CN111937880A - Cotton defoliating agent - Google Patents

Cotton defoliating agent Download PDF

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Publication number
CN111937880A
CN111937880A CN202010827711.1A CN202010827711A CN111937880A CN 111937880 A CN111937880 A CN 111937880A CN 202010827711 A CN202010827711 A CN 202010827711A CN 111937880 A CN111937880 A CN 111937880A
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parts
cotton
agent
defoliating
fomesafen
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CN202010827711.1A
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CN111937880B (en
Inventor
孙杰
刘峰
张新宇
薛飞
李艳军
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Shihezi University
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Shihezi University
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/06Sulfonic acid amides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a cotton defoliating agent. Belongs to the technical field of pesticides. The defoliant comprises the following components in parts by weight: 20-30 parts of cyclopropylamide, 30-50 parts of fomesafen, 10-15 parts of glyphosine and 10-15 parts of sodium bicarbonate. Compared with the prior art, the invention has the following beneficial effects: the composition has a synergistic effect, and the defoliating effect is far better than that of a component used alone; the defoliation of cotton can be promoted, the boll opening of cotton can be accelerated, the yield of cotton can be improved, and the quality of cotton is not influenced; the good activity and defoliation effect can be still kept in the environment of lower than 20 ℃; the dosage is less, and the environment is not polluted.

Description

Cotton defoliating agent
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a cotton defoliant.
Background
Cotton is an important economic crop, can be made into fabrics of various specifications, can also be used for extracting edible oil, and plays an important role in the agricultural and economic pattern of China. But in recent years, the economic benefit of cotton is obviously reduced due to shortage of labor resources and large rise of labor cost. In order to reduce the cost and improve the cotton planting benefit, the realization of fully-mechanized cotton picking is the inevitable choice for the development of the cotton industry. Defoliation and ripening are important prerequisites for mechanical cotton picking. The defoliation and ripening method mainly adopts a plant growth regulator to intervene in the physiological and biochemical processes of cotton, accelerate the plant aging and realize defoliation.
Currently, the common cotton defoliants include thidiazuron and ethephon. The principle of the Thidiazuron defoliation is that after the Thidiazuron defoliation is absorbed by plants, abscisic acid and ethylene can be generated by the cotton plants, so that a separation layer is formed between a leaf stalk and the cotton plants, and cotton leaves automatically shed. However, thidiazuron has high cost, slow defoliation speed and poor low temperature resistance. Ethephon has good ripening effect, but has poor defoliation effect, thereby influencing the influence of mechanical harvesting on the quality of cotton.
In conclusion, the problem to be solved by the technical personnel in the field is how to provide a cotton defoliating agent with low temperature resistance and good defoliating effect.
Disclosure of Invention
In view of the above, the present invention provides a cotton defoliating agent.
In order to achieve the purpose, the invention adopts the following technical scheme:
a cotton defoliating agent comprises the following components in parts by weight: 20-30 parts of cyclopropylamide, 30-50 parts of fomesafen, 10-15 parts of glyphosine and 10-15 parts of sodium bicarbonate.
The cyclopropyl propionamide is an important plant growth regulator containing a cyclopropane structure, and can promote cotton seed flowering and leaf dropping and inhibit leaf dropping regeneration in a cotton maturation period. In addition, the cyclopropanamide is added into the defoliating agent, so that the use temperature of the defoliating agent can be effectively reduced, and the defoliating agent can still keep good activity and defoliating effect in the environment with the daily average temperature of lower than 20 ℃. The defoliating agent can prolong the functional period and boll development period of cotton leaves and promote the effective development of bolls.
Fomesafen is a herbicide for treating stems and leaves, can prevent and kill annual and perennial broadleaf weeds, and has the action mechanism of destroying the photosynthesis of plants, leading the leaves to yellow and wither rapidly. The drug effect is rapid and the precipitation does not influence the drug effect.
The glyphosine has the function of accelerating the ripening of plants, belongs to a medicament capable of stimulating the plants to generate ethylene, inhibits the growth of the plants by being absorbed by the leaf surfaces of the plants, also inhibits the activity of acid invertase, can delay the growth of the crops, reduces the respiration consumption and increases the sugar accumulation. The compound is used together with fomesafen, and has obvious synergistic effect on defoliation and ripening of cotton.
The leaf blade reduces the respiration, transpiration and photosynthesis of the leaf blade under the saline-alkali stress action of sodium bicarbonate, the growth of the leaf blade is hindered, the leaf blade enters the aging period in advance to be yellow, and the growth of cotton plants is not affected after the sodium bicarbonate is applied.
Preferably, the cotton defoliating agent comprises the following components in parts by weight: 10-25 parts of cyclopropylamide, 35-45 parts of fomesafen, 10-12 parts of glyphosine and 10-12 parts of sodium bicarbonate.
Preferably, the cotton defoliating agent comprises the following components in parts by weight: 25 parts of cyclopropylamide, 38 parts of fomesafen, 12 parts of glyphosine and 10 parts of sodium bicarbonate.
Preferably, one or more of a wetting agent, a dispersing agent and an emulsifying agent is also included.
Preferably, the humectant is glycerin or dimethyl sulfoxide.
The wetting agent is a surfactant, and is composed of hydrophilic group and lipophilic group, when the wetting agent is contacted with solid surface, the lipophilic group is attached to the solid surface, and the hydrophilic group is extended outwards into the liquid, so that the liquid can form continuous phase on the solid surface. When the pesticide is a hydrophobic solid powder, the surface of the pesticide is not easily wetted by water, and is difficult to dissolve in water to sink and agglomerate. If a wetting agent is added, the wetting molecules are directionally arranged on the surface of the solid, so that the surface energy of water is reduced, water can wet the solid, and solid powder is dispersed in the water to form a stable suspension. In addition, if wax is present on the plant leaves, the liquid medicine is not wetted after being sprayed, and becomes spherical and falls off. In order to spread the liquid medicine on the plant leaves to exert its effect sufficiently with good wetting property, a wetting agent is added.
Preferably, the dispersant is sodium dodecyl sulfate.
The action mechanism of the dispersant is as follows: (1) the adsorption on the surface of solid particles reduces the interfacial tension between liquid and liquid or between solid and liquid. The surface of the condensed solid particles is easy to wet; (2) the surface of the solid ion forms a bilayer structure, the polar end of the outer dispersant has stronger affinity with water, the degree of wetting the solid particles by water is increased, and the solid particles are far away from each other due to electrostatic repulsion; (3) the system is uniform, and the suspension performance is improved.
Preferably, the emulsifier is Tween 80 or NP-10.
The emulsifier forms a firm emulsion film to form a stable emulsion by reducing the interfacial free energy, and the droplet particles form a sphere to keep the minimum surface area by reducing the interfacial free energy.
Preferably, the dosage form of the cotton defoliating agent is suspension.
The suspending agent has the advantages of both wettable powder and missible oil, can be wetted by water, has better suspension property after being diluted by water, and can be directly sprayed with liquid.
According to the technical scheme, compared with the prior art, the invention has the following beneficial effects: (1) the composition has a synergistic effect, and the defoliating effect is far better than that of a component used alone; (2) the defoliation of cotton can be promoted, the boll opening of cotton can be accelerated, the yield of cotton can be improved, and the quality of cotton is not influenced; (3) the good activity and defoliation effect can be still kept in the environment of lower than 20 ℃; (4) the dosage is less, and the environment is not polluted.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The required medicament is a conventional experimental medicament purchased from a market channel; the unrecited experimental method is a conventional experimental method, and is not described in detail herein.
Example 1
The defoliating agent formula (in parts by mass) comprises:
20 parts of cyclopropylamide, 30 parts of fomesafen, 10 parts of glyphosine and 10 parts of sodium bicarbonate.
Example 2
The defoliating agent formula (in parts by mass) comprises:
30 parts of cyclopropylamide, 50 parts of fomesafen, 15 parts of glyphosine and 15 parts of sodium bicarbonate.
Example 3
The defoliating agent formula (in parts by mass) comprises:
10 parts of cyclopropylamide, 35 parts of fomesafen, 10 parts of glyphosine and 10 parts of sodium bicarbonate.
Example 4
The defoliating agent formula (in parts by mass) comprises:
25 parts of cyclopropylamide, 45 parts of fomesafen, 12 parts of glyphosine and 12 parts of sodium bicarbonate.
Example 5
The defoliating agent formula (in parts by mass) comprises:
25 parts of cyclopropylamide, 38 parts of fomesafen, 12 parts of glyphosine and 10 parts of sodium bicarbonate.
Example 6
The formula of the defoliating agent comprises:
fomesafen.
Example 7
The formula of the defoliating agent comprises:
and (3) glyphosine.
Example 8
The formula of the defoliating agent comprises:
sodium bicarbonate.
Example 9
The defoliating agent formula (in parts by mass) comprises:
25 parts of cyclopropylamide, 38 parts of fomesafen, 12 parts of ethephon and 10 parts of sodium bicarbonate.
Example 10
The defoliating agent formula (in parts by mass) comprises:
38 parts of fomesafen, 12 parts of glyphosine and 10 parts of sodium bicarbonate.
Example 11
The defoliating agent formula (in parts by mass) comprises:
38 parts of fomesafen and 12 parts of glyphosine.
Example 12
The defoliating agent formula (in parts by mass) comprises:
38 parts of fomesafen and 10 parts of sodium bicarbonate.
Example 13
The defoliating agent formula (in parts by mass) comprises:
20 parts of cyclopropylamide, 30 parts of fomesafen, 10 parts of glyphosine, 10 parts of sodium bicarbonate, 3 parts of glycerol and 2 parts of sodium dodecyl sulfate.
Example 14
The defoliating agent formula (in parts by mass) comprises:
20 parts of cyclopropylamide, 30 parts of fomesafen, 10 parts of glyphosine, 10 parts of sodium bicarbonate, 5 parts of dimethyl sulfoxide and 803 parts of tween.
Example 15
The defoliating agent formula (in parts by mass) comprises:
20 parts of cyclopropylamide, 30 parts of fomesafen, 10 parts of glyphosine, 10 parts of sodium bicarbonate and NP-101.
Experiment 1
(1) Test subjects: the cotton defoliants of examples 1-12 were tested.
(2) Measurement indexes are as follows: defoliation rate, boll opening rate and fiber length.
(3) Cotton variety: middle cotton plant 50.
(4) The process is as follows:
the planting density is 8 ten thousand plants per hectare, and the growth vigor of the cotton during the test period is the same as that of field management. The defoliating agent is applied in the cotton boll opening period, and the application amount is 450 kg/hectare.
After the application of the pesticide, the temperature is recorded, the total number of leaves and bolls of the cotton are investigated 14 days after the application of the pesticide, the defoliation rate and the boll opening rate are calculated, and the cotton is harvested 30 days after the application of the pesticide, and the length of cotton fibers is measured.
The defoliation rate is (total number of leaves of the plant before application-number of leaves remained in the plant during investigation)/total number of leaves of the plant before application multiplied by 100%
The boll opening rate is equal to the number of bolls opening/total bolls multiplied by 100 percent
(5) As a result:
the change in air temperature after application is shown in Table 1.
TABLE 1 air temperature Change after application of the drug
1d 2d 3d 4d 5d 6d 7d
Maximum air temperature (. degree. C.) 22 23 21 20 19 24 25
Minimum air temperature (. degree. C.) 10 9 11 8 5 13 12
Average air temperature (. degree. C.) 16 16 14 12 10 17 17
TABLE 1 continuation of the table
Figure BDA0002636832190000061
Figure BDA0002636832190000071
The results of the measurements of the defoliation rate, the opening rate and the fiber length are shown in Table 2.
TABLE 2 defoliation, boll opening, fiber length results
Defoliation Rate (%) Boll opening ratio (%) Fiber length (mm)
Example 1 95.8 79.4 28.1
Example 2 94.6 81.3 29.4
Example 3 95.0 78.6 28.5
Example 4 93.1 77.4 27.9
Example 5 96.4 80.7 30.1
Example 6 31.2 54.3 24.2
Example 7 22.8 46.7 25.3
Example 8 17.6 48.2 25.7
Example 9 79.4 70.4 27.3
Example 10 68.7 75.3 27.1
Example 11 50.4 68.3 26.7
Example 12 42.9 64.1 24.3
As can be seen from the results in Table 2, (1) the defoliating effect of the compounded defoliant of the invention is far better than that of the defoliant using a single component; (2) in the application process, the average temperature is below 20 ℃, so that the effect of the defoliant can be influenced without applying cyclopropylamide.
The embodiments in the present description are described in a progressive manner, each embodiment focuses on differences from other embodiments, and the same and similar parts among the embodiments are referred to each other.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (8)

1. The cotton defoliant is characterized by comprising the following components in parts by mass: 20-30 parts of cyclopropylamide, 30-50 parts of fomesafen, 10-15 parts of glyphosine and 10-15 parts of sodium bicarbonate.
2. The cotton defoliant according to claim 1, comprising the following components in parts by mass: 10-25 parts of cyclopropylamide, 35-45 parts of fomesafen, 10-12 parts of glyphosine and 10-12 parts of sodium bicarbonate.
3. The cotton defoliant according to claim 1, comprising the following components in parts by mass: 25 parts of cyclopropylamide, 38 parts of fomesafen, 12 parts of glyphosine and 10 parts of sodium bicarbonate.
4. The cotton defoliating agent of claim 1, further comprising one or more of a wetting agent, a dispersing agent, and an emulsifying agent.
5. The cotton defoliating agent of claim 4, wherein said humectant is glycerin or dimethyl sulfoxide.
6. The cotton defoliant according to claim 4, wherein said dispersing agent is sodium dodecyl sulfate.
7. The cotton defoliating agent according to claim 4, wherein said emulsifier is Tween 80 or NP-10.
8. The cotton defoliant according to any one of claims 1 to 7, wherein the formulation of said cotton defoliant is a suspension.
CN202010827711.1A 2020-08-17 2020-08-17 Cotton defoliating agent Expired - Fee Related CN111937880B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112450223A (en) * 2020-11-25 2021-03-09 中国农业科学院棉花研究所 Cotton defoliating agent additive and preparation and use methods thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110250195A (en) * 2019-05-08 2019-09-20 江苏省农业科学院 A kind of composition for disleave, cotton defoliant and preparation method thereof
CN110463717A (en) * 2019-09-02 2019-11-19 中国农业科学院棉花研究所 Cotton defoliation ripening composition and cotton defoliation ripening agent
CN111264550A (en) * 2020-03-30 2020-06-12 中国农业科学院棉花研究所 Cotton defoliating agent composition and application thereof
CN111374141A (en) * 2020-03-30 2020-07-07 中国农业科学院棉花研究所 Pesticide composition for defoliation and ripening of cotton and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110250195A (en) * 2019-05-08 2019-09-20 江苏省农业科学院 A kind of composition for disleave, cotton defoliant and preparation method thereof
CN110463717A (en) * 2019-09-02 2019-11-19 中国农业科学院棉花研究所 Cotton defoliation ripening composition and cotton defoliation ripening agent
CN111264550A (en) * 2020-03-30 2020-06-12 中国农业科学院棉花研究所 Cotton defoliating agent composition and application thereof
CN111374141A (en) * 2020-03-30 2020-07-07 中国农业科学院棉花研究所 Pesticide composition for defoliation and ripening of cotton and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112450223A (en) * 2020-11-25 2021-03-09 中国农业科学院棉花研究所 Cotton defoliating agent additive and preparation and use methods thereof
CN112450223B (en) * 2020-11-25 2021-06-29 中国农业科学院棉花研究所 Cotton defoliating agent additive and preparation and use methods thereof

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