CN112174575A - Photocuring clay printing material and preparation method thereof - Google Patents
Photocuring clay printing material and preparation method thereof Download PDFInfo
- Publication number
- CN112174575A CN112174575A CN202011029926.5A CN202011029926A CN112174575A CN 112174575 A CN112174575 A CN 112174575A CN 202011029926 A CN202011029926 A CN 202011029926A CN 112174575 A CN112174575 A CN 112174575A
- Authority
- CN
- China
- Prior art keywords
- parts
- clay
- kaolin
- printing material
- photocuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00181—Mixtures specially adapted for three-dimensional printing (3DP), stereo-lithography or prototyping
Abstract
The invention relates to the technical field of photocuring clay, in particular to a photocuring clay printing material which is prepared from the following raw materials in parts by weight: 60-75 parts of kaolin, 15-25 parts of ball clay, 5-10 parts of zirconia particles, 5-10 parts of superfine carbon fibers, 25-35 parts of a photo-curing resin prepolymer, 20-30 parts of a reactive diluent, 0.15-0.25 part of a photoinitiator, 2.5-5.5 parts of a dispersing agent and 0-10 parts of a pigment; the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 40-55 parts of epoxy resin, 0-20 parts of polyether acrylate, 0-18 parts of acrylic resin, 0-15 parts of polyester acrylate and 0-15 parts of polyurethane acrylate. The kaolin and the ball clay are compounded, the zirconia micro powder and the superfine carbon fibers are added simultaneously, the mechanical property of the clay is improved, the mixture is mechanically beaten during processing, and the processing property of the material is improved.
Description
Technical Field
The invention relates to the technical field of photocuring clay, in particular to a photocuring clay printing material and a preparation method thereof.
Background
With the continuous development of the three-dimensional printing technology, the clay material is more and more widely applied to the three-dimensional printing technology, wherein the photocuring forming curing speed is high, the energy utilization rate is high, and the organic volatile is less, so that the method is an energy-saving, environment-friendly and efficient curing forming method. Unprocessed clay materials are not suitable for 3D printing, so clay materials dedicated to 3D printing are available on the market.
Chinese patent, a clay material for 3D printing and a preparation method thereof (patent number: CN201710692211.X), discloses a clay material specially used for 3D printing, wherein kaolin is used as a main raw material, but the plasticity and cohesiveness of kaolin are poor, so that the mechanical property of a processed product is poor.
Therefore, we propose a photo-curing clay printing material and a preparation method thereof to solve the above problems.
Disclosure of Invention
The invention aims to solve the defects in the prior art and provides a photocuring clay printing material and a preparation method thereof.
The photo-curing clay printing material is prepared from the following raw materials in parts by weight: 60-75 parts of kaolin, 15-25 parts of ball clay, 5-10 parts of zirconia particles, 5-10 parts of superfine carbon fibers, 25-35 parts of a photo-curing resin prepolymer, 20-30 parts of a reactive diluent, 0.15-0.25 part of a photoinitiator, 2.5-5.5 parts of a dispersing agent and 0-10 parts of a pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 40-55 parts of epoxy resin, 0-20 parts of polyether acrylate, 0-18 parts of acrylic resin, 0-15 parts of polyester acrylate and 0-15 parts of polyurethane acrylate.
Preferably, the diameter of the superfine carbon fiber is 5-9 μm, and the length of the powder is 10-2500 μm.
Preferably, the reactive diluent is one of TMPTA, TPGDA and HDDA.
Preferably, the photoinitiator is one or a mixture of TPO, TPO-L, 819, diaryl iodonium salt and triaryl sulfonium salt.
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles into particles with the particle size of 2-15 mu m to obtain mixed micro powder;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 5-15 min, adding the superfine carbon fiber in proportion, mechanically stirring for 15-30 min, then adding the pigment in proportion, and mechanically stirring for 5-15 min;
s3, mechanically beating the mixture obtained in the step S2 for 20-30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 90-120 min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
Preferably, in the step S1, kaolin, ball clay, and zirconia particles are put into a ball mill and pulverized to a particle size of 2 to 15 μm.
Preferably, in the step S1, kaolin, ball clay and zirconia particles are first put into a ball mill and pulverized into particles with a size of 175 to 246 μm, and then pulverized into particles with a size of 2 to 15 μm by a jet mill.
The invention has the beneficial effects that:
1. the kaolin and the ball clay are compounded, so that the plasticity and the cohesiveness of a clay material are improved, and meanwhile, the zirconia micro powder and the superfine carbon fibers are added into the clay, so that the mechanical property of the clay is further improved.
2. Adopt the mode that mechanical stirring and supersound stirring combined to stir the material, guarantee stirring efficiency and mixing uniformity simultaneously, carry out mechanical beating to the mixture between mechanical stirring and supersound stirring, can alleviate clay miropowder and reunite the phenomenon, promote the processability of material.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
The first embodiment is as follows:
the photo-curing clay printing material is prepared from the following raw materials in parts by weight: 60 parts of kaolin, 25 parts of ball clay, 7 parts of zirconia particles, 8 parts of superfine carbon fibers, 30 parts of a light-cured resin prepolymer, 25 parts of an active diluent, 0.2 part of a photoinitiator, 4.5 parts of a dispersant and 2 parts of a pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 50 parts of epoxy resin, 15 parts of acrylic resin and 10 parts of polyester acrylate.
In this example, the diameter of the ultrafine carbon fiber is between 5 μm and 9 μm, the length of the powder is between 10 μm and 2500 μm, the reactive diluent is TMPTA, the photoinitiator is composed of TPO and triarylsulfonium salt, the weight ratio of TPO to triarylsulfonium salt is 1:4, and the dispersant is PMAA-NH4。
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles to obtain mixed micro powder, wherein the particle size of the crushed particles is 2-15 mu m;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 10min, then adding the superfine carbon fiber in proportion, mechanically stirring for 25min, then adding the pigment in proportion, and mechanically stirring for 10 min;
s3, mechanically beating the mixture obtained in the S2 step for 30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 110min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
In this example, in step S1, kaolin, ball clay, and zirconia particles were placed in a ball mill and pulverized to a particle size of 2 μm to 15 μm.
Example two:
the photo-curing clay printing material is prepared from the following raw materials in parts by weight: 65 parts of kaolin, 22 parts of ball clay, 7 parts of zirconia particles, 6 parts of superfine carbon fibers, 30 parts of a light-cured resin prepolymer, 25 parts of an active diluent, 0.2 part of a photoinitiator, 4.5 parts of a dispersant and 2 parts of a pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 45 parts of epoxy resin, 10 parts of polyether acrylate, 5 parts of acrylic resin, 5 parts of polyester acrylate and 5 parts of polyurethane acrylate.
In this example, the diameter of the ultrafine carbon fiber is between 5 μm and 9 μm, the length of the powder is between 10 μm and 2500 μm, the reactive diluent is TPGDA, the photoinitiator is composed of TPO and triarylsulfonium salt, the weight ratio of TPO to triarylsulfonium salt is 5:9, and the dispersant is PMAA-NH4。
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles to obtain mixed micro powder, wherein the particle size of the crushed particles is 2-15 mu m;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 10min, then adding the superfine carbon fiber in proportion, mechanically stirring for 25min, then adding the pigment in proportion, and mechanically stirring for 10 min;
s3, mechanically beating the mixture obtained in the S2 step for 30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 110min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
In this example, in step S1, kaolin, ball clay, and zirconia particles were placed in a ball mill and pulverized to a particle size of 2 μm to 15 μm.
Example three:
the photo-curing clay printing material is prepared from the following raw materials in parts by weight: 70 parts of kaolin, 15 parts of ball clay, 8 parts of zirconia particles, 7 parts of superfine carbon fibers, 32 parts of light-cured resin prepolymer, 28 parts of active diluent, 0.22 part of photoinitiator, 3.5 parts of dispersant and 2 parts of pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 45 parts of epoxy resin, 10 parts of polyether acrylate, 5 parts of acrylic resin, 5 parts of polyester acrylate and 5 parts of polyurethane acrylate.
This implementationIn the example, the diameter of the superfine carbon fiber is between 5 μm and 9 μm, the length of the powder is between 10 μm and 2500 μm, the active diluent is TPGDA, the photoinitiator is composed of TPO and triarylsulfonium salt, the weight ratio of TPO to triarylsulfonium salt is 5:9, and the dispersant is PMAA-NH4。
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles to obtain mixed micro powder, wherein the particle size of the crushed particles is 2-15 mu m;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 10min, then adding the superfine carbon fiber in proportion, mechanically stirring for 25min, then adding the pigment in proportion, and mechanically stirring for 10 min;
s3, mechanically beating the mixture obtained in the S2 step for 30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 110min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
In this example, in step S1, kaolin, ball clay, and zirconia particles were first put into a ball mill and pulverized to a particle size of 175 to 246 μm, and then pulverized to a particle size of 2 to 15 μm with a jet mill.
Example four:
the photo-curing clay printing material is prepared from the following raw materials in parts by weight: 70 parts of kaolin, 15 parts of ball clay, 8 parts of zirconia particles, 7 parts of superfine carbon fibers, 32 parts of light-cured resin prepolymer, 28 parts of active diluent, 0.22 part of photoinitiator, 3.5 parts of dispersant and 2 parts of pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 40 parts of epoxy resin, 5 parts of polyether acrylate, 15 parts of acrylic resin and 5 parts of polyurethane acrylate.
In this embodiment, the diameter of the ultrafine carbon fibers is 5 μm to 9Mu m, the length of the powder is between 10 mu m and 2500 mu m, the active diluent is HDDA, the photoinitiator consists of TPO and triarylsulfonium salt, the weight ratio of TPO to triarylsulfonium salt is 5:8, and the dispersant is PMAA-NH4。
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles to obtain mixed micro powder, wherein the particle size of the crushed particles is 2-15 mu m;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 10min, then adding the superfine carbon fiber in proportion, mechanically stirring for 25min, then adding the pigment in proportion, and mechanically stirring for 10 min;
s3, mechanically beating the mixture obtained in the S2 step for 30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 110min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
In this example, in step S1, kaolin, ball clay, and zirconia particles were first put into a ball mill and pulverized to a particle size of 175 to 246 μm, and then pulverized to a particle size of 2 to 15 μm with a jet mill.
Example five:
the photo-curing clay printing material is prepared from the following raw materials in parts by weight: 75 parts of kaolin, 15 parts of ball clay, 5 parts of zirconia particles, 5 parts of superfine carbon fibers, 35 parts of a light-cured resin prepolymer, 30 parts of an active diluent, 0.25 part of a photoinitiator, 3 parts of a dispersant and 2 parts of a pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 40 parts of epoxy resin, 5 parts of polyether acrylate, 15 parts of acrylic resin and 5 parts of polyurethane acrylate.
In this embodiment, the diameter of the ultrafine carbon fiber is between 5 μm and 9 μm, and the length of the powder is between 10 μm and 2500 μmThe active diluent is HDDA, the photoinitiator consists of TPO and diaryl iodonium salt, the weight ratio of TPO to diaryl iodonium salt is 5:8, and the dispersant is PMAA-NH4。
A preparation method of a photocuring clay printing material comprises the following steps:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles to obtain mixed micro powder, wherein the particle size of the crushed particles is 2-15 mu m;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 10min, then adding the superfine carbon fiber in proportion, mechanically stirring for 25min, then adding the pigment in proportion, and mechanically stirring for 10 min;
s3, mechanically beating the mixture obtained in the S2 step for 30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 110min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
In this example, in step S1, kaolin, ball clay, and zirconia particles were first put into a ball mill and pulverized to a particle size of 175 to 246 μm, and then pulverized to a particle size of 2 to 15 μm with a jet mill.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (7)
1. The photocuring clay printing material is characterized by comprising the following raw materials in parts by weight: 60-75 parts of kaolin, 15-25 parts of ball clay, 5-10 parts of zirconia particles, 5-10 parts of superfine carbon fibers, 25-35 parts of a photo-curing resin prepolymer, 20-30 parts of a reactive diluent, 0.15-0.25 part of a photoinitiator, 2.5-5.5 parts of a dispersing agent and 0-10 parts of a pigment;
the light-cured resin prepolymer is prepared from the following raw materials in parts by weight: 40-55 parts of epoxy resin, 0-20 parts of polyether acrylate, 0-18 parts of acrylic resin, 0-15 parts of polyester acrylate and 0-15 parts of polyurethane acrylate.
2. The photo-curing clay printing material as claimed in claim 1, wherein the ultrafine carbon fibers have a diameter of 5 μm to 9 μm and a powder length of 10 μm to 2500 μm.
3. The photo-curable clay printing material according to claim 1, wherein the reactive diluent is one of TMPTA, TPGDA and HDDA.
4. The photo-curable clay printing material as claimed in claim 1, wherein the photo-initiator is one or more selected from TPO, TPO-L, 819, diaryliodonium salt and triarylsulfonium salt.
5. The preparation method of the photocuring clay printing material is characterized by comprising the following steps of:
s1, proportionally taking kaolin, ball clay and zirconia particles, putting the kaolin, ball clay and zirconia particles into a crushing device, and crushing the kaolin, ball clay and zirconia particles into particles with the particle size of 2-15 mu m to obtain mixed micro powder;
s2, putting the mixed micro powder, the photo-curing resin prepolymer, the active diluent and the dispersing agent into a mechanical stirrer in proportion, mechanically stirring for 5-15 min, adding the superfine carbon fiber in proportion, mechanically stirring for 15-30 min, then adding the pigment in proportion, and mechanically stirring for 5-15 min;
s3, mechanically beating the mixture obtained in the step S2 for 20-30 min;
s4, transferring the mixture obtained in the step S3 to an ultrasonic stirrer, adding a photoinitiator in proportion, and ultrasonically stirring for 90-120 min to obtain a photocuring clay printing material;
and S5, placing the prepared photocuring clay printing material on a vibration platform.
6. The method of claim 5, wherein in the step S1, the kaolin, ball clay and zirconia particles are ball-milled to a particle size of 2 μm to 15 μm.
7. The method of claim 5, wherein in step S1, the kaolin, ball clay, and zirconia particles are ball milled to particle size of 175-246 μm, and then milled to particle size of 2-15 μm with a jet mill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011029926.5A CN112174575A (en) | 2020-09-27 | 2020-09-27 | Photocuring clay printing material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011029926.5A CN112174575A (en) | 2020-09-27 | 2020-09-27 | Photocuring clay printing material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112174575A true CN112174575A (en) | 2021-01-05 |
Family
ID=73943590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011029926.5A Pending CN112174575A (en) | 2020-09-27 | 2020-09-27 | Photocuring clay printing material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112174575A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115304392A (en) * | 2021-05-08 | 2022-11-08 | 中国石油化工股份有限公司 | Kaolin-based 3D printing powder and integral active porous material prepared from same |
| CN115304392B (en) * | 2021-05-08 | 2024-05-17 | 中国石油化工股份有限公司 | Kaolin-based 3D printing powder and integral active porous material prepared from same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105541298A (en) * | 2015-12-24 | 2016-05-04 | 成都新柯力化工科技有限公司 | Continuous inorganic fiber reinforced ceramic and 3D (3-Dimensional) printing forming method for same |
| CN105693945A (en) * | 2016-02-05 | 2016-06-22 | 湖南正阳精密陶瓷有限公司 | Photo-curing material and preparation method and application thereof |
| TW201702049A (en) * | 2015-07-14 | 2017-01-16 | 優克材料科技股份有限公司 | Three dimensional printing composite and three dimensional printing object |
| CN108147830A (en) * | 2018-01-17 | 2018-06-12 | 龙泉市金宏瓷业有限公司 | A kind of 3D printing ceramic setter composite material and preparation method thereof |
| KR20200029656A (en) * | 2018-09-05 | 2020-03-19 | 서울대학교산학협력단 | Bioink compositions for visible light curing for 3D printing and method of manufacturing the same |
| CN111690096A (en) * | 2020-05-20 | 2020-09-22 | 广西春景环保科技有限公司 | Preparation method of 3D printing photosensitive resin material |
-
2020
- 2020-09-27 CN CN202011029926.5A patent/CN112174575A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201702049A (en) * | 2015-07-14 | 2017-01-16 | 優克材料科技股份有限公司 | Three dimensional printing composite and three dimensional printing object |
| CN105541298A (en) * | 2015-12-24 | 2016-05-04 | 成都新柯力化工科技有限公司 | Continuous inorganic fiber reinforced ceramic and 3D (3-Dimensional) printing forming method for same |
| CN105693945A (en) * | 2016-02-05 | 2016-06-22 | 湖南正阳精密陶瓷有限公司 | Photo-curing material and preparation method and application thereof |
| CN108147830A (en) * | 2018-01-17 | 2018-06-12 | 龙泉市金宏瓷业有限公司 | A kind of 3D printing ceramic setter composite material and preparation method thereof |
| KR20200029656A (en) * | 2018-09-05 | 2020-03-19 | 서울대학교산학협력단 | Bioink compositions for visible light curing for 3D printing and method of manufacturing the same |
| CN111690096A (en) * | 2020-05-20 | 2020-09-22 | 广西春景环保科技有限公司 | Preparation method of 3D printing photosensitive resin material |
Non-Patent Citations (2)
| Title |
|---|
| 张明之等: "《铸造词典》", 30 April 1986, 中国农业机械出版社 * |
| 王永信等: "《光固化3D打印技术》", 30 November 2018, 华中科技大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115304392A (en) * | 2021-05-08 | 2022-11-08 | 中国石油化工股份有限公司 | Kaolin-based 3D printing powder and integral active porous material prepared from same |
| CN115304392B (en) * | 2021-05-08 | 2024-05-17 | 中国石油化工股份有限公司 | Kaolin-based 3D printing powder and integral active porous material prepared from same |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107298546A (en) | Alkali-activated carbonatite binder materials and its Method of printing for 3D printing | |
| CN108529984A (en) | A kind of surface modified carbon fiber reinforcement high impedance high-tensile cement base 3D printing base material and preparation method thereof | |
| CN108609611A (en) | The aqueous dispersions and preparation method thereof of the Environment-friendlycarbon carbon nanotube of high stability | |
| CN103204660A (en) | High-hardness artificial quartz stone plate and production process thereof | |
| CN107236506A (en) | A kind of double-component epoxy resin embedding adhesive | |
| CN101941816A (en) | Pretreatment recycling method of waste powder from polishing of artificial stone | |
| CN100404600C (en) | Starch base material system for tridimensional spraying and adhesive bonding and preparation method thereof | |
| CN107418375A (en) | A kind of aqueous epoxide resin paint and preparation method thereof | |
| CN1850694A (en) | Gypsum base material system for 3-D spraying binding and preparing method therefor | |
| CN109929321A (en) | Offset litho printing ink and its preparation process | |
| CN112174575A (en) | Photocuring clay printing material and preparation method thereof | |
| CN103553435A (en) | Preparation method of quartz synthetic stone slab | |
| CN105839452B (en) | A kind of special calcium carbonate of papermaking | |
| CN103773158A (en) | Preparation method for thermoplastic acrylic resin plastic paint | |
| CN112679142B (en) | High-strength epoxy mortar and preparation method thereof | |
| CN108977081A (en) | A kind of efficient energy-saving coating for building and preparation method thereof | |
| CN102675717B (en) | Modified nonmetallic reclaimed material of printed circuit board and preparation method thereof | |
| CN107365509A (en) | A kind of banana stalks 3D printing environment-friendly materials and preparation method thereof | |
| CN115636636A (en) | Double-component tile glue and preparation process thereof | |
| CN110628240B (en) | Water-soluble composite modified grinding aid, preparation method and application | |
| CN104230213B (en) | A kind of polypropylene fibre strengthens the preparation method of quartz synthetic stone slab | |
| CN100378167C (en) | Polymer/silicon dioxide nano particle composite material and preparing method | |
| CN104673162A (en) | Joint sealant for thermosetting composite floor as well as preparation method and application of joint sealant | |
| CN113416030B (en) | Ecological ramp grass planting slope protection brick and production process thereof | |
| CN109111592A (en) | High adhesion force high-weatherability foamed board and its manufacture craft based on electronic beam curing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210105 |