CN112006034A - Plant growth regulator containing prohexadione calcium and uniconazole and application thereof - Google Patents
Plant growth regulator containing prohexadione calcium and uniconazole and application thereof Download PDFInfo
- Publication number
- CN112006034A CN112006034A CN202010928849.0A CN202010928849A CN112006034A CN 112006034 A CN112006034 A CN 112006034A CN 202010928849 A CN202010928849 A CN 202010928849A CN 112006034 A CN112006034 A CN 112006034A
- Authority
- CN
- China
- Prior art keywords
- agent
- uniconazole
- calcium
- plant growth
- growth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 title claims abstract description 46
- 239000005648 plant growth regulator Substances 0.000 title claims abstract description 44
- NLKUPINTOLSSLD-UHFFFAOYSA-L calcium;4-(1-oxidopropylidene)-3,5-dioxocyclohexane-1-carboxylate Chemical compound [Ca+2].CCC([O-])=C1C(=O)CC(C([O-])=O)CC1=O NLKUPINTOLSSLD-UHFFFAOYSA-L 0.000 title claims abstract description 43
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 54
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 36
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- 239000005869 Pyraclostrobin Substances 0.000 claims abstract description 17
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims abstract description 16
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims abstract description 16
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- 239000004062 cytokinin Substances 0.000 claims description 11
- UQHKFADEQIVWID-UHFFFAOYSA-N cytokinin Natural products C1=NC=2C(NCC=C(CO)C)=NC=NC=2N1C1CC(O)C(CO)O1 UQHKFADEQIVWID-UHFFFAOYSA-N 0.000 claims description 11
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- IXVMHGVQKLDRKH-KNBKMWSGSA-N brassinolide Chemical compound C1OC(=O)[C@H]2C[C@H](O)[C@H](O)C[C@]2(C)[C@H]2CC[C@]3(C)[C@@H]([C@H](C)[C@@H](O)[C@H](O)[C@@H](C)C(C)C)CC[C@H]3[C@@H]21 IXVMHGVQKLDRKH-KNBKMWSGSA-N 0.000 description 5
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- AXKBOWBNOCUNJL-UHFFFAOYSA-M sodium;2-nitrophenolate Chemical compound [Na+].[O-]C1=CC=CC=C1[N+]([O-])=O AXKBOWBNOCUNJL-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004577 thatch Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
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Abstract
Description
技术领域technical field
本发明涉及其植物生长调节剂技术领域,特别涉及其含有调环酸钙与烯效唑的植物生长调节剂及其应用。The invention relates to the technical field of plant growth regulators, in particular to the plant growth regulators containing prohexadione calcium and uniconazole and applications thereof.
背景技术Background technique
植物生长调节剂是人们在了解天然植物激素的结构和作用机制后,通过人工合成与植物激素具有类似生理和生物学效应的物质,在农业生产上使用,以有效调节作物的生育过程,达到稳产增产、改善品质、增强作物抗逆性等目的;与植物激素具有相似生理和生物学效应的物质,现已发现具有调控植物生长和发育功能物质有胺鲜酯(DA-6),氯吡脲,复硝酚钠,生长素、赤霉素、乙烯、细胞分裂素、脱落酸、油菜素内酯、水杨酸、茉莉酸、多效唑和多胺等,而作为植物生长调节剂被应用在农业生产中主要是前9大类。Plant growth regulators are substances that have physiological and biological effects similar to those of plant hormones through artificial synthesis after understanding the structure and mechanism of action of natural plant hormones, and are used in agricultural production to effectively regulate the growth process of crops and achieve stable production. For the purposes of increasing yield, improving quality, and enhancing crop stress resistance; substances with similar physiological and biological effects to plant hormones have been found to regulate plant growth and development. , Sodium nitrophenolate, auxin, gibberellin, ethylene, cytokinin, abscisic acid, brassinolide, salicylic acid, jasmonic acid, paclobutrazol and polyamine, etc., and are used as plant growth regulators in agriculture Production is mainly the first 9 categories.
专利号为CN201110166461.2公开了一种植物生长调节剂及其应用。该植物生长调节剂,其活性成分为调环酸钙和烯效唑。实验表明,烯效唑与调环酸钙混配具有明显的增效作用,达到理想的防倒伏效果,同时消除单用存在的副作用,大大降低有效成分的使用量,减少环境污染,以及明显降低农用成本,由上述专利可知,现有技术中,植物生长调节剂主要的调节方向是提高光合作用,增加叶片中叶绿素含量,从而促进植株生长,通过降低生长速率来延缓成熟期,达到抑制生长的目的,从而导致植株生长过程中光合作用速率高,但营养转化速率无法跟上光合作用的速率,导致植株生长不良率高,且抑制过程中植株呼吸消耗不变,营养积累效率降低,导致植株枯萎速率高。Patent No. CN201110166461.2 discloses a plant growth regulator and its application. The active ingredients of the plant growth regulator are prohexadione calcium and uniconazole. Experiments show that the mixing of uniconazole and procyclonic acid calcium has obvious synergistic effect, achieves the ideal anti-lodging effect, eliminates the side effects of single use, greatly reduces the use of active ingredients, reduces environmental pollution, and significantly reduces Agricultural costs, as can be seen from the above-mentioned patents, in the prior art, the main adjustment direction of plant growth regulators is to improve photosynthesis, increase the chlorophyll content in leaves, thereby promoting plant growth, and delaying the maturity period by reducing the growth rate to inhibit growth. Therefore, the rate of photosynthesis is high in the process of plant growth, but the rate of nutrient transformation cannot keep up with the rate of photosynthesis, resulting in a high rate of poor plant growth, and the respiration consumption of the plant remains unchanged during the inhibition process. high rate.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供含有调环酸钙与烯效唑的植物生长调节剂及其应用,不仅能够提高叶绿素含量,还能够促进线粒体呼吸将叶绿素光合作用的产物转化为植株的营养成分,提高植物新陈代谢速率,调节植物的营养生长,以解决上述背景技术中提出的问题。The object of the present invention is to provide a plant growth regulator containing procyclonic acid calcium and uniconazole and its application, which can not only improve the chlorophyll content, but also can promote mitochondrial respiration to convert the products of chlorophyll photosynthesis into nutrients of plants, improve plant growth Metabolic rate, regulating the vegetative growth of plants, to solve the problems raised in the background art above.
为实现上述目的,本发明提供如下技术方案:含有调环酸钙与烯效唑的植物生长调节剂,由以下质量百分比的组分构成:主剂:助剂=100:0~50,其中,所述主剂由以下质量百分比的组分构成:调环酸钙5~45%,烯效唑5~45%,乙烯10~18%,氧化磷2~12%,形态素10~18%,吡唑醚菌酯2~12%,生长剂2~10%,抑制剂2~10%,所述助剂由以下质量百分比的组分构成:湿润剂1~18,分散剂6~36%,消泡剂1~5%,粘接剂1~1.2%,崩解剂2~24%,载体10~60%;In order to achieve the above purpose, the present invention provides the following technical scheme: a plant growth regulator containing prohexadione calcium and uniconazole, which is composed of the following components by mass percentage: main agent: auxiliary agent=100:0~50, wherein, The main agent is composed of the following components by mass percentage: 5-45% of prohexadione calcium, 5-45% of dinoconazole, 10-18% of ethylene, 2-12% of phosphorus oxide, 10-18% of morphogen, Pyraclostrobin 2-12%, growth agent 2-10%, inhibitor 2-10%, the auxiliary agent is composed of the following components in mass percentage: wetting agent 1-18, dispersing agent 6-36%, 1-5% of defoamer, 1-1.2% of adhesive, 2-24% of disintegrant, 10-60% of carrier;
所述分散剂为木质素磺酸盐与选自烷基酚聚氧乙烯醚甲醛缩合物或脂肪醇聚氧乙烯醚硫酸盐的复合分散剂,二者的重量比为6:1;所述木质素磺酸盐为木质素磺酸钠或木质素磺酸钙。The dispersant is a lignosulfonate and a composite dispersant selected from alkylphenol polyoxyethylene ether formaldehyde condensate or fatty alcohol polyoxyethylene ether sulfate, and the weight ratio of the two is 6:1; The sulfonate is sodium lignosulfonate or calcium lignosulfonate.
进一步地,所述主剂由以下质量百分比的组分构成:调环酸钙45%,烯效唑5%,乙烯18%,氧化磷12%,形态素10%,吡唑醚菌酯2%,生长剂6%,抑制剂2%。Further, the main agent is composed of the following components by mass percentage: procyclonic acid calcium 45%, uniconazole 5%, ethylene 18%, phosphorus oxide 12%, morphogen 10%, pyraclostrobin 2% , growth agent 6%, inhibitor 2%.
进一步地,所述主剂由以下质量百分比的组分构成:调环酸钙35%,烯效唑15%,乙烯18%,氧化磷12%,形态素10%,吡唑醚菌酯2%,生长剂6%,抑制剂2%。Further, the main agent is composed of the following components by mass percentage: procyclonic acid calcium 35%, uniconazole 15%, ethylene 18%, phosphorus oxide 12%, morphogen 10%, pyraclostrobin 2% , growth agent 6%, inhibitor 2%.
进一步地,所述主剂由以下质量百分比的组分构成:调环酸钙15%,烯效唑35%,乙烯10%,氧化磷2%,形态素18%,吡唑醚菌酯12%,生长剂2%,抑制剂6%。Further, the main agent is composed of the following components by mass percentage: 15% of prohexadione calcium, 35% of uniconazole, 10% of ethylene, 2% of phosphorus oxide, 18% of morphogen, and 12% of pyraclostrobin , growth agent 2%, inhibitor 6%.
进一步地,所述主剂由以下质量百分比的组分构成:调环酸钙5%,烯效唑45%,乙烯10%,氧化磷2%,形态素18%,吡唑醚菌酯12%,生长剂2%,抑制剂6%。Further, the main agent is composed of the following components by mass percentage: 5% of prohexadione calcium, 45% of uniconazole, 10% of ethylene, 2% of phosphorus oxide, 18% of morphogen, and 12% of pyraclostrobin , growth agent 2%, inhibitor 6%.
进一步地,所述生长剂为生长素、细胞分裂素和生长刺激剂中的一种或多种。Further, the growth agent is one or more of auxin, cytokinin and growth stimulator.
进一步地,所述抑制剂为脱叶剂、抗生长素和生长阻滞剂中的一种或多种。Further, the inhibitor is one or more of defoliants, anti-growth hormones and growth retarders.
根据本发明的另一方面,提供含有调环酸钙与烯效唑的植物生长调节剂的应用,将含有调环酸钙与烯效唑的植物生长调节剂作为农药的应用。According to another aspect of the present invention, there is provided the application of a plant growth regulator containing prohexadione calcium and uniconazole as a pesticide.
与现有技术相比,本发明的有益效果是:本发明提出的含有调环酸钙与烯效唑的植物生长调节剂及其应用,调环酸钙促进叶绿素的生成,加速光合作用,氧化磷促进线粒体呼吸,加速营养转化,定量喷洒药剂的植株吸收该药剂后不仅能够提高叶绿素含量,还能够促进线粒体呼吸将叶绿素光合作用的产物转化为植株的营养成分,提高植物新陈代谢速率,调节植物的营养生长,施用后可壮秆、控旺、促根、抗倒、矮化,使茎叶保持浓绿,叶片挺立,还能提高植物的抗逆性,增强植株的抗病害、抗寒冷和抗旱的能力,在植株成熟后或者其果实成熟后,喷洒高浓度植物生长调节剂,其中,高浓度的调环酸钙、烯效唑和吡唑醚菌酯抑制线粒体呼吸,加速光合作用,进而抑制赤霉酸和形态素的合成,提高座果率,促进果实成熟。Compared with the prior art, the beneficial effects of the present invention are as follows: the plant growth regulator containing prohexadione calcium and uniconazole and application thereof proposed by the present invention, prohexadione calcium promotes the generation of chlorophyll, accelerates photosynthesis, and oxidizes Phosphorus promotes mitochondrial respiration and accelerates nutrient transformation. Plants that are sprayed quantitatively can not only increase chlorophyll content after absorbing the drug, but also promote mitochondrial respiration, convert the products of chlorophyll photosynthesis into plant nutrients, increase plant metabolic rate, and regulate plants. Vegetative growth, after application, it can strengthen the stalk, control prosperity, promote root, resist lodging and dwarf, keep the stem and leaves dark green, and keep the leaves erect. It can also improve the stress resistance of plants, and enhance the resistance of plants to disease, cold and drought After the plants are mature or their fruits are mature, spray high concentrations of plant growth regulators, among which, high concentrations of prohexadione, niconazole and pyraclostrobin inhibit mitochondrial respiration, accelerate photosynthesis, and then inhibit The synthesis of gibberellic acid and morphogens can improve fruit setting rate and promote fruit ripening.
附图说明Description of drawings
图1为本发明的含有调环酸钙与烯效唑的植物生长调节剂的调环酸钙结构图。Fig. 1 is the structure diagram of calcium prohexadione of the plant growth regulator containing prohexadione calcium and uniconazole of the present invention.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
实施例一Example 1
请参阅图1,含有调环酸钙与烯效唑的植物生长调节剂,由以下质量百分比的组分构成:主剂:助剂=100:0~50,其中,主剂由以下质量百分比的组分构成:调环酸钙45%,烯效唑5%,乙烯18%,氧化磷12%,形态素10%,吡唑醚菌酯2%,生长剂6%,抑制剂2%,助剂由以下质量百分比的组分构成:湿润剂10,分散剂20%,消泡剂2%,粘接剂1%,崩解剂7%,载体60%;乙烯通过乙烯释放剂释放形成,乙烯释放剂为ACC、硅长素(etacelasil)、乙烯利(ethephon)、乙二醛肟(glyoxime)中的一种或多种,在使用过程中,可以增加乙烯调节剂,乙烯调节剂为艾维激素(aviglycine)、1~甲基环丙烯(1~MCP)、调环酸(prohexadione)、调环酸钙(prohexadionecalcium)、抗倒酯(trinexapac),抗倒酯(trinexapac~ethyl)中的一种或两种。Please refer to Fig. 1, the plant growth regulator containing prohexadione calcium and uniconazole is composed of the following components by mass percentage: main agent: auxiliary agent=100:0~50, wherein, the main agent is composed of the following mass percentages Component composition: procyclonic acid calcium 45%, uniconazole 5%, ethylene 18%, phosphorus oxide 12%, morphogen 10%, pyraclostrobin 2%, growth agent 6%, inhibitor 2%, auxiliary The agent is composed of the following components by mass percentage: 10% of wetting agent, 20% of dispersant, 2% of defoamer, 1% of adhesive, 7% of disintegrant, and 60% of carrier; ethylene is formed by the release of ethylene release agent, ethylene The release agent is one or more of ACC, etacelasil, ethephon, and glyoxime. During use, an ethylene regulator can be added, and the ethylene regulator is Aiviy Hormone (aviglycine), 1-methylcyclopropene (1-MCP), one of prohexadione, prohexadionecalcium, trinexapac, trinexapac-ethyl species or both.
生长剂为生长素、细胞分裂素和生长刺激剂中的一种或多种;其中,生长素为4~CPA、2,4~D、2,4~DB、2,4~DEP、2,4~滴丙酸(dichlorprop)、2,4,5~涕丙酸(fenoprop)、IAA(吲哚~3~乙酸)、IBA、萘乙酰胺、α~萘乙酸、1~萘酚、萘氧基乙酸、环烷酸钾、环烷酸钠、2,4,5~T中的一种或多种;细胞分裂素为2iP、6~苄基氨基嘌呤(6~BA)(=N~6~苄基腺嘌呤)、2,6~二甲基puridine(N~氧化物~2,6~卢剔啶)、2,6~二甲基吡啶、激动素、玉米素中的一种或多种;生长刺激剂为油菜素内酯(brassinolide)、调吡脲(forchlorfenuron)、土菌消(hymexazol)中的一种。Growth agent is one or more of auxin, cytokinin and growth stimulator; wherein, auxin is 4~CPA, 2,4~D, 2,4~DB, 2,4~DEP, 2, 4-dichlorprop, 2,4,5-fenoprop, IAA (indole-3-acetic acid), IBA, naphthaleneacetamide, α-naphthaleneacetic acid, 1-naphthol, naphthoxy One or more of acetic acid, potassium naphthenate, sodium naphthenate, 2,4,5~T; cytokinin is 2iP, 6~benzylaminopurine (6~BA) (=N~6 One or more of ~benzyl adenine), 2,6~dimethyl puridine (N~oxide~2,6~lutidine), 2,6~lutidine, kinetin, zeatin The growth stimulator is one of brassinolide, forchlorfenuron and hymexazol.
抑制剂为脱叶剂、抗生长素和生长阻滞剂中的一种或多种;其中,抗生长素为祛酯酸或者2,3,5~三碘苯甲酸;脱叶剂为氰氨化钙、噻节因(dimethipin)、敌草腈(endothal)、脱叶亚磷(merphos)、甲氧隆(metoxuron)、五氯酚(pentachlorophenol)、赛二唑素(thidiazuron)、脱叶磷(tribufos)、三硫代磷酸三丁酯中的一种或多种。The inhibitor is one or more of defoliants, anti-growth hormones and growth retarders; wherein, the anti-growth hormone is quercetin or 2,3,5-triiodobenzoic acid; the defoliant is cyanamide Calcium, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos ), one or more of tributyl trithiophosphate.
分散剂为木质素磺酸盐与选自烷基酚聚氧乙烯醚甲醛缩合物或脂肪醇聚氧乙烯醚硫酸盐的复合分散剂,二者的重量比为6:1;木质素磺酸盐为木质素磺酸钠或木质素磺酸钙。The dispersant is a lignosulfonate and a composite dispersant selected from alkylphenol polyoxyethylene ether formaldehyde condensate or fatty alcohol polyoxyethylene ether sulfate, and the weight ratio of the two is 6:1; lignosulfonate It is sodium lignosulfonate or calcium lignosulfonate.
本实施例现提出含有调环酸钙与烯效唑的植物生长调节剂的应用,将含有调环酸钙与烯效唑的植物生长调节剂作为农药的应用。This example now proposes the application of the plant growth regulator containing prohexadione calcium and uniconazole, and the application of the plant growth regulator containing prohexadione calcium and uniconazole as a pesticide.
实施例二Embodiment 2
请参阅图1,含有调环酸钙与烯效唑的植物生长调节剂,由以下质量百分比的组分构成:主剂:助剂=100:0~50,其中,主剂由以下质量百分比的组分构成:调环酸钙35%,烯效唑15%,乙烯18%,氧化磷12%,形态素10%,吡唑醚菌酯2%,生长剂6%,抑制剂2%,助剂由以下质量百分比的组分构成:湿润剂10,分散剂20%,消泡剂2%,粘接剂1%,崩解剂7%,载体60%;乙烯通过乙烯释放剂释放形成,乙烯释放剂为ACC、硅长素(etacelasil)、乙烯利(ethephon)、乙二醛肟(glyoxime)中的一种或多种,在使用过程中,可以增加乙烯调节剂,乙烯调节剂为艾维激素(aviglycine)、1~甲基环丙烯(1~MCP)、调环酸(prohexadione)、调环酸钙(prohexadionecalcium)、抗倒酯(trinexapac),抗倒酯(trinexapac~ethyl)中的一种或两种。Please refer to Fig. 1, the plant growth regulator containing prohexadione calcium and uniconazole is composed of the following components by mass percentage: main agent: auxiliary agent=100:0~50, wherein, the main agent is composed of the following mass percentages Component composition: procyclonic acid calcium 35%, uniconazole 15%, ethylene 18%, phosphorus oxide 12%, morphogen 10%, pyraclostrobin 2%, growth agent 6%, inhibitor 2%, auxiliary The agent is composed of the following components by mass percentage: 10% of wetting agent, 20% of dispersant, 2% of defoamer, 1% of adhesive, 7% of disintegrant, and 60% of carrier; ethylene is formed by the release of ethylene release agent, ethylene The release agent is one or more of ACC, etacelasil, ethephon, and glyoxime. During use, an ethylene regulator can be added, and the ethylene regulator is Aiviy Hormone (aviglycine), 1-methylcyclopropene (1-MCP), one of prohexadione, prohexadionecalcium, trinexapac, trinexapac-ethyl species or both.
生长剂为生长素、细胞分裂素和生长刺激剂中的一种或多种;其中,生长素为4~CPA、2,4~D、2,4~DB、2,4~DEP、2,4~滴丙酸(dichlorprop)、2,4,5~涕丙酸(fenoprop)、IAA(吲哚~3~乙酸)、IBA、萘乙酰胺、α~萘乙酸、1~萘酚、萘氧基乙酸、环烷酸钾、环烷酸钠、2,4,5~T中的一种或多种;细胞分裂素为2iP、6~苄基氨基嘌呤(6~BA)(=N~6~苄基腺嘌呤)、2,6~二甲基puridine(N~氧化物~2,6~卢剔啶)、2,6~二甲基吡啶、激动素、玉米素中的一种或多种;生长刺激剂为油菜素内酯(brassinolide)、调吡脲(forchlorfenuron)、土菌消(hymexazol)中的一种。Growth agent is one or more of auxin, cytokinin and growth stimulator; wherein, auxin is 4~CPA, 2,4~D, 2,4~DB, 2,4~DEP, 2, 4-dichlorprop, 2,4,5-fenoprop, IAA (indole-3-acetic acid), IBA, naphthaleneacetamide, α-naphthaleneacetic acid, 1-naphthol, naphthoxy One or more of acetic acid, potassium naphthenate, sodium naphthenate, 2,4,5~T; cytokinin is 2iP, 6~benzylaminopurine (6~BA) (=N~6 One or more of ~benzyl adenine), 2,6~dimethyl puridine (N~oxide~2,6~lutidine), 2,6~lutidine, kinetin, zeatin The growth stimulator is one of brassinolide, forchlorfenuron and hymexazol.
抑制剂为脱叶剂、抗生长素和生长阻滞剂中的一种或多种;其中,抗生长素为祛酯酸或者2,3,5~三碘苯甲酸;脱叶剂为氰氨化钙、噻节因(dimethipin)、敌草腈(endothal)、脱叶亚磷(merphos)、甲氧隆(metoxuron)、五氯酚(pentachlorophenol)、赛二唑素(thidiazuron)、脱叶磷(tribufos)、三硫代磷酸三丁酯中的一种或多种。The inhibitor is one or more of defoliants, anti-growth hormones and growth retarders; wherein, the anti-growth hormone is quercetin or 2,3,5-triiodobenzoic acid; the defoliant is cyanamide Calcium, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos ), one or more of tributyl trithiophosphate.
分散剂为木质素磺酸盐与选自烷基酚聚氧乙烯醚甲醛缩合物或脂肪醇聚氧乙烯醚硫酸盐的复合分散剂,二者的重量比为6:1;木质素磺酸盐为木质素磺酸钠或木质素磺酸钙。The dispersant is a lignosulfonate and a composite dispersant selected from alkylphenol polyoxyethylene ether formaldehyde condensate or fatty alcohol polyoxyethylene ether sulfate, and the weight ratio of the two is 6:1; lignosulfonate It is sodium lignosulfonate or calcium lignosulfonate.
本实施例现提出含有调环酸钙与烯效唑的植物生长调节剂的应用,将含有调环酸钙与烯效唑的植物生长调节剂作为农药的应用。This example now proposes the application of the plant growth regulator containing prohexadione calcium and uniconazole, and the application of the plant growth regulator containing prohexadione calcium and uniconazole as a pesticide.
实施例三Embodiment 3
请参阅图1,含有调环酸钙与烯效唑的植物生长调节剂,由以下质量百分比的组分构成:主剂:助剂=100:0~50,其中,主剂由以下质量百分比的组分构成:调环酸钙15%,烯效唑35%,乙烯10%,氧化磷2%,形态素18%,吡唑醚菌酯12%,生长剂2%,抑制剂6%,助剂由以下质量百分比的组分构成:湿润剂10,分散剂20%,消泡剂2%,粘接剂1%,崩解剂7%,载体60%;乙烯通过乙烯释放剂释放形成,乙烯释放剂为ACC、硅长素(etacelasil)、乙烯利(ethephon)、乙二醛肟(glyoxime)中的一种或多种,在使用过程中,可以增加乙烯调节剂,乙烯调节剂为艾维激素(aviglycine)、1~甲基环丙烯(1~MCP)、调环酸(prohexadione)、调环酸钙(prohexadionecalcium)、抗倒酯(trinexapac),抗倒酯(trinexapac~ethyl)中的一种或两种。Please refer to Fig. 1, the plant growth regulator containing prohexadione calcium and uniconazole is composed of the following components by mass percentage: main agent: auxiliary agent=100:0~50, wherein, the main agent is composed of the following mass percentages Composition: 15% procyclonic acid calcium, 35% uniconazole, 10% ethylene, 2% phosphorus oxide, 18% morphogen, 12% pyraclostrobin, 2% growth agent, 6% inhibitor, auxin The agent is composed of the following components by mass percentage: 10% of wetting agent, 20% of dispersant, 2% of defoamer, 1% of adhesive, 7% of disintegrant, and 60% of carrier; ethylene is formed by the release of ethylene release agent, ethylene The release agent is one or more of ACC, etacelasil, ethephon, and glyoxime. During use, an ethylene regulator can be added, and the ethylene regulator is Aiviy Hormone (aviglycine), 1-methylcyclopropene (1-MCP), one of prohexadione, prohexadionecalcium, trinexapac, trinexapac-ethyl species or both.
生长剂为生长素、细胞分裂素和生长刺激剂中的一种或多种;其中,生长素为4~CPA、2,4~D、2,4~DB、2,4~DEP、2,4~滴丙酸(dichlorprop)、2,4,5~涕丙酸(fenoprop)、IAA(吲哚~3~乙酸)、IBA、萘乙酰胺、α~萘乙酸、1~萘酚、萘氧基乙酸、环烷酸钾、环烷酸钠、2,4,5~T中的一种或多种;细胞分裂素为2iP、6~苄基氨基嘌呤(6~BA)(=N~6~苄基腺嘌呤)、2,6~二甲基puridine(N~氧化物~2,6~卢剔啶)、2,6~二甲基吡啶、激动素、玉米素中的一种或多种;生长刺激剂为油菜素内酯(brassinolide)、调吡脲(forchlorfenuron)、土菌消(hymexazol)中的一种。Growth agent is one or more of auxin, cytokinin and growth stimulator; wherein, auxin is 4~CPA, 2,4~D, 2,4~DB, 2,4~DEP, 2, 4-dichlorprop, 2,4,5-fenoprop, IAA (indole-3-acetic acid), IBA, naphthaleneacetamide, α-naphthaleneacetic acid, 1-naphthol, naphthoxy One or more of acetic acid, potassium naphthenate, sodium naphthenate, 2,4,5~T; cytokinin is 2iP, 6~benzylaminopurine (6~BA) (=N~6 One or more of ~benzyl adenine), 2,6~dimethyl puridine (N~oxide~2,6~lutidine), 2,6~lutidine, kinetin, zeatin The growth stimulator is one of brassinolide, forchlorfenuron and hymexazol.
抑制剂为脱叶剂、抗生长素和生长阻滞剂中的一种或多种;其中,抗生长素为祛酯酸或者2,3,5~三碘苯甲酸;脱叶剂为氰氨化钙、噻节因(dimethipin)、敌草腈(endothal)、脱叶亚磷(merphos)、甲氧隆(metoxuron)、五氯酚(pentachlorophenol)、赛二唑素(thidiazuron)、脱叶磷(tribufos)、三硫代磷酸三丁酯中的一种或多种。The inhibitor is one or more of defoliants, anti-growth hormones and growth retarders; wherein, the anti-growth hormone is quercetin or 2,3,5-triiodobenzoic acid; the defoliant is cyanamide Calcium, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos ), one or more of tributyl trithiophosphate.
分散剂为木质素磺酸盐与选自烷基酚聚氧乙烯醚甲醛缩合物或脂肪醇聚氧乙烯醚硫酸盐的复合分散剂,二者的重量比为6:1;木质素磺酸盐为木质素磺酸钠或木质素磺酸钙。The dispersant is a lignosulfonate and a composite dispersant selected from alkylphenol polyoxyethylene ether formaldehyde condensate or fatty alcohol polyoxyethylene ether sulfate, and the weight ratio of the two is 6:1; lignosulfonate It is sodium lignosulfonate or calcium lignosulfonate.
本实施例现提出含有调环酸钙与烯效唑的植物生长调节剂的应用,将含有调环酸钙与烯效唑的植物生长调节剂作为农药的应用。This example now proposes the application of the plant growth regulator containing prohexadione calcium and uniconazole, and the application of the plant growth regulator containing prohexadione calcium and uniconazole as a pesticide.
实施例四Embodiment 4
请参阅图1,含有调环酸钙与烯效唑的植物生长调节剂,由以下质量百分比的组分构成:主剂:助剂=100:0~50,其中,主剂由以下质量百分比的组分构成:调环酸钙5%,烯效唑45%,乙烯10%,氧化磷2%,形态素18%,吡唑醚菌酯12%,生长剂2%,抑制剂6%,助剂由以下质量百分比的组分构成:湿润剂10,分散剂20%,消泡剂2%,粘接剂1%,崩解剂7%,载体60%;乙烯通过乙烯释放剂释放形成,乙烯释放剂为ACC、硅长素(etacelasil)、乙烯利(ethephon)、乙二醛肟(glyoxime)中的一种或多种,在使用过程中,可以增加乙烯调节剂,乙烯调节剂为艾维激素(aviglycine)、1~甲基环丙烯(1~MCP)、调环酸(prohexadione)、调环酸钙(prohexadionecalcium)、抗倒酯(trinexapac),抗倒酯(trinexapac~ethyl)中的一种或两种。Please refer to Fig. 1, the plant growth regulator containing prohexadione calcium and uniconazole is composed of the following components by mass percentage: main agent: auxiliary agent=100:0~50, wherein, the main agent is composed of the following mass percentages Component composition: procyclonic acid calcium 5%, uniconazole 45%, ethylene 10%, phosphorus oxide 2%, morphogen 18%, pyraclostrobin 12%, growth agent 2%, inhibitor 6%, auxiliary The agent is composed of the following components by mass percentage: 10% of wetting agent, 20% of dispersant, 2% of defoamer, 1% of adhesive, 7% of disintegrant, and 60% of carrier; ethylene is formed by the release of ethylene release agent, ethylene The release agent is one or more of ACC, etacelasil, ethephon, and glyoxime. During use, an ethylene regulator can be added, and the ethylene regulator is Aiviy Hormone (aviglycine), 1-methylcyclopropene (1-MCP), one of prohexadione, prohexadionecalcium, trinexapac, trinexapac-ethyl species or both.
生长剂为生长素、细胞分裂素和生长刺激剂中的一种或多种;其中,生长素为4~CPA、2,4~D、2,4~DB、2,4~DEP、2,4~滴丙酸(dichlorprop)、2,4,5~涕丙酸(fenoprop)、IAA(吲哚~3~乙酸)、IBA、萘乙酰胺、α~萘乙酸、1~萘酚、萘氧基乙酸、环烷酸钾、环烷酸钠、2,4,5~T中的一种或多种;细胞分裂素为2iP、6~苄基氨基嘌呤(6~BA)(=N~6~苄基腺嘌呤)、2,6~二甲基puridine(N~氧化物~2,6~卢剔啶)、2,6~二甲基吡啶、激动素、玉米素中的一种或多种;生长刺激剂为油菜素内酯(brassinolide)、调吡脲(forchlorfenuron)、土菌消(hymexazol)中的一种。Growth agent is one or more of auxin, cytokinin and growth stimulator; wherein, auxin is 4~CPA, 2,4~D, 2,4~DB, 2,4~DEP, 2, 4-dichlorprop, 2,4,5-fenoprop, IAA (indole-3-acetic acid), IBA, naphthaleneacetamide, α-naphthaleneacetic acid, 1-naphthol, naphthoxy One or more of acetic acid, potassium naphthenate, sodium naphthenate, 2,4,5~T; cytokinin is 2iP, 6~benzylaminopurine (6~BA) (=N~6 One or more of ~benzyl adenine), 2,6~dimethyl puridine (N~oxide~2,6~lutidine), 2,6~lutidine, kinetin, zeatin The growth stimulator is one of brassinolide, forchlorfenuron and hymexazol.
抑制剂为脱叶剂、抗生长素和生长阻滞剂中的一种或多种;其中,抗生长素为祛酯酸或者2,3,5~三碘苯甲酸;脱叶剂为氰氨化钙、噻节因(dimethipin)、敌草腈(endothal)、脱叶亚磷(merphos)、甲氧隆(metoxuron)、五氯酚(pentachlorophenol)、赛二唑素(thidiazuron)、脱叶磷(tribufos)、三硫代磷酸三丁酯中的一种或多种。The inhibitor is one or more of defoliants, anti-growth hormones and growth retarders; wherein, the anti-growth hormone is quercetin or 2,3,5-triiodobenzoic acid; the defoliant is cyanamide Calcium, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos ), one or more of tributyl trithiophosphate.
分散剂为木质素磺酸盐与选自烷基酚聚氧乙烯醚甲醛缩合物或脂肪醇聚氧乙烯醚硫酸盐的复合分散剂,二者的重量比为6:1;木质素磺酸盐为木质素磺酸钠或木质素磺酸钙。The dispersant is a lignosulfonate and a composite dispersant selected from alkylphenol polyoxyethylene ether formaldehyde condensate or fatty alcohol polyoxyethylene ether sulfate, and the weight ratio of the two is 6:1; lignosulfonate It is sodium lignosulfonate or calcium lignosulfonate.
为了更好的展现含有调环酸钙与烯效唑的植物生长调节剂的流程,本实施例现提出含有调环酸钙与烯效唑的植物生长调节剂的应用,将含有调环酸钙与烯效唑的植物生长调节剂作为农药的应用。In order to better demonstrate the process of the plant growth regulator containing prohexadione calcium and uniconazole, the present embodiment now proposes the application of the plant growth regulator containing prohexadione calcium and uniconazole. Application of plant growth regulators with uniconazole as pesticides.
氧化磷酸化伴随着ATP生成的作用,具体有代谢物连接的磷酸化和呼吸链连接的磷酸化两种类型,均能够促进线粒体呼吸。Oxidative phosphorylation is accompanied by the role of ATP generation, specifically metabolite-linked phosphorylation and respiratory chain-linked phosphorylation, both of which can promote mitochondrial respiration.
调环酸钙通过植物种子、根系和叶面吸收可以阻断赤霉酸的合成,从而调节植物的营养生长,施用后可壮秆、控旺、促根、抗倒、矮化,使茎叶保持浓绿,叶片挺立,可控制开花时间,提高座果率,促进果实成熟;还能提高植物的抗逆性,增强植株的抗病害、抗寒冷和抗旱的能力,减轻除草剂的药害,从而改善收益率;可通过浸种、浇灌、喷洒处理而起作用,对轮作植物无残留毒性,对环境无污染,作为农药使用,具体可用用于水稻、小麦、大麦等禾本类作物、花生、果树、棉花、葡萄、草坪、菊花、甘蓝、香石竹、甜菜、黄瓜、番茄等。Prohexadione calcium can block the synthesis of gibberellic acid through the absorption of plant seeds, roots and foliage, thereby regulating the vegetative growth of plants. Keeping dark green and erect leaves can control the flowering time, improve the fruit setting rate, and promote fruit ripening; it can also improve the stress resistance of plants, enhance the ability of plants to resist disease, cold and drought, and reduce the phytotoxicity of herbicides. Thereby improving the yield; it can work through seed soaking, watering, spraying treatment, no residual toxicity to rotating plants, no pollution to the environment, and can be used as a pesticide, specifically for rice, wheat, barley and other grass crops, peanuts, Fruit trees, cotton, grapes, lawns, chrysanthemums, cabbage, carnations, beets, cucumbers, tomatoes, etc.
在水稻移栽成活至水稻分蘖期(拔节前7~10天)施用本实施例一至实施例三中的植物生长调节剂,施用量为0.5~1.5克/亩,获取水稻的生长情况,如表1所示;The plant growth regulators in the first to third embodiments are applied from the transplanting of the rice to the tillering stage of the rice (7 to 10 days before jointing), and the application amount is 0.5 to 1.5 g/mu, and the growth conditions of the rice are obtained, such as as shown in Table 1;
表1水稻的生长情况表统计表Table 1 Statistical table of the growth situation of rice
其中,一方面对水稻植株具有缩短基部节间长度、增加节间粗度及机械强度,提高抗倒伏的能力;另一方面具有降低瘪粒率,增加实粒数,从而增加单位面积产量的作用,是实现水稻高产量的重要途径,化解了水稻抗倒伏和高产的矛盾,在保证水稻一定的株高和栽插密度的前提下,从生物特性上提高水稻抗倒伏能力和增产能力,使每亩水稻增产5%~15%,从而达到完美的栽培调控之目的。Among them, on the one hand, it can shorten the length of the basal internodes, increase the thickness and mechanical strength of the internodes, and improve the lodging resistance; on the other hand, it can reduce the rate of shriveled grains and increase the number of solid grains, thereby increasing the yield per unit area. , is an important way to achieve high rice yield, resolves the contradiction between rice lodging resistance and high yield, and on the premise of ensuring a certain plant height and planting density of rice, improves rice lodging resistance and yield increase ability from biological characteristics, so that each The yield of rice per mu can be increased by 5% to 15%, so as to achieve the purpose of perfect cultivation regulation.
在花生生长后期期间施用本实施例一至实施例三中的植物生长调节剂,施用量为2克/亩,获取花生的生长情况,如表2所示;During the later period of peanut growth, the plant growth regulator in the present embodiment one to the third embodiment is applied, and the application amount is 2 g/mu, and the growth situation of the peanut is obtained, as shown in Table 2;
表2花生的生长情况表统计表Table 2 Statistics of the growth situation of peanuts
田间试验结果表明,可显著增加花生叶片厚度和叶绿素含量,促进叶片光合作用;提高叶片SOD、POD和CAT等保护酶活性的可溶性蛋白质含量,但对根系活力和MDA含量影响不大;调环酸钙对控制花生地上部分营养体生长、增加单株果数和果重、提高经济系数以及荚果产量作用显著。The field test results showed that it can significantly increase the leaf thickness and chlorophyll content of peanut, and promote leaf photosynthesis; increase the soluble protein content of protective enzymes such as SOD, POD and CAT in leaves, but have little effect on root activity and MDA content; procyclonic acid Calcium plays a significant role in controlling the growth of aerial vegetative bodies, increasing fruit number and fruit weight per plant, improving economic coefficient and pod yield.
在棉花生长后期期间施用本实施例一至实施例三中的植物生长调节剂,每亩用有效成分3克叶面喷施,获取棉花的生长情况,如表3所示;During the later period of cotton growth, the plant growth regulator in the present embodiment one to three is applied, and 3 grams of active ingredient foliar spray is used per mu to obtain the growth situation of cotton, as shown in Table 3;
表3棉花的生长情况表统计表Table 3 cotton growth table statistics table
在棉花生长中期,可抑制叶和枝条的营养生长,促进生殖生长,显著降低植株的高度,优化通风透光效果,可提高产量并改善品质。In the middle stage of cotton growth, it can inhibit the vegetative growth of leaves and branches, promote reproductive growth, significantly reduce the height of the plant, optimize the effect of ventilation and light transmission, and increase yield and improve quality.
于葡萄谢花后,采用250ppm浓度进行叶面喷施,可有效抑制葡萄的营养生长,提早成熟,改善葡萄的品质,同时具有一定的增产作用。After the grapes have faded, 250ppm concentration of foliar spray can effectively inhibit the vegetative growth of the grapes, ripen earlier, improve the quality of the grapes, and at the same time have a certain effect of increasing production.
百慕大草(狗牙草)、翦股颖(木特草)、草地早熟禾、日本地毯草、黑麦草、结缕草、高芽草等,使用有效成份10~20g/亩进行叶面喷施,整个生长季均可使用,可降低高度50~90%,割草次数明显减少;当用量达到每亩20g时可完全抑制高茅草的生长,其它草坪的最高用量可达到每亩45g,而不会对草坪造成伤害。Bermuda grass (Bermudagrass), bentgrass (Mute grass), bluegrass, Japanese carpet grass, ryegrass, Zoysia, tall sprouts, etc., use 10-20g/mu of active ingredients for foliar spraying , can be used throughout the growing season, the height can be reduced by 50-90%, and the number of mowings is significantly reduced; when the dosage reaches 20g per mu, the growth of tall thatch can be completely inhibited, and the maximum dosage of other lawns can reach 45g per mu, instead of Will cause damage to lawns.
菊花、甘蓝、香石竹等观赏类植物用有效成份1.5~3g/亩进行叶面喷施,具有诱导矮化作用,保持叶片浓绿,延缓衰老,对叶和花无不良影响。Chrysanthemum, cabbage, carnation and other ornamental plants are foliar sprayed with active ingredients of 1.5-3g/mu, which can induce dwarfing, keep leaves dark green, delay senescence, and have no adverse effects on leaves and flowers.
对甜菜、黄瓜和番茄以有效成份1.5~3g/亩进行叶面喷施,可抑制叶和茎的营养生长,优化通风透光效果,可提高产量并改善品质。Foliar spraying of 1.5-3g/mu of active ingredients on sugar beet, cucumber and tomato can inhibit the vegetative growth of leaves and stems, optimize the ventilation and light transmission effect, increase yield and improve quality.
在在果树花后10天内,用125~250ppm浓度的植物生长调节剂叶面喷施,能显著抑制叶和枝条的营养生长,提高果树结果率,改善果实的品质,并提高产量,同时对火疫病等由细菌和真菌引起的病害亦有很好的预防作用。Within 10 days after flowering of fruit trees, foliar spraying of plant growth regulators with a concentration of 125-250 ppm can significantly inhibit the vegetative growth of leaves and branches, improve fruit tree fruiting rate, improve fruit quality, and increase yield. Diseases caused by bacteria and fungi such as blight also have a good preventive effect.
综上所述:本发明提出的含有调环酸钙与烯效唑的植物生长调节剂及其应用,调环酸钙促进叶绿素的生成,加速光合作用,氧化磷促进线粒体呼吸,加速营养转化,定量喷洒药剂的植株吸收该药剂后不仅能够提高叶绿素含量,还能够促进线粒体呼吸将叶绿素光合作用的产物转化为植株的营养成分,提高植物新陈代谢速率,调节植物的营养生长,施用后可壮秆、控旺、促根、抗倒、矮化,使茎叶保持浓绿,叶片挺立,还能提高植物的抗逆性,增强植株的抗病害、抗寒冷和抗旱的能力,在植株成熟后或者其果实成熟后,喷洒高浓度植物生长调节剂,其中,高浓度的调环酸钙、烯效唑和吡唑醚菌酯抑制线粒体呼吸,加速光合作用,进而抑制赤霉酸和形态素的合成,提高座果率,促进果实成熟。To sum up: the plant growth regulator containing prohexadione and uniconazole and its application proposed by the present invention, prohexadione calcium promotes chlorophyll generation, accelerates photosynthesis, phosphorus oxide promotes mitochondrial respiration, accelerates nutrient transformation, Quantitatively sprayed plants can not only increase the chlorophyll content after absorbing the drug, but also promote mitochondrial respiration, convert the products of chlorophyll photosynthesis into plant nutrients, increase plant metabolism rate, and regulate plant vegetative growth. Controlling prosperity, promoting roots, resisting lodging and dwarfing, keeping the stems and leaves dark green, and the leaves standing upright, it can also improve the stress resistance of plants, and enhance the ability of plants to resist disease, cold and drought. After the fruit is ripe, spray high-concentration plant growth regulators. Among them, high-concentration procyclonic acid calcium, uniconazole and pyraclostrobin inhibit mitochondrial respiration, accelerate photosynthesis, and then inhibit the synthesis of gibberellic acid and morphogens. Improve fruit set rate and promote fruit ripening.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明披露的技术范围内,根据本发明的技术方案及其其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the protection scope of the present invention is not limited to this. Equivalent replacements or changes to its inventive concept should be included within the protection scope of the present invention.
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