CN111790243A - Disposable waste gas adsorption device, system and use method - Google Patents

Disposable waste gas adsorption device, system and use method Download PDF

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Publication number
CN111790243A
CN111790243A CN202010791582.5A CN202010791582A CN111790243A CN 111790243 A CN111790243 A CN 111790243A CN 202010791582 A CN202010791582 A CN 202010791582A CN 111790243 A CN111790243 A CN 111790243A
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CN
China
Prior art keywords
disposable
adsorption device
gas adsorption
waste gas
exhaust gas
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Pending
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CN202010791582.5A
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Chinese (zh)
Inventor
高月静
罗忌斌
张乐
刘样
王刚
刘琼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunresin New Materials Co ltd Xi'an
Gaoling Lanxiao Science And Technology New Materials Co ltd
Original Assignee
Sunresin New Materials Co ltd Xi'an
Gaoling Lanxiao Science And Technology New Materials Co ltd
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Application filed by Sunresin New Materials Co ltd Xi'an, Gaoling Lanxiao Science And Technology New Materials Co ltd filed Critical Sunresin New Materials Co ltd Xi'an
Priority to CN202010791582.5A priority Critical patent/CN111790243A/en
Publication of CN111790243A publication Critical patent/CN111790243A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/30Particle separators, e.g. dust precipitators, using loose filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a disposable waste gas adsorption device, a system and a use method, wherein the disposable waste gas adsorption device comprises a cylinder body, the top end of the cylinder body is provided with a first opening, and a first flange is arranged on the first opening; the end cover is connected to the cylinder body in a sealing mode through the second flange and the third flange, the bottom end of the end cover is provided with a second opening, and the second opening is provided with a fourth flange; the filter is arranged in the cylinder body, and the filter is filled with adsorption filtering materials. The disposable waste gas adsorption device is suitable for systems with small exhaust volume but serious air pollution; can deal with waste gas with complex components and is flexible to use.

Description

Disposable waste gas adsorption device, system and use method
Technical Field
The invention belongs to the technical field of waste gas treatment, and particularly relates to a disposable waste gas adsorption device, a disposable waste gas adsorption system and a use method.
Background
In order to protect and improve the environment, guarantee public health, promote ecological civilization construction, promote sustainable development of economy and society, and prevent and treat atmospheric pollution, strict control on the emission of waste gas pollutants of various enterprises is required. At present, whether the emission of the waste gas pollutants of industrial enterprises reaches the standard or not becomes one of the key factors restricting the development of the enterprises.
Because the components of the waste gas are complex and diverse, enterprises select proper treatment ways to comprehensively treat and utilize the waste gas according to the characteristics and specific conditions of the waste gas, such as spraying, carbon fiber adsorption, RTO incineration, high polymer material adsorption and the like, and the methods are widely popularized and applied. However, most of the existing exhaust gas treatment methods are directed to large-scale discharge devices with large discharge amount, and each method is directed to a narrow field, and the targeted discharge gas is single and can not be used universally.
In the resin column device for treating the VOCs gas disclosed in Chinese patent CN109499266A, the VOCs gas can effectively treat the waste gas by the device to reach the discharge standard, and the effective components are recycled. However, the device and the method mainly aim at treating gases with large system discharge amount and single waste gas components, and cannot be applied to small-sized discharge devices with small system discharge amount and complex waste gas components.
Therefore, the development of an exhaust gas treatment device is urgently needed, and the device can treat toxic, odorous and volatile exhaust gas with low system emission, high air pollution and complex exhaust gas components.
Disclosure of Invention
The invention aims to provide a disposable waste gas adsorption device which is particularly suitable for a waste gas discharge system with small discharge capacity, can be used for dealing with various waste gas discharges with complex components by selecting a filter element according to needs, and is simple and flexible; in addition, the invention also provides a system provided with the disposable waste gas adsorption device and a using method of the disposable waste gas adsorption device.
On one hand, in order to achieve the purpose, the technical scheme of the invention is as follows: a disposable waste gas adsorption device comprises a cylinder body, wherein a first opening is formed in the top end of the cylinder body, and a first flange is arranged on the first opening; the cylinder body is provided with a first flange, a second flange is arranged on an opening at the top end of the end cover, a third flange is arranged on an opening at the bottom end of the cylinder body, the end cover is connected to the cylinder body through the second flange and the third flange in a sealing mode, a second opening is formed in the bottom end of the end cover, and a fourth flange is arranged on the second opening; the filter is arranged in the cylinder body, and an adsorption filtering material is filled in the filter.
According to the disposable waste gas adsorption device, the adsorption material in the filter can be replaced according to the type of waste gas, and the bolt connection between the second flange and the third flange can be detached for replacement. The disposable set may be mounted on an exhaust line, which may be an exhaust line of a small exhaust emission system, including but not limited to a container in which harmful substances are stored, through the first flange and the fourth flange. According to one embodiment of the invention, a plurality of capacity-increasing cylinder sections are further arranged between the second flange and the third flange, and connecting flanges are arranged at two ends of each capacity-increasing cylinder section. The size of the cylinder body and the size of the filter can be adjusted according to the components and the discharge amount of the waste gas, and the use is more flexible.
According to the disposable exhaust gas adsorption device, preferably, the adsorption filter material is at least one selected from adsorption resin, activated carbon and molecular sieve.
According to the disposable exhaust gas adsorption device, preferably, the material of the cylinder is selected from one of stainless steel, carbon steel or polypropylene.
A disposable exhaust gas adsorbing device according to the present invention, preferably, the housing of the filter is one of a johnson mesh, a tiled micro-mesh or a perforated plate; the material of the filter is selected from one of stainless steel, carbon steel or polypropylene.
According to the disposable exhaust gas adsorption device, the end cover is preferably in a truncated cone shape, a cylindrical shape or a circular arc shape.
According to the disposable exhaust gas adsorption device, a sealing mechanism is preferably arranged between the second flange and the third flange.
In another aspect, the present invention also provides a system installed with the disposable exhaust gas adsorption device as described above, preferably, comprising a container storing harmful substances, the container being provided with an exhaust gas line for discharging exhaust gas from the container, the disposable exhaust gas adsorption device being installed on the exhaust gas line through a first flange and a fourth flange; and a VOC detector is arranged on a waste gas pipeline at the downstream of the disposable waste gas adsorption device.
The system according to the present invention preferably further comprises a nitrogen-sealed line connected to the exhaust line upstream of the disposable exhaust gas adsorption device, the nitrogen-sealed line being configured to provide sealed nitrogen gas to the container storing the hazardous substance; and the nitrogen seal pipeline is sequentially provided with a nitrogen inlet switch valve, a pressure reducing valve and a nitrogen outlet switch valve. When the nitrogen seal is normal, the nitrogen seal pipeline provides sealed nitrogen to prevent the container with the stored harmful substances from discharging unqualified waste gas outwards; when the nitrogen seal became invalid, the container storing harmful substances began to discharge waste gas outwards, and the waste gas was adsorbed through disposable waste gas adsorption device on the waste gas pipeline and was handled, guaranteed to reach emission standard through the detection of VOC detector and in time change disposable waste gas adsorption device. The container storing harmful substances is a small waste gas discharge system, the components of the discharged waste gas are different, and the disposable waste gas adsorption device can be flexibly treated.
In another aspect, the present invention further provides a method for using the disposable exhaust gas adsorption device, including the following steps:
(1) providing a disposable exhaust gas adsorption unit as described above; the waste gas enters from the first opening of the disposable waste gas adsorption device and is discharged through the second opening to pass through the disposable waste gas adsorption device; controlling the passing time to be 0.5-20 s;
(2) detecting the waste gas discharged from the second opening through a VOC detector; when the detection result is not higher than the preset value, the current disposable waste gas adsorption device is continuously used; and when the detection result exceeds a preset value, the disposable exhaust gas adsorption device is replaced by a new disposable exhaust gas adsorption device.
According to the using method, the VOC detector detects the VOC at intervals of a preset time period.
In still another aspect, the present invention provides another method for using the disposable exhaust gas adsorption device, including the following steps:
(1) providing a disposable exhaust gas adsorption unit as described above; the waste gas enters from the second opening of the disposable waste gas adsorption device and is discharged through the first opening to pass through the disposable waste gas adsorption device; controlling the passing time to be 0.5-20 s;
(2) detecting the waste gas discharged from the first opening through a VOC detector; when the detection result is not higher than the preset value, the current disposable waste gas adsorption device is continuously used; and when the detection result exceeds a preset value, the disposable exhaust gas adsorption device is replaced by a new disposable exhaust gas adsorption device.
The invention has the beneficial effects that:
the disposable waste gas adsorption device is particularly suitable for systems with small exhaust volume but serious air pollution; different adsorbing materials can be configured according to requirements, and the method can be applied to different types of waste gas treatment; the structure is simple and easy to manufacture, the replacement is simple and convenient, and the regeneration treatment is not needed;
the optimal technical scheme of the invention is mainly to increase a reliable emission guarantee through the disposable waste gas adsorption device aiming at the storage equipment of the existing nitrogen sealing system for discharging toxic and harmful gases, and can ensure that the overproof emission condition does not occur under the condition that the nitrogen sealing system fails. Through the operation data display of a plurality of projects, the emission qualified rate can reach 100 percent by utilizing the device and the method.
Drawings
FIG. 1 is a schematic view of the structure of a disposable exhaust gas adsorption unit of the present invention;
FIG. 2 is a schematic view showing the construction of a system of the present invention in which a disposable exhaust gas adsorbing device is installed;
in the figure, 1-a first flange, 2-a cylinder, 3-a filter, 4-a third flange, 5-a sealing gasket, 6-a second flange, 7-an end cover, 8-a fourth flange, 9-a gas inlet switch valve, 10-a nitrogen outlet switch valve, 11-a tank breathing system switch valve, 12-a nitrogen device, 13-a waste gas outlet switch valve, 14-a pressure reducing valve, 15-a disposable waste gas adsorption device and 16-a container.
Detailed Description
The technical solution in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings.
Examples1
As shown in fig. 1-2, a disposable exhaust gas adsorption device 15 of the present embodiment includes a cylinder 2, a first opening is disposed at a top end of the cylinder 2, and a first flange 1 is disposed on the first opening; the cylinder is characterized by further comprising an end cover 7, the end cover 7 is in an inverted circular truncated cone shape, a second flange 6 is arranged on an opening in the top end of the end cover 7, a third flange 4 is arranged on an opening in the bottom end of the cylinder body 2, the end cover 7 is connected to the cylinder body through the second flange 6 and the third flange 4 in a sealing mode, a sealing gasket 5 is arranged between the second flange 6 and the third flange 4 and connected through bolts, a second opening is formed in the bottom end of the end cover 7, and a fourth flange 8 is arranged on the second opening; a filter 3 is arranged in the cylinder 2, and an adsorption filtering material is filled in the filter 3; the adsorption filtering material selects at least one of adsorption resin, activated carbon and molecular sieve according to the type of the adsorbed waste gas;
wherein, the material of barrel 2 and filter 3 is stainless steel, and the casing of filter 3 is johnson's net structure, tiling microgroove net structure or porous plate structure one of.
Example 2
The system of the present embodiment is equipped with the disposable exhaust gas adsorption device of embodiment 1, which includes a container 16 for storing harmful substances, a waste gas pipeline is provided on the container 16, the waste gas pipeline is used for discharging the waste gas in the container 16, the disposable exhaust gas adsorption device 15 is installed on the waste gas pipeline through a first flange 1 and a fourth flange 8, wherein the first flange 1 is provided at the downstream of the fourth flange 8; a tank breathing system switch valve 11 and a waste gas outlet switch valve 13 are arranged on waste gas pipelines at two sides of the disposable waste gas adsorption device 15, and a VOC detector is arranged on the waste gas pipeline at the downstream of the disposable waste gas adsorption device 15;
the device also comprises a nitrogen sealing pipeline, wherein the inlet of the nitrogen sealing pipeline is connected with the nitrogen device 12, the outlet of the nitrogen sealing pipeline is connected with the exhaust pipeline at the upstream of the disposable exhaust adsorption device 15 and at the downstream of the tank body respiratory system switch valve 11, and the nitrogen sealing pipeline is used for providing sealing nitrogen for the container 16 with the stored harmful substances; and a nitrogen inlet switch valve 9, a pressure reducing valve 14 and a nitrogen outlet switch valve 10 are sequentially arranged on the nitrogen sealing pipeline.
Example 3
The system in this embodiment has the same structure as that in embodiment 2 except for the following structure.
The disposable exhaust gas adsorption device 15 is installed on the exhaust gas pipeline by a first flange 1 and a fourth flange 8, wherein the first flange 1 is provided upstream of the fourth flange 8.
Example 4
This example provides a method of using the disposable exhaust gas adsorption unit of example 1, comprising the steps of:
(1) the waste gas discharged from the waste discharge line equipped with the container 16 for tetraethyl lead and dibromoethane enters from the second opening of the disposable waste gas adsorption device 15 provided in example 1 and is discharged through the first opening, and the time from the entrance to the discharge is 0.5 s;
(2) detecting the exhaust gas discharged from the first opening every 20min by a VOC detector (model: RAE 3000); when the detection result is not higher than 20mg/m3Continuing to use the current disposable exhaust gas adsorption device 15; when the detection result exceeds 20mg/m3The disposable exhaust gas adsorbing device 15 is replaced with a new one.
Wherein, the filter 3 is made of stainless steel and has Johnson net structure, the specification is a cylinder with the diameter of 160mm and the height of 180mm, and 3.5L of LXQ-10 macroporous absorption resin sold in Xian blue Xiao science and technology is filled in the filter. Experiments prove that the detection results of the VOC detector are within 16h of the nitrogen seal failure of the tetraethyl lead and dibromoethane container 16Less than 20mg/m3
Example 5
This example provides a method of using the disposable exhaust gas adsorption unit of example 1, comprising the steps of:
(1) the waste gas discharged from the waste discharge line equipped with the dichloromethane container 16 enters from the second opening of the disposable waste gas adsorption device 15 provided in example 1 and is discharged through the first opening, and the time from the entering to the discharging is 3 s;
(2) detecting the exhaust gas discharged from the first opening every 20min by a VOC detector (model: RAE 3000); when the detection result is not higher than 22mg/m3Continuing to use the current disposable exhaust gas adsorption device 15; when the detection result exceeds 22mg/m3The disposable exhaust gas adsorbing device 15 is replaced with a new one.
Wherein, the filter 3 is made of stainless steel material and has a flat dense-grain net structure, the specification is a cylinder with the diameter of 300mm and the height of 600mm, and 40 liters of wood columnar activated carbon is filled in the filter. Experiments prove that the detection results of the VOC detector are all less than 22mg/m within 30 days of failure of the nitrogen seal of the dichloromethane container 163
Example 6
This example provides a method of using the disposable exhaust gas adsorption unit of example 1, comprising the steps of:
(1) the waste gas discharged from the waste discharge line equipped with the ethyl acetate container 16 entered from the second opening of the disposable waste gas adsorption device 15 provided in example 1 and was discharged through the first opening, and the time from the entry to the discharge was 10 seconds;
(2) detecting the exhaust gas discharged from the first opening every 20min by a VOC detector (model: RAE 3000); when the detection result is not higher than 51mg/m3Continuing to use the current disposable exhaust gas adsorption device 15; when the detection result exceeds 51mg/m3The disposable exhaust gas adsorbing device 15 is replaced with a new one.
Wherein, the filter 3 is made of stainless steel and has a porous plate structure, the specification is a cylinder with the diameter of 200mm and the height of 350mm, and 10 liters of inorganic molecular sieve is filled in the filter. Experiments have shown that, within 15d of failure of the nitrogen seal of the ethyl acetate container 16,the detection results of the VOC detector are all less than 51mg/m3
The described embodiments are only some embodiments of the invention, not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Claims (10)

1. A disposable waste gas adsorption device is characterized by comprising a cylinder body, wherein a first opening is formed in the top end of the cylinder body, and a first flange is arranged on the first opening; the cylinder body is provided with a first flange, a second flange is arranged on an opening at the top end of the end cover, a third flange is arranged on an opening at the bottom end of the cylinder body, the end cover is connected to the cylinder body through the second flange and the third flange in a sealing mode, a second opening is formed in the bottom end of the end cover, and a fourth flange is arranged on the second opening; the filter is arranged in the cylinder body, and an adsorption filtering material is filled in the filter.
2. The disposable exhaust gas adsorption device of claim 1, wherein the adsorption filter material is at least one selected from the group consisting of an adsorbent resin, activated carbon, and a molecular sieve.
3. A disposable exhaust gas adsorption device according to claim 1, wherein the material of the cartridge is selected from one of stainless steel, carbon steel or polypropylene.
4. A disposable exhaust gas adsorption device according to claim 1, wherein the housing of the filter is one of a johnson mesh, a tiled, micro-corrugated mesh or a perforated plate; the material of the filter is selected from one of stainless steel, carbon steel or polypropylene.
5. The disposable exhaust gas adsorption device of claim 1, wherein the end cap is in the shape of a truncated cone, a cylinder, or a circular arc.
6. A disposable exhaust gas adsorption device according to claim 5, wherein a sealing mechanism is provided between said second flange and said third flange.
7. A system equipped with a disposable exhaust gas adsorbing device as set forth in any of claims 1 to 6, comprising a container for storing a harmful material, the container being provided with an exhaust gas line for discharging exhaust gas from the container, the disposable exhaust gas adsorbing device being mounted on the exhaust gas line via a first flange and a fourth flange; and a VOC detector is arranged on a waste gas pipeline at the downstream of the disposable waste gas adsorption device.
8. The system of claim 7, further comprising a nitrogen-sealed line connected to the exhaust line upstream of the disposable exhaust gas adsorption unit, the nitrogen-sealed line configured to provide sealed nitrogen gas to the hazardous material storage container; and the nitrogen seal pipeline is sequentially provided with a nitrogen inlet switch valve, a pressure reducing valve and a nitrogen outlet switch valve.
9. The use method of the disposable waste gas adsorption device is characterized by comprising the following steps:
(1) providing a disposable exhaust gas adsorption unit according to any one of claims 1 to 6; the waste gas enters from the first opening of the disposable waste gas adsorption device and is discharged through the second opening to pass through the disposable waste gas adsorption device; controlling the passing time to be 0.5-20 s;
(2) detecting the waste gas discharged from the second opening through a VOC detector; when the detection result is not higher than the preset value, the current disposable waste gas adsorption device is continuously used; and when the detection result exceeds a preset value, the disposable exhaust gas adsorption device is replaced by a new disposable exhaust gas adsorption device.
10. The use method of the disposable waste gas adsorption device is characterized by comprising the following steps:
(1) providing a disposable exhaust gas adsorption unit according to any one of claims 1 to 6; the waste gas enters from the second opening of the disposable waste gas adsorption device and is discharged through the first opening to pass through the disposable waste gas adsorption device; controlling the passing time to be 0.5-20 s;
(2) detecting the waste gas discharged from the first opening through a VOC detector; when the detection result is not higher than the preset value, the current disposable waste gas adsorption device is continuously used; and when the detection result exceeds a preset value, the disposable exhaust gas adsorption device is replaced by a new disposable exhaust gas adsorption device.
CN202010791582.5A 2020-08-07 2020-08-07 Disposable waste gas adsorption device, system and use method Pending CN111790243A (en)

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CN202010791582.5A CN111790243A (en) 2020-08-07 2020-08-07 Disposable waste gas adsorption device, system and use method

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Application Number Priority Date Filing Date Title
CN202010791582.5A CN111790243A (en) 2020-08-07 2020-08-07 Disposable waste gas adsorption device, system and use method

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008302348A (en) * 2007-06-11 2008-12-18 Ooden:Kk Exhaust gas treatment monitor/monitoring method, exhaust gas treating device
CN202638228U (en) * 2012-07-05 2013-01-02 天津市艾奇科技发展有限公司 Waste gas treatment device
CN107252616A (en) * 2017-08-11 2017-10-17 河北先河正源环境治理技术有限公司 VOCs absorptive collection devices
CN206762590U (en) * 2017-05-28 2017-12-19 立邦工业涂料(上海)有限公司 A kind of device for reducing solvent tank VOC volatilizations
CN108689441A (en) * 2018-05-21 2018-10-23 山东京博石油化工有限公司 A kind of sewage stripping system and its water storage device
CN109847417A (en) * 2017-11-30 2019-06-07 南通星辰合成材料有限公司 A kind of high organic wastewater with high salt is temporary and precipitates storage tank
CN212548897U (en) * 2020-08-07 2021-02-19 高陵蓝晓科技新材料有限公司 Disposable waste gas adsorption device and system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008302348A (en) * 2007-06-11 2008-12-18 Ooden:Kk Exhaust gas treatment monitor/monitoring method, exhaust gas treating device
CN202638228U (en) * 2012-07-05 2013-01-02 天津市艾奇科技发展有限公司 Waste gas treatment device
CN206762590U (en) * 2017-05-28 2017-12-19 立邦工业涂料(上海)有限公司 A kind of device for reducing solvent tank VOC volatilizations
CN107252616A (en) * 2017-08-11 2017-10-17 河北先河正源环境治理技术有限公司 VOCs absorptive collection devices
CN109847417A (en) * 2017-11-30 2019-06-07 南通星辰合成材料有限公司 A kind of high organic wastewater with high salt is temporary and precipitates storage tank
CN108689441A (en) * 2018-05-21 2018-10-23 山东京博石油化工有限公司 A kind of sewage stripping system and its water storage device
CN212548897U (en) * 2020-08-07 2021-02-19 高陵蓝晓科技新材料有限公司 Disposable waste gas adsorption device and system

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