CN112175511A - Marine industrial paint with strong antifouling effect - Google Patents
Marine industrial paint with strong antifouling effect Download PDFInfo
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- CN112175511A CN112175511A CN202011260403.1A CN202011260403A CN112175511A CN 112175511 A CN112175511 A CN 112175511A CN 202011260403 A CN202011260403 A CN 202011260403A CN 112175511 A CN112175511 A CN 112175511A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/04—Polysulfides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a marine industrial paint with strong antifouling effect, which comprises a component A, a component B and a component C; the component A comprises the following components: the coating comprises a water-based isocyanate curing agent, inorganic salt powder, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent, titanium dioxide, an alcohol ester dodecafilming aid and a flash rust inhibitor; the component B comprises the following components: methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium dodecyl sulfate, an ammonium persulfate initiator, deionized water and sodium acetate; the component C is polysulfide rubber emulsion. The industrial paint for the ship has the advantages of excellent corrosion resistance, environmental protection, good flexibility and strong adhesive force, particularly, the addition of the polysulfide rubber emulsion has good intersolubility with the traditional acrylate components, and after the polysulfide rubber and the epoxy resin are mixed, the thiol group (-SH) at the tail end can have chemical action with an epoxy group, so that the crosslinked epoxy resin has better flexibility and impermeability.
Description
Technical Field
The invention relates to the technical field of industrial paint, in particular to marine industrial paint with a strong antifouling effect.
Background
The application of the water-based anticorrosive paint in the field of anticorrosive paint is on the rise, particularly, with the development of the ship industry and the improvement of social environmental protection requirements, the water-based industrial anticorrosive paint is required to provide effective protection for steel under extreme conditions, water is a main solvent of the water-based industrial anticorrosive paint, water can also be used for cleaning and diluting the water-based paint, the water-based industrial anticorrosive paint has almost no solvent taste, meanwhile, the use of the water-based paint can bring lower cost for users, such as quick drying can save time, low flammability can reduce insurance cost, less indoor ventilation can reduce energy consumption, and the cost on the solvent and cleaning agent is not needed, a single-layer coating is matched, the downtime and the cost for erecting scaffolds can be saved, the research of the water-based anticorrosive paint has become a great trend of the development of the paint industry, and the application prospect.
In order to improve the antifouling effect of the traditional anticorrosive paint, the invention provides the industrial paint for the ship, which has a strong antifouling effect.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides the marine industrial paint with a strong antifouling effect.
The technical scheme of the invention is as follows:
the marine industrial paint with strong antifouling effect comprises a component A, a component B and a component C;
the component A comprises the following components in parts by mass: 15-20 parts of water-based isocyanate curing agent, 20-30 parts of inorganic salt powder, 0.2-0.5 part of organic silicon defoamer, 5-12 parts of polyhydroxy acid ammonium salt dispersant, 10-15 parts of titanium dioxide, 6-10 parts of alcohol ester dodecafilming aid and 2-5 parts of flash rust inhibitor;
the component B comprises the following components in parts by mass: 10-20 parts of methyl methacrylate, 10-15 parts of styrene, 2-5 parts of itaconic acid, 2-5 parts of methacrylic acid, 3-5 parts of sodium dodecyl sulfate, 0.2-0.4 part of ammonium persulfate initiator, 320-350 parts of deionized water and 0.1-0.5 part of sodium acetate;
the component C is polysulfide rubber emulsion.
Preferably, the industrial paint for the ship consists of the following components in percentage by weight: 60-70% of component A, 10-15% of component B and the balance of component C.
Preferably, the inorganic salt powder is a mixed powder of zinc oxide, aluminum oxide, tin dioxide and silicon dioxide.
Preferably, the preparation method of the polysulfide rubber emulsion comprises the following steps: uniformly mixing 100 parts of polysulfide rubber, 2-3 parts of emulsifier and 4-6 parts of polyvinyl alcohol, pre-emulsifying for 30-45min at 50-70 ℃, then stirring and dropwise adding 0.5-1 part of defoamer, stirring and dropwise adding 150 parts of deionized water after the defoamer is completely added, and stirring for 2-3h at the rotating speed of 2000 plus 2500rpm after the deionized water is completely added to obtain the polysulfide rubber emulsion.
A preparation method of a superstrong anticorrosive marine water-based paint comprises the following steps:
step one, mixing a water-based isocyanate curing agent, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent and an alcohol ester dodecafilming aid, and then uniformly stirring; then adding inorganic salt powder, titanium dioxide and flash rust inhibitor, grinding and filtering to obtain a component A;
step two, mixing deionized water, methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium acetate and sodium dodecyl sulfate, stirring uniformly, heating to 80-85 ℃, slowly adding ammonium persulfate initiator solution within 60-90min, reacting for 8-12h, and standing for 3-5h to obtain a component B;
and step three, mixing the component A and the component C, then slowly adding the component B, controlling the adding time to be 10-15min, and then continuously stirring at 600-800rpm for 25-35 min.
Preferably, the ammonium persulfate initiator solution is prepared by adding 60-100 times of deionized water into an ammonium persulfate initiator and uniformly mixing; and D, combining the deionized water in the ammonium persulfate initiator solution with part of the deionized water in the step II to obtain the total deionized water.
The invention has the advantages that: the industrial paint with strong antifouling effect for the ship has the advantages of excellent anticorrosion performance, environmental protection, good flexibility and strong adhesive force, particularly, the addition of the polysulfide rubber emulsion has good intersolubility with the traditional acrylate components, and after the polysulfide rubber and the epoxy resin are mixed, thiol (-SH) at the tail end can have chemical action with an epoxy group, so that the crosslinked epoxy resin has better flexibility and impermeability.
Detailed Description
Example 1
The marine industrial paint with strong antifouling effect comprises a component A, a component B and a component C;
the component A comprises the following components in parts by mass: 18 parts of water-based isocyanate curing agent, 25 parts of inorganic salt powder, 0.35 part of organic silicon defoamer, 8 parts of polyhydroxy acid ammonium salt dispersant, 12 parts of titanium dioxide, 8 parts of alcohol ester dodecafilming aid and 3 parts of flash rust inhibitor;
the component B comprises the following components in parts by mass: 15 parts of methyl methacrylate, 12 parts of styrene, 3 parts of itaconic acid, 4 parts of methacrylic acid, 4 parts of sodium dodecyl sulfate, 0.35 part of ammonium persulfate initiator, 330 parts of deionized water and 0.25 part of sodium acetate;
the component C is polysulfide rubber emulsion.
The industrial paint for the ship comprises the following components in percentage by weight: 65% of component A, 12% of component B and the balance of component C.
The inorganic salt powder is mixed powder of zinc oxide, aluminum oxide, tin dioxide and silicon dioxide.
The preparation method of the polysulfide rubber emulsion comprises the following steps: 100 parts of polysulfide rubber, 2.5 parts of emulsifier and 5 parts of polyvinyl alcohol are uniformly mixed, pre-emulsified for 35min at 65 ℃, stirred and dropwise added with 0.8 part of defoaming agent, stirred and dropwise added with 120 parts of deionized water after the defoaming agent is dropwise added, and stirred for 2.5h at the rotating speed of 2250rpm after the deionized water is dropwise added, so that the polysulfide rubber emulsion is obtained.
A preparation method of a superstrong anticorrosive marine water-based paint comprises the following steps:
step one, mixing a water-based isocyanate curing agent, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent and an alcohol ester dodecafilming aid, and then uniformly stirring; then adding inorganic salt powder, titanium dioxide and flash rust inhibitor, grinding and filtering to obtain a component A;
step two, mixing deionized water, methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium acetate and sodium dodecyl sulfate, stirring uniformly, heating to 82 ℃, slowly adding ammonium persulfate initiator solution within 70min, reacting for 10h, and standing for 3.5h to obtain a component B;
and step three, mixing the component A and the component C, then slowly adding the component B, controlling the adding time to be 12min, and then continuously stirring at 750rpm for 30 min.
The ammonium persulfate initiator solution is prepared by adding 80 times of deionized water into an ammonium persulfate initiator and uniformly mixing; and D, combining the deionized water in the ammonium persulfate initiator solution with part of the deionized water in the step II to obtain the total deionized water.
Example 2
The marine industrial paint with strong antifouling effect comprises a component A, a component B and a component C;
the component A comprises the following components in parts by mass: 20 parts of water-based isocyanate curing agent, 20 parts of inorganic salt powder, 0.5 part of organic silicon defoamer, 5 parts of polyhydroxy acid ammonium salt dispersant, 15 parts of titanium dioxide, 6 parts of alcohol ester dodecafilming aid and 5 parts of flash rust inhibitor;
the component B comprises the following components in parts by mass: 10 parts of methyl methacrylate, 15 parts of styrene, 2 parts of itaconic acid, 5 parts of methacrylic acid, 3 parts of sodium dodecyl sulfate, 0.4 part of ammonium persulfate initiator, 320 parts of deionized water and 0.5 part of sodium acetate;
the component C is polysulfide rubber emulsion.
The industrial paint for the ship comprises the following components in percentage by weight: 60 percent of component A, 15 percent of component B and the balance of component C.
The inorganic salt powder is mixed powder of zinc oxide, aluminum oxide, tin dioxide and silicon dioxide.
The preparation method of the polysulfide rubber emulsion comprises the following steps: 100 parts of polysulfide rubber, 2 parts of emulsifier and 6 parts of polyvinyl alcohol are uniformly mixed, pre-emulsified for 45min at 50 ℃, stirred and dropwise added with 0.5 part of defoaming agent, stirred and dropwise added with 150 parts of deionized water after the defoaming agent is dropwise added, and stirred for 3h at the rotating speed of 2000rpm after the deionized water is dropwise added, so that the polysulfide rubber emulsion is obtained.
A preparation method of a superstrong anticorrosive marine water-based paint comprises the following steps:
step one, mixing a water-based isocyanate curing agent, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent and an alcohol ester dodecafilming aid, and then uniformly stirring; then adding inorganic salt powder, titanium dioxide and flash rust inhibitor, grinding and filtering to obtain a component A;
step two, mixing deionized water, methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium acetate and sodium dodecyl sulfate, stirring uniformly, heating to 80 ℃, slowly adding ammonium persulfate initiator solution within 90min, reacting for 8h, and standing for 5h to obtain a component B;
and step three, mixing the component A and the component C, then slowly adding the component B, controlling the adding time to be 10min, and then continuously stirring at 800rpm for 25 min.
The ammonium persulfate initiator solution is prepared by adding 100 times of deionized water into an ammonium persulfate initiator and uniformly mixing; and D, combining the deionized water in the ammonium persulfate initiator solution with part of the deionized water in the step II to obtain the total deionized water.
Example 3
The marine industrial paint with strong antifouling effect comprises a component A, a component B and a component C;
the component A comprises the following components in parts by mass: 15 parts of water-based isocyanate curing agent, 30 parts of inorganic salt powder, 0.2 part of organic silicon defoamer, 12 parts of polyhydroxy acid ammonium salt dispersant, 10 parts of titanium dioxide, 10 parts of alcohol ester dodecafilming aid and 2 parts of flash rust inhibitor;
the component B comprises the following components in parts by mass: 20 parts of methyl methacrylate, 10 parts of styrene, 5 parts of itaconic acid, 2 parts of methacrylic acid, 5 parts of sodium dodecyl sulfate, 0.2 part of ammonium persulfate initiator, 350 parts of deionized water and 0.1 part of sodium acetate;
the component C is polysulfide rubber emulsion.
The industrial paint for the ship comprises the following components in percentage by weight: 70 percent of component A, 10 percent of component B and the balance of component C.
The inorganic salt powder is mixed powder of zinc oxide, aluminum oxide, tin dioxide and silicon dioxide.
The preparation method of the polysulfide rubber emulsion comprises the following steps: uniformly mixing 100 parts of polysulfide rubber, 3 parts of emulsifier and 4 parts of polyvinyl alcohol, pre-emulsifying for 30min at 70 ℃, then stirring and dropwise adding 1 part of defoaming agent, stirring and dropwise adding 100 parts of deionized water after the defoaming agent is dropwise added, and stirring for 2h at the rotating speed of 2500rpm after the deionized water is dropwise added to obtain the polysulfide rubber emulsion.
A preparation method of a superstrong anticorrosive marine water-based paint comprises the following steps:
step one, mixing a water-based isocyanate curing agent, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent and an alcohol ester dodecafilming aid, and then uniformly stirring; then adding inorganic salt powder, titanium dioxide and flash rust inhibitor, grinding and filtering to obtain a component A;
step two, mixing deionized water, methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium acetate and sodium dodecyl sulfate, stirring uniformly, heating to 85 ℃, slowly adding ammonium persulfate initiator solution within 60min, reacting for 12h, and standing for 3h to obtain a component B;
and step three, mixing the component A and the component C, then slowly adding the component B, controlling the adding time to be 15min, and then continuously stirring at 600rpm for 35 min.
The ammonium persulfate initiator solution is prepared by adding 60 times of deionized water into an ammonium persulfate initiator and uniformly mixing; and D, combining the deionized water in the ammonium persulfate initiator solution with part of the deionized water in the step II to obtain the total deionized water.
The paint films of examples 1 to 3 were examined below, and the following examination results were obtained.
Table 1: paint film test results of examples 1 to 3;
| adhesion force | Surface dryness/min | Salt tolerance | Acid resistance | Alkali resistance | |
| Example 1 | Level 1 | <30min | >90d | >90d | >90d |
| Example 2 | Level 1 | <30min | >90d | >90d | >90d |
| Example 3 | Level 1 | <30min | >90d | >90d | >90d |
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (6)
1. The marine industrial paint with strong antifouling effect is characterized by comprising a component A, a component B and a component C;
the component A comprises the following components in parts by mass: 15-20 parts of water-based isocyanate curing agent, 20-30 parts of inorganic salt powder, 0.2-0.5 part of organic silicon defoamer, 5-12 parts of polyhydroxy acid ammonium salt dispersant, 10-15 parts of titanium dioxide, 6-10 parts of alcohol ester dodecafilming aid and 2-5 parts of flash rust inhibitor;
the component B comprises the following components in parts by mass: 10-20 parts of methyl methacrylate, 10-15 parts of styrene, 2-5 parts of itaconic acid, 2-5 parts of methacrylic acid, 3-5 parts of sodium dodecyl sulfate, 0.2-0.4 part of ammonium persulfate initiator, 320-350 parts of deionized water and 0.1-0.5 part of sodium acetate;
the component C is polysulfide rubber emulsion.
2. The industrial paint for ships with strong antifouling effect according to claim 1, wherein the industrial paint for ships comprises the following components in percentage by weight: 60-70% of component A, 10-15% of component B and the balance of component C.
3. The industrial paint for ships having a strong antifouling effect according to claim 1, wherein the inorganic salt powder is a mixed powder of zinc oxide, aluminum oxide, tin dioxide and silicon dioxide.
4. The industrial paint for ships having strong antifouling effect according to claim 1, wherein the preparation method of the polysulfide rubber emulsion comprises the following steps: uniformly mixing 100 parts of polysulfide rubber, 2-3 parts of emulsifier and 4-6 parts of polyvinyl alcohol, pre-emulsifying for 30-45min at 50-70 ℃, then stirring and dropwise adding 0.5-1 part of defoamer, stirring and dropwise adding 150 parts of deionized water after the defoamer is completely added, and stirring for 2-3h at the rotating speed of 2000 plus 2500rpm after the deionized water is completely added to obtain the polysulfide rubber emulsion.
5. A preparation method of a superstrong anticorrosive marine water-based paint is characterized by comprising the following steps:
step one, mixing a water-based isocyanate curing agent, an organic silicon defoaming agent, a polyhydroxy acid ammonium salt dispersing agent and an alcohol ester dodecafilming aid, and then uniformly stirring; then adding inorganic salt powder, titanium dioxide and flash rust inhibitor, grinding and filtering to obtain a component A;
step two, mixing deionized water, methyl methacrylate, styrene, itaconic acid, methacrylic acid, sodium acetate and sodium dodecyl sulfate, stirring uniformly, heating to 80-85 ℃, slowly adding ammonium persulfate initiator solution within 60-90min, reacting for 8-12h, and standing for 3-5h to obtain a component B;
and step three, mixing the component A and the component C, then slowly adding the component B, controlling the adding time to be 10-15min, and then continuously stirring at 600-800rpm for 25-35 min.
6. The preparation method of the marine waterborne coating with ultra-strong corrosion resistance as claimed in claim 5, wherein the ammonium persulfate initiator solution is prepared by adding 60-100 times of deionized water into an ammonium persulfate initiator and uniformly mixing; and D, combining the deionized water in the ammonium persulfate initiator solution with part of the deionized water in the step II to obtain the total deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011260403.1A CN112175511A (en) | 2020-11-12 | 2020-11-12 | Marine industrial paint with strong antifouling effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011260403.1A CN112175511A (en) | 2020-11-12 | 2020-11-12 | Marine industrial paint with strong antifouling effect |
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| CN112175511A true CN112175511A (en) | 2021-01-05 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388196A (en) * | 2002-07-01 | 2003-01-01 | 湖北大学 | Low-surface energy antifouling seagoing ship paint and its prepn |
| CN1470566A (en) * | 2003-06-25 | 2004-01-28 | 华南理工大学 | Polysulfide rubber emulsion and its preparing method |
| CN102391762A (en) * | 2011-09-23 | 2012-03-28 | 北京国泰瑞华硅藻应用科技有限公司 | Epoxy abrasion-resisting anticorrosive paint |
| CN103087611A (en) * | 2013-01-22 | 2013-05-08 | 四川大学 | Water-borne epoxy resin paint and preparation method thereof |
| US20150191607A1 (en) * | 2002-09-09 | 2015-07-09 | Reactive Surfaces, Ltd | Anti-fouling Paints and Coatings |
| CN110698946A (en) * | 2019-09-17 | 2020-01-17 | 湖州市南浔联谊喷涂厂 | Superstrong anti-corrosion marine water-based paint and preparation method thereof |
-
2020
- 2020-11-12 CN CN202011260403.1A patent/CN112175511A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388196A (en) * | 2002-07-01 | 2003-01-01 | 湖北大学 | Low-surface energy antifouling seagoing ship paint and its prepn |
| US20150191607A1 (en) * | 2002-09-09 | 2015-07-09 | Reactive Surfaces, Ltd | Anti-fouling Paints and Coatings |
| CN1470566A (en) * | 2003-06-25 | 2004-01-28 | 华南理工大学 | Polysulfide rubber emulsion and its preparing method |
| CN102391762A (en) * | 2011-09-23 | 2012-03-28 | 北京国泰瑞华硅藻应用科技有限公司 | Epoxy abrasion-resisting anticorrosive paint |
| CN103087611A (en) * | 2013-01-22 | 2013-05-08 | 四川大学 | Water-borne epoxy resin paint and preparation method thereof |
| CN110698946A (en) * | 2019-09-17 | 2020-01-17 | 湖州市南浔联谊喷涂厂 | Superstrong anti-corrosion marine water-based paint and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| M 利温: "《纺织品功能整理 上册》", 30 May 1992, 纺织工业出版社 * |
| 冯瑞华: "《中国科学院科学传播系列丛书 新材料》", 30 June 2015, 科学普及出版社 * |
| 雷霆: "《锡冶金》", 30 December 2013, 冶金工业出版社 * |
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