CN111446463A - Industrial production process of flexible carbon-based bipolar plate of fuel cell - Google Patents

Industrial production process of flexible carbon-based bipolar plate of fuel cell Download PDF

Info

Publication number
CN111446463A
CN111446463A CN202010149444.7A CN202010149444A CN111446463A CN 111446463 A CN111446463 A CN 111446463A CN 202010149444 A CN202010149444 A CN 202010149444A CN 111446463 A CN111446463 A CN 111446463A
Authority
CN
China
Prior art keywords
plate
bipolar plate
flexible carbon
unipolar
bipolar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202010149444.7A
Other languages
Chinese (zh)
Other versions
CN111446463B (en
Inventor
周凤满
周罡
江文根
章曙东
万书径
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Zhonghe Sky Technology Co ltd
Original Assignee
Zhejiang Zhonghe Sky Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Zhonghe Sky Technology Co ltd filed Critical Zhejiang Zhonghe Sky Technology Co ltd
Priority to CN202010149444.7A priority Critical patent/CN111446463B/en
Publication of CN111446463A publication Critical patent/CN111446463A/en
Application granted granted Critical
Publication of CN111446463B publication Critical patent/CN111446463B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0213Gas-impermeable carbon-containing materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention mainly discloses an industrial production process of a fuel cell flexible carbon-based bipolar plate, which sequentially comprises the following steps of S1 and a raw material plate pretreatment process; s2, after the pretreatment of the raw material plate is finished, the unipolar plate forming process is carried out; s3, cleaning the unipolar plate; s4, a monopolar plate arrangement process; s5, performing airtight treatment on the unipolar plate; s6, the unipolar plate after airtight treatment and the reforming tool enter a cleaning process together; s7, a monopolar plate leveling procedure; s8, gluing the polar plate; s9, a bipolar plate synthesis process; s10, a bipolar plate curing process; and S11, detecting the bipolar plate. The production efficiency is improved, the product percent of pass is improved, the labor intensity is reduced, the manufacturing cost is reduced, and the commercialized and large-scale manufacturing of the bipolar plate is realized.

Description

Industrial production process of flexible carbon-based bipolar plate of fuel cell
Technical Field
The invention relates to the technical field of fuel cells, in particular to an industrial production process of a flexible carbon-based bipolar plate of a fuel cell.
Background
Fuel cells are one of a number of electrochemical power sources, and more specifically, fuel cells are a process module that converts the energy of a chemical reaction directly into electrical energy. A fuel cell is greatly different from a general battery, in which an active material is stored inside the battery, so that the capacity of the battery is determined by the amount of the stored active material, and the active material of the fuel cell can be continuously input. The fuel cell mainly comprises a proton exchange membrane fuel cell and an alkaline fuel cellCells, phosphoric acid fuel cells, molten carbonate fuel cells, solid oxide fuel cells, and the like. The proton exchange membrane fuel cell is widely applied, and particularly, the proton exchange membrane fuel cell takes hydrogen and oxygen as reaction substances. The hydrogen-oxygen fuel cell has the advantages of large capacity, high specific energy, high conversion efficiency, wide power range and the like, has wide application prospect, and is known as the ultimate energy of twenty-first century. The single cell consists of bipolar plate and membrane electrode. The bipolar plate mainly has the following functions: providing current paths between adjacent cells, reactant gas distribution channels, cooling channels, separating fuel, coolant (water) and oxidant supplied to the cells, and oxidant (0) separating adjacent cells2) And a reducing agent (H)2) Therefore, the bipolar plate needs to have good electrical conductivity, reliable sealing performance, and mechanical strength necessary for providing stable structure of the stack.
In the prior art, the material of the fuel cell bipolar plate mostly adopts a composite plate or a metal plate, and the structure of a common bipolar plate surface flow field is a channel type structure on both sides of the polar plate, namely, a complex groove-convex channel structure is respectively processed on both sides of the monopolar plate. The "groove" portion functions as a gas transmission channel, and the "land" portion functions as a current path. The metal plate has high mechanical strength, good conductivity and good machining performance, but has poor corrosion resistance, is easy to corrode, and easily pollutes a membrane electrode to influence the service life of a fuel cell. In addition, the bipolar plates with the same volume have the advantages that the metal material plate is heavy, the manufacturing cost of the surface flow field is high, and meanwhile, the manufacturing cost is high due to the fact that the surface of the metal plate is subjected to a coating treatment process, so that the light weight of the galvanic pile cannot be achieved, the energy density is low, and meanwhile, the material cost and the processing cost are high, and the application is greatly limited.
Compared with the bipolar plate made of the flexible carbon-based plate, the flexible carbon-based plate is strong in corrosion resistance, good in electric conductivity, good in processability, large in thickness range, light in weight, and low in material cost and manufacturing cost. But because flexible carbon-based plate is fragile, loose material, it is high to protect the requirement in suppression, material in the transportation. Therefore, limited by material characteristics, the manufacturing of the flexible carbon-based bipolar plate is completed by manual operation at present, and the automation or even semi-automation of the manufacturing process cannot be realized. Due to the adoption of manual operation, the whole process has high requirement on the operating skills of operators, the consistency of the product quality is difficult to be effectively guaranteed, and meanwhile, due to the fact that large-scale production cannot be realized, the efficiency is low, the labor intensity is high, the loss is high, and the cost in the manufacturing process is greatly increased.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides an industrial production process of a flexible carbon-based bipolar plate of a fuel cell, which improves the production efficiency, improves the product percent of pass, reduces the labor intensity and the manufacturing cost, and realizes the commercial and large-scale manufacturing of the bipolar plate.
In order to achieve the purpose, the invention is realized by the following technical scheme: an industrial production process of a fuel cell flexible carbon-based bipolar plate sequentially comprises the following steps,
s1, a raw material plate pretreatment procedure;
s2, after the pretreatment of the raw material plate is finished, the unipolar plate forming process is carried out;
s3, cleaning the unipolar plate;
s4, a monopolar plate arrangement process;
s5, performing airtight treatment on the unipolar plate;
s6, the unipolar plate after airtight treatment and the reforming tool enter a cleaning process together;
s7, a monopolar plate leveling procedure;
s8, gluing the polar plate;
s9, a bipolar plate synthesis process;
s10, a bipolar plate curing process;
and S11, detecting the bipolar plate.
The invention further comprises: s1, a raw material plate pretreatment procedure, which comprises heating, dehumidifying and drying the flexible carbon-based raw material plate, and adsorbing and cleaning the surface dust to obtain a dry and clean raw material plate;
the single-pole plate forming process in the step S2 comprises the steps that after a raw material plate is conveyed to a forming machine through an automatic conveying system, a mechanical arm grabs the raw material plate and conveys the raw material plate into a forming die, the forming machine is started, after pressure is applied, the thickness of the raw material plate is compressed to 0.5-5mm, a required flow field is pressed on the upper surface or the upper surface and the lower surface of the raw material plate, the raw material plate is pressed into a flexible carbon-based single-pole plate, and after the actions are finished, the mechanical arm grabs the manufactured flexible carbon-based single-pole plate onto the conveying system and conveys the flexible carbon;
s3, a single-pole plate cleaning process comprises the steps that the flexible carbon-based single-pole plate reaches a buffer storage workbench, the flexible carbon-based single-pole plate is grabbed to the cleaning workbench of the full-automatic cleaning machine by a manipulator, the waste edges of the single-pole plate are cleaned, then the flexible carbon-based single-pole plate is sent to a reversible cleaning mechanism by the manipulator to be scrubbed on two sides of the single-pole plate, then the manipulator of the automatic surface cleaning machine of the single-pole plate grabs the flexible carbon-based single-pole plate to the turnover workbench, the single-pole plate is sent to a transition tool by the cleaning manipulator, and then the flexible carbon-based single-pole plate is automatically and accurately sent to the cleaning tool by the transition tool;
s4, a single-pole plate arrangement process, wherein the loaded arrangement tool and the flexible carbon-based single-pole plate are transferred to the single-pole plate airtight treatment step;
s5, hoisting a certain number of finished flexible carbon-based unipolar plates into an airtight working tank through a hoisting and carrying mechanism, closing a sealing cover, vacuumizing the airtight working tank, injecting raw material liquid to a certain liquid level of the working tank, maintaining the pressure until the vacuum degree in the airtight working tank reaches a set value, breaking the vacuum of the working tank after the pressure is maintained for a set time, releasing the pressure and draining the pressure after the set value is reached, opening a working tank cover, hoisting and taking out the finished plate, and transferring to a cleaning process.
The method comprises the steps of S6, enabling the hermetically treated unipolar plate and the reforming tool to enter a cleaning process, immersing the hermetically treated flexible carbon-based unipolar plate and the reforming tool into a cleaning tank together, removing residues of the flexible carbon-based polar plate, immersing the flexible carbon-based unipolar plate into a hot water curing tank for high-temperature curing, drying the flexible carbon-based unipolar plate and the reforming tool in a drying tank, conveying the flexible carbon-based unipolar plate and the reforming tool into a dehumidifying oven through a hoisting process module for drying, and transferring to a leveling process after dehumidifying and drying;
s7, a single-pole-plate leveling procedure, which comprises the steps of placing the flexible carbon-based pole plate after dehumidification and drying in a leveling tool, starting a press to pressurize, conveying the leveling tool into a leveling furnace integrally, and after leveling, transferring the finished flexible carbon-based pole plate to a gluing process module to carry out gluing treatment;
the pole plate gluing process in the step S8 includes grabbing the flexible carbon-based unipolar plate to a gluing machine working platform through a manipulator on a unipolar plate feeding machine, positioning and fixing, then carrying out glue dispensing or screen printing gluing, after the gluing is finished, grabbing the glued unipolar plate to a bipolar plate synthesis process module or a unipolar plate blanking working platform through the manipulator on the unipolar plate feeding machine, and then carrying out flow blanking or transferring to the bipolar plate synthesis process module through a conveying system;
s9, a bipolar plate synthesizing process, which comprises the steps of placing the flexible carbon-based unipolar plate coated with glue in a bipolar plate synthesizing tool, accurately placing the paired unipolar plates, pressurizing, and transferring to a bipolar plate curing step;
in the step of the S10 bipolar plate curing process, the bonded bipolar plate flows into a bipolar plate curing furnace along with a tool to be cured, and the bipolar plate curing furnace automatically feeds and discharges materials to complete the synthesis of the bipolar plate according to the temperature control;
and step S11, a bipolar plate detection procedure, namely, sending the bipolar plate into a bipolar plate detection device, and detecting the bipolar plate, wherein the bipolar plate meeting the requirements is the finished product flexible carbon-based bipolar plate.
The invention further comprises: the bipolar plate cutting process is selected to be carried out after the bipolar plate curing process, the multi-connected-piece structure to be cut is sent into the bipolar plate cutting module, the multi-connected-piece bipolar plate is cut through the hydraulic driving upper die of the cutting machine, the bipolar plate with the suitable specification is obtained, and the cut bipolar plate is sent into the bipolar plate detection equipment to be detected.
The invention further comprises: the head tank and the airtight working tank are both provided with a jacket, the top of the head tank and the airtight working tank is provided with a vacuum pumping pipeline valve system, the airtight working tank is a pressure container with a sealed structure, a pressure adjusting system is arranged on the airtight working tank, and the bottom of the tank body is provided with a drain outlet.
The invention further comprises: the dehumidification oven is airtight structure, and the top sets up the sealing door that can open, and the inside heated air circulation of dehumidification oven, airtight working tank, washing tank and hot water solidification groove's top set up hoist and mount transport mechanism.
The invention further comprises: the gluing station can adopt a dispenser or a screen printing machine.
The invention further comprises: the bipolar plate curing oven is provided with a temperature control system and a hot air circulating system, and a heat insulation device is arranged in the bipolar plate curing oven.
The invention further comprises: the bipolar plate curing furnace is divided into five functional sections, namely a feeding functional section, a heating functional section, a constant temperature functional section, a cooling functional section and a discharging functional section, wherein each functional section is provided with a temperature sensor, the temperature is controlled by PID (proportion integration differentiation), the temperature is ensured to be accurate and controllable, and automatic doors are sealed among the heating functional section, the constant temperature functional section and the cooling functional section, and are sealed by the automatic doors.
The invention further comprises: the bipolar plate curing furnace is provided with a temperature control system and a hot air circulating system, so that the temperature in the furnace is ensured to meet the process requirements.
The invention further comprises: the bipolar plate curing oven is internally provided with a heat insulation device, the outer side of the bipolar plate curing oven is provided with an observation window, and the inner part of the bipolar plate curing oven is provided with a lighting lamp. So as to observe the operation condition of the internal product from the outside of the furnace body.
The invention has the following beneficial effects:
the continuous production of the flexible carbon-based bipolar plate can be realized, the consistency of the product quality is achieved through the continuous production and the system control of the production process, the production efficiency is improved, the product qualification rate is improved, the labor intensity is reduced, the manufacturing cost is reduced, and the commercialized and large-scale manufacturing of the bipolar plate is realized.
Detailed Description
An industrial production process of a fuel cell flexible carbon-based bipolar plate sequentially comprises the following steps,
s1, a raw material plate pretreatment procedure, which comprises heating, dehumidifying and drying the flexible carbon-based raw material plate, and adsorbing and cleaning the dust on the surface to obtain a dry and clean raw material plate;
s2, after the raw material plate is pretreated, the raw material plate enters a unipolar plate forming process, the raw material plate is conveyed to a forming machine through an automatic conveying system, a mechanical arm grabs the raw material plate and conveys the raw material plate into a forming die, the forming machine is started, after pressure is applied, the thickness of the raw material plate is compressed to 0.5-5mm, meanwhile, a required flow field is pressed on the upper surface or the upper surface and the lower surface of the raw material plate, the raw material plate is pressed into a flexible carbon-based unipolar plate, and after the actions are completed, the mechanical arm grabs the manufactured flexible carbon-based unipolar plate onto the conveying system and conveys the flexible carbon-based unipolar plate;
s3, a single-pole plate cleaning process, which comprises the steps that a flexible carbon-based single-pole plate reaches a buffer storage workbench, the flexible carbon-based single-pole plate is grabbed to the cleaning workbench of the full-automatic cleaning machine by a manipulator, the waste edges of the single-pole plate are cleaned, then the flexible carbon-based single-pole plate is conveyed to a reversible cleaning mechanism by the manipulator to perform two-side scrubbing and cleaning work on the single-pole plate, and the other side of the single-pole plate is automatically turned and cleaned when the cleaned brush finishes one side each time; the device can also be a rolling brush, the rolling is carried out while brushing, meanwhile, a dust absorption pipeline system is arranged, dust enters a dust collection device, then a manipulator of the automatic single-pole plate leveling machine grabs the flexible carbon-based single-pole plate with the cleaned surface to a turnover worktable, the single-pole plate is sent to a transition tool through the leveling manipulator, and then the transition tool automatically and accurately sends the flexible carbon-based single-pole plate into the leveling tool;
s4, a single-pole plate arrangement process, wherein the loaded arrangement tool and the flexible carbon-based single-pole plate are transferred to the single-pole plate airtight treatment step;
s5, a monopolar plate airtight treatment process, which mainly completes monopolar plate leakage stoppage, comprises a raw material tank and an airtight working tank, wherein the raw material tank and the airtight working tank are provided with an accurate temperature control system, the raw material tank and the airtight working tank are both provided with a jacket, the tops of the raw material tank and the airtight working tank are provided with a vacuum pumping pipeline valve system, the airtight working tank is a pressure container with a sealing structure, the airtight working tank can respectively bear positive pressure and negative pressure, the upper part of the airtight working tank is provided with a pressure regulating system, and the bottom of the tank body is provided with a. Firstly, hoisting a certain number of finished flexible carbon-based unipolar plates together with a finishing tool into an airtight working tank through a hoisting and carrying mechanism, closing a sealing cover, vacuumizing the airtight working tank, injecting raw materials into the working tank from a raw material tank, continuously vacuumizing the working tank until the liquid level in the working tank is in place, maintaining the pressure for a set time, breaking the vacuum of the working tank, releasing the pressure and draining after the set time is reached, opening a working tank cover, hoisting and taking out the finishing tool, and transferring to a cleaning process;
s6, the unipolar plate after airtight treatment and the reforming tool enter a cleaning process, the unipolar plate after airtight treatment and the reforming tool are immersed into a cleaning tank together, the cleaning tank is a closed structure box body, cleaning solution is filled in the box body, residues of the unipolar plate after flexible carbon are removed, then the unipolar plate after airtight treatment and the reforming tool are immersed into a hot water solidification tank for airtight high-temperature solidification treatment, then the unipolar plate is dried through a drying tank, finally the unipolar plate is conveyed into a dehumidification drying oven for drying treatment through a hoisting process module, and after dehumidification and drying are finished, the unipolar plate and the reforming tool are transferred to a leveling process treatment step;
s7, a unipolar plate leveling procedure, which comprises the steps of placing the flexible carbon-based polar plate after dehumidification and drying in a leveling tool, starting a press to pressurize, integrally conveying the leveling tool into a leveling furnace, and after leveling, transferring the finished flexible carbon-based polar plate to a gluing process module to carry out gluing treatment;
and S8, gluing the polar plate, wherein the gluing process comprises the steps that the flexible carbon-based unipolar plate is grabbed to a working platform of a gluing machine through a manipulator on a unipolar plate feeding machine, and is positioned and fixed, and the gluing station can adopt a dispenser or a screen printing machine. Dispensing or screen printing glue, after the glue is coated, the manipulator on the unipolar plate feeding machine grabs the unipolar plate coated with the glue to the bipolar plate synthesis process module or a unipolar plate blanking worktable, and then the unipolar plate is circularly blanked by a conveying system or is transferred to the bipolar plate synthesis process module;
s9, a bipolar plate synthesis procedure, which comprises the steps of placing the flexible carbon-based unipolar plate coated with glue in a bipolar plate synthesis tool, then accurately placing the paired unipolar plates, then pressurizing, and transferring to a bipolar plate curing step;
s10, a bipolar plate curing process, wherein the bonded bipolar plate flows into a bipolar plate curing furnace along with the tool to be cured, and the bipolar plate curing furnace automatically feeds and discharges materials to complete the synthesis of the bipolar plate according to the temperature control;
and S11, a bipolar plate detection process, wherein the bipolar plate cutting process is selected after the bipolar plate solidification process, the multi-connected-piece structure to be cut is sent to a bipolar plate cutting module, the multi-connected-piece bipolar plate is cut by a hydraulically-driven cutting machine upper die to obtain a bipolar plate with a suitable specification, and the cut bipolar plate is sent to a bipolar plate detection device for detection. And for a multi-connected structure which does not need to be cut, the bipolar plate is directly sent into bipolar plate detection equipment, the bipolar plate is detected, and the bipolar plate meeting the requirements is the finished product flexible carbon-based bipolar plate.
The dehumidification oven is of a closed structure, the top of the dehumidification oven is provided with an openable sealing door, hot air in the dehumidification oven body circulates, and air in the dehumidification oven body is heated and dehumidified outside and then is sent into the dehumidification oven body, so that energy consumption is saved; and a hoisting and carrying mechanism is arranged above the hot air circulation airtight working tank, the cleaning tank and the hot water curing tank in the box body.
The bipolar plate curing furnace is divided into five functional sections, namely a feeding functional section, a heating functional section, a constant temperature functional section, a cooling functional section and a discharging functional section, wherein each functional section is provided with a temperature sensor, the temperature is controlled by PID (proportion integration differentiation), the temperature is ensured to be accurate and controllable, and automatic doors are sealed among the heating functional section, the constant temperature functional section and the cooling functional section, and are sealed by the automatic doors. The bipolar plate curing furnace is provided with a temperature control system and a hot air circulating system, so that the temperature in the furnace is ensured to meet the process requirements. The bipolar plate curing oven is internally provided with a heat insulation device, the outer side of the bipolar plate curing oven is provided with an observation window, and the inner part of the bipolar plate curing oven is provided with a lighting lamp. So as to observe the operation condition of the internal product from the outside of the furnace body
The continuous production of the flexible carbon-based bipolar plate can be realized, the consistency of the product quality is achieved through the continuous production and the system control of the production process, the production efficiency is improved, the product qualification rate is improved, the labor intensity is reduced, the manufacturing cost is reduced, and the commercialized and large-scale manufacturing of the bipolar plate is realized.
The above-mentioned embodiments are only used for explaining the inventive concept of the present invention, and do not limit the protection of the claims of the present invention, and any insubstantial modifications of the present invention using this concept shall fall within the protection scope of the present invention.

Claims (9)

1. An industrial production process of a fuel cell flexible carbon-based bipolar plate is characterized by sequentially comprising the following steps,
s1, a raw material plate pretreatment procedure;
s2, after the pretreatment of the raw material plate is finished, the unipolar plate forming process is carried out;
s3, cleaning the unipolar plate;
s4, a monopolar plate arrangement process;
s5, performing airtight treatment on the unipolar plate;
s6, the unipolar plate after airtight treatment and the reforming tool enter a cleaning process together;
s7, a monopolar plate leveling procedure;
s8, gluing the unipolar plate;
s9, a bipolar plate synthesis process;
s10, a bipolar plate curing process;
and S11, detecting the bipolar plate.
2. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein:
s1, a raw material plate pretreatment procedure, which comprises heating, dehumidifying and drying the flexible carbon-based raw material plate, and adsorbing and cleaning the surface dust to obtain a dry and clean raw material plate;
the single-pole plate forming process in the step S2 comprises the steps that after a raw material plate is conveyed to a forming machine through an automatic conveying system, a mechanical arm grabs the raw material plate and conveys the raw material plate into a forming die, the forming machine is started, after pressure is applied, the thickness of the raw material plate is compressed to 0.5-5mm, a required flow field is pressed on the upper surface or the upper surface and the lower surface of the raw material plate, the raw material plate is pressed into a flexible carbon-based single-pole plate, and after the actions are finished, the mechanical arm grabs the manufactured flexible carbon-based single-pole plate onto the conveying system and conveys the flexible carbon;
s3, a single-pole plate cleaning process comprises the steps that the flexible carbon-based single-pole plate reaches a buffer storage workbench, the flexible carbon-based single-pole plate is grabbed to the cleaning workbench of the full-automatic cleaning machine by a manipulator, the waste edges of the single-pole plate are cleaned, then the flexible carbon-based single-pole plate is sent to a reversible cleaning mechanism by the manipulator to be scrubbed on two sides of the single-pole plate, then the manipulator of the automatic surface cleaning machine of the single-pole plate grabs the flexible carbon-based single-pole plate to the turnover workbench, the single-pole plate is sent to a transition tool by the cleaning manipulator, and then the flexible carbon-based single-pole plate is automatically and accurately sent to the cleaning tool by the transition tool;
s4, a single-pole plate arrangement process, wherein the loaded arrangement tool and the flexible carbon-based single-pole plate are transferred to the single-pole plate airtight treatment step;
s5, a single-pole plate airtight treatment process, which comprises the steps of hoisting a certain number of finished flexible carbon-based single-pole plates together with a reforming tool into an airtight working tank through a hoisting and carrying mechanism, vacuumizing the airtight working tank after closing a sealing cover and sealing, injecting raw material liquid into the working tank to a certain liquid level, vacuumizing the airtight working tank after the vacuum degree in the airtight working tank reaches, maintaining the pressure for a set time, breaking the vacuum of the working tank, releasing pressure and draining after the set time is reached, opening a working tank cover, hoisting and taking out the reforming tool, and transferring to a cleaning process.
The method comprises the steps of S6, enabling the hermetically treated unipolar plate and the reforming tool to enter a cleaning process, immersing the hermetically treated flexible carbon-based unipolar plate and the reforming tool into a cleaning tank together, removing residues of the flexible carbon-based polar plate, immersing the flexible carbon-based unipolar plate into a hot water curing tank for high-temperature curing, drying the flexible carbon-based unipolar plate and the reforming tool in a drying tank, conveying the flexible carbon-based unipolar plate and the reforming tool into a dehumidifying oven through a hoisting process module for drying, and transferring to a leveling process after dehumidifying and drying;
s7, a single-pole-plate leveling procedure, which comprises the steps of placing the flexible carbon-based pole plate after dehumidification and drying in a leveling tool, starting a press to pressurize, conveying the leveling tool into a leveling furnace integrally, and after leveling, transferring the finished flexible carbon-based pole plate to a gluing process module to carry out gluing treatment;
the pole plate gluing process in the step S8 includes grabbing the flexible carbon-based unipolar plate to a gluing machine working platform through a manipulator on a unipolar plate feeding machine, positioning and fixing, then carrying out glue dispensing or screen printing gluing, after the gluing is finished, grabbing the glued unipolar plate to a bipolar plate synthesis process module or a unipolar plate blanking working platform through the manipulator on the unipolar plate feeding machine, and then carrying out flow blanking or transferring to the bipolar plate synthesis process module through a conveying system;
s9, a bipolar plate synthesizing process, which comprises the steps of placing the flexible carbon-based unipolar plate coated with glue in a bipolar plate synthesizing tool, accurately placing the paired unipolar plates, pressurizing, and transferring to a bipolar plate curing step;
in the step of the S10 bipolar plate curing process, the bonded bipolar plate flows into a bipolar plate curing furnace along with a tool to be cured, and the bipolar plate curing furnace automatically feeds and discharges materials to complete the synthesis of the bipolar plate according to the temperature control;
and step S11, a bipolar plate detection procedure, namely, sending the bipolar plate into a bipolar plate detection device, and detecting the bipolar plate, wherein the bipolar plate meeting the requirements is the finished product flexible carbon-based bipolar plate.
3. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the bipolar plate cutting process is selected to be carried out after the bipolar plate curing process, the multi-connected-piece structure to be cut is sent into the bipolar plate cutting module, the multi-connected-piece bipolar plate is cut through the hydraulic driving upper die of the cutting machine, the bipolar plate with the suitable specification is obtained, and the cut bipolar plate is sent into the bipolar plate detection equipment to be detected.
4. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the head tank and the airtight working tank are both provided with a jacket, the top of the head tank and the airtight working tank is provided with a vacuum pumping pipeline valve system, the airtight working tank is a pressure container with a sealed structure, a pressure adjusting system is arranged on the airtight working tank, and the bottom of the tank body is provided with a drain outlet.
5. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the dehumidification oven is airtight structure, and the top sets up the sealing door that can open, and the inside heated air circulation of dehumidification oven, airtight working tank, washing tank and hot water solidification groove's top set up hoist and mount transport mechanism.
6. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the gluing station can adopt a dispenser or a screen printing machine.
7. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the bipolar plate curing furnace is divided into five functional sections, namely a feeding functional section, a heating functional section, a constant temperature functional section, a cooling functional section and a discharging functional section, wherein each functional section is provided with a temperature sensor, the temperature is controlled by PID, and automatic doors are sealed among the heating functional section, the constant temperature functional section and the cooling functional section and are sealed outwards.
8. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the bipolar plate curing oven is provided with a temperature control system and a hot air circulating system.
9. The industrial production process of the flexible carbon-based bipolar plate of the fuel cell according to claim 1, wherein: the bipolar plate curing oven is internally provided with a heat insulation device, the outer side of the bipolar plate curing oven is provided with an observation window, and the inner part of the bipolar plate curing oven is provided with a lighting lamp.
CN202010149444.7A 2020-03-06 2020-03-06 Industrial production process of flexible carbon-based bipolar plate of fuel cell Active CN111446463B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010149444.7A CN111446463B (en) 2020-03-06 2020-03-06 Industrial production process of flexible carbon-based bipolar plate of fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010149444.7A CN111446463B (en) 2020-03-06 2020-03-06 Industrial production process of flexible carbon-based bipolar plate of fuel cell

Publications (2)

Publication Number Publication Date
CN111446463A true CN111446463A (en) 2020-07-24
CN111446463B CN111446463B (en) 2021-11-12

Family

ID=71655776

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010149444.7A Active CN111446463B (en) 2020-03-06 2020-03-06 Industrial production process of flexible carbon-based bipolar plate of fuel cell

Country Status (1)

Country Link
CN (1) CN111446463B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112366331A (en) * 2020-12-07 2021-02-12 无锡先导自动化设备股份有限公司 Fuel cell graphite bipolar plate production system
CN112563528A (en) * 2020-12-15 2021-03-26 广东国鸿氢能科技有限公司 Preparation method of compression molding bipolar plate
CN114464838A (en) * 2022-02-16 2022-05-10 安徽瑞氢动力科技有限公司 Method for manufacturing fuel cell bipolar plate

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070111078A1 (en) * 2005-11-11 2007-05-17 Nisshinbo Industries, Inc. Fuel cell bipolar plate
CN1992399A (en) * 2005-12-28 2007-07-04 大连新源动力股份有限公司 Method for preparation of flexible graphite material for fuel cell with groove plate on both sides
CN101143395A (en) * 2007-10-29 2008-03-19 大连交通大学 Stainless steel dual-polar plate welding method
US20100248052A1 (en) * 2009-03-27 2010-09-30 Sony Corporation Fuel cell, fuel cell system, and electronic device
US20110262829A1 (en) * 2010-04-22 2011-10-27 Gm Global Technology Operations, Inc. Electroformed bipolar plates for fuel cells
US20110281192A1 (en) * 2010-05-13 2011-11-17 Thomas Jones Method for producing bipolar plates
CN102569842A (en) * 2012-01-13 2012-07-11 南京航空航天大学 Preparation method of hybrid ordered mesoporous carbon coat for protecting stainless steel bipolar plate of proton exchange membrane fuel cell
CN205133710U (en) * 2015-11-20 2016-04-06 江西凯美达铝业有限公司 Efficient aluminium alloy ageing furnace
CN106935885A (en) * 2017-03-10 2017-07-07 中国科学院青岛生物能源与过程研究所 A kind of fuel cell flow field structure of high porosity porous carbon filling and preparation method thereof
CN108172859A (en) * 2016-12-07 2018-06-15 中国科学院大连化学物理研究所 A kind of bipolar plates used for high-temperature fuel cell and its manufacturing method
CN108296206A (en) * 2018-02-07 2018-07-20 广东国鸿氢能科技有限公司 A kind of cleaning storage tooling of fuel battery double plates
CN108311341A (en) * 2018-02-07 2018-07-24 深圳市世椿智能装备股份有限公司 Dispenser, the automatic assembly line of fuel battery double plates
CN109216713A (en) * 2018-10-31 2019-01-15 长兴欧森科技有限公司 A kind of fuel cell flexible graphite bi-polar plate volume production production system and its production method
CN109514904A (en) * 2018-09-30 2019-03-26 武汉喜玛拉雅光电科技股份有限公司 A kind of rolling process of fuel battery double plates

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070111078A1 (en) * 2005-11-11 2007-05-17 Nisshinbo Industries, Inc. Fuel cell bipolar plate
CN1992399A (en) * 2005-12-28 2007-07-04 大连新源动力股份有限公司 Method for preparation of flexible graphite material for fuel cell with groove plate on both sides
CN101143395A (en) * 2007-10-29 2008-03-19 大连交通大学 Stainless steel dual-polar plate welding method
US20100248052A1 (en) * 2009-03-27 2010-09-30 Sony Corporation Fuel cell, fuel cell system, and electronic device
US20110262829A1 (en) * 2010-04-22 2011-10-27 Gm Global Technology Operations, Inc. Electroformed bipolar plates for fuel cells
US20110281192A1 (en) * 2010-05-13 2011-11-17 Thomas Jones Method for producing bipolar plates
CN102569842A (en) * 2012-01-13 2012-07-11 南京航空航天大学 Preparation method of hybrid ordered mesoporous carbon coat for protecting stainless steel bipolar plate of proton exchange membrane fuel cell
CN205133710U (en) * 2015-11-20 2016-04-06 江西凯美达铝业有限公司 Efficient aluminium alloy ageing furnace
CN108172859A (en) * 2016-12-07 2018-06-15 中国科学院大连化学物理研究所 A kind of bipolar plates used for high-temperature fuel cell and its manufacturing method
CN106935885A (en) * 2017-03-10 2017-07-07 中国科学院青岛生物能源与过程研究所 A kind of fuel cell flow field structure of high porosity porous carbon filling and preparation method thereof
CN108296206A (en) * 2018-02-07 2018-07-20 广东国鸿氢能科技有限公司 A kind of cleaning storage tooling of fuel battery double plates
CN108311341A (en) * 2018-02-07 2018-07-24 深圳市世椿智能装备股份有限公司 Dispenser, the automatic assembly line of fuel battery double plates
CN109514904A (en) * 2018-09-30 2019-03-26 武汉喜玛拉雅光电科技股份有限公司 A kind of rolling process of fuel battery double plates
CN109216713A (en) * 2018-10-31 2019-01-15 长兴欧森科技有限公司 A kind of fuel cell flexible graphite bi-polar plate volume production production system and its production method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SHU-HANG LIAO ET AL: "Preparation and properties of carbon nanotube-reinforced vinyl ester/nanocomposite bipolar plates for polymer elecrolyte membrane fuel cells", 《JOURNAL OF POWER SOURCES》 *
张金营等: "PEMFC金属双极板成形工艺分析及数值模拟", 《模具工业》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112366331A (en) * 2020-12-07 2021-02-12 无锡先导自动化设备股份有限公司 Fuel cell graphite bipolar plate production system
CN112366331B (en) * 2020-12-07 2022-05-20 江苏氢导智能装备有限公司 Production system of graphite bipolar plate of fuel cell
CN112563528A (en) * 2020-12-15 2021-03-26 广东国鸿氢能科技有限公司 Preparation method of compression molding bipolar plate
CN114464838A (en) * 2022-02-16 2022-05-10 安徽瑞氢动力科技有限公司 Method for manufacturing fuel cell bipolar plate

Also Published As

Publication number Publication date
CN111446463B (en) 2021-11-12

Similar Documents

Publication Publication Date Title
CN111446463B (en) Industrial production process of flexible carbon-based bipolar plate of fuel cell
CN109473683B (en) Industrial mass production system and production method for fuel cell membrane electrode
CN109216713B (en) Flexible graphite bipolar plate mass production system of fuel cell and production method thereof
CN1883070A (en) Improved proton exchange membrane fuel cell
CN106953050A (en) A kind of high temperature resistance multilayer barrier film composite lithium ion cell barrier film and preparation method thereof
CN109244340B (en) Functional diaphragm coating material of lithium-sulfur battery and preparation method thereof
CN101752570B (en) Preparation method of proton exchange membrane fuel cell electrode
CN105720317A (en) Recycling method and apparatus for waste lithium ion battery
CN101702439B (en) Catalyst coated membrane electrode of fuel cell with self-moistening function and preparation method thereof
CN101783416A (en) Method for manufacturing lithium ion battery
CN210379266U (en) Continuous hydrophobic treatment equipment for gas diffusion layer of fuel cell
CN113488712A (en) Discharging device and method for intermittent closed power lithium battery
CN117525659A (en) Automatic stripping equipment for lithium battery pole piece
CN106558662B (en) Ion-conductive membranes, flow battery and preparation method using the ion-conductive membranes
CN1581567A (en) Solid polymer Zinc-air cell preparing method
CN111261900B (en) Activation method of cathode open type air-cooled fuel cell membrane electrode
CN207062408U (en) A kind of electrolytic copper foil electroplating bath
CN214065445U (en) Drying box for lithium battery production and processing
CN213687565U (en) Drying cabinet is used in lithium cell production
CN211350868U (en) Production device for lithium battery electrolyte
CN111403827B (en) Air cooling formation method and air cooling formation system for lead-acid storage battery
CN115117380A (en) Porous bipolar plate and preparation method thereof
CN113369238B (en) Method and device for cleaning graphite bipolar plate
CN213556893U (en) Stirring cooling device and automatic stirring cooling equipment with same
CN108110366A (en) A kind of processing method of waste and old lithium ion battery

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant