CN111777906A - Color gold glaze paint and preparation method thereof - Google Patents

Color gold glaze paint and preparation method thereof Download PDF

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Publication number
CN111777906A
CN111777906A CN201910264565.3A CN201910264565A CN111777906A CN 111777906 A CN111777906 A CN 111777906A CN 201910264565 A CN201910264565 A CN 201910264565A CN 111777906 A CN111777906 A CN 111777906A
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China
Prior art keywords
percent
agent
preservative
diatomite
titanium dioxide
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201910264565.3A
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Chinese (zh)
Inventor
孔海法
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Guangdong Shunde Hongyan Building Materials Co ltd
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Guangdong Shunde Hongyan Building Materials Co ltd
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Priority to CN201910264565.3A priority Critical patent/CN111777906A/en
Publication of CN111777906A publication Critical patent/CN111777906A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a color gold glaze paint which comprises the following components in parts by mass: 30-40% of acrylic acid synthetic emulsion; dispersing agent: 0.5% -1%; 0.3 to 0.5 percent of defoaming agent; wetting agent: 0.3% -0.5%; film-forming auxiliary agent: 2% -3%; an antifreezing agent: 2% -3%; preservative: 0.3% -0.5%; mildew preventive: 0.5% -0.8%; thickening agent: 1% -2%; leveling agent: 1% -2%; titanium dioxide: 3% -5%; pearl powder: 15% -20%; diatomite: 3% -5%; emery: 20% -30%; silicon dioxide: 2% -4%; and (5) residual water. The paint prepared by adopting the formula has beautiful color, and has a flashing effect after being coated and dried after being added with the pearl powder; and a certain amount of carborundum is added into the coating, so that the hardness of the dried paint surface can be effectively enhanced, and the service life is prolonged.

Description

Color gold glaze paint and preparation method thereof
Technical Field
The invention relates to the technical field of coatings, in particular to a color gold glaze coating and a preparation method thereof.
Background
The paint is a coating material for protecting and decorating the surface of an object, can form a layer of film after being dried, and endows the object with protection, beautification or other functions, and is usually mainly based on resin, oil or emulsion.
With the continuous development of the coating, the coating is coated on the surface of an object, and has various functions of mildew resistance, drying and the like besides the decoration function; since the surface of an object is exposed to the atmosphere for a long time and is corroded by nutrients, water and the like, and is easy to cause damage phenomena such as decoration, decay and the like, the coating components used for different purposes and different objects are different.
The existing coatings are mostly water-based coatings, the water-based coatings are widely applied in the industry, all internal and external wall coatings, metal paints, automobile paints and the like have corresponding water-based paint products, but the existing coatings are single in color, poor in aesthetic feeling, poor in hardness and easy to damage and fall off after being dried.
Disclosure of Invention
In view of the above, the invention provides a gold-colored glaze paint and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme: the color gold glaze paint comprises the following components in percentage by mass: 30-40% of acrylic acid synthetic emulsion; dispersing agent: 0.5% -1%; 0.3 to 0.5 percent of defoaming agent; wetting agent: 0.3% -0.5%; film-forming auxiliary agent: 2% -3%; an antifreezing agent: 2% -3%; preservative: 0.3% -0.5%; mildew preventive: 0.5% -0.8%; thickening agent: 1% -2%; leveling agent: 1% -2%; titanium dioxide: 3% -5%; pearl powder: 15% -20%; diatomite: 3% -5%; emery: 20% -30%; silicon dioxide: 2% -4%; and (5) residual water.
In a preferred technical scheme, the color gold glaze coating comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 19.1 percent of water.
In a preferred technical scheme, the color gold glaze coating comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 1 percent; 0.5 percent of defoaming agent; wetting agent: 0.5 percent; film-forming auxiliary agent: 3 percent; an antifreezing agent: 3 percent; preservative: 0.5 percent; mildew preventive: 0.8 percent; thickening agent: 2 percent; leveling agent: 2 percent; titanium dioxide: 5 percent; pearl powder: 15 percent; diatomite: 5 percent; emery: 20 percent; silicon dioxide: 4 percent; water: 7.7 percent.
In a preferred technical scheme, the color gold glaze coating comprises the following components in percentage by mass: 40% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 9.1 percent of water.
In a preferred technical scheme, the color gold glaze coating comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 30 percent; silicon dioxide: 2 percent; 9.1 percent of water.
In a preferred technical scheme, the color gold glaze coating comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 20 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; and 14.1 percent of water.
In a preferred technical scheme, in the above components, the dispersant is: 602N; the defoaming agent is: a10; the wetting agents are: CF 10; the film forming auxiliary agent is as follows: OE 400; the preservative is as follows: LXE; the mildew preventive is as follows: NB 203; the thickening agent is: TT 935; the leveling agent is: RM 2020; the titanium dioxide is: and R706.
The preparation method of the color gold glaze paint comprises the following steps:
1) weighing acrylic acid synthetic emulsion, titanium dioxide, diatomite, pearl powder, carborundum and silicon dioxide according to mass fraction;
2) adding the acrylic acid synthetic emulsion, titanium dioxide, diatomite and water into a stirring kettle, uniformly stirring, gradually adding the dispersing agent, the defoaming agent, the wetting agent and the film-forming auxiliary agent during stirring, and uniformly stirring;
3) adding pearl powder and carborundum into the solution obtained in the step 2), and further uniformly stirring at the stirring speed of 800-1200rpm for 10-25 min;
4) and (3) gradually adding silicon dioxide, an antifreezing agent, a preservative, a mildew preventive, a thickening agent and a flatting agent in the step (3), and stirring to control the viscosity to be within the range of 80-130 KU.
According to the technical scheme, compared with the prior art, the invention has the following beneficial effects: the paint prepared by adopting the formula has beautiful color, and has a flashing effect after being coated and dried after being added with the pearl powder; and a certain amount of carborundum is added into the coating, so that the hardness of the dried paint surface can be effectively enhanced, and the service life is prolonged.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the color gold glaze paint comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 19.1 percent of water.
Before preparation, the components with the mass fraction are weighed according to the mass fraction,
adding the acrylic acid synthetic emulsion, titanium dioxide, diatomite and water into a reaction kettle, uniformly stirring at normal temperature, and gradually adding a dispersing agent, a defoaming agent, a wetting agent and a film-forming auxiliary agent in the stirring process; and the dispersant, defoamer, wetting agent and film forming aid are well known to those skilled in the art, and are not particularly limited, and in the present invention, the dispersant is preferably: 602N; the defoaming agent is: a10; the wetting agents are: CF 10; the film forming auxiliary agent is as follows: OE 400; the titanium dioxide is: and R706.
Then, adding pearl powder and carborundum into the solution for stirring, and adding silicon dioxide, an antifreezing agent, a preservative, an anti-mildew agent, a thickening agent and a flatting agent during stirring, wherein the stirring speed is 800-1200rpm, and the stirring time is 10-25 min; and the adopted antifreezing agent, preservative, mildew preventive, thickening agent and leveling agent are generally known to those skilled in the art, and are not particularly limited, and the preferred preservatives in the present invention are: LXE; the mildew preventive is as follows: NB 203; the thickening agent is: TT 935; the leveling agent is: RM 2020;
and finally, stirring to control the viscosity to be within the range of 80-130KU, and obtaining a finished product.
Example two:
the color gold glaze paint comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 1 percent; 0.5 percent of defoaming agent; wetting agent: 0.5 percent; film-forming auxiliary agent: 3 percent; an antifreezing agent: 3 percent; preservative: 0.5 percent; mildew preventive: 0.8 percent; thickening agent: 2 percent; leveling agent: 2 percent; titanium dioxide: 5 percent; pearl powder: 15 percent; diatomite: 5 percent; emery: 20 percent; silicon dioxide: 4 percent; water: 7.7 percent. The preparation process is the same as in the first example.
Example three:
the color gold glaze paint comprises the following components in percentage by mass: 40% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 9.1 percent of water. The preparation process is the same as in the first example.
Example four:
the color gold glaze paint comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 30 percent; silicon dioxide: 2 percent; 9.1 percent of water. The preparation process is the same as in the first example.
Example five:
the color gold glaze paint comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 20 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; and 14.1 percent of water. The preparation process is the same as in the first example.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (9)

1. A color gold glaze paint is characterized in that: the composite material comprises the following components in percentage by mass:
30-40% of acrylic acid synthetic emulsion; dispersing agent: 0.5% -1%; 0.3 to 0.5 percent of defoaming agent; wetting agent: 0.3% -0.5%; film-forming auxiliary agent: 2% -3%; an antifreezing agent: 2% -3%; preservative: 0.3% -0.5%; mildew preventive: 0.5% -0.8%; thickening agent: 1% -2%; leveling agent: 1% -2%; titanium dioxide: 3% -5%; pearl powder: 15% -20%; diatomite: 3% -5%; emery: 20% -30%; silicon dioxide: 2% -4%; and (5) residual water.
2. The color gold glaze paint as claimed in claim 1, wherein: the composite material comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 19.1 percent of water.
3. The color gold glaze paint as claimed in claim 1, wherein: the composite material comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 1 percent; 0.5 percent of defoaming agent; wetting agent: 0.5 percent; film-forming auxiliary agent: 3 percent; an antifreezing agent: 3 percent; preservative: 0.5 percent; mildew preventive: 0.8 percent; thickening agent: 2 percent; leveling agent: 2 percent; titanium dioxide: 5 percent; pearl powder: 15 percent; diatomite: 5 percent; emery: 20 percent; silicon dioxide: 4 percent; water: 7.7 percent.
4. The color gold glaze paint as claimed in claim 1, wherein: the composite material comprises the following components in percentage by mass: 40% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; 9.1 percent of water.
5. The color gold glaze paint as claimed in claim 1, wherein: the composite material comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 15 percent; diatomite: 3 percent; emery: 30 percent; silicon dioxide: 2 percent; 9.1 percent of water.
6. The color gold glaze paint as claimed in claim 1, wherein: the composite material comprises the following components in percentage by mass: 30% of acrylic acid synthetic emulsion; dispersing agent: 0.5 percent; 0.3 percent of defoaming agent; wetting agent: 0.3 percent; film-forming auxiliary agent: 2 percent; an antifreezing agent: 2 percent; preservative: 0.3 percent; mildew preventive: 0.5 percent; thickening agent: 1 percent; leveling agent: 1 percent; titanium dioxide: 3 percent; pearl powder: 20 percent; diatomite: 3 percent; emery: 20 percent; silicon dioxide: 2 percent; and 14.1 percent of water.
7. The color gold glaze paint according to any one of claims 1 to 6, wherein: the dispersant is as follows: 602N; the defoaming agent is: a10; the wetting agents are: CF 10; the film forming auxiliary agent is as follows: OE 400; the preservative is as follows: LXE; the mildew preventive is as follows: NB 203; the thickening agent is: TT 935; the leveling agent is: RM 2020; the titanium dioxide is: and R706.
8. A method for preparing a color gold glaze coating is characterized by comprising the following steps: the method comprises the following steps:
1) weighing acrylic acid synthetic emulsion, titanium dioxide, diatomite, pearl powder, carborundum and silicon dioxide according to mass fraction;
2) adding the acrylic acid synthetic emulsion, titanium dioxide, diatomite and water into a stirring kettle, uniformly stirring, gradually adding the dispersing agent, the defoaming agent, the wetting agent and the film-forming auxiliary agent during stirring, and uniformly stirring;
3) adding pearl powder and carborundum into the solution obtained in the step 2), and further uniformly stirring at the stirring speed of 800-1200rpm for 10-25 min;
4) and (3) gradually adding silicon dioxide, an antifreezing agent, a preservative, a mildew preventive, a thickening agent and a flatting agent in the step (3), and stirring to control the viscosity to be within the range of 80-130 KU.
9. The method for manufacturing the color gold glaze paint according to claim 8, wherein: the color gold glaze coating comprises the following components in percentage by mass: 30-40% of acrylic acid synthetic emulsion; dispersing agent: 0.5% -1%; 0.3 to 0.5 percent of defoaming agent; wetting agent: 0.3% -0.5%; film-forming auxiliary agent: 2% -3%; an antifreezing agent: 2% -3%; preservative: 0.3% -0.5%; mildew preventive: 0.5% -0.8%; thickening agent: 1% -2%; leveling agent: 1% -2%; titanium dioxide: 3% -5%; pearl powder: 15% -20%; diatomite: 3% -5%; emery: 20% -30%; silicon dioxide: 2% -4%; and (5) residual water.
CN201910264565.3A 2019-04-03 2019-04-03 Color gold glaze paint and preparation method thereof Pending CN111777906A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910264565.3A CN111777906A (en) 2019-04-03 2019-04-03 Color gold glaze paint and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910264565.3A CN111777906A (en) 2019-04-03 2019-04-03 Color gold glaze paint and preparation method thereof

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Publication Number Publication Date
CN111777906A true CN111777906A (en) 2020-10-16

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102167937A (en) * 2011-05-04 2011-08-31 合众（佛山）化工有限公司 Long-acting antimicrobial water-based environment-friendly paint and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102167937A (en) * 2011-05-04 2011-08-31 合众（佛山）化工有限公司 Long-acting antimicrobial water-based environment-friendly paint and preparation method thereof

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Application publication date: 20201016