CN112172290B - Film, production method thereof, packaging bag containing film and application of packaging bag - Google Patents

Film, production method thereof, packaging bag containing film and application of packaging bag Download PDF

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Publication number
CN112172290B
CN112172290B CN201910589224.3A CN201910589224A CN112172290B CN 112172290 B CN112172290 B CN 112172290B CN 201910589224 A CN201910589224 A CN 201910589224A CN 112172290 B CN112172290 B CN 112172290B
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surface layer
film
layer
ldpe
raw materials
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CN112172290A (en
Inventor
杨帅
高静
夏进京
范协诚
张培培
顾宗珍
马金杉
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Xinte Energy Co Ltd
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Xinte Energy Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D29/00—Sacks or like containers made of fabrics; Flexible containers of open-work, e.g. net-like construction
    • B65D29/02—Sacks with laminated or multiple walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/30—Containers, packaging elements or packages, specially adapted for particular articles or materials for articles particularly sensitive to damage by shock or pressure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/242—All polymers belonging to those covered by group B32B27/32
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536—Hardness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/80—Packaging reuse or recycling, e.g. of multilayer packaging

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Wrappers (AREA)

Abstract

The invention discloses a film and a production method thereof, the film comprises an inner surface layer, a middle layer and an outer surface layer, wherein the inner surface layer comprises the following raw materials in percentage by weight: 95-100% of LDPE and 0-5% of auxiliary reagent; the middle layer comprises the following raw materials in percentage by weight: 75 to 100 percent of metallocene PE and 0 to 25 percent of LDPE; the outer surface layer comprises the following raw materials in percentage by weight: 95-100% of LDPE and 0-5% of auxiliary reagent. The production method of the film comprises the steps of batching, mixing, forming and the like. The invention also discloses a packaging bag prepared by adopting the film, which is used for packaging polycrystalline silicon and products with high cleanliness requirement and high hardness. The invention has the characteristics of high tensile strength, strong puncture resistance, low surface metal precipitation amount and the like.

Description

Film, production method thereof, packaging bag containing film and application of packaging bag
Technical Field
The invention belongs to the technical field of polycrystalline silicon, and particularly relates to a film, a production method, a packaging bag containing the film and application of the film.
Background
Polycrystalline silicon is an important material in industries such as semiconductors and solar energy, is extremely afraid of being polluted, and a polycrystalline silicon packaging bag is used as a barrier for isolating polycrystalline silicon from the outside, and the performance of the polycrystalline silicon packaging bag is directly related to the quality of a polycrystalline silicon product. However, in the polysilicon industry, product contamination accidents caused by polysilicon packaging bag breakage occur, and the complaint rate of packaging bag breakage per year is as high as more than 10%, and still shows an increasing trend.
The damage to the packaging bag is mainly caused by the following two factors: on one hand, because the hardness of polysilicon is high (the mohs hardness is 7), the section of a silicon material generated when the polysilicon is broken is relatively sharp, and the surface of the polysilicon is often polluted (metal impurities on the surface of the polysilicon are increased or powder on the surface of the polysilicon is accumulated) due to the breakage of a film when a product is packaged, so that the quality requirement of the silicon material when the polysilicon is used for pulling the single crystal is influenced. On the other hand, during transportation, the polycrystalline silicon packaging film is often damaged due to unreasonable packaging design of polycrystalline silicon products, poor transportation road conditions and physical properties of polycrystalline silicon. Therefore, there is a need for improvement of the existing packaging bag to improve its performance.
In order to improve the performance of the polysilicon packaging bag, a great deal of research is carried out by foreign companies such as Waker, OCI and the like, but most of the research focuses on improving the elongation at break and the puncture resistance of the packaging bag, the improvement effect is not obvious, and the research on reducing the metal precipitation amount on the surface of the packaging bag is very little.
At present, the materials and processing technology of polysilicon packaging are basically monopolized abroad, and the domestic polysilicon packaging bag production technology cannot meet the requirement of polysilicon packaging. The common polysilicon packing bag at home and abroad is mainly produced by processing PE (polyethylene) or PVC (polyvinyl chloride) materials, the thickness is usually 20-30 um, and the packaging bag has the following defects:
(1) The elongation at break is low, the puncture resistance is insufficient, and the requirement of polycrystalline silicon packaging cannot be met;
(2) The amount of epi-metal deposition is high (epi-metal refers to partially ionizable ions present on the surface of polysilicon, the contents of Fe, cr, ni, cu, zn, al, K, na and the like are mainly concerned);
(3) Most adopt monolayer PE integral material, and a few of the PE integral material is doped with other elements, but all adopt one-step compression molding process, the components are distributed in a point mode, and the improvement on the ductility and the puncture resistance is not obvious.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a film, a production method, a packaging bag containing the film and an application of the packaging bag, aiming at the defects existing in the prior art, the produced packaging bag containing the film has the characteristics of high tensile strength, strong puncture resistance, low surface metal precipitation amount and the like, and can solve the problems of high surface metal precipitation amount and unqualified toughness strength.
The technical scheme adopted for solving the technical problem of the invention is as follows:
a film comprises an inner surface layer, a middle layer and an outer surface layer,
the inner surface layer comprises the following raw materials in percentage by weight: 95 to 100 percent of LDPE (low density polyethylene is also called high pressure polyethylene), 0 to 5 percent of auxiliary reagent;
the middle layer comprises the raw materials by weight percentage are as follows: 75-100% of metallocene PE (metallocene polyethylene) and 0-25% of LDPE;
the outer surface layer comprises the following raw materials in percentage by weight: 95 to 100 percent of LDPE, 0 to 5 percent of auxiliary reagent;
preferably, the density of the LDPE is 0.904-0.926 g/cm 3 Melting point 85-100 deg.C; the density of the metallocene PE is 0.920 to 0.925g/cm 3 Melting point of 170 230 ℃ to.
Preferably, the inner surface layer comprises the following raw materials in percentage by weight: 95% of LDPE and 5% of auxiliary agent;
the middle layer comprises the following raw materials in percentage by weight: 100% of metallocene PE;
the outer surface layer comprises the following raw materials in percentage by weight: 95% of LDPE and 5% of auxiliary agent.
Preferably, the thickness ratio of the inner surface layer, the middle layer and the outer surface layer is 1.
Preferably, the total thickness of the film is 200-275 μm.
Preferably, the auxiliary agent is an ethylene propylene copolymer elastomer or an ethylene propylene copolymer elastomer.
The film in the embodiment has a three-layer structure, wherein the inner surface layer and the outer surface layer are made of pure LDPE, so that the film has strong tensile strength and basic heat resistance; the intermediate layer adopts metallocene PE, so that the surface metal is effectively prevented from being introduced due to the addition of additives such as viscose and the like in the processing process of the traditional process, the precipitation amount of the surface metal is reduced to be less than or equal to 30ppb, the toughness of the film can be enhanced, and the puncture resistance and the impact resistance are improved.
The invention also provides a production method of the film, which specifically comprises the following steps:
(1) Preparing materials: preparing raw materials or mixture materials of the inner surface layer, the middle layer and the outer surface layer respectively according to the raw material proportion;
(2) Mixing materials: respectively adding the prepared raw material mixtures of the inner surface layer, the middle layer and the outer surface layer into each mixer to be uniformly mixed:
(3) Molding: respectively pouring raw material mixture in which the inner surface layer, the middle layer and the outer surface layer are uniformly mixed in each mixer into three hoppers of a three-layer co-extrusion film blowing machine, feeding each hopper, and preparing the film with the inner surface layer, the middle layer and the outer surface layer by the steps of heating, compression molding, inflation traction, air ring cooling and the like.
The film production method provided by the invention has the advantages of easily available raw materials, simple process flow and easy operation.
The invention also provides a packaging bag which is prepared by adopting the film with the inner surface layer, the middle layer and the outer surface layer as raw materials.
The invention also provides application of the packaging bag, which is used for packaging polycrystalline silicon and products with high cleanliness requirement and high hardness.
The packaging bag provided by the invention has the advantages that the inner surface layer and the outer surface layer have high tensile strength and good heat sealing performance, the breaking elongation and the puncture resistance of the packaging bag can be improved, the processing is convenient, and the packaging bag not only can be suitable for photovoltaic semiconductor products such as polycrystalline silicon and the like, but also can be applied to other products with high requirements on cleanliness and high hardness. The metallocene PE is added in the middle layer, so that the amount of surface metals introduced during production and processing can be effectively reduced, the surface metal precipitation rate is low, the puncture resistance is high, and the requirement of polycrystalline silicon packaging is met. The packaging bag made of the film has excellent tensile strength, puncture resistance, toughness and other properties under the conditions of normal temperature or low temperature.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following will clearly and completely describe the technical solution of the present invention in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without any inventive step based on the embodiments of the present invention, belong to the scope of the present invention.
Example 1
This embodiment discloses a film, including interior skin, intermediate layer and outer skin, includes:
the inner surface layer is prepared from the following raw materials in percentage by weight: 95-100% of LDPE (low density polyethylene (called high pressure polyethylene) and 0-5% of auxiliary agent;
the middle layer is prepared from the following raw materials in percentage by weight: 75-100% of metallocene PE (metallocene polyethylene) and 0-25% of LDPE;
the outer surface layer is prepared from the following raw materials in percentage by weight: 95-100% of LDPE and 0-5% of auxiliary reagent.
Specifically, the film in this embodiment is formed by adopting a three-layer co-extrusion film blowing machine to co-extrude and blow-mold the raw materials of the inner surface layer, the middle layer and the outer surface layer, wherein: the raw materials of the inner surface layer and the outer surface layer are respectively mainly LDPE materials with good heat fusion property, forming processing property, impact toughness and low temperature resistance so as to enable the film to have high-strength stretching capability, and the middle layer is mainly metallocene PE with good processing property, high strength, good rigidity and good transparency so as to improve the low surface metal precipitation rate of the film (the surface metal refers to part of ionizable ions existing on the surface of polycrystalline silicon, and the contents of ions such as Fe, cr, ni, cu, zn, al, K, na and the like are mainly concerned). In the embodiment, the LDPE preferably has the density of 0.904-0.926 g/cm < 3 > and the melting point of 85-100 ℃; the metallocene PE preferably has a density of 0.920 to 0.925g/cm3 and a melting point of 170 to 230 ℃.
Furthermore, a proper amount of auxiliary reagents can be added into the inner surface layer and the outer surface layer to increase the elasticity of the film and improve the puncture resistance. The auxiliary agent can be ethylene-propylene copolymer elastomer, and can also be other similar compounds containing ethylene-propylene copolymer, such as ethylene-propylene-styrene-acrylonitrile copolymer. The auxiliary agent in this embodiment is preferably ethylene propylene copolymer elastomer, and the amount of the auxiliary agent ethylene propylene copolymer elastomer is within 5% of the total weight of the inner surface layer or the outer surface layer. LDPE can be added into the middle layer to enhance the tensile strength and improve the toughness of the film.
Specifically, the thickness ratio of the inner surface layer, the intermediate layer, and the outer surface layer in the film in this example is 1:1:1, namely the raw materials of the inner surface layer, the middle layer and the outer surface layer are used in the same amount. Setting the total thickness of the film to be 100%, the thickness of the inner, middle and outer three-layer structures is preferably 33% + -5%, and in the actual operation process, due to errors, the thickness of the inner surface layer is controlled to be 33% + -5%, the thickness of the middle layer is controlled to be 33% + -5%, and the thickness of the outer surface layer is controlled to be 33% + -5%.
The embodiment also discloses a production method of the film, which is prepared by adopting a three-layer co-extrusion film blowing machine and comprises the following specific steps:
s1: ingredients
Preparing raw materials or mixed materials of the inner surface layer, the middle layer and the outer surface layer respectively.
Wherein: the inner surface layer contains 95-100% of LDPE (by weight, the component content of each layer of raw material is calculated by weight percentage and is not described again), and 0-5% of auxiliary reagent; the middle layer contains 75-100% of metallocene PE and 0-25% of LDPE; the outer surface layer contains 95-100% of LDPE and 0-5% of auxiliary reagent. In this example, the inner surface layer is 95% of LDPE and 5% of ethylene propylene copolymer elastomer, the middle layer is 100% of metallocene PE, and the outer surface layer is 95% of LDPE and 5% of ethylene propylene copolymer elastomer.
Specifically, the following steps are as follows: 1, taking LDPE and ethylene-propylene copolymer elastomer (namely 95 percent of LDPE and 5 percent of ethylene-propylene copolymer elastomer) as raw material mixture of the inner surface layer. Taking metallocene PE with the same total weight as the inner surface layer as the raw material of the middle layer. According to the following steps of 19:1 taking LDPE and ethylene propylene copolymerized elastomer (namely 95 percent of LDPE and 5 percent of ethylene propylene copolymerized elastomer) as raw material mixture of the outer surface layer.
S2: mixing material
The prepared raw material mixtures of the inner surface layer, the middle layer and the outer surface layer are respectively added into each mixer to be uniformly mixed.
Specifically, the inner-surface raw material mixture prepared in the step S1 is added into an inner-surface raw material mixer, the middle-layer raw material is added into a middle-layer raw material mixer, and the outer-surface raw material mixture is added into an outer-surface raw material mixer, so that the inner-surface raw material mixture, the middle-layer raw material mixer and the outer-surface raw material mixture are uniformly mixed respectively.
S3: shaping of
Respectively pouring raw material mixture of the inner surface layer, the middle layer and the outer surface layer which are uniformly mixed in each mixer into three hoppers of a three-layer co-extrusion film blowing machine, feeding each hopper, and preparing the film with the inner surface layer, the middle layer and the outer surface layer through the steps of heating, compression molding, inflation traction, air ring cooling and the like, wherein the specific steps are as follows:
s301, pouring the uniformly mixed inner surface layer raw material mixture in the inner surface layer raw material mixer into an inner surface layer hopper of a three-layer co-extrusion film blowing machine, introducing the uniformly mixed middle layer raw material in the middle layer raw material mixer into the middle layer hopper of the three-layer co-extrusion film blowing machine, and pouring the uniformly mixed outer surface layer raw material mixture in the outer surface layer raw material mixer into the inner surface layer hopper of the three-layer co-extrusion film blowing machine;
s302, according to actual requirements, feeding proportions of an inner surface layer, a middle layer and an outer surface layer are arranged on a three-layer co-extrusion film blowing machine so as to control the thickness proportions of the inner surface layer, the middle layer and the outer surface layer. In this embodiment, the thickness ratio of the middle inner surface layer, the middle layer, and the outer surface layer is preferably 1:1:1, namely the feeding proportion of the inner surface layer, the middle layer and the outer surface layer is 1:1:1.
s302, the three hoppers are used for feeding materials simultaneously, the fed raw material mixture is heated and subjected to compression molding, the heated raw material mixture is extruded, and an inner surface layer, a middle layer and an outer surface layer are respectively formed through the steps of inflation traction, air ring cooling and the like, so that the film with the three-layer structure of the inner surface layer, the middle layer and the outer surface layer is obtained.
Further, by changing the drawing speed, the thickness of the prepared film can be adjusted.
In this embodiment, the total thickness of the film used for the packaging bag is preferably 200 to 275 μm, and more preferably 245 to 268 μm, in order to satisfy the performance requirements and cost issues, considering that the greater the total thickness of the film, the more excellent the puncture resistance, tensile strength and impact resistance, but the higher the cost of the film, the higher the sealing process and heat sealability required for the preparation of the packaging bag. In this embodiment, the total film thickness is preferably 250 μm.
The film in the embodiment has a three-layer structure, wherein the inner surface layer and the outer surface layer are made of pure LDPE, so that the film has strong tensile strength and basic heat resistance; the intermediate layer adopts metallocene PE, so that the surface metal is effectively prevented from being introduced due to the addition of additives such as viscose and the like in the processing process of the traditional process, the precipitation amount of the surface metal is reduced to be less than or equal to 30ppb, the toughness of the film can be enhanced, and the puncture resistance and the impact resistance are improved. The film production method in the embodiment has the advantages of easily available raw materials, simple process flow and easy operation.
The embodiment also discloses a packaging bag which is prepared by adopting the film with the three-layer structure of the inner surface layer, the middle layer and the outer surface layer as a raw material.
The embodiment also discloses application of the packaging bag, which is used for packaging polycrystalline silicon and products with high cleanliness requirement and high hardness.
The production method of the packaging bag in the implementation comprises the following steps:
s4, making bags
And (4) folding the 250 mu m film prepared in the step (S3) into a quadrangular cylindrical film with folding corners by adopting a folding corner die, and then, carrying out bag making and forming by using a heat-sealing bag making machine to prepare the packaging bag.
In this embodiment, the size of wrapping bag, heat-seal distance can be selected as required, and this embodiment does not do further and limits.
The packaging bag disclosed by the embodiment has the advantages that the inner surface layer and the outer surface layer have high tensile strength and good heat sealing performance, the elongation at break and the puncture resistance of the packaging bag can be improved, the processing is convenient, the packaging bag is not only suitable for photovoltaic semiconductor products such as polycrystalline silicon, but also can be applied to other products which have high requirements on cleanliness and high hardness. The metallocene PE is added in the middle layer, so that the amount of surface metal introduced during production and processing can be effectively reduced, the surface metal precipitation rate is low, the puncture resistance is high, and the requirement of polycrystalline silicon packaging is met. The packaging bag made of the film has excellent tensile strength, puncture resistance, toughness and other properties at normal temperature or low temperature.
Example 2
The present embodiment discloses a film, which is different from embodiment 1 in the ratio of raw materials of an inner surface layer, an intermediate layer, and an outer surface layer of the film, and specifically includes the following:
the raw material percentage of the inner surface layer is as follows: 100% of LDPE;
the middle layer comprises the following raw materials in percentage by weight: 100% of metallocene PE;
the outer surface layer comprises the following raw materials in percentage by weight: 100 percent of LDPE.
The total thickness of the film in this example was 225 μm.
Example 3
The present embodiment discloses a film, which is different from embodiment 1 in the ratio of raw materials of an inner surface layer, an intermediate layer and an outer surface layer of the film, and specifically comprises the following components:
the raw material percentage of the inner surface layer is as follows: 100% of LDPE;
the middle layer comprises the following raw materials in percentage by weight: 75% of metallocene PE and 25% of LDPE;
the outer surface layer comprises the following raw materials in percentage by weight: 100 percent of LDPE.
In this example, the total thickness of the film was 270. Mu.m.
Example 4
The present embodiment discloses a film, which is different from embodiment 1 in the ratio of raw materials of an inner surface layer, an intermediate layer and an outer surface layer of the film, and specifically comprises the following components:
the raw material percentage of the inner surface layer is as follows: 98% of LDPE, 2% of ethylene propylene styrene acrylonitrile copolymer;
the middle layer comprises the following raw materials in percentage by weight: 75% of metallocene PE and 25% of LDPE;
the outer surface layer comprises the following raw materials in percentage by weight: 98 percent of LDPE and 2 percent of ethylene propylene styrene acrylonitrile copolymer.
In this example, the total thickness of the film was 200. Mu.m.
The packaging bags made of the films obtained in the above examples 1 to 4 were subjected to tests of properties such as surface metal extraction rate, bulk metal extraction rate, tensile strength, elongation, puncture resistance, dart impact, etc., and the test environment was set at-40 deg.C, -20 deg.C, and 23 deg.C. The Test was carried out according to ASTM D882 Standard Test Method for Tensile Properties of Thin Plastic Sheeting, SEMI PV50-0114 Specification for high purity polyethylene packaging for polysilicon, ISO 527-3, ISO 7765-1/A. Comparing the detection result with a common thousand-level packaging bag (made of LDPE material and adopting a three-layer composite processing mode), wherein the specific test result pair is shown in Table 1:
table 1 performance test meter for packing bag
Figure GDA0003960445560000091
From the data, the film and the packaging bag disclosed by the embodiment can ensure that the inner surface layer and the outer surface layer have lower surface metal precipitation amount and better heat sealing performance, can also integrally improve the breaking elongation and puncture resistance of the packaging bag, can be suitable for photovoltaic semiconductor products such as polycrystalline silicon and the like, and can also be applied to other products which have high requirements on cleanliness and high hardness. By adding the metallocene PE in the middle layer, the amount of surface metals introduced during production and processing is effectively reduced, the low surface metal precipitation rate is realized, and the requirement of polycrystalline silicon packaging is met. The packaging bag made of the film has excellent tensile strength, puncture resistance, toughness and other properties at normal temperature or low temperature.
It will be understood that the above embodiments are merely exemplary embodiments taken to illustrate the principles of the present invention, which is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.

Claims (5)

1. A film comprises an inner surface layer, a middle layer and an outer surface layer, and is characterized in that,
the inner surface layer comprises the following raw materials in percentage by weight: 95-98% of LDPE and 2-5% of auxiliary reagent;
the middle layer comprises the following raw materials in percentage by weight: 75 to 100 percent of metallocene PE and 0 to 25 percent of LDPE;
the outer surface layer comprises the following raw materials in percentage by weight: 95-98% of LDPE and 2-5% of auxiliary reagent;
wherein the density of the LDPE is 0.904-0.926 g/cm 3 The melting point is 85-100 ℃; the density of the metallocene PE is 0.920 to 0.925g/cm 3 The melting point is 170-230 ℃; the thickness proportion of the inner surface layer, the middle layer and the outer surface layer is 1; the precipitation amount of the surface metal is less than or equal to 30ppb;
the auxiliary reagent is ethylene-propylene copolymer elastomer or ethylene-propylene-styrene-acrylonitrile copolymer.
2. The film of claim 1,
the inner surface layer comprises the following raw materials in percentage by weight: 95% of LDPE and 5% of auxiliary agent;
the middle layer comprises the following raw materials in percentage by weight: 100% of metallocene PE;
the outer surface layer comprises the following raw materials in percentage by weight: 95% of LDPE and 5% of auxiliary agent.
3. A method of producing a film, comprising the steps of:
(1) Preparing materials: preparing raw materials or mixture materials of an inner surface layer, an intermediate layer and an outer surface layer according to the raw material proportion of any one of claims 1-2;
(2) Mixing materials: respectively adding the prepared raw material mixtures of the inner surface layer, the middle layer and the outer surface layer into each mixer to be uniformly mixed;
(3) Molding: the raw materials or the mixture of the inner surface layer, the middle layer and the outer surface layer which are uniformly mixed in each mixer are respectively poured into three hoppers of a three-layer co-extrusion film blowing machine, and the film with the inner surface layer, the middle layer and the outer surface layer is prepared by feeding the hoppers through the steps of heating, compression molding, inflation traction and air ring cooling.
4. A packaging bag characterized by being produced from the film having an inner surface layer, an intermediate layer and an outer surface layer according to any one of claims 1 to 2.
5. Use of the packaging bag according to claim 4 for packaging of polycrystalline silicon and for packaging of products with high cleanliness requirements and high hardness.
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Application publication date: 20210105

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Denomination of invention: A film and its production method, as well as a packaging bag containing the film and its application

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