CN111825110A - Recycling method of waste lithium ion battery anode material - Google Patents
Recycling method of waste lithium ion battery anode material Download PDFInfo
- Publication number
- CN111825110A CN111825110A CN202010394927.3A CN202010394927A CN111825110A CN 111825110 A CN111825110 A CN 111825110A CN 202010394927 A CN202010394927 A CN 202010394927A CN 111825110 A CN111825110 A CN 111825110A
- Authority
- CN
- China
- Prior art keywords
- solution
- anode material
- cobalt
- nickel
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/08—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Abstract
The invention relates to a recycling method of a waste lithium ion battery anode material, which heats and calcines battery powder in a vacuum atmosphere, and reduces metal ions by using cathode carbon as a reducing agent. Then adding water into the reduced powder and introducing CO2Hydrogenation and filtration are carried out. And evaporating, washing and drying the water leaching solution to obtain the high-purity lithium carbonate. The water leaching slag is subjected to acid leaching to obtain acid leaching solution, the acid leaching solution is subjected to copper and iron-aluminum removal, and then P is added204Extract and obtainTo obtain the nickel-cobalt-manganese purifying liquid. Adding soluble salt into the purified solution to adjust the ratio, then carrying out coprecipitation reaction, and filtering to obtain NixCoyMn1‑x‑y(OH)2. When the method is used for treating the lithium ion battery, the recovery rates of nickel, cobalt and manganese are all more than 98%, the recovery rate of lithium is more than 95%, the purity of the obtained lithium carbonate is high, and the lithium carbonate can be directly used for preparing the anode material of the ternary battery, so that the resource recycling is realized. The method has simple process, preferentially extracts high-purity lithium carbonate, improves the recovery rate of lithium, does not need to use a reducing agent for leaching, and improves the recovery rate of valuable metal elements.
Description
Technical Field
The invention relates to the technical field of battery recovery, in particular to a method for recycling a waste lithium ion battery anode material.
Background
With the rapid growth of the electric automobile industry, the scrappage of the power battery of the electric automobile also rapidly increases, and according to prediction, the annual accumulated scrappage of the power battery of the electric automobile in China reaches the scale of 32.3 million tons by 2020.
The power battery does not contain heavy metal elements with high toxicity such as mercury, cadmium, lead and the like, but also can bring various pollutions to the environment, such as: heavy metals in the battery anode material can raise the pH value of the environment, and toxic gas can be generated when the heavy metals are not properly treated; the power battery contains various metals and electrolyte, which can harm human health. In addition, the power battery contains a large amount of recyclable valuable metals, such as Co, Ni, Mn, Cu, Li, Al, Fe and the like. Wherein, part of the metal resources belong to elements which are relatively lacked in the nature and are relatively expensive. Therefore, if the power battery cannot be effectively recycled, precious metal loss and heavy metal pollution are inevitably caused, and the recycling of the power battery not only has economic value, but also has environmental protection significance.
At present, two methods for recycling waste ternary batteries mainly comprise a high-temperature solid phase repair method and a wet element extraction method. Wherein: the high-temperature solid phase repairing method is that the nickel cobalt lithium manganate is separated from other impurity elements by methods of sorting, chemical impurity removal and the like, and the obtained nickel cobalt lithium manganate is subjected to lithium supplement and high-temperature calcination to obtain the nickel cobalt lithium manganate ternary battery anode material with restored performance; the wet element extraction method is to carry out acid leaching, chemical impurity removal, deep impurity removal by extraction or nickel, cobalt and manganese separation on the nickel cobalt lithium manganate ternary powder to obtain sulfate, and add sodium carbonate into a lithium-containing solution to carry out evaporation concentration to obtain lithium carbonate. The method synchronously reduces and leaches valuable metals such as nickel, cobalt, manganese, lithium and the like, and a large amount of reducing agents such as hydrogen peroxide or sodium hypochlorite and the like are consumed; lithium loss occurs in each step in the subsequent working procedures, so that the final recovery rate of lithium can only reach about 65-70%; the obtained lithium carbonate is industrial-grade lithium carbonate, and high-purity lithium carbonate can be obtained by adding hydrogenation and purification; meanwhile, a large amount of water leaching slag containing cathode carbon is generated, and the disposal cost is increased; and a sodium precipitation process is required to be added before lithium precipitation, and a washing procedure is added after lithium precipitation, so that the production cost is increased.
In summary, the prior art for recycling and preparing the anode material of the waste lithium ion battery mainly has the following defects: the process is complex, and a large amount of chemical reagents are used; the lithium recovery rate is low, the lithium loss is serious, and the production cost of the lithium ion battery is undoubtedly increased when the price of the lithium raw material rises; the valuable metal elements are recovered by leaching with a large amount of reducing agents, and the recovery rate of the valuable metal elements is low.
Disclosure of Invention
The invention aims to solve the technical problem of providing a method for recycling the anode material of the waste lithium ion battery, simplifying the recycling process of the anode material of the lithium ion battery, preferentially extracting high-purity lithium carbonate, improving the lithium recovery rate, not using a reducing agent for leaching and improving the recovery rate of valuable metal elements.
The invention provides a method for recycling a waste lithium ion battery anode material, which comprises the following steps:
(1) calcining and reducing: heating, calcining and reducing battery powder containing the lithium ion battery anode material in a vacuum atmosphere, and crushing and sieving the battery powder to obtain reduced powder;
(2) and (3) extracting lithium: adding water into the reduced powder obtained in the step (1) and mixing uniformlyHomogenizing, then introducing CO2Carrying out hydrogenation reaction, and filtering to obtain a lithium bicarbonate solution and water-soaked slag;
(3) preparing high-purity lithium carbonate: heating, evaporating and concentrating the lithium bicarbonate solution obtained in the step (2), and washing and drying to obtain high-purity lithium carbonate;
(4) acid leaching: adding the water leaching residue obtained in the step (2) into an acid solution, and stirring and leaching to obtain a pickle liquor containing nickel, cobalt, manganese, aluminum, copper and iron;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), and filtering to obtain copper-removed liquor after the reaction is completed;
(6) removing iron and aluminum: adding sodium sulfate into the copper-removed solution obtained in the step (5), stirring, slowly dropwise adding industrial hydrogen peroxide, adding an alkali solution to adjust the pH value to 1.5-2.0, heating to react, cooling after the reaction is finished, adding an alkali solution to adjust the pH value to 3.0-4.0, and filtering to obtain an iron and aluminum-removed solution;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) except for the iron and the aluminum to adjust the pH value to 1.5-2.5, extracting by using an organic extractant to enable nickel, cobalt and manganese in the pickle liquor to be retained in a water phase, enabling all impurities except the nickel, the cobalt and the manganese to enter an organic phase, and separating and collecting the water phase to obtain a purified solution;
(8) preparing a ternary precursor: detecting the concentration of nickel, cobalt and manganese in the purified liquid obtained in the step (7), adding soluble nickel salt, cobalt salt or manganese salt into the purified liquid to adjust the proportion, so that the molar ratio of the nickel, the cobalt and the manganese in the purified liquid reaches the required molar ratio of the ternary anode material precursor, then adding ammonia water and alkali liquor to carry out coprecipitation reaction, and filtering to obtain the ternary anode precursor precipitated NixCoyMn1-x-y(OH)2;
Preferably, the battery powder in the step (1) comprises a lithium ion battery anode material, a cathode material and elements such as copper, aluminum and iron, wherein the lithium ion battery anode material comprises one or more of lithium cobaltate, lithium manganate, lithium nickel cobalt aluminate and lithium nickel cobalt manganate; the calcining temperature in the step (1) is 700-1000 ℃, the calcining time is 1-6 h, and the vacuum degree is-0.1 MPa to-0.01 MPa.
Preferably, the solid-liquid mass ratio in the step (2) is that of the battery powder: water 1: (10 to 15) introducing CO2The flow rate of the soaking solution is 20ml/min, the soaking temperature is room temperature, and the soaking time is 2-3 h.
Preferably, the evaporation concentration temperature in the step (3) is 85-95 ℃.
Preferably, the acid in the step (4) is one or a mixture of sulfuric acid, hydrochloric acid and nitric acid, and the concentration of the acid solution is 0.1-1 mol/L; the solid-liquid mass ratio is water immersion slag: acid solution 1: (3-5), the leaching temperature is 40-80 ℃, the leaching time is 1-3 h, and the stirring speed is 200-500 r/min.
Preferably, in the step (5), the molar weight of the added iron powder is 1-3 times of the copper content in the solution, the reaction temperature is 30-80 ℃, and the reaction time is 10-60 min.
Preferably, the adding amount of the sodium sulfate and the hydrogen peroxide in the step (6) is as follows: sodium sulfate: hydrogen peroxide (100 mL): (1-3) g: (2-10) calculating the volume of the solution, wherein the dropping time of hydrogen peroxide is 1-2 hours, and the dropping temperature is 40-50 ℃; heating to 85-95 ℃ for reaction for 1-2 h, and adding an alkali solution to adjust the pH after the temperature is reduced to 55-65 ℃.
Preferably, the alkali in the step (6) is one or a mixture of sodium hydroxide, ammonia water, potassium hydroxide, lithium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate, potassium bicarbonate and ammonium bicarbonate.
Preferably, the extractant used in the step (7) is P204, the saponification rate of P204 is 60-75%, the pH value of the aqueous phase solution is controlled to be 2-3, and the volume ratio of the organic phase to the aqueous phase is that of the organic phase: water phase (0.2-1): 1, the extraction stage is 3-5 stages of countercurrent extraction.
Preferably, one or more of nickel sulfate, nickel nitrate, nickel chloride, cobalt sulfate, cobalt nitrate, cobalt chloride, manganese nitrate or manganese sulfate is/are added when the mixture ratio is adjusted in the step (8), alkali liquor added during coprecipitation is one or more of sodium hydroxide, sodium carbonate, sodium bicarbonate, ammonium carbonate and ammonium bicarbonate solution, the concentration of the alkali liquor is 1-2 mol/L, the concentration of ammonia water is 10-15%, the reaction pH is 10.5-12.5, the reaction temperature is 40-90 ℃, and the stirring speed is 800-1500 r/min.
The principle of the invention is as follows: firstly, heating and calcining battery powder containing a lithium ion battery anode material in a vacuum atmosphere, and reducing metal ions in the mixed battery powder by using cathode carbon as a reducing agent. Then adding water into the reduction powder and mixing evenly, and then introducing CO2Carrying out a hydrogenation reaction, Li+Is leached with HCO3 +And reacting to obtain a lithium bicarbonate solution, filtering to obtain the lithium bicarbonate solution, heating, evaporating and concentrating, washing and drying to obtain the high-purity lithium carbonate. Adding the filtered water leaching residue into an acid solution, stirring and leaching to obtain a pickling solution containing nickel, cobalt, manganese, aluminum, copper and iron, adding iron powder into the obtained pickling solution, and replacing Cu in the solution by iron2+Filtering to remove copper, adding sodium sulfate into the copper-removed solution, stirring, slowly adding industrial hydrogen peroxide dropwise, adjusting pH and temperature to separate out iron and aluminum in a precipitation form, filtering to remove iron and aluminum, adding an organic extractant P204 for extraction to keep nickel, cobalt and manganese in the pickle liquor in a water phase, allowing impurities except nickel, cobalt and manganese to enter an organic phase, separating and collecting the water phase to obtain a purified solution to obtain a pure nickel, cobalt and manganese solution, namely a purified solution. Detecting the concentration of nickel, cobalt and manganese in the purified solution, adding soluble nickel salt, cobalt salt or manganese salt into the purified solution to adjust the proportion, so that the molar ratio of nickel, cobalt and manganese in the purified solution reaches the required molar ratio of the ternary anode material precursor, then adding ammonia water and alkali liquor to carry out coprecipitation reaction, and filtering to obtain the ternary anode precursor precipitate NixCoyMn1-x-y(OH)2。
The invention has the beneficial effects that:
1. the lithium is preferentially extracted to prepare the high-purity lithium carbonate, the recovery rate of the lithium is as high as 95 percent, the recovery rate is high, and the product purity is high;
2. the lithium carbonate obtained by recycling does not need to be washed by pure water for many times, so that the generation amount of waste water is greatly reduced, and water resources are saved;
3. the cathode carbon is fully utilized as a reducing agent, so that the generation amount of solid waste is greatly reduced;
4. the nickel-cobalt separation process is omitted, the components of the purified liquid are adjusted according to the proportion and then directly precipitated to obtain the ternary positive precursor materials with different proportions, and the production cost is greatly reduced;
5. the obtained ternary precursor and lithium carbonate have high purity, can be directly used for preparing the ternary battery anode material, and really realizes the cyclic utilization of resources.
In conclusion, according to the method for recycling the waste lithium ion battery anode material, the recovery rates of nickel, cobalt and manganese are all larger than 98%, the recovery rate of lithium is larger than 95%, the purity of the obtained lithium carbonate is high, the method can be directly used for preparing the ternary battery anode material, and the resource recycling is really realized. The method has simple process, preferentially extracts high-purity lithium carbonate, greatly improves the recovery rate of lithium, does not need to use a reducing agent for leaching, and greatly improves the recovery rate of valuable metal elements.
Drawings
Fig. 1 is a process flow chart of the method for recycling the anode material of the waste lithium ion battery.
Detailed Description
The invention provides a method for recycling a waste lithium ion battery anode material, which comprises the following steps:
(1) calcining and reducing: heating, calcining and reducing battery powder containing the lithium ion battery anode material in a vacuum atmosphere, and crushing and sieving the battery powder to obtain reduced powder; the battery powder comprises a lithium ion battery anode material, a lithium ion battery cathode material and elements such as copper, aluminum, iron and the like, wherein the lithium ion battery anode material comprises one or more of lithium cobaltate, lithium manganate, lithium nickel cobalt aluminate and lithium nickel cobalt manganate; the calcination temperature is 700-1000 ℃, the calcination time is 1-6 h, and the vacuum degree is-0.1 MPa to-0.01 MPa;
(2) and (3) extracting lithium: adding water into the reduced powder obtained in the step (1), uniformly mixing, and then introducing CO2Hydrogenating and filtering to obtain a lithium bicarbonate solution and water-soaked slag; the solid-liquid mass ratio is battery powder: water 1: (10 to 15) introducing CO2The flow rate of the catalyst is 20ml/min, the immersion temperature is room temperature, and the hydrogenation time is 2-3 h;
(3) preparing high-purity lithium carbonate: heating, evaporating and concentrating the lithium bicarbonate solution obtained in the step (2), and washing and drying to obtain high-purity lithium carbonate; the evaporation concentration temperature is 85-95 ℃;
(4) acid leaching: adding the water leaching residue obtained in the step (2) into an acid solution, and stirring and leaching to obtain a pickle liquor containing nickel, cobalt, manganese, aluminum, copper and iron; the acid is one or a mixture of more of sulfuric acid, hydrochloric acid and nitric acid, and the concentration of the acid solution is 0.1-1 mol/L; the solid-liquid mass ratio is water immersion slag: acid solution 1: (3-5), leaching at the temperature of 40-80 ℃, for 1-3 h, and stirring at the speed of 200-500 r/min;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), and filtering to obtain copper-removed liquor after the reaction is completed; adding iron powder into the solution, wherein the molar weight of the added iron powder is 1-3 times of the content of copper in the solution, the reaction temperature is 30-80 ℃, and the reaction time is 10-60 min.
(6) Removing iron and aluminum: according to the solution after copper removal: sodium sulfate: hydrogen peroxide (100 mL): (1-3) g: (2-10) mL, adding sodium sulfate into the copper-removed liquid obtained in the step (5), stirring, slowly dropwise adding industrial hydrogen peroxide, dropwise adding the hydrogen peroxide for 1-2 hours at the dropwise adding temperature of 40-50 ℃, adding an alkali solution to adjust the pH value to 1.5-2.0, heating to 85-95 ℃, reacting for 1-2 hours, adding the alkali solution to adjust the pH value to 3.0-4.0 after the temperature is reduced to 55-65 ℃, and filtering to obtain an iron and aluminum-removed liquid; the alkali is one or a mixture of sodium hydroxide, ammonia water, potassium hydroxide, lithium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate, potassium bicarbonate and ammonium bicarbonate;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) after iron and aluminum removal to adjust the pH value to 1.5-2.5, wherein the volume ratio of an organic phase to a water phase is as follows: water phase (0.2-1): 1, adding an organic extractant P204 with the saponification rate of 60-75% into the mixed solution, controlling the pH value of the aqueous phase solution to be 2-3, carrying out countercurrent extraction with the extraction stages of 3-5, retaining nickel, cobalt and manganese in the pickle liquor in the aqueous phase through the extraction of the organic extractant P204, allowing all impurities except the nickel, cobalt and manganese to enter an organic phase, and separating and collecting the aqueous phase to obtain a purified solution;
(8) preparing a ternary precursor: detecting the concentration of nickel, cobalt and manganese in the purified liquid obtained in the step (7), adding soluble nickel salt, cobalt salt or manganese salt into the purified liquid to adjust the proportion, so that the molar ratio of the nickel, the cobalt and the manganese in the purified liquid reaches the required molar ratio of the ternary anode material precursor, then adding ammonia water and alkali liquor to carry out coprecipitation reaction, and filtering to obtain the ternary anode precursor precipitated NixCoyMn1-x-y(OH)2(ii) a And one or more of nickel sulfate, cobalt sulfate or manganese sulfate is/are added during the adjustment of the mixture ratio, the alkali liquor added during the coprecipitation is one or more of sodium hydroxide, sodium carbonate, sodium bicarbonate, ammonium carbonate and ammonium bicarbonate solution, the concentration of the alkali liquor is 1-2 mol/L, the concentration of ammonia water is 10-15%, the reaction pH is 10.5-12.5, the reaction temperature is 40-90 ℃, and the stirring speed is 800-1500 r/min.
Example 1:
the method for recycling the anode material of the waste lithium ion battery comprises the following steps:
(1) taking 20g of waste ternary battery powder containing NCM523, putting the waste ternary battery powder into a vacuum furnace, maintaining the vacuum degree of-0.05 MPa, preserving the heat at 900 ℃ for 4h, and crushing and sieving the waste ternary battery powder to obtain reduced powder;
(2) and (3) extracting lithium: taking the reduced powder obtained in the step (1), adding 200g of pure water into the reduced powder, uniformly mixing, and then introducing CO at room temperature at a flow rate of 20ml/min2Continuously stirring, carrying out hydrogenation reaction for 2 hours, and filtering to obtain a lithium bicarbonate solution and water-soaked slag;
(3) preparing high-purity lithium carbonate: heating the lithium bicarbonate solution obtained in the step (2) at 90 ℃, evaporating and concentrating to 20mL, and washing and drying to obtain 2.9g of high-purity lithium carbonate; the lithium carbonate analysis results are shown in table 2;
(4) acid leaching: soaking slag in water according to the mass ratio: acid solution 1: 5, adding the water leaching residue obtained in the step (2) into a 0.25mol/L dilute sulfuric acid solution, reacting for 1.5 hours at the stirring speed of 300r/min and the temperature of 40-80 ℃, and filtering to obtain an acid leaching solution;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), wherein the molar weight of the iron powder is 2 times of the copper content in the pickle liquor, stirring and reacting for 30min at the temperature of 50 ℃, and filtering to obtain a copper-removed liquor;
(6) removing iron and aluminum: according to the solution after copper removal: sodium sulfate: hydrogen peroxide (100 mL): 2.5 g: adding 7.5mL of sodium sulfate into the copper-removed solution obtained in the step (5), stirring, slowly dropwise adding industrial hydrogen peroxide, wherein the dropwise adding time of the hydrogen peroxide is 1h, the dropwise adding temperature is 45 ℃, adding a sodium hydroxide solution to adjust the pH value to 1.8, heating to 90 ℃, reacting for 1h, cooling to 60 ℃, adding a sodium hydroxide solution to adjust the pH value to 3.5, and filtering to obtain an iron-aluminum-removed solution;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) after iron and aluminum removal to adjust the pH value to 2.5, and taking the volume ratio of an organic phase to a water phase as an organic phase: water phase 0.5: 1, adding an organic extractant P204 with a saponification rate of 65% into the mixed solution, controlling the pH value of the aqueous phase solution to be 2.8, performing 3-level countercurrent extraction, extracting by using the organic extractant P204 to keep nickel, cobalt and manganese in the pickle liquor in the aqueous phase, introducing all impurities except the nickel, cobalt and manganese into an organic phase, and separating and collecting the aqueous phase to obtain a purified solution;
(8) preparing a ternary precursor: detecting the concentration of nickel, cobalt and manganese in the purified liquid obtained in the step (7), adding soluble nickel sulfate, cobalt sulfate or manganese sulfate into the purified liquid to adjust the proportion, so that the molar ratio of nickel, cobalt and manganese in the purified liquid is 5:2:3, then adding 2mol/L sodium hydroxide solution and 10% ammonia water solution in volume fraction into the solution in a concurrent flow manner, maintaining the pH value of the solution at 11, stirring at the speed of 800r/min and the reaction temperature of 50 ℃, aging for 10h after the reaction is finished, filtering, washing with deionized water for multiple times, and drying to obtain the Ni precipitate of the ternary cathode precursor0.5Co0.2Mn0.3(OH)2And the analysis result of the ternary precursor is shown in table 2, and the precursor and the prepared high-purity lithium carbonate are mixed according to the following ratio of M: mixing Li 1:1.05, adding a proper amount of ethanol, ball-milling for 8h, drying, calcining at 900 ℃ for 10h in an air atmosphere to obtain a ternary cathode material, and carrying out assembly and discharge detection, wherein the charge-discharge specific capacity of 0.2C is 165 mAh/g.
Example 2:
the method for recycling the anode material of the waste lithium ion battery comprises the following steps:
(1) taking 100g of battery powder containing lithium cobaltate, putting the battery powder into a vacuum furnace, maintaining the vacuum degree of-0.1 MPa, preserving the heat at 800 ℃ for 3 hours, crushing and sieving the battery powder to obtain reduced powder;
(2) and (3) extracting lithium: taking the reduced powder obtained in the step (1), adding 1500g of pure water into the reduced powder, uniformly mixing, and then introducing CO at room temperature at a flow rate of 20ml/min2Continuously stirring, carrying out hydrogenation reaction for 3 hours, and filtering to obtain a lithium bicarbonate solution and water-soaked slag;
(3) preparing high-purity lithium carbonate: heating the lithium bicarbonate solution obtained in the step (2) at 95 ℃, evaporating and concentrating to 100mL, and washing and drying to obtain 24.8g of high-purity lithium carbonate; the lithium carbonate analysis results are shown in table 2;
(4) acid leaching: soaking slag in water according to the mass ratio: acid solution 1: 5, adding the water leaching residue obtained in the step (2) into 0.5mol/L dilute hydrochloric acid solution, reacting for 2.5 hours at the stirring speed of 400r/min and the temperature of 70 ℃, and filtering to obtain acid leaching solution;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), wherein the molar weight of the iron powder is 3 times of the copper content in the pickle liquor, stirring and reacting for 20min at the temperature of 60 ℃, and filtering to obtain a copper-removed liquor;
(6) removing iron and aluminum: according to the solution after copper removal: sodium sulfate: hydrogen peroxide (100 mL): 1 g: adding sodium sulfate into the copper-removed liquid obtained in the step (5) in an amount of 5mL, stirring, slowly dropwise adding industrial hydrogen peroxide, dropwise adding hydrogen peroxide for 1.5h at the dropwise adding temperature of 40 ℃, adding a sodium carbonate solution to adjust the pH value to 2.0, heating to 85 ℃, reacting for 1.5h, cooling to 60 ℃, adding a sodium carbonate solution to adjust the pH value to 4.0, and filtering to obtain iron and aluminum-removed liquid;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) after iron and aluminum removal to adjust the pH value to 1.8, and taking the volume ratio of an organic phase to a water phase as an organic phase: water phase 0.3: 1, adding an organic extractant P204 with the saponification rate of 60% into the mixed solution, controlling the pH value of the aqueous phase solution to be 2.0, performing 5-stage countercurrent extraction, extracting by using the organic extractant P204 to keep cobalt in the pickle liquor in the aqueous phase, allowing all impurities except the cobalt to enter the organic phase, and separating and collecting the aqueous phase to obtain a purified solution;
(8) preparation of ternary precursors: detecting the concentration of cobalt in the purified liquid obtained in the step (7), adding nickel nitrate, cobalt nitrate or manganese nitrate into the purified liquid to adjust the mixture ratio, so that the molar ratio of nickel, cobalt and manganese in the purified liquid is 6:2:2, then adding 2mol/L sodium hydroxide solution and 10% ammonia water solution in volume fraction into the solution in a concurrent flow manner, maintaining the pH value of the solution at 10.5, stirring at the speed of 800r/min and the reaction temperature of 60 ℃, aging for 10h after the reaction is finished, filtering, washing with deionized water for multiple times, and drying to obtain a ternary anode precursor precipitate Ni0.6Co0.2Mn0.2(OH)2And the analysis result of the ternary precursor is shown in table 1, and the precursor and the prepared high-purity lithium carbonate are mixed according to the following ratio of M: mixing Li 1:1.05, adding a proper amount of ethanol, ball-milling for 8h, drying, calcining at 800 ℃ for 10h in an air atmosphere to obtain a ternary cathode material, and carrying out assembly and discharge detection, wherein the charge-discharge specific capacity of 0.2C is 175 mAh/g.
Example 3:
the method for recycling the anode material of the waste lithium ion battery comprises the following steps:
(1) taking 100g of waste ternary battery powder containing NCM111, putting the powder into a vacuum furnace, maintaining the vacuum degree of-0.03 MPa, preserving the heat at 750 ℃ for 6h, crushing and sieving the powder to obtain reduced powder;
(2) and (3) extracting lithium: taking the reduced powder obtained in the step (1), adding 1200g of pure water into the reduced powder, uniformly mixing, and then introducing CO at room temperature at a flow rate of 20ml/min2Continuously stirring, carrying out hydrogenation reaction for 2.5h, and filtering to obtain a lithium bicarbonate solution and water-soaked slag;
(3) preparing high-purity lithium carbonate: heating the lithium bicarbonate solution obtained in the step (2) at 85 ℃, evaporating and concentrating to 120mL, and washing and drying to obtain 24.5g of high-purity lithium carbonate; the lithium carbonate analysis results are shown in table 2;
(4) acid leaching: soaking slag in water according to the mass ratio: acid solution 1: 5, adding the water leaching residue obtained in the step (2) into a 0.8mol/L dilute nitric acid solution, reacting for 2 hours at the temperature of 50 ℃ at the stirring speed of 500r/min, and filtering to obtain a pickle liquor;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), wherein the molar weight of the iron powder is 2.5 times of the copper content in the pickle liquor, stirring and reacting for 45min at the temperature of 50 ℃, and filtering to obtain a copper-removed liquid;
(6) removing iron and aluminum: according to the solution after copper removal: sodium sulfate: hydrogen peroxide (100 mL): 1.5 g: adding 3mL of sodium sulfate into the copper-removed liquid obtained in the step (5), stirring and slowly dropwise adding industrial hydrogen peroxide, wherein the dropwise adding time of the hydrogen peroxide is 2 hours, the dropwise adding temperature is 50 ℃, adding a sodium carbonate solution to adjust the PH to 1.5, then heating to 95 ℃, reacting for 2 hours, cooling to 55 ℃, adding a sodium carbonate solution to adjust the PH to 3.0, and filtering to obtain iron and aluminum-removed liquid;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) after iron and aluminum removal to adjust the pH value to 2.2, and taking the volume ratio of an organic phase to a water phase as an organic phase: water phase 1:1, adding an organic extractant P204 with the saponification rate of 70% into the mixed solution, controlling the pH value of the aqueous phase solution to be 2.5, performing 4-stage countercurrent extraction, extracting by using the organic extractant P204 to keep nickel, cobalt and manganese in the pickle liquor in the aqueous phase, introducing all impurities except the nickel, cobalt and manganese into an organic phase, and separating and collecting the aqueous phase to obtain a purified solution;
(8) preparing a ternary precursor: detecting the concentration of nickel, cobalt and manganese in the purified liquid obtained in the step (7), adding soluble cobalt sulfate, nickel sulfate or manganese chloride into the purified liquid to adjust the mixture ratio so that the molar ratio of nickel, cobalt and manganese in the purified liquid is 8:1:1, then adding 2mol/L ammonium carbonate solution and 10 volume percent ammonia water solution into the solution in a concurrent flow manner, maintaining the pH value of the solution at 11.8, stirring at the speed of 1500r/min and the reaction temperature of 70 ℃, aging for 10 hours after the reaction is finished, filtering, washing with deionized water for multiple times, and drying to obtain a ternary positive precursor precipitate Ni0.8Co0.1Mn0.1(OH)2The results of the analysis of the ternary precursor are shown in table 1, and the precursor and the prepared high-purity lithium hydroxide monohydrate are mixed according to the following formula: mixing Li 1:1.05, adding a proper amount of ethanol, ball-milling for 8h, drying, calcining for 8h at 700 ℃ in an air atmosphere to obtain a ternary cathode material, and carrying out assembly and discharge detection, wherein the charge-discharge specific capacity of 0.2C is 200 mAh/g.
As can be seen from Table 1, the molar ratios of the main elements of the ternary precursor obtained by the method for recycling the waste lithium ion battery anode material all accord with 5:2:3, 6:2:2 and 8:1:1, and the detection of the impurity content, the specific surface area and the like also accord with the GB/T26300-2010 standard and is the qualified ternary precursor.
As shown in Table 2, the main element content and the impurity content of the lithium carbonate obtained by the method for recycling the waste lithium ion battery anode material meet the industry standard YS/T582-.
As can be seen from table 3, the recycling method of the waste lithium ion battery cathode material according to the present invention has lithium recovery rates of 95.7%, 95.1% and 95.9%, respectively.
Results of analysis of ternary precursor obtained in Table 1
TABLE 2 analytical results of lithium carbonate
Table 3 analysis results of component contents of each recovered material in examples
Item | Li | Co | Ni | Mn | Al | Fe | Cu | C |
Example 1 | 2.85% | 2.3% | 5% | 14.5% | 0.98% | 0.2% | 0.2% | 30% |
Example 2 | 4.9% | 10.5% | / | / | 1.03% | 0.18% | 0.22% | 28% |
Example 3 | 4.8% | 4.1% | 32.92% | 3.86% | 0.4% | 0.18% | 0.2% | 31% |
Claims (10)
1. A method for recycling a waste lithium ion battery anode material is characterized by comprising the following steps:
(1) calcining and reducing: heating, calcining and reducing battery powder containing the lithium ion battery anode material in a vacuum atmosphere, and crushing and sieving the battery powder to obtain reduced powder;
(2) and (3) extracting lithium: adding water into the reduced powder obtained in the step (1), uniformly mixing, and then introducing CO2Hydrogenating and filtering to obtain a lithium bicarbonate solution and water-soaked slag;
(3) preparing high-purity lithium carbonate: heating, evaporating and concentrating the lithium bicarbonate solution obtained in the step (2), and washing and drying to obtain high-purity lithium carbonate;
(4) acid leaching: adding the water leaching residue obtained in the step (2) into an acid solution, and stirring and leaching to obtain a pickle liquor containing nickel, cobalt, manganese, aluminum, copper and iron;
(5) copper removal: adding iron powder into the pickle liquor obtained in the step (4), and filtering to obtain copper-removed liquor after the reaction is completed;
(6) removing iron and aluminum: adding sodium sulfate into the copper-removed solution obtained in the step (5), stirring, slowly dropwise adding industrial hydrogen peroxide, adding an alkali solution to adjust the pH value to 1.5-2.0, heating to react, cooling after the reaction is finished, adding an alkali solution to adjust the pH value to 3.0-4.0, and filtering to obtain an iron and aluminum-removed solution;
(7) and (3) extraction and impurity removal: adding an acid solution into the liquid obtained in the step (6) except for the iron and the aluminum to adjust the pH value to 1.5-2.5, extracting by using an organic extractant to enable nickel, cobalt and manganese in the pickle liquor to be retained in a water phase, enabling all impurities except the nickel, the cobalt and the manganese to enter an organic phase, and separating and collecting the water phase to obtain a purified solution;
(8) preparing a ternary precursor: detecting the concentration of nickel, cobalt and manganese in the purified liquid obtained in the step (7), adding soluble nickel salt, cobalt salt or manganese salt into the purified liquid to adjust the proportion, so that the molar ratio of the nickel, the cobalt and the manganese in the purified liquid reaches the required molar ratio of the ternary anode material precursor, then adding ammonia water and alkali liquor to carry out coprecipitation reaction, and filtering to obtain the ternary anode precursor precipitated NixCoyMn1-x-y(OH)2。
2. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the battery powder in the step (1) includes the anode material and the cathode material of the lithium ion battery and elements such as copper, aluminum and iron, and the anode material of the lithium ion battery includes one or more of lithium cobaltate, lithium manganate, lithium nickel cobalt aluminate and lithium nickel cobalt manganate; the calcining temperature in the step (1) is 700-1000 ℃, the calcining time is 1-6 h, and the vacuum degree is-0.1 MPa to-0.01 MPa.
3. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the solid-liquid mass ratio in the step (2) is battery powder: water 1: (10 to 15) introducing CO2The flow rate of (A) is 20ml/min, the hydrogenation temperature is room temperature, and the hydrogenation time is 2-3 h.
4. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the evaporation and concentration temperature in the step (3) is 85-95 ℃.
5. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the acid in the step (4) is one or a mixture of sulfuric acid, hydrochloric acid and nitric acid, and the concentration of the acid solution is 0.1-1 mol/L; the solid-liquid mass ratio is water immersion slag: acid solution 1: (3-5), the leaching temperature is 40-80 ℃, the leaching time is 1-3 h, and the stirring speed is 200-500 r/min.
6. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the molar weight of the added iron powder in the step (5) is 1-3 times of the copper content in the solution, the reaction temperature is 30-80 ℃, and the reaction time is 10-60 min.
7. The method for recycling the anode material of the waste lithium ion battery according to claim 1, wherein the adding amount of the sodium sulfate and the hydrogen peroxide in the step (6) is as follows: sodium sulfate: hydrogen peroxide (100 mL): (1-3) g: (2-10) calculating the volume of the solution, wherein the dropping time of hydrogen peroxide is 1-2 hours, and the dropping temperature is 40-50 ℃; heating to 85-95 ℃ for reaction for 1-2 h, and adding an alkali solution to adjust the pH after the temperature is reduced to 55-65 ℃.
8. The method for recycling the anode material of the waste lithium ion battery according to claim 1, wherein the alkali in the step (6) is one or more mixed solution of sodium hydroxide, ammonia water, potassium hydroxide, lithium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, sodium bicarbonate, potassium bicarbonate and ammonium bicarbonate.
9. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein the extractant used in the step (7) is P204, the saponification rate of the P204 is 60-75%, the volume fraction of the P204 is 15-25%, the PH value of the aqueous phase solution is controlled to 2-3, and the volume ratio of the organic phase to the aqueous phase is organic phase: water phase (0.2-1): 1, the extraction stage is 3-5 stages of countercurrent extraction.
10. The recycling method of the anode material of the waste lithium ion battery according to claim 1, wherein one or more of nickel sulfate, nickel nitrate, nickel chloride, cobalt sulfate, cobalt nitrate, cobalt chloride, manganese nitrate or manganese sulfate is added during the adjustment of the mixture ratio in the step (8), the alkali liquor added during the coprecipitation is one or more of sodium hydroxide solution, sodium carbonate solution, sodium bicarbonate solution, ammonium carbonate solution and ammonium bicarbonate solution, the concentration of the alkali liquor is 1-2 mol/L, the concentration of ammonia water is 10-15%, the reaction pH is 10.5-12.5, the reaction temperature is 40-90 ℃, and the stirring speed is 800-1500 r/min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010394927.3A CN111825110A (en) | 2020-05-12 | 2020-05-12 | Recycling method of waste lithium ion battery anode material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010394927.3A CN111825110A (en) | 2020-05-12 | 2020-05-12 | Recycling method of waste lithium ion battery anode material |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111825110A true CN111825110A (en) | 2020-10-27 |
Family
ID=72913810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010394927.3A Pending CN111825110A (en) | 2020-05-12 | 2020-05-12 | Recycling method of waste lithium ion battery anode material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111825110A (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112531159A (en) * | 2021-02-05 | 2021-03-19 | 矿冶科技集团有限公司 | Recycling method and application of waste lithium ion battery |
CN112537807A (en) * | 2020-12-30 | 2021-03-23 | 浙江帕瓦新能源股份有限公司 | High-performance nano rod-shaped nickel-manganese binary precursor and preparation method thereof |
CN112626558A (en) * | 2020-12-29 | 2021-04-09 | 派尔森环保科技有限公司 | Method for preparing high-activity ternary metal oxide oxygen evolution catalyst by utilizing waste ternary nickel cobalt lithium manganate |
CN112981112A (en) * | 2021-02-07 | 2021-06-18 | 余姚市鑫和电池材料有限公司 | Method for preparing high-purity cobalt sulfate solution from waste ternary lithium battery cathode material |
CN113061730A (en) * | 2021-03-23 | 2021-07-02 | 北京佰利格瑞资源科技有限公司 | Method for removing iron in waste ternary lithium battery recovery process |
CN113086996A (en) * | 2021-03-25 | 2021-07-09 | 宁夏百川新材料有限公司 | Recycling method of waste ternary fluorine-doped battery positive electrode material |
CN113106257A (en) * | 2021-04-12 | 2021-07-13 | 广东佳纳能源科技有限公司 | Recycling method of lithium battery waste and application thereof |
CN113117637A (en) * | 2021-04-19 | 2021-07-16 | 重庆大学 | Method for preparing carbon dioxide adsorbing material by using waste lithium cobaltate battery as raw material |
CN113151680A (en) * | 2021-02-08 | 2021-07-23 | 中国科学院宁波材料技术与工程研究所 | Method for recycling waste lithium batteries |
CN113437379A (en) * | 2021-06-24 | 2021-09-24 | 齐鲁理工学院 | Method for recycling and regenerating waste ternary lithium battery |
CN113430395A (en) * | 2021-06-30 | 2021-09-24 | 天津市职业大学 | Method for extracting lithium from waste lithium ion battery material by using lithium ion sieve |
CN114085995A (en) * | 2021-11-09 | 2022-02-25 | 湖北亿纬动力有限公司 | Method for preparing metal simple substance and compound thereof by recycling waste lithium ion battery and application thereof |
CN114335545A (en) * | 2022-01-06 | 2022-04-12 | 天能帅福得能源股份有限公司 | Lithium ion battery lithium supplement additive and preparation method thereof |
WO2022089203A1 (en) * | 2020-10-29 | 2022-05-05 | 湖南邦普循环科技有限公司 | Extraction method for removing aluminum from leaching solution of ternary battery material |
CN115074540A (en) * | 2022-08-16 | 2022-09-20 | 矿冶科技集团有限公司 | Comprehensive recovery method for valuable components of waste power battery |
GB2609212A (en) * | 2021-07-22 | 2023-02-01 | Mexichem Fluor Sa De Cv | Process |
WO2023024599A1 (en) * | 2021-08-23 | 2023-03-02 | 广东邦普循环科技有限公司 | Method for recovery of waste lithium batteries and preparing ternary precursor |
CN116002725A (en) * | 2022-11-28 | 2023-04-25 | 广州大学 | Method for efficiently separating lithium element in waste lithium ion battery anode material |
EP4245868A1 (en) * | 2022-03-18 | 2023-09-20 | Northvolt Revolt AB | Process for generating a metal-containing aqueous solution |
WO2023243385A1 (en) * | 2022-06-15 | 2023-12-21 | Dowaエコシステム株式会社 | Recycled positive electrode material, method for producing same, method for using recycled positive electrode material, recycled positive electrode, and lithium ion secondary battery |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106129511A (en) * | 2016-06-27 | 2016-11-16 | 北京科技大学 | A kind of method of comprehensively recovering valuable metal from waste and old lithium ion battery material |
CN106505272A (en) * | 2016-12-12 | 2017-03-15 | 江西赣锋锂业股份有限公司 | A kind of processing method of anode material of lithium battery waste material |
CN107267759A (en) * | 2017-06-12 | 2017-10-20 | 合肥国轩高科动力能源有限公司 | A kind of comprehensive recovering process of anode material for lithium-ion batteries |
CN107419096A (en) * | 2017-06-27 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of preparation method of waste lithium cell reclaiming tertiary cathode material |
CN107666022A (en) * | 2017-09-25 | 2018-02-06 | 湖南工业大学 | Lithium, the recovery method of nickel cobalt manganese in a kind of discarded tertiary cathode material |
CN107828966A (en) * | 2017-10-12 | 2018-03-23 | 合肥国轩高科动力能源有限公司 | A kind of comprehensive recovering process of ternary anode material for lithium-ion batteries |
CN107994288A (en) * | 2017-12-14 | 2018-05-04 | 眉山顺应动力电池材料有限公司 | Valuable metal recovery method in waste and old nickle cobalt lithium manganate ternary cell positive material |
CN108011150A (en) * | 2017-12-28 | 2018-05-08 | 许昌学院 | A kind of method that lithium carbonate is produced from waste and old ternary lithium ion cell electrode powder |
CN110512080A (en) * | 2019-09-12 | 2019-11-29 | 金川集团股份有限公司 | Valuable metal separation and recovery method in a kind of waste and old nickel cobalt manganese lithium ion battery |
CN110862110A (en) * | 2019-11-26 | 2020-03-06 | 宁夏百川新材料有限公司 | Method for preparing ternary positive electrode material precursor by using waste lithium ion battery |
CN111082043A (en) * | 2019-11-26 | 2020-04-28 | 宁夏百川新材料有限公司 | Recycling method of waste nickel cobalt lithium manganate ternary battery positive electrode material |
-
2020
- 2020-05-12 CN CN202010394927.3A patent/CN111825110A/en active Pending
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106129511A (en) * | 2016-06-27 | 2016-11-16 | 北京科技大学 | A kind of method of comprehensively recovering valuable metal from waste and old lithium ion battery material |
CN106505272A (en) * | 2016-12-12 | 2017-03-15 | 江西赣锋锂业股份有限公司 | A kind of processing method of anode material of lithium battery waste material |
CN107267759A (en) * | 2017-06-12 | 2017-10-20 | 合肥国轩高科动力能源有限公司 | A kind of comprehensive recovering process of anode material for lithium-ion batteries |
CN107419096A (en) * | 2017-06-27 | 2017-12-01 | 常州市沃兰特电子有限公司 | A kind of preparation method of waste lithium cell reclaiming tertiary cathode material |
CN107666022A (en) * | 2017-09-25 | 2018-02-06 | 湖南工业大学 | Lithium, the recovery method of nickel cobalt manganese in a kind of discarded tertiary cathode material |
CN107828966A (en) * | 2017-10-12 | 2018-03-23 | 合肥国轩高科动力能源有限公司 | A kind of comprehensive recovering process of ternary anode material for lithium-ion batteries |
CN107994288A (en) * | 2017-12-14 | 2018-05-04 | 眉山顺应动力电池材料有限公司 | Valuable metal recovery method in waste and old nickle cobalt lithium manganate ternary cell positive material |
CN108011150A (en) * | 2017-12-28 | 2018-05-08 | 许昌学院 | A kind of method that lithium carbonate is produced from waste and old ternary lithium ion cell electrode powder |
CN110512080A (en) * | 2019-09-12 | 2019-11-29 | 金川集团股份有限公司 | Valuable metal separation and recovery method in a kind of waste and old nickel cobalt manganese lithium ion battery |
CN110862110A (en) * | 2019-11-26 | 2020-03-06 | 宁夏百川新材料有限公司 | Method for preparing ternary positive electrode material precursor by using waste lithium ion battery |
CN111082043A (en) * | 2019-11-26 | 2020-04-28 | 宁夏百川新材料有限公司 | Recycling method of waste nickel cobalt lithium manganate ternary battery positive electrode material |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022089203A1 (en) * | 2020-10-29 | 2022-05-05 | 湖南邦普循环科技有限公司 | Extraction method for removing aluminum from leaching solution of ternary battery material |
EP4239086A4 (en) * | 2020-10-29 | 2024-04-17 | Hunan Brunp Recycling Tech Co Ltd | Extraction method for removing aluminum from leaching solution of ternary battery material |
CN112626558A (en) * | 2020-12-29 | 2021-04-09 | 派尔森环保科技有限公司 | Method for preparing high-activity ternary metal oxide oxygen evolution catalyst by utilizing waste ternary nickel cobalt lithium manganate |
CN112537807A (en) * | 2020-12-30 | 2021-03-23 | 浙江帕瓦新能源股份有限公司 | High-performance nano rod-shaped nickel-manganese binary precursor and preparation method thereof |
CN112531159B (en) * | 2021-02-05 | 2021-11-26 | 矿冶科技集团有限公司 | Recycling method and application of waste lithium ion battery |
CN112531159A (en) * | 2021-02-05 | 2021-03-19 | 矿冶科技集团有限公司 | Recycling method and application of waste lithium ion battery |
CN112981112A (en) * | 2021-02-07 | 2021-06-18 | 余姚市鑫和电池材料有限公司 | Method for preparing high-purity cobalt sulfate solution from waste ternary lithium battery cathode material |
CN113151680A (en) * | 2021-02-08 | 2021-07-23 | 中国科学院宁波材料技术与工程研究所 | Method for recycling waste lithium batteries |
CN113061730A (en) * | 2021-03-23 | 2021-07-02 | 北京佰利格瑞资源科技有限公司 | Method for removing iron in waste ternary lithium battery recovery process |
CN113086996A (en) * | 2021-03-25 | 2021-07-09 | 宁夏百川新材料有限公司 | Recycling method of waste ternary fluorine-doped battery positive electrode material |
CN113106257A (en) * | 2021-04-12 | 2021-07-13 | 广东佳纳能源科技有限公司 | Recycling method of lithium battery waste and application thereof |
CN113117637A (en) * | 2021-04-19 | 2021-07-16 | 重庆大学 | Method for preparing carbon dioxide adsorbing material by using waste lithium cobaltate battery as raw material |
CN113437379A (en) * | 2021-06-24 | 2021-09-24 | 齐鲁理工学院 | Method for recycling and regenerating waste ternary lithium battery |
CN113430395A (en) * | 2021-06-30 | 2021-09-24 | 天津市职业大学 | Method for extracting lithium from waste lithium ion battery material by using lithium ion sieve |
GB2609212A (en) * | 2021-07-22 | 2023-02-01 | Mexichem Fluor Sa De Cv | Process |
WO2023024599A1 (en) * | 2021-08-23 | 2023-03-02 | 广东邦普循环科技有限公司 | Method for recovery of waste lithium batteries and preparing ternary precursor |
CN114085995A (en) * | 2021-11-09 | 2022-02-25 | 湖北亿纬动力有限公司 | Method for preparing metal simple substance and compound thereof by recycling waste lithium ion battery and application thereof |
CN114335545B (en) * | 2022-01-06 | 2024-01-26 | 天能帅福得能源股份有限公司 | Lithium ion battery lithium supplementing additive and preparation method thereof |
CN114335545A (en) * | 2022-01-06 | 2022-04-12 | 天能帅福得能源股份有限公司 | Lithium ion battery lithium supplement additive and preparation method thereof |
EP4245868A1 (en) * | 2022-03-18 | 2023-09-20 | Northvolt Revolt AB | Process for generating a metal-containing aqueous solution |
WO2023175161A1 (en) * | 2022-03-18 | 2023-09-21 | Northvolt Revolt Ab | Process for generating a metal-containing aqueous solution |
WO2023243385A1 (en) * | 2022-06-15 | 2023-12-21 | Dowaエコシステム株式会社 | Recycled positive electrode material, method for producing same, method for using recycled positive electrode material, recycled positive electrode, and lithium ion secondary battery |
CN115074540A (en) * | 2022-08-16 | 2022-09-20 | 矿冶科技集团有限公司 | Comprehensive recovery method for valuable components of waste power battery |
CN116002725A (en) * | 2022-11-28 | 2023-04-25 | 广州大学 | Method for efficiently separating lithium element in waste lithium ion battery anode material |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111825110A (en) | Recycling method of waste lithium ion battery anode material | |
CN108878866B (en) | Method for preparing ternary material precursor and recovering lithium by using ternary cathode material of waste lithium ion battery | |
CN111129632B (en) | Method for recycling anode and cathode mixed materials of waste ternary lithium ion battery | |
CN108832215A (en) | A kind of method of selective recovery anode material for lithium-ion batteries | |
CN106848474A (en) | A kind of method of high efficiente callback positive electrode material precursor and lithium carbonate from lithium ion cell anode waste | |
CN111082043A (en) | Recycling method of waste nickel cobalt lithium manganate ternary battery positive electrode material | |
CN112158894A (en) | Method for recovering anode material of waste lithium battery | |
CN108963371B (en) | Method for recovering valuable metals from waste lithium ion batteries | |
EP4324949A1 (en) | Method for recovering valuable metals from spent lithium-ion batteries | |
CN113200574A (en) | Method for regenerating lithium-rich manganese-based positive electrode from mixed waste lithium battery | |
CN110862110A (en) | Method for preparing ternary positive electrode material precursor by using waste lithium ion battery | |
CN113415813A (en) | Method for recovering lithium nickel cobalt manganese from waste ternary battery material | |
CN114085997A (en) | Waste lithium ion battery recovery method | |
CN113086996A (en) | Recycling method of waste ternary fluorine-doped battery positive electrode material | |
CN114477240A (en) | Preparation method of battery-grade lithium hydroxide | |
CN111254276A (en) | Method for selectively extracting valuable metals from waste lithium ion battery powder based on phase conversion of sodium reduction roasting | |
CN113745683A (en) | Method for recycling cobalt-containing waste lithium ion battery | |
CN117210687A (en) | Alkaline leaching recovery method for waste oxide battery anode material | |
CN116102080A (en) | Method for preparing positive electrode material by regenerating waste sodium ion battery | |
CN112093787B (en) | Method for recycling and preparing olivine type five-element high-entropy lithium battery precursor | |
CN115571925B (en) | Method for recycling and preparing lithium carbonate and ternary precursor from waste lithium batteries | |
CN115216649B (en) | Method for preparing vanadium dioxide battery material by using waste vanadium-titanium-based SCR catalyst | |
CN113611857B (en) | Method for preparing ternary cathode material by using manganese-containing cobalt-nickel waste residues | |
CN116790909A (en) | Method for selectively leaching lithium in waste lithium ion battery electrode material | |
CN117902639A (en) | Method for preparing nickel-cobalt-manganese ternary precursor and lithium carbonate from waste lithium ion battery anode powder |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |