CN111410899A - Photocureable coating and preparation method and application thereof - Google Patents

Photocureable coating and preparation method and application thereof Download PDF

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CN111410899A
CN111410899A CN202010343196.XA CN202010343196A CN111410899A CN 111410899 A CN111410899 A CN 111410899A CN 202010343196 A CN202010343196 A CN 202010343196A CN 111410899 A CN111410899 A CN 111410899A
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coating
acrylate
pull head
slider
photocureable
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CN111410899B (en
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尹利国
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Zhejiang Weixing Industrial Development Co Ltd
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Zhejiang Weixing Industrial Development Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B19/00—Slide fasteners
    • A44B19/24—Details
    • A44B19/26—Sliders
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention belongs to the field of coatings, and particularly relates to a photocureable coating as well as a preparation method and application thereof. The photocureable coating provided by the invention comprises the following components in percentage by mass: 20-60% of epoxy acrylate; 5-35% of polyurethane acrylate; 10-40% of acrylate; 2-6% of 2-phenoxyethyl acrylate; 0.3-1% of 1-hydroxycyclohexyl phenyl ketone; 0.3-1% of an organic silicon defoaming agent; 0.3-1% of polyether modified polysiloxane. According to the invention, the photocureable coating with good wear resistance, washing resistance and yellowing resistance is obtained by optimally designing the component formula of the photocureable coating. The coating is very suitable for serving as a coating material on the outermost layer of the pull head, is used for protecting the pull head, solves the problems that a color film on the surface of the pull head is easy to wear and yellow, and prolongs the service life of the pull head. In addition, the photocureable coating provided by the invention does not contain volatile organic solvents, and is green and environment-friendly.

Description

Photocureable coating and preparation method and application thereof
Technical Field
The invention belongs to the field of coatings, and particularly relates to a photocureable coating as well as a preparation method and application thereof.
Background
The pull head is an important component of the clothing accessories, and for the uniformity of the overall appearance of the clothing, the shape and the appearance of the pull head on the clothing are correspondingly designed and produced according to the current fashion trend. In order to make the slider show different colors to meet the market demand, the most common method adopted at present is to paste films with various colors on the surface of the slider.
Although diversified sticking films with various colors greatly enrich the types of sliders, most sticking films do not have wear resistance, so that a protective coating needs to be coated on the surface of the sticking film. At present, the surface film of the pull head is protected by mainly adopting epoxy resin thermosetting paint, but due to the fact that the abrasion resistance, the washing resistance and the yellowing resistance of the epoxy resin are not enough, the surface film of the pull head is obviously abraded and yellowed after being drawn together or washed for many times.
Disclosure of Invention
In view of this, the present invention aims to provide a photocurable coating, and a preparation method and an application thereof, and the photocurable coating provided by the present invention has good wear resistance, good washing resistance and good yellowing resistance.
The invention provides a photocureable coating which comprises the following components in percentage by mass:
Figure BDA0002469152840000011
preferably, the epoxy acrylate is under the trademark DY 1101; the polyurethane acrylate is named Agisyn670A 2; the grade of the acrylic ester is V-5500; the grade of the organic silicon defoaming agent is byk-067A; the grade of the polyether modified polysiloxane is SF-733.
Preferably, the photocurable coating comprises, in mass percent:
Figure BDA0002469152840000021
the invention provides a preparation method of the photocureable coating, which comprises the following steps:
mixing epoxy acrylate, polyurethane acrylate, 2-phenoxyethyl acrylate, 1-hydroxycyclohexyl phenyl ketone, an organic silicon defoaming agent and polyether modified polysiloxane according to a proportion to obtain the photocuring coating.
Preferably, the mixing is carried out in a disperser.
The invention provides a pull head, wherein the outermost layer of the pull head is a photocuring coating, and the photocuring coating is formed by ultraviolet curing the photocuring coating in the technical scheme.
Preferably, the thickness of the photocuring coating is 3-8 μm.
Preferably, the slider comprises: the zipper puller comprises a puller body, a color film and a light curing coating, wherein the color film is compounded on the surface of the puller body, and the light curing coating is compounded on the surface of the color film.
The invention provides a zipper, which comprises the zipper head in the technical scheme.
The invention provides an application of the photocureable coating in the technical scheme as a coating material of the outermost layer of the pull head.
Compared with the prior art, the invention provides a photocureable coating and a preparation method and application thereof. The photocureable coating provided by the invention comprises the following components in percentage by mass: 20-60% of epoxy acrylate; 5-35% of polyurethane acrylate; 10-40% of acrylate; 2-6% of 2-phenoxyethyl acrylate; 0.3-1% of 1-hydroxycyclohexyl phenyl ketone; 0.3-1% of an organic silicon defoaming agent; 0.3-1% of polyether modified polysiloxane. According to the invention, the photocureable coating with good wear resistance, washing resistance and yellowing resistance is obtained by optimally designing the component formula of the photocureable coating. The coating is very suitable for serving as a coating material on the outermost layer of the pull head, is used for protecting the pull head, solves the problems that a color film on the surface of the pull head is easy to wear and yellow, and prolongs the service life of the pull head. In addition, the photocureable coating provided by the invention does not contain volatile organic solvents, and is green and environment-friendly.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the provided drawings without creative efforts.
FIG. 1 is a digital photograph of the wear level of sliders with different washing grades according to an embodiment of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a photocureable coating which comprises the following components in percentage by mass:
Figure BDA0002469152840000031
the photocuring coating provided by the invention comprises epoxy acrylate, polyurethane acrylate, 2-phenoxyethyl acrylate, 1-hydroxycyclohexyl phenyl ketone, an organic silicon defoaming agent and polyether modified polysiloxane. The CAS number of the epoxy acrylate is 71281-65-7, the preferred mark is DY1101, and the epoxy acrylate is provided by KalinRuiyang chemical industry. In the present invention, the content of the epoxy acrylate in the photocurable coating is 20 to 60 wt%, and specifically may be 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt%, 29 wt%, 30 wt%, 31 wt%, 32 wt%, 33 wt%, 34 wt%, 35 wt%, 36 wt%, 37 wt%, 38 wt%, 39 wt%, 40 wt%, 41 wt%, 42 wt%, 43 wt%, 44 wt%, 45 wt%, 46 wt%, 47 wt%, 48 wt%, 49 wt%, 50 wt%, 51 wt%, 52 wt%, 53 wt%, 54 wt%, 55 wt%, 56 wt%, 57 wt%, 58 wt%, 59 wt%, or 60 wt%.
In the light-cured coating provided by the invention, the grade of the polyurethane acrylate is preferably Agisyn670A2, and the grade of the polyurethane acrylate is provided by Dismann of the Netherlands. In the present invention, the urethane acrylate may be contained in the photocurable coating in an amount of 5 to 35 wt%, specifically 5 wt%, 6 wt%, 7 wt%, 8 wt%, 9 wt%, 10 wt%, 11 wt%, 12 wt%, 13 wt%, 14 wt%, 15 wt%, 16 wt%, 17 wt%, 18 wt%, 19 wt%, 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt%, 29 wt%, 30 wt%, 31 wt%, 32 wt%, 33 wt%, 34 wt%, or 35 wt%.
In the photocurable coating provided by the present invention, the acrylate is preferably provided in a brand number of V-5500, and the acrylate is provided by the company DIC, Japan. In the present invention, the content of the acrylate in the photocurable coating material is 10 to 40 wt%, and specifically may be 10 wt%, 11 wt%, 12 wt%, 13 wt%, 14 wt%, 15 wt%, 16 wt%, 17 wt%, 18 wt%, 19 wt%, 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt%, 29 wt%, 30 wt%, 31 wt%, 32 wt%, 33 wt%, 34 wt%, 35 wt%, 36 wt%, 37 wt%, 38 wt%, 39 wt%, or 40 wt%.
In the present invention, the 2-phenoxyethyl acrylate may be present in the photocurable coating in an amount of 2 to 6 wt%, specifically 2 wt%, 2.1 wt%, 2.2 wt%, 2.3 wt%, 2.4 wt%, 2.5 wt%, 2.6 wt%, 2.7 wt%, 2.8 wt%, 2.9 wt%, 3 wt%, 3.1 wt%, 3.2 wt%, 3.3 wt%, 3.4 wt%, 3.5 wt%, 3.6 wt%, 3.7 wt%, 3.8 wt%, 3.9 wt%, 4 wt%, 4.1 wt%, 4.2 wt%, 4.3 wt%, 4.4 wt%, 4.5 wt%, 4.6 wt%, 4.7 wt%, 4.8 wt%, 4.9 wt%, 5 wt%, 5.1 wt%, 5.2 wt%, 5.3 wt%, 5.4 wt%, 5.5.5 wt%, 5.6 wt%, 5.7 wt%, 5.8 wt%, 5.9 wt%, or 6 wt%.
In the present invention, the content of the 1-hydroxycyclohexyl phenyl ketone in the photocurable coating is 0.3 to 1 wt%, specifically 0.3 wt%, 0.35 wt%, 0.4 wt%, 0.45 wt%, 0.5 wt%, 0.55 wt%, 0.6 wt%, 0.65 wt%, 0.7 wt%, 0.75 wt%, 0.8 wt%, 0.85 wt%, 0.9 wt%, 0.95 wt%, or 1 wt%.
In the present invention, the silicone defoamer is preferably available under the trade designation byk-067A, which is available from Bick, Germany. In the present invention, the content of the silicone antifoaming agent in the photocurable coating is 0.3 to 1 wt%, specifically 0.3 wt%, 0.35 wt%, 0.4 wt%, 0.45 wt%, 0.5 wt%, 0.55 wt%, 0.6 wt%, 0.65 wt%, 0.7 wt%, 0.75 wt%, 0.8 wt%, 0.85 wt%, 0.9 wt%, 0.95 wt%, or 1 wt%.
In the present invention, the polyether-modified polysiloxane is preferably SF-733, which is provided by BioMax (trade Mark). In the present invention, the content of the polyether-modified polysiloxane in the photocurable coating material is 0.3 to 1 wt%, specifically 0.3 wt%, 0.35 wt%, 0.4 wt%, 0.45 wt%, 0.5 wt%, 0.55 wt%, 0.6 wt%, 0.65 wt%, 0.7 wt%, 0.75 wt%, 0.8 wt%, 0.85 wt%, 0.9 wt%, 0.95 wt%, or 1 wt%.
The invention also provides a preparation method of the photocureable coating, which comprises the following steps:
mixing epoxy acrylate, polyurethane acrylate, 2-phenoxyethyl acrylate, 1-hydroxycyclohexyl phenyl ketone, an organic silicon defoaming agent and polyether modified polysiloxane according to a proportion to obtain the photocuring coating.
In the preparation method of the photocureable coating provided by the invention, the raw materials are directly and uniformly mixed to obtain the photocureable coating provided by the invention. Wherein the mixing device is preferably a disperser.
According to the invention, the photocureable coating with good wear resistance, washing resistance and yellowing resistance is obtained by optimally designing the component formula of the photocureable coating. The coating is very suitable for serving as a coating material on the outermost layer of the pull head, is used for protecting the pull head, solves the problems that a color film on the surface of the pull head is easy to wear and yellow, and prolongs the service life of the pull head. In addition, the photocureable coating provided by the invention does not contain volatile organic solvents, and is green and environment-friendly.
The invention also provides the pull head, wherein the outermost layer of the pull head is a photocuring coating, and the photocuring coating is formed by ultraviolet curing the photocuring coating in the technical scheme. Wherein the ultraviolet radiation intensity of the ultraviolet curing is preferably 100-500 mu W/cm2Specifically, it may be 240. mu.W/cm2(ii) a The thickness of the photocuring coating is preferably 3-8 μm, and specifically can be 3 μm, 3.5 μm, 4 μm, 4.5 μm, 5 μm, 5.5 μm, 6 μm, 6.5 μm, 7 μm, 7.5 μm or 8 μm.
In one embodiment provided by the present invention, the slider includes: the zipper puller comprises a puller body, a color film and a light curing coating, wherein the color film is compounded on the surface of the puller body, and the light curing coating is compounded on the surface of the color film. Wherein the material of the slider body includes, but is not limited to, a resin material; the color film can be selected according to actual requirements, such as a metal color film.
The surface of the pull head provided by the invention is provided with the coating formed by curing the photocuring coating provided by the invention, and the coating can well protect the pull head, so that the problems that a film is easily worn and yellowed on the surface of the pull head in a color mode are solved, and the service life of the pull head is prolonged.
The invention also provides a zipper, which comprises the zipper head in the technical scheme. The zipper provided by the invention comprises the zipper head, so that the problems that a color film is easy to wear and turn yellow on the surface of the zipper head part of the zipper can be solved, and the service life of the zipper is prolonged.
For the sake of clarity, the following examples are given in detail.
In the following examples of the present invention, the specific information of each raw material used is as follows:
epoxy acrylate: DY1101, CAS71281-65-7, Kalin Ruiyang chemical;
urethane acrylate: trade designation Agisyn670a2, disembarkia;
acrylate ester: trademark V-5500, Nippon DIC corporation;
and (3) organic silicon defoaming agent: the trade mark byk-067A, Bike Germany;
polyether-modified polysiloxane: trade mark SF-733, BioMax (trade mark USA).
Example 1
1) The coating formula comprises:
45 wt% of epoxy acrylate, 16 wt% of polyurethane acrylate, 30 wt% of acrylate, 6 wt% of 2-phenoxyethyl acrylate, 1 wt% of 1-hydroxycyclohexyl phenyl ketone, 1 wt% of an organic silicon defoaming agent and 1 wt% of polyether modified polysiloxane.
2) Preparing the coating:
and (3) putting the raw materials into a dispersion machine according to the formula in no sequence, and dispersing and stirring uniformly at a high speed to obtain the coating to be sprayed.
3) Preparing a pull head:
sticking a color film on the surface of the resin pull head; then, spraying the coating on the surface of the pad pasting by using coating equipment, wherein the spraying thickness is 5 mu m, and the spraying speed is 6 m/min; after the coating is finished, ultraviolet irradiation (240 mu W/cm) is carried out on the surface sprayed with the coating2) And curing the coating to obtain a finished product.
Example 2
1) The coating formula comprises:
30 wt% of epoxy acrylate, 25 wt% of polyurethane acrylate, 40 wt% of acrylate, 3 wt% of 2-phenoxyethyl acrylate, 0.5 wt% of 1-hydroxycyclohexyl phenyl ketone, 0.5 wt% of organic silicon defoamer and 1 wt% of polyether modified polysiloxane.
2) Preparing the coating:
and (3) putting the raw materials into a dispersion machine according to the formula in no sequence, and dispersing and stirring uniformly at a high speed to obtain the coating to be sprayed.
3) Preparing a pull head:
sticking a color film on the surface of the resin pull head; then, spraying the coating on the surface of the pad pasting by using coating equipment, wherein the spraying thickness is 4 mu m, and the spraying speed is 5 m/min; after the coating is finished, ultraviolet irradiation (240 mu W/cm) is carried out on the surface sprayed with the coating2) And curing the coating to obtain a finished product.
Example 3
1) The coating formula comprises:
60 wt% of epoxy acrylate, 5 wt% of polyurethane acrylate, 30 wt% of acrylate, 3 wt% of 2-phenoxyethyl acrylate, 1 wt% of 1-hydroxycyclohexyl phenyl ketone, 0.5 wt% of organic silicon defoamer and 0.5 wt% of polyether modified polysiloxane.
2) Preparing the coating:
and (3) putting the raw materials into a dispersion machine according to the formula in no sequence, and dispersing and stirring uniformly at a high speed to obtain the coating to be sprayed.
3) Preparing a pull head:
sticking a color film on the surface of the resin pull head; then, spraying the coating on the surface of the pad pasting by using coating equipment, wherein the spraying thickness is 6 mu m, and the spraying speed is 6 m/min; after the coating is finished, ultraviolet irradiation (240 mu W/cm) is carried out on the surface sprayed with the coating2) And curing the coating to obtain a finished product.
Performance testing
The finished sliders prepared in the examples 1-3 are respectively assembled into zippers, and the zippers are subjected to 1000 times of load pulling, 5 times of water washing and yellowing resistance tests, wherein the load pulling is tested according to a load pulling method in QB/T2173-2014 nylon zippers, the number of the zippers is No. 5, the water washing is carried out according to the washing test procedure of ISO633020124N, the specific conditions are that the water temperature is 40 ℃, 17L water, 68 grams of washing powder (SDCECE (A) detergent) and a W555h washing machine, the yellowing resistance test is carried out in a sun-drying machine, the temperature in a cabin of the sun-drying machine is 35 ℃, the blackboard temperature is 48 ℃, the relative humidity in the cabin is 40%, and the irradiance is 42W/m2。
The test results are shown in table 1:
TABLE 1 test results of tensile load, water washing, yellowing resistance
Example 1 Example 2 Example 3
Water wash grade 4 stage Stage 2 Stage 2
Load pull Qualified Qualified Qualified
48 hours of illumination of sun-curing machine No change in color No change in color No change in color
In table 1, the washing grade was determined based on the degree of wear of the slider after washing. Referring to fig. 1, fig. 1 is a digital photograph of wear degrees of sliders with different washing grades provided by an embodiment of the present invention, wherein the digital photograph sequentially shows 1-5 grades from left to right in the drawing.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (10)

1. A photocureable coating comprises the following components in percentage by mass:
Figure FDA0002469152830000011
2. the photocurable coating of claim 1 wherein the epoxy acrylate is designated by the designation DY 1101; the polyurethane acrylate is named Agisyn670A 2; the grade of the acrylic ester is V-5500; the grade of the organic silicon defoaming agent is byk-067A; the grade of the polyether modified polysiloxane is SF-733.
3. The photocurable coating according to claim 1, comprising, in mass percent:
Figure FDA0002469152830000012
4. a method for preparing the photocurable coating of claim 1, comprising the steps of:
mixing epoxy acrylate, polyurethane acrylate, 2-phenoxyethyl acrylate, 1-hydroxycyclohexyl phenyl ketone, an organic silicon defoaming agent and polyether modified polysiloxane according to a proportion to obtain the photocuring coating.
5. The production method according to claim 4, wherein the mixing is performed in a disperser.
6. A slider characterized in that the outermost layer of the slider is a photo-curable coating formed by ultraviolet curing the photo-curable coating according to any one of claims 1 to 3.
7. The slider according to claim 6, wherein the thickness of said photo-curable coating is 3 to 8 μm.
8. The pull head of claim 6, wherein the pull head comprises: the zipper puller comprises a puller body, a color film and a light curing coating, wherein the color film is compounded on the surface of the puller body, and the light curing coating is compounded on the surface of the color film.
9. A slide fastener comprising the slider according to any one of claims 6 to 8.
10. Use of the photocurable coating according to any one of claims 1 to 3 as a coating material for the outermost layer of a slider.
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