospora colata (c.beticola) induced sugar beet brown spot disease, Cercospora sp. induced oriental cherry brown spot disease, clove brown spot disease, osmanthus fragrans leaf spot disease, azalea leaf spot disease;
68) fungal plant diseases caused by Alternaria (Alternaria): alternaria apple specialization (a. Alternaria f. sp mali) induced Alternaria leaf spot, a. solani induced tomato early blight, a. alternata induced tobacco brown spot, Alternaria sp induced cotton ring spot, apple brown spot, Alternaria late blight, almond root rot, radish black spot;
69) fungal plant diseases caused by Cladosporium (Cladosporium): cucumber scab caused by cladosporium cucumerinum (c. cucumerinum);
70) plant fungal diseases caused by the genus nigrospora (fusarium): pear scab caused by black bean fungus (Fusicillarium virecens);
71) fungal plant diseases caused by helmholysis (Drechslera): barley net blotch caused by helminthosporium cucumerinum (d. teres);
72) fungal plant diseases caused by helminthosporium peregrinum (Cochliobolus): leaf spot of rice flax caused by helminthosporium oryzae (c.miyabenus);
73) fungal plant diseases caused by helminthosporium (Exserohilum): northern leaf blight of corn caused by eurotium megamaculatum (e.turcicum);
74) fungal diseases of plants caused by Curvularia (Curvularia): leaf spot of Curvularia lunata caused by Lunata;
75) fungal plant diseases caused by Pseudocercospora (Pseudocercospora): sigatoka caused by pseudocercospora banana (p.musae), sigatoka caused by pseudocercospora fijiensis (p.fijiensis), cercospora viticola (p.vitis);
76) fungal plant diseases caused by the genus Lawsonia (Cordana): banana gray streak disease caused by banana dim spore (c.musae);
77) fungal diseases of plants caused by Stemphylium (stemphyllium): rhizopus solanacearum (s.solani) tomato gray leaf spot disease, and phoma termatamum leptopodum (s.botryosum) induced leaf blight of chive;
78) plant fungal diseases caused by the genus trichoderma (Fulvia): tomato leaf mold and pepper leaf mold caused by fulvia fulva (f.fulva);
79) fungal plant diseases caused by corynebacterium (Corynespora): cucumber brown spot disease caused by cucumber brown spot pathogen (Corynespora cassiicola);
80) fungal diseases of plants caused by Rhizoctonia (Rhizoctonia): rhizoctonia solani (r.solani) induced sheath blight of rice, cucumber rhizoctonia solani;
81) fungal diseases of plants caused by sclerotium (Selerotium): oil tea, Aleurites fordii, catalpa bungei, citrus, apple, phoenix tree, paulownia, walnut, masson pine, peanut, pepper, shallot southern blight caused by sclerotium rolfsii (Selerotium rolfsii);
82) fungal plant diseases caused by Fusarium (Fusarium): fusarium oxysporum cucumber fusarium wilt caused by cucumber specialization (f.oxysporum f.sp.cucumerium), cotton fusarium wilt caused by fusarium oxysporum wilting specialization (f.oxysporum f.sp.vassifnfectium), and fusarium graminearum caused by fusarium graminearum;
83) fungal plant diseases caused by the genus sclerotium virescens (Ustilaginoidea): rice false smut caused by sclerotinia graminicola (u.oryzae);
84) plant fungal diseases caused by the genus Sphaceloma (Sphaceloma): grape anthracnose caused by Stachybotrys scaber (S.ampelium), citrus scab caused by Stachybotrys citricola (S.fawcettii), solanaceous vegetable scab, pomelo scab and peanut scab caused by Sphaceloma sp;
85) plant fungal diseases caused by Colletotrichum (Colletotrichum): grape anthracnose caused by Colletotrichum gloeosporioides (c.gloeosporioides), cucurbitaceae Colletotrichum sp, oat, brome, orange, citrus, apple, banana, pea, bean, cabbage, melon, beet, tea, tobacco and sugarcane anthracnose;
86) fungal plant diseases caused by discorea (Marssonina): cercospora leaf spot of apple caused by diplospora piricola (m.mali);
87) fungal diseases of plants caused by ray-spores (Actinonema): rosae-induced melasma roseoflavae;
88) fungal plant diseases caused by Pestalotia (Pestalotia): tea leaf spot caused by pestalotiopsis chaetosa (p. theta.);
89) fungal plant diseases caused by discothrix (Gloeosporium): tea anthracnose caused by theasinesis;
90) fungal diseases of plants caused by Phoma (Phoma): brassica napus black shank caused by phoma nigricans (p.lingam);
91) fungal diseases of plants caused by the genus Phyllosticta (Phyllosticta): cotton brown spot caused by cotton lobular spot mould (p. gossypina);
92) fungal diseases of plants caused by the genus Macrophoma (Macrophoma): apple and pear ring rot caused by verticillium dahliae (m.kuwatsukai);
93) fungal diseases of plants caused by Phomopsis (Phomopsis): pseudophomopsis solanacearum (p. vexans);
94) plant fungal diseases caused by Septoria (Septoria): wheat glume blight caused by septoria nodorum (s.nodorum);
95) fungal plant diseases caused by ascochyta (Valsa): pear tree rot caused by apple black hull pear variety (v.mali var. pyri);
96) fungal plant diseases caused by the species Diplodia (Diplodia): cotton boll melanosis caused by cotton bicells (Diplodia gossypina);
97) fungal diseases of plants caused by Ascochyta (Ascochyta): cucumber gummy stem blight caused by Ascochyta cucumis (Ascochyta cucumis);
98) fungal plant diseases caused by Fusarium (Fusicoccum): vine blight caused by Fusarium botrytis (F. viticola);
99) fungal plant diseases caused by the genus Microcospora (Coniella): grape white rot caused by colletotrichum solani (c. diplodiella);
100) fungal plant diseases caused by Coniothyrium (Coniothyrium): white rot of grape caused by Coniothyrium dipnodiella;
101) plant fungal diseases caused by globisporus (Botryodiplodia): mango rot caused by theobromae;
102) fungal diseases of plants caused by Rhizopus (Rhizopus): sweet potato soft rot caused by rhizopus stolonifer (r.stolonifer);
103) fungal diseases of plants caused by Choanephora (Choanephora): rotting of melon flowers or young fruits, rotting of seeds and bulbs during storage, soft rotting of fleshy organs of flowers, rotting of flowers and trees, soft rotting of strawberries and soft rotting of melons caused by Choanephora sp.
8. An agricultural fungicide having a chemical structure of formula I or formula II as follows:
wherein the sum of the probability of the formula I and the probability of the formula II is 100 percent, the probability of the formula I is X, the probability of the formula II is Y, X is 1 to 99 percent, Y is 1 to 99 percent,
the agricultural bactericide is at 25 ℃ and Cu-KαThe X-ray powder diffraction pattern under radiation has the following characteristic data expressed by the d value of the interplanar spacing:
9. the use of the agricultural fungicide according to claim 8, characterized in that the use is for controlling bacterial diseases or fungal diseases of plants.
10. Use according to claim 9, characterized in that the plant bacterial disease is caused by Pseudomonas (Pseudomonas), Xanthomonas (Xanthomonas), Agrobacterium (Agrobacterium), Erwinia (Erwinia), Pantoea (Pantoea), pectinase (petobacterium), Burkholderia (Burkholderia), Ralstonia (Ralstonia), Acidovorax (acidoax), xylem (Xylella), phlobacterium (libobacter), Enterobacter (Enterobacter), rhizobacterium (rhizobacterium), Xylophilus (Xylophilus), dicky (Dickeya), clavibacterium (clavobacter), streptothrix (Streptomyces), brevibacterium (bactrum), Arthrobacter (Arthrobacter), rhodobacter (Rhodococcus), rhodobacter (corynebacterium), or Bacillus (Bacillus).
11. Use according to claim 9, characterized in that the plant bacterial diseases are selected from any one or more of the following bacterial diseases 1) to 22):
1) bacterial diseases in plants caused by the genus Pseudomonas (Pseudomonas): bacterial blight of rice caused by pseudomonas glumae (p. glumae); bacterial black spot of capsicum caused by pseudomonas aeruginosa (p.syringae var. capsicii); cucumber bacterial angular leaf spot and cucumber bacterial angular leaf spot caused by pseudomonas syringae lachrymans (p. syringae pv. lachrymans); tobacco wildfire caused by pseudomonas syringae tobacco pathogenic variant (p.syringae pv. tabaci); kiwifruit canker disease caused by syzygium aromaticum pseudomonas pvt. actinoniae; kiwi fruit floral rot caused by pseudomonas (p. viriflava); bacterial medullary necrosis of tomato, pseudomonitis of tomato caused by pseudomonas winkle (p.corrugate); bacterial leaf spot disease in tomato caused by pseudomonas syringae tomato pathogenic variety (p.syringae pv. tomato); pseudomonas syringae is suitable for pepper bacterial leaf spot caused by pathotype (p.syringae pv. aptata); broccoli head rot caused by fluorescent pseudomonads (p.fluoroscens); bacterial black spot of rape caused by pseudomonas syringae var maculata (p. syringae pv. maculicola); bacterial angular leaf spot of sesame caused by pseudomonas syringae sesame cultivar (p.syringae pv. sesami); bacterial brown spot in corn caused by pseudomonas oryzae (p.oryzihabituans); broad bean bacterial stem blight caused by pseudomonas fasuensis (p.fabae); bacterial leaf spot disease in soybean caused by pseudomonas stutzeri soybean pathogenic variant (p. savastanoi pv. glycinea); bacterial leaf blight of sugar beet caused by pseudomonas solanacearum (p.aptata); pseudomonas aeruginosa (p. aeruginosa) causes ginseng pseudomonas aeruginosa soft rot;
2) bacterial diseases in plants caused by Xanthomonas (Xanthomonas): bacterial blight of rice caused by xanthomonas oryzae pathovar oryzae (x. oryzae pv. oryzae); bacterial leaf streak of rice caused by xanthomonas oryzae germinal pathogenic variant (x. oryzae pv. oryzae) and; citrus canker disease caused by xanthomonas citri (x.citri subsp.citri); peach bacterial perforation disease caused by xanthomonas arborescens peach pathogenic variant (X. arboricola pv. prune); brassicaceae black rot caused by Xanthomonas campestris pathogenic variety X.campestris pv. campestris; watermelon spot disease caused by Xanthomonas glycanorrhoeae (X.campestis pv. cucurbitae); bacterial scab of tomato and pepper caused by Xanthomonas campestris pepper spot pathogenic variety (X.campestis pv. vesicatoria); bacterial black spot disease in mango caused by xanthomonas campestris mango pathovar (x. campestis pv. mangifereae); bacterial leaf spot of pepper caused by xanthomonas campestris piperis pathogenic variety (x. campestis pv. betuliola); bacterial blight of poinsettia caused by xanthomonas campestris poinsettia pathovar x.campesticola (pv. poinsetticola); cotton angular leaf spot caused by xanthomonas carpi mallow pathogenic variety (x. axonopodis pv. malvacearum); soybean bacterial leaf spot disease caused by Xanthomonas carpi soybean pathogenic variety (X.axonopodis pv. glycines); bacterial wilt of cassava caused by Xanthomonas carpi (X. axonopodis pv. manihot); anthurium bacterial blight caused by Xanthomonas carpi Huanyanqing pathogenic variety (X.axonopodis pv. dieffenbachiae); strawberry angular leaf spot caused by xanthomonas strawberrii (x. fragariae);
3) bacterial diseases in plants caused by the genus Agrobacterium (Agrobacterium): watermelon bacterial crown gall and rosaceous root cancer caused by agrobacterium tumefaciens (a. tumefaciens); melon bacterial hairy root disease caused by agrobacterium rhizogenes (a. grobacter tumefaciens);
4) bacterial diseases in plants caused by Erwinia (Erwinia): clearing away erwinia amylovora (E.amylovora) caused pear fire blight; bacterial basal rot of rice caused by erwinia maize cultivar (e.chrysanthemi pv. zeae); soft rot of cruciferae, watermelon and onion caused by erwinia carotovora (e.carotovora subsp.carotovora); watermelon wilt disease caused by erwinia avicularis (e.tracheiphila);
5) bacterial diseases in plants caused by Pantoea (Pantoea): pantoea zeae leaf spot caused by Pantoea ananatis (P.ananatis); bacterial leaf blight of red bean caused by Pantoea agglomerans (P.agglomerans);
6) bacterial diseases in plants caused by the genus Pectobacterium (Pectibacter): tomato soft rot and pepper soft rot caused by pectobacterium carotovorum subsp. Soft rot disease of potato caused by p.carotovorum subsp.brasiliensis; potato black shank caused by p.atrosepticum;
7) bacterial diseases in plants caused by Burkholderia (Burkholderia): onion bulb rot disease caused by burkholderia cepacia (b.cepacia); bacterial spike blight of rice caused by burkholderia glumae (b.glumae); bacterial wilt of dianthus caryophyllus caused by burkholderia malabarica (b. caryophyli);
8) bacterial diseases in plants caused by the genus Ralstonia (Ralstonia): potato bacterial wilt, tomato bacterial wilt, pepper bacterial wilt and watermelon bacterial wilt caused by Laurella r.solanacearum;
9) bacterial diseases in plants caused by Acidovorax (Acidovorax): bacterial fruit rot of melons caused by acidovorax citrulli (a. citrulli); bacterial brown streak disease in rice caused by oat acidovorax avenae subsp.
10) Bacterial diseases in plants caused by xylaria (Xylella): grapevine dermatosis caused by xylella fastidiosa x.fastidiosa;
11) bacterial diseases in plants caused by the genus of the genus Liberobacter: citrus yellow shoot caused by asian (l.asiaticus), african (l.africanus), american (l.americanus);
12) bacterial diseases in plants caused by the genus Enterobacter (Enterobacter): yellowing disease in papaya fruits caused by enterobacter cloacae (e.cloacae); poplar wilt disease caused by enterobacter carcinogens (e.cancerogenus);
13) bacterial diseases in plants caused by the genus rhizobacterium (Rhizobacter): carrot gall disease caused by daucus;
14) bacterial diseases in plants caused by the genus Xylophilus (Xylophilus): grape canker disease caused by ampelinus;
15) bacterial diseases in plants caused by dikaya (Dickeya): bacterial stalk rot in maize caused by d.zeae; sweet potato stem rot caused by daldantii (d.dadantii); potato black shank caused by diskettsia solanacearum (d.solani); erwinia rust disease caused by daldikaea (d. fangzhongdai);
16) bacterial diseases in plants caused by the genus Clavibacter (Clavibacter): potato ring rot disease caused by clavibacter michiganensis subsp. Tomato canker disease caused by clavibacter michiganensis subsp.
17) Bacterial diseases in plants caused by the genus Streptomyces (Streptomyces): potato scab caused by streptomyces scab (s.scabies);
18) bacterial diseases in plants caused by the genus brevibacterium (Curtobacterium): bean wilt caused by Bacillus pumilus wilt pathogenic variety (C. flaccumfaciens pv. flaccumfaciens); bacterial leaf spot of beet caused by Bacillus pumilus beet pathogenic variant (C. flaccumfaciens pv. bet); tulip yellow bleb spot caused by bacillus pumilus austenic variant (c. flaccumfaciens pv. orctii);
19) bacterial diseases in plants caused by Arthrobacter (Arthrobacter): ilex purpurea caused by ilicis;
20) bacterial diseases in plants caused by the genus Rhodococcus (Rhodococcus): sweet pea banding disease caused by fascians;
21) bacterial diseases in plants caused by the genus Bacillus (Bacillus): bacillus megaterium (b.megaterium) induced leaf spot of bacillus zeae;
22) bacterial diseases in plants caused by the genus Rathaibacter (Rathayibacter): rathayi causes dactylosia.
12. The use according to claim 9, characterized in that the plant fungal diseases are plant fungal diseases caused by one or more pathogenic bacteria selected from any one of the following 1) to 7):
1) pythium (Pythium), Phytophthora (Phytophthora), Phytophthora (sclerophora), peronophythora (perophthora), peronophythora (peronophytora), Albugo (Albugo), Peronospora (Peronospora), Pseudoperonospora (Pseudoperonospora), plasmopara (Plasmopora), stemphylium (Bremia), aureospora (Sclerospora) in Oomycetes (Oomycetes);
2) chytrium (Olpidium), chytrium (syncytium), chytrium (phynoderma) in chytrium (chydiycetes);
3) plasmodiophoromycetes (Plasmodiophoromycetes), sphaerotheca (Spongospora), Polymyxa (Polymyxa) among Plasmodiophoromycetes (Plasmodiophoromycetes);
4) puccinia (Puccinia), colletotrichum (gynosporangium), polyspora (Phragmidium), unicospora (Uromyces), Phakopsora (Phakopsora), corymbosa (Melampsora), Ustilago (Ustilago), Ustilago (Urocystis), Ustilago (Entyloma), triticale (Tilletia), Ustilago (sphacelotheca), eurotia (doassasiopsis), and ectomycosis (isobasidium) among Basidiomycetes (Basidiomycetes);
5) penicillium (Penicillium), Aspergillus (Aspergillus), Mycosphaerella (Mycosphaeralla), Encapsulated (Physiospora), Mycosphaerella (Guignardia), Staphyloccocus (Botryosphaeria), Venturia (Venturia), Erysiphe (Erysiphe), Sphaerotheca (Sphaerotheca), Blumeria (Blumeria), Sphaerotheca (Podosphaera), Sphaerotheca (Phyllantia), Sphaerotheca (Microsphaera), Uncaria (Uncaria), Rhynchophylla (Ceratocarpis), gibberella (Gibberella), humicola (Valsa), plexiglas (Glomerella), pustulosis (Polystima), ischium (Diaporthe), Elsinoe (Elsinoe), pyrenophora (Drechslera), Cochliobolus (Cochliobolus), Sclerotinia (sclerotiotinotia), soot (Capnodium), sphaerotheca (setospora), streptoverticillium (Monilinia), acrocarpus (Gaeumannomyces), ergothrips (Claviceps), botrytis (Pleospora);
6) pediobolus species (Monilinia), Botrytis, Microsporum species (Trichothecium), Cylindrocarpon species (Ramularia), Trichosporon species (Oidium), Pyricularia species (Pyricularia), Verticillium species (Verticillium), Cercospora species (Cercospora), Alternaria species (Alternaria), Cladosporium species (Cladosporium), Venerigeron species (Fusarium), Helicoveromyces species (Drecholera), Helicoveromyces species (Cochliobolus), Theobromyces species (Exophilum), Curvularia species (Curvularia), Pseudocercospora species (Pseudorhizospora), Phaeococcus species (Cordada), Thelephora species (Corynebacterium), Rhizoctonia species (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia), Rhizoctonia (Rhizoctonia ), Rhizoctonia (Rhizoctonia, or (Rhizoctonia, or a, Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, or (Rhizoctonia, phoma (Phoma), Phoma (Phytolytica), Phoma (Macrophoma), Phomopsis (Phomopsis), Septoria (Septoria), Ascomyces (Valsa), Dichloropsis (Diplodia), Trichosporon (Ascochyta), Fusarium (Fusiococcum), Trichosporon (Coniella), Coniothyrium (Coniothyrium), Coccidium globosum (Botrydiplodia);
7) rhizopus (Rhizopus) and Choanephora (Choanephora) in the subdivision Zygomycotina (Zygomycotina).
13. Use according to claim 9, characterized in that the fungal plant diseases are selected from any one or more of the following fungal diseases 1) to 103):
1) fungal diseases of plants caused by Pythium (Pythium): cucumber rot caused by pythium aphanidermatum (P.aphanidermatum), cucurbit rot rape damping-off, soybean damping-off, cabbage damping-off, cauliflower damping-off, spinach damping-off, water spinach damping-off, vegetable soybean damping-off, beet root cluster disease, tobacco damping-off, cotton seedling damping-off, broccoli seedling damping-off, fennel damping-off, sunflower seedling rot, bitter gourd damping-off;
2) fungal diseases of plants caused by Phytophthora (Phytophthora): potato late blight, tomato late blight, phytophthora parasitica tobacco pathogenic type (p.parasitica var. nicotianae) tobacco black shank, phytophthora capsici (p.capsicii) pepper blight, phytophthora parasitica (p.nicotianae var. parasitica) pineapple heart rot, p.citrophthora induced citrus brown rot, p.fragaria induced strawberry red heart, phytophthora melonis (p.melonis) cucumber blight;
3) fungal diseases of plants caused by Phytophthora (Sclerophora): maize mad top disease caused by macropora;
4) plant fungal diseases caused by phytophthora parasitica (Peronophythora): downy blight of litchi caused by downy phytophthora litchi (p. litchii);
5) fungal plant diseases caused by white rust (Albugo): white rust of rape, cabbage and radish caused by cruciferae white rust (a. Candida);
6) fungal diseases of plants caused by Peronospora (Peronospora): tobacco downy mildew caused by tobacco downy mildew (p.tabacina); downy mildew of Chinese cabbage caused by parasitic downy mildew (p. parasitica); downy mildew of soybean caused by downy mildew of northeast downy mildew (p.man-schurica);
7) fungal plant diseases caused by the genus Pseudoperonospora (Pseudoperonospora): cucumber, pumpkin downy mildew caused by pseudoperonospora cubensis (p. cubensis);
8) fungal plant diseases caused by Plasmopora (Plasmopora): grapevine downy mildew caused by grapevine downy mildew (p.viticola);
9) fungal plant diseases caused by the genus stemphylium (Bremia): lettuce downy mildew caused by Bremia lactucae (B.lactucae);
10) fungal plant diseases caused by the genus stemphylium (Sclerospora): rhizopus graminicola (s.graminicola) causing the development of millet bloom;
11) fungal diseases of plants caused by the genus olea (Olpidium): a Vicia faba-Hui fungus fire swelling disease caused by Soy bean oil chytrid (O.vitae);
12) fungal plant diseases caused by the genus thraustochytrium (syncytrium): potato canceration caused by endophytic chytrium (s.endobioticum);
13) fungal plant diseases caused by the genus nodularia (phynoderma): zea mays (p. maydis) causes brown spot in corn;
14) fungal diseases of plants caused by Plasmodiophora (Plasmodiophora): plasmodiophora brassicae (p. brassicae) causes plasmodiophora brassicae;
15) plant fungal diseases caused by the genus eschar (Spongospora): potato powdery scab is caused by potato powdery scab bacteria (s. subterranean);
16) fungal plant diseases caused by Puccinia (Puccinia): wheat straw rust caused by puccinia graminis (p.graminis per. var. tritici);
17) fungal plant diseases caused by the genus phakopsora (Gymnosphaangium): pear rust caused by rust of pear gum (g. acanthom);
18) fungal plant diseases caused by the genus Puccinia (Phragmidium): rust disease of rose caused by rust of short-tipped polyspora (p. mucronatum);
19) fungal plant diseases caused by the genus rust (Uromyces): bean rust disease caused by p.verrucosa (u.apendiculus);
20) fungal plant diseases caused by Phakopsora (Phakopsora): jujube rust caused by multi-layer rust of jujube (P. ziziphi-vulgaris);
21) fungal plant diseases caused by the genus Graptosphaera (Melampsora): lini-induced flax rust;
22) fungal plant diseases caused by smut (Ustilago): wheat powdery mildew caused by wheat aleuromyces dispersus (U.tritici);
23) fungal plant diseases caused by the genus Ustilago (Urocystis): wheat straw smut caused by wheat smut (u.tritic);
24) plant fungal diseases caused by smut (Entyloma): smut of rice leaves caused by smut (e.oryzae);
25) plant fungal diseases caused by Tilletia (Tilletia): tilletia reticulata (T.caries) Tilletia foetida; rice smut caused by stinkbug-layana (t. barc-layana);
26) fungal plant diseases caused by axial smut (Sphacelootheca): sorghum smut caused by ustilago sorghum (s.cruenta);
27) plant fungal diseases caused by the genus nigrospora (Doassansiopsis): arrowhead smut caused by arrowhead smut (d.horiana);
28) fungal plant diseases caused by the genus Exobasidium (Exobasidium): tea cake disease caused by exobasidiomycetes (e.vexans);
29) fungal plant diseases caused by the genus Penicillium (Penicillium): citrus rot disease caused by penicillium italicum (p. italicum);
30) fungal plant diseases caused by Aspergillus (Aspergillus): fruit mildew rot caused by Aspergillus sp;
31) fungal diseases of plants caused by the genus Mycosphaerella (Mycosphaerella): citrus brown spot due to mycosphaerella citri (m.citri), cercospora cherry (m.cerasella), cercospora persimmon (m.nawae), cercospora peanut (m.berkeley), and cercospora peanut (m.arachidis);
32) fungal diseases of plants caused by the genus ascochyta (physiospora): peanut stem rot caused by citrus cystospora (Physalospora rhododendron), grape house blight caused by grape cyst (p. baccae), and ring rot caused by cyst (Physalospora sp) (various fruit trees such as pear trees, apple trees, peach trees, plum trees and apricot trees);
33) fungal plant diseases caused by globulus (Guignardia): grape black rot caused by ascosphaera botrytis (G.biwellii), and leaf blight of tea caused by G.camelliae;
34) fungal plant diseases caused by plasmodiophora (Botryosphaeria): apple white rot and blueberry stem blight caused by globispherea sp, peach gummosis, peach branch withering, grape canker and grape branch blight caused by botrytis sp;
35) fungal plant diseases caused by the genus Venturia (Venturia): black spot disease of pear caused by black bean fungus (v.pirina), and black spot disease of peach caused by black bean fungus (v.carpopocilum);
36) fungal diseases of plants caused by powdery mildew (Erysiphe): powdery mildew of cereal caused by powdery mildew (e.graminis), powdery mildew of cabbage caused by powdery mildew (e.cruciferae);
37) fungal plant diseases caused by the genus Sphaerotheca (Sphaerotheca): powdery mildew of melons and beans caused by cucurbit unisporum powdery mildew (s.furiginea);
38) plant fungal diseases caused by erysiphe (Blumeria): powdery mildew of gramineous plants caused by powdery mildew of gramineous powdery mildew (b.graminis);
39) fungal plant diseases caused by the genus aphanotheca (Podosphaera): powdery mildew of crab apple, plum and apple caused by P.leucotricha;
40) fungal diseases of plants caused by the genus Stropharia (Phyllantia): chinese chestnut, papaya, phoenix tree, pear, persimmon and walnut powdery mildew caused by corylus heterophylla (p. chrysosporium);
41) fungal plant diseases caused by the genus aphanidermia (microphaga): berberis powdery mildew caused by sphaerotheca berberidis (m.berberidicola), and aristolochia debilis caused by sphaerotheca aristolochiae (m.aristolochiae);
42) fungal plant diseases caused by the genus Uncinula (Uncinula): grape powdery mildew caused by leptospira vitis (u.necator);
43) fungal diseases of plants caused by the genus Ceratocystis (Ceratocystis): sweet potato black spot disease caused by sweet potato chayote (C.fimbriata) and sugarcane pineapple disease caused by paradoxa (C.paradoxa);
44) fungal plant diseases caused by the genus Gibberella (Gibberella): gibberella zeae (g.zeae) causes wheat scab, gibberella granatum (g.jikuroi) causes rice bakanae disease;
45) fungal plant diseases caused by the genus Humicola (Valsa): apple tree rot caused by apple humicola (v.mali);
46) fungal plant diseases caused by the genus Lepidium (Glomerella): anthracnose of fruit trees caused by cingulata;
47) fungal diseases of plants caused by furunculosis (Polystima): red spot disease of plum caused by plum furunculosis (Polystigma rubrum);
48) fungal plant diseases caused by Diaporthe (Diaporthe): citrus gummosis caused by citrus intercropping fungus (d.citricola), sweet potato dry rot caused by sweet potato intercropping fungus (d.batatatis), soybean northern stem canker caused by kidney bean intercropping fungus (d.phaseolorum var.caulivora), apple hypocotyl (d.pomigena) causes apple black spot disease;
49) plant fungal diseases caused by Elsinoe (Elsinoe): vitis vinifera anthracnose caused by Elsinoe ampelina (E.ampelina);
50) fungal plant diseases caused by Pyrenophora (Drechslera): wheat stripe disease caused by wheat sclerotinia (d.graminea);
51) plant fungal diseases caused by the genus Cochliobolus (Cochliobolus): wheat root rot caused by colletotrichum gloeosporioides (c.sativas);
52) fungal diseases of plants caused by Sclerotinia (sclerotiotinia): sclerotinia rot of colza and cucumber caused by sclerotinia sclerotiorum (s.sclerotiorum);
53) fungal diseases of plants caused by soot (Capnodium): citrus sooty mould, hawthorn sooty mould, tea mould and mango mould caused by citrus bituminous coal pathogen (c.citri);
54) fungal plant diseases caused by the genus phyllosphaeria (setosperia): northern leaf blight of maize caused by sitophila macrosperma (s.turcicaca);
55) fungal plant diseases caused by the genus streptomyces (Monilinia): brown rot of apple, pear, peach caused by sclerotinia sclerotiorum (m.fructicola);
56) fungal plant diseases caused by the genus Gaeumannomyces (Gaeumannomyces): cereal and wheat take-all caused by gaeumannomyces graminis variety (g.graminis var. graminis), gaeumannomyces graminis variety (g.graminis (Sacc.) arxet oliver var. tritici);
57) fungal diseases of plants caused by the ergot genus (Claviceps): ergot (c. purpurea) graminis;
58) fungal plant diseases caused by the genus botrytis (Pleospora): tomato gray leaf spot caused by tomato botrytis cinerea (p.lycopersici), and chive leaf blight caused by onion blight (p.herbarum);
59) fungal plant diseases caused by the genus aureobasidium (Monilinia): apple and pear brown rot caused by aureobasidium reniformis (M.fructigena), peach brown rot and apricot brown rot caused by M.laxa;
60) fungal diseases of plants caused by Botrytis (Botrytis): botrytis cinerea (b.cinerea) causes botrytis cinerea, cucumber gray mold, pepper gray mold, grape gray mold, and apple gray mold;
61) fungal plant diseases caused by the genus polyporus (Trichothecium): maize polyporus pinus head rot caused by polyporus pinus (t. roseum);
62) fungal plant diseases caused by the genus septoria (Ramularia): cotton vitiligo caused by exosporium leucotrichum (r. areola);
63) fungal plant diseases caused by the genus Trichosporon (Oidium): lycium barbarum powdery mildew caused by Oidium sp, tomato powdery mildew caused by tomato powdery mildew (o.lycopersic);
64) fungal diseases of plants caused by Pyricularia (Pyricularia): pyricularia oryzae (P.oryae) caused by Pyricularia oryzae;
65) fungal plant diseases caused by Verticillium (Verticillium): verticillium wilt of cotton and verticillium wilt of eggplant caused by verticillium dahliae (V.dahliae);
66) fungal diseases of plants caused by Cercosporella (Cercosporella): white spot disease of Chinese cabbage caused by Cercospora leucoderma (C.albo-maculans);
67) fungal diseases of plants caused by Cercospora (Cercospora): cercospora arachidicola (c.arachidicola) induced peanut brown spot disease, Cercospora colata (c.beticola) induced sugar beet brown spot disease, Cercospora sp. induced oriental cherry brown spot disease, clove brown spot disease, osmanthus fragrans leaf spot disease, azalea leaf spot disease;
68) fungal plant diseases caused by Alternaria (Alternaria): alternaria apple specialization (a. Alternaria f. sp mali) induced Alternaria leaf spot, a. solani induced tomato early blight, a. alternata induced tobacco brown spot, Alternaria sp induced cotton ring spot, apple brown spot, Alternaria late blight, almond root rot, radish black spot;
69) fungal plant diseases caused by Cladosporium (Cladosporium): cucumber scab caused by cladosporium cucumerinum (c. cucumerinum);
70) plant fungal diseases caused by the genus nigrospora (fusarium): pear scab caused by black bean fungus (Fusicillarium virecens);
71) fungal plant diseases caused by helmholysis (Drechslera): barley net blotch caused by helminthosporium cucumerinum (d. teres);
72) fungal plant diseases caused by helminthosporium peregrinum (Cochliobolus): leaf spot of rice flax caused by helminthosporium oryzae (c.miyabenus);
73) fungal plant diseases caused by helminthosporium (Exserohilum): northern leaf blight of corn caused by eurotium megamaculatum (e.turcicum);
74) fungal diseases of plants caused by Curvularia (Curvularia): leaf spot of Curvularia lunata caused by Lunata;
75) fungal plant diseases caused by Pseudocercospora (Pseudocercospora): sigatoka caused by pseudocercospora banana (p.musae), sigatoka caused by pseudocercospora fijiensis (p.fijiensis), cercospora viticola (p.vitis);
76) fungal plant diseases caused by the genus Lawsonia (Cordana): banana gray streak disease caused by banana dim spore (c.musae);
77) fungal diseases of plants caused by Stemphylium (stemphyllium): rhizopus solanacearum (s.solani) tomato gray leaf spot disease, and phoma termatamum leptopodum (s.botryosum) induced leaf blight of chive;
78) plant fungal diseases caused by the genus trichoderma (Fulvia): tomato leaf mold and pepper leaf mold caused by fulvia fulva (f.fulva);
79) fungal plant diseases caused by corynebacterium (Corynespora): cucumber brown spot disease caused by cucumber brown spot pathogen (Corynespora cassiicola);
80) fungal diseases of plants caused by Rhizoctonia (Rhizoctonia): rhizoctonia solani (r.solani) induced sheath blight of rice, cucumber rhizoctonia solani;
81) fungal diseases of plants caused by sclerotium (Selerotium): oil tea, Aleurites fordii, catalpa bungei, citrus, apple, phoenix tree, paulownia, walnut, masson pine, peanut, pepper, shallot southern blight caused by sclerotium rolfsii (Selerotium rolfsii);
82) fungal plant diseases caused by Fusarium (Fusarium): fusarium oxysporum cucumber fusarium wilt caused by cucumber specialization (f.oxysporum f.sp.cucumerium), cotton fusarium wilt caused by fusarium oxysporum wilting specialization (f.oxysporum f.sp.vassifnfectium), and fusarium graminearum caused by fusarium graminearum;
83) fungal plant diseases caused by the genus sclerotium virescens (Ustilaginoidea): rice false smut caused by sclerotinia graminicola (u.oryzae);
84) plant fungal diseases caused by the genus Sphaceloma (Sphaceloma): grape anthracnose caused by Stachybotrys scaber (S.ampelium), citrus scab caused by Stachybotrys citricola (S.fawcettii), solanaceous vegetable scab, pomelo scab and peanut scab caused by Sphaceloma sp;
85) plant fungal diseases caused by Colletotrichum (Colletotrichum): grape anthracnose caused by Colletotrichum gloeosporioides (c.orbiosporioides), cucurbitaceae Colletotrichum sp, oats, brome, orange, citrus, apple, banana, pea, bean, cabbage, melon, sugar beet, tea, tobacco and sugarcane anthracnose;
86) fungal plant diseases caused by discorea (Marssonina): cercospora leaf spot of apple caused by diplospora piricola (m.mali);
87) fungal diseases of plants caused by ray-spores (Actinonema): rosae-induced melasma roseoflavae;
88) fungal plant diseases caused by Pestalotia (Pestalotia): tea leaf spot caused by pestalotiopsis chaetosa (p. theta.);
89) fungal plant diseases caused by discothrix (Gloeosporium): tea anthracnose caused by theasinesis;
90) fungal diseases of plants caused by Phoma (Phoma): brassica napus black shank caused by phoma nigricans (p.lingam);
91) fungal diseases of plants caused by the genus Phyllosticta (Phyllosticta): cotton brown spot caused by cotton lobular spot mould (p. gossypina);
92) fungal diseases of plants caused by the genus Macrophoma (Macrophoma): apple and pear ring rot caused by verticillium dahliae (m.kuwatsukai);
93) fungal diseases of plants caused by Phomopsis (Phomopsis): pseudophomopsis solanacearum (p. vexans);
94) plant fungal diseases caused by Septoria (Septoria): wheat glume blight caused by septoria nodorum (s.nodorum);
95) fungal plant diseases caused by ascochyta (Valsa): pear tree rot caused by apple black hull pear variety (v.mali var. pyri);
96) fungal plant diseases caused by the species Diplodia (Diplodia): cotton boll melanosis caused by cotton bicells (Diplodia gossypina);
97) fungal diseases of plants caused by Ascochyta (Ascochyta): cucumber gummy stem blight caused by Ascochyta cucumis (Ascochyta cucumis);
98) fungal plant diseases caused by Fusarium (Fusicoccum): vine blight caused by Fusarium botrytis (F. viticola);
99) fungal plant diseases caused by the genus Microcospora (Coniella): grape white rot caused by colletotrichum solani (c. diplodiella);
100) fungal plant diseases caused by Coniothyrium (Coniothyrium): white rot of grape caused by Coniothyrium dipnodiella;
101) plant fungal diseases caused by globisporus (Botryodiplodia): mango rot caused by theobromae;
102) fungal diseases of plants caused by Rhizopus (Rhizopus): sweet potato soft rot caused by rhizopus stolonifer (r.stolonifer);
103) fungal diseases of plants caused by Choanephora (Choanephora): rotting of melon flowers or young fruits, rotting of seeds and bulbs during storage, soft rotting of fleshy organs of flowers, rotting of flowers and trees, soft rotting of strawberries and soft rotting of melons caused by Choanephora sp.
14. A method for producing an agricultural fungicide according to any one of claims 1 to 2 or 8, characterized by reacting a base, 1, 2-benzisothiazol-3 (2H) -one and a zinc salt in organic solvent-free water to produce an agricultural fungicide.
15. The method for preparing according to claim 14, characterized in that the method comprises the steps of: sequentially adding water, alkali and 1, 2-benzisothiazol-3 (2H) -ketone into a reaction vessel, then dropwise adding a zinc salt water solution, stirring and reacting for 1-5 hours at the temperature of room temperature to 100 ℃, separating out crystals, filtering, washing and drying to obtain the agricultural bactericide.
16. The method according to claim 14, wherein the base is sodium hydroxide, potassium hydroxide, aqueous ammonia, or aqueous trimethylamine.
17. The method according to claim 14, wherein the zinc salt is zinc sulfate, zinc chloride or zinc acetate containing crystal water or anhydrous.
18. The process according to claim 14, wherein the ratio of base: 1, 2-benzisothiazol-3 (2H) -one: zinc salt is from 1: 5: 1: 5.
19. The process according to claim 18, wherein the ratio of base: 1, 2-benzisothiazol-3 (2H) -one: zinc salt is 2: 3: 1.
20. A formulation comprising an agricultural fungicide, characterized in that the formulation comprises the agricultural fungicide according to any one of claims 1 to 2 or 8 and an adjuvant for agricultural chemicals, and the agricultural fungicide in the formulation accounts for 0.1 to 90% by mass of the formulation.
21. The formulation of claim 20, wherein the formulation is in the form of powder, granule, water dispersible granule, wettable powder, oil dispersible powder, emulsion powder, suspension, microcapsule suspension, dispersible oil suspension, suspoemulsion, or smoke agent.
22. The formulation of claim 21, wherein the formulation is in the form of a suspension, an aqueous dispersion or a wettable powder.
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