CN111480234B - Method of incorporating a funnel device into a capacitor configuration to reduce cell interference and capacitor configuration incorporating a funnel device - Google Patents
Method of incorporating a funnel device into a capacitor configuration to reduce cell interference and capacitor configuration incorporating a funnel device Download PDFInfo
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- CN111480234B CN111480234B CN201880080638.7A CN201880080638A CN111480234B CN 111480234 B CN111480234 B CN 111480234B CN 201880080638 A CN201880080638 A CN 201880080638A CN 111480234 B CN111480234 B CN 111480234B
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- bottom electrode
- shaped bottom
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- electrode
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/38—Multiple capacitors, i.e. structural combinations of fixed capacitors
- H01G4/385—Single unit multiple capacitors, e.g. dual capacitor in one coil
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B53/00—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/21—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements
- G11C11/22—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements
- G11C11/221—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements using ferroelectric capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/33—Thin- or thick-film capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/48—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
- H01L23/482—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of lead-in layers inseparably applied to the semiconductor body
- H01L23/485—Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor consisting of lead-in layers inseparably applied to the semiconductor body consisting of layered constructions comprising conductive layers and insulating layers, e.g. planar contacts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body
- H01L27/06—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration
- H01L27/0611—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region
- H01L27/0617—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region comprising components of the field-effect type
- H01L27/0629—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being a semiconductor body including a plurality of individual components in a non-repetitive configuration integrated circuits having a two-dimensional layout of components without a common active region comprising components of the field-effect type in combination with diodes, or resistors, or capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/55—Capacitors with a dielectric comprising a perovskite structure material
- H01L28/56—Capacitors with a dielectric comprising a perovskite structure material the dielectric comprising two or more layers, e.g. comprising buffer layers, seed layers, gradient layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
- H01L28/90—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
- H01L28/91—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by depositing layers, e.g. by depositing alternating conductive and insulating layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B53/00—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors
- H10B53/30—Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory capacitors characterised by the memory core region
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Semiconductor Memories (AREA)
Abstract
Some embodiments include an apparatus having a horizontally spaced bottom electrode supported by a support structure. The funnel material is directly against the bottom electrode. An insulating material is over the bottom electrode and an upper electrode is over the insulating material. A plate material extends across and couples the upper electrodes to one another. The sheet material is directly against the funnel device material. The funnel device material electrically couples the bottom electrode to the plate material, and may be configured to discharge at least a portion of excess charge from the bottom electrode to the plate material. Some embodiments include methods of forming an apparatus including a capacitor having a bottom electrode and a top electrode, wherein the top electrodes are electrically coupled to each other by a conductive plate. A funnel means is formed to electrically couple the bottom electrode to the conductive plate.
Description
Technical Field
The present invention relates to a method of incorporating a funnel device into a capacitor configuration to reduce cell interference and a capacitor configuration incorporating a funnel device.
Background
Computers and other electronic systems (e.g., digital televisions, digital cameras, cellular telephones, etc.) often have one or more memory devices to store information. Memory devices are increasingly smaller in size to achieve higher density storage capacities. Even when increased density is achieved, consumers often require that the memory device also use less power while maintaining high speed access and reliability of data stored on the memory device.
Leakage within a memory cell can be problematic, at least because it can make it difficult to reliably store data, and power can otherwise be wasted. Leakage can become increasingly difficult to control as the circuits scale to ever smaller dimensions.
It would be desirable to develop an architecture that mitigates or even prevents unwanted leakage; and it is desirable to develop methods for fabricating such architectures.
Drawings
Fig. 1-9 are diagrammatic cross-sectional views of an example assembly at an example process stage of an example method for fabricating an example capacitor.
Fig. 3A is a top view of the assembly at a stage of the process of fig. 3.
Fig. 10 and 11 are diagrammatic cross-sectional views of an example assembly at an example process stage of an example method for fabricating an example capacitor. In some embodiments, the process stages of fig. 10 may follow the process stages of fig. 6.
Fig. 12-16 are diagrammatic cross-sectional views of an example assembly at an example process stage of an example method for fabricating an example capacitor. In some embodiments, the process stages of fig. 12 may follow the process stages of fig. 3.
Fig. 17 and 18 are diagrammatic cross-sectional views of an example assembly at an example process stage of an example method for fabricating an example capacitor. In some embodiments, the process stages of fig. 17 may follow the process stages of fig. 2.
Fig. 19 is a diagrammatic cross-sectional view of an example assembly at an example process stage alternative to that of fig. 16.
Fig. 20 is a schematic diagram of an example memory array including ferroelectric capacitors.
Fig. 21 is a schematic diagram of an example memory cell including a ferroelectric capacitor.
Detailed Description
Some embodiments include utilizing a funnel device to reduce charge accumulation along the bottom electrode of the capacitor. The funnel means may couple the bottom electrode to the conductive plate. The conductive plate may be along the top electrodes of the capacitors and may be used to electrically couple the top electrodes to each other. The funnel device may have a conductivity (or alternatively, resistance) tailored to enable excess charge to drain from the bottom electrode to the conductive plate while not achieving a problematic short circuit between the bottom electrode and the conductive plate.
Many, if not most, of the main memory cell disturb mechanisms are due to the accumulation of potential at the bottom of Cell (CB) electrode nodes. As discussed in more detail below, this interference mechanism applies to ferroelectric RAM (FERAM). However, other types of electronic devices may likewise benefit from the disclosed subject matter.
In an embodiment, each of the memory cells in the memory array may be programmed to one of two data states to represent a binary value of "0" or "1" in a single bit. This cell is sometimes referred to as a Single Level Cell (SLC). Various operations relating to these types of cells are independently known in the semiconductor and related arts.
Regardless of the memory cell arrangement, the dominant disturb mechanism discussed above may occur due to different factors. For example, the charge on the bottom node of the cell may rise due to factors such as plate glitches (glitch), access transistor leakage, cell-to-cell interactions, and/or other factors. If the dielectric material in the memory cell leaks significantly, the state of the cell may be adversely affected.
In various embodiments described herein, a funnel device is introduced into a memory array to prevent accumulation of potential at the bottom node of a capacitor associated with an individual memory cell. Example embodiments are described with reference to fig. 1-21.
A first method for incorporating the funnel device into the capacitor array is described with fig. 1-9.
Referring to fig. 1, an assembly (i.e., device, construction, etc.) 10 includes a structure 14 over a substrate 12.
The substrate 12 may comprise a semiconductor material; and may, for example, comprise, consist essentially of, or consist of single crystal silicon. The base 12 may be referred to as a semiconductor substrate. The term "semiconductor substrate" means any construction comprising semiconductor material, including but not limited to bulk semiconductor material, such as semiconductor wafers (alone or in assemblies comprising other materials), and layers of semiconductor material (alone or in assemblies comprising other materials). The term "substrate" refers to any support structure including, but not limited to, the semiconductor substrates described above. In some applications, base 12 may correspond to a semiconductor substrate containing one or more materials associated with integrated circuit fabrication. Such materials may include, for example, one or more of refractory metal materials, barrier materials, diffusion materials, insulator materials, and the like.
A gap is shown between the substrate 12 and the structure 14 to indicate that there may be additional materials, components, etc. provided between the substrate 12 and the structure 14.
The structure 14 is shown to include a first material 16 over a second material 18, wherein the first material and the second material are directly adjacent to each other along an interface 17. The first material may be selectively etchable relative to the second material. For example, in some embodiments, the first material 16 may comprise, consist essentially of, or consist of silicon nitride; and second material 18 may comprise, consist essentially of, or consist of silicon dioxide.
The structure 14 has an upper surface 15 that extends across an upper surface of the first material 16.
Conductive structures 20 are shown in the bottom region of the second material 18. The conductive structures 20 are conductive interconnects. The processes described herein form capacitors (e.g., the capacitors shown in fig. 9), and conductive structures 20 may be utilized to couple the electrodes of such capacitors with additional circuitry (e.g., transistors).
Conductive structure 20 may comprise any suitable composition or combination of compositions; such as, for example, one or more of various metals (e.g., titanium, tungsten, cobalt, ruthenium, nickel, platinum, etc.), metal-containing compositions (e.g., metal silicides, metal nitrides, metal carbides, etc.), and/or conductively-doped semiconductor materials (e.g., conductively-doped silicon, conductively-doped germanium, etc.).
Although materials 16 and 18 are shown as homogeneous in the illustrated embodiment, in other embodiments one or both of materials 16 and 18 may be heterogeneous combinations of two or more compositions.
Material 16 may be formed to any suitable thickness and, in some embodiments, may be formed to be from about 100 angstromsTo aboutWithin a range of (2).
The structure 14 may be referred to as a "support structure" because it ultimately may support a capacitor formed therein.
Referring to fig. 2, an opening 22 is formed in the support structure 14. An opening 22 extends through materials 16 and 18 and exposes an upper surface of conductive structure 20. Any suitable process may be used to form the openings 22. For example, a patterned mask (not shown) may be provided over the support structure 14 and used to define the locations of the openings 22, and then the openings 22 may be extended into the support structure 14 using one or more suitable etches. Subsequently, the patterned mask may be removed to leave the assembly of fig. 2.
Referring to fig. 3, the opening 22 is lined with an electrode material 24 (which may be referred to as a bottom electrode material). Electrode material 24 may comprise any suitable composition or combination of compositions; such as, for example, one or more of various metals (e.g., titanium, tungsten, cobalt, ruthenium, nickel, platinum, etc.), metal-containing compositions (e.g., metal silicides, metal nitrides, metal carbides, etc.), and/or conductively-doped semiconductor materials (e.g., conductively-doped silicon, conductively-doped germanium, etc.). In some embodiments, electrode material 24 may comprise, consist essentially of, or consist of titanium nitride.
The electrode material 24 is configured as an upwardly opening container-shaped bottom electrode 26 within each opening. Each of the bottom electrodes has an upper surface 27, the upper surface 27 being recessed below the upper surface 15 of the support structure 14.
Each of the openings 22 has an exposed vertically extending surface 29 of the support structure 14 received therein above a recessed upper surface 27 of the upwardly opening container-shaped bottom electrode 26. In the illustrated embodiment, the upper surface 27 of the bottom electrode 26 extends above the interface 17 between the first material 16 and the second material 18, and correspondingly the vertically extending surface 29 includes only the first material 16.
The container-shaped electrode 26 has an interior region 28 extending therein. The electrode 26 may have any suitable shape when viewed from above, and correspondingly the interior region 28 may have any suitable shape. For example, fig. 3A shows a top view of assembly 10 at the processing stage of fig. 3 in an example application in which bottom electrode 26 is circular and contains a circular interior region 28. In other embodiments, the bottom electrode 26 may have other shapes, including, for example, elliptical shapes, polygonal shapes, and the like.
The bottom electrode 26 may be formed using any suitable process. For example, in some embodiments, the electrode material 24 may be initially formed to extend across the upper surface 15 of the support structure 14, also within the opening 22. Subsequently, one or more suitable etches may be employed to remove the excess material 24 to leave a remaining material 24 configured as the shown upwardly open container-shaped bottom electrode 26.
Electrode material 24 may have any suitable thickness; and in some embodiments may have a range of from aboutTo aboutWithin a range of (2).
Referring to fig. 4, an interior region 28 of the bottom electrode 26 is lined with an insulating material 30. The insulating material 30 narrows the interior region 28 of the upwardly open container-shaped bottom electrode 26.
Insulating material 30 may be referred to as a capacitor insulating material because it is ultimately used in a capacitor configuration. At least some of the capacitor insulating material may comprise ferroelectric insulating material, and in some embodiments, all of the capacitor insulating material is ferroelectric insulating material.
The ferroelectric-insulating material may comprise any suitable composition or combination of compositions; and in some example embodiments may include one or more of transition metal oxides, zirconium oxide, niobium oxide, hafnium oxide, lead zirconium titanate, and barium strontium titanate. Also, in some example embodiments, the ferroelectric insulating material may have dopants therein that include one or more of silicon, aluminum, lanthanum, yttrium, erbium, calcium, magnesium, strontium, and rare earth elements.
Insulating material 30 may be formed to any suitable thickness; and in some embodiments may have a range of from aboutTo about Within a range of (2).
An upper electrode material 32 is formed over the insulating material 30 and within the narrowed interior region 28 that extends into the container-shaped bottom electrode 26.
The upper electrode material 32 may comprise any suitable composition or combination of compositions; such as, for example, one or more of various metals (e.g., titanium, tungsten, ruthenium, cobalt, nickel, platinum, etc.), metal-containing compositions (e.g., metal silicides, metal nitrides, metal carbides, etc.), and/or conductively-doped semiconductor materials (e.g., conductively-doped silicon, conductively-doped germanium, etc.). In some embodiments, electrode material 32 may comprise, consist essentially of, or consist of one or more of molybdenum silicide, titanium nitride, titanium silicon nitride, ruthenium silicide, ruthenium, molybdenum, tantalum nitride, tantalum silicon nitride, and tungsten.
Electrode material32 may have any suitable thickness, and in some embodiments may have a thickness of from aboutTo aboutWithin a range of (2).
In some embodiments, electrode materials 24 and 32 may comprise the same composition as one another, or may comprise different compositions relative to one another. In some embodiments, both electrode materials 24 and 32 may comprise, consist essentially of, or consist of titanium nitride.
Referring to fig. 5, the assembly 10 is subjected to planarization (e.g., chemical mechanical polishing) to form a planarized upper surface 33. Planarization patterns the electrode material 32 into an upper electrode 36 and the insulating material 30 into an upwardly opening container-shaped insulating structure 34. The electrodes 26 and 36 together with the insulating material 30 therebetween form a plurality of capacitors 38. In some embodiments, the capacitor 38 may be a ferroelectric capacitor.
Referring to fig. 6, first material 16 (fig. 5) is removed to expose upper sidewall regions 39 of capacitor 38. The upper sidewall region 39 may be considered along the exposed portion 37 of the capacitor 38.
The exposed upper sidewall region 39 includes the portion (i.e., section) of the bottom electrode 26 that is under the portion (i.e., section) of the insulating material 30. In some embodiments, the exposed upper sidewall region 39 may have a thickness of from aboutTo about->Height H in the range of (2).
Referring to fig. 7, funnel device material 40 is formed across the upper surface of assembly 10, wherein funnel device material 40 extends along the upper surface of capacitor 38, along the upper surface of material 18, and along upper sidewall region 39 of capacitor 38.
The funnel device material may comprise any suitable composition or combination of compositions. In some embodiments, funnel device material 40 may comprise, consist essentially of, or consist of one or more of titanium, nickel, and niobium in combination with one or more of germanium, silicon, oxygen, nitrogen, and carbon. In some embodiments, the funnel device material may comprise, consist essentially of, or consist of one or more of Si, ge, siN, tiSiN, tiO, tiN, niO, niON and ton; wherein the chemical formula indicates the main component rather than a specific stoichiometry. In some embodiments, the funnel device material may comprise, consist essentially of, or consist of titanium, oxygen, and nitrogen. In some embodiments, the funnel device material may include amorphous silicon, niobium monoxide, silicon-rich silicon nitride, and the like; alone or in any suitable combination.
In some embodiments, the funnel material may be of a material from aboutTo about->A continuous layer of thickness in the range of (a). In some embodiments, the funnel device material may be of a material from about +.>To about->A continuous layer of thickness in the range of (a). It should be noted that the thickness of the funnel material 40 corresponds to the vertical thickness along the horizontally extending section 41 of the funnel material and to the horizontal thickness along the vertically extending section 43 of the funnel material.
Referring to fig. 8, the funnel material 40 is patterned into vertically extending funnel 44 using a spacer (i.e., anisotropic) etch. The funnel device 44 is electrically coupled with the bottom electrode 26 and, in the embodiment shown, directly contacts the bottom electrode 26. Each of the funnel devices 44 extends along a section of bottom electrode material 24 and along a section of insulating material 30 associated with an upper sidewall region 39 of the capacitor 38.
Referring to fig. 9, a plate material 46 is formed to extend across the upper electrodes 36 of the capacitors 38 and electrically couple the upper electrodes to one another. The plate material 46 is directly against the top electrode 36 of the capacitor 38 and directly against the vertically extending funnel means 44.
The plate material 46 may include any suitable conductive material such as, for example, one or more of various metals (e.g., titanium, tungsten, cobalt, nickel, ruthenium, platinum, etc.), metal-containing compositions (e.g., metal silicide, metal nitride, metal carbide, etc.), and/or conductively-doped semiconductor materials (e.g., conductively-doped silicon, conductively-doped germanium, etc.). The plate material 46 may comprise any composition different from the top electrode 36. For example, in some embodiments, the top electrode 36 may comprise, consist essentially of, or consist of TiSiN and/or TiN (where the formulas list the primary composition rather than a particular stoichiometry), and the plate material 46 may comprise, consist essentially of, or consist of tungsten.
The funnel means 44 electrically couples the bottom electrode 26 of the capacitor 38 with the sheet material 46 to enable at least a portion of any excess charge to be discharged from the bottom electrode 26 to the sheet material 46. In some embodiments, the electrical resistance of the funnel device 44 is tailored such that the funnel device 44 has an appropriate electrical conductivity to remove excess charge from the bottom electrode 26 while having a sufficiently low electrical conductivity (e.g., a sufficiently high electrical resistance) such that the funnel device 44 does not undesirably electrically short the bottom electrode 26 to the sheet material 46.
In some embodiments, the capacitor 38 may be incorporated into a memory cell 50, such as, for example, a ferroelectric memory cell, by coupling the capacitor with appropriate circuit components. For example, transistor 48 is illustrated in fig. 9 as being coupled to bottom electrode 26 through conductive interconnect 20. Transistor 48 and/or other suitable components may be fabricated at any suitable process stage. For example, in some embodiments, transistor 48 may be fabricated at a processing stage that precedes the illustrated process stage of FIG. 1.
Memory cell 50 may be part of a memory array; such as, for example, feRAM (ferroelectric random access memory) arrays.
In some embodiments, the funnel device 44 may be considered a resistive interconnect coupling the bottom electrode 26 within the memory cell 50 to the conductive plate material 46. If the funnel device is too leaky, one or more memory cells may experience inter-cell interference. If the funnel 44 is not sufficiently leaky (conductive), then excess charge from the bottom electrode 26 will not be discharged. One of ordinary skill in the art will recognize how to calculate the resistance required for the funnel device 44 for a given memory array. In some embodiments, the funnel 44 may have a resistance in the range of from about 0.1 megaohms to about 5 megaohms. The following factors may be considered in determining the resistance for the funnel arrangement 44: such as the separation between adjacent memory cells, the dielectric material used between memory cells, the physical dimensions of the memory cells, the amount of charge placed in the memory cells, the size of the memory array, the frequency of operations performed by the memory array, etc.
The embodiment of fig. 8 and 9 shows the funnel device 44 as comprising only a vertically extending section along the upper sidewall region 39 of the capacitor 38. In other embodiments, the funnel 44 may have other configurations. For example, FIG. 10 shows assembly 10a at a process stage that replaces the process stage of FIG. 8 and that may follow the process stage of FIG. 7. The assembly 10a includes a funnel device material 40 configured as a funnel device 44a, wherein each of such funnel device structures includes a horizontal section 51 along an upper surface of the material 18, and a vertical section 53 along an upper sidewall region 39 of the capacitor 38. Fig. 11 shows a funnel device 44a incorporated into a memory cell 50 similar to that described above with reference to fig. 9.
Another example process for incorporating a funnel device into a memory unit is described with reference to fig. 12-16.
Referring to fig. 12, an assembly 10b is shown at a process stage that may follow the process stage of fig. 3. The assembly 10b includes a support structure 14 having an opening 22 extending therein, and includes an upwardly opening container-shaped bottom electrode 26 within the bottom of the opening 22. Material 56 is deposited over upper surface 15 of support structure 14 and within opening 22. The material 56 extends along the vertically extending surface 29 of the support structure within the opening 22. Material 56 is the precursor that ultimately converts to the funnel material; and may comprise any composition suitable for conversion to the desired funnel device material. In some embodiments, material 56 may be referred to as a first composition. In some embodiments, the first composition may comprise, consist essentially of, or consist of titanium nitride.
Referring to fig. 13, the first composition 56 (fig. 12) is chemically modified to convert the first composition to a second composition corresponding to the funnel device material 40. In some embodiments, chemical modification may include reducing electrical conductivity within the first composition to thereby convert the first composition into funnel device material 40. Chemical modification may utilize any suitable conditions. In the illustrated embodiment, chemical modification includes exposing the assembly 10b to an oxidizing agent 58, and correspondingly includes oxidizing the material 56 (fig. 12) to convert the material 56 into the funnel device material 40. The oxidizing agent may be any suitable oxidizing agent; including, for example, one or more of ozone, hydrogen peroxide, diatomic oxygen, and the like. In some embodiments, the first composition 56 of fig. 12 comprises, consists essentially of, or consists of titanium nitride; and the funnel device material 40 of fig. 13 comprises, consists essentially of, or consists of ton (where the formulas indicate the main components rather than the specific stoichiometry).
Although the illustrated embodiment of fig. 12 and 13 utilizes a multi-step process in which the first composition 56 is deposited and thereafter converted to the funnel material 40 to form the funnel material 40, in other embodiments, a simple deposition of the funnel material across the upper surface 15 of the support structure 14 and within the opening 22 may be employed to form the funnel material 40 of fig. 13. Regardless of the method used to form the funnel device material, the funnel device material 40 of fig. 13 may comprise any of the compositions described above with reference to the funnel device material 40 of fig. 7.
The funnel device material 40 of fig. 13 extends within the interior region 28 of the container-shaped bottom electrode 26 and also along the sidewall surfaces 29 of the support structure 14 (with such sidewall surfaces 29 within the opening 22 and above the uppermost surface 27 of the bottom electrode 26)). The funnel device material 40 may be a continuous layer (as shown), or may be a discontinuous layer. In some embodiments, the funnel material 40 is of from aboutTo about->A continuous layer of thickness in the range of (a). In some embodiments, funnel device material 40 may be of a material from about +.>To about->A continuous layer of thickness in the range of (a).
Referring to fig. 14, an insulating material 30 is formed over the funnel material 40, and an upper electrode material 32 is formed over the insulating material 30. Materials 30 and 32 may comprise the same compositions discussed above with respect to fig. 4. The insulating material 30 extends within and narrows such an interior region 28 of the upwardly open container-shaped bottom electrode 26, and the upper electrode material 32 extends into the narrowed interior region.
Referring to fig. 15, the assembly 10b is subjected to planarization (i.e., polishing conditions); such as, for example, chemical mechanical polishing. This forms a planarized upper surface 33. Planarization patterns the electrode material 32 into an upper electrode 36 and the insulating material 30 into an upwardly opening container-shaped insulating structure 34. The electrodes 26 and 36 together with the materials 40 and 30 therebetween form a plurality of capacitors 38. In some embodiments, the capacitor 38 may be a ferroelectric capacitor.
Referring to fig. 16, a plate material 46 is formed to extend along the planarized upper surface 33. The plate material 46 electrically couples the upper electrodes 36 of the capacitors 38 to one another. The plate material 46 is directly against the funnel device material 40, and the corresponding floor drain funnel device material 40 may electrically couple the bottom electrode 26 to the plate material 46. The funnel device material 40 of fig. 16 may be configured to include an appropriate composition and dimensions to be configured to discharge at least a portion of the excess charge from the bottom electrode 26 to the plate material 46.
In some embodiments, the assembly 10b of fig. 16 may be considered to include a horizontally spaced upwardly open container-shaped bottom electrode 26 supported by the support structure 14. The support structure 14 has an upper surface 33 above the upper surface 27 of the bottom electrode. The vertically extending surface 29 of the support structure extends from the upper surface 27 of the bottom electrode to the upper surface 33 of the support structure and to the bottom surface 47 of the plate material 46.
The funnel device material 40 extends along the vertically extending surface 29 of the support structure 14 and also within the interior region 28 of the container-shaped bottom electrode 26. In the illustrated embodiment, the funnel device material 40 adds to the interior region of the substrate portion electrode 26 and directly against the bottom electrode.
The insulating material 30 is over the funnel material 40 and within the interior region 28 of the container-shaped bottom electrode 26. The insulating material 30 is configured as an upwardly opening container-shaped insulating structure 34.
The upper electrode 36 extends into the vessel-shaped insulating structure 34.
Capacitor 38 includes electrodes 26 and 36 with insulating material 30 therebetween. In some embodiments, such capacitors may be ferroelectric capacitors. Capacitor 38 may be coupled with transistor 48 through interconnect 20 (as shown) and may be incorporated into memory cell 50b. Such memory cells may correspond to a plurality of substantially identical memory cells within memory array 52b (where the term "substantially identical" means identical within reasonable manufacturing and measurement tolerances). Although three memory cells 50b are shown, it should be appreciated that the memory array may include any suitable number of memory cells 50b; and in some embodiments may include hundreds, thousands, millions, billions, etc., of substantially identical memory cells.
The plate material 46 extends across the upper electrodes 36 of the capacitors 38 and couples the upper electrodes to one another. The plate material 46 also directly abuts against the upper surface of the funnel material 40. The funnel device material may be configured to have an appropriate conductivity such that this material will discharge at least a portion of the excess charge from the bottom electrode 26 to the sheet material 46 without creating an undesirable electrical short between the bottom electrode 26 and the sheet material 46.
The illustrated embodiment of fig. 13 has an upper surface 27 of the bottom electrode 26 above the interface 17 between the first material 16 and the second material 18. Correspondingly, the vertically extending surface 29 is only along the first material 16. Fig. 13 shows an example of an embodiment in which the interface 17 between the first material 16 and the second material 18 is at or below the upper surface 27 of the bottom electrode 26. In other embodiments, the interface 17 may be above the upper surface of the bottom electrode, as described with reference to fig. 17 and 18.
Referring to fig. 17, an assembly 10c is shown at a process stage similar to that described above with reference to fig. 3. The embodiment of fig. 17 differs from the embodiment of fig. 3 in that the bottom electrode 26 of the assembly 10c has an upper surface 27 below the interface 17, while the bottom electrode 26 shown in the assembly 10 of fig. 3 has an upper surface 27 above the interface 17.
Referring to fig. 18, assembly 10c is shown at a processing stage similar to that of fig. 16. Assembly 10c includes memory cells 50c within array 52 c. Memory cell 50c is similar to memory cell 50b of fig. 16. However, the difference is that the upper surface 27 of the bottom electrode 26 is below the interface 17 between the materials 16 and 18. Correspondingly, the vertically extending surface 29 extends along the material 16, and also along an upper region of the material 18. In some embodiments, materials 16 and 18 include silicon nitride and silicon dioxide, respectively. In such embodiments, the configuration of fig. 16 has funnel device material 40 extending only along the silicon nitride of material 16 supporting vertically extending surface 29 of material 14, while the configuration of fig. 18 has funnel device material 40 extending along both the silicon nitride of material 16 and the silicon dioxide of material 18.
The funnel material 40 shown in the above-described embodiments of fig. 1-18 is a continuous layer. In other embodiments, the funnel material may be a discontinuous layer. For example, fig. 19 shows an assembly 10d similar to assembly 10b of fig. 16, but wherein funnel device material 40 is a discontinuous film. The opening extending through the funnel device material 40 may be very small and, in some embodiments, may be a pinhole opening. The assembly 10d of fig. 19 is shown with the capacitor 38 incorporated into the memory cell 50d, which memory cell 50d is in turn comprised by the memory array 52 d.
The memory arrays described above (e.g., memory array 52 of fig. 9, memory array 52b of fig. 16, etc.) may be ferroelectric memory arrays and may have any suitable configuration. An example ferroelectric memory array 52 is described with reference to fig. 20. The memory array comprises a plurality of substantially identical ferroelectric capacitors 38. Word lines 70 extend along rows of the memory array and digit lines 72 extend along columns of the memory array. Each of the capacitors 38 uniquely addresses a memory cell 50 within the memory cell 50 with a combination of word lines and digit lines. Word line 70 extends to driver circuit 76 and digit line 72 extends to sense circuit 78. In some applications, the memory array 52 may be configured as a ferroelectric random access memory (FeRAM).
Memory cell 50 may include transistor 48 in combination with a ferroelectric capacitor. For example, in some applications, each of the memory cells 50 may include a transistor 48 in combination with a ferroelectric capacitor 38, as shown in fig. 21. Memory 56 is shown coupled with word line 70 and digit line 72. Also, one of the electrodes of the capacitor 38 is shown coupled with a plate line comprising a plate material 46. Plate lines may be used in combination with word lines 70 to control the operating state of ferroelectric capacitor 38.
The structure discussed above may be incorporated into an electronic system. Such electronic systems may be used, for example, in memory modules, device drivers, power modules, communication modems, processor modules, and application-specific modules, and may include multilayer, multichip modules. The electronic system may be any of a wide range of systems, such as, for example, cameras, wireless devices, displays, chipsets, set-top boxes, games, lighting fixtures, vehicles, clocks, televisions, cell phones, personal computers, automobiles, industrial control systems, aircraft, and the like.
Unless otherwise specified, any suitable methodology now known or yet to be developed may be employed to form the various materials, substances, compositions, and the like described herein, including, for example, atomic Layer Deposition (ALD), chemical Vapor Deposition (CVD), physical Vapor Deposition (PVD), and the like.
The terms "dielectric" and "insulating" may be utilized to describe materials having insulating electrical properties. The terms are considered synonymous in the present invention. The use of the term "dielectric" in some examples and the term "insulating" (or "electrically insulating") in other examples may provide a language variation within the disclosure to simplify the underlying precondition within the appended claims, and is not used to indicate any obvious chemical or electrical difference.
The particular orientations of the various embodiments in the drawings are for illustrative purposes only, and embodiments may be rotated relative to the orientation shown in some applications. The description provided herein and the claims appended hereto relate to any structure having the described relationship between various features, whether or not the structure is in the particular orientation of the drawings or rotated relative to such orientation.
The cross-sectional view of the drawing only shows features in the plane of the cross-section, and does not show material behind the plane of the cross-section (unless otherwise indicated) in order to simplify the drawing.
When a structure is referred to above as being "on" or "against" another structure, it can be directly on the other structure or intervening structures may also be present. In contrast, when a structure is referred to as being "directly on" or "directly against" another structure, there are no intervening structures present.
Structures (e.g., layers, materials, etc.) may be referred to as "vertically extending" to indicate that the structure extends generally upward from an underlying base (e.g., substrate). The vertically extending structures may extend substantially orthogonally with respect to the upper surface of the substrate, or not.
Some embodiments include a method of forming an apparatus. The opening is formed to extend into the support structure. The openings are lined with bottom electrode material. The bottom electrode material within each opening is configured as an upwardly opening container-shaped bottom electrode having an interior region. The upper surface of each upwardly open container-shaped bottom electrode is recessed below the upper surface of the support structure. The inner region of the upwardly open container-shaped bottom electrode is lined with an insulating material to narrow the inner region of the upwardly open container-shaped bottom electrode. An upper electrode is formed in a narrowed inner region of the upwardly open container-shaped bottom electrode. The upper electrode, insulating material and upwardly opening container-shaped bottom electrode together form a plurality of capacitors. The plate material is formed to extend across the upper electrodes and couple the upper electrodes to each other. The funnel means is formed to electrically couple the bottom electrode to the sheet material.
Some embodiments include a method of forming an apparatus. The opening extends into the support structure. The support structure has an upper surface between the openings. The openings are lined with bottom electrode material. The bottom electrode material within each opening is configured as an upwardly opening container-shaped bottom electrode having an interior region. The upper surface of each upwardly open container-shaped bottom electrode is recessed below the upper surface of the support structure. Each of the openings has an exposed vertically extending surface of the support structure above a recessed upper surface of an upwardly opening container-shaped bottom electrode received therein. Above the upper surface of the support structure, a funnel material is formed along the exposed vertically extending surface of the support structure and within the interior region of the upwardly open container-shaped bottom electrode. An insulating material is formed over the funnel material. The insulating material extends into the interior region of the upwardly opening container-shaped bottom electrode to narrow the interior region of the upwardly opening container-shaped bottom electrode. An upper electrode is formed in a narrowed inner region of the upwardly open container-shaped bottom electrode. The upper electrode, insulating material and upwardly opening container-shaped bottom electrode together form a plurality of capacitors. The plate material is formed to extend across the upper electrodes and couple the upper electrodes to each other. The sheet material is directly against the funnel device material. The funnel device material electrically couples the bottom electrode to the sheet material and is configured to discharge at least a portion of the excess charge from the upwardly open container-shaped bottom electrode to the sheet material.
Some embodiments include an apparatus having a horizontally spaced upwardly open container-shaped bottom electrode supported by a support structure. The upper surface of the upwardly open container-shaped bottom electrode is below the upper surface of the support structure. The vertically extending surface of the support structure is above the upper surface of the upwardly opening container-shaped bottom electrode. The funnel material is along the vertically extending surface of the support structure and within the interior region of the upwardly open container-shaped bottom electrode. The insulating material is over the funnel material and within the interior region of the upwardly open container-shaped bottom electrode. The insulating material is configured as an upwardly opening container-shaped insulating structure within the upwardly opening container-shaped bottom electrode. The upper electrode extends into an upwardly opening container-shaped insulating structure. The upper electrode, the upwardly-opening container-shaped insulating structure, and the upwardly-opening container-shaped bottom electrode are all comprised together by a plurality of capacitors. The sheet material extends across and couples the upper electrodes to one another. The sheet material is directly against the funnel device material. The funnel device material electrically couples the bottom electrode to the sheet material and is configured to discharge at least a portion of the excess charge from the upwardly open container-shaped bottom electrode to the sheet material.
Claims (15)
1. A method of forming a memory apparatus, comprising:
forming an opening extending into the support structure;
lining the openings with a bottom electrode material, the bottom electrode material within each opening forming an upwardly opening container-shaped bottom electrode having an interior region; an upper surface of each of the upwardly open container-shaped bottom electrodes is recessed below an upper surface of the support structure;
lining the interior region of the upwardly opening container-shaped bottom electrodes with an insulating material to narrow the interior region of each of the upwardly opening container-shaped bottom electrodes;
forming an upper electrode within the narrowed interior region of each of the upwardly open container-shaped bottom electrodes; each of the upper electrode, the insulating material, and the upwardly open container-shaped bottom electrode together form a plurality of capacitors;
forming a plate material extending across and coupling the upper electrodes to each other; a kind of electronic device with high-pressure air-conditioning system
A funnel device is formed that electrically couples each of the upwardly open container-shaped bottom electrodes to the plate material.
2. The method of claim 1, wherein the insulating material is a ferroelectric insulating material.
3. The method of claim 1, wherein the funnel device comprises one or more of Ti, ni, and Nb in combination with one or more of Ge, si, O, N and C.
4. The method of claim 1, wherein the funnel device comprises a continuous vertically extending section.
5. The method of claim 1, wherein the funnel device comprises a discontinuous vertically extending section.
6. The method of claim 1, wherein each of the openings has an exposed sidewall area above the recessed upper surface of the upwardly opening container-shaped bottom electrode received therein; and wherein the forming of the funnel device comprises forming funnel device material to extend along the exposed sidewall region and along the interior region of each of the upwardly opening container-shaped bottom electrodes.
7. The method of claim 1, wherein the funnel comprises a funnel material; and wherein the support structure comprises a first material over a second material, wherein an interface between the first material and the second material is below the recessed upper surface of each of the upwardly open container-shaped bottom electrodes; and the method further comprises:
after forming the upper electrode, removing the first material to expose an upper region of each of the capacitors; the exposed upper region of each of the capacitors has an exposed upper sidewall region that includes a portion of an associated one of the upwardly-opening container-shaped bottom electrodes and a portion of the insulating material over the portion of the associated one of the upwardly-opening container-shaped bottom electrodes;
forming the funnel device material to extend along the exposed upper sidewall regions of each of the capacitors; the funnel device material along each of the exposed upper sidewall regions is configured as a vertically extending funnel device extending along the portion of the associated one of the upwardly opening container-shaped bottom electrodes and along the portion of the insulating material; a kind of electronic device with high-pressure air-conditioning system
Forming the plate material to be above the capacitor and along the upper sidewall region of the capacitor; the sheet material along the upper sidewall region of the capacitor is directly against the vertically extending funnel means.
8. A memory apparatus, comprising:
horizontally spaced apart upwardly open container-shaped bottom electrodes supported by a support structure; an upper surface of the upwardly open container-shaped bottom electrode is below an upper surface of the support structure; a vertically extending surface of the support structure is above the upper surface of the upwardly open container-shaped bottom electrode;
funnel means material along said vertically extending surface of said support structure and within an interior region of said upwardly open container-shaped bottom electrode;
an insulating material over the funnel device material and within the interior region of the upwardly open container-shaped bottom electrode; the insulating material is configured as an upwardly open container-shaped insulating structure within the upwardly open container-shaped bottom electrode;
an upper electrode extending into the upwardly open container-shaped insulating structure; the upper electrode, the upwardly open container-shaped insulating structure and the upwardly open container-shaped bottom electrode together comprise a plurality of capacitors; a kind of electronic device with high-pressure air-conditioning system
A plate material extending across and coupling the upper electrodes to each other; the sheet material directly against the funnel device material; the funnel device material electrically couples the bottom electrode to the plate material and is configured to discharge at least a portion of excess charge from the upwardly opening container-shaped bottom electrode to the plate material.
9. The memory apparatus of claim 8, wherein the funnel means comprises one or more of Ti, ni, and Nb in combination with one or more of Ge, si, O, N and C.
10. The memory device of claim 8, wherein the insulating material is a ferroelectric insulating material.
11. A method of forming a memory apparatus, comprising:
forming openings extending into a support structure, the support structure having an upper surface between the openings;
lining the openings with a bottom electrode material, the bottom electrode material within each opening forming an upwardly opening container-shaped bottom electrode having an interior region; the upper surface of each upwardly open container-shaped bottom electrode is recessed below the upper surface of the support structure; each of the openings having an exposed vertically extending surface of the support structure above the recessed upper surface of the upwardly opening container-shaped bottom electrode received therein;
forming funnel device material along the exposed vertically extending surface of the support structure above the upper surface of the support structure and within the interior region of the upwardly open container-shaped bottom electrode;
forming an insulating material over the funnel device material; the insulating material extends into the interior region of the upwardly opening container-shaped bottom electrode to narrow the interior region of the upwardly opening container-shaped bottom electrode;
forming an upper electrode within said narrowed interior region of said upwardly open container-shaped bottom electrode; the upper electrode, the insulating material, and the upwardly open container-shaped bottom electrode together form a plurality of capacitors; a kind of electronic device with high-pressure air-conditioning system
Forming a plate material extending across and coupling the upper electrodes to each other; the sheet material directly against the funnel device material; the funnel device material electrically couples the bottom electrode to the plate material and is configured to discharge at least a portion of excess charge from the upwardly opening container-shaped bottom electrode to the plate material.
12. The method of claim 11, wherein the insulating material is a ferroelectric insulating material.
13. The method of claim 11, wherein the funnel device material comprises one or more of Ti, ni, and Nb in combination with one or more of Ge, si, O, N and C.
14. The method of claim 11, wherein the forming of the funnel device material comprises:
depositing a first composition along the exposed vertically extending surface of the support structure above the upper surface of the support structure and within the interior region of the upwardly open container-shaped bottom electrode; the first composition has a first conductivity;
chemically modifying the first composition converts the first composition to a second composition having a second conductivity less than the first conductivity.
15. The method of claim 11, wherein the insulating material extends over the upper surface of the support structure, along the exposed vertically extending surface of the support structure, and within the interior region of the upwardly open container-shaped bottom electrode; and wherein the forming of the upper electrode comprises:
forming an upper electrode material over the insulating material; wherein the upper electrode material extends above the upper surface of the support structure, along the exposed vertically extending surface of the support structure, and within the interior region of the upwardly open container-shaped bottom electrode; the upper electrode material, the insulating material, the funnel device material, and the bottom electrode material together form an assembly; a kind of electronic device with high-pressure air-conditioning system
An upper surface of the assembly is polished to remove the upper electrode material from above the upper surface of the support structure.
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US15/843,278 US10650978B2 (en) | 2017-12-15 | 2017-12-15 | Methods of incorporating leaker devices into capacitor configurations to reduce cell disturb |
US15/843,278 | 2017-12-15 | ||
PCT/US2018/062811 WO2019118178A1 (en) | 2017-12-15 | 2018-11-28 | Methods of incorporating leaker devices into capacitor configurations to reduce cell disturb, and capacitor configurations incorporating leaker devices |
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