CN111613349A - Device and method for removing trace gas based on fluid self-oscillation and micro-interface strengthening - Google Patents

Device and method for removing trace gas based on fluid self-oscillation and micro-interface strengthening Download PDF

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CN111613349A
CN111613349A CN202010477560.1A CN202010477560A CN111613349A CN 111613349 A CN111613349 A CN 111613349A CN 202010477560 A CN202010477560 A CN 202010477560A CN 111613349 A CN111613349 A CN 111613349A
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CN111613349B (en
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尹俊连
张泽楷
宋煜晨
王德忠
方浚麟
李宏轩
卫雪岩
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Shanghai Jiao Tong University
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    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D19/0073Degasification of liquids by a method not covered by groups B01D19/0005 - B01D19/0042
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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Abstract

本发明提供了一种基于流体自振荡和微界面强化的微量气体脱除装置,包括文丘里微气泡生成装置、流体振荡器、反应釜和气液分离装置;气液分离装置的底端设有切向底流口,侧面设有切向进口,顶端设有溢流管;反应釜的侧面设有切向出口,顶部设有气液混合物进口;文丘里微气泡生成装置的底部与熔盐回路连通,顶部与流体振荡器的底部连接;流体振荡器的顶部连接至反应釜的底端;反应釜顶端的气液混合物进口与溢流管连通;气液分离装置侧面的切向进口与反应釜的切向出口连接;底端的切向底流口与熔盐回路连通。本发明的微量气体脱除装置,可以有效脱除熔盐堆熔盐回路中的裂变气体氪、氙等,减少中子损耗,减轻设备维护成本,显著提高熔盐堆经济效益。

Figure 202010477560

The invention provides a trace gas removal device based on fluid self-oscillation and micro-interface enhancement, including a venturi micro-bubble generating device, a fluid oscillator, a reaction kettle and a gas-liquid separation device; the bottom end of the gas-liquid separation device is provided with a cutting The bottom flow port is provided with a tangential inlet on the side and an overflow pipe on the top; the side of the reaction kettle is provided with a tangential outlet, and the top is provided with a gas-liquid mixture inlet; the bottom of the venturi micro-bubble generating device is communicated with the molten salt circuit, The top is connected to the bottom of the fluid oscillator; the top of the fluid oscillator is connected to the bottom of the reactor; the gas-liquid mixture inlet at the top of the reactor is communicated with the overflow pipe; the tangential inlet on the side of the gas-liquid separation device is connected to the tangential inlet of the reactor. Connect to the outlet; the tangential underflow port at the bottom end communicates with the molten salt circuit. The trace gas removal device of the invention can effectively remove the fission gases krypton, xenon, etc. in the molten salt circuit of the molten salt reactor, reduce neutron loss, reduce equipment maintenance costs, and significantly improve the economic benefits of the molten salt reactor.

Figure 202010477560

Description

基于流体自振荡和微界面强化的微量气体脱除装置及方法Device and method for removing trace gas based on fluid self-oscillation and micro-interface strengthening

技术领域technical field

本发明涉及裂变气体脱除技术领域,具体地,涉及一种微量气体脱除装置及脱除方法,尤其是,涉及一种基于流体自振荡和微界面强化技术的微量气体脱除装置及脱除方法。The invention relates to the technical field of fission gas removal, in particular, to a trace gas removal device and a removal method, in particular, to a trace gas removal device and removal method based on fluid self-oscillation and micro-interface strengthening technology method.

背景技术Background technique

钍基核能具有中子增殖性能好、产生高放废料少和储量丰富等特点;熔盐堆作为第四代先进反应堆个候选堆之一,具有钍高效利用、高温制氢、无水冷却、适合小型模块化设计等优势和潜力。但是熔盐堆反应过程中会产生大量如氙和氪等气体中子毒物,不仅阻碍了熔盐堆的链式反应,而且还会对管道设备产生极大地危害。由于中子毒物微溶于燃料盐并以微小气泡存在,美国提出了先鼓入气泡,使裂变气体扩散到气泡,后进行分离的模式。针对熔盐堆回路中气泡小、熔盐介质粘度大等特点,国际上主流采用旋流式分离方法对中子毒物进行去除。Thorium-based nuclear energy has the characteristics of good neutron breeding performance, less high-level waste and abundant reserves. As one of the candidate reactors of the fourth generation advanced reactor, the molten salt reactor has the advantages of efficient utilization of thorium, high-temperature hydrogen production, water-free cooling, suitable for Advantages and potentials such as small modular design. However, a large amount of gaseous neutron poisons such as xenon and krypton will be produced during the reaction of the molten salt reactor, which not only hinders the chain reaction of the molten salt reactor, but also causes great harm to the pipeline equipment. Since the neutron poison is slightly soluble in the fuel salt and exists in the form of tiny bubbles, the United States proposes a mode of infusing the bubbles first, so that the fission gas diffuses into the bubbles, and then separates. In view of the characteristics of small bubbles and high viscosity of the molten salt medium in the molten salt reactor circuit, the international mainstream adopts the cyclone separation method to remove neutron poisons.

旋流分离技术是一种利用离心力及两相密度差来实现多相分离的高效分离技术,其结构简单、体积紧凑质量轻且分离效率高,目前正逐步替代传统的重力沉降式分离设备。但是旋流分离技术具体分离条件苛刻,对分离器背压有一定要求的特点,Cyclone separation technology is a high-efficiency separation technology that utilizes centrifugal force and two-phase density difference to achieve multi-phase separation. However, the specific separation conditions of cyclone separation technology are harsh, and there are certain requirements for the back pressure of the separator.

经过对现有技术的检索,李华等在期刊《核技术》中发表的文章《不同背压下旋流式气液分离器工作特性》中,公开了一种适用于熔盐堆脱气系统的旋流式气液分离器,该分离器的分离条件主要是要控制背压,鲁棒性能不好。After searching the prior art, in the article "Working Characteristics of Cyclone Gas-Liquid Separator under Different Back Pressures" published in the journal "Nuclear Technology", Li Hua et al. disclosed a degassing system suitable for molten salt reactors. The cyclone gas-liquid separator, the separation condition of the separator is mainly to control the back pressure, and the robust performance is not good.

发明内容SUMMARY OF THE INVENTION

针对现有技术中的缺陷,本发明的目的是提供一种基于流体自振荡和微界面强化的微量气体脱除装置及方法。In view of the defects in the prior art, the purpose of the present invention is to provide a trace gas removal device and method based on fluid self-oscillation and micro-interface enhancement.

本发明的目的是通过以下方案实现的:The purpose of this invention is to realize through the following scheme:

本发明的第一方面提供一种基于流体自振荡和微界面强化的微量气体脱除装置,包括文丘里微气泡生成装置、流体振荡器、反应釜和气液分离装置;所述气液分离装置的底端设有切向底流口,侧面设有切向进口,顶端设有溢流管;所述反应釜的侧面设有切向出口,顶部设有气液混合物进口;所述文丘里微气泡生成装置的底部与熔盐回路连通,顶部与所述流体振荡器的底部连接,所述文丘里微气泡生成装置的中部还设有注气孔;所述流体振荡器的顶部连接至所述反应釜的底端;所述反应釜顶端的气液混合物进口与所述气液分离装置顶端的溢流管连通;所述气液分离装置侧面的切向进口与所述反应釜侧面的切向出口连接;所述气液分离装置底端的切向底流口与熔盐回路连通。A first aspect of the present invention provides a trace gas removal device based on fluid self-oscillation and micro-interface enhancement, including a venturi micro-bubble generating device, a fluid oscillator, a reaction kettle and a gas-liquid separation device; The bottom end is provided with a tangential underflow port, the side is provided with a tangential inlet, and the top is provided with an overflow pipe; the side of the reaction kettle is provided with a tangential outlet, and the top is provided with a gas-liquid mixture inlet; the venturi microbubbles are formed The bottom of the device is connected to the molten salt circuit, the top is connected to the bottom of the fluid oscillator, and the middle of the venturi microbubble generating device is also provided with a gas injection hole; the top of the fluid oscillator is connected to the reactor of the reactor. the bottom end; the gas-liquid mixture inlet at the top of the reaction kettle is communicated with the overflow pipe at the top of the gas-liquid separation device; the tangential inlet on the side of the gas-liquid separation device is connected with the tangential outlet on the side of the reaction kettle; The tangential underflow port at the bottom end of the gas-liquid separation device is communicated with the molten salt circuit.

优选的,所述流体振荡器包括进口渐缩段、扩散腔、导流凸台及出口扩散段,所述文丘里微气泡生成装置的顶部与所述进口渐缩段连接,所述进口渐缩段与所述扩散腔相连,所述导流凸台置于所述扩散腔之中,所述扩散腔与所述出口扩散段相连,所述出口扩散段与所述反应釜的底端连通。Preferably, the fluid oscillator includes an inlet tapered section, a diffusion cavity, a guide boss and an outlet diffusion section, the top of the venturi microbubble generating device is connected to the inlet tapered section, and the inlet is tapered The diffuser section is connected with the diffusion chamber, the guide boss is placed in the diffusion chamber, the diffusion chamber is connected with the outlet diffusion section, and the outlet diffusion section is communicated with the bottom end of the reaction kettle.

优选的,所述反应釜从下至上包括渐扩段和直筒腔,所述直筒腔的侧面设置切向出口,所述直筒腔的顶部设置气液混合物进口;所述渐扩段与所述流体振荡器的出口扩散段连通。Preferably, the reaction kettle includes a gradually expanding section and a straight cylinder cavity from bottom to top, a tangential outlet is set on the side of the straight cylinder cavity, and a gas-liquid mixture inlet is set on the top of the straight cylinder cavity; the expanding section and the fluid The outlet diffuser of the oscillator is connected.

优选的,所述渐扩段与所述出口扩散段的扩散角度一致。Preferably, the diffusion angle of the gradually expanding section is consistent with the diffusion angle of the outlet diffusion section.

优选的,所述气液分离装置为离心式柱状气液分离器,包括自上而下设置的内径为D1的溢流管,长度为L1,内径为D2的大径直筒腔、长度为L2的渐缩腔和长度为L3,直径为D3的小径直筒腔,所述大径直筒腔的侧面设有切向角度为α的切向进口,所述小径直筒腔的底端侧壁设有内径为D4的切向底流口,所述溢流管的一端圆管段部分插入至所述大径直筒腔中,另一端与所述反应釜的所述气液混合物进口连接。Preferably, the gas-liquid separation device is a centrifugal columnar gas-liquid separator, comprising an overflow pipe with an inner diameter of D1 arranged from top to bottom, a length of L1, a large-diameter straight cylindrical cavity with an inner diameter of D2, and a large-diameter cylindrical cavity with a length of L2. The tapered cavity and the small-diameter straight cylindrical cavity with a length of L3 and a diameter of D3, the side of the large-diameter straight cylindrical cavity is provided with a tangential inlet with a tangential angle of α, and the bottom end side wall of the small-diameter straight cylindrical cavity is provided with an inner diameter of α. For the tangential underflow port of D4, one end of the overflow pipe is partially inserted into the large-diameter straight cylindrical cavity, and the other end is connected to the gas-liquid mixture inlet of the reactor.

优选的,所述小径直筒腔内底部设置有顶角角度为β的圆锥形稳流器。Preferably, the inner bottom of the small diameter straight cylinder cavity is provided with a conical flow stabilizer with an apex angle of β.

优选的,所述圆锥形稳流器的顶角角度β为30°。Preferably, the apex angle β of the conical flow stabilizer is 30°.

优选的,所述溢流管的内径D1为40-50mm,所述大径直筒腔长度L1为600mm,内径D2为96-150mm,所述切向进口的切向角度α为24°-30°,所述渐缩腔的长度L2为300-675mm,所述小径直筒腔的长度L3为50-75mm,内径D3为64-100mm,所述切向底流口的内径D4为40-50mm。Preferably, the inner diameter D1 of the overflow pipe is 40-50mm, the length L1 of the large-diameter straight cylinder cavity is 600mm, the inner diameter D2 is 96-150mm, and the tangential angle α of the tangential inlet is 24°-30° , the length L2 of the tapered cavity is 300-675mm, the length L3 of the small diameter straight cylinder cavity is 50-75mm, the inner diameter D3 is 64-100mm, and the inner diameter D4 of the tangential underflow port is 40-50mm.

本发明的第二方面提供一种微量气体脱除方法,采用了上述所述的基于流体自振荡和微界面强化的微量气体脱除装置,具体包括如下步骤:The second aspect of the present invention provides a trace gas removal method, which adopts the above-mentioned trace gas removal device based on fluid self-oscillation and micro-interface enhancement, and specifically includes the following steps:

S1、将载有裂变气体的熔盐通入所述文丘里微气泡生成装置,载气通过文丘里微气泡生成装置的注气孔注入;S1, pass the molten salt carrying the fission gas into the venturi microbubble generating device, and the carrier gas is injected through the gas injection hole of the venturi microbubble generating device;

S2、载有裂变气体的熔盐与载气从所述文丘里微气泡生成装置进入所述流体振荡器的流道,由于附壁效应,会产生振荡射流,实现流体自振荡;S2. The molten salt and carrier gas loaded with fission gas enter the flow channel of the fluid oscillator from the Venturi microbubble generating device, and due to the Coanda effect, an oscillating jet will be generated to realize the fluid self-oscillation;

S3、载有裂变气体的熔盐与载气从所述流体振荡器进入反应釜,在反应釜中,加强流体的搅浑,加快传质效率,使载气充分吸收裂变气体,熔盐形成夹带微气泡的泡状流;S3. The molten salt and the carrier gas carrying the fission gas enter the reaction kettle from the fluid oscillator. In the reaction kettle, the turbidity of the fluid is strengthened to speed up the mass transfer efficiency, so that the carrier gas can fully absorb the fission gas, and the molten salt forms an entrained microbe bubbly flow of bubbles;

S4、熔盐夹带微气泡的泡状流进入离心式柱状气液分离器侧面切向进口后绕腔体形成旋流,由于气液密度差异产生不同的重力与离心力,进而形成气芯,气芯自上部所述溢流管返回所述反应釜,脱除裂变气体后的熔盐自切向底流口返回熔盐回路。S4. The bubbly flow of molten salt entrained with micro-bubbles enters the tangential inlet of the centrifugal columnar gas-liquid separator on the side and then forms a swirling flow around the cavity. Due to the difference in gas-liquid density, different gravity and centrifugal force are generated, thereby forming a gas core. The overflow pipe from the upper part returns to the reaction kettle, and the molten salt after removing the fission gas returns to the molten salt circuit from the tangential bottom flow port.

进一步地,需要脱除的所述裂变气体为氪、氙。Further, the fission gas to be removed is krypton and xenon.

与现有技术相比,本发明具有如下的有益效果:而离心式分离器则不具备这样的缺点,因此考虑利用离心式分离器替代现有的旋流分离技术。Compared with the prior art, the present invention has the following beneficial effects: the centrifugal separator does not have such a disadvantage, so the centrifugal separator is considered to replace the existing cyclone separation technology.

1、本发明的微量气体脱除装置,可以有效脱除熔盐堆熔盐回路中的裂变气体氪、氙等,减少中子损耗,减轻设备维护成本,显著提高熔盐堆经济效益。1. The trace gas removal device of the present invention can effectively remove the fission gas krypton, xenon, etc. in the molten salt circuit of the molten salt reactor, reduce neutron loss, reduce equipment maintenance costs, and significantly improve the economic benefits of the molten salt reactor.

2、本发明的微量气体脱除装置,采用流体振荡器与反应釜相结合的方式进行传质,由于流体的自振荡,无需利用搅拌器即可使流体充分搅浑,加强传质的效率。2. The trace gas removal device of the present invention adopts the combination of a fluid oscillator and a reaction kettle for mass transfer. Due to the self-oscillation of the fluid, the fluid can be fully turbid without using a stirrer, thereby enhancing the mass transfer efficiency.

3、本发明的微量气体脱除装置,采用离心式柱状气液分离器,改变了传统的旋流式分离器分离条件苛刻,对背压要求高的缺点,具有很好的鲁棒性能。3. The trace gas removal device of the present invention adopts a centrifugal columnar gas-liquid separator, which changes the shortcomings of the traditional cyclone separator, which has harsh separation conditions and high requirements for back pressure, and has good robust performance.

4、本发明的微量气体脱除装置,采用传质装置与分离器集成式设计,大大减少了设备占地面积,为熔盐堆的小型模块化设计提供可能性。4. The trace gas removal device of the present invention adopts the integrated design of the mass transfer device and the separator, which greatly reduces the floor space of the equipment and provides the possibility for the small modular design of the molten salt reactor.

附图说明Description of drawings

通过阅读参照以下附图对非限制性实施例所作的详细描述,本发明的其它特征、目的和优点将会变得更明显:Other features, objects and advantages of the present invention will become more apparent by reading the detailed description of non-limiting embodiments with reference to the following drawings:

图1为本发明的微量气体脱除装置的立体图;1 is a perspective view of a trace gas removal device of the present invention;

图2为本发明的微量气体脱除装置的结构简图;Fig. 2 is a schematic diagram of the structure of the trace gas removal device of the present invention;

图3为本发明的微量气体脱除装置中文丘里微气泡生成装置的立体图;Fig. 3 is the perspective view of the micro-bubble generation device of Chinese Churi micro-bubble generation device of the trace gas removal device of the present invention;

图4为本发明的微量气体脱除装置中文丘里微气泡生成装置的透视图;Fig. 4 is the perspective view of the micro-bubble generation device of Chinese Churi micro-bubble of the trace gas removal device of the present invention;

图5为本发明的微量气体脱除装置中流体振荡器的立体图;5 is a perspective view of a fluid oscillator in the trace gas removal device of the present invention;

图6为图5的主视图;Fig. 6 is the front view of Fig. 5;

图7为本发明的微量气体脱除装置中反应釜的主视图;Fig. 7 is the front view of the reactor in the trace gas removal device of the present invention;

图8为本发明的微量气体脱除装置中反应釜的立体图;Fig. 8 is the perspective view of the reactor in the trace gas removal device of the present invention;

图9为本发明的微量气体脱除装置中离心式柱状气液分离器的结构示意图;9 is a schematic structural diagram of a centrifugal columnar gas-liquid separator in the trace gas removal device of the present invention;

具体实施方式Detailed ways

下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明,但不以任何形式限制本发明。应当指出的是,对本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变化和改进。这些都属于本发明的保护范围。The present invention will be described in detail below with reference to specific embodiments. The following examples will help those skilled in the art to further understand the present invention, but do not limit the present invention in any form. It should be noted that, for those skilled in the art, several changes and improvements can be made without departing from the inventive concept. These all belong to the protection scope of the present invention.

熔盐堆在运行过程中,会产生大量如氙和氪等气体中子毒物,危害反应堆的安全及效率,因此对裂变气体产物进行在线分离十分必要。鉴于熔盐堆液态熔盐介质粘度高、一回路中气泡微小等特点,设计了包含文丘里微气泡生成装置、流体振荡器、反应釜及离心式柱状气液分离器在内的一回路在线除气装置。夹带微小气泡的熔盐进入整体装置,经文丘里微气泡生成装置、流体振荡器与反应釜将裂变气体吸附在载气上,通过离心式柱状气液分离器的入口段后在其管柱内形成旋流,在筒体中心形成低压区,使得气泡向中心聚拢,并由上端溢流口引出分离器,沿筒体壁面的熔盐从分离器底流口引出回到熔盐回路,完成气液分离。During the operation of the molten salt reactor, a large amount of gaseous neutron poisons such as xenon and krypton will be produced, which will endanger the safety and efficiency of the reactor. Therefore, it is necessary to separate the fission gas products online. In view of the high viscosity of liquid molten salt medium of molten salt reactor and the tiny bubbles in the primary circuit, an online primary circuit removal device including a venturi microbubble generator, fluid oscillator, reactor and centrifugal columnar gas-liquid separator is designed. gas device. The molten salt entrained with micro-bubbles enters the overall device. The Venturi micro-bubble generating device, fluid oscillator and reaction kettle adsorb the fission gas on the carrier gas, and pass through the inlet section of the centrifugal columnar gas-liquid separator in its column. A swirling flow is formed, a low pressure area is formed in the center of the cylinder, so that the bubbles gather to the center, and are led out of the separator from the upper overflow port, and the molten salt along the wall of the cylinder is led out from the bottom flow port of the separator and returned to the molten salt circuit to complete the gas-liquid separation.

如图1至图9所示,接下来结合具体实施例对本发明做进一步详细的描述。As shown in FIG. 1 to FIG. 9 , the present invention will be further described in detail below with reference to specific embodiments.

实施例1Example 1

一种基于流体自振荡和微界面强化的微量气体脱除装置,包括文丘里微气泡生成装置1、流体振荡器2、反应釜3和气液分离装置4;所述气液分离装置4的底端设有切向底流口41,侧面设有切向进口42,切向进口有利于流体沿壁面流动形成旋流,顶端设有溢流管43;所述反应釜3的侧面设有切向出口31,顶部设有气液混合物进口32;所述文丘里微气泡生成装置1的底部与熔盐回路连通,顶部与所述流体振荡器2的底部连接,所述文丘里微气泡生成装置1的中部还设有注气孔11;所述流体振荡器2的顶部连接至所述反应釜3的底端;所述反应釜3顶端的气液混合物进口32与所述气液分离装置4顶端的溢流管43连通;所述气液分离装置4侧面的切向进口42与所述反应釜3侧面的切向出口31连接;所述气液分离装置4底端的切向底流口41与熔盐回路连通。A trace gas removal device based on fluid self-oscillation and micro-interface strengthening, comprising a venturi micro-bubble generating device 1, a fluid oscillator 2, a reactor 3 and a gas-liquid separation device 4; the bottom end of the gas-liquid separation device 4 A tangential bottom flow port 41 is provided, and a tangential inlet 42 is provided on the side. The tangential inlet is conducive to the flow of fluid along the wall to form a swirl, and the top is provided with an overflow pipe 43; the side of the reaction kettle 3 is provided with a tangential outlet 31 , the top is provided with a gas-liquid mixture inlet 32; the bottom of the venturi microbubble generating device 1 is connected with the molten salt circuit, the top is connected with the bottom of the fluid oscillator 2, and the middle of the venturi microbubble generating device 1 There is also a gas injection hole 11; the top of the fluid oscillator 2 is connected to the bottom end of the reactor 3; the gas-liquid mixture inlet 32 at the top of the reactor 3 and the overflow at the top of the gas-liquid separation device 4 The pipe 43 is connected; the tangential inlet 42 on the side of the gas-liquid separation device 4 is connected with the tangential outlet 31 on the side of the reaction kettle 3; the tangential bottom flow port 41 at the bottom end of the gas-liquid separation device 4 is communicated with the molten salt circuit .

文丘里微气泡生成装置1、流体振荡器2、反应釜3和气液分离装置4的具体结构如下:The specific structures of the venturi microbubble generating device 1, the fluid oscillator 2, the reaction kettle 3 and the gas-liquid separation device 4 are as follows:

所述文丘里微气泡生成装置1从下至上包括:进口直管段12、收缩段13、圆柱形喉部14、扩张段15、出口直管段16以及喉部的注气孔11六个部分,注气孔11与外部气源联通引入氮气作为载气进入文丘里管。优选的,在所述文丘里管前安装溶氧探测器,用于探测氧气浓度。The venturi microbubble generating device 1 includes from bottom to top: an inlet straight pipe section 12, a constricted section 13, a cylindrical throat 14, an expansion section 15, an outlet straight pipe section 16 and six parts of the gas injection hole 11 in the throat, the gas injection hole 11 Connect with an external gas source and introduce nitrogen as a carrier gas into the Venturi tube. Preferably, a dissolved oxygen detector is installed in front of the venturi tube for detecting the oxygen concentration.

所述流体振荡器2包括进口渐缩段21、扩散腔22、导流凸台23及出口扩散段24,所述文丘里微气泡生成装置1的顶部与所述进口渐缩段21连接,所述进口渐缩段21与所述扩散腔22相连,所述导流凸台23置于所述扩散腔22之中,所述扩散腔22与所述出口扩散段24相连,所述出口扩散段24与所述反应釜3的底端连通。The fluid oscillator 2 includes an inlet tapered section 21, a diffusion cavity 22, a guide boss 23 and an outlet diffusion section 24. The top of the venturi microbubble generating device 1 is connected to the inlet tapered section 21, so The inlet tapered section 21 is connected to the diffusion cavity 22, the guide boss 23 is placed in the diffusion cavity 22, the diffusion cavity 22 is connected to the outlet diffusion section 24, and the outlet diffusion section 24 communicates with the bottom end of the reactor 3 .

所述反应釜3从下至上包括渐扩段33和直筒腔34,所述直筒腔34的侧面设置切向出口31,所述直筒腔34的顶部设置气液混合物进口32;所述渐扩段33与所述流体振荡器2的出口扩散段24连通。The reaction kettle 3 includes a gradually expanding section 33 and a straight cylinder cavity 34 from bottom to top, a tangential outlet 31 is set on the side of the straight cylinder cavity 34, and a gas-liquid mixture inlet 32 is set on the top of the straight cylinder cavity 34; 33 communicates with the outlet diffusion section 24 of the fluid oscillator 2 .

所述气液分离装置4为离心式柱状气液分离器,包括自上而下设置的内径为D1的溢流管43,长度为L1,内径为D2的大径直筒腔44、长度为L2的渐缩腔45和长度为L3,直径为D3的小径直筒腔46,所述大径直筒腔44的侧面设有切向角度为α的切向进口42,所述小径直筒腔46的底端侧壁设有内径为D4的切向底流口41,所述溢流管43的一端圆管段部分插入至所述大径直筒腔44中,另一端与所述反应釜3的所述气液混合物进口32连接。其中,所述溢流管43的内径D1为50mm,所述大径直筒腔44长度L1为600mm,内径D2为150mm,所述切向进口42的切向角度α为27°,设置一个切向角度能更好地形成旋流,加强分离效果,所述渐缩腔45的长度L2为675mm,所述小径直筒腔46的长度L3为75mm,内径D3为100mm,所述切向底流口41的内径D4为50mm。The gas-liquid separation device 4 is a centrifugal columnar gas-liquid separator, including an overflow pipe 43 with an inner diameter of D1 arranged from top to bottom, a length of L1, a large-diameter straight cylindrical cavity 44 with an inner diameter of D2, and a large-diameter cylindrical cavity 44 with an inner diameter of D2. The tapered cavity 45 and the small diameter straight cylindrical cavity 46 with a length of L3 and a diameter of D3, the side of the large diameter straight cylindrical cavity 44 is provided with a tangential inlet 42 with a tangential angle α, and the bottom end side of the small diameter straight cylindrical cavity 46 The wall is provided with a tangential underflow port 41 with an inner diameter of D4, one end of the overflow pipe 43 is partially inserted into the large-diameter straight cylindrical cavity 44, and the other end is connected to the gas-liquid mixture inlet of the reactor 3. 32 connections. Wherein, the inner diameter D1 of the overflow pipe 43 is 50mm, the length L1 of the large-diameter straight cylindrical cavity 44 is 600mm, the inner diameter D2 is 150mm, the tangential angle α of the tangential inlet 42 is 27°, and a tangential direction is provided. The angle can better form a swirl flow and enhance the separation effect. The length L2 of the tapered cavity 45 is 675mm, the length L3 of the small diameter straight cylinder cavity 46 is 75mm, and the inner diameter D3 is 100mm. The inner diameter D4 is 50mm.

实施例2Example 2

实施例2是实施例1的优选例。Embodiment 2 is a preferred example of Embodiment 1.

在实施例2中,所述渐扩段33与所述出口扩散段24的扩散角度一致,所述小径直筒腔46内底部设置有顶角角度β=30°的圆锥形稳流器47,稳流器可以使气液分离装置内更好地形成气芯。其他与实施例1中的结构相同。In Embodiment 2, the diffusion angles of the gradually expanding section 33 and the outlet diffusion section 24 are the same, and the inner bottom of the small diameter straight cylindrical cavity 46 is provided with a conical flow stabilizer 47 with an apex angle β=30° to stabilize The flow device can better form the gas core in the gas-liquid separation device. Others are the same as those in Embodiment 1.

实施例3Example 3

实施例3是实施例1或实施例2的应用例。Embodiment 3 is an application example of Embodiment 1 or Embodiment 2.

采用上述所述基于流体自振荡和微界面强化的微量气体脱除装置来脱除微量气体方法,具体包括如下步骤:The method for removing trace gas using the above-mentioned trace gas removal device based on fluid self-oscillation and micro-interface enhancement specifically includes the following steps:

S1、将载有裂变气体的熔盐通入所述文丘里微气泡生成装置1,载气通过循环泵由文丘里微气泡生成装置的注气孔11注入;需要脱除的所述裂变气体为氪、氙。S1, pass the molten salt loaded with fission gas into the venturi microbubble generating device 1, and the carrier gas is injected by the gas injection hole 11 of the venturi microbubble generating device through a circulating pump; the fission gas that needs to be removed is krypton ,xenon.

S2、载有裂变气体的熔盐与载气从所述文丘里微气泡生成装置1进入所述流体振荡器2的流道,由于附壁效应,会产生振荡射流,实现流体自振荡;S2, the molten salt and carrier gas carrying the fission gas enter the flow channel of the fluid oscillator 2 from the venturi microbubble generating device 1, and due to the Coanda effect, an oscillating jet will be generated to realize the fluid self-oscillation;

S3、载有裂变气体的熔盐与载气从所述流体振荡器2进入反应釜3,在反应釜3中,加强流体的搅浑,加快传质效率,使载气充分吸收裂变气体,熔盐形成夹带微气泡的泡状流;S3, the molten salt and the carrier gas carrying the fission gas enter the reactor 3 from the fluid oscillator 2. In the reactor 3, the fluid is turbid and the mass transfer efficiency is accelerated, so that the carrier gas can fully absorb the fission gas and the molten salt Formation of a bubbly flow with entrained microbubbles;

S4、熔盐夹带微气泡的泡状流进入离心式柱状气液分离器侧面切向进口后绕腔体形成旋流,由于气液密度差异产生不同的重力与离心力,进而形成气芯,气芯自上部所述溢流管43返回所述反应釜2,脱除裂变气体后的熔盐自切向底流口41返回熔盐回路。S4. The bubbly flow of molten salt entrained with micro-bubbles enters the tangential inlet of the centrifugal columnar gas-liquid separator on the side and then forms a swirling flow around the cavity. Due to the difference in gas-liquid density, different gravity and centrifugal force are generated, thereby forming a gas core. Return to the reaction kettle 2 from the overflow pipe 43 at the upper part, and the molten salt after removing the fission gas returns to the molten salt circuit from the tangential bottom flow port 41 .

为测试回路运行,验证分离效果,设计进行如下实验:In order to test the operation of the loop and verify the separation effect, the following experiments are designed:

具体地,将要脱除的气体裂变产物替换为氧气,将熔盐堆中载气氩气替换为氮气。所述氧气由刃天青试剂进行染色后,再由所述高速摄像机进行拍摄分析,便于观察氧气分布情况。氧浓度由所述溶氧探测器探测后,通过对比流体经振荡器、反应釜及分离装置前后的氧气浓度变化确定气体脱除效率。Specifically, the gas fission products to be removed are replaced with oxygen, and the carrier gas argon in the molten salt reactor is replaced with nitrogen. After the oxygen is dyed with the resazurin reagent, it is photographed and analyzed by the high-speed camera, so as to facilitate the observation of the oxygen distribution. After the oxygen concentration is detected by the dissolved oxygen detector, the gas removal efficiency is determined by comparing the change of the oxygen concentration before and after the fluid passes through the oscillator, the reactor and the separation device.

具体地,载有“裂变气体”氧气的蒸馏水与载气氮气通过流体振荡器流道时由于附壁效应,会产生振荡射流,并且在通过反应釜时加强流体的搅浑,加快传质效率,使氮气载气充分吸收氧气。Specifically, the oscillating jet will be generated due to the Coanda effect when the distilled water and the carrier gas nitrogen carrying "fission gas" oxygen pass through the flow channel of the fluid oscillator, and the turbidity of the fluid will be strengthened when passing through the reactor, and the mass transfer efficiency will be accelerated. Nitrogen carrier gas fully absorbs oxygen.

具体地,蒸馏水夹带微气泡的泡状流进入离心式柱状气液分离器侧面切向进口后绕腔体形成旋流,由于气液密度差异产生不同的重力与离心力,进而形成气芯,气芯自上部溢流口返回反应釜,脱除气体后的蒸馏水自底流口返回循环泵形成回路循环。Specifically, the bubble-like flow of distilled water entrained with micro-bubbles enters the tangential inlet on the side of the centrifugal columnar gas-liquid separator and then forms a swirling flow around the cavity. Different gravitational and centrifugal forces are generated due to the difference in gas-liquid density, thereby forming a gas core. Return to the reactor from the upper overflow port, and the distilled water after degassing returns to the circulation pump from the bottom flow port to form a loop circulation.

在本申请的描述中,需要理解的是,术语“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。In the description of this application, it should be understood that the terms "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", The orientation or positional relationship indicated by "bottom", "inner", "outer", etc. is based on the orientation or positional relationship shown in the accompanying drawings, which is only for the convenience of describing the present application and simplifying the description, rather than indicating or implying the indicated device. Or elements must have a particular orientation, be constructed and operate in a particular orientation, and therefore should not be construed as a limitation of the present application.

以上对本发明的具体实施例进行了描述。需要理解的是,本发明并不局限于上述特定实施方式,本领域技术人员可以在权利要求的范围内做出各种变化或修改,这并不影响本发明的实质内容。在不冲突的情况下,本申请的实施例和实施例中的特征可以任意相互组合。Specific embodiments of the present invention have been described above. It should be understood that the present invention is not limited to the above-mentioned specific embodiments, and those skilled in the art can make various changes or modifications within the scope of the claims, which do not affect the essential content of the present invention. The embodiments of the present application and features in the embodiments may be arbitrarily combined with each other without conflict.

Claims (10)

1. A micro gas removing device based on fluid self-oscillation and micro-interface strengthening is characterized by comprising a Venturi micro-bubble generating device (1), a fluid oscillator (2), a reaction kettle (3) and a gas-liquid separating device (4);
the bottom end of the gas-liquid separation device (4) is provided with a tangential underflow port (41), the side surface is provided with a tangential inlet (42), and the top end is provided with an overflow pipe (43);
a tangential outlet (31) is arranged on the side surface of the reaction kettle (3), and a gas-liquid mixture inlet (32) is arranged at the top of the reaction kettle;
the bottom of the Venturi microbubble generation device (1) is communicated with the molten salt loop, the top of the Venturi microbubble generation device is connected with the bottom of the fluid oscillator (2), and the middle of the Venturi microbubble generation device (1) is also provided with a gas injection hole (11);
the top of the fluid oscillator (2) is connected to the bottom end of the reaction kettle (3); a gas-liquid mixture inlet (32) at the top end of the reaction kettle (3) is communicated with an overflow pipe (43) at the top end of the gas-liquid separation device (4); a tangential inlet (42) on the side surface of the gas-liquid separation device (4) is connected with a tangential outlet (31) on the side surface of the reaction kettle (3); and a tangential underflow port (41) at the bottom end of the gas-liquid separation device (4) is communicated with the molten salt loop.
2. The micro-gas removal device based on fluid self-oscillation and micro-interface strengthening as claimed in claim 1, wherein the fluid oscillator (2) comprises an inlet tapered section (21), a diffusion cavity (22), a flow guiding boss (23) and an outlet diffusion section (24), the top of the venturi micro-bubble generation device (1) is connected to the inlet tapered section (21), the inlet tapered section (21) is connected to the diffusion cavity (22), the flow guiding boss (23) is disposed in the diffusion cavity (22), the diffusion cavity (22) is connected to the outlet diffusion section (24), and the outlet diffusion section (24) is communicated to the bottom end of the reaction kettle (3).
3. The micro-gas removal device based on fluid self-oscillation and micro-interface strengthening as claimed in claim 1 or 2, wherein the reaction kettle (3) comprises a divergent section (33) and a straight cylindrical cavity (34) from bottom to top, a tangential outlet (31) is arranged on the side surface of the straight cylindrical cavity (34), and a gas-liquid mixture inlet (32) is arranged on the top of the straight cylindrical cavity (34); the divergent section (33) communicates with an outlet divergent section (24) of the fluidic oscillator (2).
4. The micro gas removal device based on self-oscillation of fluid and micro interface strengthening according to claim 3, wherein the divergent section (33) is in accordance with the diffusion angle of the outlet divergent section (24).
5. The micro-gas removal device based on fluid self-oscillation and micro-interface strengthening according to claim 1, wherein the gas-liquid separation device (4) is a centrifugal cylindrical gas-liquid separator, and comprises an overflow pipe (43) with an inner diameter of D1, a large-diameter straight cylindrical cavity (44) with a length of L1 and an inner diameter of D2, a tapered cavity (45) with a length of L2 and a small-diameter straight cylindrical cavity (46) with a length of L3 and a diameter of D3, which are arranged from top to bottom, the side surface of the large-diameter straight cylindrical cavity (44) is provided with a tangential inlet (42) with a tangential angle of alpha, the bottom end side wall of the small-diameter straight cylindrical cavity (46) is provided with a tangential underflow port (41) with an inner diameter of D4, one end of a circular pipe section of the overflow pipe (43) is partially inserted into the large-diameter straight cylindrical cavity (44), and the other end of the overflow pipe is connected with the inlet (32) of the gas-.
6. The micro-gas removal device based on self-oscillation of fluid and micro-interface strengthening according to claim 5, characterized in that the bottom of the small diameter straight cylinder cavity (46) is provided with a conical flow stabilizer (47) with a vertex angle β.
7. Micro gas removal device based on fluidic self-oscillation and micro-interface strengthening according to claim 6, characterized in that the conical flow stabilizer (47) has a vertex angle β of 30 °.
8. The micro-gas removal device based on fluid self-oscillation and micro-interface intensification as claimed in claim 5, wherein the inner diameter D1 of the overflow pipe (43) is 40-50mm, the length L1 of the large-diameter straight cylinder cavity (44) is 600mm, the inner diameter D2 is 96-150mm, the tangential angle α of the tangential inlet (42) is 24-30 °, the length L2 of the tapered cavity (45) is 300-675mm, the length L3 of the small-diameter straight cylinder cavity (46) is 50-75mm, the inner diameter D3 is 64-100mm, and the inner diameter D4 of the tangential underflow port (41) is 40-50 mm.
9. A trace gas removal method, which is characterized by adopting the trace gas removal device based on fluid self-oscillation and micro-interface strengthening as claimed in any one of claims 1 to 8, and comprises the following steps:
s1, introducing the molten salt carrying the fission gas into the Venturi microbubble generation device (1), and injecting the carrier gas through a gas injection hole (11) of the Venturi microbubble generation device;
s2, enabling molten salt carrying fission gas and carrier gas to enter a flow channel of the fluid oscillator (2) from the Venturi microbubble generation device (1), and generating oscillation jet flow due to the wall attachment effect to realize self oscillation of the fluid;
s3, enabling the molten salt carrying the fission gas and the carrier gas to enter a reaction kettle (3) from the fluid oscillator (2), and in the reaction kettle (3), enhancing the turbidness of the fluid to enable the carrier gas to fully absorb the fission gas, so that the molten salt forms bubble-shaped flow carrying micro bubbles;
s4, enabling the bubbly flow of the molten salt carrying the micro bubbles to enter a tangential inlet on the side face of the centrifugal columnar gas-liquid separator and then form a rotational flow around the cavity, generating different gravity and centrifugal force due to gas-liquid density difference, further forming a gas core, returning the gas core to the reaction kettle (3) from the upper part of the overflow pipe (43), and returning the molten salt subjected to fission gas removal to a molten salt loop from the tangential underflow port (41).
10. A trace gas removal method as claimed in claim 9, wherein said fission gas to be removed is krypton or xenon.
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