CN112012039A - Energy-saving environment-friendly carton material - Google Patents

Energy-saving environment-friendly carton material Download PDF

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Publication number
CN112012039A
CN112012039A CN202010830561.XA CN202010830561A CN112012039A CN 112012039 A CN112012039 A CN 112012039A CN 202010830561 A CN202010830561 A CN 202010830561A CN 112012039 A CN112012039 A CN 112012039A
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CN
China
Prior art keywords
parts
energy
straw
environment
saving environment
Prior art date
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Pending
Application number
CN202010830561.XA
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Chinese (zh)
Inventor
张志军
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Jinshang Packaging Jiangsu Co ltd
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Jinshang Packaging Jiangsu Co ltd
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Priority to CN202010830561.XA priority Critical patent/CN112012039A/en
Publication of CN112012039A publication Critical patent/CN112012039A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14—Secondary fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/53—Polyethers; Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28—Colorants ; Pigments or opacifying agents

Abstract

The invention discloses an energy-saving environment-friendly carton material, relates to the technical field of cartons, and aims to solve the problems that a carton made of the existing carton material is poor in energy-saving environment-friendly performance, so that raw materials required by the carton are expensive, and the waste carton pollutes the environment seriously. The composition comprises the following components in parts by mass: 10-20 parts of straw, 20-30 parts of waste paper, 20-30 parts of wheat straw, 1-10 parts of pigment, 10-20 parts of polypropylene resin, 5-10 parts of titanium dioxide, 15-25 parts of polyaluminium chloride, 15-25 parts of polyglycolic acid, 10-15 parts of cellulose, 100 parts of deionized water, 1-6 parts of photoinitiator, 1-6 parts of antioxidant, 1-6 parts of antistatic agent, 1-6 parts of antibacterial agent and 1-6 parts of antacid, wherein the sum of the contents of the straw, the waste paper and the wheat straw is not more than 90 parts at most, the straw, the waste paper and the wheat straw need to be respectively pulped and then mixed and stirred to prepare paper pulp, the polypropylene resin needs to be modified by 0.25% of beta crystal form nucleating agent and then can be added for use, and modified beta crystal form polypropylene fiber is generated.

Description

Energy-saving environment-friendly carton material
Technical Field
The invention relates to the technical field of cartons, in particular to an energy-saving and environment-friendly carton material.
Background
The paper box is a most widely applied packaging product, and comprises a corrugated paper box, a single-layer carton box and the like with various specifications and models according to different materials, the special-shaped corrugated paper box is a packaging variety with the most form change in the current corrugated paper box packaging, goods in a supermarket are directly placed on a goods shelf and need to have a good product display function, and the influence of packaging printing wastes on the environment is mainly reflected in two processes of manufacturing and consumption. The manufacturing process refers to the waste generated in each production link, such as the pollution of waste water, waste residue and the like generated in the production of beverage packages; the consumption process refers to the waste which is discarded in nature and difficult to degrade after being used, such as plastic handbags which are convenient for people to use, and the influence of the packaging and printing waste on the environment is mainly reflected in two processes of manufacturing and consumption. The manufacturing process refers to the waste generated in each production link, such as the pollution of waste water, waste residue and the like generated in the production of beverage packages; the consumption process refers to the waste which is discarded in nature and difficult to degrade after being used, such as plastic handbags which are convenient for people to use.
The carton made of the existing carton material is poor in energy-saving and environment-friendly performance, so that raw materials required by the carton are expensive, and the waste carton pollutes the environment seriously, therefore, the existing requirements are not met, and the energy-saving and environment-friendly carton material is provided.
Disclosure of Invention
The invention aims to provide an energy-saving and environment-friendly carton material, and aims to solve the problems that the carton made of the existing carton material in the background art is poor in energy-saving and environment-friendly performance, so that raw materials required by the carton are expensive, and the waste carton pollutes the environment seriously.
In order to achieve the purpose, the invention provides the following technical scheme: an energy-saving environment-friendly carton material comprises the following components by mass: 10-20 parts of straw, 20-30 parts of waste paper, 20-30 parts of wheat straw, 1-10 parts of pigment, 10-20 parts of polypropylene resin, 5-10 parts of titanium dioxide, 15-25 parts of polyaluminium chloride, 15-25 parts of polyglycolic acid, 10-15 parts of cellulose, 100 parts of deionized water, 1-6 parts of photoinitiator, 1-6 parts of antioxidant, 1-6 parts of antistatic agent, 1-6 parts of antibacterial agent and 1-6 parts of antacid.
Preferably, the sum of the contents of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Preferably, the polypropylene resin can be added after being modified by 0.25% of beta-crystal nucleating agent, and the modified beta-crystal polypropylene fiber is generated, so that the molecular weight and the distribution of polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Preferably, the titanium dioxide is obtained by reacting ground ilmenite and sulfuric acid under the conditions of continuously introducing air and stirring and hydrolyzing titanium liquid.
Preferably, the polyaluminium chloride, when used, is present in a solid mass of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Preferably, the polyglycolic acid is a degradable polymer material in which a crystalline polyglycolic acid is dissolved in a strongly polar organic solvent such as hexafluoroisopropanol when used.
Preferably, when the deionized water is used, the impurities with relatively coarse particles are filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most preferably, the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Preferably, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Compared with the prior art, the invention has the beneficial effects that:
1. the waste materials of the straw, the waste paper and the wheat straw are used as the materials for producing the paper boxes, so that the cost for producing the paper boxes is effectively saved, the straw, the waste paper and the wheat straw are all the waste materials polluting the environment, most of the straw and the wheat straw are burnt by peasant households, the generated smoke causes the environmental pollution, the waste materials are used as the raw materials for producing the paper boxes and can also change the direction to play a role in protecting the environment, and the problems that the paper boxes made of the existing paper box materials are poor in energy-saving and environment-friendly performance, so that the raw materials required by the paper boxes are expensive, and the waste paper boxes seriously pollute the environment are solved.
2. The photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are added into the carton production raw materials, so that the overall structural strength and the weather resistance of the energy-saving and environment-friendly carton can be effectively improved, the photoinitiator is a substance which can absorb radiation energy and generate an active intermediate with the polymerization initiating capability through photochemical change after excitation, and the carton with waste gas can be degraded under the illumination condition, so that the environment-friendly concept is realized.
3. The polypropylene resin chemical fiber is light, the density of the polypropylene resin chemical fiber is 0.90-0.92g/cm3, the polypropylene resin chemical fiber has the advantages of high strength, good toughness, good chemical resistance and antimicrobial property, low price and the like, 60-80 parts by weight of homo-polypropylene, 20-40 parts by weight of ethylene-vinyl alcohol copolymer and 1-10 parts by weight of a reactant of compatilizer polypropylene maleic anhydride graft and the ethylene-vinyl alcohol copolymer are adopted, and a polypropylene composite material prepared by mixing at the temperature of 170-190 ℃ has high toughness, the impact strength of the polypropylene composite material is as high as 210J/m, the polypropylene composite material has high gas barrier property, and the water vapor permeation rate is close to 2000 g.mu m/(m 2.24 h), so that the overall structural strength and the service life of the energy-saving and environment-friendly carton are.
4. Polyaluminium chloride the solid product was prepared according to the following weight ratio of 1: 3 adding water to dissolve the mixture into liquid, and adding 10-30 times of clear water to dilute the mixture into the required concentration for use. The optimal pH value for adding is 3.5-5.0, and the optimal pH value is selected for adding, so that the maximum benefit of coagulation can be exerted. The dosage can be determined according to different turbidity degrees of raw water, the optimal dosage is generally 10-20kg per kiloton when the turbidity degree of the raw water is 500mg/L, the dosage is properly increased when the turbidity degree of the raw water is high, and the dosage can be properly reduced when the turbidity degree is low, so that micro-toxic substances and heavy metal ions can be effectively removed in the step of sizing for papermaking.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments.
Example 1
An energy-saving environment-friendly carton material comprises the following components by mass: 10 parts of straw, 20 parts of waste paper, 23 parts of wheat straw, 5 parts of pigment, 12 parts of polypropylene resin, 6 parts of titanium dioxide, 16 parts of polyaluminium chloride, 17 parts of polyglycolic acid, 12 parts of cellulose, 100 parts of deionized water, 1 part of photoinitiator, 1 part of antioxidant, 1 part of antistatic agent, 1 part of antibacterial agent and 1 part of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Example 2
An energy-saving environment-friendly carton material comprises the following components by mass: 19 parts of straw, 22 parts of waste paper, 23 parts of wheat straw, 3 parts of pigment, 12 parts of polypropylene resin, 7 parts of titanium dioxide, 17 parts of polyaluminium chloride, 18 parts of polyglycolic acid, 12 parts of cellulose, 100 parts of deionized water, 2 parts of photoinitiator, 2 parts of antioxidant, 2 parts of antistatic agent, 2 parts of antibacterial agent and 2 parts of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Example 3
An energy-saving environment-friendly carton material comprises the following components by mass: 18 parts of straw, 21 parts of waste paper, 25 parts of wheat straw, 2 parts of pigment, 14 parts of polypropylene resin, 8 parts of titanium dioxide, 17 parts of polyaluminum chloride, 18 parts of polyglycolic acid, 13 parts of cellulose, 100 parts of deionized water, 3 parts of photoinitiator, 3 parts of antioxidant, 3 parts of antistatic agent, 3 parts of antibacterial agent and 3 parts of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Example 4
An energy-saving environment-friendly carton material comprises the following components by mass: 13 parts of straw, 24 parts of waste paper, 25 parts of wheat straw, 6 parts of pigment, 13 parts of polypropylene resin, 7 parts of titanium dioxide, 23 parts of polyaluminium chloride, 21 parts of polyglycolic acid, 14 parts of cellulose, 100 parts of deionized water, 4 parts of photoinitiator, 4 parts of antioxidant, 4 parts of antistatic agent, 4 parts of antibacterial agent and 4 parts of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Example 5
An energy-saving environment-friendly carton material comprises the following components by mass: 18 parts of straw, 24 parts of waste paper, 25 parts of wheat straw, 7 parts of pigment, 14 parts of polypropylene resin, 8 parts of titanium dioxide, 22 parts of polyaluminium chloride, 17 parts of polyglycolic acid, 12 parts of cellulose, 100 parts of deionized water, 5 parts of photoinitiator, 5 parts of antioxidant, 5 parts of antistatic agent, 5 parts of antibacterial agent and 5 parts of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
Example 6
An energy-saving environment-friendly carton material comprises the following components by mass: 19 parts of straw, 29 parts of waste paper, 15 parts of wheat straw, 10 parts of pigment, 15 parts of polypropylene resin, 5 parts of titanium dioxide, 24 parts of polyaluminium chloride, 15 parts of polyglycolic acid, 11 parts of cellulose, 100 parts of deionized water, 6 parts of photoinitiator, 6 parts of antioxidant, 6 parts of antistatic agent, 6 parts of antibacterial agent and 6 parts of antacid.
Furthermore, the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then are mixed and stirred to prepare paper pulp.
Furthermore, the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and the modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of the polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
Furthermore, titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring, and hydrolyzing titanium liquid.
Further, the polyaluminium chloride is used as a solid of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
Further, polyglycolic acid is used by dissolving crystalline polyglycolic acid in a strongly polar organic solvent such as hexafluoroisopropanol, and polyglycolic acid is a degradable polymer material.
Furthermore, when the deionized water is used, the impurities with thicker particles are firstly filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and most of the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
Furthermore, the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (8)

1. The utility model provides an energy-concerving and environment-protective carton material which characterized in that: the composition comprises the following components in parts by mass: 10-20 parts of straw, 20-30 parts of waste paper, 20-30 parts of wheat straw, 1-10 parts of pigment, 10-20 parts of polypropylene resin, 5-10 parts of titanium dioxide, 15-25 parts of polyaluminium chloride, 15-25 parts of polyglycolic acid, 10-15 parts of cellulose, 100 parts of deionized water, 1-6 parts of photoinitiator, 1-6 parts of antioxidant, 1-6 parts of antistatic agent, 1-6 parts of antibacterial agent and 1-6 parts of antacid.
2. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: the total content of the straw, the waste paper and the wheat straw is not more than 90 parts at most, and the straw, the waste paper and the wheat straw need to be respectively pulped and then mixed and stirred to prepare paper pulp.
3. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: the polypropylene resin can be added after being modified by 0.25 percent of beta-crystal form nucleating agent, and modified beta-crystal form polypropylene fiber is generated, so that the molecular weight and the distribution of polypropylene are reduced, the spinnability of the polypropylene fiber is improved, and the impact resistance of the polypropylene fiber is greatly improved.
4. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: the titanium dioxide is obtained by reacting finely ground ilmenite with sulfuric acid under the conditions of continuously introducing air and stirring and hydrolyzing titanium liquid.
5. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: the polyaluminium chloride is used according to the following solid ratio of polyaluminium chloride: clear water =1:9-1:15, and the solution with the alumina content lower than 1% is easy to hydrolyze, which can reduce the using effect, and the concentration is too high and is not easy to be added uniformly.
6. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: when the polyglycolic acid is used, the crystalline polyglycolic acid is dissolved by a strong polar organic solvent such as hexafluoroisopropanol and the like, and the polyglycolic acid is a degradable high molecular material.
7. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: when the deionized water is used, the impurities with thicker particles are filtered by quartz sand, then the deionized water passes through a reverse osmosis membrane under high pressure, and finally the deionized water is subjected to ultraviolet sterilization to remove microorganisms in the water.
8. The energy-saving environment-friendly carton material as claimed in claim 1, wherein: the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are auxiliary materials required for producing the energy-saving and environment-friendly carton, and the components of the photoinitiator, the antioxidant, the antistatic agent, the antibacterial agent and the antacid are required to be consistent.
CN202010830561.XA 2020-08-18 2020-08-18 Energy-saving environment-friendly carton material Pending CN112012039A (en)

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CN101676326A (en) * 2008-09-19 2010-03-24 绵阳长鑫新材料发展有限公司 High-performance PS and PP alloy novel synthetic paper material
CN103865157A (en) * 2014-03-31 2014-06-18 宋旭 Water-absorbable composite environment-friendly stone paper and preparation method thereof
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CN109235117A (en) * 2018-09-28 2019-01-18 锦上包装江苏有限公司 A kind of recyclable carton material
CN110952373A (en) * 2019-11-26 2020-04-03 陈良地 High-strength ultrathin composite corrugated paper and preparation method thereof
JP2020056131A (en) * 2018-10-02 2020-04-09 大王製紙株式会社 Coated paper for packaging container and packaging container

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101676326A (en) * 2008-09-19 2010-03-24 绵阳长鑫新材料发展有限公司 High-performance PS and PP alloy novel synthetic paper material
CN101633761A (en) * 2009-08-27 2010-01-27 洛阳石化聚丙烯有限责任公司 Isolating polypropylene composite material and preparation method thereof
JP2015163688A (en) * 2014-01-31 2015-09-10 ユニチカ株式会社 Anchor coat agent for polypropylene resin extrusion lamination, packaging material and production method thereof
CN103865157A (en) * 2014-03-31 2014-06-18 宋旭 Water-absorbable composite environment-friendly stone paper and preparation method thereof
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