CN111978150A - 用于生产甲醇的方法和设备 - Google Patents
用于生产甲醇的方法和设备 Download PDFInfo
- Publication number
- CN111978150A CN111978150A CN202010418294.5A CN202010418294A CN111978150A CN 111978150 A CN111978150 A CN 111978150A CN 202010418294 A CN202010418294 A CN 202010418294A CN 111978150 A CN111978150 A CN 111978150A
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- CN
- China
- Prior art keywords
- gas
- methanol
- reactor stage
- reactor
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 369
- 238000000034 method Methods 0.000 title claims abstract description 54
- 239000007789 gas Substances 0.000 claims abstract description 294
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 35
- 239000001257 hydrogen Substances 0.000 claims abstract description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
- 230000003197 catalytic effect Effects 0.000 claims abstract description 8
- 238000000926 separation method Methods 0.000 claims abstract description 3
- 238000003786 synthesis reaction Methods 0.000 claims description 57
- 230000015572 biosynthetic process Effects 0.000 claims description 54
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 19
- 230000036961 partial effect Effects 0.000 claims description 18
- 239000001569 carbon dioxide Substances 0.000 claims description 17
- 238000001816 cooling Methods 0.000 claims description 16
- 150000002431 hydrogen Chemical class 0.000 claims description 13
- 239000003245 coal Substances 0.000 claims description 11
- 238000002309 gasification Methods 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 238000002453 autothermal reforming Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 13
- 230000006835 compression Effects 0.000 abstract description 8
- 238000007906 compression Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000000047 product Substances 0.000 description 49
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
- 238000005201 scrubbing Methods 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 238000000629 steam reforming Methods 0.000 description 4
- 239000012808 vapor phase Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000005751 Copper oxide Substances 0.000 description 1
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19020337.2A EP3741738B1 (de) | 2019-05-22 | 2019-05-22 | Verfahren zur herstellung von methanol |
EP19020337.2 | 2019-05-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111978150A true CN111978150A (zh) | 2020-11-24 |
Family
ID=66646999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010418294.5A Pending CN111978150A (zh) | 2019-05-22 | 2020-05-18 | 用于生产甲醇的方法和设备 |
Country Status (3)
Country | Link |
---|---|
US (1) | US11180433B2 (de) |
EP (1) | EP3741738B1 (de) |
CN (1) | CN111978150A (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023147524A2 (en) * | 2022-01-28 | 2023-08-03 | M2X Energy, Inc. | Systems, devices and methods for rich engine control |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4464483A (en) * | 1981-06-12 | 1984-08-07 | Stamicarbon B.V. | Process for the preparation of methanol |
US5827901A (en) * | 1996-02-15 | 1998-10-27 | Metallgesellschaft Aktiengesellschaft | Process of producing methanol |
US5832747A (en) * | 1997-08-12 | 1998-11-10 | Air Products And Chemicals, Inc. | Cryogenic adjustment of hydrogen and carbon monoxide content of syngas |
DE19951137A1 (de) * | 1999-09-07 | 2001-03-15 | Krupp Uhde Gmbh | Verfahren zur Methanolsynthese aus Wasserstoff, Kohlenmonoxid und Kohlendioxid unter Druck |
WO2008079046A1 (fr) * | 2006-12-27 | 2008-07-03 | Obschestvo S Ogranichennoyi Otvetstvennosti 'est-Invest' | Procédé de production de méthanol |
CN108463450A (zh) * | 2016-01-15 | 2018-08-28 | 庄信万丰戴维科技有限公司 | 甲醇方法 |
US20190047931A1 (en) * | 2016-02-11 | 2019-02-14 | Gascontec Ag | Method for the synthesis of methanol |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69221556T2 (de) | 1991-07-09 | 1997-12-18 | Ici Plc | Synthesegaserzeugung |
DE10126719A1 (de) | 2001-05-31 | 2002-12-19 | Uhde Gmbh | Verfahren zur Methanolherstellung aus Erdgas |
DE102008049622B4 (de) | 2008-09-30 | 2012-10-31 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung von Methanol |
DE102011017300A1 (de) | 2011-04-15 | 2012-10-18 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung vom Methanol aus inertenreichem Synthesegas |
GB201600794D0 (en) * | 2016-01-15 | 2016-03-02 | Johnson Matthey Davy Technologies Ltd | Methanol process |
-
2019
- 2019-05-22 EP EP19020337.2A patent/EP3741738B1/de active Active
-
2020
- 2020-05-18 CN CN202010418294.5A patent/CN111978150A/zh active Pending
- 2020-05-22 US US16/881,149 patent/US11180433B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4464483A (en) * | 1981-06-12 | 1984-08-07 | Stamicarbon B.V. | Process for the preparation of methanol |
US5827901A (en) * | 1996-02-15 | 1998-10-27 | Metallgesellschaft Aktiengesellschaft | Process of producing methanol |
US5832747A (en) * | 1997-08-12 | 1998-11-10 | Air Products And Chemicals, Inc. | Cryogenic adjustment of hydrogen and carbon monoxide content of syngas |
DE19951137A1 (de) * | 1999-09-07 | 2001-03-15 | Krupp Uhde Gmbh | Verfahren zur Methanolsynthese aus Wasserstoff, Kohlenmonoxid und Kohlendioxid unter Druck |
WO2008079046A1 (fr) * | 2006-12-27 | 2008-07-03 | Obschestvo S Ogranichennoyi Otvetstvennosti 'est-Invest' | Procédé de production de méthanol |
CN108463450A (zh) * | 2016-01-15 | 2018-08-28 | 庄信万丰戴维科技有限公司 | 甲醇方法 |
US20190047931A1 (en) * | 2016-02-11 | 2019-02-14 | Gascontec Ag | Method for the synthesis of methanol |
Non-Patent Citations (1)
Title |
---|
许小梅: "焦炉煤气制甲醇的工艺技术研究", 《科技风》, 30 June 2013 (2013-06-30), pages 44 * |
Also Published As
Publication number | Publication date |
---|---|
US11180433B2 (en) | 2021-11-23 |
EP3741738B1 (de) | 2022-09-21 |
EP3741738A1 (de) | 2020-11-25 |
US20200369585A1 (en) | 2020-11-26 |
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PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
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