CN111921345A - Deuterium gas generator heavy water recovery device - Google Patents
Deuterium gas generator heavy water recovery device Download PDFInfo
- Publication number
- CN111921345A CN111921345A CN202010828705.8A CN202010828705A CN111921345A CN 111921345 A CN111921345 A CN 111921345A CN 202010828705 A CN202010828705 A CN 202010828705A CN 111921345 A CN111921345 A CN 111921345A
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- heavy water
- metal
- clamping plate
- gas generator
- diaphragm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention relates to a deuterium gas generator heavy water recovery device which comprises a diaphragm component, a three-dimensional metal screen plate, an upper metal clamping plate and a lower metal clamping plate which are connected with each other, wherein accommodating cavities and through holes communicated with the accommodating cavities are formed in the metal clamping plate and the lower metal clamping plate, and the diaphragm component and the three-dimensional metal screen plate are arranged in the accommodating cavities of the upper metal clamping plate and the lower metal clamping plate. The invention well prevents deuterium from mixing into an oxygen system by selecting the permeable and gas-barrier diaphragm, ensures that heavy water condensed from deuterium returns to a circulating system in time, and ensures that the function of the diaphragm is normally played by the support and the clamping of the metal powder sintering plate and the three-dimensional metal screen plate. Finally, the recovery of expensive heavy water materials is realized, and the production cost is greatly saved.
Description
Technical Field
The invention relates to a reflux device for recovering condensed heavy water in deuterium gas by a deuterium gas generator system, in particular to a heavy water recovery device for a deuterium gas generator.
Background
The existing heavy water electrolysis deuterium production equipment adopts a filter-pressing type structure, then a circulating pump is used for forcibly circulating electrolyte on an anode side and a cathode side to take away heat and bubbles generated by electrolysis, and the electrolytic cell structure is called as a double-circulation structure. In order to increase the purity of deuterium gas and reduce the influence of impurities in the electrolyte, an electrolytic cell structure has been developed in which the electrolyte is circulated only on the anode side by increasing the gas pressure on the cathode side, and this electrolytic cell structure is called a single-cycle structure. No matter single-cycle or double-cycle structure electrolytic cells, the gas electrolyzed from the electrolytic cells carries a large amount of heavy water vapor, and the heavy water vapor is condensed into heavy water after passing through a condenser. For the double-circulation structure, in order to avoid wasting expensive heavy water, only the heavy water condensed by the deuterium gas and oxygen condenser is required to flow back to respective phase separators; for the single-cycle structure, the deuterium pipeline cannot be connected to the oxygen-side phase separator in single-side cycle, so that the heavy water condensed from the deuterium is prevented from being wasted due to mixed explosion of the deuterium and the oxygen.
Disclosure of Invention
The deuterium generator heavy water recovery device can save cost, prevent expensive heavy water from being wasted, and not only can return heavy water condensed in deuterium gas to electrolyte at a circulating side, but also can prevent deuterium gas from being mixed into an oxygen side system.
The technical scheme provided by the invention for solving the technical problems is as follows: deuterium gas generator heavy water recovery unit, including diaphragm subassembly, three-dimensional metal mesh board and interconnect's last metal splint, lower metal splint, all be equipped with on metal splint, the lower metal splint and hold the chamber and with hold the communicating through-hole in chamber, diaphragm subassembly, three-dimensional metal mesh board are installed the intracavity is held to last metal splint, lower metal splint.
The diaphragm assembly comprises an upper diaphragm clamping plate, a lower diaphragm clamping plate and a water-permeable and gas-barrier diaphragm clamped between the upper diaphragm clamping plate and the lower diaphragm clamping plate.
The further technical scheme is that the upper diaphragm clamping plate and the lower diaphragm clamping plate are both alkali-resistant metal powder sintered plates.
The further technical scheme is that the porosity of the alkali-resistant metal powder sintered plate is 30-40%.
The further technical scheme is that the aperture ratio of the three-dimensional metal mesh plate is 60-80%.
The further technical scheme is that an O-shaped ring is arranged between the upper metal clamping plate and the lower metal clamping plate.
The invention has the following advantages: the invention well prevents deuterium from mixing into an oxygen system by selecting the permeable and gas-barrier diaphragm, ensures that heavy water condensed from deuterium returns to a circulating system in time, and ensures that the function of the diaphragm is normally played by the support and the clamping of the metal powder sintering plate and the three-dimensional metal screen plate. Finally, the recovery of expensive heavy water materials is realized, and the production cost is greatly saved.
Drawings
Fig. 1 is a schematic diagram of an explosive structure of the present invention.
Detailed Description
The present invention will be further described with reference to the following examples and the accompanying drawings.
As shown in fig. 1, the deuterium gas generator heavy water recovery device of the present invention comprises a diaphragm assembly, a three-dimensional metal mesh plate 5, and an upper metal splint 1 and a lower metal splint 2 which are connected with each other, wherein both the metal splint 1 and the lower metal splint 2 are provided with an accommodating cavity 3 and a through hole 4 communicated with the accommodating cavity 3, the diaphragm assembly and the three-dimensional metal mesh plate are installed in the accommodating cavity 3 of the upper metal splint 1 and the lower metal splint 2, and the diaphragm assembly comprises an upper diaphragm splint 6, a lower diaphragm splint 7, and a water and gas permeable and gas barrier diaphragm 8 sandwiched between the upper diaphragm splint 6 and the lower diaphragm splint 7.
In the embodiment, the invention selects the water-permeable gas-barrier diaphragm 8 with water-permeable and gas-barrier characteristics as the separation interface of deuterium and oxygen systems, and the deuterium gas transmission capacity is lower than 300cc/m2H/atm, heavy water permeability not less than 800g/m2/h/atm。
In this embodiment, the upper diaphragm clamping plate 6 and the lower diaphragm clamping plate 7 are both alkali-resistant metal powder sintered plates with a porosity of 30-40%. So that the support membrane remains flat and unfolded.
In this embodiment, the aperture ratio of the three-dimensional metal mesh plate is 60 to 80%; to keep the heavy water dispersed flowing.
As shown in fig. 1, in order to improve the sealing effect of the present embodiment, it is preferable that an O-ring 9 is provided between the upper metal clamping plate 1 and the lower metal clamping plate 2.
Although the present invention has been described with reference to the above embodiments, it should be understood that the present invention is not limited to the above embodiments, and those skilled in the art can make various changes and modifications without departing from the scope of the present invention.
Claims (6)
1. Deuterium gas generator heavy water recovery unit, its characterized in that includes diaphragm subassembly, three-dimensional metal otter board (5) and interconnect's last metal splint (1), lower metal splint (2), all be equipped with on metal splint (1), lower metal splint (2) and hold chamber (3) and with hold communicating through-hole (4) in chamber (3), diaphragm subassembly, three-dimensional metal otter board are installed in holding chamber (3) of last metal splint (1), lower metal splint (2).
2. Deuterium gas generator heavy water recovery device according to claim 1, characterized in that the membrane assembly comprises an upper membrane clamp plate (6), a lower membrane clamp plate (7) and a water and gas permeable barrier membrane (8) sandwiched between the upper and lower membrane clamp plates (6, 7).
3. Deuterium gas generator heavy water recovery device according to claim 2, characterized in that both the upper diaphragm clamping plate (6) and the lower diaphragm clamping plate (7) are alkali-resistant metal powder sintered plates.
4. Deuterium gas generator heavy water recovery device according to claim 3, characterized in that said alkali resistant metal powder sintered plate has a porosity of 30-40%.
5. The deuterium gas generator heavy water recovery device according to claim 1, wherein the aperture ratio of said solid metal mesh plate is 60-80%.
6. Deuterium gas generator heavy water recovery device according to claim 1, characterized in that an O-ring (9) is provided between the upper metal clamping plate (1) and the lower metal clamping plate (2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010828705.8A CN111921345A (en) | 2020-08-18 | 2020-08-18 | Deuterium gas generator heavy water recovery device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010828705.8A CN111921345A (en) | 2020-08-18 | 2020-08-18 | Deuterium gas generator heavy water recovery device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111921345A true CN111921345A (en) | 2020-11-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010828705.8A Pending CN111921345A (en) | 2020-08-18 | 2020-08-18 | Deuterium gas generator heavy water recovery device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111921345A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023026721A1 (en) * | 2021-08-25 | 2023-03-02 | 大陽日酸株式会社 | Deuterium recovery method and deuterium recovery equipment |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1107034A (en) * | 1977-03-29 | 1981-08-18 | Yuji Naruse | Process for removing tritium from tritium-containing heavy water to recover tritium gas of high purity |
| CN202237447U (en) * | 2011-07-20 | 2012-05-30 | 中国科学院广州地球化学研究所 | Flat plate filter |
| CN105776438A (en) * | 2016-02-04 | 2016-07-20 | 福建方明环保科技股份有限公司 | Device and method for reducing content of deuterium in water |
| CN208250427U (en) * | 2018-05-21 | 2018-12-18 | 江苏皇冠鸟生物科技股份有限公司 | A kind of low deuterium-oxide production equipment |
| CN109680286A (en) * | 2019-02-28 | 2019-04-26 | 王丽琴 | A kind of device and method for producing deuterium |
| CN208893990U (en) * | 2018-07-05 | 2019-05-24 | 王梁 | A kind of device of semi-transparent bipolar membrane electrodialysis separation of deuterium |
-
2020
- 2020-08-18 CN CN202010828705.8A patent/CN111921345A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1107034A (en) * | 1977-03-29 | 1981-08-18 | Yuji Naruse | Process for removing tritium from tritium-containing heavy water to recover tritium gas of high purity |
| CN202237447U (en) * | 2011-07-20 | 2012-05-30 | 中国科学院广州地球化学研究所 | Flat plate filter |
| CN105776438A (en) * | 2016-02-04 | 2016-07-20 | 福建方明环保科技股份有限公司 | Device and method for reducing content of deuterium in water |
| CN208250427U (en) * | 2018-05-21 | 2018-12-18 | 江苏皇冠鸟生物科技股份有限公司 | A kind of low deuterium-oxide production equipment |
| CN208893990U (en) * | 2018-07-05 | 2019-05-24 | 王梁 | A kind of device of semi-transparent bipolar membrane electrodialysis separation of deuterium |
| CN109680286A (en) * | 2019-02-28 | 2019-04-26 | 王丽琴 | A kind of device and method for producing deuterium |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023026721A1 (en) * | 2021-08-25 | 2023-03-02 | 大陽日酸株式会社 | Deuterium recovery method and deuterium recovery equipment |
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Application publication date: 20201113 |