CN112030580A - High-fastness elastic suede foaming slurry and preparation method thereof - Google Patents
High-fastness elastic suede foaming slurry and preparation method thereof Download PDFInfo
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Abstract
The application relates to high-fastness elastic suede foaming slurry and a preparation method thereof, wherein the high-fastness elastic suede foaming slurry comprises the following components in parts by mass: 50-75 parts of ethylene-vinyl acetate copolymer emulsion; 8-12 parts of a microsphere foaming agent; 2-6 parts of fatty alcohol-polyoxyethylene ether; 0.02-0.11 part of preservative; 3-8 parts of odorless kerosene; the preservative is a compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone; the solid content of the ethylene-vinyl acetate copolymer emulsion is 52-55%. The application has the effect of making the three-dimensional stamp of foaming be difficult for rubbing off the look.
Description
Technical Field
The application relates to the technical field of printing and dyeing, in particular to high-fastness elastic suede foaming slurry and a preparation method thereof.
Background
At present, with the development of society, in order to meet the pursuit of people for clothing personalization, people usually print patterns with various colors on the appearance of clothing, so that the style of clothing is varied, and the requirements of people with different hobbies are met.
The foaming three-dimensional printing shows the artistic effect of embossment on the fabric, and generates strong contrast under the irradiation of light, so that the real and striking three-dimensional sense is formed on the vision of people, and the fabric has better decoration.
Aiming at the related technologies, the inventor thinks that the dye and the foaming three-dimensional printing are easy to rub and fade in the washing process of the clothes due to the fact that the foaming three-dimensional printing protrudes out of the surface of the clothes, and the beauty of the clothes is seriously affected in the past.
Disclosure of Invention
In order to solve the problem that foamed three-dimensional printing is easy to rub and fade, the application provides high-fastness elastic suede foaming slurry and a preparation method thereof.
In a first aspect, the application provides a high-fastness elastic suede foaming slurry, which adopts the following technical scheme:
the high-fastness elastic suede foaming slurry comprises the following components in parts by mass:
50-75 parts of ethylene-vinyl acetate copolymer emulsion;
8-12 parts of a microsphere foaming agent;
2-6 parts of fatty alcohol-polyoxyethylene ether;
0.02-0.11 part of preservative;
3-8 parts of odorless kerosene;
the preservative is a compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone;
the solid content of the ethylene-vinyl acetate copolymer emulsion is 52-55%.
Preferably, the composition comprises the following components in parts by mass:
55-65 parts of ethylene-vinyl acetate copolymer emulsion;
9-11 parts of a microsphere foaming agent;
3-5 parts of fatty alcohol-polyoxyethylene ether;
0.02-0.09 part of preservative;
4-6 parts of odorless kerosene;
the preservative is a compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone;
the solid content of the ethylene-vinyl acetate copolymer emulsion is 52-55%.
By adopting the technical scheme, the ethylene-vinyl acetate copolymer emulsion is selected as the main material, has no special smell, is safe and nontoxic, is not easy to stimulate the human body, has better flexibility, higher melt flow rate and better processability, meets the requirements of safety and environmental protection, and is suitable to be used as the base material of the foaming material;
by adding the microsphere foaming agent, patterns formed by printing and dyeing of the product have a microporous structure, and the appearance of the product is relatively flat, so that the product printed and dyed on the fabric has certain elasticity, the product foamed three-dimensional printing has suede handfeel, the handfeel of the product is relatively good, the product foamed three-dimensional printing also has relatively obvious three-dimensional sense, and the decoration of clothes is improved;
by adding the fatty alcohol-polyoxyethylene ether, the specific surface area of the mixed resin and powder can be reduced by the fatty alcohol-polyoxyethylene ether, so that the surface tension of the foaming slurry is reduced, the contact area of a glue film of the foaming slurry and fibers is increased, the adhesive force of the foaming slurry and a fabric is increased, the permeability is good, the fatty alcohol-polyoxyethylene ether also has good emulsifying property, the stability of the foaming slurry can be effectively increased, and the emulsifying effect of the foaming slurry is good;
1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone can rapidly and irreversibly inhibit the growth of microorganisms after contacting with the microorganisms, thereby causing the death of the microorganisms, having stronger sterilization effect and ensuring that the foaming slurry is not easy to deteriorate;
by adding the odorless kerosene, the odorless kerosene usually volatilizes at about 100 ℃, volatilizes completely when printing and drying are carried out, is not easy to remain on the surface of the fabric, has low aromatic hydrocarbon content and no pungent smell, is environment-friendly, can improve hand feeling to a certain extent, and can also help to improve washing color fastness;
by adding the interaction of the 1, 2-benzisothiazole-3-ketone and the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone with the odorless kerosene, the soaping-resistant color fastness and the rubbing color fastness of the foaming three-dimensional printing are further improved, so that the color of the foaming three-dimensional printing is not easy to fade during the washing process of the fabric, and the foaming three-dimensional printing is favorable for keeping a relatively complete state for a long time.
Preferably, the preservative comprises the following components in parts by mass:
0.01-0.05 part of 1, 2-benzisothiazole-3-ketone;
0.01-0.06 part of 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone.
Through adopting above-mentioned technical scheme, cooperate with specific proportion through each component for the sterilization effect preferred makes the effect preferred that improves the soaping-resistant colour fastness and the friction colour fastness of three-dimensional stamp of foaming simultaneously.
Preferably, the high-fastness elastic suede foaming slurry further comprises the following components in parts by mass:
and 2-4 parts of a humectant.
By adopting the technical scheme, the wetting agent is added, so that the wetting degree of the foaming slurry is improved, and the printing and dyeing of the foaming slurry on the fabric are softer and smoother.
Preferably, the humectant is one or more of glycerin, propylene glycol, butanediol, polyethylene glycol and urea.
By adopting the technical scheme, one or more of glycerol, propylene glycol, butanediol, polyethylene glycol and urea are added, and the glycerol, the propylene glycol, the butanediol, the polyethylene glycol and the urea have better moisturizing performance, so that the moisturizing and lubricating effects of the foaming slurry are better, and the printed and dyed patterns are smoother.
Preferably, the high-fastness elastic suede foaming slurry further comprises the following components in parts by mass:
12-20 parts of a filling agent.
Through adopting above-mentioned technical scheme, through adding the filler, the filler price is comparatively cheap, can effectively reduce the cost of product, and the filler has certain reinforcement for the intensity of product is preferred.
Preferably, the filler is one or more of ground calcium carbonate, calcium sulfate and calcium chloride.
By adopting the technical scheme, the filling agent is one or more of heavy calcium carbonate, calcium sulfate and calcium chloride which are compounded, and the heavy calcium carbonate, the calcium sulfate, the calcium chloride and the ethylene-vinyl acetate copolymer emulsion have better compatibility, low price and better reinforcing effect, and have less influence on foaming after being matched with use, so that the product has better overall effect and lower cost.
Preferably, the high-fastness elastic suede foaming slurry further comprises the following components in parts by mass:
0.4-0.6 part of thickening agent.
By adopting the technical scheme, the thickening agent is added, so that the consistency of the product is increased, the flowability of the product is reduced, the generated foaming slurry is not easy to sag and splash, the shape of the product foaming three-dimensional printing is favorably controlled, and the foaming three-dimensional printing is more exquisite.
In a second aspect, the application provides a preparation method of high-fastness elastic suede foaming slurry, which adopts the following technical scheme:
a preparation method of high-fastness elastic suede foaming slurry comprises the following steps:
step 1), adding 1, 2-benzisothiazole-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol polyoxyethylene ether and tasteless kerosene while stirring the ethylene-vinyl acetate copolymer emulsion, stirring for 20-40min, and uniformly mixing to obtain a first mixture;
and 2) adding a microsphere foaming agent into the first mixture, stirring for 30-60min, and uniformly mixing to obtain the high-fastness elastic suede foaming slurry.
By adopting the technical scheme, 1, 2-benzisothiazole-3-ketone, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol polyoxyethylene ether and odorless kerosene are added while the ethylene-vinyl acetate copolymer emulsion is stirred, so that the 1, 2-benzisothiazole-3-ketone, the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, the fatty alcohol polyoxyethylene ether and the odorless kerosene are uniformly dispersed in the ethylene-vinyl acetate copolymer emulsion, and the mixing effect of the components is better;
the microsphere foaming agent is added into the first mixture and is uniformly mixed, and the compatibility of the microsphere foaming agent and the ethylene-vinyl acetate copolymer emulsion is better, so that the dispersion effect of the microsphere foaming agent in the first mixture is better, and the distribution of foaming micropores of the foaming slurry is more uniform.
Preferably, in the step 1), acrylic acid and glycerol are also added into the ethylene-vinyl acetate copolymer emulsion, and the mixture is uniformly stirred to obtain a first mixture; in the step 2), ground limestone, calcium sulfate and calcium chloride are added into the first mixture and are uniformly stirred to obtain the high-fastness elastic suede foaming slurry.
By adopting the technical scheme, the acrylic acid and the glycerol are added into the ethylene-vinyl acetate copolymer emulsion, so that the acrylic acid, the glycerol and the ethylene-vinyl acetate copolymer emulsion are fully stirred, and the dispersion effect of each component in the ethylene-vinyl acetate copolymer emulsion is better;
by adding the ground calcium carbonate, the calcium sulfate and the calcium chloride into the first mixture, the ground calcium carbonate, the calcium sulfate and the calcium chloride have better compatibility with the ethylene-vinyl acetate copolymer emulsion, so that the ground calcium carbonate, the calcium sulfate and the calcium chloride are quickly dispersed in the ethylene-vinyl acetate copolymer emulsion, and the ground calcium carbonate, the calcium sulfate and the calcium chloride are uniformly dispersed in the first mixture.
In summary, the present application includes at least one of the following beneficial technical effects:
1. by adding the interaction of the 1, 2-benzisothiazole-3-ketone and the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone with the odorless kerosene, the washing color fastness and the tensile strength of the foamed three-dimensional printing are further improved, the foamed three-dimensional printing is not easy to wear, and the dye is not easy to escape from the foamed three-dimensional printing, so that the foamed three-dimensional printing is favorable for keeping a relatively complete state for a long time.
2. The humectant is added, so that the wettability of the foaming slurry is improved, and the printing and dyeing of the foaming slurry on the fabric are softer and smoother.
3. By adding the thickening agent, the shape of the foamed three-dimensional printing of the product can be controlled, so that the foamed three-dimensional printing is more exquisite.
Drawings
Fig. 1 is a schematic flow chart of a preparation method of the high-fastness elastic suede foaming slurry.
Detailed Description
The present application is described in further detail below with reference to fig. 1.
The information on the source of each raw material component in the following examples and comparative examples is shown in Table 1
TABLE 1
Examples 1 to 4
The high-fastness elastic suede foaming slurry comprises the following components:
ethylene-vinyl acetate copolymer emulsion, a microsphere foaming agent, fatty alcohol-polyoxyethylene ether, odorless kerosene and a preservative.
The preservative is the compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone.
The ethylene-vinyl acetate copolymer emulsion had a solids content of 54%.
In examples 1-4, the amounts (in Kg) of each component added are specified in Table 2
TABLE 2
Referring to fig. 1, in examples 1 to 4, the preparation method of the high-fastness elastic suede foaming slurry comprises the following specific steps:
step 1), adding the ethylene-vinyl acetate copolymer emulsion into a stirring kettle at 900r/min, adding fatty alcohol-polyoxyethylene ether, odorless kerosene, 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone while stirring, continuously stirring for 30min, and uniformly stirring to obtain a first mixture.
And 2) adding a microsphere foaming agent into the first mixture, stirring at 900r/min for 50min, and uniformly stirring to obtain the high-fastness elastic suede foaming slurry.
Example 5
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the ethylene-vinyl acetate copolymer emulsion had a solids content of 52%.
The preparation method of the high-fastness elastic suede foaming slurry comprises the following steps:
step 1), adding 1, 2-benzisothiazole-3-ketone, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol-polyoxyethylene ether and odorless kerosene while stirring, and continuously stirring for 20 min.
And step 2), adding the microsphere foaming agent, and stirring for 30 min.
Example 6
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the ethylene-vinyl acetate copolymer emulsion had a solids content of 55%.
The preparation method of the high-fastness elastic suede foaming slurry comprises the following steps:
step 1), adding 1, 2-benzisothiazole-3-ketone, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol-polyoxyethylene ether and odorless kerosene while stirring, and continuously stirring for 40 min.
And step 2), adding the microsphere foaming agent, and stirring for 60 min.
Examples 7 to 10
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the high-fastness elastic suede foaming slurry also comprises the following components:
a humectant.
The humectant is prepared by compounding glycerol, propylene glycol, butanediol, polyethylene glycol and urea.
In examples 7-10, the amounts (in Kg) of each component added are specified in Table 3
TABLE 3
Adding glycerol, propylene glycol, butanediol, polyethylene glycol and urea in the step 1) together with 1, 2-benzisothiazol-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol-polyoxyethylene ether, odorless kerosene and a microsphere foaming agent into a stirring kettle, and uniformly stirring to obtain a first mixture.
Examples 11 to 14
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the high-fastness elastic suede foaming slurry also comprises the following components:
a filler.
The filler is one or more of ground calcium carbonate, calcium chloride and calcium sulfate.
In examples 11 to 14, the amounts (in Kg) of the respective components added are specified in Table 4
TABLE 4
Adding the ground calcium carbonate, the calcium chloride and the calcium sulfate into the first mixture together with the microsphere foaming powder in the step 2), and uniformly stirring to obtain the high-fastness elastic suede foaming slurry.
Examples 15 to 18
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the high-fastness elastic suede foaming slurry also comprises the following components:
a thickening agent.
The thickener is one or more of acrylic acid, polyurethane, polyvinyl alcohol, sodium carboxymethylcellulose and polyvinylpyrrolidone.
In examples 15 to 18, the amounts (in Kg) of the components added are specified in Table 5
TABLE 5
Adding acrylic acid, polyurethane, polyvinyl alcohol, sodium carboxymethylcellulose and polyvinylpyrrolidone into the microsphere foaming agent in the step 2), stirring for 30min, adding the mixture, stirring at 900r/min for 10min, and stirring uniformly to obtain the high-fastness elastic foaming slurry.
Examples 19 to 22
The embodiment discloses high-fastness elastic suede foaming slurry:
the only difference from example 2 is:
the high-fastness elastic suede foaming slurry also comprises the following components:
humectant, filler, thickener.
The humectant is glycerol, propylene glycol, butanediol, polyethylene glycol, and urea;
the filler is the compound of heavy calcium carbonate, calcium chloride and calcium sulfate;
the thickener is one or more of acrylic acid, polyurethane, polyvinyl alcohol, sodium carboxymethylcellulose and polyvinylpyrrolidone.
In examples 19 to 22, the amounts (in Kg) of the respective components added are specified in Table 6
TABLE 6
Adding glycerol, propylene glycol, butanediol, polyethylene glycol and urea in the step 1) together with 1, 2-benzisothiazol-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol-polyoxyethylene ether and odorless kerosene into a stirring kettle, and uniformly stirring to obtain a first mixture.
Adding ground calcium carbonate, calcium chloride and calcium sulfate into the first mixture together with the microsphere foaming powder in the step 2), uniformly stirring, then adding acrylic acid, polyurethane, polyvinyl alcohol, sodium carboxymethylcellulose and polyvinylpyrrolidone, stirring at 900r/min for 10min, uniformly stirring, and obtaining the high-fastness elastic suede foaming slurry.
Comparative example 1
The only difference from example 2 is:
in step 1), odorless kerosene, 1, 2-benzisothiazolin-3-one and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone are replaced with equal amount of water.
Comparative example 2
The only difference from example 2 is:
in step 1), 1, 2-benzisothiazolin-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone is replaced with an equal amount of water.
Comparative example 3
The only difference from example 2 is:
in the step 1), 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone and tasteless kerosene are replaced by equal amount of water.
Comparative example 4
The only difference from example 2 is:
in the step 1), 1, 2-benzisothiazolin-3-one and tasteless kerosene are replaced by equal amount of water.
Comparative example 5
The only difference from example 2 is:
in step 1), the odorless kerosene is replaced with an equal amount of water.
Comparative example 6
The only difference from example 2 is:
in step 1), 1, 2-benzisothiazolin-3-one is replaced with an equal amount of water.
Comparative example 7
The only difference from example 2 is:
in step 1), 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone is replaced with an equal amount of water.
Experiment 1
The viscosities of the high-fastness elastic suede foaming slurries prepared in the examples and comparative examples were measured by means of a rotary viscometer model NDJ-1.
Experiment 2
The velvet feeling grades of the patterns printed by the high-fastness elastic velvet foaming paste prepared in the examples and the comparative examples are detected by the following detection method:
respectively adopting the high-fastness elastic suede foaming slurry prepared in each example and each comparative example to prepare a sample;
when preparing a sample, firstly, ironing a white fabric without velvet feeling and paving the white fabric on a printing table, selecting a 800-mesh full-area screen printing plate, scraping and printing the white fabric with two knives, drying the white fabric with hot air, and baking the white fabric at a high temperature of 150 ℃ for 3 minutes;
the samples prepared in the examples and the comparative examples were manually subjected to contact-receiving comparison with white fabrics which were not velvet and were printed with printing pastes, 5 persons in each group were averaged, and the rating was obtained to be 5 grades at the highest.
Experiment 3
The tensile shear strength (MPa) of the high-fastness elastic suede foam pastes prepared in the examples and comparative examples was measured according to GB/T7124-2008 "determination of adhesive tensile shear strength" (rigid material to rigid material).
Experiment 4
The SW8A type color fastness to washing tester is adopted to test the color fastness to washing of the high-fastness elastic suede foaming pulp prepared in each example and each comparative example according to GB/T3921 and 2008 textile color fastness to washing.
Experiment 5
The rubbing color fastness of the high-fastness elastic suede foaming slurry prepared in each example and each comparative example is tested by a Y571W type textile rubbing color fastness instrument according to GB3920-1983 method for testing rubbing color fastness of textiles.
The assay data for experiments 1-5 are detailed in Table 7
TABLE 7
According to the comparison of the data of comparative example 2 and comparative example 1 in table 7, the tensile strength is improved to a certain extent by adding the odorless kerosene, and it is proved that the tensile resistance of the three-dimensional foam printing can be improved to a greater extent by adding the odorless kerosene, so that the three-dimensional foam printing is not easy to deform, and the pile feeling grade, the soaping color fastness, the wet friction color fastness and the dry friction color fastness of the three-dimensional foam printing are improved to a certain extent, so that the pile feeling and the color fixing effect of the three-dimensional foam printing are better, and the fabric is favorable for keeping attractive appearance.
According to the comparison of the data of comparative example 3 and comparative example 1 in Table 7, the tensile strength and soaping fastness, wet rubbing fastness and dry rubbing fastness of the foamed three-dimensional printing are not obviously changed by adding the 1, 2-benzisothiazolin-3-one, and the tensile resistance and printing effect of the foamed three-dimensional printing are not greatly influenced after adding the 1, 2-benzisothiazolin-3-one.
According to the comparison of the data of comparative example 4 and comparative example 1 in Table 7, the tensile strength and the fluffy grade, the soaping color fastness, the wet rubbing color fastness and the dry rubbing color fastness are not obviously changed by adding the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, and the tensile strength and the printing effect of the foaming three-dimensional printing after adding the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone are not greatly influenced.
According to the comparison of the data of comparative example 5 with comparative examples 3 and 4 in Table 7, it can be seen that the tensile strength and pile-feeling grade, soaping fastness, wet rubbing fastness and dry rubbing fastness were not significantly changed by using 1, 2-benzisothiazolin-3-one and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone in combination, and the tensile strength and printing effect of foamed three-dimensional printing were not greatly affected by using 1, 2-benzisothiazolin-3-one and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone in combination.
According to the comparison of the data of comparative example 6 and comparative example 2 in table 7, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone is added to match with odorless kerosene, so that the tensile strength and the washing fastness of the foamed three-dimensional printing are improved to a certain extent, and the 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone can improve the tensile strength, the soaping fastness, the wet rubbing fastness and the dry rubbing fastness of the foamed three-dimensional printing to a certain extent, so that the color fixing effect of the foamed three-dimensional printing is better, and the deformation resistance of the foamed three-dimensional printing is improved.
According to the comparison of the data of comparative example 7 and comparative example 2 in table 7, the tensile strength and soaping resistance, wet rubbing fastness and dry rubbing fastness of the foamed three-dimensional printing are improved to a certain extent by adding 1, 2-benzisothiazolin-3-one to match with odorless kerosene, and the 1, 2-benzisothiazolin-3-one is proved to be capable of improving the tensile strength and the washing resistance fastness of the foamed three-dimensional printing to a certain extent, so that the color fixing effect of the foamed three-dimensional printing is improved, and the deformation resistance of the foamed three-dimensional printing is improved.
According to the comparison of the data of example 2, comparative example 6 and comparative example 7 in table 7, the tensile strength and the soaping fastness, the wet rubbing fastness and the dry rubbing fastness of the foamed three-dimensional printing are further improved by adding 1, 2-benzisothiazolin-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone and odorless kerosene together, and the 1, 2-benzisothiazolin-3-one and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone have better synergistic effect on the improvement of the color fixing effect and the tensile resistance of the odorless kerosene, so that the whole color fixing effect is better.
As can be seen from comparison of the data of examples 7 to 10 with example 2 in Table 7, the pile level of the foamed three-dimensional prints was improved to some extent by the addition of the humectant, demonstrating that the hand feeling was improved to some extent by the addition of the humectant.
From the comparison of the data of examples 11 to 14 and example 2 in table 7, it can be seen that the tensile strength of the foamed three-dimensional print is improved to some extent by adding the filler, demonstrating that the filler has a certain reinforcing effect on the foamed three-dimensional print.
According to the comparison of the data of examples 15 to 18 and example 2 in table 7, the viscosity of the foaming paste is increased by adding the thickener, so that the fluidity of the foaming paste is reduced, the printing and dyeing are facilitated, the tensile strength of the foamed three-dimensional printing is not greatly changed from the soaping color fastness, the wet rubbing color fastness and the dry rubbing color fastness, and the thickener has small influence on the rubbing color fastness of the foamed three-dimensional printing.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.
Claims (10)
1. The high-fastness elastic suede foaming slurry is characterized in that: the paint comprises the following components in parts by mass:
50-75 parts of ethylene-vinyl acetate copolymer emulsion;
8-12 parts of a microsphere foaming agent;
2-6 parts of fatty alcohol-polyoxyethylene ether;
0.02-0.11 part of preservative;
3-8 parts of odorless kerosene;
the preservative is a compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone;
the solid content of the ethylene-vinyl acetate copolymer emulsion is 52-55%.
2. The high-fastness elastic suede foaming paste according to claim 1, characterized in that: the paint comprises the following components in parts by mass:
55-65 parts of ethylene-vinyl acetate copolymer emulsion;
9-11 parts of a microsphere foaming agent;
3-5 parts of fatty alcohol-polyoxyethylene ether;
0.02-0.09 part of preservative;
4-6 parts of odorless kerosene;
the preservative is a compound of 1, 2-benzisothiazole-3-ketone and 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone;
the solid content of the ethylene-vinyl acetate copolymer emulsion is 52-55%.
3. The high-fastness elastic suede foaming paste according to claim 1, characterized in that: the preservative comprises the following components in parts by mass:
0.01-0.05 part of 1, 2-benzisothiazole-3-ketone;
0.01-0.06 part of 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone.
4. The high-fastness elastic suede foaming paste according to claim 1, characterized in that: the paint also comprises the following components in parts by mass:
and 2-4 parts of a humectant.
5. The high-fastness elastic suede foaming paste according to claim 4, characterized in that: the humectant comprises one or more of glycerin, propylene glycol, butanediol, polyethylene glycol and urea.
6. The high-fastness elastic suede foaming paste according to claim 1, characterized in that: the high-fastness elastic suede foaming slurry also comprises the following components in parts by mass:
12-20 parts of a filling agent.
7. The high-fastness elastic suede foaming paste according to claim 6, characterized in that: the filler is one or more of ground calcium carbonate, calcium sulfate and calcium chloride.
8. The high-fastness elastic suede foaming paste according to claim 1, characterized in that: the high-fastness elastic suede foaming slurry also comprises the following components in parts by mass:
0.4-0.6 part of thickening agent.
9. The preparation method of the high-fastness elastic suede foaming paste according to claim 1, characterized by comprising the following steps: the method comprises the following steps:
step 1), adding 1, 2-benzisothiazole-3-one, 4, 5-dichloro-2-methyl-3 (2H) -isothiazolinone, fatty alcohol polyoxyethylene ether and tasteless kerosene while stirring the ethylene-vinyl acetate copolymer emulsion, stirring for 20-40min, and uniformly mixing to obtain a first mixture;
and 2) adding a microsphere foaming agent into the first mixture, stirring for 30-60min, and uniformly mixing to obtain the high-fastness elastic suede foaming slurry.
10. The high-fastness elastic suede foaming paste according to claim 9, characterized in that: in the step 1), acrylic acid and glycerol are also added into the ethylene-vinyl acetate copolymer emulsion, and the mixture is uniformly stirred to obtain a first mixture; in the step 2), ground limestone, calcium sulfate and calcium chloride are added into the first mixture and are uniformly stirred to obtain the high-fastness elastic suede foaming slurry.
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