CN111574796A - Novel material capable of being dissolved after damp-heat sterilization for protective clothing and preparation method - Google Patents
Novel material capable of being dissolved after damp-heat sterilization for protective clothing and preparation method Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/26—Cellulose ethers
- C08J2401/28—Alkyl ethers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
- C08J2403/12—Amylose; Amylopectin; Degradation products thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2429/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2429/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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Abstract
The invention relates to a novel material capable of being dissolved after moist heat sterilization for protective clothing and a preparation method thereof, wherein the novel material is prepared from the following components in parts by weight: 5-20 parts of amylose, 1-10 parts of carboxymethyl cellulose, 5-30 parts of glycerol, 10-70 parts of modified polyvinyl alcohol, 0.1-2 parts of diethylene glycol, 1-6 parts of dioleate, 0.1-2 parts of stearic acid, 0.1-1.5 parts of sodium benzoate, 0.1-5 parts of benzamide and 15-17 parts of water, wherein the preparation method comprises the three steps of material mixing, extrusion granulation and film blowing; the raw materials are natural, the method is simple, and the prepared product has good barrier property and high-temperature water solubility, is low in cost, and is energy-saving and environment-friendly; the membrane prepared by the method can be made into protective clothing, disposable gloves, foot covers, head covers and other medical supplies, has damp-heat sterilization performance, can be dissolved in water with the temperature of 95-100 ℃ to destroy the supplies, and can kill viruses at the same time, thereby effectively blocking the secondary transmission and secondary pollution of the polluted protective supplies.
Description
Technical Field
The invention relates to a novel material for protective clothing and a preparation method thereof, in particular to a novel material for protective clothing capable of being dissolved after moist heat sterilization and a preparation method thereof, and belongs to the technical field of material processing.
Background
The medical protective clothing is used for reducing the invasion of infectious substances such as viruses to medical workers in a working environment. Research on medical protective clothing has been developed in the developed countries, and the research on medical protective clothing in the united states is always at an advanced level in the world. In the period of second war, the army uses the superfine bimatous mercerized cotton to make the protective clothing with stronger water-proof performance, and after the second war is finished, it is used in the medical operation. 4 film materials of heterogeneous membrane, asymmetric membrane, homogeneous membrane and composite membrane and Gore fabric composite material developed in the United states in the 80 s of the 20 th century have good virus transmission resistance and good air permeability.
The medical protective clothing in China is valued and developed after the SARS virus Mat volume in 2003 in the whole country. Aiming at SARS infectious virus, the materials for manufacturing protective clothing in China are mainly common non-woven fabrics or rubber, etc., wherein the common non-woven fabrics have poor protective performance and can not reach the national protective standard; although the rubber has good protective performance, the air permeability is poor, and the rubber cannot be applied to medical working environments. After the combined efforts of science and technology workers, polypropylene spun-bond and melt-blown spun-bond composite material (SMS) non-woven fabric is developed, the SMS material not only has good antibacterial property and air permeability, but also can resist high hydrostatic pressure, and can adapt to various different environmental conditions through the technical treatment of the SMS material such as antibacterial, anti-aging, antistatic and the like, and high-grade surgical gowns made of the SMS non-woven fabric are widely applied at home and abroad; however, in the region with extremely strong infectivity, the SMS protection efficiency still can not meet the requirements, and further research is needed. Later, relevant scholars in China prepare the nylon-6/TiO 2 composite superfine fiber non-woven fabric by using an electrostatic filament device, and the antibacterial performance and the ultraviolet resistance of the protective clothing can be improved by applying the non-woven fabric to medical protective clothing. An antibacterial agent made of a chloramine compound has also been proposed as a protective layer of a protective mask to improve the bactericidal performance of the protective mask.
In 2019 to 2020, the novel coronavirus is rolled up around the world, relates to more than two hundred countries, has more infected people and wide range, is rare in human history, and has great influence on the health and economy of the global people. Medical protective articles become scarce materials, and medical protective clothing has important meaning in the aspect of infectious disease protection, especially for medical personnel, the material of protective clothing is vital, and medical personnel can be protected well in a special period, so that medical personnel are prevented from being infected in a large quantity, and the medical protective clothing has important meaning for prevention and control of epidemic situations.
At present, the protective clothing takes the renewal of materials as a core and develops to the aspects of high performance, multifunction, composite, health, comfort and the like. With the environmental requirements, the degradability is also an important aspect of research.
Disclosure of Invention
Aiming at the problems in the prior art, the invention provides a novel material for protective clothing capable of being dissolved after moist heat sterilization and a preparation method thereof, the raw materials are natural, the method is simple, and the prepared product has good barrier property, high-temperature water solubility, low cost, energy conservation and environmental protection. The film prepared by the method can be made into protective clothing, disposable gloves, foot covers, head covers and other medical supplies, has the damp-heat sterilization performance, can destroy the supplies after the damp-heat sterilization, and effectively prevents the secondary propagation and the secondary pollution of the contaminated protective supplies.
In order to achieve the purpose, the invention adopts the technical scheme that:
a novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
5-20 parts of amylose with the linear chain ratio of more than 50%, 1-10 parts of carboxymethyl cellulose, 5-30 parts of glycerol, 10-70 parts of modified polyvinyl alcohol, 0.1-2 parts of diethylene glycol, 1-6 parts of dioleate, 0.1-2 parts of stearic acid, 0.1-1.5 parts of sodium benzoate, 0.1-5 parts of benzamide and 15-17 parts of water;
the modified polyvinyl alcohol is modified by mixing 1-20 parts of polyvinyl alcohol 1799 and 1-10 parts of polyvinyl alcohol 2099.
Another object of the present invention is to provide a method for preparing a novel material for protective clothing which can be dissolved after moist heat sterilization, comprising the steps of:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 50-85 ℃ by a high-speed mixer, and mixing;
(2) extruding: adding the mixed material into an extruder through a feeding machine, and extruding and granulating by adopting a double-screw extruder with the length-diameter ratio of 48: 1;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a novel material with the film thickness of 15 +/-2-25 +/-3 mu m;
the rotating speed of the feeding machine in the step (2) is 10-30r/min, the rotating speed of a screw of an extruder is 50-100r/min, and the working temperature of the extruder is 85-190 ℃;
the working temperature of the single-screw extruder in the step (3) is 120-195 ℃, the blowing ratio of the film blowing machine is 1:4-8, and the drawing speed is 2 +/-0.4 m/min.
The invention has the beneficial effects that:
(1) the raw materials are natural, the method is simple, and the prepared product has good barrier property, high-temperature water solubility, low cost, energy conservation and environmental protection;
(2) the film prepared by the method can be made into protective clothing, disposable gloves, foot covers, head covers and other medical supplies, has the damp-heat sterilization performance, can destroy the supplies after the damp-heat sterilization, and effectively prevents the secondary propagation and secondary pollution of the contaminated protective supplies;
(3) the protective product made of the prepared film can be dissolved in water with the temperature of 95-120 ℃ and can kill viruses at the same time.
Detailed Description
The present invention is further illustrated in detail by the following examples, which are provided only for illustrating the present invention and are not intended to limit the scope of the present invention.
Example 1
A novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
5 parts of amylose with the linear chain ratio of more than 50 percent, 1 part of carboxymethyl cellulose, 5 parts of glycerol, 10 parts of modified polyvinyl alcohol, 0.1 part of diethylene glycol, 1 part of dioleate, 0.1 part of stearic acid, 0.1 part of sodium benzoate, 0.1 part of benzamide and 15 parts of water;
a preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization comprises the following steps:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 50 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material prepared in the step (1) into an extruder with the length-diameter ratio of 48:1 through a feeder, and carrying out extrusion granulation, wherein the rotating speed of the feeder is 10r/min, the rotating speed of a screw of the extruder is 50r/min, and the working temperature of the extruder is 110 ℃;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a film with the thickness of 15 +/-2 mu m; wherein the working temperature of the single screw extruder is 120 ℃, the blowing ratio of the film blowing machine is 1:8, and the drawing speed is 2 +/-0.4 m/min.
Example 2
A novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
10 parts of amylose with the straight chain ratio of more than 50%, 10 parts of carboxymethyl cellulose, 30 parts of glycerol, 70 parts of modified polyvinyl alcohol, 2 parts of diethylene glycol, 6 parts of dioleate, 2 parts of stearic acid, 1.5 parts of sodium benzoate, 5 parts of benzamide and 17 parts of water;
a preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization comprises the following steps:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 85 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material prepared in the step (1) into an extruder with the length-diameter ratio of 48:1 through a feeder, and carrying out extrusion granulation, wherein the rotating speed of the feeder is 30r/min, the rotating speed of a screw of the extruder is 100r/min, and the working temperature of the extruder is 85 ℃;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a film with the thickness of 25 +/-3 mu m; wherein the working temperature of the single screw extruder is 180 ℃, the blowing ratio of the film blowing machine is 1:4, and the drawing speed is 2 +/-0.4 m/min.
Example 3
A novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
15 parts of amylose with the linear chain ratio of more than 50 percent, 5 parts of carboxymethyl cellulose, 15 parts of glycerol, 40 parts of modified polyvinyl alcohol, 1 part of diethylene glycol, 3 parts of dioleate, 1 part of stearic acid, 0.8 part of sodium benzoate, 2.5 parts of benzamide and 16 parts of water;
a preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization comprises the following steps:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 65 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material prepared in the step (1) into an extruder with the length-diameter ratio of 48:1 through a feeder, and carrying out extrusion granulation, wherein the rotating speed of the feeder is 20r/min, the rotating speed of a screw of the extruder is 80r/min, and the working temperature of the extruder is 100 ℃;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a film with the thickness of 20 +/-3 mu m; wherein the working temperature of the single screw extruder is 180 ℃, the blowing-up ratio of the film blowing machine is 1:6, and the drawing speed is 2 +/-0.4 m/min.
Example 4
A novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
20 parts of amylose with the linear chain ratio of more than 50%, 2 parts of carboxymethyl cellulose, 6 parts of glycerol, 15 parts of modified polyvinyl alcohol, 0.5 part of diethylene glycol, 2 parts of dioleate, 0.5 part of stearic acid, 0.5 part of sodium benzoate, 0.5 part of benzamide and 15 parts of water;
a preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization comprises the following steps:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 55 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material prepared in the step (1) into an extruder with the length-diameter ratio of 48:1 through a feeder, and carrying out extrusion granulation, wherein the rotating speed of the feeder is 15r/min, the rotating speed of a screw of the extruder is 90r/min, and the working temperature of the extruder is 190 ℃;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a film with the thickness of 15 +/-2 mu m; wherein the working temperature of the single screw extruder is 180 ℃, the blowing ratio of the film blowing machine is 1:5, and the drawing speed is 2 +/-0.4 m/min.
Example 5
A novel material capable of being dissolved after moist heat sterilization for protective clothing is prepared from the following components in parts by weight:
5 parts of amylose with the straight chain ratio of more than 50 percent, 8 parts of carboxymethyl cellulose, 25 parts of glycerol, 60 parts of modified polyvinyl alcohol, 1.8 parts of diethylene glycol, 5 parts of dioleate, 1.5 parts of stearic acid, 1.2 parts of sodium benzoate, 4 parts of benzamide and 17 parts of water;
a preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization comprises the following steps:
(1) mixing materials: heating amylose, carboxymethyl cellulose, glycerol, modified polyvinyl alcohol, diethylene glycol, dioleate, stearic acid, sodium benzoate, benzamide and water to 80 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material prepared in the step (1) into an extruder with the length-diameter ratio of 48:1 through a feeder, and carrying out extrusion granulation, wherein the rotating speed of the feeder is 25r/min, the rotating speed of a screw of the extruder is 60r/min, and the working temperature of the extruder is 150 ℃;
(3) film blowing: blowing a film on the particles obtained in the step (2) by using a single-screw extruder with the length-diameter ratio of 36:1 to obtain a film with the thickness of 15 +/-2 mu m; wherein the working temperature of the single screw extruder is 195 ℃, the blowing-up ratio of the film blowing machine is 1:8, and the drawing speed is 2 +/-0.4 m/min.
Claims (8)
1. A novel material of protective clothing capable of being dissolved after moist heat sterilization is characterized in that: the composition is prepared from the following components in parts by weight:
5-20 parts of amylose with the linear chain ratio of more than 50%, 1-10 parts of carboxymethyl cellulose, 5-30 parts of glycerol, 10-70 parts of modified polyvinyl alcohol, 0.1-2 parts of diethylene glycol, 1-6 parts of dioleate, 0.1-2 parts of stearic acid, 0.1-1.5 parts of sodium benzoate, 0.1-5 parts of benzamide and 15-17 parts of water.
2. The novel material for protective clothing capable of dissolving after moist heat sterilization as claimed in claim 1, wherein: the modified polyvinyl alcohol is modified by mixing 1-20 parts of polyvinyl alcohol 1799 and 1-10 parts of polyvinyl alcohol 2099.
3. A preparation method of a novel material of protective clothing capable of being dissolved after moist heat sterilization is characterized in that: the method comprises the following steps:
(1) mixing materials: heating 5-20 parts of amylose, 1-10 parts of carboxymethyl cellulose, 5-30 parts of glycerol, 10-70 parts of modified polyvinyl alcohol, 0.1-2 parts of diethylene glycol, 1-6 parts of dioleate, 0.1-2 parts of stearic acid, 0.1-1.5 parts of sodium benzoate, 0.1-5 parts of benzamide and 15-17 parts of water to 50-85 ℃ by a high-speed mixer for mixing;
(2) extruding: adding the mixed material obtained in the step (1) into an extruder through a feeder, and extruding and granulating by adopting a double-screw extruder;
(3) film blowing: and (3) blowing the film on the particles obtained in the step (2) by adopting a single-screw extruder to obtain a novel material with the film thickness of 15 +/-2-25 +/-3 mu m.
4. The method for preparing the novel material for the protective clothing capable of being dissolved after moist heat sterilization according to claim 3, wherein the method comprises the following steps: the rotating speed of the feeder in the step (2) is 10-30r/min, the rotating speed of a screw of the extruder is 50-100r/min, and the working temperature of the extruder is 85-190 ℃.
5. The method for preparing the novel material for the protective clothing capable of being dissolved after moist heat sterilization according to claim 3, wherein the method comprises the following steps: the length-diameter ratio of the double-screw extruder in the step (2) is 48: 1.
6. The method for preparing the novel material for the protective clothing capable of being dissolved after moist heat sterilization according to claim 3, wherein the method comprises the following steps: the length-diameter ratio of the single-screw extruder in the step (3) is 36: 1.
7. The method for preparing the novel material for the protective clothing capable of being dissolved after moist heat sterilization according to claim 3, wherein the method comprises the following steps: the working temperature of the single-screw extruder in the step (3) is 120-195 ℃.
8. The method for preparing the novel material for the protective clothing capable of being dissolved after moist heat sterilization according to claim 3, wherein the method comprises the following steps: the blowing ratio of the blown film in the step (3) is 1:4-8, and the drawing speed is 2 +/-0.4 m/min.
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CN112300448A (en) * | 2020-10-28 | 2021-02-02 | 泰州诺盟新材料科技有限公司 | Degradable protective clothing novel material capable of being dissolved after sterilization and preparation method |
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