CN111713682A - Preparation method of colored salt and colored salt product - Google Patents

Preparation method of colored salt and colored salt product Download PDF

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Publication number
CN111713682A
CN111713682A CN202010601488.9A CN202010601488A CN111713682A CN 111713682 A CN111713682 A CN 111713682A CN 202010601488 A CN202010601488 A CN 202010601488A CN 111713682 A CN111713682 A CN 111713682A
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CN
China
Prior art keywords
salt
alcohol
colored salt
pigment
colored
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010601488.9A
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Chinese (zh)
Inventor
熊泽华
邱常义
胡景
宋信信
邓强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangxi Fu Da Salt Product Co ltd
Original Assignee
Jiangxi Fu Da Salt Product Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangxi Fu Da Salt Product Co ltd filed Critical Jiangxi Fu Da Salt Product Co ltd
Priority to CN202010601488.9A priority Critical patent/CN111713682A/en
Publication of CN111713682A publication Critical patent/CN111713682A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/40Table salts; Dietetic salt substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/40Colouring or decolouring of foods
    • A23L5/42Addition of dyes or pigments, e.g. in combination with optical brighteners
    • A23L5/43Addition of dyes or pigments, e.g. in combination with optical brighteners using naturally occurring organic dyes or pigments, their artificial duplicates or their derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/40Colouring or decolouring of foods
    • A23L5/42Addition of dyes or pigments, e.g. in combination with optical brighteners
    • A23L5/43Addition of dyes or pigments, e.g. in combination with optical brighteners using naturally occurring organic dyes or pigments, their artificial duplicates or their derivatives
    • A23L5/44Addition of dyes or pigments, e.g. in combination with optical brighteners using naturally occurring organic dyes or pigments, their artificial duplicates or their derivatives using carotenoids or xanthophylls
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

The invention provides a preparation method of colored salt and a colored salt product, wherein the preparation method of the colored salt comprises the following steps: adding an alcohol solution of pigment into saturated brine; heating and stirring, and filtering after precipitation; the precipitate obtained by filtration is dried to obtain a colored salt. The method has simple process, and the prepared colored salt has uniform particles, uniform color, high purity and high material recovery rate.

Description

Preparation method of colored salt and colored salt product
Technical Field
The invention relates to the technical field of salt preparation, in particular to a preparation method of colored salt and a colored salt product obtained by the preparation method.
Background
The color salt is one of fine chemical products with high added value in salt products, and has the advantages of wide application, higher price and large market demand. The colored salt can be roughly divided into the following two types according to the application and the preparation method: natural color salt and artificial color salt.
The color salt is one of fine chemical products with high added value in salt products, and has wide application: 1) the product can be widely applied to products such as shampoo, shower gel, hand sanitizer, microemulsion baby oil, facial cleanser, salt white toothpaste, mouthwash, deodorant soap, W/O cream, mineral bath salt, hot spring bath salt, explosion salt, crystal foot powder, fragrant bath salt, wheat protein skin-tendering salt oil-immersed cream, cappuccino double-layer no-clean spray hair conditioner, water-outlet cream, exfoliating shower gel and the like; 2) the colored salt lamp is used for making ornamental craft gifts and the like; 3) the colored salt can also be used as flavoring for special food materials.
The traditional color salt is prepared from natural color salt and artificial color salt. The natural color salt is mainly related to the geological structure of a production area and the mineral content in the color salt, is more representative of himalaya red salt, Hawaii black salt and the like, is greatly limited by regions and ore bodies and belongs to non-renewable resources. The artificial color salt is mainly used for achieving the purpose of dyeing by extracting pigments and then physically mixing the pigments with granular salt, but the physical mixing method has the following defects: because the salt particles are fine and large in amount, the salt particles cannot be uniformly dyed simply through physical mixing, and the material loss is large, so that the method is not beneficial to industrial production.
Chinese patent application publication No. CN109998083A describes "a plant color salt product and a production method thereof", wherein the technical scheme described in the patent document uses salt as a main material, treats plant organs rich in pigment to obtain natural extracts of anthocyanin, lutein, chlorophyll and the like with bright color, and uses the natural extracts as an auxiliary material, and adds color strengthening factors and auxiliary materials to prepare the color salt with bright color. According to the technical scheme, the color degree of the color salt can be improved through the color-sharing and compounding effects, but the method still prepares the color salt through a physical mixing method, and the defect of physical mixing can not be solved.
Disclosure of Invention
The first purpose of the invention is to provide a preparation method of color salt, which improves the color uniformity of the color salt and the yield of materials in a 'co-crystallization' mode.
It is a second object of the present invention to provide a colored salt obtained by the above-mentioned preparation method.
In order to achieve the first object, the present invention provides a method for preparing a color salt, comprising the steps of: adding alcohol solution of edible pigment into saturated brine; heating and stirring, and filtering after precipitation; the precipitate obtained by filtration is dried to obtain a colored salt.
In a further scheme, the edible pigment is a plant pigment.
Preferably, the plant pigment is at least one of chlorophyll, lutein, crocin and capsorubin.
The further scheme is that the chlorophyll is obtained by leaching spinach leaves with alcohol; the xanthophyll is obtained by extracting flos Tagetis Erectae with ethanol; crocin is obtained by extracting stigma croci with ethanol; capsorubin is obtained by extracting mature red pepper fruits with alcohol.
The further proposal is that the concentration of the alcohol in the alcohol solution of the edible pigment is 92 percent to 99 percent.
The further scheme is that the mass ratio of the saturated brine to the alcohol solution of the pigment is 1: 0.7-1: 4.
in a further proposal, the temperature of the liquid is kept between 40 and 45 ℃ in the heating and stirring step.
In order to achieve the second object, the present invention provides a colored salt product obtained by the above preparation method.
In a further aspect, a colored salt product comprises: according to the mass percentage, 95-98% of sodium chloride, 1.5-5% of pigment and 0.5-1.2% of water.
The invention has the beneficial effects that: (1) according to the invention, by utilizing the characteristic that sodium chloride is insoluble in alcohol, an alcohol solution of edible pigment is added into refined saturated brine, a large amount of sodium chloride can be separated out, the ethanol volatilizes through heating and stirring, the pigment is continuously separated out while the sodium chloride is separated out, the sodium chloride and the pigment are combined to form a colored precipitate, and the colored salt obtained through filtering and drying has uniform particles and uniform color;
(2) the method does not need to add any anticaking agent, and the obtained colored salt has high purity and less impurities;
(3) experiments show that the yield of the sodium chloride in the method reaches 35-60%, and the yield of the pigment reaches 55-80%.
(4) The invention is easy for mass production, and the ethanol can be recycled by the device.
Detailed Description
The invention provides a preparation method of colored salt, which specifically comprises the following steps:
(1) taking 1 part of refined saturated brine and 1 part of alcohol extraction solution of edible pigment;
(2) slowly adding the alcohol extraction solution of the edible pigment into the refined saturated brine;
(3) slowly heating, stirring and mixing for a period of time, controlling the heating temperature of the liquid at 40-45 ℃ until the color precipitation is complete;
(4) filtering, drying, pulverizing, and sieving to obtain colored salt.
The refined saturated brine is extracted from brine supply center refined brine of Fuda salinization Co, Jiangxi, wherein the NaCl content is 310-.
Example one
Preparation of Green salt
(1) Taking 1 part of 100mL of refined saturated brine and 1 part of 100mL of alcohol solution of chlorophyll extract, wherein the concentration of alcohol is 97.5 percent, and in the invention, the concentration of alcohol refers to the content (mass fraction) of ethanol in the alcohol;
(2) slowly adding alcohol solution of chlorophyll extract into refined saturated brine;
(3) slowly heating, stirring and mixing for half an hour, controlling the heating temperature of the liquid to be 40 ℃, and waiting for complete precipitation;
(4) filtering the precipitate, drying, pulverizing, and sieving to obtain green salt.
Preferably, the alcoholic solution of chlorophyll extract is obtained by extracting leaves of spinach with alcohol.
The content of sodium chloride in the green salt prepared by the method is 96.4%, the content of pigment is 2.8%, the content of water is 0.8%, the sodium chloride and the pigment are cocrystallized, the color of the green salt is uniform, the yield of the sodium chloride is 41.6%, and the yield of the pigment is 61.3%.
Example two
Preparation of yellow salt
(1) Taking 1 part of 100mL of refined saturated brine and 1 part of 200mL of alcoholic solution of lutein extract, wherein the concentration of alcohol is 95.5%;
(2) slowly adding the alcohol solution of the lutein extract into the refined saturated brine;
(3) slowly heating, stirring and mixing for half an hour, controlling the heating temperature of the liquid to be 40 ℃, and waiting for complete precipitation;
(4) filtering the precipitate, drying, pulverizing, and sieving to obtain green salt.
Preferably, the alcoholic solution of the above xanthophyll extract is obtained by alcohol extraction of marigold.
The content of sodium chloride in the yellow salt prepared by the method is 96.3%, the content of pigment is 2.9%, the content of water is 0.8%, the sodium chloride and the pigment achieve cocrystallization, the color of the yellow salt is uniform, the yield of the sodium chloride is 38.4%, and the yield of the pigment is 58.5%.
EXAMPLE III
Preparation of Red salt
(1) Collecting 1 part of 100mL refined saturated brine and 1 part of 300mL crocin extract alcohol solution, wherein the alcohol concentration is 98.7%;
(2) slowly adding crocin extract alcoholic solution into refined saturated brine;
(3) slowly heating, stirring and mixing for half an hour, controlling the heating temperature of the liquid to be 43 ℃, and waiting for complete precipitation;
(4) filtering the precipitate, drying, pulverizing, and sieving to obtain green salt.
Preferably, the alcoholic solution of crocin extract is obtained by extracting saffron with alcohol.
The red salt prepared by the method has the sodium chloride content of 97.2 percent, the pigment content of 1.9 percent and the water content of 0.9 percent, and the sodium chloride and the pigment achieve cocrystallization, the red salt has uniform color, the sodium chloride yield reaches 41.1 percent, and the pigment yield reaches 61.3 percent.
Example four
Preparation of Red salt
(1) Taking 1 part of 100mL of refined saturated brine and 1 part of 400mL of alcohol solution of capsorubin extract, wherein the concentration of the alcohol is 92.5%;
(2) slowly adding the alcohol solution of capsorubin extract into refined saturated brine;
(3) slowly heating, stirring and mixing for half an hour, controlling the heating temperature of the liquid to be 40 ℃, and waiting for complete precipitation;
(4) filtering the precipitate, drying, pulverizing, and sieving to obtain green salt.
Preferably, the alcoholic solution of the above capsorubin extract is obtained by alcohol extraction of mature red pepper fruits.
The red salt prepared by the method has the sodium chloride content of 96.2 percent, the pigment content of 3.0 percent and the water content of 0.8 percent, and the sodium chloride and the pigment are cocrystallized, so that the red salt has uniform color, the sodium chloride yield reaches 39.2 percent and the pigment yield reaches 58.9 percent.
Finally, it should be emphasized that the above-described preferred embodiments of the present invention are merely examples of implementations, rather than limitations, and that many variations and modifications of the invention are possible to those skilled in the art, without departing from the spirit and scope of the invention.

Claims (9)

1. The preparation method of the colored salt is characterized by comprising the following steps of:
adding alcohol solution of edible pigment into saturated brine;
heating and stirring, and filtering after precipitation;
and drying the precipitate obtained by filtering to obtain the colored salt.
2. The method of claim 1, wherein:
the edible pigment is plant pigment.
3. The method of claim 2, wherein:
the plant pigment is at least one of chlorophyll, lutein, crocin and capsorubin.
4. The method of claim 3, wherein:
the chlorophyll is obtained by leaching spinach leaves with alcohol;
the lutein is obtained by leaching marigold with alcohol;
the crocin is obtained by extracting saffron with alcohol;
the capsorubin is obtained by extracting mature red pepper fruits with alcohol.
5. The method of claim 1, wherein:
the concentration of the alcohol in the alcohol solution of the edible pigment is 92-99%.
6. The method of claim 1, wherein:
the mass ratio of the saturated brine to the alcoholic solution of the edible pigment is 1: 0.7-1: 4.
7. the method of preparing a colored salt according to any one of claims 1 to 6, wherein:
in the heating and stirring step, the liquid temperature is kept between 40 and 45 ℃.
8. A colored salt preparation obtained by the method for producing a colored salt according to any one of claims 1 to 7.
9. The colored salt article of claim 8, wherein:
the colored salt article comprises: according to the mass percentage, 95-98% of sodium chloride, 1.5-4% of edible pigment and 0.5-1.2% of water.
CN202010601488.9A 2020-06-28 2020-06-28 Preparation method of colored salt and colored salt product Pending CN111713682A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020090194A (en) * 2002-10-30 2002-11-30 도대홍 Production of colored and flavored table salt
JP2007145945A (en) * 2005-11-25 2007-06-14 San Akuteisu:Kk Method for producing anthocyanin-based pigment
JP2007191683A (en) * 2005-10-07 2007-08-02 Yasumasa Tsukuda Food containing nasunine or the like and method for producing the same
JP2015174858A (en) * 2014-03-18 2015-10-05 理研ビタミン株式会社 pepper dye extract
JP2015229610A (en) * 2014-06-04 2015-12-21 進 池田 Salt production method
CN107927702A (en) * 2017-11-06 2018-04-20 云南省盐业有限公司 A kind of natural seven-color nourishing salt
CN109998083A (en) * 2019-04-10 2019-07-12 云南省盐业有限公司 A kind of plant color salt product and its production method
JP2019137818A (en) * 2018-02-15 2019-08-22 国立大学法人 鹿児島大学 Red dye contained in passion fruit pericarp and method for producing the same

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020090194A (en) * 2002-10-30 2002-11-30 도대홍 Production of colored and flavored table salt
JP2007191683A (en) * 2005-10-07 2007-08-02 Yasumasa Tsukuda Food containing nasunine or the like and method for producing the same
JP2007145945A (en) * 2005-11-25 2007-06-14 San Akuteisu:Kk Method for producing anthocyanin-based pigment
JP2015174858A (en) * 2014-03-18 2015-10-05 理研ビタミン株式会社 pepper dye extract
JP2015229610A (en) * 2014-06-04 2015-12-21 進 池田 Salt production method
CN107927702A (en) * 2017-11-06 2018-04-20 云南省盐业有限公司 A kind of natural seven-color nourishing salt
JP2019137818A (en) * 2018-02-15 2019-08-22 国立大学法人 鹿児島大学 Red dye contained in passion fruit pericarp and method for producing the same
CN109998083A (en) * 2019-04-10 2019-07-12 云南省盐业有限公司 A kind of plant color salt product and its production method

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