CN112137075A - Compound emulsifier fine powder and preparation method thereof - Google Patents

Compound emulsifier fine powder and preparation method thereof Download PDF

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CN112137075A
CN112137075A CN202010939568.5A CN202010939568A CN112137075A CN 112137075 A CN112137075 A CN 112137075A CN 202010939568 A CN202010939568 A CN 202010939568A CN 112137075 A CN112137075 A CN 112137075A
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acid ester
fine powder
emulsifier
fatty acid
compound emulsifier
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CN112137075B (en
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孟宪伟
姜黎黎
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Fujian Yile Baobao Biotechnology Co ltd
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Fujian Yile Baobao Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/10Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D15/00Preserving finished, partly finished or par-baked bakery products; Improving
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/16Fatty acid esters
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)

Abstract

The invention discloses compound emulsifier fine powder and a preparation method thereof, belonging to the field of emulsifier compounding. The compound emulsifier fine powder comprises the following components in percentage by weight: polyglycerin fatty acid ester: 0% -10%, mono-diglycerol fatty acid ester: 65% -100%, sucrose fatty acid ester: 0% -5%, sodium stearoyl lactylate or diacetyl tartaric acid esters of mono-and diglycerides: 0 to 20 percent. The preparation method comprises mixing optional several or all of polyglycerol fatty acid ester, mono-diglycerol fatty acid ester, sucrose fatty acid ester, sodium stearyl lactate or diacetyl tartaric acid monoglyceride, heating for melting, and cooling by cold air spray to obtain compound emulsifier fine powder of more than 80 meshes. The fine powder of the compound emulsifier can prolong the shelf life of starch finished products and increase the chewy taste.

Description

Compound emulsifier fine powder and preparation method thereof
Technical Field
The invention relates to compound emulsifier fine powder and a preparation method thereof, belonging to the field of emulsifier compounding.
Background
The emulsifier is an important food additive and is widely applied to the preparation of starch foods such as cakes, bread and the like. Its molecular two ends are composed of hydrophilic and lipophilic groups, and can form an adsorption layer on the interface between water and oil to connect them together, so playing a role in emulsification. The emulsifier can also perform multiple functions by performing special interaction with carbohydrates, proteins, lipids and the like in starch foods. The proper amount of emulsifier is added into the starch product to ensure that the ingredients are fully emulsified and uniformly mixed, the flavor of the product is improved, the effects of softening and refreshing, increasing the chewy taste, prolonging the shelf life are achieved, and the product quality is improved.
The monoglyceride/diglyceride fatty acid ester and polyglycerin fatty acid ester have excellent emulsifying property, hydrophilic and lipophilic properties, and have functions of improving starch viscosity and preventing starch aging, and can be decomposed in human body metabolism process, with high safety.
Sucrose fatty acid ester can make the dough increase, and its interact with between the protein in the flour especially can form the compound with gluten protein, and gliadin in the starch combines the hydrophilic group of emulsifier, and glutenin combines the oleophylic group of emulsifier to make more protein combine each other, form the macromolecule gluten network, strengthened gluten intensity, improve the extensibility and the gas retentivity of gluten, make dough and finished product volume increase.
The sodium stearoyl lactylate can be combined with starch to form a spiral complex, prevent amylose from aggregating from the interior of starch granules and prevent the starch from aging; but also can form a compound with gluten protein, a smooth film structure is formed between gluten and starch, and the binding gluten reduces the viscosity of dough, thereby improving the ductility of the gluten.
The diacetyl tartaric acid ester of mono-and diglycerides has strong emulsifying and anti-aging effects, can effectively enhance the elasticity, toughness and gas-holding property of dough, reduce the weakening degree of the dough, increase the volume of bread and improve the texture structure of the bread.
In the prior art, the used compound emulsifier contains fillers such as water, sorbitol, maltodextrin and the like, and the used emulsifier has large particles such as mono-diglycerol fatty acid ester, polyglycerin fatty acid ester and the like, which are generally 30-60 meshes, and cannot be well combined with starch particles (130 meshes) in starch products such as flour and the like, so that the purpose of preventing starch aging cannot be well achieved, and the using effect of the emulsifier is reduced. In the prior art, the emulsifier is dried by hot air spray drying, which can affect the performance of the emulsifier.
Based on the prior art, the field needs a compound emulsifier which can be fully combined with starch, and simultaneously has the advantages of preventing starch from aging, prolonging the shelf life of starch finished products and increasing the chewy taste.
Disclosure of Invention
In order to solve the problems, the invention aims to provide the compound emulsifier fine powder and the preparation method thereof.
The first purpose of the invention is to provide a preparation method of compound emulsifier fine powder, which comprises the following steps:
firstly, mixing any one or more of polyglycerol fatty acid ester, mono-diglycerol fatty acid ester (C16: 0/C18: 0), sucrose fatty acid ester, sodium stearyl lactate and diacetyl tartaric acid ester, heating to 70-80 ℃, and keeping the temperature for 10-20 min;
step two, carrying out cold air type spray cooling on the melted mixed emulsifier obtained in the step one, wherein the inlet temperature of the mixed emulsifier is 65-70 ℃, and the pressure of a pressure spray nozzle is 5-150 kg/cm2The inlet temperature of cold air/nitrogen is 0-10 deg.C, and the wind pressure is 10-20 kg/cm2Thus obtaining the compound emulsifier fine powder with 80 meshes of passing rate more than or equal to 90 percent.
In one embodiment of the invention, the compound emulsifier fine powder comprises the following components in percentage by weight:
polyglycerin fatty acid ester: 0% -10%;
mono-diglycerol fatty acid ester (C16: 0/C18: 0): 65% -100%;
sucrose fatty acid ester: 0% -5%;
sodium stearoyl lactylate or diacetyl tartaric acid esters of mono-and diglycerides: 0 to 20 percent.
In one embodiment of the present invention, the polyglycerin fatty acid ester is preferably a polyglycerin fatty acid ester E475; the mono-diglycerol fatty acid ester (C16: 0/C18: 0) is preferably mono-diglycerol fatty acid ester E471; the sucrose fatty acid ester is preferably sucrose fatty acid ester E473; the sodium stearoyl lactylate is preferably sodium stearoyl lactylate E481 i; the diacetyl tartaric acid ester of mono-and diglycerides is preferably diacetyl tartaric acid ester of mono-and diglycerides E472.
In one embodiment of the present invention, preferably, the content of the polyglycerol fatty acid ester and the sucrose fatty acid ester in the fine compound emulsifier powder is greater than 0%; the content of the sodium stearyl lactate or the diacetyl tartaric acid ester of mono-and diglycerides in the compound emulsifier fine powder is more than 0%.
In one embodiment of the invention, in the step one, during the heating and the heat preservation, stirring is required, and the stirring speed is 5-30 rpm.
In one embodiment of the present invention, in step one, the optimal stirring speed is 25rpm, and the optimal holding time is 15 min.
In one embodiment of the present invention, step two, the optimum inlet temperature for mixing the emulsifier is 70 ℃.
In one embodiment of the present invention, in step two, the optimum pressure of the pressure spray nozzle is 60 kg/cm2
In one embodiment of the present invention, step two, the optimum cold air/nitrogen inlet temperature is 0 ℃.
In one embodiment of the present invention, in step two, the optimum wind pressure is 15 kg/cm2
The second purpose of the invention is to provide the compound emulsifier fine powder prepared by the method.
A third object of the present invention is to provide a food product, preferably a starch-based finished product, more preferably a baked dough product, comprising the above fine powder of a compounded emulsifier.
The fourth purpose of the invention is to provide the application of the compound emulsifier fine powder in the food field.
The invention provides compound emulsifier fine powder and a preparation method thereof, and compared with the prior art, the compound emulsifier fine powder has the following advantages:
the compound emulsifier fine powder provided by the invention is prepared by adopting a cold air type spray cooling method, and a fine powder compound emulsifier with 80-mesh passing rate of more than or equal to 90% is obtained.
Detailed Description
Bread texture (hardness, elasticity, chewiness): the texture analyzer selects a P/25 test probe, the speed before, during and after the test is 1.5mm/s, the compression rate is 50%, the triggering type is automatic, and the starting point induced stress is 5 g.
Mesh number determination of the components: and (4) measuring the weight of undersize materials by using an 80-mesh standard sieve, and calculating the passing rate.
Examples 1-5 preparation of finely divided powders of Complex emulsifiers
Step one, weighing polyglycerol fatty acid ester (E475), mono-diglycerol fatty acid ester (C16: 0/C18: 0) (E471), sucrose fatty acid ester (E473) and sodium stearoyl lactylate (E481i) according to the weight percentage in the following table 1, heating to 75 ℃, and keeping the temperature for 15min, wherein stirring is required during the heating and the keeping temperature, and the stirring speed is 25 rpm.
And step two, carrying out cold air type spray cooling on the melted mixed emulsifier obtained in the step one. The inlet temperature of the mixed emulsifier is 70 ℃, and the pressure of the pressure spray nozzle is 60 kg/cm2The inlet temperature of cold air/nitrogen is 0 ℃, and the air pressure is as follows: 15 kg/cm2. Obtain the compound emulsifier fine powder with 80 meshes of passing rate more than or equal to 90 percent.
Table 1: each component of compound emulsifier fine powder and weight percentage thereof
Figure BDA0002673146840000031
Comparative example 1
The polyglycerin fatty acid ester (E475), the mono-diglycerin fatty acid ester (C16: 0/C18: 0) (E471), the sucrose fatty acid ester (E473) and the sodium stearoyl lactylate (E481i) are weighed according to the proportion of the comparative example 1 in the table 1 and are directly mixed to obtain the compound emulsifier. Through determination, the mesh number of the components of the compound emulsifier is 30-60 meshes.
Comparative example 2
The polyglycerol fatty acid ester (E475), the mono-diglycerol fatty acid ester (C16: 0/C18: 0) (E471), the sucrose fatty acid ester (E473) and the sodium stearoyl lactylate (E481i) are weighed according to the proportion of the comparative example 2 in the table 1, and are directly mechanically ground after being mixed, and researches show that the grinding is difficult and can not be normally carried out due to softening of an emulsifier in the grinding process, and the obtained compound emulsifier is seriously caked and can not be used in the subsequent application process.
Example 6
Bread was prepared using the compound emulsifier prepared in comparative example 1 and the compound emulsifier fine powder prepared in examples 1 to 5, in terms of weight fraction, using the following formulation and manufacturing method:
the formula of the bread is as follows: 1000g of high gluten wheat flour, 120g of white granulated sugar, 14g of salt, 80g of butter, 12g of yeast, 575g of water, 1g of calcium propionate, 0.3g of sodium dehydroacetate and 10g of compound emulsifier (fine powder).
The preparation method of the bread comprises the following steps: stirring procedure: stirring for 11min at a low speed and a high speed; and (3) segmentation and reshaping: 150g per dough; relaxing at room temperature for 15 min; temperature of fermentation (. degree. C.): 35 ℃; relative humidity (%): 80 percent; time to wake up (min): 100 min; baking temperature (. degree. C.): baking for 25 minutes at the upper fire temperature of 180 ℃ and the lower fire temperature of 200 ℃. The prepared bread was tested for hardness, elasticity and chewiness with a texture tester. The results of the performance tests are shown in table 2.
TABLE 2 results of various property tests of comparative example 1 and examples 1 to 5
Figure BDA0002673146840000041
As can be seen from the above table, the hardness, elasticity and chewiness of the breads of examples 1-5 are better than those of comparative example 1, because the compound emulsifier of examples 1-5, finely powdered by the preparation method of the present invention, can be better combined with starch granules in the flour, promote sufficient interaction between proteins and lipid compounds in the breads and each emulsifier component, maintain the network structure of gluten, and improve the softness, elasticity and chewiness of the breads. Improves the edible performances of the bread such as moisture retention, chewy taste and the like, and simultaneously, the compound emulsifier fine powder is fully combined with the amylose, maintains the active alpha-crystal form for a longer time, and has the effect of prolonging the shelf life.
In addition, at present, the shelf life of the commercial compound emulsifier is generally 12-18 months. The storage performance of the compound emulsifier fine powder is tested, and researches show that the shelf life of the compound emulsifier fine powder can reach 24 months, the phenomenon of agglomeration of the conventional compound emulsifier can not occur under the conventional storage condition, and the texture and the taste of bread prepared in the shelf life are not changed.
Although the present invention has been described with reference to the preferred embodiments, it should be understood that various changes and modifications can be made therein by those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (10)

1. The preparation method of the compound emulsifier fine powder is characterized by comprising the following steps:
firstly, mixing any one or more of polyglycerol fatty acid ester, mono-diglycerol fatty acid ester (C16: 0/C18: 0), sucrose fatty acid ester, sodium stearyl lactate and diacetyl tartaric acid ester, heating to 70-80 ℃, and keeping the temperature for 10-20 min;
step two, carrying out cold air type spray cooling on the melted mixed emulsifier obtained in the step one, wherein the inlet temperature of the mixed emulsifier is 65-70 ℃, and the pressure of a pressure spray nozzle is 5-150 kg/cm2The inlet temperature of cold air/nitrogen is 0-10 deg.C, and the wind pressure is 10-20 kg/cm2Thus obtaining the compound emulsifier fine powder with 80 meshes of passing rate more than or equal to 90 percent.
2. The preparation method of the compound emulsifier fine powder according to claim 1, wherein the compound emulsifier fine powder comprises the following components in percentage by weight:
polyglycerin fatty acid ester: 0% -10%;
mono-diglycerol fatty acid ester (C16: 0/C18: 0): 65% -100%;
sucrose fatty acid ester: 0% -5%;
sodium stearoyl lactylate or diacetyl tartaric acid esters of mono-and diglycerides: 0 to 20 percent.
3. The preparation method of the compound emulsifier fine powder according to claim 1 or 2, wherein stirring is required during the heating and heat preservation, and the stirring speed is 5-30 rpm.
4. The preparation method of the compound emulsifier fine powder according to any one of claims 1 to 3, wherein in the second step, the inlet temperature of the mixed emulsifier is 70 ℃.
5. The preparation method of the compound emulsifier fine powder according to any one of claims 1 to 4, characterized in that in the second step, the pressure of the pressure spray nozzle is 60 kg/cm2
6. The preparation method of the compound emulsifier fine powder according to any one of claims 1 to 5, wherein in the second step, the inlet temperature of the cold air/nitrogen is 0 ℃; the wind pressure is 15 kg/cm2
7. The fine compound emulsifier powder prepared by the preparation method of the fine compound emulsifier powder according to any one of claims 1 to 6.
8. A food product comprising the compounded emulsifier fines of claim 8.
9. The food product of claim 9, wherein the food product is a starchy food product.
10. The use of the fine powder of the compounded emulsifier of claim 7 in the field of food.
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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN113424926A (en) * 2021-06-17 2021-09-24 江苏邦臣生物科技股份有限公司 Compound emulsifier fine powder and preparation method thereof

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CN101684984A (en) * 2008-09-28 2010-03-31 赵君哲 Spray drying method and device thereof
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CN101684984A (en) * 2008-09-28 2010-03-31 赵君哲 Spray drying method and device thereof
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Publication number Priority date Publication date Assignee Title
CN113424926A (en) * 2021-06-17 2021-09-24 江苏邦臣生物科技股份有限公司 Compound emulsifier fine powder and preparation method thereof

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