CN111471305A - Preparation method of two-component heat-conducting gel capable of being rapidly cured at room temperature - Google Patents
Preparation method of two-component heat-conducting gel capable of being rapidly cured at room temperature Download PDFInfo
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Abstract
The invention relates to a preparation technology of an interface heat conduction material, and aims to provide a preparation method of a two-component heat conduction gel capable of being rapidly cured at room temperature. The method comprises the following steps: the preparation method of the two-component heat-conducting gel capable of being rapidly cured at room temperature is provided, and comprises the following steps: mixing and stirring vinyl silicone oil, a catalyst, a plasticizer and a silane coupling agent to obtain a liquid A; mixing and stirring vinyl silicone oil, hydrogen-containing silicone oil, a plasticizer and a silane coupling agent to obtain a liquid B; and respectively stirring, grinding and stirring the heat-conducting filler with the liquid A and the liquid B under a vacuum condition to obtain gel E and gel F, and packaging to obtain the double-component heat-conducting gel. The invention can greatly reduce the powder consumption under the same heat conductivity coefficient, radically reduce the metal ion quantity in the system and greatly enhance the activity of the catalyst in the two-component system; when the two components are mixed, the time required by curing the two components is greatly reduced, and the room temperature quick curing is achieved.
Description
Technical Field
The invention belongs to preparation and application of interface heat conduction materials, and particularly relates to a preparation method of a two-component heat conduction gel capable of being rapidly cured at room temperature.
Background
The interface heat conduction material plays an extremely important role in the fields of electronics, electricity, aviation, aerospace and other manufacturing industries and high technology. The heat-conducting gasket has excellent ageing resistance and oil separation resistance, so the market mainly takes the heat-conducting gasket as a main material. However, with the rapid development of the miniaturization of electronic equipment, the internal structure of the device is more and more complex, and the operable space is smaller and smaller, the traditional heat conducting gasket is difficult to meet the requirements due to the processing precision and the manual operation space, and at the moment, the heat conducting gel with better fluidity is required to meet the heat dissipation requirements of the special-shaped structure and the small space.
The two-component heat-conducting gel has the advantages of convenient construction and almost all the advantages of a heat-conducting gasket after being cured. However, the curing modes of the current two-component heat-conducting gel are all temperature-rising curing (>100 ℃), but some electronic components do not have the high-temperature-resistant condition. However, the curing time of the two-component heat-conducting gel at room temperature is very long, more than 24 hours are basically needed to achieve complete curing, and the fluidity of the gel in the curing process can cause pollution of the gel to other devices. While increasing the amount of catalyst in the system can reduce cure time, the effect is limited. The main reason is that the surface of the filler powder has a large amount of metal ions such as sodium, potassium and the like, and the existence of the metal ions can inhibit the activity of the catalyst. In the high heat conduction product, the proportion of the powder in the system is more than 90 percent, even more than 95 percent, and the influence of the metal ions on the surface of the powder on the catalyst is more obvious. In addition, the aging resistance of the system is greatly affected by the excessive dosage of the catalyst, and the service life of the product is greatly reduced as a result.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides a preparation method of a two-component heat-conducting gel capable of being rapidly cured at room temperature.
In order to solve the technical problem, the solution of the invention is as follows:
the preparation method of the two-component heat-conducting gel capable of being rapidly cured at room temperature is provided, and comprises the following steps:
(1) taking at least two of aluminum oxide, aluminum nitride, zinc oxide, boron nitride, aluminum hydroxide, silicon carbide, silicon dioxide, graphite, carbon fiber or carbon nano tube as inorganic heat-conducting powder for forming the composite heat-conducting filler; adding inorganic heat-conducting powder and sufficient ethanol water into a flask, and then hanging a stainless steel mesh frame filled with the graphene ion adsorption film in the mixed solution; carrying out condensation reflux treatment under magnetic stirring and heating conditions, taking out a stainless steel screen frame, and carrying out suction filtration on the mixture while the mixture is hot; cleaning the powder for several times by using hot deionized water, and then carrying out vacuum drying treatment on the powder to obtain the heat-conducting filler with the surface metal ions removed;
(2) weighing vinyl silicone oil, a catalyst, a plasticizer and a silane coupling agent according to the mass ratio of 100: 0.2-2: 0.5-5: 1-10; mixing and stirring to obtain liquid A;
(3) weighing vinyl silicone oil, hydrogen-containing silicone oil, a plasticizer and a silane coupling agent according to the mass ratio of 100: 2-50: 0.5-5: 1-10; mixing and stirring to obtain liquid B;
(4) adding the heat-conducting filler obtained in the step (1) and the liquid A into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid A is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture C; grinding the mixture C for several times by a three-roller machine, and then putting the mixture C into a planetary stirrer; stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel E, and packaging to obtain a first component of the two-component heat-conducting gel;
(5) adding the heat-conducting filler obtained in the step (1) and liquid B into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid B is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture D; grinding the mixture D for a plurality of times by a three-roller machine, and then putting the mixture into a planetary stirrer; and stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel F, and packaging to obtain a second component of the two-component heat-conducting gel.
In the invention, the mass ratio of ethanol to deionized water in the ethanol aqueous solution in the step (1) is 1: 10-10: 1.
In the invention, in the step (1), the monomer morphology of the inorganic heat-conducting powder comprises: spherical, spheroidal, cubic, platelet, linear, tubular, or platelet-assembled spherical; wherein the spherical particle size is 1-200 um, the quasi-spherical or cubic particle size is 0.1-5 um, the flaky particle size is 1-50 um, the linear or tubular particle size is 10-50 um, and the flaky assembled spherical particle size is 30-200 um; in the composite heat-conducting filler, the mass ratio of various monomers is as follows: 10-80% of spherical particles; 10-50% of spheroidal or cubic particles; 5 to 50 percent of flaky particles; 0 to 25 percent of linear or tubular particles; 0-30% of flake-shaped assembled spherical particles.
In the invention, in the step (1), the graphene ion adsorption film is prepared by oxidizing and reducing graphene and TiO by using a redox method2、ZnO2And (3) compounding the nano particles to obtain the enhanced ion adsorption film.
In the invention, in the step (1), the heating temperature during condensation reflux is 80-100 ℃.
In the invention, in the step (2) and the step (3), the vinyl silicone oil is double-ended vinyl silicone oil, the vinyl content of the vinyl silicone oil is 0.1-1%, and the viscosity of the vinyl silicone oil is 200-10000 cps.
In the invention, in the step (2) and the step (3), the plasticizer is methyl silicone oil with the viscosity of 100-1000 cps.
In the present invention, in the step (2) and the step (3), the silane coupling agent is vinyltriethoxysilane, vinyltrimethoxysilane or vinyltris (β -methoxyethoxy) silane.
In the present invention, in the step (2), the catalyst is a Karster catalyst.
In the invention, in the step (3), the hydrogen-containing silicone oil is double-end hydrogen-containing silicone oil or branched-chain hydrogen-containing silicone oil, the hydrogen content of the hydrogen-containing silicone oil is 0.05-0.5%, and the viscosity of the hydrogen-containing silicone oil is 100-500 cps.
Description of the inventive principles:
the graphene ion adsorption film has excellent chemical adsorption performance, and most metal ions in the heat-conducting filler are removed. Through reasonable structure building and particle size matching, the using amount of powder is reduced, a high heat conductivity coefficient is obtained under low filling, and the quantity of metal ions of a system is reduced fundamentally. The heat-conducting gel provided by the invention can ensure the mechanical strength of curing at room temperature and greatly shorten the curing time. The surface dry curing time can be realized within 5min and 10min of complete curing under the room temperature condition (25 ℃, 50 percent of humidity), and the service environment of the heat-conducting gel under the complex conditions of special-shaped structures and small spaces is met.
Compared with the prior art, the invention has the technical effects that:
1. according to the invention, by adopting the heat-conducting filler pretreatment technology and the excellent chemical adsorption performance of the graphene ion adsorption film, metal ions on the surface of the filler are removed to a greater extent.
2. According to the invention, through reasonable structure construction and particle size collocation, the using amount of powder can be reduced to a great extent under the same heat conductivity coefficient, the number of metal ions in the system is radically reduced, so that the activity of the catalyst in the final two-component system is greatly enhanced, and when two components are mixed, the time required by curing the two components can be greatly reduced, and the rapid curing at room temperature is achieved.
3. The invention adopts a mixing mode of combining a planetary mixer and a three-roller machine, can more uniformly disperse the filler in the matrix while destroying the matrix structure of the system as little as possible, further ensures the rapid curing of the system, and better increases the mechanical strength after curing.
4. The raw materials involved in the invention are easy to obtain, the preparation process is simple, the cost is low, and the method can be applied to large-scale industrial production.
Detailed Description
The following describes in detail specific embodiments of the present invention.
The invention provides a preparation method of a two-component heat-conducting gel capable of being rapidly cured at room temperature, which comprises the following steps:
(1) taking at least two of aluminum oxide, aluminum nitride, zinc oxide, boron nitride, aluminum hydroxide, silicon carbide, silicon dioxide, graphite, carbon fiber or carbon nano tube as inorganic heat-conducting powder for forming the composite heat-conducting filler; adding inorganic heat-conducting powder and sufficient ethanol water solution (the mass ratio of ethanol to deionized water is 1: 10-10: 1) into a flask, and then hanging a stainless steel mesh frame filled with a graphene ion adsorption film in the mixed solution; carrying out condensation reflux treatment under magnetic stirring and heating conditions of 80-100 ℃, taking out a stainless steel screen frame, and carrying out suction filtration on the hot mixture; cleaning the powder for several times by using hot deionized water, and then carrying out vacuum drying treatment on the powder to obtain the heat-conducting filler with the surface metal ions removed;
the monomer morphology of the inorganic heat-conducting powder comprises: spherical, spheroidal, cubic, platelet, linear, tubular, or platelet-assembled spherical; wherein the spherical particle size is 1-200 um, the quasi-spherical or cubic particle size is 0.1-5 um, the flaky particle size is 1-50 um, the linear or tubular particle size is 10-50 um, and the flaky assembled spherical particle size is 30-200 um; in the composite heat-conducting filler, the mass ratio of various monomers is as follows: 10-80% of spherical particles; 10-50% of spheroidal or cubic particles; 5 to 50 percent of flaky particles; 0 to 25 percent of linear or tubular particles; 0-30% of flake-shaped assembled spherical particles.
The graphene ion adsorption film is prepared by oxidizing and reducing graphene and TiO by using an oxidation-reduction method2、ZnO2The preparation method of the enhanced ion adsorption membrane obtained after the nano particles are compounded can be referred toThe introduction of the research on removing ions in water by using graphene materials is provided.
(2) Weighing vinyl silicone oil, a catalyst, a plasticizer and a silane coupling agent according to the mass ratio of 100: 0.2-2: 0.5-5: 1-10; mixing and stirring to obtain liquid A; weighing vinyl silicone oil, hydrogen-containing silicone oil, a plasticizer and a silane coupling agent according to the mass ratio of 100: 2-50: 0.5-5: 1-10; mixing and stirring to obtain liquid B;
the vinyl silicone oil is double-end vinyl silicone oil, the vinyl content of the vinyl silicone oil is 0.1-1%, the viscosity of the vinyl silicone oil is 200-10000 cps, the catalyst is a Kaster catalyst, the plasticizer is methyl silicone oil, the viscosity of the plasticizer is 100-1000 cps, the silane coupling agent is vinyl triethoxysilane, vinyl trimethoxysilane or vinyl tris (β -methoxyethoxy) silane, and the hydrogen-containing silicone oil is double-end hydrogen-containing silicone oil or branched chain hydrogen-containing silicone oil, the hydrogen content of the hydrogen-containing silicone oil is 0.05-0.5%, and the viscosity of the hydrogen-containing silicone oil is 100-500 cps.
(3) Adding the heat-conducting filler obtained in the step (1) and the liquid A into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid A is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture C; grinding the mixture C for several times by a three-roller machine, and then putting the mixture C into a planetary stirrer; stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel E, and packaging to obtain a first component of the two-component heat-conducting gel;
adding the heat-conducting filler obtained in the step (1) and liquid B into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid B is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture D; grinding the mixture D for a plurality of times by a three-roller machine, and then putting the mixture into a planetary stirrer; and stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel F, and packaging to obtain a second component of the two-component heat-conducting gel.
The gel of the two components is respectively filled into a pipe A and a pipe B in a 1:1 two-component rubber pipe, the rubber pipe A and the pipe B are connected with a rubber mixing pipe with at least 15 sections, and a sample is extruded by a two-component rubber gun or a two-component dispenser.
The following 8 examples are given to enable those skilled in the art to more fully understand the present invention, but are not intended to limit the invention in any way.
In each embodiment, a performance test is performed on the finally obtained two-component heat-conducting gel, and the performance test includes:
1. the thermal conductivity of the thermally conductive gel obtained in each example was measured in accordance with the standard of ASTM 5470; the results are shown in Table 2.
2. Testing the solidification time of the heat-conducting gel prepared in each embodiment by adopting a normal-temperature solidification method; the ambient temperature at the time of the test was 25 degrees celsius and the test results are shown in table 2.
3. The cured thermal conductive gels prepared in the examples were tested for hardness by baking at 150 ℃ for 24 hours, and the test results are shown in table 2.
Table 1 filler treatment examples
TABLE 2 two-component gel examples (where "fillers 1-8" are the fillers prepared in examples 1-8).
According to the test method, the commercial two-component heat-conducting gel product of the same type (produced by Begers) is tested, and the results are as follows:
| model number | Manufacturer of the product | Coefficient of thermal conductivity | Curing time at normal temperature |
| Gap Filler 3500 | Begges | 3.5W/m·K | Greater than 12 hours |
Therefore, the two-component heat-conducting gel provided by the invention has the performance of faster coagulation at room temperature while keeping the same heat-conducting performance, so that the two-component heat-conducting gel can meet the requirements of complex use environments.
Finally, it should also be noted that the above list is only a specific implementation example of the present invention. It is obvious that the invention is not limited to the above embodiment examples, but that many variations are possible. All modifications which can be derived or suggested by a person skilled in the art from the disclosure of the present invention are to be considered within the scope of the invention.
Claims (10)
1. A preparation method of a two-component heat-conducting gel capable of being rapidly cured at room temperature is characterized by comprising the following steps:
(1) taking at least two of aluminum oxide, aluminum nitride, zinc oxide, boron nitride, aluminum hydroxide, silicon carbide, silicon dioxide, graphite, carbon fiber or carbon nano tube as inorganic heat-conducting powder for forming the composite heat-conducting filler; adding inorganic heat-conducting powder and sufficient ethanol water into a flask, and then hanging a stainless steel mesh frame filled with the graphene ion adsorption film in the mixed solution; carrying out condensation reflux treatment under magnetic stirring and heating conditions, taking out a stainless steel screen frame, and carrying out suction filtration on the mixture while the mixture is hot; cleaning the powder for several times by using hot deionized water, and then carrying out vacuum drying treatment on the powder to obtain the heat-conducting filler with the surface metal ions removed;
(2) weighing vinyl silicone oil, a catalyst, a plasticizer and a silane coupling agent according to the mass ratio of 100: 0.2-2: 0.5-5: 1-10; mixing and stirring to obtain liquid A;
(3) weighing vinyl silicone oil, hydrogen-containing silicone oil, a plasticizer and a silane coupling agent according to the mass ratio of 100: 2-50: 0.5-5: 1-10; mixing and stirring to obtain liquid B;
(4) adding the heat-conducting filler obtained in the step (1) and the liquid A into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid A is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture C; grinding the mixture C for several times by a three-roller machine, and then putting the mixture C into a planetary stirrer; stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel E, and packaging to obtain a first component of the two-component heat-conducting gel;
(5) adding the heat-conducting filler obtained in the step (1) and liquid B into a planetary mixer together, wherein the mass ratio of the heat-conducting filler to the liquid B is 1: 2-15: 1; stirring under the condition of continuous vacuum pumping to obtain a mixture D; grinding the mixture D for a plurality of times by a three-roller machine, and then putting the mixture into a planetary stirrer; and stirring for 60-180 min under the condition of continuous vacuum pumping to obtain gel F, and packaging to obtain a second component of the two-component heat-conducting gel.
2. The method according to claim 1, wherein in the step (1), the mass ratio of the ethanol to the deionized water in the ethanol aqueous solution is 1: 10-10: 1.
3. The method according to claim 1, wherein in the step (1), the monomer morphology of the inorganic thermal conductive powder comprises: spherical, spheroidal, cubic, platelet, linear, tubular, or platelet-assembled spherical; wherein the spherical particle size is 1-200 um, the quasi-spherical or cubic particle size is 0.1-5 um, the flaky particle size is 1-50 um, the linear or tubular particle size is 10-50 um, and the flaky assembled spherical particle size is 30-200 um; in the composite heat-conducting filler, the mass ratio of various monomers is as follows: 10-80% of spherical particles; 10-50% of spheroidal or cubic particles; 5 to 50 percent of flaky particles; 0 to 25 percent of linear or tubular particles; 0-30% of flake-shaped assembled spherical particles.
4. The method of claim 1,in the step (1), the graphene ion adsorption film is prepared by oxidizing and reducing graphene and TiO by using a redox method2、ZnO2And (3) compounding the nano particles to obtain the enhanced ion adsorption film.
5. The method according to claim 1, wherein the heating temperature in the condensation reflux in the step (1) is 80 to 100 ℃.
6. The method as claimed in claim 1, wherein in the step (2) and the step (3), the vinyl silicone oil is a double-ended vinyl silicone oil, the vinyl content of the vinyl silicone oil is 0.1-1%, and the viscosity of the vinyl silicone oil is 200-10000 cps.
7. The method as claimed in claim 1, wherein in the step (2) and the step (3), the plasticizer is methyl silicone oil with a viscosity of 100 to 1000 cps.
8. The method according to claim 1, wherein in the step (2) and the step (3), the silane coupling agent is vinyltriethoxysilane, vinyltrimethoxysilane or vinyltris (β -methoxyethoxy) silane.
9. The method according to claim 1, wherein in the step (2), the catalyst is a Karster catalyst.
10. The method according to claim 1, wherein in the step (3), the hydrogen-containing silicone oil is double-ended hydrogen-containing silicone oil or branched hydrogen-containing silicone oil, the hydrogen content of the hydrogen-containing silicone oil is 0.05-0.5%, and the viscosity of the hydrogen-containing silicone oil is 100-500 cps.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112322042A (en) * | 2020-11-17 | 2021-02-05 | 广东和润新材料股份有限公司 | High-thermal-conductivity single-component heat-conducting gel and preparation method thereof |
| CN112985624A (en) * | 2021-02-24 | 2021-06-18 | 上海军辉信息技术有限公司 | Building intelligent monitoring system for weak current engineering |
| CN113897066A (en) * | 2021-11-17 | 2022-01-07 | 浙江商林科技股份有限公司 | High-thermal-conductivity bi-component heat-conducting gel and preparation method thereof |
| CN116666610A (en) * | 2023-07-31 | 2023-08-29 | 江苏正力新能电池技术有限公司 | Silicon-carbon negative electrode material and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019021825A1 (en) * | 2017-07-24 | 2019-01-31 | 東レ・ダウコーニング株式会社 | Thermally-conductive silicone gel composition, thermally-conductive member, and heat dissipation structure |
| CN110333278A (en) * | 2019-07-16 | 2019-10-15 | 中国科学院南京地理与湖泊研究所 | A kind of three-dimensional grapheme-metal oxide composite sensing film modified electrod and preparation method thereof |
| CN111004510A (en) * | 2019-12-19 | 2020-04-14 | 苏州赛伍应用技术股份有限公司 | Heat-conducting silica gel and preparation method and application thereof |
-
2020
- 2020-04-21 CN CN202010318826.8A patent/CN111471305A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019021825A1 (en) * | 2017-07-24 | 2019-01-31 | 東レ・ダウコーニング株式会社 | Thermally-conductive silicone gel composition, thermally-conductive member, and heat dissipation structure |
| CN110333278A (en) * | 2019-07-16 | 2019-10-15 | 中国科学院南京地理与湖泊研究所 | A kind of three-dimensional grapheme-metal oxide composite sensing film modified electrod and preparation method thereof |
| CN111004510A (en) * | 2019-12-19 | 2020-04-14 | 苏州赛伍应用技术股份有限公司 | Heat-conducting silica gel and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 刘建周: "《工业催化工程》", 30 June 2018, 中国矿业大学出版社有限责任公司 * |
| 朱浩: "《石墨烯系材料去除水中离子的研究》", 《中国硕士学位论文全文数据库工程科技Ⅰ辑》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112322042A (en) * | 2020-11-17 | 2021-02-05 | 广东和润新材料股份有限公司 | High-thermal-conductivity single-component heat-conducting gel and preparation method thereof |
| CN112985624A (en) * | 2021-02-24 | 2021-06-18 | 上海军辉信息技术有限公司 | Building intelligent monitoring system for weak current engineering |
| CN113897066A (en) * | 2021-11-17 | 2022-01-07 | 浙江商林科技股份有限公司 | High-thermal-conductivity bi-component heat-conducting gel and preparation method thereof |
| CN116666610A (en) * | 2023-07-31 | 2023-08-29 | 江苏正力新能电池技术有限公司 | Silicon-carbon negative electrode material and preparation method and application thereof |
| CN116666610B (en) * | 2023-07-31 | 2023-09-29 | 江苏正力新能电池技术有限公司 | Silicon-carbon negative electrode material and preparation method and application thereof |
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