CN111663129A - 一种化学镀铝合金工艺(氯化铝型) - Google Patents
一种化学镀铝合金工艺(氯化铝型) Download PDFInfo
- Publication number
- CN111663129A CN111663129A CN201910260654.0A CN201910260654A CN111663129A CN 111663129 A CN111663129 A CN 111663129A CN 201910260654 A CN201910260654 A CN 201910260654A CN 111663129 A CN111663129 A CN 111663129A
- Authority
- CN
- China
- Prior art keywords
- plating
- tin
- aluminum
- chemical
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007747 plating Methods 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000000126 substance Substances 0.000 title claims abstract description 14
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 title description 4
- 229910001128 Sn alloy Inorganic materials 0.000 claims description 12
- YVIMHTIMVIIXBQ-UHFFFAOYSA-N [SnH3][Al] Chemical compound [SnH3][Al] YVIMHTIMVIIXBQ-UHFFFAOYSA-N 0.000 claims description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 229910018140 Al-Sn Inorganic materials 0.000 claims description 5
- 229910018564 Al—Sn Inorganic materials 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 229910000906 Bronze Inorganic materials 0.000 claims description 3
- 239000010974 bronze Substances 0.000 claims description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 2
- 238000007323 disproportionation reaction Methods 0.000 claims description 2
- 230000001603 reducing effect Effects 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims 4
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1827—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment only one step pretreatment
- C23C18/1831—Use of metal, e.g. activation, sensitisation with noble metals
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
Abstract
本发明化学镀铝合金工艺的特点:所有镀液工作温度均为20℃以上,镀液工作时不产生气体,镀液长期稳定,易调整,镀出的铝合金镀层为阳极镀层(对钢铁件而言),镀层光亮,为银白色,长期存放不变色。本发明是高节能又环保的加工工艺。
Description
说明书
本发明属化学镀技术领域。
本发明化学镀铝合金工艺,是以化学镀低锡青铜为底层,经化学镀薄层锡后,再化学镀铝合金。该工艺的特点:所有镀液工作温度均为20℃以上,镀液工作时不产生气体,镀液长期稳定,易调整,镀出的铝合金镀层为阳极镀层(对钢铁件而言)。镀层光亮为银白色,长期保存不变色。本发明是高度节能又环保的加工工艺。
本发明化学镀铝合金工艺,既为化学镀铝锡合金工艺。
本发明化学镀铝锡合金工艺的程序及工艺条件(以钢铁件为例):
1、除油除锈和钢铁件电镀预处理相同。
2、化学镀低锡青铜。
3、冷水清洗。
4、化学镀薄层锡。
镀液配方及工艺条件:
温度:20℃以上
处理时间:不超过一分钟
5、冷水清洗
6、化学镀铝锡合金。镀液配方:
温度:20℃以上
处理时间:40分钟以上
Claims (3)
1.化学镀铝锡合金工艺,其特征在于化学镀低锡青铜为底层,经化学镀薄层锡后,最后进行化学镀铝锡合金。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910260654.0A CN111663129A (zh) | 2019-03-06 | 2019-03-06 | 一种化学镀铝合金工艺(氯化铝型) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910260654.0A CN111663129A (zh) | 2019-03-06 | 2019-03-06 | 一种化学镀铝合金工艺(氯化铝型) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111663129A true CN111663129A (zh) | 2020-09-15 |
Family
ID=72382281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910260654.0A Pending CN111663129A (zh) | 2019-03-06 | 2019-03-06 | 一种化学镀铝合金工艺(氯化铝型) |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111663129A (zh) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06330330A (ja) * | 1993-05-26 | 1994-11-29 | Seiko Epson Corp | アルミニウム無電解メッキ法 |
| JP2008013845A (ja) * | 2006-06-06 | 2008-01-24 | Nobuyuki Koura | 無電解アルミニウムめっき浴及びアルミニウムの無電解めっき方法 |
| CN101210319A (zh) * | 2007-12-21 | 2008-07-02 | 凌国平 | 化学镀铝溶液及化学镀铝方法 |
| JP2014098180A (ja) * | 2012-11-14 | 2014-05-29 | Sumitomo Electric Ind Ltd | めっき鋼線 |
| CN104178755A (zh) * | 2014-09-16 | 2014-12-03 | 朱忠良 | 一种金属镀层的涂覆方法 |
| US9803283B1 (en) * | 2013-10-18 | 2017-10-31 | Hrl Laboratories, Llc | Method of electroless deposition of aluminum or aluminum alloy, an electroless plating composition, and an article including the same |
| CN108505024A (zh) * | 2018-06-29 | 2018-09-07 | 林忠华 | 化学镀镍-锡-铝-磷非晶态多功能合金镀液及其镀层 |
-
2019
- 2019-03-06 CN CN201910260654.0A patent/CN111663129A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06330330A (ja) * | 1993-05-26 | 1994-11-29 | Seiko Epson Corp | アルミニウム無電解メッキ法 |
| JP2008013845A (ja) * | 2006-06-06 | 2008-01-24 | Nobuyuki Koura | 無電解アルミニウムめっき浴及びアルミニウムの無電解めっき方法 |
| CN101210319A (zh) * | 2007-12-21 | 2008-07-02 | 凌国平 | 化学镀铝溶液及化学镀铝方法 |
| JP2014098180A (ja) * | 2012-11-14 | 2014-05-29 | Sumitomo Electric Ind Ltd | めっき鋼線 |
| US9803283B1 (en) * | 2013-10-18 | 2017-10-31 | Hrl Laboratories, Llc | Method of electroless deposition of aluminum or aluminum alloy, an electroless plating composition, and an article including the same |
| CN104178755A (zh) * | 2014-09-16 | 2014-12-03 | 朱忠良 | 一种金属镀层的涂覆方法 |
| CN108505024A (zh) * | 2018-06-29 | 2018-09-07 | 林忠华 | 化学镀镍-锡-铝-磷非晶态多功能合金镀液及其镀层 |
Non-Patent Citations (2)
| Title |
|---|
| 吕选忠等: "《元素生物学》", 31 January 2011, 中国科学技术大学出版社 * |
| 姜晓霞等: "《化学镀理论及实践》", 30 June 2000, 国防工业出版社 * |
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Application publication date: 20200915 |







