CN111978782A - Solvent type varnish for high-temperature sintering glass ink and preparation method thereof - Google Patents
Solvent type varnish for high-temperature sintering glass ink and preparation method thereof Download PDFInfo
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- CN111978782A CN111978782A CN202010940553.0A CN202010940553A CN111978782A CN 111978782 A CN111978782 A CN 111978782A CN 202010940553 A CN202010940553 A CN 202010940553A CN 111978782 A CN111978782 A CN 111978782A
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- 239000002966 varnish Substances 0.000 title claims abstract description 41
- 239000002904 solvent Substances 0.000 title claims abstract description 36
- 239000011521 glass Substances 0.000 title claims abstract description 24
- 238000005245 sintering Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 claims abstract description 10
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 12
- 239000004642 Polyimide Substances 0.000 claims description 11
- 229920001721 polyimide Polymers 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- 239000001856 Ethyl cellulose Substances 0.000 claims description 8
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical group CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 8
- 229920001249 ethyl cellulose Polymers 0.000 claims description 8
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000025 natural resin Substances 0.000 claims description 7
- 229920001568 phenolic resin Polymers 0.000 claims description 7
- 239000005011 phenolic resin Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 239000012456 homogeneous solution Substances 0.000 claims description 6
- 230000010355 oscillation Effects 0.000 claims description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 239000003350 kerosene Substances 0.000 claims description 5
- 230000009965 odorless effect Effects 0.000 claims description 5
- 229920005749 polyurethane resin Polymers 0.000 claims description 5
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 claims description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 3
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 3
- 238000003889 chemical engineering Methods 0.000 abstract description 2
- 239000012847 fine chemical Substances 0.000 abstract description 2
- 239000000976 ink Substances 0.000 description 24
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 14
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 14
- 229940116411 terpineol Drugs 0.000 description 14
- 239000000203 mixture Substances 0.000 description 7
- 239000000049 pigment Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000011068 loading method Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- 238000003848 UV Light-Curing Methods 0.000 description 1
- -1 and finally Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a solvent type varnish for high-temperature sintering glass ink, which belongs to the field of new materials and fine chemical engineering, and comprises the following raw materials in parts by weight: 1-20 parts of oil-soluble resin, 70-95 parts of low-odor solvent, 5-10 parts of adhesive, 0.1-5 parts of viscosity regulator and 0.1-5 parts of auxiliary agent.
Description
Technical Field
The invention belongs to the field of new materials and fine chemical engineering, and particularly relates to a solvent type varnish for high-temperature sintered glass ink and a preparation method thereof.
Background
The toughened glass ink applied to automobiles, buildings, household appliances and the like is mainly divided into a solvent type, a water-based type and a UV curing type. The solvent type is basically a terpineol system, occupies a main position, has good storage stability and good adhesive force, but is accompanied with the attention and requirements of people on environmental protection and health, finds one of the disadvantages of the terpineol system product, namely, has large smell and certain harm to the environment and human body, the ink system is easy to generate bubbles, the problem of the bubbles can be solved by adding a defoaming agent, the pigment loading amount of the ink adjusting oil is low, the preparation of the ink with high solid content is not facilitated, meanwhile, a screen printing plate and glass for printing are required to be cleaned by using a special cleaning agent, and the pollution of underground water is easily caused by random discharge; moreover, the terpineol is mainly extracted from natural substances, the production capacity is limited, the price of the terpineol is high, and the cost pressure is also applied to production enterprises. Therefore, the varnish capable of replacing a terpineol system is developed, has the advantages of low odor, low volatilization, easiness in cleaning and the like, and can well solve the problem of the conventional solvent type varnish.
The terpineol system is used as a mature product, companies have few researches on the product, main hot spots are concentrated on the water-based varnish, but the current water-based varnish still has the problems of poor storage stability, large residual ash content after high-temperature sintering and the like, and cannot completely replace solvent-based products in a short time, so the terpineol system has great significance for optimizing the current terpineol system product which is the mainstream.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to provide the solvent type varnish for the high-temperature sintering glass ink and the preparation method thereof.
In order to realize the purpose, the invention adopts the technical scheme that:
the solvent type varnish for the high-temperature sintered glass ink comprises the following raw materials in parts by weight: 1-20 parts of oil-soluble resin, 70-95 parts of low-odor solvent, 5-10 parts of adhesive, 0.1-5 parts of viscosity regulator and 0.1-5 parts of auxiliary agent.
Further, the oil-soluble resin is one or two of acrylic resin, polyurethane resin, phenolic resin, alkyd resin and natural resin.
Preferably, the oil-soluble resin is one or both of a natural resin and a phenolic resin.
Further, the low-odor solvent is one or more of odorless kerosene, ethylene glycol phenyl ether, DBE, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, methyl pyrrolidone, diethylene glycol, dipropylene glycol, diethylene glycol butyl ether, and dipropylene glycol methyl ether.
Further, the adhesive is a polyimide solution.
Further, the viscosity modifier is ethyl cellulose.
Further, the auxiliary agent is one or more of a dispersing agent, a coupling agent, a surfactant and a leveling agent.
A preparation method of a solvent type varnish for high-temperature sintering glass ink specifically comprises the following steps:
step 1: according to the weight portion, dissolving water-soluble resin in a low-odor solvent under a heating condition, then stirring, adding an adhesive and a viscosity regulator under the stirring condition, cooling to room temperature after uniformly mixing to form a homogeneous solution, and finally adding an auxiliary agent and fully stirring to obtain a uniform liquid;
step 2: and (3) carrying out ultrasonic oscillation on the uniform liquid obtained in the step (1) for 60-120min, and finally standing for 30-50min to obtain the varnish product.
Further, the heating temperature in the step 1 is controlled to be 40-70 ℃.
The invention has the beneficial effects that: (1) the solvent type varnish prepared by the invention has extremely low smell, greatly reduces the cost compared with a terpineol system, has good compatibility with the ink of various terpineol systems, has proper volatilization speed and high pigment loading capacity, simultaneously produces no bubbles, can wash the glass printed with the ink by water, and can well replace the varnish of the terpineol system on the market at present;
(2) the oil-soluble resin adopted by the invention preferably selects natural resin and phenolic resin, the two resins have good pigment wettability and printability, and simultaneously, the residual ash content of high-temperature sintering is low, and the odor-free flux adopted reduces the odor of the produced ink, thereby having certain benefits on the environment and human health;
(3) according to the invention, the polyimide solution is used as an adhesive, so that the adhesive force of the varnish is improved, the storage stability and thixotropy adjustment of the varnish are improved by combining with a viscosity regulator, the thermal stability of the pigment in the varnish can be improved by the polyimide, the wettability of the pigment can be improved by the low-odor solvent, and the loading capacity of the pigment in the varnish is improved by the synergistic effect of the polyimide solution, the viscosity regulator and the viscosity regulator;
(4) the surfactant in the auxiliary agent is respectively compatible with two phases through different parts in molecules, so that the two phases are both regarded as components of the phase, the molecules are arranged between the two phases, the surfaces of the two phases are equivalently transferred into the interior of the molecules, the surface tension is reduced, the surfactant is used as the auxiliary agent and added into the ink adjusting oil to play a role in inhibiting the generation of foam, so that bubbles are not easy to generate during the production of the ink, and the ultrasonic oscillation treatment is carried out in the preparation process of the ink adjusting oil to remove the generated bubbles, so that the bubbles can be further prevented from being generated.
Detailed Description
For a better understanding of the present invention, embodiments of the present invention are described in detail below with reference to examples, but those skilled in the art will understand that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention.
The oil-soluble resin in the following examples is one or two of acrylic resin, polyurethane resin, phenolic resin, alkyd resin and natural resin; the low-odor solvent is one or more of odorless kerosene, ethylene glycol phenyl ether, DBE, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, methyl pyrrolidone, diethylene glycol, dipropylene glycol, diethylene glycol butyl ether and dipropylene glycol methyl ether; the auxiliary agent is one or more of a dispersing agent, a coupling agent, a surfactant and a flatting agent.
Example 1:
the solvent type varnish for the high-temperature sintered glass ink comprises the following raw materials in parts by weight: 18 parts of natural resin, 70 parts of ethylene glycol phenyl ether, 5 parts of polyimide solution, 2 parts of ethyl cellulose and 5 parts of surfactant.
A preparation method of a solvent type varnish for high-temperature sintering glass ink specifically comprises the following steps:
step 1: according to the weight portion, natural resin is dissolved in ethylene glycol phenyl ether under the heating condition, the heating temperature is controlled at 40 ℃, then stirring is carried out, polyimide solution and ethyl cellulose are added under the stirring condition, the mixture is cooled to room temperature after being uniformly mixed into homogeneous solution, and finally, surfactant is added and the mixture is fully stirred to obtain uniform liquid;
step 2: and (3) carrying out ultrasonic oscillation on the uniform liquid obtained in the step (1) for 120min, and finally standing for 30min to obtain the varnish product.
Example 2:
the solvent type varnish for the high-temperature sintered glass ink comprises the following raw materials in parts by weight: 1 part of phenolic resin, 95 parts of methyl pyrrolidone, 10 parts of polyimide solution, 5 parts of ethyl cellulose and 0.1 part of dispersant.
A preparation method of a solvent type varnish for high-temperature sintering glass ink specifically comprises the following steps:
step 1: according to the weight portion, phenolic resin is dissolved in methyl pyrrolidone under the heating condition, the heating temperature is controlled at 70 ℃, then stirring is carried out, polyimide solution and ethyl cellulose are added under the stirring condition, the mixture is cooled to room temperature after being uniformly mixed into homogeneous solution, and finally dispersing agent is added and fully stirred to obtain uniform liquid;
step 2: and (3) carrying out ultrasonic oscillation on the uniform liquid obtained in the step (1) for 60min, and finally standing for 50min to obtain the varnish product.
Example 3:
the solvent type varnish for the high-temperature sintered glass ink comprises the following raw materials in parts by weight: 20 parts of polyurethane resin, 80 parts of odorless kerosene, 6 parts of polyimide solution, 0.1 part of ethyl cellulose and 3 parts of flatting agent.
A preparation method of a solvent type varnish for high-temperature sintering glass ink specifically comprises the following steps:
step 1: according to the weight portion, polyurethane resin is dissolved in odorless kerosene under the heating condition, the heating temperature is controlled at 65 ℃, then stirring is carried out, polyimide solution and ethyl cellulose are added under the stirring condition, after the mixture is uniformly mixed into homogeneous solution, the homogeneous solution is cooled to the room temperature, and finally, a leveling agent is added, and the mixture is fully stirred to obtain uniform liquid;
step 2: and (3) carrying out ultrasonic oscillation on the uniform liquid obtained in the step (1) for 100min, and finally standing for 35min to obtain the varnish product.
Comparative example 1:
comparative example 1 is different from example 1 in that the binder is removed from the formulation of the varnish, and the rest is the same as example 1.
Comparative example 2:
comparative example 2 is different from example 1 in that the viscosity modifier is removed from the formulation of the base material of the varnish, and the rest is the same as example 1.
The varnish prepared in the above examples and comparative examples was subjected to performance testing, and the test results are shown in table 1.
TABLE 1
As can be seen from the above Table 1, the solvent type varnish prepared by the invention has extremely low odor, greatly reduced cost compared with the terpineol system, good compatibility with various inks of the terpineol system, proper volatilization speed and high pigment loading capacity, no bubbles in the produced ink, and the glass printed with the ink can be washed by water and can well replace the varnish of the terpineol system on the market at present.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without the use of the inventive faculty. Therefore, the present invention is not limited to the above-described embodiments. Those skilled in the art should appreciate that many modifications and variations are possible in light of the above teaching without departing from the scope of the invention.
Claims (8)
1. The solvent type varnish for the high-temperature sintered glass ink is characterized by comprising the following raw materials in parts by weight: 1-20 parts of oil-soluble resin, 70-95 parts of low-odor solvent, 5-10 parts of adhesive, 0.1-5 parts of viscosity regulator and 0.1-5 parts of auxiliary agent.
2. The solvent type varnish for the high-temperature sintering glass ink, according to claim 1, wherein the oil-soluble resin is one or two of acrylic resin, polyurethane resin, phenolic resin, alkyd resin and natural resin.
3. The solvent type varnish for the high-temperature sintering glass ink, according to claim 1, wherein the low-odor solvent is one or more of odorless kerosene, ethylene glycol phenyl ether, DBE, diethylene glycol butyl ether acetate, diethylene glycol ethyl ether acetate, methyl pyrrolidone, diethylene glycol, dipropylene glycol, diethylene glycol butyl ether, and dipropylene glycol methyl ether.
4. The solvent type varnish for the high-temperature sintering glass ink, as recited in claim 1, wherein the adhesive is a polyimide solution.
5. The solvent type varnish for the high-temperature sintering glass ink, according to claim 1, wherein the viscosity regulator is ethyl cellulose.
6. The solvent type varnish for the high-temperature sintered glass ink as claimed in claim 1, wherein the auxiliary agent is one or more of a dispersant, a coupling agent, a surfactant and a leveling agent.
7. The preparation method of the solvent type varnish for the high-temperature sintering glass ink as claimed in any one of claims 1 to 6, which is characterized by comprising the following steps:
step 1: according to the weight portion, dissolving water-soluble resin in a low-odor solvent under a heating condition, then stirring, adding an adhesive and a viscosity regulator under the stirring condition, cooling to room temperature after uniformly mixing to form a homogeneous solution, and finally adding an auxiliary agent and fully stirring to obtain a uniform liquid;
step 2: and (3) carrying out ultrasonic oscillation on the uniform liquid obtained in the step (1) for 60-120min, and finally standing for 30-50min to obtain the varnish product.
8. The method for preparing the solvent type varnish for the high-temperature sintering glass ink according to the claim 7, wherein the heating temperature in the step 1 is controlled to be 40-70 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010940553.0A CN111978782A (en) | 2020-09-09 | 2020-09-09 | Solvent type varnish for high-temperature sintering glass ink and preparation method thereof |
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| CN202010940553.0A CN111978782A (en) | 2020-09-09 | 2020-09-09 | Solvent type varnish for high-temperature sintering glass ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024104498A1 (en) * | 2023-08-16 | 2024-05-23 | 黄山市晶特美新材料有限公司 | New solvent-type varnish for glass frit, and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101984004A (en) * | 2010-10-28 | 2011-03-09 | 上海曾云化工科技有限公司 | Environment friendly water soluble varnish for high temperature sintered coating and preparation method thereof |
| CN105315770A (en) * | 2014-07-23 | 2016-02-10 | 中山本州电子浆料科技有限公司 | High-temperature-sintered environment-friendly type water-soluble automotive glass varnish and preparation method |
| CN106280682A (en) * | 2015-05-13 | 2017-01-04 | 孙宝林 | A kind of environmental protection leather aqueous stamp-pad ink and preparation method thereof |
| CN107236357A (en) * | 2017-07-25 | 2017-10-10 | 合肥利裕泰玻璃制品有限公司 | A kind of high temp glass ink and preparation method thereof |
| CN111635666A (en) * | 2020-06-19 | 2020-09-08 | 佛山荷韵特种材料有限公司 | LED-UV (light-emitting diode-ultraviolet) cured environment-friendly high-temperature sintering varnish and preparation method thereof |
-
2020
- 2020-09-09 CN CN202010940553.0A patent/CN111978782A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101984004A (en) * | 2010-10-28 | 2011-03-09 | 上海曾云化工科技有限公司 | Environment friendly water soluble varnish for high temperature sintered coating and preparation method thereof |
| CN105315770A (en) * | 2014-07-23 | 2016-02-10 | 中山本州电子浆料科技有限公司 | High-temperature-sintered environment-friendly type water-soluble automotive glass varnish and preparation method |
| CN106280682A (en) * | 2015-05-13 | 2017-01-04 | 孙宝林 | A kind of environmental protection leather aqueous stamp-pad ink and preparation method thereof |
| CN107236357A (en) * | 2017-07-25 | 2017-10-10 | 合肥利裕泰玻璃制品有限公司 | A kind of high temp glass ink and preparation method thereof |
| CN111635666A (en) * | 2020-06-19 | 2020-09-08 | 佛山荷韵特种材料有限公司 | LED-UV (light-emitting diode-ultraviolet) cured environment-friendly high-temperature sintering varnish and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李勇: "《废旧高分子材料循环利用》", 31 July 2019, 冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024104498A1 (en) * | 2023-08-16 | 2024-05-23 | 黄山市晶特美新材料有限公司 | New solvent-type varnish for glass frit, and preparation method therefor |
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