CN111847373A - Support hole structure of infrared MEMS and forming method - Google Patents
Support hole structure of infrared MEMS and forming method Download PDFInfo
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- CN111847373A CN111847373A CN202010756191.XA CN202010756191A CN111847373A CN 111847373 A CN111847373 A CN 111847373A CN 202010756191 A CN202010756191 A CN 202010756191A CN 111847373 A CN111847373 A CN 111847373A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B1/00—Devices without movable or flexible elements, e.g. microcapillary devices
- B81B1/002—Holes characterised by their shape, in either longitudinal or sectional plane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B3/00—Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
- B81B3/0064—Constitution or structural means for improving or controlling the physical properties of a device
- B81B3/0086—Electrical characteristics, e.g. reducing driving voltage, improving resistance to peak voltage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00023—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
- B81C1/00087—Holes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00134—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems comprising flexible or deformable structures
- B81C1/00142—Bridges
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
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Abstract
The invention discloses a supporting hole structure of an infrared MEMS and a forming method thereof, wherein the supporting hole structure is in a groove shape on a semiconductor substrate, and a plurality of film layers cover the side wall and the bottom in the groove; the structure includes: a semiconductor substrate; a metal reflective layer formed over the semiconductor substrate; a dielectric layer; a release layer, and a first release protection layer for release protection; the photosensitive layer is formed on the first release protective layer; a metal electrode layer formed on the photosensitive layer; the support hole metal film layer is formed in the support hole and is positioned on the metal electrode layer; the DARC layer is formed on the metal electrode layer and the support hole metal film layer; a second release protection layer formed over the DARC layer. The invention adds a layer of support hole metal aluminum film layer to the support hole under the condition of not changing the structure of the induction layer, and prevents the open circuit at the bottom of the support hole by utilizing the fluidity of the metal aluminum.
Description
Technical Field
The invention relates to the field of semiconductor device manufacturing, in particular to a support hole structure capable of effectively supporting an MEMS hollowed infrared MEMS in an MEMS product bridge structure, and the problem of metal open circuit at the bottom of the support hole structure can be effectively solved.
The invention also relates to a forming method of the supporting hole structure of the infrared MEMS.
Background
Micro-Electro-Mechanical systems (MEMS), also called Micro-electromechanical systems, microsystems, micromachines, etc., refer to high-tech devices with dimensions of several millimeters or even smaller, whose internal structure is generally in the micrometer or even nanometer level, and which are independent intelligent systems. The device mainly comprises a sensor, an actuator and a micro-energy source. The micro electro mechanical system relates to various subjects and engineering technologies such as physics, semiconductor, optics, electronic engineering, chemistry, material engineering, mechanical engineering, medicine, information engineering, biological engineering and the like, and develops wide application in the fields of synthetic biology, microfluidic technology and the like of intelligent systems, consumer electronics, wearable equipment, smart homes, system biotechnology and the like. Common products include MEMS accelerometers, MEMS microphones, micro-motors, micro-pumps, micro-vibrators, MEMS pressure sensors, MEMS gyroscopes, MEMS humidity sensors, and the like, as well as integrated products thereof.
MEMS have several basic features: miniaturization, intellectualization, multifunction, high integration and suitability for mass production. The goal of MEMS technology is to explore elements and systems with new principles and new functions through the miniaturization and integration of systems. MEMS technology is a typical multidisciplinary, cross-sectional, frontline research area that focuses on ultra-precision machining, involving almost all areas of nature and engineering sciences, such as electronics, mechanics, physics, chemistry, biomedicine, materials science, energy science, and the like. The research content can be generally summarized into the following three basic aspects: 1. theoretical basis: under the scale which can be achieved by the current MEMS, the basic physical laws of the macroscopic world still play a role, but due to the influence (Scaling Effects) caused by size reduction, a plurality of physical phenomena are greatly different from the macroscopic world, so that a plurality of original theoretical bases can be changed, such as force size effect, micro-structural surface effect, micro-friction mechanism and the like, and therefore deep research on micro-dynamics, micro-fluid mechanics, micro-thermodynamics, micro-tribology, micro-optics and micro-mechanics is necessary. Although the research on the aspect is regarded as important, the difficulty is high, and basic research is often required for multi-disciplinary students. 2. Research on technical basis: the method mainly comprises the technical basic researches of micro-mechanical design, micro-mechanical materials, micro-machining, micro-assembly and packaging, integration technology, micro-measurement and the like. 3. The application of micromachines in various disciplines is studied.
The micro electro mechanical system is developed on the basis of microelectronic technology (semiconductor manufacturing technology), and integrates high-tech electronic mechanical devices manufactured by technologies such as photoetching, corrosion, thin film, LIGA, silicon micromachining, non-silicon micromachining, precision machining and the like.
Amorphous silicon is an allotrope form of silicon that can be deposited in thin film form on a variety of substrates to provide certain unique functions for a variety of electronic applications. Amorphous silicon is useful in mass-produced microelectromechanical systems (MEMS) and nanoelectromechanical systems (NEMS), solar cells, microcrystalline and micro amorphous silicon, and even for roll-on-roll processing techniques on a variety of substrates. Conventional mems devices rely more on typical materials used in silicon-based circuit fabrication, such as single crystal silicon, polysilicon, silicon oxide and silicon nitride. Due to the mechanical nature of MEMS devices, material properties like young's modulus, coefficient of thermal expansion and yield strength are very important for MEMS design. There are often unsupported (or overhanging) elements in the MEMS structure, and therefore tight control is required for the stress and stress gradient in the membrane, otherwise the unsupported elements will crack or curl, rendering the structure ineffective. Fig. 1 is a schematic diagram of a conventional infrared MEMS bridge column structure, which includes a support hole structure, and a bridge warpage caused by stress release of the bridge structure affects subsequent packaging tests.
The existing process comprises the following steps as shown in figures 4-5:
forming a metal reflecting layer on a semiconductor substrate, and depositing and patterning a sacrificial layer after patterning;
step two, a protective layer and a photosensitive layer are integrally deposited;
step three, patterning the photosensitive layer;
fourthly, imaging the membrane layer of the support hole area outside the bridge column;
step five, integrally depositing to form a metal electrode film;
sixthly, integrally depositing and forming a DARC film (Dielectric Anti-reflection coating, DARC) and patterning;
step seven, etching the metal electrode film layer;
depositing a protective layer film, and imaging the bridge column structure area;
and step nine, patterning the contact PAD area.
After the support hole is etched, the side surface of the metal at the bottom of the support hole is easily corroded in the wet cleaning process to cause the electrode open circuit phenomenon.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a supporting hole structure of an infrared MEMS and a forming method thereof, which mainly improve the structural design of the supporting hole and avoid the bottom of the supporting hole from being broken.
In order to solve the problems, the supporting hole structure of the infrared MEMS is in a groove shape on a semiconductor substrate, and a plurality of film layers cover the side wall and the bottom in the groove; support pore structure from supreme including in proper order down:
a semiconductor substrate;
a metal reflective layer formed over the semiconductor substrate;
a dielectric layer;
a release layer, and a first release protection layer for release protection; the release layer and the first release protective layer are formed on the dielectric layer;
a photosensitive layer formed on the first release protection layer;
a metal electrode layer formed on the photosensitive layer;
a support hole metal film layer; the support hole metal film layer is formed in the support hole and is positioned on the metal electrode layer;
the DARC layer is formed on the metal electrode layer and the support hole metal film layer;
a second release protection layer formed over the DARC layer.
The further improvement is that the bridge column structure is provided with an MEMS structure formed by other various film layers in the region outside the bridge column structure, and the layers outside the bridge column structure region comprise a substrate, a metal reflecting layer, a dielectric layer, a release layer, a first release protective layer, a photosensitive sensitive layer, a metal electrode, a DARC layer and a second release protective layer;
the first release protective layer is deposited on the release layer and is positioned on the dielectric layer;
the photosensitive sensitive layer is deposited on the first release protective layer;
the DARC layer is deposited on the metal electrode;
the second release protection layer is deposited over the DARC layer.
In a further improvement, the semiconductor substrate is a silicon substrate and is a circuit substrate for reading infrared sensing signals.
The further improvement is that the metal reflecting layer is a metal film with high reflectivity, and the material is gold, silver, aluminum or copper, or a mixture of several materials.
The further improvement is that the dielectric layer, the first release protection layer and the DARC layer are all electric insulation layers made of one or more of silicon dioxide, silicon nitride, silicon oxynitride and silicon carbide; or one or more of silicon nitride and silicon oxynitride with non-stoichiometric ratio; the silicon carbide may replace silicon oxide.
In a further improvement, the photosensitive layer is an infrared absorbing amorphous silicon material.
The further improvement is that the metal electrode layer is made of a metal film with a Ti/TiN structure.
The further improvement is that the support hole metal film layer is made of aluminum.
In order to solve the above problems, the present invention provides a method for forming a support hole structure of an infrared MEMS, the method comprising:
forming a metal reflecting layer on a semiconductor substrate, and depositing and patterning a sacrificial layer after patterning;
step two, integrally depositing a first release protective layer and a photosensitive layer;
step three, patterning the photosensitive layer;
fourthly, imaging the membrane layer of the support hole area outside the bridge column;
step five, integrally depositing to form a metal electrode layer;
step six, integrally depositing a support hole metal film layer;
seventhly, etching and patterning the support hole metal film layer;
step eight, DARC film layer electrode is etched and patterned;
step nine, etching the metal electrode layer;
step ten, depositing a second release protection layer and etching and patterning;
and step eleven, patterning the contact PAD area.
In a further improvement, the semiconductor substrate is a circuit substrate for reading infrared sensing signals.
In a further improvement, the semiconductor substrate is a silicon substrate.
The further improvement is that the first release protection layer is a silicon oxide layer, the metal layer is a Ti/TiN layer, and the second release protection layer is a composite layer formed by a mixed layer of silicon oxynitride and silicon oxide, a silicon oxide layer, a silicon oxynitride layer and a silicon oxide layer.
According to the support hole structure of the infrared MEMS and the forming method thereof, after the support hole is etched, in the wet cleaning process, aiming at the electrode open circuit phenomenon caused by the side surface corrosion of the metal at the bottom of the support hole, under the condition that the structure of the induction layer is not changed, the support hole is modified, a support hole metal aluminum film layer is added, and the open circuit at the bottom of the support hole is prevented by utilizing the fluidity of metal aluminum, so that the defects are prevented.
Drawings
Fig. 1 is a schematic view of a general infrared MENS structure, including a support hole and a bridge post structure.
FIG. 2 is a schematic view of an infrared MEMS bridge post structure provided by the present invention, including a support hole of a metal film.
Fig. 3 is an enlarged view of the support hole illustrated in fig. 2.
FIGS. 4-5 are schematic diagrams of steps of a fabrication process of an infrared MEMS structure in the prior art.
Fig. 6 is a schematic diagram of steps of a process for fabricating an infrared MEMS structure according to the present invention (following the process shown in fig. 4, i.e., the same process flow shown in fig. 4 exists in the process of the present invention and the prior art process, and fig. 5 and 6 are different portions of the prior art process from the process of the present invention).
Description of the reference numerals
1 is a substrate, 2 is a photosensitive layer, 3 is a metal electrode layer, 4 is a first release protect layer, 5 is a second release protect layer, 6 is a support hole metal layer, 7 is a metal reflective layer, 8 is a release layer, and 9 is a DARC layer.
Detailed Description
The supporting hole structure of the infrared MEMS bridge column is mainly improved aiming at a supporting hole film layer of the MEMS structure bridge column, and due to the fact that in the prior art, after the supporting hole is etched, the phenomenon of electrode open circuit caused by side surface corrosion of metal at the bottom of the supporting hole exists in the wet cleaning process.
As shown in fig. 1, the cross-sectional view of an infrared MEMS structure includes a supporting hole structure, a bridge post structure and a film structure outside the bridge post region, wherein the supporting holes are located at two ends, and the MEMS structure is located between the two supporting holes.
Fig. 2 is a cross-sectional view of an infrared MEMS bridge-column structure provided by the present invention, which further includes an MEMS structure formed by other various film layers in an area outside the bridge-column structure, and the layers outside the bridge-column structure area include a substrate, a metal reflective layer, a dielectric layer, a release layer, a first release protection layer, a photosensitive layer, a metal electrode, a DARC layer, and a second release protection layer.
For the supporting hole part, mainly refer to the enlarged partial view of the supporting hole as shown in fig. 3, the whole supporting hole is in a groove shape and comprises a plurality of different film layers which are overlapped, and the structure in fig. 3 comprises:
the semiconductor device comprises a semiconductor substrate 1, a first substrate, a second substrate and a third substrate, wherein the semiconductor substrate is a circuit substrate for reading infrared sensing signals, and is generally a silicon substrate;
a metal reflective layer 7 formed over the semiconductor substrate; the metal reflecting layer is a high-reflectivity metal film made of gold, silver, aluminum or copper or a mixture of several materials.
A dielectric layer (not shown);
a release layer 8, and a first release protective layer 4 for release protection; the release layer 8 and the first release protection layer 4 are formed on the dielectric layer;
the photosensitive layer 2 is an infrared absorption amorphous silicon material, and the photosensitive layer 2 is formed on the first release protection layer 4;
the metal electrode layer 3 is formed on the photosensitive layer 2, and is made of a metal film with a Ti/TiN structure;
a support hole metal film layer 6; the support hole metal film layer 6 is formed in the support hole and positioned on the metal electrode layer, the metal film layer 6 is made of aluminum, and the invention prevents the open circuit of the bottom of the support hole by utilizing the fluidity of the metal aluminum.
A DARC layer 9, wherein the DARC layer 9 is formed on the metal electrode layer 3 and the support hole metal film layer 6;
a second release protection layer 5 formed over the DARC layer.
The dielectric layer, the first release protection layer and the DARC layer are all electric insulation layers and are made of one or more of silicon dioxide, silicon nitride, silicon oxynitride and silicon carbide; or one or more of silicon nitride and silicon oxynitride with non-stoichiometric ratio; the silicon carbide may replace silicon oxide.
In order to solve the above problems, the present invention provides a method for forming a support hole structure of an infrared MEMS, the method comprising, in combination with fig. 4 and 6:
step one, forming a metal reflecting layer on a semiconductor substrate such as a silicon substrate, and depositing and patterning a sacrificial layer after patterning;
step two, integrally depositing a first release protective layer, such as a silicon oxide layer, and then depositing a photosensitive layer;
step three, patterning the photosensitive layer;
fourthly, imaging the membrane layer of the support hole area outside the bridge column;
step five, integrally depositing to form a metal electrode layer, wherein the metal electrode layer is a Ti/TiN layer;
step six, integrally depositing a support hole metal film layer;
seventhly, etching and patterning the support hole metal film layer;
step eight, DARC film layer electrode is etched and patterned;
step nine, etching the metal electrode layer;
step ten, depositing a second release protection layer and etching and patterning; the second release protection layer is a composite layer formed by a mixed layer of silicon oxynitride and silicon oxide, a silicon oxide layer, a silicon oxynitride layer and a silicon oxide layer;
and step eleven, patterning the contact PAD area.
The structure of the bridge column (comprising the supporting hole) of the infrared MEMS is formed through the process.
The above are merely preferred embodiments of the present invention, and are not intended to limit the present invention. Various modifications and alterations to this invention will become apparent to those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (12)
1. The utility model provides an infrared MEMS's support pore structure which characterized in that: the supporting hole structure is in a groove shape on the semiconductor substrate, and a plurality of film layers cover the side wall and the bottom in the groove; support pore structure from supreme including in proper order down:
a semiconductor substrate;
a metal reflective layer formed over the semiconductor substrate;
a dielectric layer;
a release layer, and a first release protection layer for release protection; the release layer and the first release protective layer are formed on the dielectric layer;
a photosensitive layer formed on the first release protection layer;
a metal electrode layer formed on the photosensitive layer;
a support hole metal film layer; the support hole metal film layer is formed in the support hole and is positioned on the metal electrode layer;
the DARC layer is formed on the metal electrode layer and the support hole metal film layer;
a second release protection layer formed over the DARC layer.
2. The support hole structure of infrared MEMS of claim 1, wherein: the MEMS structure formed by other various film layers is arranged in the area outside the bridge column structure, and the layers outside the bridge column structure area comprise a substrate, a metal reflecting layer, a dielectric layer, a release layer, a first release protective layer, a photosensitive sensitive layer, a metal electrode, a DARC layer and a second release protective layer;
the first release protective layer is deposited on the release layer and is positioned on the dielectric layer;
the photosensitive sensitive layer is deposited on the first release protective layer;
the DARC layer is deposited on the metal electrode;
the second release protection layer is deposited over the DARC layer.
3. The support hole structure of infrared MEMS of claim 1, wherein: the semiconductor substrate is a silicon substrate and is a circuit substrate for reading infrared sensing signals.
4. The support hole structure of infrared MEMS of claim 1, wherein: the metal reflecting layer is a high-reflectivity metal film made of gold, silver, aluminum or copper or a mixture of several materials.
5. The support hole structure of infrared MEMS of claim 1, wherein: the dielectric layer, the first release protection layer and the DARC layer are all electric insulation layers and are made of one or more of silicon dioxide, silicon nitride, silicon oxynitride and silicon carbide; or one or more of silicon nitride and silicon oxynitride with non-stoichiometric ratio; the silicon carbide may replace silicon oxide.
6. The support hole structure of infrared MEMS of claim 1, wherein: the photosensitive layer is an infrared absorption amorphous silicon material.
7. The support hole structure of infrared MEMS of claim 1, wherein: the metal electrode layer is made of a metal film with a Ti/TiN structure.
8. The support hole structure of infrared MEMS of claim 1, wherein: the support hole metal film layer is made of aluminum.
9. A forming method of a supporting hole structure of an infrared MEMS is characterized in that: the method comprises the following steps:
forming a metal reflecting layer on a semiconductor substrate, and depositing and patterning a sacrificial layer after patterning;
step two, integrally depositing a first release protective layer and a photosensitive layer;
step three, patterning the photosensitive layer;
fourthly, imaging the membrane layer of the support hole area outside the bridge column;
step five, integrally depositing to form a metal electrode layer;
step six, integrally depositing a support hole metal film layer;
seventhly, etching and patterning the support hole metal film layer;
step eight, DARC film layer electrode is etched and patterned;
step nine, etching the metal electrode layer;
step ten, depositing a second release protection layer and etching and patterning;
and step eleven, patterning the contact PAD area.
10. The method of claim 9, wherein: the semiconductor substrate is a circuit substrate for reading infrared sensing signals.
11. The method of claim 10, wherein: the semiconductor substrate is a silicon substrate.
12. The method of claim 9, wherein: the first release protection layer is a silicon oxide layer, the metal layer is a Ti/TiN layer, and the second release protection layer is a mixed layer of silicon oxynitride and silicon oxide, a silicon oxide layer, a silicon oxynitride layer and a composite layer formed by the silicon oxide layer.
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