CN111995253A - Anti-static self-cleaning antibacterial ceramic glaze and preparation method thereof - Google Patents

Anti-static self-cleaning antibacterial ceramic glaze and preparation method thereof Download PDF

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Publication number
CN111995253A
CN111995253A CN202010821762.3A CN202010821762A CN111995253A CN 111995253 A CN111995253 A CN 111995253A CN 202010821762 A CN202010821762 A CN 202010821762A CN 111995253 A CN111995253 A CN 111995253A
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parts
glaze
ceramic glaze
powder
raw material
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曾新宇
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Fujian Dehua Yukun Ceramic Co ltd
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Fujian Dehua Yukun Ceramic Co ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions

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Abstract

The invention discloses an anti-static self-cleaning antibacterial ceramic glaze which comprises the following raw material components: 30-40 parts of silicon dioxide, 5-8 parts of zeolite, 15-25 parts of melilite, 3-5 parts of absolute ethyl alcohol, 1-3 parts of aluminum oxide, 3-5 parts of chromium oxide, 1-3 parts of zinc oxide, 2-4 parts of copper sulfate, 3-5 parts of manganese oxide, 1-3 parts of boron trioxide, 25-30 parts of kaolin, 12-18 parts of boric acid powder, 10-15 parts of calcite, 12-22 parts of nodular clay, 15-20 parts of glazes, 10-20 parts of talcum powder, 2-5 parts of tin crystal material, 2-5 parts of magnesium carbonate, 2-5 parts of calcium carbonate, 2-5 parts of lime glaze and 15-25 parts of composite powder. Has the advantages that: the ceramic glaze has the advantages that the ceramic glaze can achieve rapid and lasting antibacterial performance and good self-cleaning function, even if residual dirt is formed, the residual dirt can be combined with water to form water beads, the uniform and lasting antibacterial characteristic of the spectrum and the antistatic function are achieved, and the application range of the ceramic glaze is further widened.

Description

Anti-static self-cleaning antibacterial ceramic glaze and preparation method thereof
Technical Field
The invention relates to the technical field of ceramic glaze, in particular to an anti-static self-cleaning antibacterial ceramic glaze and a preparation method thereof.
Background
The glaze is a kind of silicate, the glaze applied on the ceramic ware generally uses quartz, feldspar and clay as raw materials, after grinding and adding water to modulate, coats on the surface of the body, and is roasted at a certain temperature to melt, when the temperature is reduced, a glass thin layer with high glossiness is formed on the surface of the ceramic body, and the function of the glaze is to improve the physical and chemical properties of the surface of the body.
The same glaze color of the ceramic products at present can be generally roughly divided into a glazed glaze and a dull glaze in gloss, so that the ceramic products can be presented. The glaze with luster and beautiful and smooth surface cannot be obtained due to the fact that the glossiness is relatively single, meanwhile, the ceramic surface is easily stained with stains, the self-cleaning function effect is not obvious, but the glaze used by the existing ceramic product is high in lead content, great harm is caused to human health due to lead dissolution in the preparation and use processes of the ceramic product, the existing glaze does not have antibacterial performance, discoloration or pollution to contained articles caused by bacteria breeding easily occurs, and the antistatic effect is not achieved.
An effective solution to the problems in the related art has not been proposed yet.
Disclosure of Invention
Aiming at the problems in the related art, the invention provides an anti-static self-cleaning antibacterial ceramic glaze and a preparation method thereof, so as to overcome the technical problems in the prior related art.
Therefore, the invention adopts the following specific technical scheme:
according to one aspect of the invention, the invention provides an anti-static self-cleaning antibacterial ceramic glaze which comprises the following raw material components:
30-40 parts of silicon dioxide, 5-8 parts of zeolite, 15-25 parts of melilite, 3-5 parts of absolute ethyl alcohol, 1-3 parts of aluminum oxide, 3-5 parts of chromium oxide, 1-3 parts of zinc oxide, 2-4 parts of copper sulfate, 3-5 parts of manganese oxide, 1-3 parts of boron trioxide, 25-30 parts of kaolin, 12-18 parts of boric acid powder, 10-15 parts of calcite, 12-22 parts of nodular clay, 15-20 parts of glazes, 10-20 parts of talcum powder, 2-5 parts of tin crystal material, 2-5 parts of magnesium carbonate, 2-5 parts of calcium carbonate, 2-5 parts of lime glaze and 15-25 parts of composite powder;
wherein, the composite powder comprises the following raw material components: 2-4 parts of lithium carbonate, 2-4 parts of barium phosphate, 2-4 parts of conductive powder, 5-8 parts of silver molybdate and 3-5 parts of ammonium dihydrogen phosphate.
Optionally, the anti-static self-cleaning antibacterial ceramic glaze comprises the following raw material components:
30 parts of silicon dioxide, 5 parts of zeolite, 15 parts of melilite, 3 parts of absolute ethyl alcohol, 1 part of alumina, 3 parts of chromium oxide, 1 part of zinc oxide, 2 parts of copper sulfate, 3 parts of manganese oxide, 1 part of diboron trioxide, 25 parts of kaolin, 12 parts of boric acid powder, 10 parts of calcite, 12 parts of knar clay, 15 parts of glazed fruit, 10 parts of talcum powder, 2 parts of tin crystal material, 2 parts of magnesium carbonate, 2 parts of calcium carbonate, 2 parts of lime glaze and 15 parts of composite powder;
wherein the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
Optionally, the anti-static self-cleaning antibacterial ceramic glaze comprises the following raw material components:
35 parts of silicon dioxide, 7.5 parts of zeolite, 20 parts of melilite, 4 parts of absolute ethyl alcohol, 2 parts of aluminum oxide, 4 parts of chromium oxide, 2 parts of zinc oxide, 3 parts of copper sulfate, 4 parts of manganese oxide, 2 parts of diboron trioxide, 27.5 parts of kaolin, 15 parts of boric acid powder, 12.5 parts of calcite, 17 parts of nodular clay, 17.5 parts of glazed fruit, 15 parts of talcum powder, 3.5 parts of tin crystal, 3 parts of magnesium carbonate, 3 parts of calcium carbonate, 3 parts of lime glaze and 20 parts of composite powder.
Wherein, the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
Optionally, the anti-static self-cleaning antibacterial ceramic glaze comprises the following raw material components:
40 parts of silicon dioxide, 8 parts of zeolite, 25 parts of melilite, 5 parts of absolute ethyl alcohol, 3 parts of alumina, 5 parts of chromium oxide, 3 parts of zinc oxide, 4 parts of copper sulfate, 5 parts of manganese oxide, 3 parts of diboron trioxide, 30 parts of kaolin, 18 parts of boric acid powder, 15 parts of calcite, 22 parts of knar clay, 20 parts of glazed fruit, 20 parts of talcum powder, 5 parts of tin crystal material, 5 parts of magnesium carbonate, 5 parts of calcium carbonate, 5 parts of lime glaze and 25 parts of composite powder.
Wherein, the composite powder comprises the following raw material components: 4 parts of lithium carbonate, 4 parts of barium phosphate, 4 parts of conductive powder, 8 parts of silver molybdate and 5 parts of ammonium dihydrogen phosphate.
According to another aspect of the invention, a preparation method of an anti-static self-cleaning antibacterial ceramic glaze is provided, which comprises the following steps:
purchasing a ceramic glaze raw material and a packaging material in advance, and respectively warehousing and storing;
sampling and detecting the ceramic glaze raw material, analyzing whether the detection result reaches the standard, if not, carrying out isolation and sealing storage, and if so, releasing the raw material;
gathering the released raw materials in batches, and weighing the raw materials of the ceramic glaze according to preset raw material components;
adding silicon dioxide, aluminum oxide, chromium oxide, zinc oxide, copper sulfate, manganese oxide and diboron trioxide into a jet mill, and carrying out crushing treatment to obtain a primary mixture I;
putting boric acid powder, calcite, knar clay, glazed fruit, talcum powder, tin crystal material, magnesium carbonate and calcium carbonate into a ball mill for ball milling for 7-10 h to obtain a primary mixture II with the granularity of 400-450 meshes;
uniformly stirring the primary mixture I and the primary mixture II, performing ball milling, and adding zeolite, melilite, absolute ethyl alcohol, 25-30 parts of kaolin, lime glaze and composite powder into a ball mill;
then smelting for 2-3 hours, then smelting for 2-5 hours at 1000-1600 ℃, and then water quenching to obtain a block glaze;
after wet ball milling, sieving and removing impurities to obtain glaze slurry, and coating or spraying the glaze slurry on the surface of a ceramic biscuit;
and (3) drying until the moisture in the glaze slip is less than 2%, taking out, cooling to room temperature, standing for 3-5 days, spraying again, firing at 1000-1100 ℃ for 1-5 times in a nitrogen atmosphere, wherein the firing time is 15-30 minutes each time, and cooling to obtain the ceramic glaze.
The invention has the beneficial effects that: the glaze has stable chemical performance, can achieve quick and lasting antibacterial performance and good self-cleaning function, avoids lead dissolution in the use process, ensures the human health in the preparation and use processes, has opaque ivory white glaze color, is exquisite and simple, is integrally matt under the same glaze color, has luminous and transparent decorative texture parts, can show the decoration made by a product or an artwork while having high-tone luster in the relatively dull matt glaze, has high smoothness of the glaze surface, is not easy to adsorb dirt, and is very easy to clean. When the ceramic glaze is cleaned by water, dirt can be easily washed away with the water, even if residual dirt is remained, the dirt and the water are combined together to form water beads, and the ceramic glaze also has uniform and durable antibacterial property and antistatic function, so that the application range of the ceramic glaze is further widened.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings needed in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings without creative efforts.
FIG. 1 is one of the flow charts of the steps of a preparation method of an antistatic self-cleaning antibacterial ceramic glaze according to the embodiment of the invention;
fig. 2 is a second step flow chart of a method for preparing an anti-static self-cleaning antibacterial ceramic glaze according to an embodiment of the invention.
Detailed Description
For further explanation of the various embodiments, the drawings which form a part of the disclosure and which are incorporated in and constitute a part of this specification, illustrate embodiments and, together with the description, serve to explain the principles of operation of the embodiments, and to enable others of ordinary skill in the art to understand the various embodiments and advantages of the invention, and, by reference to these figures, reference is made to the accompanying drawings, which are not to scale and wherein like reference numerals generally refer to like elements.
According to the embodiment of the invention, the invention provides an anti-static self-cleaning antibacterial ceramic glaze and a preparation method thereof.
The first embodiment;
as shown in fig. 1-2, the anti-static self-cleaning antibacterial ceramic glaze according to the embodiment of the invention comprises the following raw material components:
30-40 parts of silicon dioxide, 5-8 parts of zeolite, 15-25 parts of melilite, 3-5 parts of absolute ethyl alcohol, 1-3 parts of aluminum oxide, 3-5 parts of chromium oxide, 1-3 parts of zinc oxide, 2-4 parts of copper sulfate, 3-5 parts of manganese oxide, 1-3 parts of boron trioxide, 25-30 parts of kaolin, 12-18 parts of boric acid powder, 10-15 parts of calcite, 12-22 parts of nodular clay, 15-20 parts of glazes, 10-20 parts of talcum powder, 2-5 parts of tin crystal material, 2-5 parts of magnesium carbonate, 2-5 parts of calcium carbonate, 2-5 parts of lime glaze and 15-25 parts of composite powder;
wherein, the composite powder comprises the following raw material components: 2-4 parts of lithium carbonate, 2-4 parts of barium phosphate, 2-4 parts of conductive powder, 5-8 parts of silver molybdate and 3-5 parts of ammonium dihydrogen phosphate.
In order to clearly understand the technical scheme of the invention, the technical scheme of the invention is described in detail through specific examples.
Example two;
as shown in fig. 1-2, the anti-static self-cleaning antibacterial ceramic glaze according to the embodiment of the invention comprises the following raw material components:
30 parts of silicon dioxide, 5 parts of zeolite, 15 parts of melilite, 3 parts of absolute ethyl alcohol, 1 part of alumina, 3 parts of chromium oxide, 1 part of zinc oxide, 2 parts of copper sulfate, 3 parts of manganese oxide, 1 part of diboron trioxide, 25 parts of kaolin, 12 parts of boric acid powder, 10 parts of calcite, 12 parts of knar clay, 15 parts of glazed fruit, 10 parts of talcum powder, 2 parts of tin crystal material, 2 parts of magnesium carbonate, 2 parts of calcium carbonate, 2 parts of lime glaze and 15 parts of composite powder;
wherein the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
Example three;
as shown in fig. 1-2, the anti-static self-cleaning antibacterial ceramic glaze according to the embodiment of the invention comprises the following raw material components:
35 parts of silicon dioxide, 7.5 parts of zeolite, 20 parts of melilite, 4 parts of absolute ethyl alcohol, 2 parts of aluminum oxide, 4 parts of chromium oxide, 2 parts of zinc oxide, 3 parts of copper sulfate, 4 parts of manganese oxide, 2 parts of diboron trioxide, 27.5 parts of kaolin, 15 parts of boric acid powder, 12.5 parts of calcite, 17 parts of nodular clay, 17.5 parts of glazed fruit, 15 parts of talcum powder, 3.5 parts of tin crystal, 3 parts of magnesium carbonate, 3 parts of calcium carbonate, 3 parts of lime glaze and 20 parts of composite powder.
Wherein, the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
Example four;
as shown in fig. 1-2, the anti-static self-cleaning antibacterial ceramic glaze according to the embodiment of the invention comprises the following raw material components:
40 parts of silicon dioxide, 8 parts of zeolite, 25 parts of melilite, 5 parts of absolute ethyl alcohol, 3 parts of alumina, 5 parts of chromium oxide, 3 parts of zinc oxide, 4 parts of copper sulfate, 5 parts of manganese oxide, 3 parts of diboron trioxide, 30 parts of kaolin, 18 parts of boric acid powder, 15 parts of calcite, 22 parts of knar clay, 20 parts of glazed fruit, 20 parts of talcum powder, 5 parts of tin crystal material, 5 parts of magnesium carbonate, 5 parts of calcium carbonate, 5 parts of lime glaze and 25 parts of composite powder.
Wherein, the composite powder comprises the following raw material components: 4 parts of lithium carbonate, 4 parts of barium phosphate, 4 parts of conductive powder, 8 parts of silver molybdate and 5 parts of ammonium dihydrogen phosphate.
Example five;
as shown in fig. 1-2, according to another aspect of the present invention, there is provided a method for preparing an antistatic self-cleaning antibacterial ceramic glaze, comprising the steps of:
step S101, purchasing a ceramic glaze raw material and a packaging material in advance, and warehousing and storing the ceramic glaze raw material and the packaging material respectively;
step S103, sampling and detecting the ceramic glaze raw material, analyzing whether the detection result reaches the standard, if not, carrying out isolation and sealing storage, and if so, carrying out release of the raw material;
s105, gathering the released raw materials in batches, and weighing each ceramic glaze raw material according to preset raw material components;
step S107, adding silicon dioxide, aluminum oxide, chromium oxide, zinc oxide, copper sulfate, manganese oxide and boron trioxide into a jet mill, and performing crushing treatment to obtain a primary mixture I;
step S, putting boric acid powder, calcite, nodular clay, glazed fruit, talcum powder, tin crystal material, magnesium carbonate and calcium carbonate into a ball mill for ball milling for 7-10 h to obtain a primary mixture II with the granularity of 400-450 meshes;
step S111, uniformly stirring the primary mixture I and the primary mixture II, performing ball milling, and adding zeolite, melilite, absolute ethyl alcohol, kaolin, lime glaze and composite powder into a ball mill;
step S113, smelting for 2-3 hours, then smelting for 2-5 hours at 1000-1600 ℃, and then water quenching to obtain a block glaze;
step S115, after wet ball milling, sieving and removing impurities to obtain glaze slurry, and coating or spraying the glaze slurry on the surface of a ceramic biscuit;
and step S117, drying until the moisture in the glaze slip is less than 2%, taking out and cooling to room temperature, standing for 3-5 days, spraying again, firing for 1-5 times at 1000-1100 ℃ in a nitrogen atmosphere, wherein the firing time is 15-30 minutes each time, and cooling to obtain the ceramic glaze.
In conclusion, by means of the technical scheme, the novel self-cleaning glaze has stable chemical performance, can achieve quick and lasting antibacterial performance and a good self-cleaning function, avoids lead dissolution in the using process, ensures the health of human bodies in the preparation and using processes, has opaque ivory white glaze color, is fine, fine and simple, is matt integrally under the same glaze color, is luminous and transparent in decorative texture parts, can show the decoration made by products or artworks while having high-tone luster in relatively dull matt, is highly smooth in glaze surface, is not easy to adsorb dirt, and is very easy to clean. When the ceramic glaze is cleaned by water, dirt can be easily washed away with the water, even if residual dirt is remained, the dirt and the water are combined together to form water beads, and the ceramic glaze also has uniform and durable antibacterial property and antistatic function, so that the application range of the ceramic glaze is further widened.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that fall within the spirit and principle of the present invention are intended to be included therein.

Claims (8)

1. An anti-static self-cleaning antibacterial ceramic glaze is characterized by comprising the following raw material components:
30-40 parts of silicon dioxide, 5-8 parts of zeolite, 15-25 parts of melilite, 3-5 parts of absolute ethyl alcohol, 1-3 parts of aluminum oxide, 3-5 parts of chromium oxide, 1-3 parts of zinc oxide, 2-4 parts of copper sulfate, 3-5 parts of manganese oxide, 1-3 parts of boron trioxide, 25-30 parts of kaolin, 12-18 parts of boric acid powder, 10-15 parts of calcite, 12-22 parts of nodular clay, 15-20 parts of glazes, 10-20 parts of talcum powder, 2-5 parts of tin crystal material, 2-5 parts of magnesium carbonate, 2-5 parts of calcium carbonate, 2-5 parts of lime glaze and 15-25 parts of composite powder;
wherein, the composite powder comprises the following raw material components: 2-4 parts of lithium carbonate, 2-4 parts of barium phosphate, 2-4 parts of conductive powder, 5-8 parts of silver molybdate and 3-5 parts of ammonium dihydrogen phosphate.
2. The anti-static self-cleaning antibacterial ceramic glaze according to claim 1, which is characterized by comprising the following raw material components:
30 parts of silicon dioxide, 5 parts of zeolite, 15 parts of melilite, 3 parts of absolute ethyl alcohol, 1 part of alumina, 3 parts of chromium oxide, 1 part of zinc oxide, 2 parts of copper sulfate, 3 parts of manganese oxide, 1 part of diboron trioxide, 25 parts of kaolin, 12 parts of boric acid powder, 10 parts of calcite, 12 parts of knar clay, 15 parts of glazed fruit, 10 parts of talcum powder, 2 parts of tin crystal material, 2 parts of magnesium carbonate, 2 parts of calcium carbonate, 2 parts of lime glaze and 15 parts of composite powder.
3. The anti-static self-cleaning antibacterial ceramic glaze according to claim 2, wherein the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
4. The anti-static self-cleaning antibacterial ceramic glaze according to claim 1, wherein the ceramic glaze comprises 35 parts of silicon dioxide, 7.5 parts of zeolite, 20 parts of melilite, 4 parts of absolute ethyl alcohol, 2 parts of alumina, 4 parts of chromium oxide, 2 parts of zinc oxide, 3 parts of copper sulfate, 4 parts of manganese oxide, 2 parts of boron trioxide, 27.5 parts of kaolin, 15 parts of boric acid powder, 12.5 parts of calcite, 17 parts of nodular clay, 17.5 parts of glazed fruit, 15 parts of talcum powder, 3.5 parts of tin crystal, 3 parts of magnesium carbonate, 3 parts of calcium carbonate, 3 parts of lime glaze and 20 parts of composite powder.
5. The anti-static self-cleaning antibacterial ceramic glaze according to claim 4, wherein the composite powder comprises the following raw material components: 2 parts of lithium carbonate, 2 parts of barium phosphate, 2 parts of conductive powder, 5 parts of silver molybdate and 3 parts of ammonium dihydrogen phosphate.
6. The anti-static self-cleaning antibacterial ceramic glaze and the preparation method thereof according to claim 1 are characterized by comprising the following raw material components: 40 parts of silicon dioxide, 8 parts of zeolite, 25 parts of melilite, 5 parts of absolute ethyl alcohol, 3 parts of alumina, 5 parts of chromium oxide, 3 parts of zinc oxide, 4 parts of copper sulfate, 5 parts of manganese oxide, 3 parts of diboron trioxide, 30 parts of kaolin, 18 parts of boric acid powder, 15 parts of calcite, 22 parts of knar clay, 20 parts of glazed fruit, 20 parts of talcum powder, 5 parts of tin crystal material, 5 parts of magnesium carbonate, 5 parts of calcium carbonate, 5 parts of lime glaze and 25 parts of composite powder.
7. The anti-static self-cleaning antibacterial ceramic glaze and the preparation method thereof as claimed in claim 6, wherein the composite powder comprises the following raw material components: 4 parts of lithium carbonate, 4 parts of barium phosphate, 4 parts of conductive powder, 8 parts of silver molybdate and 5 parts of ammonium dihydrogen phosphate.
8. A method for preparing an antistatic self-cleaning antibacterial ceramic glaze according to claim 1, which comprises the following steps:
purchasing a ceramic glaze raw material and a packaging material in advance, and respectively warehousing and storing;
sampling and detecting the ceramic glaze raw material, analyzing whether the detection result reaches the standard, if not, carrying out isolation and sealing storage, and if so, releasing the raw material;
gathering the released raw materials in batches, and weighing the raw materials of the ceramic glaze according to preset raw material components;
adding silicon dioxide, aluminum oxide, chromium oxide, zinc oxide, copper sulfate, manganese oxide and boron trioxide into a jet mill, and performing crushing treatment to obtain a primary mixture I;
putting boric acid powder, calcite, knar clay, glaze, talcum powder, tin crystal, magnesium carbonate and calcium carbonate into a ball mill for ball milling for 7-10 h to obtain a primary mixture II with the granularity of 400-450 meshes;
uniformly stirring the primary mixture I and the primary mixture II, performing ball milling, and adding the zeolite part, the melilite part, the absolute ethyl alcohol part, the kaolin part, the lime glaze part and the composite powder part into a ball mill;
then smelting for 2-3 hours, then smelting for 2-5 hours at 1000-1600 ℃, and then water quenching to obtain a block glaze;
after wet ball milling, sieving and removing impurities to obtain glaze slurry, and coating or spraying the glaze slurry on the surface of a ceramic biscuit;
and (3) drying until the moisture in the glaze slip is less than 2%, taking out, cooling to room temperature, standing for 3-5 days, spraying again, firing at 1000-1100 ℃ for 1-5 times in a nitrogen atmosphere, wherein the firing time is 15-30 minutes each time, and cooling to obtain the ceramic glaze.
CN202010821762.3A 2020-08-15 2020-08-15 Anti-static self-cleaning antibacterial ceramic glaze and preparation method thereof Pending CN111995253A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105064638A (en) * 2015-08-07 2015-11-18 东莞市唯美陶瓷工业园有限公司 Antistatic ceramic tile and manufacturing method thereof
CN109704579A (en) * 2019-03-06 2019-05-03 盐城工业职业技术学院 A kind of ceramic glaze and preparation method thereof with antibacterial functions
CN111204979A (en) * 2020-01-23 2020-05-29 林丽品 Ivory white ceramic glaze with self-cleaning function and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105064638A (en) * 2015-08-07 2015-11-18 东莞市唯美陶瓷工业园有限公司 Antistatic ceramic tile and manufacturing method thereof
CN109704579A (en) * 2019-03-06 2019-05-03 盐城工业职业技术学院 A kind of ceramic glaze and preparation method thereof with antibacterial functions
CN111204979A (en) * 2020-01-23 2020-05-29 林丽品 Ivory white ceramic glaze with self-cleaning function and preparation method thereof

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