CN111457682B - Novel freeze dryer capable of recycling condensed water and operation method thereof - Google Patents
Novel freeze dryer capable of recycling condensed water and operation method thereof Download PDFInfo
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- CN111457682B CN111457682B CN202010422456.2A CN202010422456A CN111457682B CN 111457682 B CN111457682 B CN 111457682B CN 202010422456 A CN202010422456 A CN 202010422456A CN 111457682 B CN111457682 B CN 111457682B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 31
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- 238000001035 drying Methods 0.000 claims abstract description 76
- 238000004108 freeze drying Methods 0.000 claims abstract description 58
- 238000010438 heat treatment Methods 0.000 claims abstract description 55
- 239000007788 liquid Substances 0.000 claims abstract description 54
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- 238000003860 storage Methods 0.000 claims abstract description 22
- 238000001704 evaporation Methods 0.000 claims abstract description 20
- 238000011084 recovery Methods 0.000 claims abstract description 11
- 239000002918 waste heat Substances 0.000 claims abstract description 11
- 239000003507 refrigerant Substances 0.000 claims description 48
- 238000000859 sublimation Methods 0.000 claims description 48
- 230000008022 sublimation Effects 0.000 claims description 48
- 239000012530 fluid Substances 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 35
- 238000005057 refrigeration Methods 0.000 claims description 33
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- 239000007787 solid Substances 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 230000005496 eutectics Effects 0.000 claims description 4
- 230000000630 rising effect Effects 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
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- 239000000446 fuel Substances 0.000 description 5
- 239000002828 fuel tank Substances 0.000 description 4
- 238000005485 electric heating Methods 0.000 description 3
- 235000012055 fruits and vegetables Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
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- 238000009777 vacuum freeze-drying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B5/00—Drying solid materials or objects by processes not involving the application of heat
- F26B5/04—Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum
- F26B5/06—Drying solid materials or objects by processes not involving the application of heat by evaporation or sublimation of moisture under reduced pressure, e.g. in a vacuum the process involving freezing
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B1/00—Compression machines, plants or systems with non-reversible cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/20—Disposition of valves, e.g. of on-off valves or flow control valves
- F25B41/22—Disposition of valves, e.g. of on-off valves or flow control valves between evaporator and compressor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/30—Expansion means; Dispositions thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B43/00—Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
- F25B43/006—Accumulators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/06—Removing frost
- F25D21/08—Removing frost by electric heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/14—Collecting or removing condensed and defrost water; Drip trays
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Abstract
The invention discloses a novel freeze dryer capable of recycling condensed water and an operation method thereof, and the novel freeze dryer comprises a refrigerating system, a condensed water recycling system, a waste heat recycling heating system and a defrosting system, wherein the refrigerating system comprises a refrigerating compressor, a condenser with a built-in condensing coil, a liquid storage tank, a throttle valve, an electromagnetic valve, an evaporator with a built-in evaporating coil, a built-in coil and a cold trap of a heating coil; the condensate water recovery system comprises a freeze-drying box, a box trap valve and a vacuum pump, and the waste heat recovery heating system comprises a radiator, an electromagnetic valve, a circulating pump, a heater, an electric valve and an oil tank; the defrosting system comprises the stop valve, the water collector, the electromagnetic valve and the heating coil, so that the invention achieves the purposes of fully and reasonably utilizing heat, reducing electric quantity consumption, saving energy, improving the economic benefit of freeze drying, increasing the mass production efficiency of drying, overcoming the influence of environmental temperature on condensing temperature, and well ensuring stable control of condensing temperature and efficient operation of the system.
Description
Technical Field
The invention relates to a novel freeze dryer capable of recycling condensed water and an operation method thereof, and belongs to the technical field of refrigeration.
Background
The vacuum freeze drying technology is to cool wet material below the eutectic point temperature of the material to make the water and water vapor inside the material and the freeze drying box become solid ice, to create vacuum condition for the freeze drying box with vacuum system, to sublimate the ice into water vapor through direct heating in vacuum environment, and to eliminate the water vapor with vacuum system to dry the material. There are two problems with existing drying equipment. Firstly, when a large amount of seafood or fruits and vegetables and other foods are dried, a large amount of free water and bound water are changed into water vapor through solidification and sublimation through three stages of pre-freezing, sublimation drying and analysis drying, then the water vapor is captured and condensed on the surface by a cold trap, most of the existing freeze-drying equipment captures and solidifies the water vapor directly through the cold trap in a vacuum system and is not properly collected and utilized, so that resource waste is caused, particularly for large-scale freeze-drying equipment, a large amount of water volatilized in the freeze-drying process can be captured in the cold trap, and the water stored in the materials to be dried, particularly fruits and vegetables, has good health preserving value and can be recycled. In addition, the condensate on the surface of the cold trap needs to be melted as soon as possible to start a new freeze-drying process, and long time is needed by relying on natural melting, so that the batch drying efficiency is affected. Secondly, in the freeze-drying process, the pre-freezing stage needs to be reduced to and kept at a very low temperature, more energy is required to be consumed, heat in the freeze-drying box is taken out and released, refrigeration and heating intermittent action is required in the sublimation and analysis drying stage to keep a constant drying dehydration temperature, heat is required to be repeatedly taken out and added in the process, the existing freeze-drying equipment adopts refrigeration circulation to cool down on one hand, meanwhile, the heat in the freeze-drying box is discharged, and on the other hand, electric heating is also required to heat up for adding the heat into the freeze-drying box, so that a great amount of energy is wasted. In order to solve the problems, the water obtained by freeze-drying is recovered, the drying process is quickened, and the heat released in the refrigerating process in different freeze-drying stages is recovered for subsequent heating, so that a great amount of energy or power consumption can be saved, and the method is particularly important for saving resources, improving the utilization efficiency of equipment and promoting popularization and application of freeze-drying technology.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a novel freeze dryer capable of recycling condensed water and an operation method thereof.
The technical scheme provided by the invention is as follows: the novel freeze dryer capable of recycling condensed water is characterized by comprising a refrigerating system, a condensed water recycling system, a waste heat recycling and heating system and a defrosting system, wherein the refrigerating system comprises a refrigerating compressor, a condenser, a liquid storage tank, a first throttle valve, a fifth electromagnetic valve, an evaporator, a first electromagnetic valve, a second throttle valve, a cold trap and a ninth electromagnetic valve; the condensate water recovery system comprises a freeze-drying box, a box trap valve and a vacuum pump, and the waste heat recovery heating system comprises a radiator, a second electromagnetic valve, a sixth electromagnetic valve, a first circulating pump, a heater, a third electromagnetic valve, an electric valve, an oil tank, a fourth electromagnetic valve and a second circulating pump; the defrosting system comprises a stop valve, a water collector, a seventh electromagnetic valve, an eighth electromagnetic valve, a heater and a heating coil; a condensing coil is arranged in the condenser, an evaporating coil is arranged in the evaporator, and a coil and a heating coil are arranged in the cold trap;
the outlet of the refrigeration compressor is connected with the inlet of a condensing coil of the condenser, one path of the outlet of the condensing coil of the condenser is connected with the inlet of a liquid storage tank, one path of the outlet of the liquid storage tank is connected with the inlet of a fifth electromagnetic valve, the outlet of the fifth electromagnetic valve is connected with the inlet of a first throttle valve, the outlet of the first throttle valve is connected with the inlet of an evaporating coil of the evaporator, and the outlet of the evaporating coil of the evaporator is connected with the inlet of the refrigeration compressor; the other path of the outlet of the liquid storage tank is connected with the inlet of a first electromagnetic valve, the outlet of the first electromagnetic valve is connected with the inlet of a second throttle valve, the outlet of the second throttle valve is connected with the inlet of a coil pipe of a cold trap, the outlet of the coil pipe of the cold trap is connected with the inlet of a ninth electromagnetic valve, and the outlet of the ninth electromagnetic valve is connected with the inlet of a refrigerating compressor after being connected in series with the outlet of an evaporation coil pipe of an evaporator; an outlet at the lower side of the cold trap is connected with an inlet of a stop valve, and an outlet of the stop valve is connected with an inlet of the water collector; the outlet at the left side of the cold trap is connected with a vacuum pump, the interface at the upper side of the cold trap is connected with the outlet of a box trap valve, the inlet of the box trap valve is connected with the outlet at the lower side of the freeze-drying box, the first path of the outlet of the freeze-drying box is connected with the inlet of an evaporator, the outlet at the left side of the evaporator is connected with the inlet of a second circulating pump, the outlet of the second circulating pump is connected with the inlet of a fourth electromagnetic valve, and the outlet of the fourth electromagnetic valve is connected with the inlet of the freeze-drying box; the outlet of the freeze-drying box is connected with the inlet of the oil tank in a second way, the outlet of the oil tank is connected with the inlet of the sixth electromagnetic valve, the outlet of the sixth electromagnetic valve is connected with the inlet of the first circulating pump, the outlet of the first circulating pump is connected with the inlet of the condenser, one way of the outlet of the condenser is connected with the inlet of the radiator, the outlet of the radiator is connected with the inlet of the second electromagnetic valve in parallel, the outlet of the second electromagnetic valve is connected with the inlet of the first circulating pump after being connected with the outlet of the sixth electromagnetic valve in parallel, the other way of the outlet of the condenser is connected with the inlet of the heater, the outlet of the heater is connected with the inlet of the third electromagnetic valve, the outlet of the third electromagnetic valve is connected with the inlet of the electric valve, and the outlet of the electric valve is connected with the inlet of the freeze-drying box after being connected with the outlet of the fourth electromagnetic valve in parallel; the outlet of the freeze-drying box is also connected with the outlet of the eighth electromagnetic valve, the inlet of the eighth electromagnetic valve is connected with the outlet of the heating coil in the cold trap, the inlet of the heating coil is connected with the outlet of the seventh electromagnetic valve, and the inlet of the seventh electromagnetic valve is connected with the outlet of the heater.
Further, the ninth electromagnetic valve adopts a one-way valve.
Further, the condenser is characterized in that a plate heat exchanger or a shell-and-tube heat exchanger or a double-tube heat exchanger is adopted.
The evaporator further adopts a plate heat exchanger, a shell-and-tube heat exchanger or a double-tube heat exchanger.
The operation method of the novel freeze dryer capable of recycling condensed water is characterized by comprising four stages of prefreezing, sublimation drying, analytical drying and defrosting;
1) Pre-freezing: cooling the moisture in the material to freeze the moisture into a solid state; the fifth electromagnetic valve, the second electromagnetic valve, the first circulating pump, the fourth electromagnetic valve and the second circulating pump are opened, and the first electromagnetic valve, the heater, the third electromagnetic valve, the electric valve, the tank trap valve, the vacuum pump, the stop valve, the sixth electromagnetic valve, the seventh electromagnetic valve, the eighth electromagnetic valve and the ninth electromagnetic valve are closed;
refrigerant circuit in pre-freezing stage: the refrigerant vapor output by the refrigeration compressor enters a condensing coil in a condenser, emits a large amount of heat and becomes high-temperature and high-pressure liquid, the liquid passes through a liquid storage tank and then enters a first throttle valve through a fifth electromagnetic valve, the throttled refrigerant becomes low-temperature and low-pressure liquid, the low-temperature and low-pressure liquid enters an evaporating coil of an evaporator, and the low-temperature and low-pressure refrigerant gas flows back to the refrigeration compressor after absorbing heat;
prefreezing stage fluid medium circuit: one path of fluid medium is driven by a second circulating pump to enter a freeze-drying box through a fourth electromagnetic valve after absorbing heat in the evaporator, and absorbs heat in the box body and flows back to the evaporator; the other path of fluid medium flows through the condenser to be heated and then enters the radiator, and after radiating heat, the fluid medium flows back to the condenser under the drive of the first circulating pump through the second electromagnetic valve; the fluid medium here may be an oil or glycol solution;
2) The sublimation drying stage needs to be vacuumized, and is properly warmed up in a low-temperature environment, after the temperature is raised to the set temperature of the sublimation drying stage, the temperature is kept constant by switching cold and hot fluid media from an evaporator and a condenser, and the set temperature of the sublimation drying stage is 5-10 ℃ lower than the eutectic point of the material, and the sublimation drying stage is heated in a split way and kept constant; most of the water in the material in the sublimation drying stage is directly changed into a gas state from a solid state and is pumped away;
in the heating stage of the sublimation drying stage, a first electromagnetic valve, a box trap valve, a third electromagnetic valve, an electric valve, a ninth electromagnetic valve and a sixth electromagnetic valve are opened, a compressor, a first circulating pump and a vacuum pump are started, and a fifth electromagnetic valve, a second electromagnetic valve, a fourth electromagnetic valve and a second circulating pump are closed; the seventh electromagnetic valve, the eighth electromagnetic valve and the stop valve are closed; in the heating process, if the opening of the electric valve is regulated to the maximum and the temperature in the freeze-drying box is still lower than the set temperature in the sublimation drying stage after the electric valve is continued for 10min, the heater starts to heat, otherwise, the heater is not started;
at the moment, the refrigerant vapor output by the refrigeration compressor enters a condensing coil in the condenser, a large amount of heat is released and then becomes high-temperature and high-pressure liquid, the liquid passes through a liquid storage tank and then enters a second throttle valve through a first electromagnetic valve, the throttled refrigerant enters a coil of a cold trap and flows back to the refrigeration compressor through a ninth electromagnetic valve; the refrigerant enters the freeze-drying box through the heater, the third electromagnetic valve and the electric valve after the condensing coil heats the fluid medium, and returns to the condensing coil through the oil tank, the sixth electromagnetic valve and the first circulating pump after flowing out; the vacuum pump operates, the air pressure in the freeze-drying box is reduced, water in the material starts to sublimate, enters a cold trap through a box trap valve, and is condensed on the surface of a cold trap coil;
a constant temperature maintaining stage of the sublimation drying stage, wherein when the temperature is lower than the set temperature of the sublimation drying stage, the valve, the equipment switching and the operation method are the same as those of the heating stage of the sublimation drying stage; when the temperature is higher than the set temperature in the sublimation drying stage, the first electromagnetic valve, the ninth electromagnetic valve, the box trap valve, the second electromagnetic valve, the fourth electromagnetic valve, the fifth electromagnetic valve and the second circulating pump are opened, the compressor, the first circulating pump and the vacuum pump are started, and the third electromagnetic valve, the electric valve, the sixth electromagnetic valve, the seventh electromagnetic valve, the eighth electromagnetic valve, the stop valve and the heater are closed; the refrigerant vapor output by the refrigeration compressor enters a condensing coil in a condenser, is changed into high-temperature high-pressure liquid after heat release, is divided into two paths after passing through a liquid storage tank, and one path of liquid enters a coil of a cold trap through a first electromagnetic valve, a second throttle valve to provide cold energy for capturing the water vapor, and then flows back to the refrigeration compressor through a ninth electromagnetic valve; the other path of the refrigerant gas enters an evaporation coil of an evaporator through a fifth electromagnetic valve, absorbs heat and becomes low-temperature low-pressure refrigerant gas, and the refrigerant gas is converged with the refrigerant flowing out of a ninth electromagnetic valve and flows back to a refrigeration compressor; the fluid medium is heated by the condenser, flows out and enters the radiator, and after radiating heat, flows back to the condenser by the second electromagnetic valve and the first circulating pump;
3) And (3) analysis and drying: the materials are further heated under the vacuum condition, and a certain temperature is maintained, so that the bound water in the materials is separated out; the analysis and drying stage is divided into two stages of heating at a rising temperature and keeping the temperature constant; the residual moisture in the materials is pumped out in a gaseous state in the analysis stage; setting the temperature in the analysis drying stage to be more than 30;
analyzing the switching states of a valve and a pump in a heating stage of the drying stage and an operation method, wherein the switching states of the valve and the pump in the heating stage of the sublimation drying stage and the operation method are completely the same as those of the valve and the pump in the heating stage of the sublimation drying stage in the step 2); analyzing the switching state and the operation method of a valve and a pump in a constant temperature maintaining stage of the drying stage, wherein the switching state and the operation method of the valve and the pump in the constant temperature maintaining stage of the sublimation drying stage in the step 2) are completely the same; 4) A defrosting stage, namely melting frost condensed in the cold trap, and collecting the frost by using a water collector;
the stop valve, the sixth electromagnetic valve, the first circulating pump, the seventh electromagnetic valve and the eighth electromagnetic valve are opened, and the tank trap valve, the second electromagnetic valve, the third electromagnetic valve, the electric valve, the fourth electromagnetic valve, the first electromagnetic valve, the ninth electromagnetic valve, the fifth electromagnetic valve, the second electromagnetic valve, the fourth electromagnetic valve and the second circulating pump are closed; the compressor and the vacuum pump stop running; the heater starts to heat;
the refrigerant does not flow in the defrosting stage;
fluid medium circuit in defrosting stage: under the drive of the first circulating pump, the fluid medium enters a heater through a condenser without heat exchange to absorb heat, after the temperature of the fluid medium rises, the fluid medium enters a heating coil in a cold trap through a seventh electromagnetic valve, after the temperature of the cold trap rises, frost condensed on the coil in the cold trap is melted, melted condensed water enters a water collector through a stop valve to be collected, and the fluid medium after heat release is returned to the first circulating pump through an eighth electromagnetic valve, an oil tank and a sixth electromagnetic valve to continue circulating.
Further, the fuel tank is characterized in that the fuel tank is provided with a fuel filling valve, when the liquid level in the fuel tank is lower than two thirds of the height of the fuel tank, the fuel is filled from the fuel filling valve to a normal liquid level, the fuel filling valve is required to be opened for exhausting before each operation, and the fuel filling valve is closed in normal operation.
The beneficial effects of the invention are as follows: the invention absorbs heat from the evaporator and the cold trap through the waste heat recovery heating system consisting of the radiator, the second electromagnetic valve, the sixth electromagnetic valve, the first circulating pump, the third electromagnetic valve, the electric valve, the oil tank, the fourth electromagnetic valve and the second circulating pump, circularly sends the heat to the condenser to be discharged through the refrigerant, and then recovers the heat of the condenser through the oil or glycol salt solution, sends the heat to the freeze-drying box to heat materials, thereby realizing the recycling of the condensation heat of the condenser in the running process of the refrigerating system, achieving the purposes of fully and reasonably utilizing the heat, reducing or even not needing electric heating, reducing the electricity consumption and obtaining the energy saving effect.
1. The invention heats the freeze-dried material moisture condensed on the surface of the cold trap in the vacuum system through a defrosting system consisting of a stop valve, a water collector, a seventh electromagnetic valve, an eighth electromagnetic valve, a heater and a heating coil, and the freeze-dried material moisture is collected and utilized after being melted. The materials, especially the water separated out in the drying process of fruits and vegetables, have good health care value. By adding the defrosting system, the three-stage freeze-drying process is improved to four-stage freeze-drying process, so that water resources generated in the drying process are recovered, and the economic benefit of freeze-drying is improved.
2. In the defrosting system provided by the invention, two spiral coils, namely a coil and a heating coil, are arranged in the cold trap, and cold and hot fluid media can be respectively introduced, so that the moisture complement and defrosting of the material drying process are realized. The fluid medium is heated up by electric heating in the defrosting system to melt the surface frost layer of the cold trap, and compared with the traditional natural defrosting, the drying mass production efficiency is improved.
3. Compared with the traditional heat dissipation only through the condenser, the invention provides a new means for adjusting the condensation temperature through the indirect heat exchange mode besides recovering waste heat, enriches the condensation temperature adjustment mode, is beneficial to overcoming the influence of the environment temperature on the condensation temperature by the system and well ensures the stable control of the condensation temperature and the efficient operation of the system.
Drawings
Fig. 1 is a schematic structural view of the present invention.
Note that: the thick line indicates the fluid medium flow path.
The thin line indicates the refrigerant flow path.
Arrows
The direction of flow of the refrigerant and the fluid medium in the first stage of lyophilization (pre-lyophilization stage) is shown.
Arrows
The flow direction of the refrigerant and the fluid medium in the second and third stages (sublimation drying stage and analytical drying stage) of lyophilization is shown.
Arrows
The direction of flow of the refrigerant and the fluid medium in the fourth stage of lyophilization (defrosting stage) is shown.
Detailed Description
The following detailed description of the embodiments of the invention refers to the accompanying drawings, which illustrate in further detail:
as shown in fig. 1, the novel freeze dryer capable of recycling condensed water comprises a refrigerating system, a condensed water recycling system, a waste heat recycling heating system and a defrosting system, wherein the refrigerating system consists of a refrigerating compressor 1, a condenser 2, a liquid storage tank 3, a first throttle valve 4, a fifth electromagnetic valve 24, an evaporator 5, a first electromagnetic valve 6, a second throttle valve 7, a cold trap 8 and a ninth electromagnetic valve 9; the condensate water recovery system consists of a freeze-drying box 10, a box trap valve 18 and a vacuum pump 22, and the waste heat recovery heating system consists of a radiator 11, a second electromagnetic valve 12, a sixth electromagnetic valve 13, a first circulating pump 14, a heater 15, a third electromagnetic valve 16, an electric valve 17, an oil tank 19, a fourth electromagnetic valve 20 and a second circulating pump 21; the defrosting system comprises a stop valve 23, a water collector 25, a seventh electromagnetic valve 26, an eighth electromagnetic valve 27, a heater 15 and a heating coil 28, and achieves the defrosting function together with the waste heat recovery heating system. The condenser 2 is internally provided with a condensing coil 2-1, the evaporator 5 is internally provided with an evaporating coil 5-1, and the cold trap 8 is internally provided with two spiral coils, namely a coil 8-1 and a heating coil 28, which are respectively arranged at two sides of the cold trap or are internally and externally nested.
The outlet of the refrigeration compressor 1 is connected with the inlet of a condensing coil 2-1 of the condenser 2, one path of the outlet of the condensing coil 2-1 of the condenser 2 is connected with the inlet of a liquid storage tank 3, one path of the outlet of the liquid storage tank 3 is connected with the inlet of a fifth electromagnetic valve 24, the outlet of the fifth electromagnetic valve 24 is connected with the inlet of a first throttle valve 4, the outlet of the first throttle valve 4 is connected with the inlet of an evaporating coil 5-1 of an evaporator 5, and the outlet of the evaporating coil 5-1 of the evaporator 5 is connected with the inlet of the refrigeration compressor 1. The other path of the outlet of the liquid storage tank 3 is connected with the inlet of a first electromagnetic valve 6, the outlet of the first electromagnetic valve 6 is connected with the inlet of a second throttle valve 7, the outlet of the second throttle valve 7 is connected with the inlet of a coil pipe 8-1 of a cold trap 8, the outlet of the coil pipe 8-1 of the cold trap 8 is connected with the inlet of a ninth electromagnetic valve 9, and the outlet of the ninth electromagnetic valve 9 is connected with the inlet of the refrigeration compressor 1 after being connected with the outlet of an evaporation coil pipe 5-1 of the evaporator 5 in series. The outlet of the lower side of the cold trap 8 is connected with the inlet of a stop valve 23, and the outlet of the stop valve 23 is connected with the inlet of a water collector 25. The outlet on the left side of the cold trap 8 is connected with the vacuum pump 22, the interface on the upper side of the cold trap 8 is connected with the outlet of the box trap valve 18, the inlet of the box trap valve 18 is connected with the outlet on the lower side of the freeze-drying box 10, the first path of the outlet of the freeze-drying box 10 is connected with the inlet of the evaporator 5, the outlet on the left side of the evaporator 5 is connected with the inlet of the second circulating pump 21, the outlet of the second circulating pump 21 is connected with the inlet of the fourth electromagnetic valve 20, and the outlet of the fourth electromagnetic valve 20 is connected with the inlet of the freeze-drying box 10. The outlet of the freeze-drying box 10 is connected with the inlet of the oil tank 19 in a second way, the outlet of the oil tank 19 is connected with the inlet of the sixth electromagnetic valve 13, the outlet of the sixth electromagnetic valve 13 is connected with the inlet of the first circulating pump 14, the outlet of the first circulating pump 14 is connected with the inlet of the condenser 2, one way of the outlet of the condenser 2 is connected with the inlet of the radiator 11, the outlet of the radiator 11 is connected with the inlet of the second electromagnetic valve 12, the outlet of the second electromagnetic valve 12 is connected with the outlet of the sixth electromagnetic valve 13 in parallel and then is connected with the inlet of the first circulating pump 14, the other way of the outlet of the condenser 2 is connected with the inlet of the heater 15, the outlet of the heater 15 is connected with the inlet of the third electromagnetic valve 16, the outlet of the third electromagnetic valve 16 is connected with the inlet of the electric valve 17, and the outlet of the electric valve 17 is connected with the outlet of the fourth electromagnetic valve 20 in parallel and then is connected with the inlet of the freeze-drying box 10. The outlet of the freeze-drying box 10 is also connected with the outlet of an eighth electromagnetic valve 27, the inlet of the eighth electromagnetic valve 27 is connected with the outlet of a heating coil 28 in the cold trap 8, the inlet of the heating coil 28 is connected with the outlet of a seventh electromagnetic valve 26, and the inlet of the seventh electromagnetic valve 26 is connected with the outlet of the heater 15.
The specific operation mode is as follows:
the working operation of the novel freeze dryer is divided into 4 stages of prefreezing, sublimation drying, analytical drying and defrosting.
1. The pre-freezing stage is to provide cold for the box body and cool the water in the material to freeze the material into solid state. At this time, the fifth solenoid valve 24, the second solenoid valve 12, the first circulation pump 14, the fourth solenoid valve 20, and the second circulation pump 21 are opened, and the first solenoid valve 6, the heater 15, the third solenoid valve 16, the motor valve 17, the trap valve 18, the vacuum pump 22, the shutoff valve 23, the sixth solenoid valve 13, the seventh solenoid valve 26, the eighth solenoid valve 27, and the ninth solenoid valve 9 are closed.
Arrows
Is the flow path between the refrigerant and the fluid medium in the pre-freezing stage.
Refrigerant circuit in pre-freezing stage: the refrigerant vapor output by the refrigeration compressor 1 enters a condensing coil 2-1 in the condenser 2, emits a large amount of heat and becomes high-temperature and high-pressure liquid, the liquid passes through a liquid storage tank 3 and then enters a first throttle valve 4 through a fifth electromagnetic valve 24, the refrigerant becomes low-temperature and low-pressure liquid after being throttled, the liquid enters an evaporating coil 5-1 of the evaporator 5, and the refrigerant gas becomes low-temperature and low-pressure refrigerant gas after absorbing heat and flows back to the refrigeration compressor 1.
Prefreezing stage fluid medium circuit: one path of fluid medium is driven by the second circulating pump 21 to enter the freeze-drying box 10 through the fourth electromagnetic valve 20 after absorbing heat in the evaporator 5, and the absorbed heat in the box body flows back to the evaporator 5. The other fluid medium flows through the condenser 2 to be heated and then enters the radiator 11, and the heat dissipation capacity flows through the second electromagnetic valve 12 and flows back to the condenser 2 under the driving of the first circulating pump 14. The fluid medium here may be an oil or glycol solution.
2. The sublimation drying stage needs to be vacuumized, and the temperature is properly raised in a low-temperature environment, and after the temperature is raised to the set temperature (5-10 ℃ below the eutectic point of the materials) in the sublimation drying stage, the temperature is kept constant by switching cold and hot fluid media from the evaporator 5 and the condenser 2, so that the sublimation drying stage is divided into two stages of heating and keeping the temperature constant. Most of the water in the material is pumped away from the solid state directly into the gaseous state during the sublimation drying stage.
Arrows
A refrigerant and fluid medium circulation loop for the sublimation drying stage.
In the heating stage of the sublimation drying stage, the first solenoid valve 6, the tank trap valve 18, the third solenoid valve 16, the electric valve 17, the ninth solenoid valve 9, and the sixth solenoid valve 13 are opened, the refrigeration compressor 1, the first circulation pump 14, and the vacuum pump 22 are started, and the fifth solenoid valve 24, the second solenoid valve 12, the fourth solenoid valve 20, and the second circulation pump 21 are closed. The seventh solenoid valve 26, the eighth solenoid valve 27, and the shutoff valve 23 are closed. The switch of the heater 15 depends on the opening degree of the electric valve 17 and the temperature change condition in the freeze-drying box 10, if the opening degree of the electric valve 17 is already adjusted to the maximum degree and the temperature in the freeze-drying box 10 is still lower than the set temperature in the sublimation drying stage after a period of time (such as 10 min) in the heating process, the heater 15 starts to heat, otherwise, the heater 15 is not started.
At this time, the refrigerant vapor output by the refrigeration compressor 1 enters the condensing coil 2-1 in the condenser 2, emits a large amount of heat and becomes high-temperature and high-pressure liquid, the liquid passes through the liquid storage tank 3, then enters the second throttle valve 7 through the first electromagnetic valve 6, the throttled refrigerant enters the coil 8-1 of the cold trap 8, and flows back to the refrigeration compressor 1 through the ninth electromagnetic valve 9. The refrigerant is heated by the condensing coil 2-1, enters the freeze-drying box 10 through the heater 15, the third electromagnetic valve 16 and the electric valve 17, flows out, and returns to the condensing coil 2-1 through the oil tank 19, the sixth electromagnetic valve 13 and the first circulating pump 14. The vacuum pump 22 is operated, the air pressure in the freeze-drying box 10 is reduced, water in the material starts to sublimate, enters the cold trap 8 through the box trap valve 18 and is condensed on the surface of the cold trap coil 8-1.
In the sublimation drying stage, the temperature is kept constant, and when the temperature is lower than the set temperature of the sublimation drying stage, the valve, the equipment are switched and operate as in the heating stage. When the temperature is higher than the sublimation drying stage setting temperature, the first solenoid valve 6, the ninth solenoid valve 9, the tank trap valve 18, the second solenoid valve 12, the fourth solenoid valve 20, the fifth solenoid valve 24, and the second circulation pump 21 are opened, the compressor 1, the first circulation pump 14, and the vacuum pump 22 are started, and the third solenoid valve 16, the electric valve 17, the sixth solenoid valve 13, the seventh solenoid valve 26, the eighth solenoid valve 27, the shutoff valve 23, and the heater 15 are closed.
The refrigerant vapor output by the refrigeration compressor 1 enters a condensing coil 2-1 in a condenser 2, is changed into high-temperature and high-pressure liquid after heat release, is divided into two paths after passing through a liquid storage tank 3, and one path of liquid enters a coil 8-1 of a cold trap 8 through a first electromagnetic valve 6 and a second throttle valve 7 to provide cold energy for capturing the water vapor, and then flows back to the refrigeration compressor 1 through a ninth electromagnetic valve 9. The other path enters the evaporation coil 5-1 of the evaporator 5 through the fifth electromagnetic valve 24, absorbs heat and becomes low-temperature and low-pressure refrigerant gas, and the refrigerant gas is converged with the refrigerant flowing out of the ninth electromagnetic valve 9 and flows back to the refrigeration compressor 1. The fluid medium is heated by the condenser 2, flows out and enters the radiator 11, and after radiating heat, the fluid medium flows back to the condenser 2 by the driving of the first circulating pump 14 through the second electromagnetic valve 12.
3. In the desorption drying stage, the materials are further heated under the vacuum condition, and a certain temperature is kept, so that the bound water in the materials is separated out. The analysis and drying stage is divided into two stages of heating at a rising temperature and keeping the temperature constant. Most of the water in the material is pumped away in the gaseous state during the desorption stage.
In the temperature rising and heating stage and the constant temperature maintaining stage of the analytic drying stage, the switching states of the valve and the pump are the same as those of the sublimation drying stage; the difference is that: the sublimation drying stage setting temperature is different from the analysis drying stage setting temperature, the specific value depends on the type of the material to be dried, and the analysis drying stage setting temperature is more than 30 ℃.
In this two-stage refrigerant circuit and fluid medium circuit flow as in the sublimation drying stage.
4. The defrosting phase melts the frost that condenses inside the cold trap, which is collected using the water collector 25.
The shutoff valve 23, the sixth solenoid valve 13, the first circulation pump 14, the seventh solenoid valve 26, and the eighth solenoid valve 27 are opened, and the trap valve 18, the second solenoid valve 12, the third solenoid valve 16, the motor valve 17, the fourth solenoid valve 20, the first solenoid valve 6, the ninth solenoid valve 9, the fifth solenoid valve 24, the second solenoid valve 12, the fourth solenoid valve 20, and the second circulation pump 21 are closed. The compressor 1 and the vacuum pump 22 stop operating. The heater 15 starts heating.
The refrigerant does not flow during the defrosting phase.
Fluid medium circuit in defrosting stage: the fluid medium is driven by the first circulating pump 14, enters the heater 15 through the condenser 2 (no heat exchange occurs), absorbs heat, enters the heating coil 28 in the cold trap 8 through the seventh electromagnetic valve 26 after the temperature is increased, the frost condensed on the coil 8-1 in the cold trap 8 melts after the temperature of the cold trap 8 is increased, the melted condensed water enters the water collector 25 through the stop valve 23 to be collected, and the fluid medium after heat release is continuously circulated through the eighth electromagnetic valve 27, the oil tank 19, the sixth electromagnetic valve 13 and returns to the first circulating pump 14.
The oil tank 19 is provided with an oil filling valve, when the liquid level in the oil tank 19 is lower than two thirds of the height of the oil tank, the oil is filled from the oil filling valve to a normal liquid level, the oil filling valve is required to be opened for exhausting before each operation, and the oil filling valve is closed in normal operation. The tank 19 also serves to store excess oil and the oil circuit expansion set pressure.
The ninth electromagnetic valve 9 can also adopt a one-way valve.
The condenser 2 is internally provided with a condensing coil 2-1 and can also adopt a plate heat exchanger, a shell-and-tube heat exchanger, a sleeve heat exchanger and other liquid-liquid heat exchangers.
The evaporator 5 is internally provided with an evaporation coil 5-1 and can also adopt a plate heat exchanger, a shell-and-tube heat exchanger, a sleeve heat exchanger and other liquid-liquid heat exchangers.
It should be understood that parts of the present specification not specifically described are prior art. The above examples are only illustrative of the preferred embodiments of the present invention and are not intended to limit the scope of the present invention, and various modifications and improvements made by those skilled in the art to the technical solution of the present invention should fall within the scope of protection defined by the claims of the present invention without departing from the spirit of the design of the present invention.
Claims (5)
1. The operation method of the novel freeze dryer capable of recycling condensed water is characterized in that the novel freeze dryer capable of recycling condensed water comprises a refrigerating system, a condensed water recycling system, a waste heat recycling heating system and a defrosting system, wherein the refrigerating system comprises a refrigerating compressor (1), a condenser (2), a liquid storage tank (3), a first throttle valve (4), a fifth electromagnetic valve (24), an evaporator (5), a first electromagnetic valve (6), a second throttle valve (7), a cold trap (8) and a ninth electromagnetic valve (9); the condensate water recovery system comprises a freeze-drying box (10), a box trap valve (18) and a vacuum pump (22), and the waste heat recovery heating system comprises a radiator (11), a second electromagnetic valve (12), a sixth electromagnetic valve (13), a first circulating pump (14), a heater (15), a third electromagnetic valve (16), an electric valve (17), an oil tank (19), a fourth electromagnetic valve (20) and a second circulating pump (21); the defrosting system comprises a stop valve (23), a water collector (25), a seventh electromagnetic valve (26), an eighth electromagnetic valve (27), a heater (15) and a heating coil (28); the condenser (2) is internally provided with a condensing coil (2-1), the evaporator (5) is internally provided with an evaporating coil (5-1), and the cold trap (8) is internally provided with a coil (8-1) and a heating coil (28);
the outlet of the refrigeration compressor (1) is connected with the inlet of a condensing coil (2-1) of the condenser (2), one path of the outlet of the condensing coil (2-1) of the condenser (2) is connected with the inlet of a liquid storage tank (3), one path of the outlet of the liquid storage tank (3) is connected with the inlet of a fifth electromagnetic valve (24), the outlet of the fifth electromagnetic valve (24) is connected with the inlet of a first throttle valve (4), the outlet of the first throttle valve (4) is connected with the inlet of an evaporating coil (5-1) of the evaporator (5), and the outlet of the evaporating coil (5-1) of the evaporator (5) is connected with the inlet of the refrigeration compressor (1); the other path of outlet of the liquid storage tank (3) is connected with the inlet of a first electromagnetic valve (6), the outlet of the first electromagnetic valve (6) is connected with the inlet of a second throttle valve (7), the outlet of the second throttle valve (7) is connected with the inlet of a coil pipe (8-1) of a cold trap (8), the outlet of the coil pipe (8-1) of the cold trap (8) is connected with the inlet of a ninth electromagnetic valve (9), and the outlet of the ninth electromagnetic valve (9) is connected with the outlet of an evaporation coil pipe (5-1) of the evaporator (5) in series and then is connected with the inlet of the refrigeration compressor (1); an outlet at the lower side of the cold trap (8) is connected with an inlet of a stop valve (23), and an outlet of the stop valve (23) is connected with an inlet of a water collector (25); the outlet at the left side of the cold trap (8) is connected with a vacuum pump (22), the interface at the upper side of the cold trap (8) is connected with the outlet of a box trap valve (18), the inlet of the box trap valve (18) is connected with the outlet at the lower side of the freeze-drying box (10), the first path of the outlet of the freeze-drying box (10) is connected with the inlet of the evaporator (5), the outlet at the left side of the evaporator (5) is connected with the inlet of a second circulating pump (21), the outlet of the second circulating pump (21) is connected with the inlet of a fourth electromagnetic valve (20), and the outlet of the fourth electromagnetic valve (20) is connected with the inlet of the freeze-drying box (10); the outlet of the freeze-drying box (10) is connected with the inlet of the oil tank (19), the outlet of the oil tank (19) is connected with the inlet of the sixth electromagnetic valve (13), the outlet of the sixth electromagnetic valve (13) is connected with the inlet of the first circulating pump (14), the outlet of the first circulating pump (14) is connected with the inlet of the condenser (2), one path of the outlet of the condenser (2) is connected with the inlet of the radiator (11), the outlet of the radiator (11) is connected with the inlet of the second electromagnetic valve (12), the outlet of the second electromagnetic valve (12) is connected with the inlet of the first circulating pump (14) after being connected with the outlet of the sixth electromagnetic valve (13) in parallel, the other path of the outlet of the condenser (2) is connected with the inlet of the heater (15), the outlet of the heater (15) is connected with the inlet of the third electromagnetic valve (16), the outlet of the third electromagnetic valve (16) is connected with the inlet of the electric valve (17), and the outlet of the electric valve (17) is connected with the outlet of the fourth electromagnetic valve (20) in parallel and then is connected with the inlet of the freeze-drying box (10); the outlet of the freeze-drying box (10) is also connected with the outlet of an eighth electromagnetic valve (27), the inlet of the eighth electromagnetic valve (27) is connected with the outlet of a heating coil pipe (28) in the cold trap (8), the inlet of the heating coil pipe (28) is connected with the outlet of a seventh electromagnetic valve (26), and the inlet of the seventh electromagnetic valve (26) is connected with the outlet of the heater (15);
the operation method of the novel freeze dryer capable of recycling condensed water comprises four stages of prefreezing, sublimation drying, analytical drying and defrosting;
1) Pre-freezing: cooling the moisture in the material to freeze the moisture into a solid state; the fifth electromagnetic valve (24), the second electromagnetic valve (12), the first circulating pump (14), the fourth electromagnetic valve (20) and the second circulating pump (21) are opened, and the first electromagnetic valve (6), the heater (15), the third electromagnetic valve (16), the electric valve (17), the tank trap valve (18), the vacuum pump (22), the stop valve (23), the sixth electromagnetic valve (13), the seventh electromagnetic valve (26), the eighth electromagnetic valve (27) and the ninth electromagnetic valve (9) are closed;
refrigerant circuit in pre-freezing stage: the refrigerant vapor output by the refrigeration compressor (1) enters a condensing coil (2-1) in the condenser (2), a large amount of heat is discharged and then turns into high-temperature high-pressure liquid, the liquid passes through a liquid storage tank (3) and then enters a first throttle valve (4) through a fifth electromagnetic valve (24), the refrigerant turns into low-temperature low-pressure liquid after throttling, the low-temperature low-pressure liquid enters an evaporating coil (5-1) of the evaporator (5), and the low-temperature low-pressure refrigerant gas turns into low-temperature low-pressure refrigerant gas after absorbing heat and flows back to the refrigeration compressor (1);
prefreezing stage fluid medium circuit: one path of fluid medium is driven by a second circulating pump (21) to enter a freeze-drying box (10) through a fourth electromagnetic valve (20) after absorbing heat in an evaporator (5), and the absorbed heat in the box body flows back to the evaporator (5); the other path of fluid medium flows through the condenser (2) to be heated and then enters the radiator (11), and after radiating, the fluid medium flows through the second electromagnetic valve (12) and flows back to the condenser (2) under the driving of the first circulating pump (14); the fluid medium here is an oil or glycol solution;
2) The sublimation drying stage needs to be vacuumized, and is properly warmed up in a low-temperature environment, after the temperature is raised to the set temperature of the sublimation drying stage, the temperature is kept constant by switching cold and hot fluid media from an evaporator (5) and a condenser (2), and the set temperature of the sublimation drying stage is 5-10 ℃ lower than the eutectic point of the material, and the sublimation drying stage is heated in a split way and kept at a constant temperature; most of the water in the material in the sublimation drying stage is directly changed into a gas state from a solid state and is pumped away;
in a heating stage of heating in a sublimation drying stage, a first electromagnetic valve (6), a box trap valve (18), a third electromagnetic valve (16), an electric valve (17), a ninth electromagnetic valve (9) and a sixth electromagnetic valve (13) are opened, a compressor (1), a first circulating pump (14) and a vacuum pump (22) are started, and a fifth electromagnetic valve (24), a second electromagnetic valve (12), a fourth electromagnetic valve (20) and a second circulating pump (21) are closed; the seventh electromagnetic valve (26), the eighth electromagnetic valve (27) and the stop valve (23) are closed; in the heating process, if the opening of the electric valve (17) is regulated to the maximum and the temperature in the freeze-drying box (10) is still lower than the set temperature in the sublimation drying stage after the time is 10min, the heater (15) starts to heat, otherwise, the heater (15) is not started;
at the moment, the refrigerant vapor output by the refrigeration compressor (1) enters a condensing coil (2-1) in the condenser (2), a large amount of heat is discharged and then turns into high-temperature high-pressure liquid, the liquid enters a second throttle valve (7) through a first electromagnetic valve (6) after passing through a liquid storage tank (3), the throttled refrigerant enters a coil (8-1) of a cold trap (8), and the refrigerant flows back to the refrigeration compressor (1) through a ninth electromagnetic valve (9); the refrigerant heats the fluid medium in the condensing coil (2-1), then enters the freeze-drying box (10) through the heater (15), the third electromagnetic valve (16) and the electric valve (17), and returns to the condensing coil (2-1) through the oil tank (19), the sixth electromagnetic valve (13) and the first circulating pump (14) after flowing out; the vacuum pump (22) operates, the air pressure in the freeze-drying box (10) is reduced, the moisture in the material starts to sublimate, the material enters the cold trap (8) through the box trap valve (18), and the material is condensed on the surface of the cold trap coil (8-1);
a constant temperature maintaining stage of the sublimation drying stage, wherein when the temperature is lower than the set temperature of the sublimation drying stage, the valve, the equipment switching and the operation method are the same as those of the heating stage of the sublimation drying stage; when the temperature is higher than the set temperature in the sublimation drying stage, the first electromagnetic valve (6), the ninth electromagnetic valve (9), the box trap valve (18), the second electromagnetic valve (12), the fourth electromagnetic valve (20), the fifth electromagnetic valve (24) and the second circulating pump (21) are opened, the compressor (1), the first circulating pump (14) and the vacuum pump (22) are started, and the third electromagnetic valve (16), the electric valve (17), the sixth electromagnetic valve (13), the seventh electromagnetic valve (26), the eighth electromagnetic valve (27), the stop valve (23) and the heater (15) are closed; the refrigerant vapor output by the refrigeration compressor (1) enters a condensing coil (2-1) in the condenser (2), is changed into high-temperature and high-pressure liquid after heat release, is divided into two paths after passing through a liquid storage tank (3), and one path of liquid passes through a first electromagnetic valve (6), a second throttle valve (7) and a coil (8-1) entering a cold trap (8) to provide cold energy for capturing the water vapor, and then flows back to the refrigeration compressor (1) through a ninth electromagnetic valve (9); the other path enters an evaporation coil (5-1) of an evaporator (5) through a fifth electromagnetic valve (24), absorbs heat and becomes low-temperature and low-pressure refrigerant gas, and the refrigerant gas is converged with the refrigerant flowing out of a ninth electromagnetic valve (9) and flows back to the refrigeration compressor (1); the fluid medium is heated by the condenser (2), flows out and enters the radiator (11), and after radiating heat, flows back to the condenser (2) by the driving of the first circulating pump (14) through the second electromagnetic valve (12);
3) And (3) analysis and drying: the materials are further heated under the vacuum condition, and a certain temperature is maintained, so that the bound water in the materials is separated out; the analysis and drying stage is divided into two stages of heating at a rising temperature and keeping the temperature constant; the residual moisture in the materials is pumped out in a gaseous state in the analysis stage; setting the temperature in the analysis drying stage to be more than 30;
analyzing the switching states of a valve and a pump in a heating stage of the drying stage and an operation method, wherein the switching states of the valve and the pump in the heating stage of the sublimation drying stage and the operation method are completely the same as those of the valve and the pump in the heating stage of the sublimation drying stage in the step 2); analyzing the switching state and the operation method of a valve and a pump in a constant temperature maintaining stage of the drying stage, wherein the switching state and the operation method of the valve and the pump in the constant temperature maintaining stage of the sublimation drying stage in the step 2) are completely the same;
4) A defrosting stage, namely melting frost condensed in the cold trap, and collecting the frost by using a water collector (25);
the stop valve (23), the sixth electromagnetic valve (13), the first circulating pump (14), the seventh electromagnetic valve (26) and the eighth electromagnetic valve (27) are opened, and the tank trap valve (18), the second electromagnetic valve (12), the third electromagnetic valve (16), the electric valve (17), the fourth electromagnetic valve (20), the first electromagnetic valve (6), the ninth electromagnetic valve (9), the fifth electromagnetic valve (24), the second electromagnetic valve (12), the fourth electromagnetic valve (20) and the second circulating pump (21) are closed; the compressor (1) and the vacuum pump (22) stop running; the heater (15) starts heating;
the refrigerant does not flow in the defrosting stage;
fluid medium circuit in defrosting stage: under the drive of a first circulating pump (14), fluid medium enters a heater (15) through a condenser (2) without heat exchange to absorb heat, after the temperature of the fluid medium rises, the fluid medium enters a heating coil (28) in a cold trap (8) through a seventh electromagnetic valve (26), after the temperature of the cold trap (8) rises, frost condensed on the coil (8-1) in the cold trap (8) is melted, melted condensed water enters a water collector (25) through a stop valve (23) to be collected, and the fluid medium after heat release is continuously circulated through an eighth electromagnetic valve (27), an oil tank (19), a sixth electromagnetic valve (13) and the first circulating pump (14).
2. The method according to claim 1, characterized in that the ninth electromagnetic valve (9) is a one-way valve.
3. The method according to claim 1, characterized in that the condenser (2) is a plate heat exchanger or a shell-and-tube heat exchanger or a double-tube heat exchanger.
4. A method of operating a new freeze dryer with recovery of condensed water according to claim 1, characterized in that the evaporator (5) is a plate heat exchanger or a shell-and-tube heat exchanger or a double tube heat exchanger.
5. The operation method of a novel freeze dryer capable of recycling condensed water according to claim 1, wherein the oil tank (19) is provided with an oil filling valve, when the liquid level in the oil tank (19) is lower than two thirds of the height of the oil tank, the oil is filled from the oil filling valve to a normal liquid level, the oil filling valve needs to be opened for exhausting before each operation, and the operation is closed in the normal operation.
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Effective date of registration: 20240109 Address after: 523429 The first floor of the factory building of Dongguan Hansen Investment Group Co., Ltd., No. 6 Keji 9th Road, Songshan Lake High tech Industrial Development Zone, Dongguan City, Guangdong Province Patentee after: Guangdong Hansen Biotechnology Co.,Ltd. Address before: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee before: Dragon totem Technology (Hefei) Co.,Ltd. Effective date of registration: 20240109 Address after: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Dragon totem Technology (Hefei) Co.,Ltd. Address before: 264003 No. 30 Qingquan Road, Laishan District, Yantai City, Shandong Province Patentee before: Yantai University |