CN111732883A - Long-acting antifogging coating and production process and application thereof - Google Patents

Long-acting antifogging coating and production process and application thereof Download PDF

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Publication number
CN111732883A
CN111732883A CN202010637465.3A CN202010637465A CN111732883A CN 111732883 A CN111732883 A CN 111732883A CN 202010637465 A CN202010637465 A CN 202010637465A CN 111732883 A CN111732883 A CN 111732883A
Authority
CN
China
Prior art keywords
long
acting
coating
liquid medicine
vpp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010637465.3A
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Chinese (zh)
Inventor
吴天恕
吴彦廷
简志仰
温祖来
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FORESIGHT OPTICAL (XIAMEN) CO LTD
Original Assignee
FORESIGHT OPTICAL (XIAMEN) CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FORESIGHT OPTICAL (XIAMEN) CO LTD filed Critical FORESIGHT OPTICAL (XIAMEN) CO LTD
Priority to CN202010637465.3A priority Critical patent/CN111732883A/en
Publication of CN111732883A publication Critical patent/CN111732883A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films

Abstract

The invention relates to a long-acting antifogging coating, a production process and application thereof, wherein the coating comprises the following components in percentage by weight: 48-52% of VPP liquid medicine and 48-52% of propylene glycol methyl ether. The invention is applied to the lens, can effectively prevent the fog of the goggles, ensures the smooth operation of medical personnel, avoids the pollution in the operation and lightens the psychological pressure of the medical personnel in the work.

Description

Long-acting antifogging coating and production process and application thereof
Technical Field
The invention relates to the technical field of glasses, in particular to a long-acting antifogging coating, a production process and application thereof, and the long-acting antifogging coating comprises goggles, masks, lens products and the like.
Background
The goggles are an eye protection device for closing or protecting the periphery of eyes, and are mainly used for preventing particles, water, chemical substances, blood, body fluid and other infectious substances from invading the eyes.
However, the goggles sold on the market at present can fog up after being worn for a period of time, which causes unclear vision, seriously affects the sight of medical staff, increases the operation difficulty and increases the pollution risk. The fogging problem of the goggles not only affects the accuracy of the operation of medical personnel, but also increases the psychological pressure.
When a significant temperature difference occurs between the material and the environment, water mist condenses on the surface. This is because the saturated vapor pressure of water decreases below the partial pressure of water vapor in the air due to the decrease in air temperature, causing the water vapor to condense into water droplets. The reason why the goggles are fogged is that the temperature of a human body is higher than the indoor temperature, and the temperature difference between the inner layer and the outer layer of the goggles is large, so that the goggles are easy to generate fog.
The treatment of antifogging lenses in the market is mainly as follows:
1. the antifogging agent of the swimming goggles is evenly coated on the surface layer of the inner layer of the goggles lens, and the goggles lens is worn after standing and airing.
The disadvantages are that: most of water stains on the surface of the lens are in a point halo shape, so that the definition is reduced, and the visual field and the visibility are influenced; moreover, the antifogging agent is expensive and not easily available.
2. And (3) uniformly coating a proper amount of the detergent on the inner layer of the lens by using a cotton swab or gauze, standing and airing for later use.
The disadvantages are that: the detergent needs to be used after being dried and wiped, the preparation time is long, the anti-fog effect cannot be immediately obtained, and the emergency use is not facilitated.
3. This phenomenon is improved by using functionalized graphene thin film materials and electronic equipment.
The disadvantages are that: high cost and influence on vision.
Disclosure of Invention
In order to solve the technical problems, the invention provides a long-acting antifogging coating and a production process thereof, and application of the coating as an antifogging coating on a long-acting antifogging lens, and relates to application of the long-acting antifogging lens on goggles, masks, lens products and the like. Compared with the existing product, the invention has low cost and can effectively prevent fog with the length of more than 24H.
The specific scheme is as follows:
one purpose of the invention is to provide a long-acting antifogging coating, which comprises the following components in percentage by weight: 48-52% of VPP liquid medicine and 48-52% of propylene glycol methyl ether.
Further, the coating comprises the following components in percentage by weight: 50% of VPP liquid medicine and 50% of propylene glycol methyl ether.
Further, the VPP liquid medicine is produced by FSICT company.
Further, the VPP liquid medicine comprises the following components in percentage by weight: 30-60% of 1-methoxy-2-propanol, 1-5% of methoxy propyl acetate, 10-30% of diacetone alcohol, 20-30% of polyurethane, 1-0% of surfactant and 0-1% of xylene.
The invention also aims to provide a production process of the long-acting antifogging coating, which comprises the following steps:
(1) mixing VPP liquid medicine and propylene glycol methyl ether according to weight percentage;
(2) pneumatically mixing in a dust-free workshop at 20-25 deg.C for 2 hr to make the medicinal liquid fully react and fully combine the chemical molecular structure of the medicinal liquid;
(3) and (3) pouring the liquid medicine fully reacted in the step (2) into an enhancement tank, raising the temperature of the liquid medicine to 28-32 ℃, and reacting the liquid medicine again to achieve better antifogging performance and processing fluidity so as to obtain a finished product.
Further, the weight percentage of the VPP liquid medicine and the propylene glycol methyl ether in the step (1) is 1: 1.
Further, the closed container in the step (2) is a stainless steel closed container.
The invention also aims to provide a long-acting anti-fog lens which is provided with an anti-fog coating, and the material of the anti-fog coating is the long-acting anti-fog coating.
The invention also aims to provide an application of the long-acting anti-fog lens on goggles and masks.
Wherein:
the VPP liquid medicine (Visgard Premium Plus) adopted by the invention is produced by FSI coating technologies, Inc. (FSICT). The VPP lotion has the performance of an antifogging coating and excellent abrasion, chemical and ultraviolet resistance, has excellent adhesion in extreme temperature and high humidity environments, can prevent fog formation after repeated cleaning, is transparent and does not yellow.
The propylene glycol methyl ether adopted by the invention has the effect of promoting the fusion and decomposition of the VPP liquid medicine, so that the anti-fog performance of the VPP liquid medicine is better, and the processing fluidity is better. The invention reasonably adjusts the proportion of the VPP liquid medicine and the propylene glycol methyl ether, so that the concentration of the VPP liquid medicine and the propylene glycol methyl ether is balanced, the cost can be reduced, and the optimal antifogging effect can be realized. The optimal ratio of the VPP liquid medicine to the propylene glycol methyl ether is 1: 1.
Has the advantages that:
the product of the invention has good antifogging effect, does not fog when being worn for 24H, and has reasonable cost and good vision.
The invention can effectively prevent the fogging of the goggles, ensure the smooth operation of medical workers, avoid the pollution in the operation and reduce the psychological pressure of the medical workers in the work.
Detailed Description
The following detailed description of embodiments of the invention is intended to be illustrative of the invention and is not to be construed as limiting the invention. The examples do not specify particular techniques or conditions, and are performed according to the techniques or conditions described in the literature in the art or according to the product specifications. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available.
Example 1: long-acting antifogging coating
The embodiment 1 provides a long-acting antifogging coating, and a production process of the long-acting antifogging coating comprises the following steps:
(1) mixing VPP liquid medicine and propylene glycol methyl ether according to the weight percentage: the VPP liquid medicine content is 50%, and the propylene glycol methyl ether content is 50%;
(2) pneumatically mixing in a stainless steel closed container for 2 hours at 20-25 ℃ in a dust-free workshop to fully perform chemical reaction on the liquid medicine and fully combine the chemical molecular structures of the liquid medicine;
(3) pouring the liquid medicine fully reacted in the step (2) into an enhancement tank, raising the temperature of the liquid medicine to 28-32 ℃ so that the liquid medicine reacts again to achieve better antifogging performance and processing fluidity, and obtaining the finished product of the example 1.
Wherein: the VPP liquid medicine is produced by FSICT company, and comprises the following components in percentage by weight: 30-60% of 1-methoxy-2-propanol, 1-5% of methoxy propyl acetate, 10-30% of diacetone alcohol, 20-30% of polyurethane, 1-0% of surfactant and 0-1% of xylene.
Example 2: long-acting antifogging coating
The production process of this example 2 is substantially the same as that of example 1, except that the VPP chemical solution content of this example 2 is 48% and the propylene glycol methyl ether content is 52%.
Example 3: long-acting antifogging coating
The production process of this example 3 is substantially the same as that of example 1, except that the VPP chemical solution content of this example 2 is 52% and the propylene glycol methyl ether content is 48%.
Example 4: long-acting antifogging lens
A long-acting anti-fog lens, the lens being provided with an anti-fog coating, and the material of the anti-fog coating being the long-acting anti-fog coating of embodiment 1.
Example 5: long-acting antifogging lens
A long-acting anti-fog lens, the lens being provided with an anti-fog coating, and the material of the anti-fog coating being the long-acting anti-fog coating of embodiment 2.
Example 6: long-acting antifogging lens
A long-acting anti-fog lens, the lens being provided with an anti-fog coating, and the material of the anti-fog coating being the long-acting anti-fog coating of embodiment 3.
Example 7: long-acting antifogging goggles
The use of the long-acting anti-fog lens of example 4 on goggles produces a finished long-acting anti-fog goggles.
Of course, the invention is equally applicable to face masks or other lens-like products.
Example 8: long-acting antifogging goggles
The use of the long-acting anti-fog lens of example 5 on goggles produces a finished long-acting anti-fog goggles.
Example 9: long-acting antifogging goggles
The use of the long-acting anti-fog lens of example 6 on goggles produces a finished long-acting anti-fog goggles.
And (3) experimental test:
the goggles of examples 7-9 were tested for anti-fogging effect and the results are shown in table 1.
TABLE 1 antifogging effect test results of the present invention
Example 7 Example 8 Example 9
Fog on 24H Does not fog Does not fog Does not fog
24H View Effect on wear Clear and clear Clear and clear Clear and clear
As can be seen from Table 1, the product of the invention has good antifogging effect, does not fog when worn for 24H, and has reasonable cost and good vision.
While the invention has been particularly shown and described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (9)

1. The long-acting antifogging coating is characterized by comprising the following components in percentage by weight: 48-52% of VPP liquid medicine and 48-52% of propylene glycol methyl ether.
2. The long-acting antifog coating of claim 1, characterized in that the coating comprises the following components in weight percent: 50% of VPP liquid medicine and 50% of propylene glycol methyl ether.
3. The long-acting anti-fog coating of claim 1, wherein the VPP solution is produced by FSICT corporation.
4. The long-acting antifog coating of claim 3, wherein the VPP lotion comprises the following components in weight percent: 30-60% of 1-methoxy-2-propanol, 1-5% of methoxy propyl acetate, 10-30% of diacetone alcohol, 20-30% of polyurethane, 1-0% of surfactant and 0-1% of xylene.
5. A process for producing a long-acting antifogging coating according to any of claims 1 to 4, characterized in that it comprises the following steps:
(1) mixing VPP liquid medicine and propylene glycol methyl ether according to weight percentage;
(2) pneumatically mixing in a dust-free workshop at 20-25 deg.C for 2 hr to make the medicinal liquid fully react and fully combine the chemical molecular structure of the medicinal liquid;
(3) and (3) pouring the liquid medicine fully reacted in the step (2) into an enhancement tank, raising the temperature of the liquid medicine to 28-32 ℃, and reacting the liquid medicine again to achieve better antifogging performance and processing fluidity so as to obtain a finished product.
6. The production process of claim 5, wherein the VPP liquid medicine and the propylene glycol methyl ether in the step (1) are 1:1 in weight percentage.
7. The process according to claim 5, wherein the closed vessel of step (2) is a stainless steel closed vessel.
8. A long-acting antifogging lens, characterized in that, the lens is provided with an antifogging coating, and the material of the antifogging coating is the long-acting antifogging coating of any one of claims 1 to 4.
9. Use of the long-acting anti-fog lens of claim 8 in goggles, face masks.
CN202010637465.3A 2020-07-04 2020-07-04 Long-acting antifogging coating and production process and application thereof Pending CN111732883A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010637465.3A CN111732883A (en) 2020-07-04 2020-07-04 Long-acting antifogging coating and production process and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010637465.3A CN111732883A (en) 2020-07-04 2020-07-04 Long-acting antifogging coating and production process and application thereof

Publications (1)

Publication Number Publication Date
CN111732883A true CN111732883A (en) 2020-10-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113755134A (en) * 2020-12-24 2021-12-07 杏晖光学(厦门)有限公司 Long-acting antibacterial permanent antifogging liquid medicine and lens as well as preparation process and application thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN102443343A (en) * 2010-09-28 2012-05-09 富士胶片株式会社 Antistatic hardcoat layer-forming composition, optical film, production method of optical film, polarizing plate and image display device
CN103003377A (en) * 2010-07-24 2013-03-27 株式会社日本触媒 Hydrophilizing treatment agent
CN108368321A (en) * 2015-12-11 2018-08-03 富士胶片株式会社 Optical functional layer working composition, optical film and liquid crystal display device
CN109337106A (en) * 2018-08-27 2019-02-15 明基材料有限公司 Hard conating optical film, polarizer and image display
CN109971327A (en) * 2017-12-28 2019-07-05 财团法人工业技术研究院 The formed method of water paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103003377A (en) * 2010-07-24 2013-03-27 株式会社日本触媒 Hydrophilizing treatment agent
CN102443343A (en) * 2010-09-28 2012-05-09 富士胶片株式会社 Antistatic hardcoat layer-forming composition, optical film, production method of optical film, polarizing plate and image display device
CN108368321A (en) * 2015-12-11 2018-08-03 富士胶片株式会社 Optical functional layer working composition, optical film and liquid crystal display device
CN109971327A (en) * 2017-12-28 2019-07-05 财团法人工业技术研究院 The formed method of water paint
CN109337106A (en) * 2018-08-27 2019-02-15 明基材料有限公司 Hard conating optical film, polarizer and image display

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
FSICT: "FSI Coating Technologies推出Visgard Premium Plus防雾涂层", 《FSICT官网》 *
FSICT: "Visgard Premium Plus防雾产品的技术数据表", 《FSICT官网》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113755134A (en) * 2020-12-24 2021-12-07 杏晖光学(厦门)有限公司 Long-acting antibacterial permanent antifogging liquid medicine and lens as well as preparation process and application thereof

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Application publication date: 20201002