CN111758940A - Method for reducing lead content of leaf and bean pickle - Google Patents

Method for reducing lead content of leaf and bean pickle Download PDF

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Publication number
CN111758940A
CN111758940A CN202010831917.1A CN202010831917A CN111758940A CN 111758940 A CN111758940 A CN 111758940A CN 202010831917 A CN202010831917 A CN 202010831917A CN 111758940 A CN111758940 A CN 111758940A
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vegetables
pickling tank
layer
bean
leaf
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周至均
王丽兰
彭慧莉
王莎莎
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Meishan Product Quality Supervision And Inspection Institute
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Meishan Product Quality Supervision And Inspection Institute
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/20Products from fruits or vegetables; Preparation or treatment thereof by pickling, e.g. sauerkraut or pickles
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Storage Of Fruits Or Vegetables (AREA)

Abstract

The invention discloses a method for reducing lead content of leaf and bean pickle, which comprises the following steps: selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, scattering a layer of pickled vegetable salt until the vegetables fill the pickling tank, and scattering a layer of pickled vegetable salt on the uppermost layer; sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, and sealing and fermenting; turning over the pool, and turning all the pickled vegetables into the other pool; adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing in the tank after the addition is finished; slowly pouring saline water into the newly turned-over pickling tank from the top of the vegetables to ensure that all the vegetables can be soaked in the saline water; taking out the soaked vegetables, washing, soaking and washing, squeezing, dewatering, cutting, mixing, packaging, pasteurizing, and making into sauerkraut. The invention improves the safety of leaf vegetables and bean vegetables, thereby improving the market competitiveness of the pickle products made of the leaf vegetables and the bean vegetables.

Description

Method for reducing lead content of leaf and bean pickle
Technical Field
The invention belongs to the technical field of safety control of deep processing quality of leaf vegetables and bean vegetables, and particularly relates to a method for reducing lead content of leaf vegetables and bean vegetables.
Background
Lead is the main heavy metal ion in the safety index of the pickle. GB 2762 (manuscript of comments) aims to adjust the lead (Pb) content of the vegetable product in the original standard from 1.0 mg/kg to 0.3 mg/kg. Due to pollution of the vegetable planting environment and the production and processing process, quality problems caused by excessive lead content of vegetable products are more and more, if the lead limit of the vegetable products is adjusted from 1.0 mg/kg to 0.3mg/kg, the rejection rate of spot check of leaf and bean vegetable products is greatly improved, and the casualties of enterprises in the pickled vegetable industry of China can be influenced. After a large amount of long-term research, the lead content of 20-25% of pickle products made of leaf vegetables and bean vegetables in China is between 0.3-0.9 mg/Kg, once the products are randomly inspected in the country, 10% of enterprises suffer loss or are closed upside down after the inspection result is published. Therefore, attention should be paid to the problem of controlling lead in the production of leafy and legume vegetables.
The traditional process mainly comprises the steps of putting fresh leaf vegetables and bean vegetables into a pickling tank, adding pickle salt for pickling, carrying out sealed fermentation for a long time, taking out a sample, and carrying out cleaning, desalting, cutting, material mixing, subpackaging and pasteurization on the sample to obtain a finished product. At present, no method for reducing the content of lead in leaf vegetables and bean vegetables by changing the processing technology is available, so that the quality safety of the deep-processed pickle finished products is ensured.
Disclosure of Invention
In view of the above, the present invention provides a method for reducing the lead content of leaf and bean pickles, aiming at the problem that the lead content in the existing leaf and bean pickles is relatively high or exceeds the standard, so as to improve the safety of the leaf and bean pickles, and thus improve the market competitiveness of the leaf and bean pickles made of the leaf and bean pickles.
In order to solve the technical problem, the invention discloses a method for reducing the lead content of leaf and bean pickle, which comprises the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled vegetable salt, wherein the interval between two adjacent layers of vegetables is 20cm until the vegetables fill the pickling tank, and spreading a layer of pickled vegetable salt on the uppermost layer;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables with tap water, putting the vegetables into a container, soaking the vegetables in the tap water, washing the vegetables with the tap water after the soaking is finished, squeezing and dehydrating the vegetables, and then cutting, mixing the vegetables, packaging and pasteurizing the vegetables to obtain the finished pickled vegetables.
Optionally, the mass ratio of the vegetables and the pickle salt in the step 1 is 8: 1-10: 1.
optionally, the mass ratio of the addition amount of the disodium ethylene diamine tetraacetate in the step 4 to the fresh vegetables in the step 1 is 1: 10000-1: 5000.
optionally, in the step 6, tap water is firstly used for washing for 1-5min, then the container is placed into the container to be soaked for 18-22min, and then washing is carried out for 1-3 min.
Compared with the prior art, the invention can obtain the following technical effects:
1) after the fermentation is finished, the reasonable and safe chelating agent is added to replace free lead ions in the vegetables, so that the content of lead in the vegetables is reduced, the problem of high lead content in leaf vegetables and bean vegetables is solved by a method which does not influence the flavor of the pickled vegetables, and the method has important practical significance for the fields of quality safety control and deep processing application of the pickled vegetables.
2) According to the invention, through pickling, fermentation and dehydration, disodium ethylene diamine tetraacetate is added in an acidic environment to remove free lead ions, and then the vegetables are soaked and washed to remove chelates and impurities attached to the vegetables, so that the vegetables can be pickled to separate out water, and firstly, the water can carry out partial lead; secondly, the vegetables can generate lactic acid in the fermentation process, the content of lead in the leaf vegetables and the bean vegetables is reduced by adopting an ethylene diamine tetraacetic acid disodium chelation method under an acidic condition, and chelates and impurities attached to the vegetables are removed by soaking and washing, so that the safety of the leaf vegetables and the bean vegetables is ensured; the lead content of the finally processed leaf vegetables and bean vegetables is also reduced.
3) The lead content removing effect of the invention is obvious, the lead content of leaf vegetables and bean vegetables can be reduced by 40-50%, and the safety of leaf vegetables and bean vegetables can be effectively improved. The method combines the leaf and bean vegetable dehydration fermentation process, the deleading process and the soaking and washing process, finally achieves the purpose of reducing lead on the premise of not influencing the flavor and the quality of the product, has simple and convenient operation, has obvious lead removal effect of the prepared product, and can obviously improve the safety and the market competitiveness of the leaf and bean vegetable product.
Of course, it is not necessary for any one product in which the invention is practiced to achieve all of the above-described technical effects simultaneously.
Detailed Description
The following embodiments are described in detail with reference to the accompanying drawings, so that how to implement the technical features of the present invention to solve the technical problems and achieve the technical effects can be fully understood and implemented.
The invention discloses a method for reducing lead content of leaf and bean pickle, which comprises the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled vegetable salt, wherein the spacing distance between two adjacent layers of vegetables is 20cm, and spreading a layer of pickled vegetable salt on the uppermost layer until the vegetables fill the pickling tank, wherein the mass ratio of the vegetables to the pickled vegetable salt is 8: 1-10: 1, in the range, the fermentation of lactic acid bacteria is facilitated, and vegetables are not easy to deteriorate. If the salt content is more than the range, the vegetables are easy to deteriorate due to too low salt content, and if the salt content is less than the range, the vegetable is not beneficial to lactobacillus fermentation due to too high salt content;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
wherein, the fermentation is finished in 3-4 months after the fermentation tank is placed in the pond in winter, and the fermentation is finished in 2 months after the fermentation tank is placed in the pond in summer;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished; the mass ratio of the addition amount of the ethylene diamine tetraacetic acid disodium to the fresh vegetables in the step 1 is 1: 10000-1: 5000, in the range, enough complexing lead ions and other harmful metal ions are present, more than the range, too much disodium ethylene diamine tetraacetate easily causes the residual content of finished disodium ethylene diamine tetraacetate to exceed the standard, and less than the range, the disodium ethylene diamine tetraacetate has less quantity, and the complexing of the lead ions and other harmful metal ions is not sufficient;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables with tap water for 1-5min, then putting the vegetables into a container, soaking the vegetables in the tap water for 18-22min, then washing the vegetables with the tap water for 1-3min, and then carrying out cutting, material mixing, packaging and pasteurization after squeezing and dehydration to obtain the finished product.
Wherein, the vegetables are washed by tap water for 1-5min, which is favorable for washing away impurities, metal complexes and salts thereof in the vegetables; less than this range, the removal of impurities in the vegetables is insufficient, the washing of the metal complex is insufficient, the desalination is insufficient, and more than this range, the loss of the nutrient content of the vegetables is easily caused; the soaking time of tap water is 18-22min, which is favorable for the separation of metal complexes and salts thereof in the vegetables, and the separation of the metal complexes and the salts thereof in the vegetables is insufficient when the soaking time is less than the range, and the vegetables are easy to deteriorate after being soaked for a long time when the soaking time is more than the range; after soaking, the washing time of tap water is 1-3min, which is beneficial to further washing away impurities, metal complexes and salts in the vegetables. If the content is less than the range, impurities in the vegetables are insufficiently removed, the metal complex is insufficiently washed, and the desalination is insufficient.
Before the fresh vegetables are put into a pool, the lead content is measured to be A mg/kg, after the processes of pickling fermentation, deleading, desalting and dehydration, the lead content is measured to be B mg/kg, and the lead content reduction rate C can be calculated by a formula C = (A-B)/A x 100.
The method has obvious lead content removing effect, 30 fresh vegetables with the lead content of more than 0.3mg/kg are subjected to lead removal according to the method, and the lead content range of the raw materials is as follows: 0.41 +/-0.11 mg/kg, and the lead content range of the desalted and dehydrated vegetables obtained after the lead is removed by the method is as follows: 0.20 plus or minus 0.05 mg/kg can reduce the lead content of leaf vegetables and bean vegetables by 40-50%.
The method adopts salt for pickling and fermenting fresh vegetables, and the vegetables are beneficial to lactobacillus fermentation under the acidic condition. The purpose of adopting the disodium ethylene diamine tetraacetate is to complex lead ions in water separated out from vegetables and free lead ions contained in the pickled vegetables. The purpose of using tap water is to wash out other impurities in the vegetables and remove most of salt and complexons of ethylene diamine tetraacetic acid and lead ions in the vegetables.
Example 1
A method for reducing lead content of leaf and bean pickle comprises the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled salt, wherein the interval between the vegetables and the pickled salt is about 20cm until the vegetables fill the pickling tank, and spreading a layer of pickled salt on the uppermost layer, wherein the mass ratio of the vegetables to the pickled salt is 8: 1;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished; the mass ratio of the addition amount of the ethylene diamine tetraacetic acid disodium to the fresh vegetables in the step 1 is 1: 5000;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables with tap water for 5min, putting the vegetables into a container, soaking the vegetables in the tap water for 20min, washing the vegetables for 3min after the soaking is finished, squeezing and dehydrating the vegetables, and then cutting, stirring, packaging and pasteurizing the vegetables to obtain the finished product.
The lead content of leaf and bean vegetables can be reduced by 49% by adopting the embodiment 1.
Example 2
A method for reducing lead content of leaf and bean pickle comprises the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled vegetable salt, wherein the interval between the vegetables and the pickled vegetable salt is about 20cm until the vegetables fill the pickling tank, and spreading a layer of pickled vegetable salt on the uppermost layer, wherein the mass ratio of the vegetables to the pickled vegetable salt is 9: 1;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished; the mass ratio of the addition amount of the ethylene diamine tetraacetic acid disodium to the fresh vegetables in the step 1 is 1: 7500;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables for 3min by using tap water, putting the vegetables into a container, soaking the vegetables for 22min by using the tap water, washing the vegetables for 2min after the soaking is finished, squeezing and dehydrating the vegetables, and then cutting, stirring the materials, packaging and pasteurizing the vegetables to obtain the finished product.
The lead content of leaf and bean vegetables can be reduced by 45% by adopting the embodiment 2.
Example 3
A method for reducing lead content of leaf and bean pickle comprises the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled salt, wherein the interval between the vegetables and the pickled salt is about 20cm until the vegetables fill the pickling tank, and spreading a layer of pickled salt on the uppermost layer, wherein the mass ratio of the vegetables to the pickled salt is 10: 1;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished; the mass ratio of the addition amount of the ethylene diamine tetraacetic acid disodium to the fresh vegetables in the step 1 is 1: 10000;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables for 1min by using tap water, then putting the vegetables into a container, soaking the vegetables for 18min by using the tap water, washing the vegetables for 1min after the soaking is finished, squeezing and dehydrating the vegetables, and then cutting, stirring, packaging and pasteurizing the vegetables to obtain the finished product.
The lead content of leaf and bean vegetables can be reduced by 41% by adopting the embodiment 3.
While the foregoing description shows and describes several preferred embodiments of the invention, it is to be understood, as noted above, that the invention is not limited to the forms disclosed herein, but is not to be construed as excluding other embodiments and is capable of use in various other combinations, modifications, and environments and is capable of changes within the scope of the inventive concept as expressed herein, commensurate with the above teachings, or the skill or knowledge of the relevant art. And that modifications and variations may be effected by those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (4)

1. A method for reducing the lead content of leaf and bean pickles is characterized by comprising the following steps:
step 1, selecting and cleaning fresh vegetables, putting the fresh vegetables into a pickling tank, putting a layer of vegetables, spreading a layer of pickled vegetable salt, wherein the interval between two adjacent layers of vegetables is 20cm until the vegetables fill the pickling tank, and spreading a layer of pickled vegetable salt on the uppermost layer;
step 2, after the whole pickling tank is fully paved with vegetables, sealing the top end of the pickling tank by using a plastic film, paving a layer of river sand on the film, sealing and fermenting, and facilitating lactobacillus fermentation;
3, turning over the pickling tank after the fermentation of the whole pickling tank is finished, and turning all pickled vegetables into the other pickling tank for later use;
step 4, adding food-grade disodium ethylene diamine tetraacetate into the brine remained in the pickling tank, and stirring and uniformly mixing the mixture in the tank for later use after the addition is finished;
step 5, slowly pouring the uniformly stirred saline water containing the ethylene diamine tetraacetic acid from the top end of the newly turned vegetables in the pickling tank, so that all the vegetables can be soaked in the saline water for 1 day for later use;
and 6, taking out the soaked vegetables, washing the vegetables with tap water, putting the vegetables into a container, soaking the vegetables in the tap water, washing the vegetables with the tap water after the soaking is finished, squeezing and dehydrating the vegetables, and then cutting, mixing the vegetables, packaging and pasteurizing the vegetables to obtain the finished pickled vegetables.
2. The method as claimed in claim 1, wherein the mass ratio of the vegetables and the kimchi salt in the step 1 is 8: 1-10: 1.
3. the method as claimed in claim 1, wherein the mass ratio of the addition amount of the disodium ethylene diamine tetraacetate in the step 4 to the fresh vegetable in the step 1 is 1: 10000-1: 5000.
4. the method as claimed in claim 1, wherein step 6 is carried out by washing with tap water for 1-5min, soaking in tap water for 18-22min, and washing for 1-3 min.
CN202010831917.1A 2020-08-18 2020-08-18 Method for reducing lead content of leaf and bean pickle Pending CN111758940A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102586148A (en) * 2012-02-28 2012-07-18 江南大学 Plant lactobacillus capable of relieving lead toxicity and application thereof
CN104273480A (en) * 2014-10-17 2015-01-14 四川东坡中国泡菜产业技术研究院 Vegetable mixing fermentation technology for pickled vegetables
CN105325977A (en) * 2015-12-11 2016-02-17 邓天华 Method for pickling vegetables in double-water-sealing mode
CN106036667A (en) * 2016-06-24 2016-10-26 贵州务川东升生态农业开发有限公司 Pickled peppers and making method thereof
CN106107714A (en) * 2016-06-24 2016-11-16 贵州务川东升生态农业开发有限公司 A kind of sweet and sour garlic and preparation method thereof
CN109788780A (en) * 2016-08-18 2019-05-21 艾斯姆食品公司 For reducing the chelating agent and its correlation technique of tenor in food product

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102586148A (en) * 2012-02-28 2012-07-18 江南大学 Plant lactobacillus capable of relieving lead toxicity and application thereof
CN104273480A (en) * 2014-10-17 2015-01-14 四川东坡中国泡菜产业技术研究院 Vegetable mixing fermentation technology for pickled vegetables
CN105325977A (en) * 2015-12-11 2016-02-17 邓天华 Method for pickling vegetables in double-water-sealing mode
CN106036667A (en) * 2016-06-24 2016-10-26 贵州务川东升生态农业开发有限公司 Pickled peppers and making method thereof
CN106107714A (en) * 2016-06-24 2016-11-16 贵州务川东升生态农业开发有限公司 A kind of sweet and sour garlic and preparation method thereof
CN109788780A (en) * 2016-08-18 2019-05-21 艾斯姆食品公司 For reducing the chelating agent and its correlation technique of tenor in food product

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Application publication date: 20201013