CN111642511A - Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof - Google Patents
Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof Download PDFInfo
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- CN111642511A CN111642511A CN202010630181.1A CN202010630181A CN111642511A CN 111642511 A CN111642511 A CN 111642511A CN 202010630181 A CN202010630181 A CN 202010630181A CN 111642511 A CN111642511 A CN 111642511A
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- Prior art keywords
- thiacloprid
- chlorantraniliprole
- deionized water
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- red pine
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention provides a microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof. According to the technical scheme, thiacloprid and chlorantraniliprole are taken as active ingredients, polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, cardanol polyoxyethylene ether and propylene glycol monomethyl ether are taken as auxiliary agents, and the auxiliary agents and water are compounded according to a specific weight ratio. Wherein, 0.5 to 5 percent of thiacloprid, 1 to 10 percent of chlorantraniliprole, 5 to 15 percent of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 1 to 10 percent of cardanol polyoxyethylene ether, 5 to 15 percent of propylene glycol monomethyl ether and deionized water are added to make up to 100 percent. The invention has obvious control effect on the red pine cone borer, and the invention utilizes the contact killing, permeation, systemic conduction, controlled release and other effects of thiacloprid and chlorantraniliprole on the red pine cone borer, has good quick action, long lasting period, no influence on non-target organisms, can improve the health of red pine and improve the quantity and quality of red pine cone seeds.
Description
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a microcapsule suspending agent for preventing and treating red pine tip mottled borer and application thereof.
Background
Korean pine is the main tree species of mixed forest with needle leaves and broad leaves in cold and warm areas, and is a precious wood. In recent years, the development of the Korean pine industry and the growth of forests are seriously influenced by Korean pine tree pests. With the increase of the planting area of the red pine and the interference of the red pine cone pinworm disease, the damage to the cones and the twigs of the red pine is more and more serious. The damage rate of cones and twigs of the Korean pine can reach about 40 percent, the seed loss rate can reach 25 percent, and the method has serious threat to forest ecological environment and forestry economic development. The fruit tip spotted borer (Diorytriaphyrii Ragonit) belongs to the family of Lepidoptera (Lepidotera) borer (Pyralidae), is a borer and also an important pest damaging the fruit of Pinus Koraiensis (Pinus Koraiensis). In recent years, the method is applied to seed gardens of Korean pine, natural Korean pine mother forests and artificial Korean pine forests. The worm damages the cones and young shoots of the Korean pine by boring with larvae, and the cones are bent and deformed, dried and withered when damaged, thereby affecting the yield and quality of seeds and causing economic loss; the growth of the tree is inhibited after the tender tips are damaged, and the normal growth of the tree is influenced.
At present, organophosphorus and organochlorine pesticides with high toxicity and pyrethroid pesticides with high toxicity to beneficial insects and birds are generally adopted in China for prevention and treatment, but because of the boring property of the fruit tip spotted borer and the long hazard period of the fruit tip spotted borer, the pesticide and the prevention and treatment method are difficult to control the generation of the fruit tip spotted borer. Due to repeated application, not only the drug resistance is generated, but also the ecological environment is destroyed.
In recent years, new insecticides such as emamectin benzoate, deltamethrin, matrine, chlorbenzuron, abamectin and the like are continuously developed, but the insecticides also have the problems of insecticide resistance and poor pesticide effect after being singly used for a long time, and the current pesticide requirements for preventing and controlling the fruit tip striped rice borer are difficult to meet. Therefore, the development of a novel pesticide for effectively controlling the red pine tip striped rice borer is urgently needed.
Disclosure of Invention
The invention aims to provide a microcapsule suspending agent for preventing and treating red pine tip mottled borer and application thereof aiming at overcoming the technical defects of the prior art, and aims to solve the technical problem that the conventional pesticide has poor prevention and treatment effect on the red pine tip mottled borer in the prior art.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
a microcapsule suspending agent for preventing and treating red pine tip striped rice borer comprises the following components in percentage by weight: 0.5-5% of thiacloprid, 1-10% of chlorantraniliprole, 5-15% of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 1-10% of cardanol polyoxyethylene ether, 5-15% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
Preferably, the paint comprises the following components in percentage by weight: 1-5% of thiacloprid, 1-6% of chlorantraniliprole, 6-12% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 2-8% of cardanol polyoxyethylene ether, 6-12% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
Preferably, the paint comprises the following components in percentage by weight: 2.5-3.5% of thiacloprid, 1-3% of chlorantraniliprole, 7-10% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 3-6% of cardanol polyoxyethylene ether, 6-10% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
Preferably, the paint comprises the following components in percentage by weight: 3% of thiacloprid, 2% of chlorantraniliprole, 8% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 5% of cardanol polyoxyethylene ether, 8% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
On the basis of the technical scheme, the invention further provides application of the microcapsule suspending agent for preventing and treating the red pine tip striped rice borer, wherein in the application, the microcapsule suspending agent is applied in the period of laying eggs of adults and hatching eggs to obtain primary-hatched larvae; the number of pesticide application is 2 per year; the application dosage is 5g to 15g of the microcapsule suspending agent per mu.
Preferably, the administration dose is 10g of the microcapsule suspension per acre.
The invention provides a microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof. According to the technical scheme, thiacloprid and chlorantraniliprole are taken as active ingredients, polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, cardanol polyoxyethylene ether and propylene glycol monomethyl ether are taken as auxiliary agents, and the auxiliary agents and water are compounded according to a specific weight ratio. Wherein, 0.5 to 5 percent of thiacloprid, 1 to 10 percent of chlorantraniliprole, 5 to 15 percent of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 1 to 10 percent of cardanol polyoxyethylene ether, 5 to 15 percent of propylene glycol monomethyl ether and deionized water are added to make up to 100 percent. The invention has obvious control effect on the red pine cone borer, and the invention utilizes the contact killing, permeation, systemic conduction, controlled release and other effects of thiacloprid and chlorantraniliprole on the red pine cone borer, has good quick action, long lasting period, no influence on non-target organisms, can improve the health of red pine and improve the quantity and quality of red pine cone seeds.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Detailed Description
Hereinafter, specific embodiments of the present invention will be described in detail. Well-known structures or functions may not be described in detail in the following embodiments in order to avoid unnecessarily obscuring the details. Approximating language, as used herein in the following examples, may be applied to identify quantitative representations that could permissibly vary in number without resulting in a change in the basic function. Unless defined otherwise, technical and scientific terms used in the following examples have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
In the invention, thiacloprid is the trade name of a compound (3- ((6-chloro-3-pyridyl) methyl) -1, 3-thiazoline-2-subunit) cyanamide, the name of English is thiacloprid, and the molecular formula is C10H9ClN4The relative molecular mass is 252.72, the CAS number is 111988-49-9, and the structural formula is shown in formula (1):
in the present invention, chlorantraniliprole is the compound 3-bromo-N- [ 4-chloro-2-methyl-6- (methylcarbamoyl) benzene]-1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide, having the tradename chloranraniprop, England name and molecular formula C18H14BrCl2N5O2The molecular weight is 483.15, CAS number is 500008-45-7, and the structural formula is shown in formula (2).
Example 1A microcapsule suspension for controlling Dioryza incertulas
The raw material components by weight percentage are as follows:
3% of thiacloprid, 2% of chlorantraniliprole, 8% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 5% of cardanol polyoxyethylene ether, 8% of polypropylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
The components are prepared into the microcapsule suspending agent preparation suitable for forestry by applying the conventional pesticide processing technology. The co-toxicity coefficient of thiacloprid and chlorantraniliprole in the example is 258.32.
The microcapsule suspending agent preparation obtained in the embodiment 1 of the invention is used for preventing and controlling the red pine tip striped rice borer, and is applied in the period of oviposition of adult and hatching of eggs and initial larva; the number of pesticide application is 2 per year; the active ingredient is 10 g/mu, the spraying is carried out for 2 times, and the control effects 7 days and 14 days after the second application are 91.4 percent and 96.3 percent respectively. The 3% thiacloprid microcapsule suspending agent is sprayed with the active ingredients for 2 times according to 20 g/mu, and the control effects 7 days and 14 days after the second application are 61.6% and 64.3% respectively. The 5% chlorantraniliprole suspending agent is sprayed for 2 times according to 20 g/mu of the applied active ingredient, and the control effects 7 days and 14 days after the second application are respectively 38.5% and 34.3%.
Example 2A microcapsule suspension for controlling Dioryzophragma nubilalis
The raw material components by weight percentage are as follows:
0.5% of thiacloprid, 6% of chlorantraniliprole, 9% of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 4% of cardanol polyoxyethylene ether, 7% of polypropylene glycol monomethyl ether and deionized water, wherein the balance is up to 100%.
The components are prepared into the microcapsule suspending agent preparation suitable for forestry by applying the conventional pesticide processing technology. The co-toxicity coefficient of thiacloprid and chlorantraniliprole in the example is 213.67.
The microcapsule suspending agent preparation obtained in the embodiment 2 is used for preventing and treating the red pine tip striped rice borer, and is applied in the period of oviposition of adults and initial larva incubation of eggs; the number of pesticide application is 2 per year; the active ingredient is 10 g/mu, the spraying is carried out for 2 times, and the control effects 7 days and 14 days after the second application are respectively 89.7 percent and 93.4 percent. The 3% thiacloprid microcapsule suspending agent is sprayed with the active ingredients for 2 times according to 20 g/mu, and the control effects 7 days and 14 days after the second application are 61.6% and 64.3% respectively. The 5% chlorantraniliprole suspending agent is sprayed for 2 times according to 20 g/mu of the applied active ingredient, and the control effects 7 days and 14 days after the second application are respectively 38.5% and 34.3%.
Example 3A microcapsule suspension for controlling Dioryza incertulas
The raw material components by weight percentage are as follows:
4% of thiacloprid, 1.5% of chlorantraniliprole, 7% of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 6% of cardanol polyoxyethylene ether, 9% of polypropylene glycol monomethyl ether and deionized water, wherein the balance is up to 100%.
The components are prepared into the microcapsule suspending agent preparation suitable for forestry by applying the conventional pesticide processing technology. The co-toxicity coefficient of thiacloprid and chlorantraniliprole in the example is 189.14.
The microcapsule suspending agent preparation obtained in the embodiment 3 is used for preventing and treating the red pine tip striped rice borer, and is applied in the period of oviposition of adult and hatching of eggs and initial larva; the number of pesticide application is 2 per year; the active ingredient is 10 g/mu, the spraying is carried out for 2 times, and the control effects 7 days and 14 days after the second application are respectively 88.6 percent and 91.5 percent. The 3% thiacloprid microcapsule suspending agent is sprayed with the active ingredients for 2 times according to 20 g/mu, and the control effects 7 days and 14 days after the second application are 61.6% and 64.3% respectively. The 5% chlorantraniliprole suspending agent is sprayed for 2 times according to 20 g/mu of the applied active ingredient, and the control effects 7 days and 14 days after the second application are respectively 38.5% and 34.3%.
Example 4A microcapsule suspension for controlling Dioryza incertulas
The raw material components by weight percentage are as follows:
5% of thiacloprid, 3% of chlorantraniliprole, 8% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 4% of cardanol polyoxyethylene ether, 6% of polypropylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
The components are prepared into the microcapsule suspending agent preparation suitable for forestry by applying the conventional pesticide processing technology. The co-toxicity coefficient of thiacloprid and chlorantraniliprole in the example is 152.35.
The microcapsule suspending agent preparation obtained in the embodiment 4 of the invention is used for preventing and controlling the red pine fruit tip striped rice borer, and is applied in the period of oviposition of adult and hatching of eggs to obtain primary larva; the number of pesticide application is 2 per year; the active ingredient is 10 g/mu, the spraying is carried out for 2 times, and the control effects 7 days and 14 days after the second application are respectively 87.7 percent and 89.2 percent. The 3% thiacloprid microcapsule suspending agent is sprayed with the active ingredients for 2 times according to 20 g/mu, and the control effects 7 days and 14 days after the second application are 61.6% and 64.3% respectively. The 5% chlorantraniliprole suspending agent is sprayed for 2 times according to 20 g/mu of the applied active ingredient, and the control effects 7 days and 14 days after the second application are respectively 38.5% and 34.3%.
Example 5A microcapsule suspension for controlling Dioryzophragma nubilalis
The raw material components by weight percentage are as follows:
1% of thiacloprid, 9% of chlorantraniliprole, 6% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 4% of cardanol polyoxyethylene ether, 9% of polypropylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
The components are prepared into the microcapsule suspending agent preparation suitable for forestry by applying the conventional pesticide processing technology. The co-toxicity coefficient of thiacloprid and chlorantraniliprole in the example is 174.58.
The microcapsule suspending agent preparation obtained in the embodiment 5 is used for preventing and controlling the red pine fruit tip striped rice borer, and is applied in the period of oviposition of adult and hatching of eggs and initial larva; the number of pesticide application is 2 per year; the active ingredient is 10 g/mu, the spraying is carried out for 2 times, and the control effects 7 days and 14 days after the second application are respectively 88.5 percent and 90.8 percent. The 3% thiacloprid microcapsule suspending agent is sprayed with the active ingredients for 2 times according to 20 g/mu, and the control effects 7 days and 14 days after the second application are 61.6% and 64.3% respectively. The 5% chlorantraniliprole suspending agent is sprayed for 2 times according to 20 g/mu of the applied active ingredient, and the control effects 7 days and 14 days after the second application are respectively 38.5% and 34.3%.
Comparing the data of the examples 1 to 5, it can be seen that the microcapsule suspending agent for controlling the red pine tip maculata suppressalis of the invention adopts a scheme of compounding two active ingredients, the biological activity and the control effect of the microcapsule suspending agent are not simple addition of the activities of the components, and compared with a preparation with a single ingredient, the microcapsule suspending agent has the advantages of remarkable control effect, remarkable synergistic effect, capability of slowing down the generation of resistance and improving the control effect, thereby improving the plant health and reducing the pollution to the environment.
The embodiments of the present invention have been described in detail, but the description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention. Any modification, equivalent replacement, and improvement made within the scope of the application of the present invention should be included in the protection scope of the present invention.
Claims (6)
1. The microcapsule suspending agent for preventing and treating the red pine tip striped rice borer is characterized by comprising the following components in percentage by weight: 0.5-5% of thiacloprid, 1-10% of chlorantraniliprole, 5-15% of polycarboxylate and polyoxyethylene polyoxypropylene ether block copolymer, 1-10% of cardanol polyoxyethylene ether, 5-15% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
2. The microcapsule suspension for controlling the yellow-eared pinworm according to claim 1, which is characterized by comprising the following components in percentage by weight: 1-5% of thiacloprid, 1-6% of chlorantraniliprole, 6-12% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 2-8% of cardanol polyoxyethylene ether, 6-12% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
3. The microcapsule suspension for controlling the yellow-eared pinworm according to claim 1, which is characterized by comprising the following components in percentage by weight: 2.5-3.5% of thiacloprid, 1-3% of chlorantraniliprole, 7-10% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 3-6% of cardanol polyoxyethylene ether, 6-10% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
4. The microcapsule suspension for controlling the yellow-eared pinworm according to claim 1, which is characterized by comprising the following components in percentage by weight: 3% of thiacloprid, 2% of chlorantraniliprole, 8% of polycarboxylate and polyoxyethylene polyoxypropylene block copolymer, 5% of cardanol polyoxyethylene ether, 8% of propylene glycol monomethyl ether and deionized water, wherein the deionized water is used for supplementing to 100%.
5. Use of the microcapsule suspension according to any one of claims 1 to 4 for controlling the pink pine tip borer, characterized in that in the use, the application is carried out at the stage of the adult laying and the initial hatching of eggs; the number of pesticide application is 2 per year; the application dosage is 5g to 15g of the microcapsule suspending agent per mu.
6. The use according to claim 5, wherein the administration dose is 10g of said suspension of microcapsules per acre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010630181.1A CN111642511A (en) | 2020-07-03 | 2020-07-03 | Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN202010630181.1A CN111642511A (en) | 2020-07-03 | 2020-07-03 | Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof |
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| CN111642511A true CN111642511A (en) | 2020-09-11 |
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| CN202010630181.1A Withdrawn CN111642511A (en) | 2020-07-03 | 2020-07-03 | Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN102273446A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Thiacloprid-containing ultralow-volume liquid |
| CN104824013A (en) * | 2015-05-14 | 2015-08-12 | 广西大学 | Film-spreading oil agent containing chlorantraniliprole and chloronicotinyl insecticide |
| CN108849959A (en) * | 2018-08-10 | 2018-11-23 | 六夫丁作物保护有限公司 | Pesticidal combination, insecticidal and bactericidal composition and seed treatment suspending agent |
| CN111602665A (en) * | 2020-06-13 | 2020-09-01 | 江西啄木蜂科技有限公司 | Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof |
-
2020
- 2020-07-03 CN CN202010630181.1A patent/CN111642511A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN102273446A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Thiacloprid-containing ultralow-volume liquid |
| CN104824013A (en) * | 2015-05-14 | 2015-08-12 | 广西大学 | Film-spreading oil agent containing chlorantraniliprole and chloronicotinyl insecticide |
| CN108849959A (en) * | 2018-08-10 | 2018-11-23 | 六夫丁作物保护有限公司 | Pesticidal combination, insecticidal and bactericidal composition and seed treatment suspending agent |
| CN111602665A (en) * | 2020-06-13 | 2020-09-01 | 江西啄木蜂科技有限公司 | Microcapsule suspending agent for preventing and treating red pine tip striped rice borer and application thereof |
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Application publication date: 20200911 |