CN111957462A - Sprinkling can for generating disinfectant fluid by direct current electrolysis - Google Patents

Sprinkling can for generating disinfectant fluid by direct current electrolysis Download PDF

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Publication number
CN111957462A
CN111957462A CN202010884700.7A CN202010884700A CN111957462A CN 111957462 A CN111957462 A CN 111957462A CN 202010884700 A CN202010884700 A CN 202010884700A CN 111957462 A CN111957462 A CN 111957462A
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China
Prior art keywords
electrolysis
mesh
cavity
electrolytic
direct current
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CN202010884700.7A
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Chinese (zh)
Inventor
郑德谋
徐道华
郑沁
施传忆
徐开钦
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Fujian Ospring Technology Development Co Ltd
Fuzhou Ospring Science and Technology Co Ltd
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Fuzhou Ospring Science and Technology Co Ltd
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Priority to CN202010884700.7A priority Critical patent/CN111957462A/en
Publication of CN111957462A publication Critical patent/CN111957462A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1042Components or details
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46157Perforated or foraminous electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46185Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4616Power supply
    • C02F2201/4617DC only

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention provides a sprinkling can for generating disinfectant fluid by direct current electrolysis, wherein a spraying nozzle, an electric water pump, a handheld switch, a pressure release valve and an electric control unit are arranged in a handheld part of the sprinkling can; the electric control unit comprises a direct-current power supply, a circuit board and a display screen, and is also electrically connected with the micro electrolysis cavity, the electric water pump and the hand-held switch; the kettle cavity of the watering can is communicated with the micro electrolysis cavity; the upper part of the miniature electrolytic cavity is provided with a substrate, the substrate is connected with a bottom plate with a water permeable hole through a buckle to form the electrolytic cavity, and an electrode plate array is arranged in the miniature electrolytic cavity; the electrode plate array is connected with a low-voltage direct-current power supply to form a direct-current electrolysis device; when producing sterilized water, the direct current electrolysis device carries out low-voltage electrolysis treatment on saline water to generate a sodium hypochlorite solution which can be used for sterilization operation, and the pH value of the liquid environment of the miniature electrolysis cavity is kept in a slightly alkaline state; the invention can prepare the domestic disinfectant fluid by a diaphragm-free brine electrolysis method and can be used for domestic sanitation and disinfection.

Description

Sprinkling can for generating disinfectant fluid by direct current electrolysis
Technical Field
The invention relates to the technical field of sanitary equipment, in particular to a watering can for generating sterilized water through direct current electrolysis.
Background
The electrolysis watering can electrolyzes water in the watering can through the electrodes to obtain electrolytic liquid (the electrolytic liquid has certain disinfection and sterilization effects), and the electrolyte in the watering can is conveyed and sprayed out through the pump body in the watering can, so that the disinfection and sterilization of a target object are realized. Taking the use of the electrode for electrolyzing the salt solution as an example, sodium hydroxide, hypochlorous acid and sodium hypochlorite can be generated in the salt solution after the electrolysis of the electrode, the manufactured chlorine-containing disinfectant solution is widely applied to the disinfection and sterilization of living goods and public environments, and can also remove pesticide remained on the surfaces of vegetables and fruits, and the chlorine-containing disinfectant solution prepared by electrolyzing the salt solution can be easily volatilized after being sprayed on the surfaces of the living goods and the ground, has no residue, and cannot cause any damage to the environment and human bodies; meanwhile, the water solution mainly containing sodium hypochlorite prepared by electrolyzing saline solution has better sterilization and disinfection effects when being applied to public places, and contributes to epidemic prevention and control.
The most important component in the electrolytic watering can is the electrolytic device, the technical core of the electrolytic salt solution generating device lies in the manufacturing technology of the electrolytic electrode, and because the diaphragm type electrolytic salt solution generates sodium hypochlorite and hypochlorous acid with strong oxidizing property, and the overpotential of the positive electrode is very high in the process of electrolyzing the salt solution, the electrode of the electrolytic salt solution must be made of a material with good conductivity, oxidation resistance, low overpotential of oxygen and no reaction with the sodium hypochlorite. At present, few materials capable of meeting the requirements of the electrodes of the electrolytic salt solution water simultaneously cause that the electrodes used at present for the electrolytic salt solution are basically coated with rare metals on the surfaces, the materials commonly used for manufacturing the positive and negative electrodes of the electrolytic salt solution mainly comprise metals such as titanium, platinum, iridium, ruthenium and the like and coatings thereof, and the commonly used titanium alloy is plated with platinum on the surface, or the titanium alloy is coated with iridium, ruthenium alloy, graphite plates and the like on the surface. Wherein, the platinum, iridium and ruthenium alloy materials belong to rare metals, and have high price, which causes the high cost of the electrode. On the other hand, the use environment, the electrolysis process, the structural design, the installation mode and the like of the electrolysis electrode have important influences on the useful function, the electrolysis efficiency and the conversion performance of the electrolysis electrode.
The problems affect the household popularization of the electrolytic watering can and need to be solved.
Disclosure of Invention
The invention provides a sprinkling can for generating disinfectant fluid by direct current electrolysis, which can be used for preparing household disinfectant fluid by a diaphragm-free brine electrolysis method and can be used for household sanitation disinfection.
The invention adopts the following technical scheme.
A spray can for generating disinfectant water by direct current electrolysis is characterized in that a spray nozzle, an electric water pump, a handheld switch, a pressure release valve and an electric control unit are arranged in a handheld part above the spray can; the electric control unit comprises a direct-current power supply, a circuit board and a display screen, and is also electrically connected with the micro electrolysis cavity, the electric water pump and the hand-held switch; the kettle cavity of the watering can main body can be used for storing raw materials and products of sterilized water, and the kettle cavity is communicated with the miniature electrolysis cavity arranged below; the upper part of the micro electrolytic cavity is provided with a substrate, the substrate is connected with a bottom plate with water permeable holes through a buckle to form the electrolytic cavity, and an electrode plate array consisting of mesh anodes and mesh cathodes which are arranged at intervals and fixedly is arranged in the micro electrolytic cavity; the electrode plate array is connected with a low-voltage direct-current power supply to form a direct-current electrolysis device; when producing the sterilized water, the direct current electrolytic device of the watering can carries out low-voltage electrolytic treatment on the saline water to generate a sodium hypochlorite solution which can be used for sterilization operation, and the pH value of the liquid environment of the miniature electrolytic cavity is kept in a slightly alkaline state.
The base plate and the bottom plate on the upper part of the miniature electrolytic cavity are connected into a whole through a buckle, a first lower cover lug arranged on the bottom plate is pressed on the concave convex column of the base plate, a second lower cover lug is pressed on the anode at the welding column of the base plate so as to assist the firmness and stability of the electrolytic cavity, and water permeable holes communicated with the kettle cavity are arranged at the bottom plate and the side wall of the miniature electrolytic cavity.
The electrode plate array comprises a titanium-based ruthenium-iridium plated mesh anode and a titanium-based ruthenium-iridium plated mesh cathode, wherein the two mesh electrodes are sheet electrodes and are respectively arranged on the concave convex columns below the substrate and the clamping grooves combined with the concave convex columns; part of the combined concave-convex column is connected with a water suction port of the electric water pump, and the other cylinder body is provided with a clamping groove which is used for separating the mesh electrodes;
the low-voltage electrolysis treatment of the brine is diaphragm-free electrolysis treatment, when the low-voltage electrolysis treatment is carried out, the electrode plate array is immersed in the brine, so that the brine is simultaneously contacted with the surfaces of the two electrified reticular electrodes, a water body can freely flow between the upper reticular electrode and the lower reticular electrode, and the meshes of the cathode reticular electrode arranged on the upper layer are larger than those of the anode reticular electrode, so that the generated hydrogen can rapidly escape; the interval range of the mesh anode and the mesh cathode is 0.5 mm-2.5 mm.
The mesh anode and the mesh cathode are respectively provided with an electric conduction part and a mesh-shaped electrolysis part connected with the electric conduction part; the low-voltage direct current power supply outputs direct current with the voltage range of 1V-24V, leads respectively penetrate through high and low welding columns arranged on the substrate to be welded with the conductance parts of the mesh anode and the mesh cathode to supply power, and waterproof glue covers the connection point for protection.
The substrate at the upper part of the micro electrolytic cavity is a transparent V-shaped substrate; a lighting device is arranged in the micro electrolytic cavity; an illuminating device is arranged in the upper part of the V-shaped substrate; when low-pressure electrolytic treatment is carried out, bubbles such as hydrogen and the like generated in brine in the micro electrolytic cavity can smoothly bypass the edge of the V-shaped substrate and rise to the pressure release valve above the V-shaped substrate to be discharged; bubbles such as hydrogen generated by electrolysis can refract or reflect light of the lighting device to form a remarkable visual effect to indicate that the saline solution electrolysis operation is currently carried out.
When the direct current electrolysis device finishes electrolysis treatment on the brine in the micro electrolysis cavity, the liquid environment of the micro electrolysis cavity is a liquid environment with the pH value range of 8-10.
The saline water in the kettle cavity is saline water with the initial concentration not lower than 10 g/L; a timer capable of timing the low-voltage electrolysis time is arranged at the sprinkling can, the frequency of the electrolysis treatment is every 3 minutes/time, and the electrolysis times are specifically determined according to the required concentration of the disinfectant.
The sodium hypochlorite solution generated in the micro electrolytic cavity can be sucked by a controlled electric water pump on the sprinkling can through a water suction port on the substrate in the electrolytic cavity and is sprayed and disinfected through a spraying port; or opening the sprinkling can, and pouring out sodium hypochlorite solution for cleaning, soaking and other disinfection modes.
The low voltage DC power supply includes a rechargeable battery; the electric water pump and the direct current electrolysis device are both powered by a low-voltage direct current power supply.
When the mesh anode and the mesh cathode are large-area soft mesh electrodes, the preparation method of the electrode slice array comprises the following steps:
step A1, distributing and attaching a mesh anode and a mesh cathode on two sides of a fork-shaped separation sheet, so that the distance between the mesh anode and the mesh cathode meets the requirement of an interval range;
a2, selecting a plurality of supporting positions on the surface of the mesh electrode, dripping non-conductive glue solution at the forked gaps of the forked separation sheets through the mesh surfaces of the mesh anode and the mesh cathode to enable the glue solution to form glue solution drops for connecting the mesh anode and the mesh cathode, standing to enable the glue solution to solidify, and forming insulating glue particles for locking the positions of the mesh anode and the mesh cathode and enabling the distance between the mesh anode and the mesh cathode to be fixed at the supporting positions;
and step A3, taking out the fork-shaped separation sheets to finish the preparation of the electrode plate array, wherein the prepared electrode plate array can be connected with a lead by using a copper nose workpiece and locked and fixed.
The invention has the beneficial effects that:
the sodium hypochlorite disinfectant is prepared by adopting the diaphragm-free direct current electrolysis salt water electrolysis technology, the liquid can meet the national standard requirement in a slightly alkaline operation range, and the electrode material can adapt to a more appropriate anti-corrosion environment, so that the corrosivity of the solution in the electrolysis process is greatly reduced, and the reliable waterproof glue seal design is adopted for the part of the power supply circuit in water, thereby reducing the corrosive loss of the electrode and the power supply circuit, and prolonging the service life of the product.
The electrolysis equipment has the advantages of simplified structure and powerful function, saves more labor and materials compared with the similar devices in the prior art, thereby greatly reducing the cost and improving the use stability of the product.
The invention can be used for spray disinfection, and can pour out the disinfectant for cleaning and soaking, thereby enlarging the application range of epidemic prevention and expansion and enlarging the product application for the post epidemic situation era.
Drawings
The invention is described in further detail below with reference to the following figures and detailed description:
FIG. 1 is a schematic of the present invention;
FIG. 2 is an enlarged schematic view of the micro electrolytic chamber of the present invention;
FIG. 3 is an enlarged schematic view of the electrical lead of the electrode of the present invention (taking the electrical connection of the anode as an example);
FIG. 4 is a schematic bottom view of an electrode sheet array according to the present invention;
FIG. 5 is a schematic bottom view of a micro electrolytic chamber according to the present invention
In the figure: 1-a spray nozzle; 2-an electric water pump; 3-pot cavity; 4-a lighting device; 5-a substrate; 6-micro electrolytic chamber; 7-electrode slice array; 8-mesh anodes; 9-mesh cathode; 10-water inlet pipe of water pump; 11-a direct current power supply; 12-a wire; 13-water permeable holes; 14-an electrical lead; 15-waterproof glue; 16-electrode surface; 17-a base plate; 18-insulating colloidal particles;
300-welding a column; 400-concave convex column.
Detailed Description
As shown in fig. 1-5, a spray can for generating sterilized water by direct current electrolysis, wherein a spray nozzle 1, an electric water pump 2, a hand-held switch, a pressure release valve and an electric control unit are arranged in a hand-held part above the spray can; the electric control unit comprises a direct current power supply 11, a circuit board and a display screen, and is also electrically connected with the micro electrolysis cavity 6, the electric water pump and the hand-held switch; the kettle cavity 3 of the watering can main body can be used for storing raw materials and products of sterilized water, and is communicated with the miniature electrolysis cavity 6 arranged below; the upper part of the micro electrolytic cavity is provided with a substrate 5, the substrate is connected with a bottom plate 17 with water permeable holes through a buckle to form the electrolytic cavity, and an electrode plate array 7 consisting of mesh anodes 8 and mesh cathodes 9 which are arranged at intervals and fixedly is arranged in the micro electrolytic cavity; the electrode plate array is connected with a low-voltage direct-current power supply to form a direct-current electrolysis device; when producing the sterilized water, the direct current electrolytic device of the watering can carries out low-voltage electrolytic treatment on the saline water to generate a sodium hypochlorite solution which can be used for sterilization operation, and the pH value of the liquid environment of the miniature electrolytic cavity is kept in a slightly alkaline state.
The base plate on the upper part of the miniature electrolytic cavity is connected with the bottom plate 17 into a whole through a buckle, a first lower cover lug arranged on the bottom plate is pressed on the concave-convex column 400 of the base plate, a second lower cover lug is pressed on the anode at the welding column of the base plate so as to assist the firmness and stability of the electrolytic cavity, and the bottom plate 17 and the side wall of the miniature electrolytic cavity are provided with water permeable holes 13 communicated with the kettle cavity.
The electrode plate array comprises a titanium-based ruthenium-iridium plated mesh anode and a titanium-based ruthenium-iridium plated mesh cathode, wherein the two mesh electrodes are sheet electrodes and are respectively arranged on the concave convex columns below the substrate and the clamping grooves combined with the concave convex columns; part of the combined concave-convex column is connected with a water suction port of the electric water pump, and the other cylinder body is provided with a clamping groove which is used for separating the mesh electrodes;
the low-voltage electrolysis treatment of the brine is diaphragm-free electrolysis treatment, when the low-voltage electrolysis treatment is carried out, the electrode plate array is immersed in the brine, so that the brine is simultaneously contacted with the surfaces 16 of the two electrified reticular electrodes, a water body can freely flow between the upper reticular electrode and the lower reticular electrode, and the meshes of the cathode reticular electrode arranged on the upper layer are larger than those of the anode reticular electrode, so that the generated hydrogen can rapidly escape; the interval range of the mesh anode and the mesh cathode is 0.5 mm-2.5 mm.
The mesh anode and the mesh cathode are respectively provided with an electric conduction part 14 and a mesh-shaped electrolysis part connected with the electric conduction part; the low-voltage direct current power supply outputs direct current with the voltage range of 1V-24V, leads respectively penetrate through high and low welding columns 300 arranged on the substrate to be welded with the conductance parts of the mesh anode and the mesh cathode to supply power, and waterproof glue 15 covers the connection point for protection.
The substrate at the upper part of the micro electrolytic cavity is a transparent V-shaped substrate; a lighting device is arranged in the micro electrolytic cavity; an illuminating device 4 is arranged in the upper part of the V-shaped substrate; when low-pressure electrolytic treatment is carried out, bubbles such as hydrogen and the like generated in brine in the micro electrolytic cavity can smoothly bypass the edge of the V-shaped substrate and rise to the pressure release valve above the V-shaped substrate to be discharged; bubbles such as hydrogen generated by electrolysis can refract or reflect light of the lighting device to form a remarkable visual effect to indicate that the saline solution electrolysis operation is currently carried out.
When the direct current electrolysis device finishes electrolysis treatment on the brine in the micro electrolysis cavity, the liquid environment of the micro electrolysis cavity is a liquid environment with the pH value range of 8-10.
The saline water in the kettle cavity is saline water with the initial concentration not lower than 10 g/L; a timer capable of timing the low-voltage electrolysis time is arranged at the sprinkling can, the frequency of the electrolysis treatment is every 3 minutes/time, and the electrolysis times are specifically determined according to the required concentration of the disinfectant.
The sodium hypochlorite solution generated in the micro electrolytic cavity can be sucked by a controlled electric water pump on the sprinkling can through a water suction port on the substrate in the electrolytic cavity and is sprayed and disinfected through a spraying port; or opening the sprinkling can, and pouring out sodium hypochlorite solution for cleaning, soaking and other disinfection modes.
The low voltage DC power supply includes a rechargeable battery; the electric water pump and the direct current electrolysis device are both powered by a low-voltage direct current power supply.
When the mesh anode and the mesh cathode are large-area soft mesh electrodes, the preparation method of the electrode slice array comprises the following steps:
step A1, distributing and attaching a mesh anode and a mesh cathode on two sides of a fork-shaped separation sheet, so that the distance between the mesh anode and the mesh cathode meets the requirement of an interval range;
step A2, selecting a plurality of supporting positions on the surface of the mesh electrode, dripping non-conductive glue solution at the forked gaps of the forked separation sheets through the mesh surfaces of the mesh anode and the mesh cathode to enable the glue solution to form glue solution drops for connecting the mesh anode and the mesh cathode, standing to enable the glue solution to solidify, and forming insulating colloidal particles 18 for locking the positions of the mesh anode and the mesh cathode and enabling the distance between the mesh anode and the mesh cathode to be fixed at the supporting positions;
and step A3, taking out the fork-shaped separation sheets to finish the preparation of the electrode plate array, wherein the prepared electrode plate array can be connected with a lead by using a copper nose workpiece and locked and fixed.
Example (b):
in this case, the sprinkling can prepares the sterilized water with the saline concentration of not less than 5%, and the user can increase the saline concentration if the user needs to prepare the sterilized water with high concentration.
Firstly, injecting saline water with preset weight into a sprinkling can to enable the saline water to be completely immersed in a miniature electrolysis cavity at the bottom of the kettle, then starting a power supply of the sprinkling can to electrolyze the saline water in the miniature electrolysis cavity, generating a sodium hypochlorite solution in the miniature electrolysis cavity in the electrolysis process, releasing the generated sodium hypochlorite solution into the saline water in the kettle cavity through a water permeable hole, enabling the saline water to have the disinfection and sterilization capacity, and sending a prompt tone by a timer of the sprinkling can after the electrolysis duration reaches a preset value.
During the electrolysis process, the generated hydrogen bubbles rise from the mesh electrode, and the bubbles are refracted under the irradiation of light rays of the lighting device to form a remarkable visual effect, which indicates that the electrolysis is currently performed.
In this example, the mesh electrodes are fixed on the concave-convex columns on the substrates at intervals, so that the concave-convex columns on one of the substrates are separated from the water suction pipe; the connecting part of the electrode plate is welded with a lead which penetrates through the substrate welding column; the welding point is surrounded and sealed by epoxy resistance glue, so that current and voltage are directly and safely transmitted to the electrode plate through a lead; the base plate is connected with a bottom plate (lower cover) through a buckle, and the lower cover is simultaneously contacted and protected with the electrode slice.
In the electrolytic process, because the device is a diaphragm-free electrolytic device, the electrolytic products of the cathode and anode mesh electrode plates are recombined after being generated, so that the main components in the solution mainly comprise sodium hypochlorite and hydrogen (continuously escaping), the electrolytic device is always immersed in the solution for keeping the pH value of the solution to be 8-10, the corrosion loss of the electrolytic device is reduced, and the service life of the product is prolonged.

Claims (10)

1. A watering can for generating sterilized water by direct current electrolysis is characterized in that: a spray nozzle, an electric water pump, a handheld switch, a pressure release valve and an electric control unit are arranged in the handheld part above the sprinkling can; the electric control unit comprises a direct-current power supply, a circuit board and a display screen, and is also electrically connected with the micro electrolysis cavity, the electric water pump and the hand-held switch; the kettle cavity of the watering can main body can be used for storing raw materials and products of sterilized water, and the kettle cavity is communicated with the miniature electrolysis cavity arranged below; the upper part of the micro electrolytic cavity is provided with a substrate, the substrate is connected with a bottom plate with water permeable holes through a buckle to form the electrolytic cavity, and an electrode plate array consisting of mesh anodes and mesh cathodes which are arranged at intervals and fixedly is arranged in the micro electrolytic cavity; the electrode plate array is connected with a low-voltage direct-current power supply to form a direct-current electrolysis device; when producing the sterilized water, the direct current electrolytic device of the watering can carries out low-voltage electrolytic treatment on the saline water to generate a sodium hypochlorite solution which can be used for sterilization operation, and the pH value of the liquid environment of the miniature electrolytic cavity is kept in a slightly alkaline state.
2. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the base plate and the bottom plate on the upper part of the miniature electrolytic cavity are connected into a whole through a buckle, a first lower cover lug arranged on the bottom plate is pressed on the concave convex column of the base plate, a second lower cover lug is pressed on the anode at the welding column of the base plate so as to assist the firmness and stability of the electrolytic cavity, and water permeable holes communicated with the kettle cavity are arranged at the bottom plate and the side wall of the miniature electrolytic cavity.
3. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the electrode plate array comprises a titanium-based ruthenium-iridium plated mesh anode and a titanium-based ruthenium-iridium plated mesh cathode, wherein the two mesh electrodes are sheet electrodes and are respectively arranged on the concave convex columns below the substrate and the clamping grooves combined with the concave convex columns; and part of the combined concave-convex column is connected with a water suction port of the electric water pump, and the other column body is provided with a clamping groove which is used for separating the mesh electrodes.
4. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the low-voltage electrolysis treatment of the brine is diaphragm-free electrolysis treatment, when the low-voltage electrolysis treatment is carried out, the electrode plate array is immersed in the brine, so that the brine is simultaneously contacted with the surfaces of the two electrified reticular electrodes, a water body can freely flow between the upper reticular electrode and the lower reticular electrode, and the meshes of the cathode reticular electrode arranged on the upper layer are larger than those of the anode reticular electrode, so that the generated hydrogen can rapidly escape; the interval range of the mesh anode and the mesh cathode is 0.5 mm-2.5 mm.
5. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the mesh anode and the mesh cathode are respectively provided with an electric conduction part and a mesh-shaped electrolysis part connected with the electric conduction part; the low-voltage direct current power supply outputs direct current with the voltage range of 1V-24V, leads respectively penetrate through high and low welding columns arranged on the substrate to be welded with the conductance parts of the mesh anode and the mesh cathode to supply power, and waterproof glue covers the connection point for protection.
6. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the substrate at the upper part of the micro electrolytic cavity is a transparent V-shaped substrate; a lighting device is arranged in the micro electrolytic cavity; an illuminating device is arranged in the upper part of the V-shaped substrate; when low-pressure electrolytic treatment is carried out, bubbles such as hydrogen and the like generated in brine in the micro electrolytic cavity can smoothly bypass the edge of the V-shaped substrate and rise to the pressure release valve above the V-shaped substrate to be discharged; bubbles such as hydrogen generated by electrolysis can refract or reflect light of the lighting device to form a remarkable visual effect to indicate that the saline solution electrolysis operation is currently carried out.
7. A watering can for direct current electrolysis for producing sterilized water according to claims 1 and 6, wherein: when the direct current electrolysis device finishes electrolysis treatment on the brine in the micro electrolysis cavity, the liquid environment of the micro electrolysis cavity is a liquid environment with the pH value range of 8-10.
8. A watering can for direct current electrolytic generation of sterilizing water according to claim 1, wherein: the saline water in the kettle cavity is saline water with the initial concentration not lower than 10 g/L; a timer capable of timing the low-voltage electrolysis time is arranged at the sprinkling can, the frequency of the electrolysis treatment is every 3 minutes/time, and the electrolysis times are specifically determined according to the required concentration of the disinfectant.
9. A watering can for direct current electrolysis for producing sterilized water according to claims 1 and 8, wherein: the sodium hypochlorite solution generated in the micro electrolytic cavity can be sucked by a controlled electric water pump on the sprinkling can through a water suction port on the substrate in the electrolytic cavity and is sprayed and disinfected through a spraying port; or opening the sprinkling can, pouring out the sodium hypochlorite solution from the sprinkling can for cleaning or soaking;
the low voltage DC power supply includes a rechargeable battery; the electric water pump and the direct current electrolysis device are both powered by a low-voltage direct current power supply.
10. A watering can for direct current electrolytic generation of sterilised water according to claim 4, characterised in that: when the mesh anode and the mesh cathode are large-area soft mesh electrodes, the preparation method of the electrode slice array comprises the following steps:
step A1, distributing and attaching a mesh anode and a mesh cathode on two sides of a fork-shaped separation sheet, so that the distance between the mesh anode and the mesh cathode meets the requirement of an interval range;
a2, selecting a plurality of supporting positions on the surface of the mesh electrode, dripping non-conductive glue solution at the forked gaps of the forked separation sheets through the mesh surfaces of the mesh anode and the mesh cathode to enable the glue solution to form glue solution drops for connecting the mesh anode and the mesh cathode, standing to enable the glue solution to solidify, and forming insulating glue particles for locking the positions of the mesh anode and the mesh cathode and enabling the distance between the mesh anode and the mesh cathode to be fixed at the supporting positions;
and step A3, taking out the fork-shaped separation sheets to finish the preparation of the electrode plate array, wherein the prepared electrode plate array can be connected with a lead by using a copper nose workpiece and locked and fixed.
CN202010884700.7A 2020-08-28 2020-08-28 Sprinkling can for generating disinfectant fluid by direct current electrolysis Pending CN111957462A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010884700.7A CN111957462A (en) 2020-08-28 2020-08-28 Sprinkling can for generating disinfectant fluid by direct current electrolysis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010884700.7A CN111957462A (en) 2020-08-28 2020-08-28 Sprinkling can for generating disinfectant fluid by direct current electrolysis

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Publication Number Publication Date
CN111957462A true CN111957462A (en) 2020-11-20

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CN202010884700.7A Pending CN111957462A (en) 2020-08-28 2020-08-28 Sprinkling can for generating disinfectant fluid by direct current electrolysis

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Country Link
CN (1) CN111957462A (en)

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