CN111825949A - High-performance FRP container floor and manufacturing method thereof - Google Patents
High-performance FRP container floor and manufacturing method thereof Download PDFInfo
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- CN111825949A CN111825949A CN202010697502.XA CN202010697502A CN111825949A CN 111825949 A CN111825949 A CN 111825949A CN 202010697502 A CN202010697502 A CN 202010697502A CN 111825949 A CN111825949 A CN 111825949A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 17
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 11
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 11
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005751 Copper oxide Substances 0.000 claims abstract description 11
- 239000010425 asbestos Substances 0.000 claims abstract description 11
- 239000004917 carbon fiber Substances 0.000 claims abstract description 11
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 11
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 11
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 11
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 11
- 239000012745 toughening agent Substances 0.000 claims abstract description 11
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims description 24
- 238000003754 machining Methods 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 5
- 238000005498 polishing Methods 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005007 epoxy-phenolic resin Substances 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims 1
- 230000000712 assembly Effects 0.000 abstract description 6
- 238000000429 assembly Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 230000000704 physical effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Moulding By Coating Moulds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-performance FRP container floor which is characterized by comprising the following components in parts by weight: 90-100 parts of base material, 30-55 parts of glass fiber, 3-5 parts of aluminum oxide, 3-5 parts of asbestos powder, 1-3 parts of polyvinyl chloride, 3-8 parts of polytetrafluoroethylene, 5-10 parts of carbon fiber, 1-3 parts of copper oxide, 2-5 parts of chlorinated polyethylene, 5-8 parts of emulsifier, 6-8 parts of curing agent, 3-6 parts of toughening agent and 1-3 parts of release agent, compared with the prior art, the material is easy to obtain, the production cost can be effectively saved, the manufacturing process is simple, and the production and the processing are convenient; by manufacturing longer assemblies, the application range of the assemblies is conveniently improved; by adding the additive, the fire resistance and corrosion resistance can be effectively improved, and the plasticity can be increased.
Description
Technical Field
The invention relates to the field of manufacturing of container floors, in particular to a high-performance FRP container floor and a manufacturing method thereof.
Background
The container floor needs to have good physical properties and chemical properties, and current container floor is generally wooden, and chemical properties such as waterproof, fire prevention, corrosion resistance are all not good, in the transportation, cause certain loss easily, and physical properties such as crushing resistance, intensity are also not strong moreover, and the container floor that makes needs to be changed after using a period of time, has increased manufacturing cost.
Disclosure of Invention
In order to solve the defects of the prior art, the invention aims to provide a high-performance FRP container floor with easily available materials and good performance and a manufacturing method thereof
In order to achieve the above object, the present invention adopts the following technical solutions:
the high-performance FRP container floor is characterized by comprising the following components in parts by weight: 90-100 parts of base material, 30-55 parts of glass fiber, 3-5 parts of aluminum oxide, 3-5 parts of asbestos powder, 1-3 parts of polyvinyl chloride, 3-8 parts of polytetrafluoroethylene, 5-10 parts of carbon fiber, 1-3 parts of copper oxide, 2-5 parts of chlorinated polyethylene, 5-8 parts of emulsifier, 6-8 parts of curing agent, 3-6 parts of toughening agent and 1-3 parts of release agent.
Preferably, the base material is an epoxy resin or a phenol resin.
1. A method for manufacturing a floor for a container, comprising the steps of:
s1: manufacturing a mould, namely uniformly dividing the container bottom plate into components capable of being spliced, and manufacturing a component mould;
s2: blending raw materials, namely mixing glass fiber into a base material, uniformly stirring, adding aluminum oxide, asbestos powder and polyvinyl chloride, fully stirring again, then adding polytetrafluoroethylene, carbon fiber and copper oxide, fully stirring again, finally adding chlorinated polyethylene, an emulsifier, a curing agent, a toughening agent and a release agent, and fully stirring to obtain a raw material;
s3: manufacturing a component, pouring the raw materials into a mold for cooling and molding, opening the mold after cooling, and taking out the component;
s4: performing finish machining on the assembly;
s5: pre-assembling the assembly after finish machining, and modifying and adjusting according to actual details;
s6: the required splicing assembly is selected according to the specific container size.
Preferably, in step S1, when the mold is manufactured, the length of the module mold is greater than that of the container, so as to meet the requirements of different containers.
Still preferably, in the step S2, the temperature of the raw materials is 230 ℃ to 300 ℃ during the mixing process, so as to prevent the solidification of the raw materials.
More preferably, in the aforementioned step S4, the finishing includes deburring, polishing, surface treatment, and machining a necessary hole or groove by machining.
Further preferably, in step S6, after the components are selected, the components are cut to a length corresponding to the length of the container, and then assembled.
The invention has the advantages that: the material is easy to obtain, the production cost can be effectively saved, the manufacturing process is simple, and the production and the processing are convenient; by manufacturing longer assemblies, the application range of the assemblies is conveniently improved; by adding the additive, the fire resistance and corrosion resistance can be effectively improved, and the plasticity can be increased.
Detailed Description
The following specific examples are intended to illustrate the invention.
The first embodiment is as follows: the high-performance FRP container floor is characterized by comprising the following components in parts by weight: 90 parts of base material, wherein the base material is epoxy resin or phenolic resin, 30 parts of glass fiber, 3 parts of aluminum oxide, 3 parts of asbestos powder, 1 part of polyvinyl chloride, 3 parts of polytetrafluoroethylene, 5 parts of carbon fiber, 1 part of copper oxide, 2 parts of chlorinated polyethylene, 5 parts of emulsifier, 6 parts of curing agent, 3 parts of toughening agent and 1 part of release agent.
A method for manufacturing a floor for a container, comprising the steps of:
s1: the method comprises the steps of manufacturing a mould, uniformly dividing a container bottom plate into components capable of being spliced, and manufacturing a component mould, wherein the length of the component mould is greater than that of a container, so that the requirement for different containers is met;
s2: mixing raw materials, namely firstly mixing glass fiber into a base material, uniformly stirring, then adding alumina, asbestos powder and polyvinyl chloride, fully stirring again, then adding polytetrafluoroethylene, carbon fiber and copper oxide, fully stirring again, finally adding chlorinated polyethylene, an emulsifier, a curing agent, a toughening agent and a release agent, and fully stirring to obtain a raw material, wherein the temperature is 230 ℃ when the raw materials are mixed, and the raw materials are prevented from being solidified;
s3: manufacturing a component, pouring the raw materials into a mold for cooling and molding, opening the mold after cooling, and taking out the component;
s4: performing finish machining on the assembly, wherein the finish machining comprises deburring, polishing, surface treatment and machining of necessary holes or grooves through mechanical machining;
s5: pre-assembling the assembly after finish machining, and modifying and adjusting according to actual details;
s6: according to the specific size of the container, the required splicing components are selected, after the components are selected, the components are cut to be long by corresponding lengths according to the length of the container, and then splicing is carried out.
Example two: the high-performance FRP container floor is characterized by comprising the following components in parts by weight: 100 parts of base material, 55 parts of glass fiber, 5 parts of aluminum oxide, 5 parts of asbestos powder, 3 parts of polyvinyl chloride, 8 parts of polytetrafluoroethylene, 10 parts of carbon fiber, 3 parts of copper oxide, 5 parts of chlorinated polyethylene, 8 parts of emulsifier, 8 parts of curing agent, 6 parts of toughening agent and 3 parts of release agent.
A method for manufacturing a floor for a container, comprising the steps of:
s1: the method comprises the steps of manufacturing a mould, uniformly dividing a container bottom plate into components capable of being spliced, and manufacturing a component mould, wherein the length of the component mould is greater than that of a container, so that the requirement for different containers is met;
s2: mixing raw materials, namely mixing glass fiber into a base material, uniformly stirring, adding aluminum oxide, asbestos powder and polyvinyl chloride, fully stirring again, then adding polytetrafluoroethylene, carbon fiber and copper oxide, fully stirring again, finally adding chlorinated polyethylene, an emulsifier, a curing agent, a toughening agent and a release agent, and fully stirring to obtain a raw material, wherein the temperature is 300 ℃ when the raw materials are mixed, and the raw materials are prevented from being solidified;
s3: manufacturing a component, pouring the raw materials into a mold for cooling and molding, opening the mold after cooling, and taking out the component;
s4: performing finish machining on the assembly, wherein the finish machining comprises deburring, polishing, surface treatment and machining of necessary holes or grooves through mechanical machining;
s5: pre-assembling the assembly after finish machining, and modifying and adjusting according to actual details;
s6: according to the specific size of the container, the required splicing components are selected, after the components are selected, the components are cut to be long by corresponding lengths according to the length of the container, and then splicing is carried out.
Example three: the high-performance FRP container floor is characterized by comprising the following components in parts by weight: 95 parts of base material, 42.5 parts of glass fiber, 4 parts of aluminum oxide, 4 parts of asbestos powder, 2 parts of polyvinyl chloride, 5.5 parts of polytetrafluoroethylene, 7.5 parts of carbon fiber, 2 parts of copper oxide, 3.5 parts of chlorinated polyethylene, 6.5 parts of emulsifier, 7 parts of curing agent, 4.5 parts of toughening agent and 4 parts of release agent.
A method for manufacturing a floor for a container, comprising the steps of:
s1: the method comprises the steps of manufacturing a mould, uniformly dividing a container bottom plate into components capable of being spliced, and manufacturing a component mould, wherein the length of the component mould is greater than that of a container, so that the requirement for different containers is met;
s2: mixing raw materials, namely mixing glass fiber into a base material, uniformly stirring, adding aluminum oxide, asbestos powder and polyvinyl chloride, fully stirring again, then adding polytetrafluoroethylene, carbon fiber and copper oxide, fully stirring again, finally adding chlorinated polyethylene, an emulsifier, a curing agent, a toughening agent and a release agent, and fully stirring to obtain a raw material, wherein the temperature is 265 ℃ to prevent the raw material from being solidified when the raw materials are mixed;
s3: manufacturing a component, pouring the raw materials into a mold for cooling and molding, opening the mold after cooling, and taking out the component;
s4: performing finish machining on the assembly, wherein the finish machining comprises deburring, polishing, surface treatment and machining of necessary holes or grooves through mechanical machining;
s5: pre-assembling the assembly after finish machining, and modifying and adjusting according to actual details;
s6: according to the specific size of the container, the required splicing components are selected, after the components are selected, the components are cut to be long by corresponding lengths according to the length of the container, and then splicing is carried out.
The invention has the advantages that: the material is easy to obtain, the production cost can be effectively saved, the manufacturing process is simple, and the production and the processing are convenient; by manufacturing longer assemblies, the application range of the assemblies is conveniently improved; by adding the additive, the fire resistance and corrosion resistance can be effectively improved, and the plasticity can be increased.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It should be understood by those skilled in the art that the above embodiments do not limit the present invention in any way, and all technical solutions obtained by using equivalent alternatives or equivalent variations fall within the scope of the present invention.
Claims (7)
1. The high-performance FRP container floor is characterized by comprising the following components in parts by weight: 90-100 parts of base material, 30-55 parts of glass fiber, 3-5 parts of aluminum oxide, 3-5 parts of asbestos powder, 1-3 parts of polyvinyl chloride, 3-8 parts of polytetrafluoroethylene, 5-10 parts of carbon fiber, 1-3 parts of copper oxide, 2-5 parts of chlorinated polyethylene, 5-8 parts of emulsifier, 6-8 parts of curing agent, 3-6 parts of toughening agent and 1-3 parts of release agent.
2. A high performance FRP container floor as claimed in claim 1, wherein said substrate is epoxy resin or phenolic resin.
3. The method for manufacturing a container floor as claimed in any one of claims 1 to 2, comprising the steps of:
s1: manufacturing a mould, namely uniformly dividing the container bottom plate into components capable of being spliced, and manufacturing a component mould;
s2: blending raw materials, namely mixing glass fiber into a base material, uniformly stirring, adding aluminum oxide, asbestos powder and polyvinyl chloride, fully stirring again, then adding polytetrafluoroethylene, carbon fiber and copper oxide, fully stirring again, finally adding chlorinated polyethylene, an emulsifier, a curing agent, a toughening agent and a release agent, and fully stirring to obtain a raw material;
s3: manufacturing a component, pouring the raw materials into a mold for cooling and molding, opening the mold after cooling, and taking out the component;
s4: performing finish machining on the assembly;
s5: pre-assembling the assembly after finish machining, and modifying and adjusting according to actual details;
s6: the required splicing assembly is selected according to the specific container size.
4. The method as claimed in claim 4, wherein the length of the assembly mold is greater than the length of the container when the mold is manufactured in step S1.
5. The method of claim 3, wherein the raw materials are mixed at a temperature of 230 ℃ to 300 ℃ in step S2.
6. The method of manufacturing a high-performance FRP container floor as claimed in claim 4, wherein in the step S4, the finishing comprises deburring, polishing, surface treatment and machining of necessary holes or grooves by machining.
7. The method as claimed in claim 4, wherein in the step S6, after the components are selected, the components are cut to length according to the length of the container and then assembled.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010697502.XA CN111825949A (en) | 2020-07-20 | 2020-07-20 | High-performance FRP container floor and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010697502.XA CN111825949A (en) | 2020-07-20 | 2020-07-20 | High-performance FRP container floor and manufacturing method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN111825949A true CN111825949A (en) | 2020-10-27 |
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| CN202010697502.XA Pending CN111825949A (en) | 2020-07-20 | 2020-07-20 | High-performance FRP container floor and manufacturing method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504492A (en) * | 2011-11-16 | 2012-06-20 | 金柏青 | Carbon fiber and glass fiber hybrid-reinforced sheet moulding compound and manufacturing technology thereof |
| CN107892794A (en) * | 2017-12-15 | 2018-04-10 | 苏州浩焱精密模具有限公司 | A kind of fiber reinforced plastic mold and preparation method thereof |
| CN109021527A (en) * | 2018-06-29 | 2018-12-18 | 宁国中信零部件有限公司 | A kind of fiberglass reinforced plastics and its production technology |
| CN110066492A (en) * | 2019-03-27 | 2019-07-30 | 深圳市吴越物流有限公司广州分公司 | A kind of preparation method of high-strength container bottom plate |
-
2020
- 2020-07-20 CN CN202010697502.XA patent/CN111825949A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504492A (en) * | 2011-11-16 | 2012-06-20 | 金柏青 | Carbon fiber and glass fiber hybrid-reinforced sheet moulding compound and manufacturing technology thereof |
| CN107892794A (en) * | 2017-12-15 | 2018-04-10 | 苏州浩焱精密模具有限公司 | A kind of fiber reinforced plastic mold and preparation method thereof |
| CN109021527A (en) * | 2018-06-29 | 2018-12-18 | 宁国中信零部件有限公司 | A kind of fiberglass reinforced plastics and its production technology |
| CN110066492A (en) * | 2019-03-27 | 2019-07-30 | 深圳市吴越物流有限公司广州分公司 | A kind of preparation method of high-strength container bottom plate |
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Application publication date: 20201027 |
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