CN112175747A - Method for preparing textile detergent - Google Patents

Method for preparing textile detergent Download PDF

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Publication number
CN112175747A
CN112175747A CN202011181969.5A CN202011181969A CN112175747A CN 112175747 A CN112175747 A CN 112175747A CN 202011181969 A CN202011181969 A CN 202011181969A CN 112175747 A CN112175747 A CN 112175747A
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China
Prior art keywords
parts
preparing
textile detergent
later use
filler
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Pending
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CN202011181969.5A
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Chinese (zh)
Inventor
曾小军
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Changxing Zhuoheng New Material Technology Co ltd
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Changxing Zhuoheng New Material Technology Co ltd
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Priority to CN202011181969.5A priority Critical patent/CN112175747A/en
Publication of CN112175747A publication Critical patent/CN112175747A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/384Animal products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38636Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Zoology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a method for preparing a textile detergent, which belongs to the technical field of preparation of softeners and comprises the following steps: (1) preparing an additive, (2) weighing raw materials, and (3) mixing to prepare a finished product. The method is simple, and the prepared detergent has the characteristics of strong oil and stain removal capacity and high efficiency.

Description

Method for preparing textile detergent
Technical Field
The invention belongs to the technical field of preparation of softening agents, and particularly relates to a preparation method of a textile detergent.
Background
Detergents are in a large category and are in a wide variety of forms, including both inorganic and organic dry cleaning. The organic detergents are simply detergents made of carbon-containing compounds, and the inorganic detergents are detergents made of carbon-free compounds, and thus they are inorganic. There are many methods for classifying detergents, and water-based detergents, semi-water-based detergents and non-water-based detergents are generally classified. The conventional textile detergents on the market mostly have the problems of common oil removal and dirt removal capability and poor comprehensive use effect, and need to be continuously improved.
Disclosure of Invention
The invention aims to provide a manufacturing method of a textile detergent.
The technical purpose of the invention is realized by the following technical scheme:
a method for manufacturing a textile detergent comprises the following steps:
(1) preparing an additive:
a. mixing and crushing sweet osmanthus, honeysuckle and lily to obtain a mixture A for later use;
b. b, putting the mixture A obtained in the operation a into boiling water, boiling for 1.5-2 h, and filtering to obtain a filtrate B for later use;
c. heating and concentrating the filtrate B obtained in the operation B to obtain an additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight for later use: 10-15 parts of the additive prepared in the step (1), 6-9 parts of sodium citrate, 5-8 parts of potassium chloride, 18-22 parts of glycerol, 2-4 parts of complex enzyme, 4-8 parts of nonylphenol polyoxyethylene ether, 3-6 parts of gelatin, 12-16 parts of ethanolamine, 5-10 parts of methyl methacrylate, 4-7 parts of filler and 500-550 parts of deionized water;
(3) mixing to prepare a finished product:
a. heating deionized water, then adding the additive prepared in the step (1), sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine, methyl methacrylate and filler together, and performing ultrasonic dispersion uniformly for later use;
b. and d, after the solution obtained in the operation a is cooled to normal temperature, adding the complex enzyme, and uniformly stirring to obtain the finished product detergent.
Further, the weight ratio of the osmanthus fragrans, the honeysuckle and the lily in the step (1) in the operation a is 10-15: 3-6: 2-4.
Further, the corresponding weight ratio of the mixture A and boiling water in the step (1) and the operation b is 1: 6-7.
Further, after the heating concentration treatment in the operation c in the step (1), controlling the volume of the filtrate B to be concentrated to 12-16% of the original volume.
Further, the filler in the step (2) is any one of kaolin, attapulgite and diatomite.
Further, the particle size of the filler in the step (2) is 300-400 meshes.
Further, the complex enzyme in the step (2) is formed by mixing ficin and hesperidinase according to the weight ratio of 4-5: 1.
Further, the temperature of the deionized water is kept between 70 and 75 ℃ during the heating in the operation a in the step (3).
Further, the frequency of the ultrasonic wave is controlled to be 700-800 kHz during the ultrasonic dispersion in the operation a of the step (3).
Compared with the prior art, the invention has the following advantages:
the invention discloses a preparation method of a detergent, the detergent prepared by the method can obviously improve the washing and protecting effects on textiles, in the preparation process, an additive is prepared firstly, the additive is obtained by mixing and extracting sweet osmanthus, honeysuckle and lily together, the additive can endow the detergent with good antibacterial property, can assist other components to enhance the decontamination effect and can improve the integral smell; the added sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine and methyl methacrylate are compounded for use, so that the decontamination and deoiling capability is effectively ensured, and the fabric damage to the textile is small; the added filler can improve the stability of the effective components of the detergent, can adsorb and promote the removal of oil stains, and improves the using effect of the detergent. The detergent prepared by the method has the characteristics of strong oil and stain removal capacity and high efficiency, and has great market competitiveness.
Detailed Description
Example 1
A method for manufacturing a textile detergent comprises the following steps:
(1) preparing an additive:
a. mixing and crushing sweet osmanthus, honeysuckle and lily to obtain a mixture A for later use;
b. b, putting the mixture A obtained in the operation a into boiling water, boiling for 1.5 hours, and filtering to obtain filtrate B for later use;
c. heating and concentrating the filtrate B obtained in the operation B to obtain an additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight for later use: 10 parts of the additive prepared in the step (1), 6 parts of sodium citrate, 5 parts of potassium chloride, 18 parts of glycerol, 2 parts of complex enzyme, 4 parts of nonylphenol polyoxyethylene ether, 3 parts of gelatin, 12 parts of ethanolamine, 5 parts of methyl methacrylate, 4 parts of filler and 500 parts of deionized water;
(3) mixing to prepare a finished product:
a. heating deionized water, then adding the additive prepared in the step (1), sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine, methyl methacrylate and filler together, and performing ultrasonic dispersion uniformly for later use;
b. and d, after the solution obtained in the operation a is cooled to normal temperature, adding the complex enzyme, and uniformly stirring to obtain the finished product detergent.
And (2) in the step (1), when the sweet osmanthus, the honeysuckle and the lily are mixed together, the corresponding weight ratio is 10:3: 2.
The corresponding weight ratio of the mixture A and the boiling water in the operation b in the step (1) is 1:6.
Controlling the volume of the filtrate B to be concentrated to 12% after the heating concentration treatment in the operation c of the step (1).
The filler in the step (2) is kaolin.
The particle size of the filler in the step (2) is 300 meshes.
The complex enzyme in the step (2) is formed by mixing ficin and hesperidinase according to the weight ratio of 4: 1.
The deionized water was maintained at a temperature of 70 ℃ during the heating described in operation a of step (3).
Controlling the frequency of the ultrasonic wave to be 700kHz during the ultrasonic dispersion in the operation a of the step (3).
Example 2
A method for manufacturing a textile detergent comprises the following steps:
(1) preparing an additive:
a. mixing and crushing sweet osmanthus, honeysuckle and lily to obtain a mixture A for later use;
b. b, putting the mixture A obtained in the operation a into boiling water, boiling for 1.8 hours, and filtering to obtain filtrate B for later use;
c. heating and concentrating the filtrate B obtained in the operation B to obtain an additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight for later use: 13 parts of the additive prepared in the step (1), 8 parts of sodium citrate, 7 parts of potassium chloride, 20 parts of glycerol, 3 parts of complex enzyme, 6 parts of nonylphenol polyoxyethylene ether, 5 parts of gelatin, 15 parts of ethanolamine, 8 parts of methyl methacrylate, 6 parts of filler and 530 parts of deionized water;
(3) mixing to prepare a finished product:
a. heating deionized water, then adding the additive prepared in the step (1), sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine, methyl methacrylate and filler together, and performing ultrasonic dispersion uniformly for later use;
b. and d, after the solution obtained in the operation a is cooled to normal temperature, adding the complex enzyme, and uniformly stirring to obtain the finished product detergent.
And (2) in the step (1), when the sweet osmanthus, the honeysuckle and the lily are mixed together, the corresponding weight ratio is 14:5: 3.
The corresponding weight ratio of the mixture A to the boiling water in the operation b in the step (1) is 1: 6.6.
Controlling the volume of the filtrate B to be concentrated to 15% after the heating concentration treatment in the operation c of the step (1).
The filler in the step (2) is attapulgite.
The particle size of the filler in the step (2) is 350 meshes.
The complex enzyme in the step (2) is formed by mixing ficin and hesperidinase according to the weight ratio of 4.5: 1.
The deionized water was maintained at a temperature of 72 ℃ during the heating described in operation a of step (3).
Controlling the frequency of the ultrasonic wave to be 780kHz during the ultrasonic dispersion in the operation a of the step (3).
Example 3
A method for manufacturing a textile detergent comprises the following steps:
(1) preparing an additive:
a. mixing and crushing sweet osmanthus, honeysuckle and lily to obtain a mixture A for later use;
b. b, putting the mixture A obtained in the operation a into boiling water, boiling for 2 hours, and filtering to obtain filtrate B for later use;
c. heating and concentrating the filtrate B obtained in the operation B to obtain an additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight for later use: 15 parts of the additive prepared in the step (1), 9 parts of sodium citrate, 8 parts of potassium chloride, 22 parts of glycerol, 4 parts of complex enzyme, 8 parts of nonylphenol polyoxyethylene ether, 6 parts of gelatin, 16 parts of ethanolamine, 10 parts of methyl methacrylate, 7 parts of filler and 550 parts of deionized water;
(3) mixing to prepare a finished product:
a. heating deionized water, then adding the additive prepared in the step (1), sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine, methyl methacrylate and filler together, and performing ultrasonic dispersion uniformly for later use;
b. and d, after the solution obtained in the operation a is cooled to normal temperature, adding the complex enzyme, and uniformly stirring to obtain the finished product detergent.
And (2) in the step (1), when the sweet osmanthus, the honeysuckle and the lily are mixed together, the corresponding weight ratio is 15:6: 4.
The corresponding weight ratio of the mixture A and the boiling water in the operation b in the step (1) is 1: 7.
Controlling the volume of the filtrate B to be concentrated to 16% after the heating concentration treatment in the operation c of the step (1).
The filler in the step (2) is diatomite.
The particle size of the filler in the step (2) is 400 meshes.
The complex enzyme in the step (2) is formed by mixing ficin and hesperidinase according to the weight ratio of 5: 1.
The deionized water was maintained at a temperature of 75 ℃ during the heating described in operation a of step (3).
Controlling the frequency of the ultrasonic waves to be 800kHz during the ultrasonic dispersion in the operation a of the step (3).
Comparative example 1
This comparative example 1 is compared to example 2 only with the difference that the additive preparation treatment of step (1) is omitted except that the process steps are otherwise identical.
Comparative example 2
This comparative example 2 is different from example 2 only in that the filler component in the raw material weighing in step (2) is omitted, and the steps are the same except for the other steps.
In order to compare the effects of the invention, the detergents prepared in the above example 2 and comparative examples 1-2 were tested, specifically: 5.00g of detergent is correspondingly taken from each group and dispersed in 2500mL of hard water, after the detergent is evenly shaken, 800mL of test solution is respectively measured in three washing barrels of a vertical decontamination machine, when the temperature of the test solution rises to 30 ℃, the cotton cloth (with the mass of m1) with oil stain of known weight and a washing rack are correspondingly put into the washing barrels, the soaking time starts to be counted after the last washing rack is put into the washing barrels, meanwhile, a stirrer is quickly arranged, the decontamination machine is started to start washing after being soaked for 1min, the machine is automatically stopped when 3min, the stirrer is quickly taken down, the washing rack is taken out, the washed cotton cloth with oil stain is clamped on the original airing rack one by one, and the cotton cloth with oil stain is arranged on the corresponding weighing rack and weighed to be m2 after being hung and aired for 3 h. The deoiling rate omega is (m1-m2)/m 1; the specific contrast data for each set are shown in table 1 below:
TABLE 1
Oil removal rate omega (%)
Example 2 33.7
Comparative example 1 24.5
Comparative example 2 18.1
As can be seen from the above table 1, the detergent prepared by the method of the invention has good cleaning and oil removing effects, and has the characteristics of good taste, safe use performance and environmental protection when in use.

Claims (9)

1. The manufacturing method of the textile detergent is characterized by comprising the following steps:
(1) preparing an additive:
a. mixing and crushing sweet osmanthus, honeysuckle and lily to obtain a mixture A for later use;
b. b, putting the mixture A obtained in the operation a into boiling water, boiling for 1.5-2 h, and filtering to obtain a filtrate B for later use;
c. heating and concentrating the filtrate B obtained in the operation B to obtain an additive for later use;
(2) weighing raw materials:
weighing the following raw materials in parts by weight for later use: 10-15 parts of the additive prepared in the step (1), 6-9 parts of sodium citrate, 5-8 parts of potassium chloride, 18-22 parts of glycerol, 2-4 parts of complex enzyme, 4-8 parts of nonylphenol polyoxyethylene ether, 3-6 parts of gelatin, 12-16 parts of ethanolamine, 5-10 parts of methyl methacrylate, 4-7 parts of filler and 500-550 parts of deionized water;
(3) mixing to prepare a finished product:
a. heating deionized water, then adding the additive prepared in the step (1), sodium citrate, potassium chloride, glycerol, nonylphenol polyoxyethylene ether, gelatin, ethanolamine, methyl methacrylate and filler together, and performing ultrasonic dispersion uniformly for later use;
b. and d, after the solution obtained in the operation a is cooled to normal temperature, adding the complex enzyme, and uniformly stirring to obtain the finished product detergent.
2. The manufacturing method of the textile detergent according to claim 1, wherein the weight ratio of the osmanthus fragrans, the honeysuckle and the lily in the operation a in the step (1) is 10-15: 3-6: 2-4.
3. The method for manufacturing the textile detergent according to claim 1, wherein the corresponding weight ratio of the mixed material A and the boiling water in the step (1) and the operation b is 1: 6-7.
4. The method for preparing a textile detergent as claimed in claim 1, wherein the volume of the filtrate B is controlled to be concentrated to 12-16% of the original volume after the heating concentration treatment in the operation c of the step (1).
5. The method for preparing a textile detergent according to claim 1, wherein the filler in the step (2) is any one of kaolin, attapulgite and diatomite.
6. The method for preparing a textile detergent as claimed in claim 1, wherein the particle size of the filler in step (2) is 300-400 mesh.
7. The method for preparing the textile detergent as claimed in claim 1, wherein the complex enzyme in the step (2) is prepared by mixing ficin and hesperidinase according to a weight ratio of 4-5: 1.
8. The method for preparing a textile detergent as claimed in claim 1, wherein the temperature of the deionized water is maintained at 70-75 ℃ during the heating in operation a of step (3).
9. The method for preparing a textile detergent according to claim 1, wherein the frequency of the ultrasonic waves is controlled to be 700 to 800kHz during the ultrasonic dispersion in the operation a of the step (3).
CN202011181969.5A 2020-10-29 2020-10-29 Method for preparing textile detergent Pending CN112175747A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107012027A (en) * 2017-04-28 2017-08-04 袁晓霞 A kind of bedding detergent
CN108102805A (en) * 2017-12-05 2018-06-01 徐云丽 Detergent composition
CN110964607A (en) * 2019-11-01 2020-04-07 付世宁 Laundry detergent with sterilization function and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107012027A (en) * 2017-04-28 2017-08-04 袁晓霞 A kind of bedding detergent
CN108102805A (en) * 2017-12-05 2018-06-01 徐云丽 Detergent composition
CN110964607A (en) * 2019-11-01 2020-04-07 付世宁 Laundry detergent with sterilization function and preparation method thereof

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Application publication date: 20210105