CN112080351A - Condenser cleaning agent - Google Patents

Condenser cleaning agent Download PDF

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Publication number
CN112080351A
CN112080351A CN202010962355.4A CN202010962355A CN112080351A CN 112080351 A CN112080351 A CN 112080351A CN 202010962355 A CN202010962355 A CN 202010962355A CN 112080351 A CN112080351 A CN 112080351A
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CN
China
Prior art keywords
parts
condenser
fatty alcohol
polyoxyethylene ether
cleaning agent
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Pending
Application number
CN202010962355.4A
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Chinese (zh)
Inventor
骆国清
梁樱莉
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Zhongshan Ubest Technology Co ltd
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Zhongshan Ubest Technology Co ltd
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Priority to CN202010962355.4A priority Critical patent/CN112080351A/en
Publication of CN112080351A publication Critical patent/CN112080351A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a condenser cleaning agent, which is prepared by the raw materials and the preparation method, and is used for cleaning the surface of a condenser, and the cleaning agent is low-foam and delayed to foam or be foamless, so that when the condenser cleaning agent is sprayed on the surface of the condenser, stains, dust and the like on the surface of the condenser can be automatically dissolved and cleaned, the dirt-removing capacity is strong, the surface of the condenser can be cleaned without excessive operation, and meanwhile, the cleaning agent is easy to clean due to low foam or foamless of the cleaning agent.

Description

Condenser cleaning agent
Technical Field
The invention relates to the technical field of chemical industry, in particular to a condenser cleaning agent.
Background
A condenser, which is a component of a refrigeration system and belongs to one of heat exchangers, can convert gas or vapor into liquid and transfer the heat in a pipe to the air near the pipe in a quick manner; most condensers are placed in outdoor atmospheric environment, after the condensers are used for a period of time, stains, dust and the like are remained on the surfaces of the condensers, the surfaces of the condensers need to be cleaned at the moment, the existing cleaning mode is generally to be cleaned by a water gun, but the effect is not ideal, and some condensers adopt cleaning agents, but the foaming amount of the existing cleaning agents is large, so that the condensers need to be cleaned repeatedly for a long time, and therefore, a low-foam or non-foam cleaning agent needs to be developed to effectively remove the stains and the like on the surfaces of the condensers with strong force, and the cleaning effect is improved.
Disclosure of Invention
Aiming at the defects of large foaming amount, poor cleaning effect and the like of the existing cleaning agent, the invention aims to provide a low-foaming or non-foaming condenser cleaning agent which is easy to clean.
In order to achieve the purpose, the scheme provided by the invention is as follows: a condenser detergent comprises the following components in parts by weight: 2-10 parts of alkylphenol polyoxyethylene, 5-25 parts of fatty alcohol polyoxyethylene ether, 5-15 parts of fatty alcohol polyoxyethylene ether sulfate, 0.5-4 parts of coconut oil fatty acid diethanolamide, 1-5 parts of benzalkonium chloride, 1-5 parts of propylene glycol monobutyl ether, 0.1-1 part of sodium hydroxide and 35-85.4 parts of deionized water. According to the invention, the fatty alcohol-polyoxyethylene ether and the fatty alcohol-polyoxyethylene ether sulfate are used as main materials, so that the detergent has the characteristics of strong integral decontamination capability, high stability and mild and hand-friendly performance, meanwhile, coconut oil fatty acid diethanolamide is used for further improving the decontamination and cleaning capability, and then alkylphenol polyoxyethylene ether is used for reducing the foaming amount, so that the detergent is low-foamed or non-foamed after being sprayed.
Further, the ratio of benzalkonium chloride to propylene glycol butyl ether was 1: 1.
Further, 6 parts of alkylphenol ethoxylates, 15 parts of fatty alcohol-polyoxyethylene ether, 10 parts of fatty alcohol-polyoxyethylene ether sulfate, 2 parts of coconut oil fatty acid diethanolamide, 3 parts of benzalkonium chloride, 3 parts of propylene glycol monobutyl ether, 0.5 part of sodium hydroxide and 60.5 parts of deionized water.
The invention also includes a process for preparing a condenser cleaner comprising the steps of:
s1, weighing alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride, propylene glycol monobutyl ether, sodium hydroxide and deionized water according to parts by weight;
s2, pouring the weighed deionized water into a homogenizer for heating and stirring, sequentially adding fatty alcohol-polyoxyethylene ether and sodium hydroxide in the stirring process, then stirring at a high speed until the mixture is uniform, and cooling to room temperature, wherein the heating temperature is 45-95 ℃;
s3, adding alkylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride and propylene glycol monobutyl ether into the solution cooled in the step S2 at room temperature in sequence, mixing and stirring until the mixture is uniformly stirred at a high speed;
s4, filtering the solution stirred in the step S3, taking filtrate, pouring the filtrate into an aerosol can, installing a valve, sealing the aerosol can by a canning machine, and finally installing a spray head on the aerosol can.
The invention has the beneficial effects that: the condenser surface is cleaned, and the cleaning agent is low-foam or foamless, the condenser cleaning agent is prepared by the raw materials and the preparation method so as to clean the condenser surface, and the cleaning agent is low-foam and delayed to foam or foamless, so that when the condenser surface is sprayed, stains, dust and the like on the condenser surface can be automatically dissolved and cleaned, the dirt-removing capability is strong, the condenser surface can be cleaned without excessive operation, and meanwhile, the cleaning agent is easy to clean due to low-foam or foamless of the cleaning agent.
Further, the optimal heating temperature in the step S2 is 70 ℃.
Furthermore, the aperture of the atomization spray hole of the spray head is 0.2-0.5 mm.
Drawings
FIG. 1 is an overall flow chart of the present invention.
Detailed Description
The invention will be further illustrated with reference to specific examples:
the first embodiment is as follows:
referring to the attached figure 1, the condenser cleaning agent comprises the following components in parts by weight: 2 parts of alkylphenol polyoxyethylene, 5 parts of fatty alcohol-polyoxyethylene ether sulfate, 0.5 part of coconut oil fatty acid diethanolamide, 1 part of benzalkonium chloride, 1 part of propylene glycol monobutyl ether, 0.1 part of sodium hydroxide and 85.4 parts of deionized water.
Wherein the ratio of the benzalkonium chloride to the propylene glycol monobutyl ether is 1: 1.
The preparation method of the condenser cleaner of the embodiment comprises the following steps:
s1, weighing alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride, propylene glycol monobutyl ether, sodium hydroxide and deionized water according to parts by weight.
S2, pouring the weighed deionized water into a homogenizer for heating and stirring, sequentially adding fatty alcohol-polyoxyethylene ether and sodium hydroxide in the stirring process, then stirring at a high speed until the mixture is uniform, and cooling to room temperature, wherein the heating temperature is 45 ℃.
And S3, adding alkylphenol polyoxyethylene, fatty alcohol polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride and propylene glycol monobutyl ether into the solution cooled in the step S2 at room temperature in sequence, mixing and stirring until the mixture is uniformly stirred at a high speed.
S4, filtering the solution stirred in the step S3, taking filtrate, pouring the filtrate into an aerosol can, installing a valve, sealing the aerosol can by a canning machine, and finally installing a spray head on the aerosol can.
Wherein the aperture of the atomization spray hole of the spray head is 0.2-0.5 mm.
After the condenser cleaning agent is prepared, the cleaning agent is sprayed on the surface of a condenser of an automobile air conditioner, then the cleaning agent can automatically dissolve stains, dust and the like on the surface of the condenser, meanwhile, the cleaning agent can automatically delay foaming and is low-foaming or non-foaming after being sprayed on the surface of the condenser, after standing for 1-3 minutes, the surface of the condenser can be cleaned by clear water, so that the stains, dust and the like on the surface of the condenser can be easily washed, the surface of an engine can recover luster again, meanwhile, the rust resistance, the antistatic property and the like on the surface of the engine are guaranteed, and the cleaning is convenient and fast, but the cleaning cannot be carried out by a high-pressure.
Example two:
referring to the attached figure 1, the condenser cleaning agent comprises the following components in parts by weight: 10 parts of alkylphenol polyoxyethylene, 25 parts of fatty alcohol-polyoxyethylene ether, 15 parts of fatty alcohol-polyoxyethylene ether sulfate, 4 parts of coconut oil fatty acid diethanolamide, 5 parts of benzalkonium chloride, 5 parts of propylene glycol monobutyl ether, 1 part of sodium hydroxide and 35 parts of deionized water.
Wherein the ratio of the benzalkonium chloride to the propylene glycol monobutyl ether is 1: 1.
The preparation method of the condenser cleaner of the embodiment comprises the following steps:
s1, weighing alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride, propylene glycol monobutyl ether, sodium hydroxide and deionized water according to parts by weight.
S2, pouring the weighed deionized water into a homogenizer for heating and stirring, sequentially adding fatty alcohol-polyoxyethylene ether and sodium hydroxide in the stirring process, then stirring at a high speed until the mixture is uniform, and cooling to room temperature, wherein the heating temperature is 95 ℃.
And S3, adding alkylphenol polyoxyethylene, fatty alcohol polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride and propylene glycol monobutyl ether into the solution cooled in the step S2 at room temperature in sequence, mixing and stirring until the mixture is uniformly stirred at a high speed.
S4, filtering the solution stirred in the step S3, taking filtrate, pouring the filtrate into an aerosol can, installing a valve, sealing the aerosol can by a canning machine, and finally installing a spray head on the aerosol can.
Wherein the aperture of the atomization spray hole of the spray head is 0.2-0.5 mm.
After the condenser cleaning agent is prepared, the cleaning agent is sprayed on the surface of a condenser of an automobile air conditioner, then the cleaning agent can automatically dissolve stains, dust and the like on the surface of the condenser, meanwhile, the cleaning agent can automatically delay foaming and is low-foaming or non-foaming after being sprayed on the surface of the condenser, after standing for 1-3 minutes, the surface of the condenser can be cleaned by clear water, so that the stains, dust and the like on the surface of the condenser can be easily washed, the surface of an engine can recover luster again, meanwhile, the rust resistance, the antistatic property and the like on the surface of the engine are guaranteed, and the cleaning is convenient and fast, but the cleaning cannot be carried out by a high-pressure.
Example three:
the embodiment is a best embodiment, and referring to the attached figure 1, the condenser cleaning agent comprises the following components in parts by weight: 6 parts of alkylphenol ethoxylates, 15 parts of fatty alcohol-polyoxyethylene ether, 10 parts of fatty alcohol-polyoxyethylene ether sulfate, 2 parts of coconut oil fatty acid diethanolamide, 3 parts of benzalkonium chloride, 3 parts of propylene glycol monobutyl ether, 0.5 part of sodium hydroxide and 60.5 parts of deionized water.
Wherein the ratio of the benzalkonium chloride to the propylene glycol monobutyl ether is 1: 1.
The preparation method of the condenser cleaner of the embodiment comprises the following steps:
s1, weighing alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride, propylene glycol monobutyl ether, sodium hydroxide and deionized water according to parts by weight.
S2, pouring the weighed deionized water into a homogenizer for heating and stirring, sequentially adding fatty alcohol-polyoxyethylene ether and sodium hydroxide in the stirring process, then stirring at a high speed until the mixture is uniform, and cooling to room temperature, wherein the heating temperature is 70 ℃.
And S3, adding alkylphenol polyoxyethylene, fatty alcohol polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride and propylene glycol monobutyl ether into the solution cooled in the step S2 at room temperature in sequence, mixing and stirring until the mixture is uniformly stirred at a high speed.
S4, filtering the solution stirred in the step S3, taking filtrate, pouring the filtrate into an aerosol can, installing a valve, sealing the aerosol can by a canning machine, and finally installing a spray head on the aerosol can.
Wherein the aperture of the atomization spray hole of the spray head is 0.2-0.5 mm.
After the condenser cleaning agent is prepared, the cleaning agent is sprayed on the surface of a condenser of an automobile air conditioner, then the cleaning agent can automatically dissolve stains, dust and the like on the surface of the condenser, meanwhile, the cleaning agent can automatically delay foaming and is low-foaming or non-foaming after being sprayed on the surface of the condenser, after standing for 1-3 minutes, the surface of the condenser can be cleaned by clear water, so that the stains, dust and the like on the surface of the condenser can be easily washed, the surface of an engine can recover luster again, meanwhile, the rust resistance, the antistatic property and the like on the surface of the engine are guaranteed, and the cleaning is convenient and fast, but the cleaning cannot be carried out by a high-pressure.
Index of experiment pH value Colour(s) Cleaning results Amount of foaming Smell(s) Tactile sensation
Example one 7.5 White colour Also has a small amount of stains and oxide residues Low foam Has no pungent odor Has no irritation
Example two 8.5 Light yellow No obvious stain and oxide residue A little more foaming Has a slight odor Has no irritation
EXAMPLE III 8 White colour No obvious stain and oxide residue Low foam Has no pungent odor Has no irritation
According to the comparison of the experimental indexes, when the pH value is alkaline and close to neutral, the cleaning effect is poor, but the foaming amount is low; when the pH value is 8.5 or more, the cleaning effect is good, but the cleaning agent has slight smell and more foaming amount; the pH value is about 8, the cleaning efficiency is good, no smell is generated, the foaming amount is low, and various experimental indexes are optimal.
The above-described embodiments are merely preferred embodiments of the present invention, which is not intended to limit the present invention in any way. Those skilled in the art can make many changes and modifications to the disclosed embodiments, or modify equivalent embodiments to practice the disclosed embodiments, without departing from the scope of the disclosed embodiments. Therefore, equivalent variations made according to the idea of the present invention should be covered within the protection scope of the present invention without departing from the contents of the technical solution of the present invention.

Claims (6)

1. A condenser cleaner characterized by: the composition comprises the following components in parts by mass: 2-10 parts of alkylphenol polyoxyethylene, 5-25 parts of fatty alcohol polyoxyethylene ether, 5-15 parts of fatty alcohol polyoxyethylene ether sulfate, 0.5-4 parts of coconut oil fatty acid diethanolamide, 1-5 parts of benzalkonium chloride, 1-5 parts of propylene glycol monobutyl ether, 0.1-1 part of sodium hydroxide and 35-85.4 parts of deionized water.
2. A condenser cleaner as claimed in claim 1 wherein: the ratio of benzalkonium chloride to propylene glycol butyl ether was 1: 1.
3. A condenser cleaner as claimed in claim 1 wherein: 6 parts of alkylphenol ethoxylates, 15 parts of fatty alcohol-polyoxyethylene ether, 10 parts of fatty alcohol-polyoxyethylene ether sulfate, 2 parts of coconut oil fatty acid diethanolamide, 3 parts of benzalkonium chloride, 3 parts of propylene glycol monobutyl ether, 0.5 part of sodium hydroxide and 60.5 parts of deionized water.
4. A method of making a condenser cleaner according to claim 1 wherein: the method comprises the following steps:
s1, weighing alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride, propylene glycol monobutyl ether, sodium hydroxide and deionized water according to parts by weight;
s2, pouring the weighed deionized water into a homogenizer for heating and stirring, sequentially adding fatty alcohol-polyoxyethylene ether and sodium hydroxide in the stirring process, then stirring at a high speed until the mixture is uniform, and cooling to room temperature, wherein the heating temperature is 45-95 ℃;
s3, adding alkylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether sulfate, coconut oil fatty acid diethanolamide, benzalkonium chloride and propylene glycol monobutyl ether into the solution cooled in the step S2 at room temperature in sequence, mixing and stirring until the mixture is uniformly stirred at a high speed;
s4, filtering the solution stirred in the step S4, taking filtrate, pouring the filtrate into an aerosol can, installing a valve, sealing the aerosol can by a canning machine, and finally installing a spray head on the aerosol can.
5. The method of claim 4, wherein the condenser cleaning agent is prepared by: the optimal heating temperature in step S2 is 70 ℃.
6. The method of claim 4, wherein the condenser cleaning agent is prepared by: the aperture of the atomization spray hole of the spray head is 0.2-0.5 mm.
CN202010962355.4A 2020-09-14 2020-09-14 Condenser cleaning agent Pending CN112080351A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020867A (en) * 2007-02-12 2007-08-22 陆丽玲 Fast foaming air conditioner cleaning agent
CN103540430A (en) * 2012-07-10 2014-01-29 3M创新有限公司 Detergent for air conditioner radiator
CN106398890A (en) * 2016-08-30 2017-02-15 广东月福汽车用品有限公司 Automobile air container evaporation box detergent and preparation method thereof
CN110184131A (en) * 2019-05-23 2019-08-30 广州三乐环保科技有限公司 A kind of environment-friendly household air conditioner cleaning agent and preparation method thereof
CN110846668A (en) * 2019-11-21 2020-02-28 中车长江车辆有限公司 Water-based cleaning agent and application thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020867A (en) * 2007-02-12 2007-08-22 陆丽玲 Fast foaming air conditioner cleaning agent
CN103540430A (en) * 2012-07-10 2014-01-29 3M创新有限公司 Detergent for air conditioner radiator
CN106398890A (en) * 2016-08-30 2017-02-15 广东月福汽车用品有限公司 Automobile air container evaporation box detergent and preparation method thereof
CN110184131A (en) * 2019-05-23 2019-08-30 广州三乐环保科技有限公司 A kind of environment-friendly household air conditioner cleaning agent and preparation method thereof
CN110846668A (en) * 2019-11-21 2020-02-28 中车长江车辆有限公司 Water-based cleaning agent and application thereof

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Application publication date: 20201215