CN111801370B - 从非化石能源和可再生木质纤维素生物质原料按需发电的方法和发电厂 - Google Patents
从非化石能源和可再生木质纤维素生物质原料按需发电的方法和发电厂 Download PDFInfo
- Publication number
- CN111801370B CN111801370B CN201980013674.6A CN201980013674A CN111801370B CN 111801370 B CN111801370 B CN 111801370B CN 201980013674 A CN201980013674 A CN 201980013674A CN 111801370 B CN111801370 B CN 111801370B
- Authority
- CN
- China
- Prior art keywords
- energy
- power generation
- liquid fraction
- lignin
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000010248 power generation Methods 0.000 title claims abstract description 28
- 239000002029 lignocellulosic biomass Substances 0.000 title claims abstract description 20
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000002309 gasification Methods 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000008569 process Effects 0.000 claims abstract description 15
- 230000005611 electricity Effects 0.000 claims abstract description 14
- 235000019253 formic acid Nutrition 0.000 claims abstract description 14
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 238000009434 installation Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 32
- 229920005610 lignin Polymers 0.000 claims description 27
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- 238000003786 synthesis reaction Methods 0.000 claims description 24
- 239000007787 solid Substances 0.000 claims description 17
- 229920002488 Hemicellulose Polymers 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 8
- 238000003860 storage Methods 0.000 claims description 6
- FDORQEIHOKEJNX-UHFFFAOYSA-N 2-[[3-(4-fluorophenyl)-3-(4-phenylphenoxy)propyl]-methylamino]acetic acid Chemical compound C=1C=C(F)C=CC=1C(CCN(C)CC(O)=O)OC(C=C1)=CC=C1C1=CC=CC=C1 FDORQEIHOKEJNX-UHFFFAOYSA-N 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- 235000005985 organic acids Nutrition 0.000 claims description 3
- 238000001556 precipitation Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 17
- 239000002028 Biomass Substances 0.000 description 16
- 229920002678 cellulose Polymers 0.000 description 10
- 239000001913 cellulose Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000002551 biofuel Substances 0.000 description 8
- 235000000346 sugar Nutrition 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 241001133760 Acoelorraphe Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000011143 downstream manufacturing Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- -1 acetic acid (CH) Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical group CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D7/00—Fertilisers producing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
- C07G1/00—Lignin; Lignin derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0057—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Xylans, i.e. xylosaccharide, e.g. arabinoxylan, arabinofuronan, pentosans; (beta-1,3)(beta-1,4)-D-Xylans, e.g. rhodymenans; Hemicellulose; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H8/00—Macromolecular compounds derived from lignocellulosic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/005—Lignin
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C7/00—Features, components parts, details or accessories, not provided for in, or of interest apart form groups F02C1/00 - F02C6/00; Air intakes for jet-propulsion plants
- F02C7/22—Fuel supply systems
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
- F02C6/02—Plural gas-turbine plants having a common power output
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/30—Energy from the sea, e.g. using wave energy or salinity gradient
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Biochemistry (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
本发明提供在发电厂中使用多个发电设施从非化石能源和可再生木质纤维素生物质原料按需发电的方法和发电厂,该多个发电设施包括:用于从非化石能源发电的第一设施,所述能源选自风能、和/或水力和/或太阳能和/或地热能和/或潮汐能;和第二设施,该第二设施使用在来自可再生木质纤维素生物质原料的几个级分的气化步骤期间生产的合成气,该可再生木质纤维素生物质原料通过使用至少由水和甲酸组成的混合物实施有机溶剂法获得。
Description
技术领域
本发明涉及从非化石能源和可再生木质纤维素生物质原料按需发电的方法。
本发明涉及从非化石能源和可再生木质纤维素生物质原料按需发电的发电厂。
背景技术
迄今为止,在不考虑生物质直接燃烧的情况下,从植物生物质产生能量的主要尝试是生产生物燃料,诸如生物乙醇和其它类型的生物燃料。
特别地,这些生物燃料在试图通过替代“化石”燃料来减少配备有内燃机的机动车辆的二氧化碳排放方面表现出吸引力。
衍生自植物生物质的燃料也排放二氧化碳,但是由此释放出的碳已经存在于大气中。
因此,从二氧化碳排放的角度来看,生物燃料似乎很有吸引力。
特别地,用于生产液体生物燃料的不同技术-无论是通过酶促水解还是热化学途径转化木质纤维素生物质-在产量和能量平衡方面的产率都较低。通过常规生化途径生产乙醇的总体能量平衡可能会因与种植专用植物相关的必要能耗以及蒸馏操作期间的能耗而受到不利影响。
另外,在此领域中,仅植物中所含的糖用于生产生物燃料,并因此用于产生能量。
此外,酶的成本不允许达到足够的经济平衡-它不断受到原油价格的影响。
在热化学途径中,生物质的所有成分都用于生产生物燃料,并且总体能量平衡可能会更好,但总体经济平衡仍然很低。
因此,对于生物燃料的工业大规模生产,还没有找到在不同的能源、经济和全球生态平衡方面令人满意的解决方案。
同时,开发所有类型的绿色或“清洁”能源生产,特别是绿色电力,即不使用化石燃料或不以核工业为基础的能源,已变得至关重要。
这些发展也与机动车辆概念的发展相一致,其推进方式和能源的主要趋势如今已在于全部“电气化”或通过混合动力机动化实现部分电气化。
例如,当考虑在伐木和棕榈或棕榈树的生产中,或在大规模的稻草和谷类稻草的生产中或在制糖业中的甘蔗渣中考虑到木质纤维素残余物时,这些木质纤维素植物原料可以大量使用。在这两种情况下,可以使用非常丰富的原料来进行本发明的方法,迄今为止,该方法没有发现有益的工业用途,并且在环境可接受的条件下也无法生产能源,例如用于“原地”发电。
生物质是太阳能独特的直接和可再生存储设施,且木质纤维素废料的确或多或少地代表了这种可再生非化石能源的重要部分。
而且,由于各种原因,在聚合物工业中也有必要逐步地用生物质衍生的产品(绿色化学)代替石油工业衍生的产品(即石油化工)。
在这种情况下,在US A1 2012/0202260中提出了根据“木质纤维素原料的混合生物精制和气化”从木质纤维素原料中同时回收木质素衍生物和合成气体(合成气)的方法。但是,在使用常规的气化设备分离木质素并气化“固体流”和“半固体和固体废物”以生产合成气之后,建议加工合成气以生产各种类型的燃料,诸如生物柴油、丁醇、乙醇、甲醇等。
合成气是主要由氢、一氧化碳和很常见地一些二氧化碳组成的燃料气体混合物。
典型地,生物质向合成气的转化是低产率的。
发电是从一次能源中产生电力的过程。对于电力行业的电力公司来说,这是向终端用户输送电力的第一阶段,其它阶段是使用抽水蓄能方法进行的传输、分配、能量存储和回收。
电力的一个特征在于它不是自然界中大量自由存在的一次能源,且其必须生产。生产在发电厂进行。电力通常是由机电发电机在发电站产生的,机电发电机主要由以燃烧或核裂变为燃料的热机驱动,但也可以通过其它方式(诸如流动的水和风的动能)来驱动。其它能源包括太阳能光伏发电和地热发电。
从理论上讲,合成气由等摩尔量的氢气H2和一氧化碳CO和一氧化碳组成。
根据现有技术,由木质纤维素生物质气化获得的合成气由灰尘、焦油、卤素和带有无机杂质的碱性化合物等杂质(为硫化氢H2S、铵NH3、氯化氢HCl、甲烷和其它轻烃C2H6污染物)组成,并且需要在下游过程中使用催化剂以及特定的清洁操作和方法以去除这些污染物。
因此,需要耗时且非常昂贵的气体清洁以去除污染物并提供用于下游方法和合成气利用的规范内的合成气,同时需要气体调节系统以消除主要气体化合物并调节H2/CO比。
这里的主要步骤是碳氢化合物的重整,CO变换以调节H2/CO比以及去除CO2。
在通过清洁和调节进行这种耗时且昂贵的气体处理之后,从木质纤维素生物质中获得的合成气在化学上(CO,H2)与衍生自化石来源的合成气相似,并且可以在所有应用中替代其化石等效物。
因此,全球需要从非化石能源和可再生木质纤维素生物质原料,特别是农业生产和林业所产生的废物按需生产电力的方法,其使得有可能通过直接生产能源(例如生产绿色的或清洁的电能)来对聚合物工业中木质纤维素生物质的一部分成分和其它成分进行增值,从而达到最佳的能源、经济和生态平衡。
发明内容
本发明提出在电力发电厂中使用多个发电设施从非化石能源和可再生木质纤维素生物质原料按需发电的方法,该多个发电设施包括:
-i)至少一个用于从非化石能源发电的第一设施,所述能源选自风能、和/或水力和/或太阳能和/或地热能和/或潮汐能;和
-ii)至少一个第二设施,该第二设施使用在用于生产以下的方法的气化步骤e)期间生产的合成气:
-具有受控的脂族羟基含量和受控的酚羟基含量的非氧化、非降解和非结合的木质素;和
-合成气,
所述方法包括以下步骤:
a)通过在至少由水和甲酸组成的混合物存在下,在80℃-110℃的温度的受控条件下,将至少一种固态木质纤维素原料置于大气压下,其中所述至少一种固体木质纤维素原料/液体混合物的稀释比为1-15,并且取决于所述至少一种木质纤维素原料的性质,持续确定的一段时间,以提取木质素和半纤维素;
b)在大气压下,将在先前的提取步骤a)结束时获得的初级固体级分(PSF)和初级液体级分分馏;
c)通过蒸发-浓缩回收所述初级液体级分中包含的全部或部分有机酸,并获得中间液体级分;
d)将所述木质素与所述中间液体级分分离,并获得残余液体级分。
e)将至少一部分所述初级固体级分和/或至少一部分所述残余液体级分气化,以生产合成气。
根据本方法的其他方面:
-所述发电厂包括用于实施所述方法的设施;
-所述基于木质纤维素生物质的发电设施包括合成气存储设施。
本发明还提供在发电厂中使用多个发电设施从非化石能源和木质纤维素可再生生物质原料按需发电的发电厂,该多个发电设施至少包括:
-i)至少一个用于从非化石能源发电的第一设施,所述能源选自风能、和/或水力和/或太阳能和/或地热能和/或潮汐能;和
-ii)至少一个第二设施,该第二设施使用在来自可再生木质纤维素生物质原料的几个级分的气化步骤期间生产的合成气,该可再生木质纤维素生物质原料通过使用至少由水和甲酸组成的混合物实施有机溶剂法获得。
附图简要说明
将结合附图描述本发明,其中:
-图1示意性地示出了用于从木质纤维素原料生产合成气的基于酸的有机溶剂生产方法的实施例的主要步骤;
-图2是类似于图1的图,其示出了以能量自给的方式的合成气生产方法的改进;
-图3是根据本发明的发电厂的示意图,该发电厂包括用于实施图1所示的合成气生产方法的第二设施;和
-图4是根据本发明的发电厂的示意图,该发电厂包括用于实施图2所示的能量自给的合成气生产方法的第二设施。
具体实施方式
所有生物质都含有不同百分比的纤维素、半纤维素和木质素,以及作为灰分来源的无机成分。纤维素是包含通过醚键连接的脱水吡喃葡萄糖的直链聚合物。半纤维素是一种无定形多糖,其含有分支的糖单元和不同的糖类型。木质素是最复杂的成分,并且是苯基丙烷单元的聚合物结构。
生物质中最突出的成分是木质纤维素,其由植物材料的非淀粉纤维部分组成。纤维素、半纤维素和木质素是木质纤维素生物质的三种主要成分。纤维素与木质素的比例可以变化,并且纤维素和半纤维素的比例与气态产物的产率直接相关,而木质素含量决定了产物中的热解油。
已经发现存在于生物质原料中的纤维素、半纤维素和木质素部分在气化期间在不同的温度范围内降解。生物质原料中这些成分的变化产生具有不同热值的产品。在早期,纯纤维素的气化不会产生水溶性焦油。
这似乎是在热解过程中木质素/纤维素相互作用期间抑制木质素热聚合的结果。
因此,热解速率与纤维素级分直接相关,而与原料中木质素含量成反比。
如图1所示,在低温和大气压下使用水和甲酸(HCOOH)的混合物从生物质木质纤维素原料(LRM)中提取木质素的第一个实施例如下。
第一步在于使用比例为85重量%的甲酸和15重量%的水制备甲酸的水溶液。
在第二步中,将30克的木质纤维素原料(LRM)的干燥样品和270克的甲酸在水中的液体混合物引入500毫升玻璃反应器中。
因此,例如,液/固质量比(稀释比)等于9/1。
为了增加液体和固体之间的接触表面,可以将木质纤维素原料样品粉碎。
在环境/大气压下并使用油浴,将酸/水溶液和生物质木质纤维素原料样品的混合物在80℃-90℃的温度下加热。
因此,使用带有Inox锚的机械搅拌器将该混合物搅拌至均匀的温度。
使用温度计将温度稳定在85℃。
该提取步骤是非常低的能量消耗步骤(在低于110℃的低温下工作)。
在该时间段的反应结束时,将反应器的内容物冷却至环境温度,并且其含有固体级分和液体级分。
然后,将内容物过滤,以将原料固体纤维素(其在本发明的意义上构成初级固体级分PSF)与内容物的液相(其在本发明的意义上构成初级液体级分PLF的第一部分P1)分离。
已经用甲酸洗涤分离的纤维素,然后将其压榨并过滤,以以液体形式去除本发明的意义上的初级液体级分PLF的第二部分P2。
然后,将第一部分P1和第二部分P2混合在一起以获得初级液体级分PLF。
将该初级液体级分PLF进一步在真空下浓缩,优选在100毫巴的压力下、在40℃-50℃下加热。
该浓缩阶段一直保持到干物质含量约为50重量%-60重量%为止。
在此阶段,回收和分离初级液体级分PLF中所含的甲酸的所有部分,以获得本发明意义上的中间液体级分(ILF)。
似乎在提取步骤中可能会从非常少量的甲酸开始生成或产生一些其它有机酸,诸如乙酸(CH3CO2H)。在回收之后,除了上述用于制备水-酸混合物的甲酸以外,还使用这些其它酸。
为了从中间液体级分ILF中的半纤维素部分中分离或“提取”木质素,已将温水添加到中间液体级分ILF中,以达到例如等于4/1的液/固质量比。
为了增强木质素与半纤维素级分的分离,仅在例如2-3分钟的分散时间期间,以大于15000转/分钟的转速使用了高性能的转子/定子分散器。
在该分散步骤的最后,已经用过滤步骤对其进行处理,以将木质素与半纤维素级分分离,并获得了本发明意义上的残余液体级分RLF。
然后,将分离的木质素用温水洗涤,直到达到滤液的中性pH。
然后,将木质素粉碎并干燥直至达到干物质重量的94%,干燥温度不大于40℃。
在此阶段,该方法已允许获得:
A)-具有受控的脂族羟基含量和受控的酚羟基含量的非氧化、非降解和非结合的木质素;和
B)包括主要固体级分PSF和残余液体级分RLF的“化合物”或混合物,其可用于直接气化以生产用于产生能量的合成气,例如以电的形式。
可用于气化的这种PSF+RLF化合物已准备好进行气化,其含义是:
i)它不含被鉴定为是气化方法的抑制剂的任何木质素,或比例大大降低;
ii)对仅含糖的化合物进行气化方法;
iii)为了获得具有最佳和最大化学和能量效率的合成气,化合物中的糖的H/C比最有利,即由等摩尔量的一氧化碳CO和氢气H2组成。
iv)例如,与使用通过直接气化生物质(生物质气化)或从起始木质纤维素原料获得的材料获得的合成气的已知发电方法(例如通过已知的有机溶剂法,但含有木质素和/或半纤维素)进行比较时,为了从通过化合物气化获得的合成气中发电,合成气净化阶段不再是必需的,或者被减少到最小,并且也避免或减少了固有的存在灰分的问题。
鉴于根据本发明的用于气化的化合物的上述特性以及从该化合物开始获得的合成气的特性和质量,为了有效地发电,可以将根据本发明获得的合成气称为“E2合成气”,以代表“电力高效的合成气”或“能源高效的合成气”。
如附图所示,在产生电或任何其它能量(例如蒸汽)之前,可以将合成气存储在非示例的存储设施中,最好直接存储,而无需任何转化或任何添加,以维护其高效的发电性能。
用于生产合成气的上述方法可以使用用于提取步骤a)的分批技术在工业上实施,其还包括搅拌每批的内容物。
与意味着需要较长且耗能的提取时间的扩散技术相比,这是有利的。
与意味着根据用作原料的植物废料,通过切碎、粉碎、微粉化等方式对木质纤维素原料(LRM)进行特定的“校准”制备步骤的扩散技术相比,这也是有利的。
如图2所示,通过使用在使用E2合成气作为能量生产合成气中产生的电力和/或任何其它能量(例如蒸汽)和例如在85℃下、使用甲酸的提取步骤中,可以将已参考图1所述的方法设计为能量自给方法。
本发明提出使用“E2合成气”作为非化石能源用于发电,即用于从发电厂中的可再生木质纤维素生物质原料发电的方法,以及根据从非化石能源(NFPS)和可再生木质纤维素生物质原料(LRM)按需发电方法。
因此,本发明提出用于从可再生电源发电的方法。
本发明还提出从非化石能源和至少木质纤维素可再生生物质原料按需连续发电的方法。
可以在如图3所示的用于发电的设施或工厂(发电厂)中实施该方法,该设施或工厂至少包括:
-用于使用非化石能源发电的第一种设施(第一设施);和
-使用可再生木质纤维素生物质原料(LRM)的第二种设施(第二设施),以用于生产根据上述方法获得的E2合成气。
可以从太阳能、风能、波浪能、潮汐能、地热能和/或水力中选择可再生非化石能源。
除了上述使用根据上述方法获得的E2合成气的优势外,木质纤维素原料确实表现为(当从非化石能源(NFPS)发电不可用或不足够可用)可用于从非化石能源(NFPS)发电的“后备燃料”或“后备能源”。
例如,在夜间太阳能、没有足够的风、潮落时、水电站大坝为“空”时,就是这种情况。
这种燃料源或能源是两种方式的备用解决方案。
首先,可再生的木质纤维素原料可以容易地存储在第一设施中。
其次,E2合成气可以容易地存储在任何适当的存储设施中,并按需分配到第二设施的发电装置。
Claims (3)
1.在电力发电厂中使用多个发电设施从非化石能源(NFPS)和可再生木质纤维素生物质原料(LRM)按需发电的方法,该多个发电设施包括:
-i)至少一个用于从非化石能源(NFPS)发电的第一设施,所述能源选自风能、和/或水力和/或太阳能和/或地热能和/或潮汐能;和
-ii)至少一个第二设施,该第二设施使用在用于生产以下的方法的气化步骤e)期间生产的合成气:
-具有受控的脂族羟基含量和受控的酚羟基含量的非氧化、非降解和非结合的木质素;和
-合成气,
所述方法包括以下步骤:
a)通过在至少由水和甲酸组成的混合物存在下,在80℃-110℃的温度的受控条件下,将至少一种固态木质纤维素原料置于大气压下,其中所述至少一种固体木质纤维素原料/液体混合物的稀释比为1-15,并且取决于所述至少一种木质纤维素原料的性质,持续确定的一段时间,以提取木质素和半纤维素;
b)在大气压下,将在先前的提取步骤a)结束时获得的初级固体级分(PSF)和初级液体级分(PLF)分馏;
c)通过蒸发-浓缩回收所述初级液体级分(PLF)中包含的全部或部分有机酸,并获得中间液体级分(ILF);
d)将所述木质素与所述中间液体级分(ILF)分离,并获得残余液体级分(RLF);
e)将至少一部分所述初级固体级分(PSF)和/或至少一部分所述残余液体级分(RLF)气化,以生产合成气。
2.根据权利要求1所述的方法,其中基于木质纤维素生物质的发电设施包括合成气存储设施。
3.根据权利要求1所述的方法,其中通过添加水通过沉淀将木质素与所述中间液体级分(ILF)分离。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP18157086.2 | 2018-02-16 | ||
EP18157086.2A EP3527608A1 (en) | 2018-02-16 | 2018-02-16 | A method and a power plant for on-demand producing electricity from non-fossil power sources and from a renewable lignocellulosic biomass feedstock |
PCT/EP2019/053379 WO2019158500A1 (en) | 2018-02-16 | 2019-02-12 | A method and a power plant for on-demand producing electricity from non-fossil power sources and from a renewable lignocellulosic biomass feedstock |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111801370A CN111801370A (zh) | 2020-10-20 |
CN111801370B true CN111801370B (zh) | 2023-03-28 |
Family
ID=61231105
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201980013674.6A Active CN111801370B (zh) | 2018-02-16 | 2019-02-12 | 从非化石能源和可再生木质纤维素生物质原料按需发电的方法和发电厂 |
CN201980013691.XA Active CN111902362B (zh) | 2018-02-16 | 2019-02-15 | 由可再生木质纤维素生物质原料生产纯的且高度浓缩的二氧化碳的方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201980013691.XA Active CN111902362B (zh) | 2018-02-16 | 2019-02-15 | 由可再生木质纤维素生物质原料生产纯的且高度浓缩的二氧化碳的方法 |
Country Status (5)
Country | Link |
---|---|
US (2) | US20210003073A1 (zh) |
EP (3) | EP3527608A1 (zh) |
CN (2) | CN111801370B (zh) |
CA (2) | CA3091064A1 (zh) |
WO (2) | WO2019158500A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114856499A (zh) * | 2022-05-12 | 2022-08-05 | 重庆大学 | 原位氧化生成二氧化碳提高煤层气井产量方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2468483A (en) * | 1947-07-08 | 1949-04-26 | Carl C Chambers | Periodic signaling apparatus |
ES2209424T3 (es) * | 1999-05-06 | 2004-06-16 | Compagnie Industrielle De La Matiere Vegetale | Procedimiento de produccion de pasta de papel, ligninas, azucares y acido acetico mediante funcionamiento de material vegetal lignocelulosico en un medio de acido acetico/formico. |
CN101117777A (zh) * | 2007-08-20 | 2008-02-06 | 南京大学 | 提高木质纤维素原料生物转化率的预处理方法 |
GB2468483A (en) * | 2009-03-09 | 2010-09-15 | Stratos Fuels Ltd | Synthesising carbon-based fuels from carbon dioxide |
US20120202260A1 (en) * | 2009-09-04 | 2012-08-09 | Lignol Innovations Ltd. | Hybrid biorefining and gasification of lignocellulosic feedstocks |
US20110113778A1 (en) * | 2009-11-16 | 2011-05-19 | Bronicki Lucien Y | Apparatus and method for using solar power in existing power plants |
FR2966154B1 (fr) * | 2010-10-13 | 2014-05-16 | Cie Ind De La Matiere Vegetale Cimv | Procede perfectionne d'hydrolyse enzymatique de la cellulose |
BR112014027001A2 (pt) * | 2012-04-30 | 2017-06-27 | Bp Corp North America Inc | processo de conversão lignocelulósico com separação de tecido |
CN110127608A (zh) * | 2012-09-18 | 2019-08-16 | 质子电力公司 | 用于生产氢或液态燃料的c-o-h化合物处理方法 |
US20140283439A1 (en) * | 2013-03-21 | 2014-09-25 | Syngas Technology, Llc | Pretreatment of Biomass Feed for Gasification |
US20170002387A1 (en) * | 2013-05-28 | 2017-01-05 | Api Intellectual Property Holdings, Llc | Processes for fermentation of lignocellulosic glucose to aliphatic alcohols or acids |
CA2933132C (en) * | 2013-12-11 | 2023-04-04 | Neste Oyj | Method of processing lignocellulosic material using a cationic compound |
US9505668B2 (en) * | 2014-05-01 | 2016-11-29 | Iogen Corporation | Process for producing a fuel and byproduct from biomass or biomass derived material |
US9108894B1 (en) * | 2014-07-22 | 2015-08-18 | Iogen Corporation | Process for using biogenic carbon dioxide derived from non-fossil organic material |
US20160130369A1 (en) * | 2014-11-11 | 2016-05-12 | Api Intellectual Property Holdings, Llc | Fractionation processes for high-ash lignocellulosic biomass feedstocks |
AU2016218259A1 (en) * | 2015-02-10 | 2017-08-24 | Ciris Energy, Inc. | Depolymerization process |
EP3294689A4 (en) * | 2015-05-13 | 2019-02-13 | Biocarb Pty Ltd | nutrient system |
CN105507051A (zh) * | 2015-11-23 | 2016-04-20 | 中国科学院青岛生物能源与过程研究所 | 一种高效分离木质纤维原料的方法 |
US20170159076A1 (en) * | 2015-12-04 | 2017-06-08 | Arbiom Inc. | Method for fractionating a lignocellulosic biomass |
CN105420289B (zh) * | 2015-12-09 | 2019-02-05 | 清华大学 | 一种以木质纤维素为原料联产乙醇和电能的方法 |
EP3527531A1 (en) * | 2018-02-16 | 2019-08-21 | Michel Delmas | A lignocellulosic biomass based process for production of lignins and syngas, and electricity production efficient syngas |
EP3527591A1 (en) * | 2018-02-20 | 2019-08-21 | Compagnie Industrielle De La Matiere Vegetale CIMV | Method of production of lignin and hemicellulose from a plant lignocellulosic material |
EP3771738A1 (en) * | 2019-07-30 | 2021-02-03 | Michel Delmas | A method to convert a cellulosic fraction into fischer tropsch products, using a lignocellulosic raw material based process for production of synthetic gas |
-
2018
- 2018-02-16 EP EP18157086.2A patent/EP3527608A1/en not_active Withdrawn
-
2019
- 2019-02-12 CA CA3091064A patent/CA3091064A1/en active Pending
- 2019-02-12 US US16/969,724 patent/US20210003073A1/en active Pending
- 2019-02-12 CN CN201980013674.6A patent/CN111801370B/zh active Active
- 2019-02-12 WO PCT/EP2019/053379 patent/WO2019158500A1/en unknown
- 2019-02-12 EP EP19708237.3A patent/EP3752550A1/en active Pending
- 2019-02-15 US US16/969,727 patent/US11952282B2/en active Active
- 2019-02-15 EP EP19705507.2A patent/EP3752459A1/en active Pending
- 2019-02-15 CA CA3091061A patent/CA3091061A1/en active Pending
- 2019-02-15 WO PCT/EP2019/053783 patent/WO2019158680A1/en unknown
- 2019-02-15 CN CN201980013691.XA patent/CN111902362B/zh active Active
Non-Patent Citations (1)
Title |
---|
地热和生物质燃气联合发电系统建模与热力性能分析;赵波等;《东北电力大学学报》;20160215;第36卷(第1期);第2部分 * |
Also Published As
Publication number | Publication date |
---|---|
EP3527608A1 (en) | 2019-08-21 |
US11952282B2 (en) | 2024-04-09 |
US20210002568A1 (en) | 2021-01-07 |
CN111801370A (zh) | 2020-10-20 |
CA3091064A1 (en) | 2019-08-22 |
EP3752550A1 (en) | 2020-12-23 |
WO2019158500A1 (en) | 2019-08-22 |
CA3091061A1 (en) | 2019-08-22 |
US20210003073A1 (en) | 2021-01-07 |
CN111902362B (zh) | 2023-07-07 |
CN111902362A (zh) | 2020-11-06 |
WO2019158680A1 (en) | 2019-08-22 |
EP3752459A1 (en) | 2020-12-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8217211B2 (en) | Process for producing liquid hydrocarbon by pyrolysis of biomass in presence of hydrogen from a carbon-free energy source | |
US20130137783A1 (en) | Storage of intermittent renewable as fuel using carbon containing feedstock | |
CN111886199A (zh) | 基于木质纤维素生物质的生产木质素和合成气以及电力产生高效的合成气的方法 | |
CN111801370B (zh) | 从非化石能源和可再生木质纤维素生物质原料按需发电的方法和发电厂 | |
US20220325187A1 (en) | Method to convert a cellulosic fraction into fischer tropsch products, using a lignocellulosic raw material based process for production of synthetic gas | |
Dinjus et al. | Green fuels–sustainable solutions for transportation | |
Antony et al. | Advanced Techniques for Bio‐Methanol Production | |
CN114477083B (zh) | 利用废弃物自供氢气和溶剂的生物质炼制方法及系统 | |
Johnson et al. | Cost-effective method for pretreatment of pearl millet biomass using catalytic downflow liquid contact reactor | |
Ramesh et al. | Thermochemical conversion methods of bio-derived lignocellulosic waste molecules into renewable fuels | |
Dash et al. | Fuel-Purpose Bioethanol from Agricultural Waste: A Step Towards Sustainable Environment and Energy Security | |
Nasir et al. | Hydrothermal Liquefaction of Lignocellulosic Biomass to Liquid Biofuels: A Review | |
Steinberg | Nuclear power for the production of synthetic fuels and feedstocks | |
Regalbuto et al. | Hydrocarbon fuels from lignocellulose | |
Godbolea et al. | Biomass to Biofuel: A Review of Technologies of Production and Future Prospects | |
Demirbas | 2 World Biofuel Scenario | |
Kumarb | M. Ramesha, K. Adithyab, CM Jagadesh Kumarb, CG Mohanb, Jayant Nalawadeb, R. Prakashb | |
Joshi et al. | Chemical Processing Techniques Related to Bio-Waste for Their Conversion to Biofuel | |
Klass | Research, development, and commercialization activities on biomass energy in the United States | |
Ghergheleş et al. | Fuel production from biomass: generation of liquid biofuels | |
Demirbas | Biochemical Processes | |
Baughman et al. | Alternative central-station electric power generation technologies: a consistent engineering-economic framework of comparison | |
Klass | 17. OVERVIEW OF ENERGY AND SYNFUELS FROM BIOMASS AND WASTES | |
Kanan et al. | SEMINAR REPORT | |
Olson et al. | Nonaqueous enzymatic synthesis of ester fuels |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |