CN111479958A - Colored polypropylene fiber and preparation method thereof - Google Patents
Colored polypropylene fiber and preparation method thereof Download PDFInfo
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- CN111479958A CN111479958A CN201880083309.8A CN201880083309A CN111479958A CN 111479958 A CN111479958 A CN 111479958A CN 201880083309 A CN201880083309 A CN 201880083309A CN 111479958 A CN111479958 A CN 111479958A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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Abstract
A colored polypropylene fiber contains a component a of hindered phenol antioxidants and a component b of phosphite antioxidants and/or a component c of hindered amine antioxidants, wherein the component a accounts for 800-15000 ppm of the colored polypropylene fiber; the weight ratio of the component b to the component a is less than 0.80, and the component c accounts for 4000-50000 ppm of the colored polypropylene fiber. The colored polypropylene fiber has excellent oxidation resistance, less cracking heat and wide application.
Description
The invention relates to a colored polypropylene fiber with good oxidation resistance and a preparation method thereof.
Polypropylene fibers are widely used because of their light weight and quick drying. However, polypropylene is subject to oxidative decomposition under the action of light and heat to generate alkyl radicals, and the reaction continues. By this chain reaction called autoxidation cycle, polypropylene is autooxidatively cracked, and at the same time, the cracking reaction is an exothermic reaction, and the polypropylene is melted, fuming or even burned under the action of self-heating.
In order to reduce the problem of oxidative heat generation of polypropylene, the main measure in the prior art is to add an antioxidant. For example, patent CN02112743.3 discloses a transparent polypropylene composition, in which phenolic and phosphonite or sulfuric acid antioxidants are added to improve the antioxidant property of polypropylene. However, unlike transparent polypropylene, colored polypropylene has poorer oxidation resistance, and colorants such as carbon black and the like in colored polypropylene have adsorption effect on antioxidants, which affects the distribution of the antioxidants in the polypropylene and weakens the effect of the antioxidants.
Disclosure of Invention
The invention aims to provide a colored polypropylene fiber with good oxidation resistance.
The technical solution of the invention is as follows:
the colored polypropylene fiber contains a component a of hindered phenol antioxidants and a component b of phosphite antioxidants and/or a component c of hindered amine antioxidants, wherein the component a accounts for 800-15000 ppm of the colored polypropylene fiber, preferably 1000-8000 ppm of the colored polypropylene fiber; when the component b is contained, the weight ratio of the component b to the component a is less than 0.80, preferably more than or equal to 0.20 and less than 0.80; when the component c is contained, the component c accounts for 4000 to 50000ppm, preferably 4000 to 20000ppm of the colored polypropylene fiber.
The colored polypropylene fiber preferably contains the component a, the component b and the component c at the same time.
The component a is preferably at least one of pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], octadecyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, 1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene or 1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione as a hindered phenol antioxidant.
The phosphite antioxidant of the component b is preferably poly (dipropylene glycol) phenyl phosphite; bis (2, 6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphate; tris (2, 4-di-tert-butylphenyl) phenyl phosphite; bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite; at least one of tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite and 3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5] undecane.
The component c hindered amine antioxidant is preferably poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino group]]-1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino group]-1, 6-hexamethylene-bis [ (2,2,6, 6-tetramethyl-4-piperidyl) imino group]}; poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate; n is a radical ofⅠ，NⅡ，NⅢ，NⅣ-tetrakis (2, 4-bis ((N-1, 2,2,6, 6-pentamethyl-4-piperidinyl) -N-butylamino) -1,3, 5-triazin-6-yl) -4, 7-diazodecane-1, 10-diamine; bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate or 1,3, 5-triazine-2, 4, 6-triamine-N-N' - [1, 2-ethanediylbis [ [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] amino]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)]At least one of (1).
The invention also discloses a preparation method of the colored polypropylene fiber, which comprises the steps of uniformly mixing polypropylene with the component a hindered phenol antioxidant and the component b phosphite antioxidant and/or the component c hindered amine antioxidant, extruding and granulating to obtain a colored polypropylene mixture, and carrying out melt spinning on the colored polypropylene mixture to obtain the colored polypropylene fiber, wherein the component a accounts for 800-15000 ppm of the polypropylene mixture, and when the component b is added, the weight ratio of the component b to the component a is less than 0.80; when the component c is added, the component c accounts for 4000-50000 ppm of the polypropylene mixture.
The colored polypropylene fiber has excellent oxidation resistance, less cracking heat and wide application.
Polypropylene itself is unstable in structure, easily oxidized, and the oxidation process is accompanied by a heat generation phenomenon, thus affecting the safety of products using polypropylene fibers. Although the addition of antioxidants can improve the antioxidant properties of polypropylene, for colored polypropylene containing colorants, which are less resistant to oxidation, the effect of the antioxidants can be affected due to the adsorption of the colorants to the antioxidants. And excessive addition of the antioxidant can reduce the physical properties of the polypropylene product and can cause the colored polypropylene product to be easily yellowed.
The colored polypropylene fiber provided by the invention has excellent oxidation resistance, and the physical properties of the fiber, such as strength, are also good, and yellowing is not easy to occur.
The colored polypropylene fiber contains a component a of hindered phenol antioxidant and a component b of phosphite antioxidant and/or a component c of hindered amine antioxidant, wherein the component a accounts for 800-15000 ppm of the colored polypropylene fiber. When the polypropylene fiber contains component b, the weight ratio of component b to component a is less than 0.80; when the polypropylene fiber contains the component c, the component c accounts for 4000-50000 ppm of the colored polypropylene fiber.
During the oxidative decomposition of polypropylene, alkyl radicals and peroxy radicals are formed, wherein the alkyl radicals are further oxidized to peroxy radicals. The peroxide free radical is unstable, and a part of the peroxide free radical can further generate hydroperoxide to accelerate the oxidative decomposition of the polypropylene. The component a hindered phenol antioxidant can capture peroxide free radicals, the component b phosphite antioxidant can capture hydroperoxides, and the component c hindered amine antioxidant can capture peroxide free radicals and alkyl free radicals simultaneously.
In order to obtain colored polypropylene fibers with certain oxidation resistance, the content of the component a hindered phenolic antioxidant in the fibers must be more than 800ppm, otherwise, the oxidation resistance of the colored polypropylene fibers is difficult to improve after most of the component a hindered phenolic antioxidant is adsorbed by the colorant in the fibers, and meanwhile, the oxidation resistance of the colorant is poor, which can further deteriorate the oxidation resistance of the colored polypropylene fibers. When the content of the hindered phenol antioxidant of the component a in the colored polypropylene fiber is higher than 15000ppm, the preparation cost of the colored polypropylene fiber is increased, and meanwhile, the excessive hindered phenol antioxidant of the component a can be oxidized in the air to generate quinone compounds, so that the colored polypropylene fiber is yellowed.
The content of the hindered phenol antioxidant in the component a in the colored polypropylene fiber is preferably 1000-8000 ppm.
The phosphite antioxidant of the component b has the function of capturing hydroperoxide, and can effectively inhibit the oxidation of the hindered phenol antioxidant of the component a in the air, thereby inhibiting the yellowing of polypropylene. In order to achieve the above effects simultaneously, the weight ratio of the component b to the component a in the colored polypropylene fiber is less than 0.80. When the weight ratio of the component b to the component a is more than or equal to 0.80, more component b phosphite antioxidant remains in the colored polypropylene fiber relative to the component a hindered phenol antioxidant, and because no hydroperoxide for catching exists, the part of the component b phosphite antioxidant does not play a role in antioxidation, but the preparation cost of the colored polypropylene fiber is increased, and meanwhile, the strength of the polypropylene fiber is reduced due to a large amount of the component b phosphite antioxidant. When the component b is a phosphite antioxidant, the weight ratio of the component b to the component a in the colored polypropylene fiber of the invention is preferably more than or equal to 0.20 and less than 0.80.
The component c is hindered amine antioxidant which has the function of capturing alkyl free radicals and peroxidation free radicals. When the content of the component c hindered amine antioxidant in the colored polypropylene fiber is lower than 4000ppm, alkyl free radicals and peroxide free radicals cannot be effectively captured, excessive alkyl free radicals can be further oxidized into peroxide free radicals, and the peroxide free radicals can generate a large amount of hydroperoxide, so that the oxidation of polypropylene is further accelerated, and the oxidation resistance of the colored polypropylene fiber cannot be improved. When the content of the hindered amine antioxidant in the component c is more than 50000ppm, the strength of the colored polypropylene fiber is reduced, and the cost is increased. When the component c is a hindered amine antioxidant, the content of the component c in the colored polypropylene fiber is preferably 4000-20000 ppm.
The colored polypropylene fiber contains a component a of hindered phenol antioxidant, a component b of phosphite antioxidant and/or a component c of hindered amine antioxidant, and three conditions exist: the first component contains a component a and a component b, the second component contains a component a and a component c, and the third component contains a component a, a component b and a component c. The third case is preferable, namely, the colored polypropylene fiber simultaneously contains a component a hindered phenol antioxidant, a component b phosphite ester antioxidant and a component c hindered amine antioxidant.
The hindered phenol antioxidant of component a is not particularly limited, and may be at least one alcohol ester of β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid methyl ester, N '-1, 6-hexylene-bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionamide ], (1,3, 5-tris- (3, 5-dicyclohexyl-4-hydroxybenzyl) isocyanurate, N' -bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl ] hydrazine, octadecyl 3- (3, 5-di-tert-butyl-4-hydroxy) propionate, 2 '-methylenebis (4-methyl-6-tert-butylphenol), 2, 6-di-tert-butyl-4-methylphenol, 4' -methylenebis (2, 6-di-tert-butylphenol), ethyl 2, 2-thiobis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate), tetra [ 42- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] tetra [3, 5-tert-butyl-4-hydroxyphenyl ] propionate ] tetra [3, 5-tert-butyl-4-hydroxyphenyl ] propan-4-1, 3, 5-trimethyl-1, 5-1-4-hydroxy-1, 5-1, 5-trimethyl-1-phenyl ] propan-5-1, 5-1-trimethyl-4-trimethyl-butyl-hydroxy-1-phenyl ] one, 5-1-4-tert-butyl-hydroxy-phenyl ] one, 5-4-trimethyl-butyl-phenyl ] one, 5-tert-phenyl ] benzene, 6-tert-butyl-4-butyl-tert-butyl-phenyl ] propan-4-phenyl ] one, 6-tert-phenyl, 6-tert-phenyl, 6-tert-butyl-tert-butyl-tert-phenyl, 2, 6.
The phosphite antioxidant of the component b is not particularly limited, and may be dimethyl phosphite, bis (2, 4-di-tert-butylphenyl) phenyl phosphite; tris (1,2,2,6, 6-pentamethylpiperidinol) phosphite; tris (nonylphenol) phosphite; bis (2, 6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite; bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite; tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite; didecyl phenyl phosphite; diphenyl isooctyl phosphite; poly (dipropylene glycol) phenyl phosphite; tris (2, 4-di-tert-butylphenyl) phosphite; 3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5] undecane; at least one of tribenzyl phosphite or tris (2-ethylhexyl) phosphite, with poly (dipropylene glycol) phenyl phosphite being preferred; bis (2, 6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphate; tris (2, 4-di-tert-butylphenyl) phosphite; bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite; at least one of tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite and 3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5] undecane.
The hindered amine antioxidant of component c is not particularly limited, and may be bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate; dodecyl 3- (2,2,6, 6-tetramethylpiperidin-4-amino) propionate; 2- (3',5' -di-tert-butyl-2 ' -hydroxyphenyl) -5-chlorobenzotriazole; 2,4, 6-trichloro-1, 3, 5-triazine; n-butyl-1-butylamine; n-butyl-2, 2,6, 6-tetramethyl-4-piperidinamine; poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino group]]-1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino group]-1, 6-hexamethylene-bis [ (2,2,6, 6-tetramethyl-4-piperidyl) imino group]}; poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate; n is a radical ofⅠ，NⅡ，NⅢ，NⅣ-tetrakis (2, 4-bis ((N-1, 2,2,6, 6-pentamethyl-4-piperidinyl) -N-butylamino) -1,3, 5-triazin-6-yl) -4, 7-diazodecane-1, 10-diamine; bis (2,2,6, 6-tetramethylpiperidinyl) sebacate or 1,3, 5-triazine-2, 4, 6-triamine-N' "- [1, 2-ethanediylbis [ [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-penta- ] -1, 2-ethanediylbis [ ]Methyl-4-piperidinyl) amino]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)](ii) a Bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate or 1,3, 5-triazine-2, 4, 6-triamine-N-N' - [1, 2-ethanediylbis [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperazinyl) amino group]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)]At least one of (1). Among them, poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino group is preferred]]-1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino group]-1, 6-hexamethylene-bis [ (2,2,6, 6-tetramethyl-4-piperidyl) imino group]}; poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate; n, N II, N III, N IV-four (2, 4-two ((N-1, 2,2,6, 6-five methyl-4-piperidyl) -N-butylamino) -1,3, 5-three triazine-6-yl) -4, 7-diazo decane-1, 10-diamine; 1,3, 5-triazine-2, 4, 6-triamine-N' "- [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidinyl) amino group]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)]Or bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate. Among them, the component c is more preferably 1,3, 5-triazine-2, 4, 6-triamine-N-N' - [1, 2-ethanediylbis [ [ [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino group]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)]When the spinning composition is used in combination with the component a and the component b, the spinning temperature is 260 ℃ or lower.
The antioxidant of the present invention may be used in combination with a hydroxylamine, and octacosylhydroxylamine may be mentioned.
The invention also discloses a preparation method of the colored polypropylene fiber, which comprises the steps of uniformly mixing polypropylene with the component a hindered phenol antioxidant and the component b phosphite antioxidant and/or the component c hindered amine antioxidant, extruding and granulating to obtain a colored polypropylene mixture, and carrying out melt spinning on the colored polypropylene mixture to obtain the colored polypropylene fiber, wherein the component a accounts for 800-15000 ppm of the polypropylene mixture, and when the component b is added, the weight ratio of the component b to the component a is less than 0.80; when the component c is added, the component c accounts for 4000-50000 ppm of the polypropylene mixture.
The colored polypropylene fiber can be obtained by blending the master batch of the colorant in the polypropylene chip and then spinning, or can be obtained by blending the polypropylene chip and the polyester and then spinning and dyeing.
The colorant can be pigment or dye, the invention does not limit the kind of the pigment and dye, it can be polymer used various pigments and dyes, such as carbon black, titanium dioxide, cadmium RED, phthalocyanine green, phthalocyanine blue, water solid RED, zinc yellow, hansa yellow, TERATOP B L UE NFB GR, TERATOP RED NFR, TERATOP YE LL OW NFG, TERASI L B L ACK WW-KSN, etc.
The colored polypropylene fiber has excellent oxidation resistance, good physical properties and difficult yellowing due to the mutual synergistic effect of the antioxidants of different components.
The test method related by the invention comprises the following steps:
(1) oxidation resistance heat test
The method comprises the steps of preparing colored polypropylene fibers into a tubular braid, pretreating the tubular braid according to JIS L0217103, testing and evaluating the tubular braid according to an acidification heating test method (acceleration method) of the polypropylene fibers (Japan chemical fiber Association method), judging that the polypropylene fibers are qualified in oxidation heat resistance if the test time reaches 100 hours, and judging that the polypropylene fibers are unqualified.
(2) Yellowing value test of fiber
Putting an NOx gas generating agent (85% phosphoric acid and 2% nitrous acid aqueous solution) into a closed container, then putting a sample and blue standard dyed cloth into the container, replacing the blue standard dyed cloth when the color of the blue standard dyed cloth fades to the number 3 of the standard gray scale plate, taking out the sample when the color of the blue standard dyed cloth reaches the number 3 of the standard gray scale plate again, cleaning for 2 times, and airing. The yellowing value was determined by a Datacolor 650 spectrophotometer.
(3) Strength testing of fibers
The test is carried out by a strength-elongation tester. The test speed was 200mm/min and the distance between the two clamps was 200 mm.
(4) Oxidation and Heat Generation Property of fiber (simple method/wt%)
Weighing a fiber sample, weighing the fiber sample to obtain W1, heating the fiber sample to 160 ℃ at a speed of 30 ℃/min by using a differential scanning calorimeter under the conditions that the gas atmosphere is compressed air and the gas flow is 60 +/-0.05 ml, keeping the temperature for 22 hours, and obtaining the weight reduction rate by analysis, wherein if the weight reduction rate is less than 10 wt%, the fiber is judged to be qualified by a Keken method. The lower the weight loss rate, the better the oxidation resistance.
(5) Value of tubular knit L
The L values were determined for the tube knit by Datacolor 650 spectrophotometer.
(6) Testing of antioxidant type and content
Dissolving the sample with solvent, centrifuging to obtain antioxidant-containing mixture, measuring the mixture with HP L C, and analyzing by map to obtain antioxidant type and content.
The antioxidant referred to in the examples of the present invention is abbreviated as follows.
A component a:
(1)1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione (abbreviation: antioxidant 1790);
(2) pentaerythrityl tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] (abbreviated as antioxidant 1010);
(3)1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene (abbreviated as antioxidant 330);
(4) β methyl (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate (abbreviation: component a 1);
(5) n, N' -bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl ] hydrazine (abbreviated as antioxidant 1024);
(6)3, 9-bis [1, 1-dimethyl-2- [ (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy ] ethyl ] -2,4,8, 10-tetraoxaspiro [5.5] undecane (abbreviated: AO 80);
(7)2,2' -methylenebis (4-methyl-6-tert-butylphenol) (abbreviation: antioxidant 2246);
(8)2, 6-di-tert-butyl-4-methylphenol (abbreviated as antioxidant BHT).
(9) N, N' -1, 6-hexylene-bis [3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionamide ] (abbreviated as antioxidant 1098).
And (b) component b:
(1) poly (dipropylene glycol) phenyl phosphite (abbreviated as antioxidant PDP);
(2)3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5] undecane (abbreviated as antioxidant 619);
(3) tris (2, 4-di-t-butylphenyl) phosphite (abbreviated as antioxidant 168);
(4) tris (1,2,2,6, 6-pentamethylpiperidinol) phosphite (abbreviation: component b 1);
(5) bis (2,4, 6-tri-t-butylphenyl) pentaerythritol diphosphite (abbreviated as antioxidant 633);
(6) bis (2, 4-di-tert-butylphenyl) phenyl phosphite (abbreviated as component b 2).
And (c) component:
(1) poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imino ] } (abbreviation: HS 944);
(2)NⅠ，NⅡ，NⅢ，NⅣtetrakis (2, 4-bis ((N-1, 2,2,6, 6-pentamethyl-4-piperidinyl) -N-butylamino) -1,3, 5-triazin-6-yl) -4, 7-diazodecane-1, 10-diamine (abbreviation: component c 1);
(3) poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate (abbreviation: UV 622);
(4) bis (2,2,6, 6-tetramethylpiperidyl) sebacate (abbreviated as TINUVIN 770);
(5) dodecyl 3- (2,2,6, 6-tetramethylpiperidin-4-ylamino) propionate (abbreviation: component c 2);
(6)2,4, 6-trichloro-1, 3, 5-triazine (abbreviated: component c 3);
(7) n-butyl-2, 2,6, 6-tetramethyl-4-piperidinamine (abbreviated: component c 4);
(8)1,3, 5-triazine-2, 4, 6-triamine-N-N ' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidinyl) amino ] -1,3, 5-triaza-zin-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N ' -dibutyl-N ', N ' -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl) ] (abbreviation: HA L S119);
(9) bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate (abbreviated as: UV-292);
(10) bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate (abbreviation: L A-81).
Example 1
Adding polypropylene chips, a component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), a component b (poly (dipropylene glycol) phenyl phosphite), a component c (poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6,6, -tetramethylpiperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imino ] }) and a colorant master batch (black) into a mixer for mixing and extrusion granulation, wherein the component a accounts for 3000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.60, and the component c accounts for 13000ppm of the polypropylene mixture; finally, the granules are melt-spun to prepare the colored polypropylene fiber.
Example 2
Slicing polypropylene and preparing component a (tetra [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol ester), component b (3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5]]Undecane) and component c (N)Ⅰ，NⅡ，NⅢ，NⅣ-a number of four (2,adding 4-bis ((N-1, 2,2,6, 6-pentamethyl-4-piperidyl) -N-butylamino) -1,3, 5-triazine-6-yl) -4, 7-diazodecane-1, 10-diamine) and colorant master batch (black) into a mixing roll for mixing and extruding and granulating, wherein the component a accounts for 15000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.20, and the component c accounts for 8000ppm of the polypropylene mixture; finally, the granules are melt-spun to prepare the colored polypropylene fiber.
Example 3
Adding polypropylene slices, a component a (1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene), a component b (tris (2, 4-di-tert-butylphenyl) phosphite) and colorant master batches (black) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1100ppm of the polypropylene mixture, and the weight ratio of the component b to the component a is 0.75; finally, the granules are melt-spun to prepare the colored polypropylene fiber.
Example 4
Adding polypropylene chips, component a (β - (3, 5-di-tert-butyl-4-hydroxyphenyl) methyl propionate), component c (poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate) and colorant master batch (black) into a mixing roll, mixing, extruding and granulating, wherein the component a accounts for 6000ppm of the polypropylene mixture, the component c accounts for 10000ppm of the polypropylene mixture, and finally carrying out melt spinning on the granules to prepare the colored polypropylene fiber.
Example 5
Adding polypropylene slices, a component a (N, N' -1, 6-hexamethylene-bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionamide ]) and a component b (bis (2, 4-di-tert-butylphenyl) phenyl phosphite) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 10000ppm of the polypropylene mixture, and the weight ratio of the component b to the component a is 0.10; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 6
Adding polypropylene slices, a component a (N, N' -bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionyl ] hydrazine) and a component b (tris (1,2,2,6, 6-pentamethylpiperidinol) phosphite) into a mixing roll, mixing, extruding and granulating, wherein the component a accounts for 6000ppm of the polypropylene mixture, and the weight ratio of the component b to the component a is 0.80; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 7
Adding polypropylene slices, a component a (3, 9-bis [1, 1-dimethyl-2- [ (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy ] ethyl ] -2,4,8, 10-tetraoxaspiro [5.5] undecane) and a component c (bis (1,2,2,6, 6-pentamethyl-4-piperidyl) sebacate) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1100ppm of the polypropylene mixture, and the component c accounts for 5000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 8
Adding polypropylene chips, a component a (3, 9-bis [1, 1-dimethyl-2- [ (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy ] ethyl ] -2,4,8, 10-tetraoxaspiro [5.5] undecane) and a component c (3- (2,2,6, 6-tetramethylpiperidine-4-amino) dodecyl propionate) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 15000ppm of the polypropylene mixture, and the component c accounts for 13000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 9
Adding polypropylene chips, a component a (2,2' -methylenebis (4-methyl-6-tert-butylphenol)), a component b (bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite) and a component c (2,4, 6-trichloro-1, 3, 5-triazine) into a mixing roll, mixing and extruding the mixture to granulate, wherein the component a accounts for 7000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.50, and the component c accounts for 5000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 10
Adding polypropylene chips, a component a (2, 6-di-tert-butyl-4-methylphenol), a component b (bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite) and a component c (N-butyl-2, 2,6, 6-tetramethyl-4-piperidylamine) into a mixing roll, mixing, extruding and granulating, wherein the component a accounts for 1300ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.75, and the component c accounts for 15000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 11
Adding polypropylene slices, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), a component b (tri (2, 4-di-tert-butylphenyl) phosphite) and a component c (bis (2,2,6, 6-tetramethylpiperidyl) sebacate) into a mixing mill for mixing and extrusion granulation, wherein the component a accounts for 1200ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.60, and the component c accounts for 50000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 12
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (tris (2, 4-di-tert-butylphenyl) phosphite) and component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] -1,3, 5-tria-mozin-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', n' -bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1200ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.75, and the component c accounts for 8000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 13
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (tris (2, 4-di-tert-butylphenyl) phosphite) and component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] -1,3, 5-tria-mozin-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', n' -bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 4000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.60, and the component c accounts for 5200ppm of the polypropylene mixture; finally, the granules and the colorant master batch (blue) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 14
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (tris (2, 4-di-tert-butylphenyl) phosphite) and component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] -1,3, 5-tria-mozin-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', n' -bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 4500ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.50, and the component c accounts for 5200ppm of the polypropylene mixture; finally, the granules and the colorant master batch (blue) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 15
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidinyl) amino ] -1,3, 5-tria-zine-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', N "-bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 7000ppm of the polypropylene mixture, and the component c accounts for 5200ppm of the polypropylene mixture; finally, the granules and the colorant master batch (red) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 16
Adding polypropylene slices, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione) and a component b (tri (2, 4-di-tert-butylphenyl) phosphite) into a mixing roll, mixing, extruding and granulating, wherein the component a accounts for 10000ppm of the polypropylene mixture, and the weight ratio of the component b to the component a is 0.10; finally, the granules and the colorant master batch (red) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 17
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidinyl) amino ] -1,3, 5-tria-zine-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', N "-bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 4000ppm of the polypropylene mixture, and the component c accounts for 4000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (yellow) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 18
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidinyl) amino ] -1,3, 5-tria-zine-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', N "-bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1000ppm of the polypropylene mixture, and the component c accounts for 50000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (blue) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 19
Adding polypropylene slices, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione) and a component c (bis (2,2,6, 6-tetramethylpiperidyl) sebacate) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1200ppm of the polypropylene mixture, and the component c accounts for 50000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (red) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 20
Adding polypropylene slices, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), a component b (tri (2, 4-di-tert-butylphenyl) phosphite) and a component c (bis (2,2,6, 6-tetramethylpiperidyl) sebacate) into a mixing mill for mixing and extrusion granulation, wherein the component a accounts for 850ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.70, and the component c accounts for 50000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (white) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Example 21
Adding polypropylene chips, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), a component b (tri (2, 4-di-tert-butylphenyl) phosphite) and a component c (bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate) into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 4500ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.65, and the component c accounts for 5200ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber.
Comparative example 1
Adding polypropylene chips, a component a (1,3, 5-tri (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), a component b (poly (dipropylene glycol) phenyl phosphite), a component c (poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imino ] }) and a colorant master batch (black) into a mixer for mixing and extrusion granulation, wherein the component a accounts for 3000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 2.00, and the component c accounts for 50000ppm of the polypropylene mixture; finally, the granules are melt-spun to prepare the colored polypropylene fiber. The weight ratio of component b to component a is too large, and an excess of component b results in a low strength of the polypropylene fiber.
Comparative example 2
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (poly (dipropylene glycol) phenyl phosphite) and component c (poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imino ] }) are fed into a mixer for mixing and extrusion granulation, wherein component a accounts for 100ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.70, and the component c accounts for 5000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber. The content of component a is too small, resulting in poor antioxidant properties of the polypropylene fiber.
Comparative example 3
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (poly (dipropylene glycol) phenyl phosphite) and component c (poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino ] ] -1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino ] -1, 6-hexamethylene [ (2,2,6, 6-tetramethyl-4-piperidyl) imino ] }) are fed into a mixer for mixing and extrusion granulation, wherein component a accounts for 25000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.10, and the component c accounts for 80000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber. The content of component c is too large, resulting in low strength of the polypropylene fiber.
Comparative example 4
Polypropylene chips, component a (1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione), component b (tris (2, 4-di-tert-butylphenyl) phosphite) and component c (1,3, 5-triazine-2, 4, 6-triamine-N "' - [1, 2-ethanediylbis [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] -1,3, 5-tria-mozin-2-yl ] imino ]3, 1-propanediyl ] ] -bis [ N ' -N" -dibutyl-N ', n' -bis (1,2,2,6, 6-pentamethyl-4-piperidyl) ]) is added into a mixing roll for mixing and extrusion granulation, wherein the component a accounts for 1000ppm of the polypropylene mixture, the weight ratio of the component b to the component a is 0.75, and the component c accounts for 3000ppm of the polypropylene mixture; finally, the granules and the colorant master batch (black) are mixed and then melt-spun to prepare the colored polypropylene fiber. The content of component c is too small, resulting in poor antioxidant properties of the polypropylene fiber.
Claims (9)
- A colored polypropylene fiber is characterized in that: the polypropylene fiber contains a component a of hindered phenol antioxidant and a component b of phosphite antioxidant and/or a component c of hindered amine antioxidant, wherein the component a accounts for 800-15000 ppm of the colored polypropylene fiber; when the component b is contained, the weight ratio of the component b to the component a is less than 0.80; when the component c is contained, the component c accounts for 4000-50000 ppm of the colored polypropylene fiber.
- The colored polypropylene fiber according to claim 1, wherein: the component a accounts for 1000-8000 ppm of the colored polypropylene fiber.
- Coloured polypropylene fibres according to claim 1 or 2, characterised in that: the weight ratio of the component b to the component a is more than or equal to 0.20 and less than 0.80.
- Coloured polypropylene fibres according to claim 1 or 2, characterised in that: the component c accounts for 4000-20000 ppm of the colored polypropylene fiber.
- The colored polypropylene fiber according to claim 1, wherein: the colored polypropylene fiber contains a component a, a component b and a component c.
- The colored polypropylene fiber of claim 1, wherein the component a comprises at least one of pentaerythrityl tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], octadecyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, 1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene or 1,3, 5-tris (4-tert-butyl-3-hydroxy-2, 6-dimethylbenzyl) -1,3, 5-triazine-2, 4,6- (1H,3H,5H) -trione.
- The colored polypropylene fiber according to claim 1, wherein: the phosphite antioxidant of the component b is poly (dipropylene glycol) phenyl phosphite; bis (2, 6-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphate; tris (2, 4-di-tert-butylphenyl) phosphite; bis (2,4, 6-tri-tert-butylphenyl) pentaerythritol diphosphite; at least one of tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite and 3, 9-dioctadecyloxy-2, 4,8, 10-tetraoxy-3, 9-diphosphospiro [5.5] undecane.
- The colored polypropylene fiber according to claim 1, wherein: the component c of hindered amine antioxidant is poly { [6- [ (1,1,3, 3-tetramethylbutyl) amino]]-1,3, 5-triazine-2, 4- [ (2,2,6, 6-tetramethyl-piperidyl) imino group]-1, 6-hexamethylene-bis [ (2,2,6, 6-tetramethyl-4-piperidyl) imino group]}; poly (4-hydroxyethyl-2, 2,6, 6-tetramethyl-1-piperidineethanol) succinate; n is a radical ofⅠ，NⅡ，NⅢ，NⅣ-tetrakis (2, 4-bis ((N-1, 2,2,6, 6-pentamethyl-4-piperidinyl) -N-butylamino) -1,3, 5-triazin-6-yl) -4, 7-diazodecane-1, 10-diamine; bis (1-undecane-2, 2,6, 6-tetramethylpiperidin-4-yl) carbonate or 1,3, 5-triazine-2, 4, 6-triamine-N-N' - [1, 2-ethanediylbis [ [ [ [ [4, 6-bis [ butyl (1,2,2,6, 6-pentamethyl-4-piperidyl) amino ] amino]-1,3, 5-Tridumosin-2-yl]Imino radical]3, 1-propanediyl radical]]-bis [ N '-N "-dibutyl-N', N" -bis (1,2,2,6, 6-pentamethyl-4-piperidinyl)]At least one of (1).
- A method for preparing colored polypropylene fiber according to claim 1, which comprises the steps of: uniformly mixing polypropylene with a component a hindered phenol antioxidant and a component b phosphite antioxidant and/or a component c hindered amine antioxidant, extruding and granulating to obtain a colored polypropylene mixture, and then carrying out melt spinning on the colored polypropylene mixture to obtain a colored polypropylene fiber, wherein the component a accounts for 800-15000 ppm of the polypropylene mixture, and when the component b is added, the weight ratio of the component b to the component a is less than 0.80; when the component c is added, the component c accounts for 4000-50000 ppm of the polypropylene mixture.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810029575 | 2018-01-12 | ||
| CN2018100295754 | 2018-01-12 | ||
| PCT/CN2018/123330 WO2019137197A1 (en) | 2018-01-12 | 2018-12-25 | Coloured polypropylene fibre and preparation method therefor |
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| CN111479958A true CN111479958A (en) | 2020-07-31 |
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| JP (1) | JP7180675B2 (en) |
| CN (1) | CN111479958A (en) |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0184191A2 (en) * | 1984-12-03 | 1986-06-11 | Phillips Petroleum Company | Stabilization of polyolefins |
| US4965301A (en) * | 1984-12-03 | 1990-10-23 | Phillips Petroleum Company | Stabilization of polyolefins |
| WO2002031237A1 (en) * | 2000-10-11 | 2002-04-18 | Sunoco, Inc. (R&M) | High strength spunbond fabric |
| US20100081741A1 (en) * | 2005-07-29 | 2010-04-01 | Chemtura Europe Gmbh | Colour stabilised polyolefins |
| CN103774265A (en) * | 2014-02-17 | 2014-05-07 | 北京化工大学 | Antibacterial fiber and preparation method thereof |
| CN106319665A (en) * | 2015-06-15 | 2017-01-11 | 东丽纤维研究所（中国）有限公司 | Colored polypropylene fiber and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0621205B2 (en) * | 1990-10-24 | 1994-03-23 | チッソ株式会社 | Crystalline polypropylene composition |
| JPH05156094A (en) * | 1991-12-11 | 1993-06-22 | Sumitomo Chem Co Ltd | Stabilized polyolefin composition |
-
2018
- 2018-12-25 CN CN201880083309.8A patent/CN111479958A/en active Pending
- 2018-12-25 TW TW107146994A patent/TW201930664A/en unknown
- 2018-12-25 JP JP2020538668A patent/JP7180675B2/en active Active
- 2018-12-25 WO PCT/CN2018/123330 patent/WO2019137197A1/en active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0184191A2 (en) * | 1984-12-03 | 1986-06-11 | Phillips Petroleum Company | Stabilization of polyolefins |
| US4965301A (en) * | 1984-12-03 | 1990-10-23 | Phillips Petroleum Company | Stabilization of polyolefins |
| WO2002031237A1 (en) * | 2000-10-11 | 2002-04-18 | Sunoco, Inc. (R&M) | High strength spunbond fabric |
| US20100081741A1 (en) * | 2005-07-29 | 2010-04-01 | Chemtura Europe Gmbh | Colour stabilised polyolefins |
| CN103774265A (en) * | 2014-02-17 | 2014-05-07 | 北京化工大学 | Antibacterial fiber and preparation method thereof |
| CN106319665A (en) * | 2015-06-15 | 2017-01-11 | 东丽纤维研究所（中国）有限公司 | Colored polypropylene fiber and preparation method thereof |
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|---|---|
| JP7180675B2 (en) | 2022-11-30 |
| TW201930664A (en) | 2019-08-01 |
| JP2021510177A (en) | 2021-04-15 |
| WO2019137197A1 (en) | 2019-07-18 |
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