CN112048672A - HB 450-grade high-wear-resistance thin steel plate and production method thereof - Google Patents
HB 450-grade high-wear-resistance thin steel plate and production method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
Abstract
The invention relates to a HB450 grade high wear-resistant thin steel plate and a production method thereof, wherein the steel plate comprises the following chemical components in percentage by weight: c: 0.18% -0.22%, Si: 0.10-0.30%, Mn: 1.0-1.5%, Cr 0.20-0.40%, B: 0.005-0.010%, Ti: 0.03% -0.06%, Ti/B is more than or equal to 3.0, Als: 0.015% -0.045%; the balance of Fe and inevitable impurities; the steel plate is mainly characterized by chemical composition design of carbon and medium boron microalloying, and trace elements such as Cr and Ti are added in a compounding manner; simple components, relatively low alloy content, good weldability, low cost and convenient smelting and continuous casting; the production process is simple, and the steel plate has good plate shape, plasticity and toughness and forming performance.
Description
Technical Field
The invention relates to the technical field of steel plate production, in particular to a HB 450-grade high-wear-resistance thin steel plate and a production method thereof.
Background
Compared with the traditional high manganese steel, the low alloy wear-resistant steel has higher surface hardness and wear resistance, is generally designed by adopting medium-low carbon B, Cr, Mo and Ni composite microalloying components, and is produced by adopting a heat treatment mode of quenching or on-line quenching and low-temperature tempering.
The wear resistance of the wear-resistant steel plate depends on the structure hardness of a steel plate matrix and the size, the number, the hardness and the distribution of wear-resistant particles precipitated in the steel, and the low-alloy wear-resistant steel is generally designed by adopting a martensite matrix and low-hardness carbides such as Cr, Mo, V and the like to strengthen the wear resistance. The improvement of the wear resistance of HB450 grade wear resistant steel is generally realized by increasing the carbon content and the alloy content of the steel plate, thereby causing the deterioration of the processing property and the welding property of the steel.
In the production process of the industries such as heavy mine cars, coal machines, cement and the like, due to the fact that materials are hard, movement is fast, equipment is abraded seriously, spare parts are abraded fast, the overhaul period is short, the abrasion resistance of a common HB450 abrasion-resistant steel plate can not meet the use requirement of the ordinary HB450 abrasion-resistant steel plate, if abrasion-resistant steel with high hardness grade is used, the machining and welding performance can be seriously reduced, and production and use are influenced. Therefore, there is a strong demand for a high wear-resistant steel sheet of grade HB450, which can prolong the service life of spare parts without increasing hardness.
In order to improve the wear resistance of low-alloy steel plates, technicians in different fields have adopted methods such as bimetal compounding, surfacing and embedding of high-hardness wear-resistant alloy layers, wear-resistant ceramic layers or rubber layers, and although better wear resistance is obtained, the working procedures are complex, the cost is higher, and the technological properties such as welding, bending and the like are poorer. In recent years, in some steel mills at home and abroad, the contents of Ti and V are increased in low-alloy wear-resistant steel, and the wear resistance is enhanced by utilizing martensite matrix to increase the hardness of TiC and VC, although the cost is lower, the plasticity and the toughness of the steel are poorer, so the popularization and the application are difficult.
The high-wear-resistance bimetal composite wear-resisting plate disclosed in the Chinese patent with the publication number of CN103725976B comprises a low-carbon steel plate or a low-carbon alloy steel plate, wherein a wear-resistance alloy layer is welded on the low-carbon steel plate or the low-carbon alloy steel plate, and the wear-resistance alloy layer comprises the following components in percentage by mass: c: 0.35-0.55%; si: 2-2.4%; mn: 2.7-3.2%; cr: 11-12.5%; mo: 2.5-2.9%; v: 0.7-1.8%; w: 2.2-3.6%; b: 0.7 to 1.1 percent; the balance being iron. Its advantages are smooth surface and high antiwear performance. The wear-resisting plate is produced by adopting a process of bimetal composite surfacing in the technical scheme, the process is complex, the cost is high, and the steel plate cannot be molded and processed due to high hardness of a surfacing layer.
The Chinese patent with publication number CN105695861B discloses a wear-resistant rolled composite steel plate, which is formed by hot rolling a base material and a composite material, wherein the base material is a common carbon steel plate, and the composite material is a high-strength wear-resistant steel plate; the general carbon steel plate comprises the following components in percentage by mass: 0.1-0.2%, Si: 0.15 to 0.35%, Mn: 0.5-1.4%, P: less than or equal to 0.04 percent, S: less than or equal to 0.04 percent, and the balance being Fe; the high-strength wear-resistant steel plate comprises the following components in percentage by mass: 0.20-0.35%, W: 1.0-2.0%, Si: 0.5-1.5%, Mn: 0.8-1.5%, Cr: 1.0-2.0%, Ti: 1.0-2.0%, S: less than or equal to 0.04 percent, P: less than or equal to 0.04 percent and the balance of Fe. The general carbon steel plate has excellent overall performance, high strength, high shaping performance, high welding performance and the like, and low cost; the high-strength wear-resistant steel plate has high hardenability, high toughness, excellent low-temperature toughness, excellent crack resistance and excellent welding performance; according to the technical scheme, the high wear resistance is obtained by a hot rolling composite method of the common carbon steel plate and the high-strength wear-resistant steel plate, the production process is complex, and the steel plate does not have the formability.
The Chinese invention patent with the publication number of CN105063497B discloses a low-alloy wear-resistant steel plate with high wear resistance and easy processing and a manufacturing method thereof, wherein the wear-resistant steel plate comprises the following components in percentage by weight: 0.12-0.35% of C, 0.20-0.60% of Si, 0.80-1.60% of Mn, less than or equal to 0.015% of P, less than or equal to 0.004% of S, 0.00-0.60% of Mo, 0.000-0.040% of V, 0.00-1.20% of Cr0.08-0.30% of Ti, 0.02-0.06% of Als, 0.0008-0.004% of B, less than or equal to 0.0045% of N, and the balance of Fe and inevitable impurities. The steel plate is excellent in mechanical property, and the wear resistance of the steel plate is 1.3-3.0 times that of the steel plate under the same hardness condition. Although the low-alloy wear-resistant steel plate in the technical scheme has good wear resistance, the low-alloy wear-resistant steel plate has high Ti content and is difficult to smelt and continuously cast, and the manufacturing method is not easy to implement.
Chinese patent application with publication number CN104789881A discloses a production method of a high-strength high-toughness wear-resistant steel plate, which comprises the following chemical components in percentage by mass: 0.15 to 0.26% of C, 0.20 to 0.55% of Si, 1.0 to 1.60% of Mn, 0.020% or less of P, 0.010% or less of S, 0.00 to 0.60% of Mo, 0.00 to 0.50% of Ni, 0.20 to 1.00% of Cr, 0.01 to 0.05% of Ti, 0.02 to 0.04% of Als, 0.0005 to 0.004% of B, and the balance of Fe and inevitable impurities. The production process flow of the steel comprises the following steps: smelting high-cleanness steel, desulfurizing molten iron, blowing at the top and the bottom of a converter, vacuum processing and casting blank. The steel has no V and no Mo and Ni or less Mo and Ni in chemical components, has low alloy content and good toughness, and can be widely applied to mines and engineering machinery products with severe working conditions and high requirements on the performance of steel grades. The high-toughness ultrahigh-strength wear-resistant steel plate produced by the method has the surface Brinell Hardness (HB) of 420-480 and the impact toughness at minus 40 ℃ of more than or equal to 40J, and meanwhile has good toughness matching and high wear resistance, the carbon equivalent is low and is between 0.41 and 0.55, and the high-toughness ultrahigh-strength wear-resistant steel plate has good welding performance; the component design adopts a component system without V and Mo and Ni or less Mo and Ni, so that the cost is saved to a certain extent. However, the steel produced by the technical scheme is HB450 grade common wear-resistant steel and does not have high wear resistance.
Chinese patent application publication No. CN109072367A discloses a "wear-resistant steel sheet and a method for producing a wear-resistant steel sheet", the steel sheet having a composition containing, in mass%: c: 0.10 to 0.23%, Si: 0.01 to 1.0%, Mn: 0.30-3.00%, P: 0.025% or less, S: 0.02% or less, Cr: 0.01-2.00%, Al: 0.001 to 0.100%, and N: 0.01% or less, and the balance being Fe and unavoidable impurities, wherein the volume fraction of martensite in the structure at a depth of 1mm from the surface of the wear-resistant steel sheet is 90% or more, the prior austenite grain diameter of the plate thickness center portion of the wear-resistant steel sheet is 80 μm or less, and the hardness at a depth of 1mm from the surface of the wear-resistant steel sheet is 360 to 490 in terms of Brinell hardness, and a method for producing the wear-resistant steel sheet and the wear-resistant steel sheet. The steel plate has complex alloy components and high cost, and only has the wear resistance of the common steel plate.
The publication of 'the influence of a hot rolling temperature system on the performance of a high-strength hot-rolled wear-resistant coiled plate' (published by the Tang dynasty et al in 2006 and a second national Bao Steel academic annual meeting treatise) researches the influence of hot rolling processes such as soaking temperature, finishing temperature and coiling temperature on the structure and performance of Ti-containing low-carbon microalloyed steel. The method is high-Ti high-strength steel, the hardness is low, and smelting and continuous casting are difficult.
The published literature, "wear performance research of vanadium-titanium modified mechanical NM450 steel" (Lei Shi Ying et al, No. 3 of 2019), describes that vanadium and titanium are added on the basis of the components of common NM450 steel for modification, and the result shows that compared with NM450 steel, the weight loss, the grinding crack depth and the grinding crack area of the NM450-0.2V sample added with vanadium are respectively reduced by 5.36%, 11.11% and 27.27%; the weight loss, the grinding crack depth and the grinding crack area of the NM450-0.2Ti sample added with the titanium element are respectively reduced by 8.93%, 13.89% and 36.36%; the weight loss, the grinding trace depth and the grinding trace area of the NM450-0.2V-0.2Ti sample added with vanadium and titanium are respectively reduced by 16.07 percent, 23.61 percent and 54.55 percent, the wear performance of the NM450 steel is favorably improved by carrying out vanadium-titanium modification on the NM450 steel, and the wear performance of the NM450-0.2V-0.2Ti sample added with vanadium and titanium is optimal. The method is V and Ti wear-resistant steel, has high cost and is difficult to smelt and continuously cast. .
In summary, the thin gauge wear resistant steel plates described in the prior documents generally have the following disadvantages: 1) the chemical components and the process are complex, or heterogeneous compounding or overlaying is needed; 2) the steel contains 0.1 to 0.5 percent of Ti or V, which causes difficulty in smelting and continuous casting; 3) the cold forming cannot be carried out; 4) the wear resistance is insufficient.
Disclosure of Invention
The invention provides a HB450 grade high wear-resistant thin steel plate and a production method thereof, wherein the chemical composition design of the steel plate is mainly characterized by carbon and medium boron microalloying, and trace elements such as Cr, Ti and the like are added in a compounding way; simple components, relatively low alloy content, good weldability, low cost and convenient smelting and continuous casting. The steel plate is produced by a mode of adding off-line heat treatment to a common hot-rolled coil, the coil is curled into a steel coil with the thickness of 4-10 mm after being cooled, and quenching and tempering heat treatment are carried out after flattening to obtain the steel plate with good wear resistance and formability; the production process is simple, and the steel plate has good plate shape, plasticity and toughness and forming performance.
In order to achieve the purpose, the invention adopts the following technical scheme:
an HB450 grade high-abrasion steel sheet, the chemical composition of the steel sheet is as follows by weight percent: c: 0.18% -0.22%, Si: 0.10-0.30%, Mn: 1.0-1.5%, Cr 0.20-0.40%, B: 0.005-0.010%, Ti: 0.03% -0.06%, Ti/B is more than or equal to 3.0, Als: 0.015% -0.045%; the balance of Fe and inevitable impurities; impurity element control in steel: p is less than or equal to 0.015 percent, S is less than or equal to 0.003 percent, N is less than or equal to 0.0040 percent, H is less than or equal to 0.00015 percent, and O is less than or equal to 0.0015 percent.
The thickness of the steel plate is 4-10 mm.
The surface hardness of the steel plate is more than HB420, and the straightness is less than or equal to 5 mm/m.
A production method of HB450 grade high abrasion steel sheet comprises the following steps: molten iron pretreatment, converter smelting, refining, slab continuous casting, rolling and heat treatment; wherein:
1) converter smelting and refining processes;
converter smelting is carried out through top blowing or top-bottom combined blowing, then refining treatment and microalloying are carried out, and the content of impurities in steel is controlled within a limited range; the RH vacuum circulation time is more than or equal to 15min during refining;
2) a slab continuous casting process;
electromagnetic stirring or soft pressing is adopted, intercooling is adopted in a secondary cooling area, and the drawing speed of the continuous casting billet is controlled to be 1.0-1.5 m/min;
3) the rolling process comprises the following steps:
the thickness of the casting blank is 135-250 mm, the heating temperature before rolling is 1150-1200 ℃, and the heating and heat preservation time is controlled to be 1.0-1.5 min/mm; two-stage controlled rolling is adopted, the initial rolling temperature of rough rolling is more than or equal to 1050 ℃, and the final rolling temperature of rough rolling is more than or equal to 980 ℃; the single-pass reduction rate of rough rolling is not lower than 15%; the finish rolling temperature is 970-1040 ℃, the reduction rate of a single stand of the finish continuous rolling is not lower than 10%, the rolling speed is 5-15 m/s, and the finish rolling temperature is 850-900 ℃; taking out the steel from the finish rolling, immediately carrying out laminar cooling at a cooling speed of more than or equal to 15 ℃/s, coiling at 550-600 ℃, and air-cooling to room temperature;
4) the heat treatment process comprises the following steps:
adopting a heat treatment mode of quenching and tempering; quenching is carried out in a continuous quenching machine in two stages, wherein the first-stage quenching adopts heating at 850-950 ℃ for total heating time of 1.5-2.0 min/mm, the second-stage quenching adopts cooling heating at 730-830 ℃ for total cooling time of 1-2 min/mm; the speed of the discharging roller way of the continuous quenching machine is more than or equal to 30 m/min; the tempering temperature is 150-250 ℃, and the tempering heat preservation time is 4-8 min/mm.
Compared with the prior art, the invention has the beneficial effects that:
1) the steel plate is mainly characterized by carbon and medium boron microalloying in the chemical composition design, and trace elements such as Cr and Ti are added compositely; the components are simple, the alloy content is relatively low, the weldability is good, the production cost is low, and the smelting and continuous casting are convenient;
2) the surface hardness of the steel plate is more than HB420, and the flatness of the steel plate is less than or equal to 5 mm/m;
3) compared with the low-alloy wear-resistant steel with the same hardness, the wear resistance is improved by more than 1.3 times;
4) simple production process, good plasticity and toughness and good forming performance.
Detailed Description
The invention relates to a HB450 grade high wear-resistant thin steel plate, which comprises the following chemical components in percentage by weight: c: 0.18% -0.22%, Si: 0.10-0.30%, Mn: 1.0-1.5%, Cr 0.20-0.40%, B: 0.005-0.010%, Ti: 0.03% -0.06%, Ti/B is more than or equal to 3.0, Als: 0.015% -0.045%; the balance of Fe and inevitable impurities; impurity element control in steel: p is less than or equal to 0.015 percent, S is less than or equal to 0.003 percent, N is less than or equal to 0.0040 percent, H is less than or equal to 0.00015 percent, and O is less than or equal to 0.0015 percent.
The thickness of the steel plate is 4-10 mm.
The surface hardness of the steel plate is more than HB420, and the straightness is less than or equal to 5 mm/m.
A production method of HB450 grade high abrasion steel sheet comprises the following steps: molten iron pretreatment, converter smelting, refining, slab continuous casting, rolling and heat treatment; wherein:
1) converter smelting and refining processes;
converter smelting is carried out through top blowing or top-bottom combined blowing, then refining treatment and microalloying are carried out, and the content of impurities in steel is controlled within a limited range; the RH vacuum circulation time is more than or equal to 15min during refining;
2) a slab continuous casting process;
electromagnetic stirring or soft pressing is adopted, intercooling is adopted in a secondary cooling area, and the drawing speed of the continuous casting billet is controlled to be 1.0-1.5 m/min;
3) the rolling process comprises the following steps:
the thickness of the casting blank is 135-250 mm, the heating temperature before rolling is 1150-1200 ℃, and the heating and heat preservation time is controlled to be 1.0-1.5 min/mm; two-stage controlled rolling is adopted, the initial rolling temperature of rough rolling is more than or equal to 1050 ℃, and the final rolling temperature of rough rolling is more than or equal to 980 ℃; the single-pass reduction rate of rough rolling is not lower than 15%; the finish rolling temperature is 970-1040 ℃, the reduction rate of a single stand of the finish continuous rolling is not lower than 10%, the rolling speed is 5-15 m/s, and the finish rolling temperature is 850-900 ℃; taking out the steel from the finish rolling, immediately carrying out laminar cooling at a cooling speed of more than or equal to 15 ℃/s, coiling at 550-600 ℃, and air-cooling to room temperature;
4) the heat treatment process comprises the following steps:
adopting a heat treatment mode of quenching and tempering; quenching is carried out in a continuous quenching machine in two stages, wherein the first-stage quenching adopts heating at 850-950 ℃ for total heating time of 1.5-2.0 min/mm, the second-stage quenching adopts cooling heating at 730-830 ℃ for total cooling time of 1-2 min/mm; the speed of the discharging roller way of the continuous quenching machine is more than or equal to 30 m/min; the tempering temperature is 150-250 ℃, and the tempering heat preservation time is 4-8 min/mm.
The chemical composition design reason of the HB450 grade high-wear-resistance steel sheet is as follows:
c: the strength and the hardness of the wear-resistant steel plate are correspondingly increased along with the increase of the carbon content in a certain range, and the equivalent carbon content is required to ensure that the steel plate has high strength and hardness; meanwhile, carbon can form carbide precipitation with B, Cr and Ti, and the wear resistance is improved. But if the carbon content is too high, the plasticity and the toughness are reduced, the welding performance is reduced, and in order to ensure that the steel plate has high wear resistance, good welding performance, forming performance and low-temperature toughness, the content of C in the invention is controlled to be 0.18-0.22%.
Si: has the effects of solid solution strengthening and deoxidation, but the excessive Si content can reduce the welding performance of the steel and influence the surface quality of the steel plate, so the Si content is controlled to be 0.10-0.30 percent in the invention.
Mn: the main effect is solid solution strengthening, the supersaturation degree of carbon in martensite can be improved, the improvement of strength and hardness is facilitated, and the cost is low; but when the content is higher than 1.5 percent, center segregation is easy to form, so that the center of the slab has the tendency of easy cracking; therefore, the Mn content in the invention is controlled to be 1.0-1.5%.
B: the key point of the invention is to add elements, and B which is obviously higher than that of the conventional low-alloy wear-resistant steel is added in the wear-resistant steel, so that the main function is to ensure the high wear resistance of the steel plate. More than 0.005% of boron and titanium are compositely added into steel to form fine metal boride TiB2，B4C、TiB2The boride has high chemical stability, high hardness and excellent wear resistance, and can improve the wear resistance of the steel plate. Because B has strong affinity with oxygen and nitrogen in molten steel during smelting and is easy to carry out chemical combination reaction with the oxygen and the nitrogen, the effect of improving the wear resistance is lost, and the content of the oxygen and the nitrogen in the molten steel is reduced as much as possible during smelting. However, if the content of B is too large, the B tends to concentrate at grain boundaries, and the grain boundary bonding energy is lowered, so that hot embrittlement occurs during rolling of the steel sheet. After comprehensive consideration, the content of B is controlled to be 0.005-0.010%. To ensure the yield of B, the invention controls [ N ]]≤0.0040％，[O]Less than or equal to 0.0015 percent; meanwhile, in order to ensure the deoxidation effect of the steel and not to generate excessive oxide inclusions, Als: 0.015 to 0.045 percent.
Ti: the invention is characterized in that the key addition elements are cheap, a certain amount of Ti element is added into boron steel, and a certain cooling speed is matchedThe boride with continuous network distribution of crystal boundary can be changed into broken network and isolated distribution, so that hot brittleness can be avoided; in addition, the addition of Ti can reduce Fe in boron steel2B. The FeB is dispersed on the ferrite matrix, so that the uniform distribution of boride is facilitated, and the wear resistance of the steel is improved; the fine titanium carbonitride can also effectively inhibit the growth of crystal grains during heating and improve the plastic toughness of steel, so more than 0.03 percent of Ti is added; but when the content of Ti is too high, the smelting difficulty is increased, excessive and coarse TiC is formed in steel, the toughness, the hardenability and the cold bending property of the steel plate are reduced, and the ratio by weight of Ti: ti is added in the proportion of B being more than or equal to 3, so that the best effect can be obtained; when Ti/B is less than 3.0, the continuous network boride in the grain boundary cannot be broken, and hot embrittlement can occur. Therefore, the adding amount of Ti is controlled to be 0.03-0.06 percent, and the Ti/B ratio is controlled to be more than or equal to 3.0.
Cr: has the functions of solid solution strengthening, strength improvement and steel hardenability improvement. Chromium is a strong carbide forming element, can form various carbides in steel, and improves the strength and hardness of the steel plate after heat treatment. However, the weldability is affected by adding too much Cr, so the invention controls the addition of Cr to be 0.2-0.4%.
Control of impurity elements: in order to ensure that the steel plate has good shaping and toughness and avoid the occurrence of delayed cracks in cutting and welding of the high-strength steel plate, the invention controls P to be less than or equal to 0.015 percent, S to be less than or equal to 0.003 percent, N to be less than or equal to 0.0040 percent, H to be less than or equal to 0.00015 percent and O to be less than or equal to 0.0015 percent.
The production process flow design principle of the HB 450-grade high-wear-resistance thin steel plate is as follows:
1) controlling RH degassing time during refining, wherein RH vacuum cycle time is more than or equal to 15min, and controlling the [ N ] of the tundish molten steel to be less than or equal to 0.0040%, the [ O ] to be less than or equal to 0.0015% and the [ H ] to be less than or equal to 0.00015% through long-time vacuum treatment. In order to avoid boride precipitation in a high-temperature area, the cooling speed of a secondary cooling area is properly increased, and the drawing speed of the continuous casting billet is controlled to be 1.0-1.5 m/min. Electromagnetic stirring or soft pressing is adopted for continuous casting to reduce center segregation.
2) In order to ensure that the alloy can be fully dissolved in the solution, the heating and heat preservation time before rolling is controlled to be 1.0-1.5 min/mm; two-stage controlled rolling is adopted during rolling, and the purpose is to fully refine the hot-rolled structure; in the rolling process of the rough rolling stage, austenite undergoes the processes of dynamic recrystallization, static recrystallization and dynamic recovery, so that austenite grains are refined;
3) the production process of the front-section quick cooling after hot rolling is adopted, the cooling speed is more than or equal to 15 ℃/s, and the steel plate is coiled at 550-600 ℃ after quick cooling, so that the aggregation of boride in a crystal boundary during slow cooling can be reduced, the wear resistance of the steel plate can be ensured, and the shaping and toughness of the steel plate are not influenced.
4) The heat treatment process of sectional heating and low-temperature quenching is adopted during quenching, high-temperature heating during one-stage quenching can ensure that the austenitizing of the steel plate is uniform, the grain boundary net-shaped boride is fully dissolved back, cooling and heating during two-stage quenching can reduce the quenching starting temperature, reduce the internal stress of the steel plate, and is favorable for obtaining a good plate shape. The tempering temperature is 150-250 ℃, and the purpose is to further remove quenching internal stress, improve the shaping of the steel plate and ensure the cold forming performance of the steel plate.
The following examples are carried out on the premise of the technical scheme of the invention, and detailed embodiments and specific operation processes are given, but the scope of the invention is not limited to the following examples. The methods used in the following examples are conventional methods unless otherwise specified.
[ examples ] A method for producing a compound
In this embodiment, the chemical components of the smelting steel type are shown in table 1, and the production process flow of the steel plate specifically is as follows: molten iron pretreatment → converter smelting → refining → slab casting → heating → preliminary rolling → finish rolling → laminar cooling → coiling → cover slow cooling → uncoiling → quenching → tempering → inspection → packaging. The rolling process parameters are shown in table 2, the heat treatment process parameters are shown in table 3, the product performance test results are shown in tables 4, 5 and 6, and the wear resistance test results are shown in table 7.
Table 1 chemical composition of the steels, Wt%
TABLE 2 Rolling Process parameters
TABLE 3 Heat treatment Process parameters
TABLE 4 mechanical Properties of the Steel sheets
TABLE 5 Cold bending Properties at 180 ℃ of Steel plates
| Examples | 1-1 | 1-2 | 2-1 | 2-2 | 3-1 | 3-2 | 4-1 | 4-2 |
| Bend diameter (D ═ 4A) | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified |
TABLE 6 tensile mechanical Properties of the Steel sheets
| Examples | Thickness/mm | RP0.2/MPa | Rm/MPa | A/％ |
| 1-1 | 4 | 1090 | 1427 | 14 |
| 1-2 | 4 | 1100 | 1435 | 17 |
| 2-1 | 6 | 1080 | 1370 | 17 |
| 2-2 | 6 | 1078 | 1339 | 19 |
| 3-1 | 8 | 1070 | 1375 | 18 |
| 3-2 | 8 | 1080 | 1380 | 18.5 |
| 4-1 | 10 | 1053 | 1375 | 18 |
| 4-2 | 10 | 1062 | 1386 | 18.5 |
A comparative experiment was conducted on the HB 450-grade high abrasion steel sheet produced in this example and a conventional NM450 steel sheet on an MLS-225 type wet sand rubber wheel type abrasion tester at an applied pressure of 70N, a grinding wheel revolution of 200r/min, a total number of revolutions of 2000r and a test time of 10 minutes, the results of which are shown in Table 7.
TABLE 7 abrasion resistance comparison
| Comparative example/example | Abrasion loss DeltaM/g | Comparison of abrasion resistance |
| Normal NM450 | 0.0432 | 1 |
| 1-1 | 0.0302 | 1.43 |
| 1-2 | 0.0304 | 1.42 |
| 2-1 | 0.0309 | 1.40 |
| 2-2 | 0.0313 | 1.38 |
| 3-1 | 0.0318 | 1.36 |
| 3-2 | 0.0320 | 1.35 |
| 4-1 | 0.0327 | 1.32 |
| 4-2 | 0.0332 | 1.30 |
In the embodiment, the wear resistance of the produced steel plate is more than 1.3 times of that of the common wear-resistant steel plate in the comparative example.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.
Claims (4)
1. An HB450 grade high abrasion steel sheet, characterized in that, the chemical composition of the steel sheet is as follows by weight percent: c: 0.18% -0.22%, Si: 0.10-0.30%, Mn: 1.0-1.5%, Cr 0.20-0.40%, B: 0.005-0.010%, Ti: 0.03% -0.06%, Ti/B is more than or equal to 3.0, Als: 0.015% -0.045%; the balance of Fe and inevitable impurities; impurity element control in steel: p is less than or equal to 0.015 percent, S is less than or equal to 0.003 percent, N is less than or equal to 0.0040 percent, H is less than or equal to 0.00015 percent, and O is less than or equal to 0.0015 percent.
2. The HB450 grade high abrasion steel sheet as claimed in claim 1, wherein the thickness of the steel sheet is 4 to 10 mm.
3. An HB450 grade high abrasion steel sheet as claimed in claim 1, wherein said steel sheet has a surface hardness of more than HB420 and a flatness of 5mm/m or less.
4. The method for producing the HB450 grade high abrasion steel sheet as claimed in any one of claims 1 to 3, wherein the production process comprises: molten iron pretreatment, converter smelting, refining, slab continuous casting, rolling and heat treatment; wherein:
1) converter smelting and refining processes;
converter smelting is carried out through top blowing or top-bottom combined blowing, then refining treatment and microalloying are carried out, and the content of impurities in steel is controlled within a limited range; the RH vacuum circulation time is more than or equal to 15min during refining;
2) a slab continuous casting process;
electromagnetic stirring or soft pressing is adopted, intercooling is adopted in a secondary cooling area, and the drawing speed of the continuous casting billet is controlled to be 1.0-1.5 m/min;
3) the rolling process comprises the following steps:
the thickness of the casting blank is 135-250 mm, the heating temperature before rolling is 1150-1200 ℃, and the heating and heat preservation time is controlled to be 1.0-1.5 min/mm; two-stage controlled rolling is adopted, the initial rolling temperature of rough rolling is more than or equal to 1050 ℃, and the final rolling temperature of rough rolling is more than or equal to 980 ℃; the single-pass reduction rate of rough rolling is not lower than 15%; the finish rolling temperature is 970-1040 ℃, the reduction rate of a single stand of the finish continuous rolling is not lower than 10%, the rolling speed is 5-15 m/s, and the finish rolling temperature is 850-900 ℃; taking out the steel from the finish rolling, immediately carrying out laminar cooling at a cooling speed of more than or equal to 15 ℃/s, coiling at 550-600 ℃, and air-cooling to room temperature;
4) the heat treatment process comprises the following steps:
adopting a heat treatment mode of quenching and tempering; quenching is carried out in a continuous quenching machine in two stages, wherein the first-stage quenching adopts heating at 850-950 ℃ for total heating time of 1.5-2.0 min/mm, the second-stage quenching adopts cooling heating at 730-830 ℃ for total cooling time of 1-2 min/mm; the speed of the discharging roller way of the continuous quenching machine is more than or equal to 30 m/min; the tempering temperature is 150-250 ℃, and the tempering heat preservation time is 4-8 min/mm.
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| CN114934156A (en) * | 2022-03-30 | 2022-08-23 | 鞍钢股份有限公司 | Production method of high-strength and high-toughness hot continuous rolling thin steel plate with Brinell hardness of 450HBW |
| CN115074628A (en) * | 2022-06-30 | 2022-09-20 | 鞍钢股份有限公司 | HB 450-grade high-wear-resistance cold-bending steel plate and production method thereof |
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