CN1117141C - Efficient metal scavenger - Google Patents

Efficient metal scavenger Download PDF

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Publication number
CN1117141C
CN1117141C CN 01115063 CN01115063A CN1117141C CN 1117141 C CN1117141 C CN 1117141C CN 01115063 CN01115063 CN 01115063 CN 01115063 A CN01115063 A CN 01115063A CN 1117141 C CN1117141 C CN 1117141C
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CN
China
Prior art keywords
ether
prescription
polyethers
trolamine
sodium nitrite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 01115063
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Chinese (zh)
Other versions
CN1323878A (en
Inventor
于志刚
单卓然
曾秋媚
陈建秋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ocean University of Oingdao
Original Assignee
Ocean University of Oingdao
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ocean University of Oingdao filed Critical Ocean University of Oingdao
Priority to CN 01115063 priority Critical patent/CN1117141C/en
Publication of CN1323878A publication Critical patent/CN1323878A/en
Application granted granted Critical
Publication of CN1117141C publication Critical patent/CN1117141C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Detergent Compositions (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The present invention relates to an efficient metal scavenger which is composed of (by weight) 1 to 5% of OP-10, 1 to 5% of 6501, 1.5 to 5% of JFC, 1 to 5% of polyether 2020, 5 to 10% of sodium nitrite, 5 to 10% of triethanol amine and water as the rest. The present invention has the advantages of low foam, high efficiency (the cleaning rate is higher than 90%), no corrosion to a metal surface (the rust protection rate reaches 0 grade), high stability and no pollution (no phosphorus or aluminum).

Description

Efficient metal scavenger
The present invention relates to a kind of washing composition, specifically a kind of washing composition that is used for the clean metal surface.
China produces at present and the metal cleaner of use contains chemical ingredientss such as strong acid, highly basic, phosphoric acid salt and aluminium salt mostly, these products are toxic to human body, the microbiological deterioration performance is poor, and grievous injury animals and plants, foam is many, polluted river water and groundwater resource can produce in various degree damage to the metallic surface that is cleaned simultaneously.
At the problems referred to above, a kind of efficient, low bubble, antirust, the free of contamination metal cleaner of providing of the present invention.
The present invention is a composition, and it forms (weight percentage) by following prescription:
Alkylphenol-polyethenoxy (10) ether 1~5%
Dodecyl diglycollic amide 1~5%
Polyoxyethylene aliphatic alcohol ether 1.5~5%
Polyethers 2,020 1~5%
Sodium Nitrite 5~10%
Trolamine 5~10%
All the other are water.
The present invention preferably fill a prescription (weight percentage) be:
Alkylphenol-polyethenoxy (10) ether 2~5%
Dodecyl diglycollic amide 1~3%
Polyoxyethylene aliphatic alcohol ether 1.5~3%
Polyethers 2,020 2~5%
Sodium Nitrite 5~8%
Trolamine 7~10%
All the other are water.
In order to reach the rot-resistant purpose, can also in prescription, add the Sodium Benzoate of 1~10% (weight percentage).
Composition of the present invention only needs each component in the prescription is mixed, and stirring gets final product.
The present invention has low bubble, efficient (cleaning rate is more than 90%), the metallic surface is not had the advantage of corrosion (rust-preventing characteristic reaches 0 grade), good stability, pollution-free (without phosphorus and aluminium).
Further specify the present invention below in conjunction with embodiment.
Embodiment 1~2:
Each component of different ratios is obtained metal cleaner according to mixing shown in the table 1, measure its cleaning rate, pH value, rust-preventing characteristic and stability respectively.Wherein,
Cleaning rate: the greasy dirt weight/greasy dirt original weight of cleaning rate=wash.
PH value: directly measure mixed composition with the wide pH value test paper.
Rust-preventing characteristic: grading standard: 0 grade of surface is rustless, no considerable change.
1 grade of surface is rustless, light discolouration or loss of gloss.
2 grades of light rust in surface or inhomogeneous variable color.
3 grades of surperficial big area corrosions.
Stability: mixed composition was placed after 4 hours, observed its layering situation, and is stable
For not stratified not muddy, shakiness is decided to be layering or muddiness.
Comparative Examples 1~2:
Increase traditional triethanolamine oleate in prescription, and do not use polyethers 2020 or trolamine, measure after the same method, every performance index see Table 1, as a result poor effect.
Table 1
OP- 10 6501 JFC Polyethers 2020 Sodium Nitrite Trolamine Triethanolamine oleate The pH value Rust-preventing characteristic Cleaning rate Stability
Embodiment 1 3.0 2.0 2.0 3.0 8.0 9.0 0 9.0 0 grade 90.2 Stable
Embodiment 2 3.0 2.0 2.0 3.0 5.0 7.0 0 9.0 0 grade 91.5 Stable
Comparative Examples 1 3.0 2.0 2.0 3.0 7.0 0 0 9.0 3 grades 90.1 Stable
Comparative Examples 2 3.0 2.0 2.0 0 10.0 6.0 8.0 9.0 0 grade 91.7 Unstable
Each component manufacturer and main component:
OP-10: second auxiliary factory, alkylphenol-polyethenoxy (10) ether Shanghai;
6501: second auxiliary factory, dodecyl diglycollic amide Shanghai;
JFC: polyoxyethylene aliphatic alcohol ether Shanghai chemical general factory;
Polyethers 2020: second auxiliary factory, Shanghai;

Claims (4)

1. efficient metal scavenger is characterized in that it is made up of following prescription, by weight percentage
The number meter:
Alkylphenol-polyethenoxy (10) ether 1~5%
Dodecyl diglycollic amide 1~5%
Polyoxyethylene aliphatic alcohol ether 1.5~5%
Polyethers 2,020 1~5%
Sodium Nitrite 5~10%
Trolamine 5~10%
All the other are water.
2. metal cleaner according to claim 1, the prescription that it is characterized in that it by weight hundred
Mark is counted:
Alkylphenol-polyethenoxy (10) ether 2~5%
Dodecyl diglycollic amide 1~3%
Polyoxyethylene aliphatic alcohol ether 1.5~3%
Polyethers 2,020 2~5%
Sodium Nitrite 5~8%
Trolamine 7~10%
All the other are water.
3. metal cleaner according to claim 1, the prescription that it is characterized in that it by weight hundred
Mark is counted:
Alkylphenol-polyethenoxy (10) ether 3%
Dodecyl diglycollic amide 2%
Polyoxyethylene aliphatic alcohol ether 2%
Polyethers 2,020 3%
Sodium Nitrite 5%
Trolamine 7%
All the other are water.
4. according to claim 1 or 2 or 3 described metal cleaners, it is characterized in that its prescription
In can also add the Sodium Benzoate of percentage ratio meter 1~10% by weight.
CN 01115063 2001-06-18 2001-06-18 Efficient metal scavenger Expired - Fee Related CN1117141C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 01115063 CN1117141C (en) 2001-06-18 2001-06-18 Efficient metal scavenger

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 01115063 CN1117141C (en) 2001-06-18 2001-06-18 Efficient metal scavenger

Publications (2)

Publication Number Publication Date
CN1323878A CN1323878A (en) 2001-11-28
CN1117141C true CN1117141C (en) 2003-08-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 01115063 Expired - Fee Related CN1117141C (en) 2001-06-18 2001-06-18 Efficient metal scavenger

Country Status (1)

Country Link
CN (1) CN1117141C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397334A (en) * 2013-07-01 2013-11-20 华南理工大学 Air valve rapidly-cleaning liquid, and preparation method and applications thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100460493C (en) * 2006-06-16 2009-02-11 大连绿洲化工有限公司 Environmental protection high concentration low foam rust proof metal cleaning agent and its technology
CN101358354B (en) * 2008-09-09 2010-06-02 中国核动力研究设计院 Cleaning agent of grease stain on metallic surface and method of use thereof
CN103343037B (en) * 2013-06-14 2015-02-18 烟台恒鑫化工科技有限公司 Production method for various metal working fluids
CN104032313A (en) * 2014-06-17 2014-09-10 顾兴 Rust removing and preventing agent
CN105647679A (en) * 2016-01-25 2016-06-08 龙笑琼 Air conditioner pipe cleaning agent and production process thereof
CN108169939A (en) * 2018-01-19 2018-06-15 京东方科技集团股份有限公司 Liquid crystal display substrate cleaning method, the method for forming oriented layer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397334A (en) * 2013-07-01 2013-11-20 华南理工大学 Air valve rapidly-cleaning liquid, and preparation method and applications thereof
CN103397334B (en) * 2013-07-01 2015-10-28 华南理工大学 A kind of valve Rapid Cleaning liquid and preparation method thereof and application

Also Published As

Publication number Publication date
CN1323878A (en) 2001-11-28

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