CN112057408A - 具有锌离子的三合一水溶液添加剂及制备、使用方法 - Google Patents

具有锌离子的三合一水溶液添加剂及制备、使用方法 Download PDF

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CN112057408A
CN112057408A CN202010959652.3A CN202010959652A CN112057408A CN 112057408 A CN112057408 A CN 112057408A CN 202010959652 A CN202010959652 A CN 202010959652A CN 112057408 A CN112057408 A CN 112057408A
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谢文富
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Abstract

本发明涉及水溶液添加剂领域，具体的涉及一种具有具远红外线、负离子与抗菌锌离子的三合一水溶液添加剂的制备及使用方法。本发明的具远红外线、负离子与抗菌锌离子的三合一水溶液添加剂可以在摄氏34度下发射能促进人体血液循环和具有高催化和吸附效应的12‑13微米远红外线光波与产生可以净化空气、消除异味、加强人体免疫系统的负离子等作用，更可以释放锌离子来达到长效抑菌和杀菌的目标。使用范围广，可用于要以水剂来做调和的环保材料上，可作为涂层喷涂于基材表面，可作为护肤保养品的水剂成分，使这些材料成为具有特殊保健、养身、安全、抗菌的特殊性功能材料，增加其附加之价值，也达到环保、安全、科技与创新之材料创新目标。

Description

具有锌离子的三合一水溶液添加剂及制备、使用方法
技术领域
本发明涉及水性环保材料领域，具体的涉及一种具有远红外线、负离子与具有锌离子的三合一水溶液添加剂及制备、使用方法。
背景技术
现有的陶瓷、木材、合板与水泥漆、乳胶漆和透明漆类努力发展的方向均在朝向环保建材，避免产生有毒黏著剂释放出甲醛和苯或是塑化剂，虽有人试著添加负离子材料来清除这些产制品的异味，但是往往效果不彰，衰退快，或是无法与材料完全均匀混合，水泥与石膏则尚未发展出能释放出负离子与远红外线的材料。
在陶瓷技术领域，已有陶瓷釉料纳米孔隙水溶液添加剂的制备和使用方法的案例，如专利号为：CN103951467B的发明专利公开了一种陶瓷陶瓷釉料纳米孔隙水溶液添加剂的制备方法，该种陶瓷釉料纳米孔隙水溶液添加剂将水蒸汽通过孔隙尺寸小于100纳米的纳米孔隙材料颗粒，经冷凝后取得的水溶液即为陶瓷釉料纳米孔隙水溶液添加剂，所述纳米孔隙材料颗粒包括SiO2、TiO2、Al2O3、Fe2O3和沸石中的至少一种。
目前所谓具有功能性的陶瓷多以具有均匀分布的微孔，体积密度小的多孔性陶瓷，即在陶瓷原料中添加如硅化物、碳化物、氮化物、硼化物及氧化物等等的物质，或添加电气土等负离子粉与及含有远红外线的粉体，这些都可以使陶瓷在经过窑炉锻烧后具备一定的功能性，各家均有其制作的特殊原料配方和制作方法。至于木材、胶合板、矽酸钙板、壁纸材料与水泥漆、乳胶漆和透明漆类努力发展的方向均在走向环保建材趋势，避免产生有毒黏著剂释放出甲醛和苯或是塑化剂，虽有人试著添加负离子粉体材料来清除这些产制品的异味，但是往往效果不彰，衰退快，或是无法与材料完全均匀混合，至于油性类涂料或是需要使用树脂来做胶合，或是油性材料，这些无法与水性物质相匹配，现有的陶瓷釉料纳米孔隙水溶液添加剂使用范围窄、在环保材料、日用化妆品、油性溶剂等方面均不能适用。
发明内容
为了解决现有技术的不足，本发明提供了一种具有远红外线、负离子、抗菌锌离子的三合一水溶液添加剂的制备及使用方法。
为实现上述目的，本发明采用的技术方案如下：具有锌离子的三合一水溶液添加剂的制备方法，其特征在于，包括如下步骤：
步骤一，将水作为载体，沸腾时变成水蒸气；
步骤二，让水蒸汽的小水分子包围在20-30纳米孔隙材料所产生的粒子，经过冷凝器冷凝后取得的水溶液，所述纳米孔隙材料包括：SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3和稀土与三维粒状沸石中的至少一种或多种；
步骤三，在水溶液中添加有机蚬壳粉，使具远红外线及负离子的水溶液呈现PH值为11的强碱水溶液，所述蚬壳粉为蚬壳经锻烧后研磨而成；
步骤四，在强碱水溶液中加入10纳米的ZaO2，使此水溶液的PH值7-8即成三合一水溶液添加剂。
进一步的，步骤一的水载体经过RO逆渗透处理及O3与紫外光杀菌后，加热至100-130度成水蒸汽。
进一步的，所述步骤2中的原料包括SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.43-0.48：0.08-0.12：0.06-0.10：0.04-0.08：0.04-0.08：0.04-0.08：0.08-0.12：0.06-0.10。
进一步的，所述纳米孔隙材料SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.46：0.10：0.08：0.06：0.06：0.06：0.10：0.08。
进一步的，将具有锌离子的三合一水溶液添加剂加入水剂中，所述具有锌离子的三合一水溶液添加剂的添加量占水剂重量百分比为30-100％，再将所述水剂与粉体材料混合后制成环保材料。
进一步的，环保材料包括水性涂料，所述混合有三合一水溶液添加剂的水剂的PH值介于7-8，具有锌离子的三合一水溶液添加剂的添加重量占水剂百分比为30-50％。
进一步的，环保材料包括水泥或石膏，所述混合有三合一水溶液添加剂的水剂的PH值介于7-8，具有锌离子的三合一水溶液添加剂的添加重量占水剂百分比为50-100％。
进一步的，所述的环保材料为陶瓷材料，所述水剂与陶瓷粉体均匀混合制成胚体，经过窑炉摄氏1200-1380度烧结后，获得陶瓷材料。
进一步的，将具有锌离子的三合一水溶液添加剂喷涂于基材表面。
进一步的，将具有锌离子的三合一水溶液添加剂加入水剂中，所述水剂作为美妆保养品制作的原料，所述具有锌离子的三合一水溶液添加剂的添加量占水剂重量百分比为10-100％。
本发明的具远红外线、负离子与抗菌锌离子的三合一水溶液添加剂可以在摄氏34度下发射能促进人体血液循环和具有高催化和吸附效应的12-13微米远红外线光波与产生可以净化空气、消除异味、加强人体免疫系统的负离子等作用，更可以释放锌离子来达到长效抑菌和杀菌的目标。使用范围广，可用于要以水剂来做调和的环保材料上，如陶瓷、水泥、石膏等粉体材料或水泥漆、乳胶漆、透明漆等，可作为涂层喷涂于基材表面，可作为护肤保养品的水剂成分，使这些材料成为具有特殊保健、养身、安全、抗菌的特殊性功能材料，增加其附加之价值，也达到环保、安全、科技与创新之材料创新目标。
附图说明
图1为三合一水溶液添加剂经检测远红外线放射率的检测示意图。
图2为具体实施例一中水性涂料经检测远红外线放射率的检测示意图。
图3为具体实施例二中陶瓷材料经检测远红外线放射率的检测示意图。
图4为具体实施例三中石膏板经检测远红外线放射率的检测示意图。
图5为具体实施例四中壁纸经检测远红外线放射率的检测示意图。
具体实施方式
以下通过具体实施方式对本发明作进一步的描述。
具有锌离子的三合一水溶液添加剂的制备方法，其特征在于，包括如下步骤：
步骤一，将水作为载体，水载体经过RO逆渗透处理及O3与紫外光杀菌后，加热至100-130度，沸腾时变成水蒸气；
步骤二，让水蒸汽的小水分子包围在20-30纳米孔隙材料所产生的粒子，经过冷凝器冷凝后取得的水溶液，所述纳米孔隙材料包括：SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3和稀土与三维粒状沸石中的至少一种或多种，优选的步骤2中的原料包括SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.43-0.48：0.08-0.12：0.06-0.10：0.04-0.08：0.04-0.08：0.04-0.08：0.08-0.12：0.06-0.10；进一步的，纳米孔隙材料SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.46：0.10：0.08：0.06：0.06：0.06：0.10：0.08；
步骤三，在水溶液中添加有机蚬壳粉，使具远红外线及负离子的水溶液呈现PH值为11的强碱水溶液，所述蚬壳粉为蚬壳经锻烧后研磨而成；
步骤四，在强碱水溶液中加入10纳米的Activity ZaO2，使此水溶液的PH值7-8即成三合一水溶液添加剂。
三合一水溶液添加剂经检测远红外线放射率，结果参见图1所示，经检测负离子，结果如下表所示：
Figure BDA0002680024200000051
具有锌离子的三合一水溶液添加剂的使用方法，
具体实施例一：
将上述的三合一水溶液添加剂加入水剂中，所述混合有三合一水溶液添加剂的水剂的PH值介于7-8，三合一水溶液添加剂添加重量占水剂百分比为48％，水剂与水泥漆、乳胶漆、透明漆等涂料材料混合，获得环保材料包括水性涂料；
获得的水性涂料材料即可以释放远红外线及负离子与锌离子抗菌效果的装修材料，让装修后的房子变成能释放远红外线及负离子及抗菌效果的健康洁净无菌房子，特别是负离子能去除原来涂料中含有的甲醛与苯的有害物质，使装修材料没有异味，更能具抗菌效果；
获得的水性涂料经检测远红外线放射率，结果参见图2所示，经检测负离子，结果如下表所示：
Figure BDA0002680024200000052
Figure BDA0002680024200000061
具体实施例二：
将上述的三合一水溶液添加剂加入水剂中，所述水剂与陶瓷粉体均匀混合制成胚体，经过窑炉摄氏1200-1380度烧结后，获得陶瓷材料；
获得的陶瓷材料可释放出远红外线与负离子，用来当作容器可以改变水质，让水质变得更细小、滑顺，人体更容易吸收，由于具有远红外线与负离子的陶瓷，产生纳米的小尺寸效应与量子效应，可以让一般陶瓷变成具有功能性的特殊效用，同时烧结的陶瓷能释放锌离子达到抗菌的效果。
获得的陶瓷材料经检测远红外线放射率，结果参见图3所示，经检测负离子，结果如下表所示：
Figure BDA0002680024200000062
具体实施例三：
将三合一水溶液添加剂加入水剂中，所述水剂与水泥或石膏混合；混合有三合一水溶液添加剂的水剂的PH值介于7-8，三合一水溶液添加剂添加重量占水剂百分比为68％；
获得的水泥、石膏等建筑装修材料成为可以释放远红外线及负离子和能释放抗菌之锌离子的保健养身抗菌之健康安全建筑材料，由于产生的12-13微米远红外线可以改善人体血液循环、活化细胞、净化血液、提高免疫力、调整自律神经和改善关节疼痛问题。而负离子能高效去除空气中的PM2.5及以下危害更大的超细颗粒物、分解有害气体及装修污染、杀灭细菌病毒及过敏源、缓释森林芬多精营造森林环境等功效，同时在这样的建筑材料环境下不怕细菌之侵袭危害，可以赋予建筑物成为保健养生抗菌之健康安全的好环境。
获得的石膏板经检测远红外线放射率，结果参见图4所示，经检测负离子，结果如下表所示：
Figure BDA0002680024200000071
具体实施例四：
将具有远红外线、负离子与抗菌锌离子的三合一水溶液添加剂喷涂于基材表面，基材为木材胶合板、矽酸钙板、壁纸材料做均匀喷涂，让水溶液添加剂深入木材、胶合板、矽酸钙板、壁纸等材料的孔洞中，由于木材、胶合板、矽酸钙板、壁纸有很高的孔洞吸附作用，于干燥后将始能释放远红外线及负离子与锌离子留存于木材、胶合板、矽酸钙板、壁纸材料上，使木材、胶合板、矽酸钙板、壁纸材料成为可以释放远红外线及负离子和抗菌锌离子的装修材料。
获得的基材亦可以变成具备可以在摄氏34度下发射能促进人体血液循环和具有高催化和吸附效应的12～13微米远红外线光波与产生可以净化空气、消除异味、加强人体免疫系统的负离子与可以抗各种细菌之锌离子等特殊作用。
获得的壁纸经检测远红外线放射率，结果参见图5所示，经检测负离子，结果如下表所示：
Figure BDA0002680024200000072
Figure BDA0002680024200000081
具体实施例五：
将具有远红外线、负离子与抗菌锌离子的三合一水溶液添加剂加入水剂中，所述水剂作为美妆保养品制作的原料，所述三合一水溶液添加剂的添加量占水剂重量百分比为10-100％。
获得的美妆保养品具有远红外线及负离子之效能，使保养品成分更能渗入肌肤，活化肌肤，远红外线作用于人体的皮肤，能激活皮肤组织细胞，使细胞内的酶胺基酸、核酸等生命活性成份被激发，促进黑色素颗粒代谢和白细胞的吞噬能力，由于强化细胞的再生和固水率抑制黑色素的形成，消除色斑，加之皮肤各层细胞能量的传递和共振，将产生一定范围的重组，使表皮层趋向平滑，并修复真皮内的纤维断层，同时还使脂肪密致化，可迅速增加皮肤的弹性和光泽，达到养颜美容的效果。同时由于锌离子可以达到长效抗菌，因此制作美妆保养品时不须添加防腐剂与抗菌剂，避免肌肤引起过敏，更能达到美妆保养之有效性；
而运用本发明之三合一水剂来取代以水作为主要成分之护肤保养品系列，可以让制作出来的护肤保养品具有远红外线及负离子与抗菌之锌离子，去保护肤保养品不用添加对人体肌肤有害之防腐剂或抑菌剂，更能因为具有能产生12-13微米的“非热效应”远红外线，使保养品成分更能渗入肌肤，活化肌肤，远红外线作用于人体的皮肤，能激活皮肤组织细胞，使细胞内的酶胺基酸、核酸等生命活性成份被激发，促进黑色素颗粒代谢和白细胞的吞噬能力，由于强化细胞的再生和固水率抑制黑色素的形成，消除色斑，加之皮肤各层细胞能量的传递和共振，将产生一定范围的重组，使表皮层趋向平滑，并修复真皮内的纤维断层，同时还使脂肪密致化，可迅速增加皮肤的弹性和光泽，达到养颜美容的效果。
上述仅为本发明的一个具体实施方式，但本发明的设计构思并不局限于此，凡利用此构思对本发明进行非实质性的改动，均应属于侵犯本发明保护范围的行为。

Claims (10)

1.具有锌离子的三合一水溶液添加剂的制备方法，其特征在于，包括如下步骤：
步骤一，将水作为载体，沸腾时变成水蒸气；
步骤二，让水蒸汽的小水分子包围在20-30纳米孔隙材料所产生的粒子，经过冷凝器冷凝后取得的水溶液，所述纳米孔隙材料包括：SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3和稀土与三维粒状沸石中的至少一种或多种；
步骤三，在水溶液中添加有机蚬壳粉，使具远红外线及负离子的水溶液呈现PH值为11的强碱水溶液，所述蚬壳粉为蚬壳经锻烧后研磨而成；
步骤四，在强碱水溶液中加入10纳米的ZaO2，使此水溶液的PH值7-8即成三合一水溶液添加剂。
2.根据权利要求1所述的具有锌离子的三合一水溶液添加剂的制备方法，其特征在于：所述步骤一的水载体经过RO逆渗透处理及O3与紫外光杀菌后，加热至100-130度成水蒸汽。
3.根据权利要求1所述的具有锌离子的三合一水溶液添加剂的制备方法，其特征在于，所述步骤2中的原料包括SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.43-0.48：0.08-0.12：0.06-0.10：0.04-0.08：0.04-0.08：0.04-0.08：0.08-0.12：0.06-0.10。
4.根据权利要求4所述的具有锌离子的三合一水溶液添加剂的制备方法，其特征在于：所述纳米孔隙材料SiO2、TiO2、Al2O3、Fe2O3、FeO、B2O3、稀土和三维粒状沸石，原料的重量比为：0.46：0.10：0.08：0.06：0.06：0.06：0.10：0.08。
5.具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：将权利要求1-4中任意一项所述的具有锌离子的三合一水溶液添加剂加入水剂中，所述具有锌离子的三合一水溶液添加剂的添加量占水剂重量百分比为30-100％，再将所述水剂与粉体材料混合后制成环保材料。
6.根据权利要求5所述的具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：所述环保材料包括水性涂料，所述混合有三合一水溶液添加剂的水剂的PH值介于7-8，具有锌离子的三合一水溶液添加剂的添加重量占水剂百分比为30-50％。
7.根据权利要求5所述具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：所述环保材料包括水泥或石膏，所述混合有三合一水溶液添加剂的水剂的PH值介于7-8，具有锌离子的三合一水溶液添加剂的添加重量占水剂百分比为50-100％。
8.根据权利要求5所述的具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：所述的环保材料为陶瓷材料，所述水剂与陶瓷粉体均匀混合制成胚体，经过窑炉摄氏1200-1380度烧结后，获得陶瓷材料。
9.具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：将权利要求1-4中任意一项所述的具有锌离子的三合一水溶液添加剂喷涂于基材表面。
10.具有锌离子的三合一水溶液添加剂的使用方法，其特征在于：将权利要求1-4中任意一项所述的具有锌离子的三合一水溶液添加剂加入水剂中，所述水剂作为美妆保养品制作的原料，所述具有锌离子的三合一水溶液添加剂的添加量占水剂重量百分比为10-100％。
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